FR2472461A1 - Dry blending and fusion of reground thermoplastics - and wood-based particles, to produce cheap granules for reprocessing by moulding or extrusion - Google Patents

Dry blending and fusion of reground thermoplastics - and wood-based particles, to produce cheap granules for reprocessing by moulding or extrusion Download PDF

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FR2472461A1
FR2472461A1 FR7932148A FR7932148A FR2472461A1 FR 2472461 A1 FR2472461 A1 FR 2472461A1 FR 7932148 A FR7932148 A FR 7932148A FR 7932148 A FR7932148 A FR 7932148A FR 2472461 A1 FR2472461 A1 FR 2472461A1
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particles
wood
composite material
material according
extrusion
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PERSON YVES
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

A composite moulding material comprises a blend of chopped wood particles and reground thermoplastic material contg. 40-80% wt. of the wood-based material, where the particles have a mean length of 5-7mm and none has a section greater than 1 sq.mm. The particles are blended and bound by fusion of the thermoplastic constituents. The components are dry belded cold under shear conditions which fuse the thermoplastic constituents without involving external heating, pref. using a screw extrusion blender opt. fitted with a face cutting die to produce composite granules. Additives such as colourants, stabilisers, fire-retardants may also be added during blending. For re-use of sawdust, chopped savings, chopped packaging films etc., to produce a composite granulate suitable for injection moulding, extrusion, milling, thermoforming etc.

Description

La présente invention concerne un nouveau matériau composite à base de bois notamment et de déchets de matières plastiques et son procédé d'obtention. The present invention relates to a new composite material based in particular on wood and plastic waste and its production process.

Le but de l'invention est la récupération de certains déchets de matieres plastiques tels que les feuilles ou films utilisés pour l'emballage, le suremballage, la réalisation de serres etc... ainsi que des déchets de bois, en vue de réaliser un matériau composite de faible coût de revient et susceptible de nombreuses applications grâce à ses bonnes qualités et propriétés mécaniques en particulier. The object of the invention is the recovery of certain plastic waste materials such as sheets or films used for packaging, overwrapping, the production of greenhouses etc ... as well as wood waste, in order to achieve a composite material of low cost price and susceptible of numerous applications thanks to its good qualities and mechanical properties in particular.

A cet effet, l'invention a pour objet un matériau composite du type à base de bois ou analogue et de matière plastique caractérisé en ce qu'il comprend entre 40 et 802d en poids de bois ou analogue sous forme de particules n'excédant pas 1 mm2 de section et 5 à 7 mm dans leur plus grande dimension et entre 60 et 20 ó en poids de matière plastique intimement melée aux dites particules et agglomérée par la seule chaleur, ladite matière plastique provenant du déchiquetage ou réduction en parcelles ou particules de divers produits en matières thermoplastiques de récupération. To this end, the subject of the invention is a composite material of the type based on wood or the like and of plastic material characterized in that it comprises between 40 and 802d by weight of wood or the like in the form of particles not exceeding 1 mm2 in cross-section and 5 to 7 mm in their largest dimension and between 60 and 20% by weight of plastic material intimately mixed with said particles and agglomerated by heat alone, said plastic material coming from shredding or reduction into plots or particles of various products in recycled thermoplastics.

Le bois utilisé provient de feuilles ou de résineux et est avantageusement obtenu à partir des résidus de bois tels que de la sciure, des copeaux, du bois éclaté etc.  The wood used comes from leaves or conifers and is advantageously obtained from wood residues such as sawdust, shavings, split wood, etc.

Ces résidus de bois sont au préalable criblés et éventuellement déchiquetés, broyés ou préparés (bois éclaté notamment) en vue agavoir des conditions granulométriques acceptables. These wood residues are screened beforehand and possibly shredded, crushed or prepared (notably split wood) with a view to accepting acceptable particle size conditions.

Qu'il s'agisse de grains de bois rond (sciure) ou de fibres allongées (bois éclaté) la section des particules ne doit pas, de préférence, dépasser i min2 alors que la plus grande dimension de ces particules allongées ne doit pas excéder 5 à 7 mm.Whether it is round wood grains (sawdust) or elongated fibers (splintered wood) the section of the particles should not preferably exceed i min2 while the largest dimension of these elongated particles must not exceed 5 to 7 mm.

