FR2113179A5 - Rhodium and iridium complexes - prepn and use as catalysts for hydrocarbon reactions - Google Patents

Rhodium and iridium complexes - prepn and use as catalysts for hydrocarbon reactions

Info

Publication number
FR2113179A5
FR2113179A5 FR7138190A FR7138190A FR2113179A5 FR 2113179 A5 FR2113179 A5 FR 2113179A5 FR 7138190 A FR7138190 A FR 7138190A FR 7138190 A FR7138190 A FR 7138190A FR 2113179 A5 FR2113179 A5 FR 2113179A5
Authority
FR
France
Prior art keywords
diene
dienes
prepn
rhodium
catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7138190A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of FR2113179A5 publication Critical patent/FR2113179A5/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C07C5/2562—Catalytic processes with hydrides or organic compounds
    • C07C5/2581—Catalytic processes with hydrides or organic compounds containing complexes, e.g. acetyl-acetonates
    • C07C5/2587—Metal-hydrocarbon complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
    • C07C5/52—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor with a hydrocarbon as an acceptor, e.g. hydrocarbon disproportionation, i.e. 2CnHp -> CnHp+q + CnHp-q
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0033—Iridium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Cationic complexes of formula ((A)xM(Z)y ) +x- (I) (where A is a neutral diene, esp. cyclopentadiene, cyclooctadiene (partic. 1,5-diene (A')) or norbornadiene; M is monovalent rh or Ir; Z is a ligand contg. a neutral mono- or divalent unit, excepting P- and/or As-contg. ligands, and esp. cnsists of MeCN, PhCH2CN, dimethyl or formamide or -sulphoxide, tert-butyl-NC or acetone; X is a monovalent anion gp.; x is 0, 1 or 2; y is 0, 1, 2 or 4 and x and y are such that sum of coordination positions occupied by A and Z is 4) catalyse disproportionation of dienes, hydrogenation of olefines and dienes and isomerisation of dienes and olefins. They are prepd. by reacting ((diene)M(AcAc)) with diene in presence of an electrophilic reagent, separating metal dienyl deriv. and opt. reacting with Z.
FR7138190A 1970-10-26 1971-10-25 Rhodium and iridium complexes - prepn and use as catalysts for hydrocarbon reactions Expired FR2113179A5 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5072870 1970-10-26

Publications (1)

Publication Number Publication Date
FR2113179A5 true FR2113179A5 (en) 1972-06-23

Family

ID=10457105

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7138190A Expired FR2113179A5 (en) 1970-10-26 1971-10-25 Rhodium and iridium complexes - prepn and use as catalysts for hydrocarbon reactions

Country Status (2)

Country Link
DE (1) DE2153314A1 (en)
FR (1) FR2113179A5 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2474026A1 (en) * 1980-01-23 1981-07-24 Montedison Spa PROCESS FOR CATALYTIC REDUCTION OF UNSATURATED CETONES

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5089536A (en) * 1982-11-22 1992-02-18 Minnesota Mining And Manufacturing Company Energy polmerizable compositions containing organometallic initiators
US5191101A (en) * 1982-11-22 1993-03-02 Minnesota Mining And Manufacturing Company Energy polymerizable compositions containing organometallic initiators

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2474026A1 (en) * 1980-01-23 1981-07-24 Montedison Spa PROCESS FOR CATALYTIC REDUCTION OF UNSATURATED CETONES

Also Published As

Publication number Publication date
DE2153314A1 (en) 1972-04-27

Similar Documents

Publication Publication Date Title
Bond Adsorption and co-ordination of unsaturated hydrocarbons with metal surfaces and metal atoms
GB1440801A (en) Silylhydrocarbyl phosphines their preparation and their use
GB1451561A (en) Preparation of zerovalent phosphorus arsenic or antimony substituted rhodium compounds and their use in the selective carbonylation of olefins
KR910000764A (en) Complexes Containing Sulfonated Phenyl Phospanes
Werner et al. Bifunctional Phosphines as Ligands and as Substrates: Synthesis of Iridium Hydrido, Carbonyl, Alkynyl, Vinyl, and Vinylidene Complexes from i-Pr2PCH2CH2X (X= OMe, NMe2), Including the X-ray Crystal Structure of an Unusual Cyclometalated Product
GB1405212A (en) Process for catalysing h-d exchange using anchored homogeneous- type catalysts
FR2113179A5 (en) Rhodium and iridium complexes - prepn and use as catalysts for hydrocarbon reactions
GB1292946A (en) Process for producing a reaction product of a 1,3-conjugated diene compounds and a compound having a terminal vinyl group
NL7114593A (en) Rhodium and iridium complexes - prepn and use as catalysts for hydrocarbon reactions
Bennett et al. Nickel Complexes As Hydrosilation Catalysts
Okoroafor et al. New ferrocenyl sulfides and selenides. Preparation and application as efficient selective hydrogenation catalysts
Lyon et al. Use of transition metal complexes as selective hydrogenation catalysts
GB1448090A (en) Catalytic hydroformylation process employing rhodium coordination complexes
KR910019958A (en) Process for preparing secondary amines and catalyst system for same
GB1325199A (en) Process for the hydroformylation of olefines and catalysts for use therein
GB1139210A (en) Preparation of unsaturated organic esters
GB1368434A (en) Hydroformylation of propylene
ES431472A1 (en) Hydrogenation of rubbers
GB1316795A (en) Process for preparing cationic complexes of rhodium and iridium
GB1377569A (en) Organometallic complexes and production of the same
GB1129554A (en) Dinuclear bridged transition metal complexes
Hirai et al. Isomerization of hexene-1 catalyzed by ruthenium (III), rhodium (III), and palladium (II) chlorides
Lyons Catalytic activation of the carbon–hydrogen bond by some iridium (I) complexes: hydrogen transfer reactions in cyclic dienes
GB1318881A (en) Hydroformylation process
GB1367623A (en) Hydroformylation using iridium catalyst

Legal Events

Date Code Title Description
ST Notification of lapse