La matière plastique provient de la récupération de déchets de matières thermoplastiques de compositions hétérogènes et de provenances diverses. Ces déchets sont notamment des feuilles ou films de polyéthylène haute ou basse pression, rétractactable ou non, de polychiorure de vinyle etc... ayant servi d'emballages divers, de suremballages, de matériaux pour la réalisation de serres, de revêtements pour culture hors sol, de films protecteurs, housses etc... ces divers produits étant maintenant couramment utilisés dans l'agriculture, l'horticulture et les transports. The plastic material comes from the recovery of waste thermoplastic materials of heterogeneous compositions and from various sources. This waste is in particular sheets or films of high or low pressure polyethylene, retractable or not, of polyvinyl chloride etc ... having been used for various packaging, overpackaging, materials for the production of greenhouses, coatings for cultivation outside soil, protective films, covers etc ... these various products are now commonly used in agriculture, horticulture and transport.

La présente invention concerne également un procédé pour l'obtention d'untel produit composite à partir notamment des produits de base ci-dessus. The present invention also relates to a process for obtaining such a composite product from in particular the above basic products.

A cet effet, les particules de bois, après préparation et criblage en vue d'obtenir les conditions granulométriques requises et,après séchage, sont mélangées intimement dans les proportions en poids également requises, avec des particules ou parcelles desdits films ou feuilles de matière plastique. To this end, the particles of wood, after preparation and screening in order to obtain the required particle size conditions and, after drying, are intimately mixed in the proportions by weight also required, with particles or plots of said plastic films or sheets .

Ces particules ou parcelles sont obtenues par exemple par passage dans un broyeur à couteaux des feuilles thermoplastiques après d'éventuels lavage et séchage de celles-ci. On peut bien entendu déchiqueter les feuilles à l'aide d'autres moyens selon par exemple la nature et la forme des produits en matière plastique de récupération. These particles or plots are obtained for example by passing a thermoplastic sheet through a knife mill after possible washing and drying thereof. It is of course possible to shred the sheets using other means, for example depending on the nature and shape of the plastic recovery products.

I1 est souhaitable dans le cas du déchiquetage des feuilles de ne pas obtenir des parcelles de dimensions supérieures à 5 à 7 mm. It is desirable in the case of shredding the sheets not to obtain plots of dimensions greater than 5 to 7 mm.

Ledit mélange est effectué à sec et à froid. Said mixing is carried out dry and cold.

Le mélange ainsi obtenu est ensuite envoyé dans un densificateur avantageusement constitué par un granulateur à vis. I1 s'agit d'un dispositif bien connu comportant, à l'intérieur d'une chambre cylindrique perforée de trous, un rotor comprimant ledit mélange contre la paroi de la chambre. Ce traitement provoque une friction intense engendrant un echauffement suffisant pour ramollir les matières plastiques qui s'amalgament aux particules de bois, la pate ainsi formée passant au travers des trous calibrés de ladite chambre cylindrique. Un ou plusieurs couteaux appliqués contre la paroi externe de la chambre sectionnent despetits boudins de pate qui en sortent et forment ainsi des granulés. The mixture thus obtained is then sent to a densifier advantageously constituted by a screw granulator. I1 is a well known device comprising, inside a cylindrical chamber perforated with holes, a rotor compressing said mixture against the wall of the chamber. This treatment causes intense friction generating sufficient heating to soften the plastics which amalgamate with the particles of wood, the paste thus formed passing through the calibrated holes of said cylindrical chamber. One or more knives applied against the external wall of the chamber cut small dough strands which exit therefrom and thus form granules.

Les granulés sont ensuite acheminés vers un poste de stockage et conditionnement après passage dans un circuit de refroidissement par air. The granules are then transported to a storage and conditioning station after passing through an air cooling circuit.

I1 est particulièrement intéressant de commercialiser sous forme de granulés le produit composite selon l'invention. It is particularly advantageous to market the composite product according to the invention in the form of granules.

Un tel demi-produit est en effet facile à conditionner, transporter et stocker. I1 est mis ensuite en oeuvre sur place à l'aide de presses à injecter, extrudeuses etc... en vue de réaliser des produits spécifiques définis et variés selon les appli cations envisagées. Such a semi-finished product is indeed easy to package, transport and store. It is then implemented on site using injection presses, extruders, etc., in order to produce specific products defined and varied according to the applications envisaged.

L'amalgame des particules de bois.et de matières plastiques par ramollissement de ces dernières se fait de préférence par friction sans apport de chaleur (par un densificateur ou similaire) car il évite l'apport de chaleur que nécessiterait une fusion ce qui rend le procédé encore plus économique. The amalgam of particles of wood and plastic by softening them is preferably done by friction without heat input (by a densifier or the like) because it avoids the heat input that would require a fusion which makes the even more economical.

Le produit composite obtenu conformément à l'invention est thermoformable, solide et hydrofuge avec des degrés plus ou moins élevés en fonction de la charge en matières plastiques. The composite product obtained in accordance with the invention is thermoformable, solid and water-repellent with varying degrees depending on the load of plastics.

I1 peut servir à la fabrication de pièces moulées, de feuilles éventuellement thermoformées ultérieurement, de cornières d'emballage, etc... It can be used for the production of molded parts, sheets which may be thermoformed later, packaging angles, etc.

En faisant varier les proportions de bois et de plastique on obtient ainsi différents degrés de souplesse ou de dureté,
Des additifs peuvent etre prévus, par exemple un colorant ou un produit ignifuge, ajouté au cours de la mise en oeuvre des granulés (extension, injection) ou après la mise en oeuvre sous forme d'introduction dans la masse du produit fini.
By varying the proportions of wood and plastic, we thus obtain different degrees of flexibility or hardness,
Additives can be provided, for example a dye or a flame retardant, added during the implementation of the granules (extension, injection) or after the implementation in the form of introduction into the mass of the finished product.

D'autres additifs tendant à améliorer certaines caractéristiques mécaniques ou de présentation sont envisageables (addition avant extrusion ou injection). Other additives tending to improve certain mechanical or presentation characteristics can be envisaged (addition before extrusion or injection).

On se rend compte ainsi de l'intérêt du procédé de l'invention, lequel permet de manière particulièrement économique, de récupérer des déchets qui, sans cela, seraient inutiles, perdus et encombrants, en vue d'obtenir un matériau bon marché et susceptible de nombreuses applications pratiques. One thus realizes the interest of the process of the invention, which makes it possible in a particularly economic way, to recover waste which, without that, would be useless, lost and bulky, with a view to obtaining a cheap and susceptible material many practical applications.

Bien entendu, l'invention n'est pas limitée aux exemples ci-dessus mais en couvre au contraire toutes les variantes. Of course, the invention is not limited to the above examples but on the contrary covers all variants.

C'est ainsi que les déchets de bois pourraient oestre remplacés par dês déchets analogues tels que papiers, paille hachée etc...This is how wood waste could be replaced by similar waste such as paper, chopped straw, etc.

quant aux déchets de matière plastique ils peuvent être de différentes origines, les matières plastiques, pourvu qu'elles ne soient pas thermodurcissables, pouvant être mélangées. as for plastic waste they can be of different origins, plastic materials, provided that they are not thermosetting, can be mixed.

Claims (7)

REVENDICATIONS.CLAIMS. 1. Matériau composite du type à basé de bois ou analogue et de matières plastiques caractérisé en ce qu'il comprend entre 40 et 80% en poids de bois ou analogue sous forme de par 2 ticules n'excédant pas 1 mm de section et S à 7 mm dans leur plus grande dimension et entre 60 et 20% en poids de matière plastique intimement mêlée aux dites particules et agglomérée par la seule chaleur, ladite matière plastique provenant du déchiquetage ou réduction ou parcelles ou particules de divers produits en matières thermoplastiques de récupération. 1. Composite material of the type based on wood or the like and plastics, characterized in that it comprises between 40 and 80% by weight of wood or the like in the form of per 2 sheets not exceeding 1 mm in cross section and S at 7 mm in their largest dimension and between 60 and 20% by weight of plastic material intimately mixed with said particles and agglomerated by heat alone, said plastic material coming from shredding or reduction or plots or particles of various thermoplastic products of recovery. 2. Matériau composite suivant la revendication 1 carac térisé en ce qu'il est réalisé à partir de matières thermoplastiques de natures diverses ou non, sous forme de feuilles ou films minces déchiquetés en parcelles dont les plus grandes dimensions n'excèdent pas 5 à 7 mm.  2. Composite material according to claim 1 charac terized in that it is made from thermoplastic materials of various kinds or not, in the form of sheets or thin films shredded into plots whose largest dimensions do not exceed 5 to 7 mm. 3. Matériau composite suivant la revendication 1 ou 2 caractérisé en ce qu'il comporte en outre un ou plusieurs additifs tels que colorant, produit ignifuge, etc... incorporés dans la masse. 3. Composite material according to claim 1 or 2 characterized in that it further comprises one or more additives such as dye, flame retardant, etc. ... incorporated in the mass. 4. Matériau composite suivant l'une des revendications 1 à 3 caractérisé en ce qu'il se présente-sous la forme de granulés mis en oeuvre ultérieurement par extrusion, injection, thermoformage etc...  4. Composite material according to one of claims 1 to 3 characterized in that it is in the form of granules used subsequently by extrusion, injection, thermoforming etc ... 5. Procédé pour l'obtention du matériau composite selon l'une des revendications 1 à 3-caractérisé en ce qu'il consiste à préparer, d'une part, les particules de bois, à les cribler et les sécher éventuellement en vue de leur conférer la granulométrie requise, à préparer, d'autre part, les particules de matière plastique, en vue de leur conférer la granulométrie requise, puis à mélanger dans les proportions en poids requises ces deux constituants et à agglomérer ou amalgamer ceux-ci par ramollissement des particules de matière plastique. 5. Method for obtaining the composite material according to one of claims 1 to 3-characterized in that it consists in preparing, on the one hand, the wood particles, in screening them and optionally drying them in order to to give them the required particle size, to prepare, on the other hand, the plastic particles, with a view to giving them the required particle size, then to mix these two constituents in the proportions by weight required and to agglomerate or amalgamate them with softening of plastic particles. 6. Procédé selon la revendication 5 caractérisé en ce que l'amalgame desdites particules des deux constituants est effectué par friction sans apport de chaleur extérieure.  6. Method according to claim 5 characterized in that the amalgamation of said particles of the two constituents is carried out by friction without the addition of external heat. 7. Procédé selon la revendication 6, plus particulièrement destiné à ltobtention du matériau selon la revendication 4, caractérisé en ce que ladite friction est opérée par passage dans un densificateur constitué par un granulateur à vis.  7. Method according to claim 6, more particularly intended for obtaining the material according to claim 4, characterized in that said friction is operated by passage through a densifier constituted by a screw granulator.
FR7932148A 1979-12-27 1979-12-27 Dry blending and fusion of reground thermoplastics - and wood-based particles, to produce cheap granules for reprocessing by moulding or extrusion Withdrawn FR2472461A1 (en)

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FR7932148A FR2472461A1 (en) 1979-12-27 1979-12-27 Dry blending and fusion of reground thermoplastics - and wood-based particles, to produce cheap granules for reprocessing by moulding or extrusion

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0515990A2 (en) * 1991-05-27 1992-12-02 Hoechst Aktiengesellschaft Moulded article of inert particles and thermally crosslinkable resin
EP0781806A3 (en) * 1995-12-28 1997-08-13 INDUSTRIAL TECHNICAL R&D LABORATORY INC. Cellulose powder pellets with a polyethylene terephthalate resin as a binder and method for manufacturing the same
FR2800083A1 (en) * 1999-10-26 2001-04-27 Cie Du Dev Durable Production of a compound material of wood particles in a synthetic polymer matrix for injection molding or extrusion, has a chemical modification of the wood before agglomeration to prevent chemical reactions with the polymers

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0515990A2 (en) * 1991-05-27 1992-12-02 Hoechst Aktiengesellschaft Moulded article of inert particles and thermally crosslinkable resin
EP0515990A3 (en) * 1991-05-27 1993-05-26 Hoechst Aktiengesellschaft Moulded article of inert particles and thermally crosslinkable resin
EP0781806A3 (en) * 1995-12-28 1997-08-13 INDUSTRIAL TECHNICAL R&D LABORATORY INC. Cellulose powder pellets with a polyethylene terephthalate resin as a binder and method for manufacturing the same
FR2800083A1 (en) * 1999-10-26 2001-04-27 Cie Du Dev Durable Production of a compound material of wood particles in a synthetic polymer matrix for injection molding or extrusion, has a chemical modification of the wood before agglomeration to prevent chemical reactions with the polymers

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