ES8701732A1 - Procedimiento para la obtencion de derivados de azolilmetil-ciclopropil-carbinol sustituido - Google Patents

Procedimiento para la obtencion de derivados de azolilmetil-ciclopropil-carbinol sustituido

Info

Publication number
ES8701732A1
ES8701732A1 ES548445A ES548445A ES8701732A1 ES 8701732 A1 ES8701732 A1 ES 8701732A1 ES 548445 A ES548445 A ES 548445A ES 548445 A ES548445 A ES 548445A ES 8701732 A1 ES8701732 A1 ES 8701732A1
Authority
ES
Spain
Prior art keywords
carbinol derivatives
cyclopropyl
aril
cyclopropyl carbinol
obtaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES548445A
Other languages
English (en)
Other versions
ES548445A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE3440116A external-priority patent/DE3440116A1/de
Priority claimed from DE19853522440 external-priority patent/DE3522440A1/de
Priority claimed from DE19853534310 external-priority patent/DE3534310A1/de
Application filed by Bayer AG filed Critical Bayer AG
Publication of ES548445A0 publication Critical patent/ES548445A0/es
Publication of ES8701732A1 publication Critical patent/ES8701732A1/es
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
    • C07D295/112Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/80Ketones containing a keto group bound to a six-membered aromatic ring containing halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/80Ketones containing a keto group bound to a six-membered aromatic ring containing halogen
    • C07C49/813Ketones containing a keto group bound to a six-membered aromatic ring containing halogen polycyclic
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/081,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/08Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/12Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/34Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/36Compounds containing oxirane rings with hydrocarbon radicals, substituted by nitrogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Epoxy Compounds (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE DERIVADOS DE AZOLILMETIL-CICLOPROPILCARBINOL SUSTITUIDO DE FORMULA GENERAL (I). CONSISTE EN HACER REACCIONAR ARIL-CICLOPROPILCETONAS CON DIMETILOXOSULFONIUM-METILIDA, EN PRESENCIA DE UN DILUYENTE, OBTENIENDOSE OXIRANOS DE ARIL-CICLOPROPILO, QUE SE HACEN REACCIONAR XON AZOLES EN PRESENCIA DE UN DILUYENTE Y UNA BASE. SE EMPLEAN COMO REGULADORES DEL CRECIMIENTO DE LAS PLANTAS Y COMO FUNGICIDAS.
ES548445A 1984-11-02 1985-10-31 Procedimiento para la obtencion de derivados de azolilmetil-ciclopropil-carbinol sustituido Expired ES8701732A1 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3440116A DE3440116A1 (de) 1984-11-02 1984-11-02 Substituierte azolylmethyl-cyclopropyl-carbinol-derivate
DE19853522440 DE3522440A1 (de) 1985-06-22 1985-06-22 Substituierte azolylmethyl-cyclopropyl-carbinol-derivate
DE19853534310 DE3534310A1 (de) 1985-09-26 1985-09-26 Substituierte azolylmethyl-cyclopropyl-carbinol-derivate

Publications (2)

Publication Number Publication Date
ES548445A0 ES548445A0 (es) 1986-12-01
ES8701732A1 true ES8701732A1 (es) 1986-12-01

Family

ID=27192476

Family Applications (5)

Application Number Title Priority Date Filing Date
ES548445A Expired ES8701732A1 (es) 1984-11-02 1985-10-31 Procedimiento para la obtencion de derivados de azolilmetil-ciclopropil-carbinol sustituido
ES555048A Expired ES8703852A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de derivados de azolilmetil-ciclopropilcarbinol sustituido
ES555050A Expired ES8703854A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de aril-ciclopropil-oxiranos
ES555049A Expired ES8703853A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de arilciclopropil-cetonas
ES555047A Expired ES8703851A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de derivados de azolilmetil-ciclopropilcarbinol sustituido

Family Applications After (4)

Application Number Title Priority Date Filing Date
ES555048A Expired ES8703852A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de derivados de azolilmetil-ciclopropilcarbinol sustituido
ES555050A Expired ES8703854A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de aril-ciclopropil-oxiranos
ES555049A Expired ES8703853A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de arilciclopropil-cetonas
ES555047A Expired ES8703851A1 (es) 1984-11-02 1986-05-16 Procedimiento para la obtencion de derivados de azolilmetil-ciclopropilcarbinol sustituido

Country Status (14)

Country Link
US (3) US5089640A (es)
EP (1) EP0180136B1 (es)
JP (1) JPH0662582B2 (es)
KR (1) KR860004034A (es)
CN (1) CN1008735B (es)
BR (1) BR8505476A (es)
CA (2) CA1257869A (es)
DE (1) DE3581051D1 (es)
DK (1) DK504485A (es)
ES (5) ES8701732A1 (es)
HU (1) HU198118B (es)
IL (1) IL76896A (es)
NZ (1) NZ214013A (es)
PT (1) PT81368B (es)

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DE3812967A1 (de) * 1987-06-24 1989-01-05 Bayer Ag Azolylmethyl-cyclopropyl-derivate
DE3813129A1 (de) * 1987-07-01 1989-01-12 Bayer Ag Hydroxyethyl-azolyl-derivate
DE3722133A1 (de) * 1987-07-04 1989-01-12 Bayer Ag Azolyl-tetrahydropyran-derivate
DE3813874A1 (de) * 1987-07-10 1989-01-19 Bayer Ag Hydroxyalkyl-azolyl-derivate
EP0322800A1 (en) * 1987-12-25 1989-07-05 Sumitomo Pharmaceuticals Company, Limited Process for preparation of sulfone derivatives
DE3811302A1 (de) * 1988-04-02 1989-10-19 Bayer Ag Derivate des triazolylmethyl-cyclopropyl-carbinols als materialschutzmittel
US5216180A (en) * 1989-06-30 1993-06-01 Bayer Aktiengesellschaft Microbicidal hydroxyethyl-cyclopropyl-azolyl derivatives
DE3921481A1 (de) * 1989-06-30 1991-01-03 Bayer Ag Hydroxyethyl-cyclopropyl-azolyl-derivate
EP0489804A1 (en) * 1989-09-01 1992-06-17 Schering Corporation Asymmetric chemical synthesis and intermediates for making antifungal compounds
DE3942417A1 (de) * 1989-12-21 1991-06-27 Bayer Ag Triazolylmethyl-cyclopropyl-derivate
US5225015A (en) * 1991-04-15 1993-07-06 Corning Incorporated Method for making stiffened ceramic matrix composite panel
DE4131139A1 (de) * 1991-09-19 1993-03-25 Bayer Ag Verfahren zur herstellung von 1-fluor-cyclopropan-1-carbonsaeure
DE4412358A1 (de) * 1994-04-11 1995-10-12 Bayer Ag Cyclopropyl-ethyl-azole
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GB0131126D0 (en) * 2001-12-05 2002-12-11 Secr Defence Detection method and apparatus
KR20050113596A (ko) * 2002-12-10 2005-12-02 커먼웰쓰 사이언티픽 앤드 인더스트리얼 리서치 오가니제이션 방사선 촬영 장치
EP2315752A4 (en) * 2008-08-26 2011-09-14 Kureha Corp 5-BENZYL-4-AZOLYLMETHYL-4-SPIRO [2.4] HEPTANOL DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND AGENTS FOR AGRICULTURE AND GARDENING AND INDUSTRIAL MATERIAL PROTECTION AGENTS THEREOF
BR112012013198A2 (pt) 2009-12-08 2015-09-15 Kureha Corp derivado de azol, composto intermediário, métodos para produzir derivado de azol e um composto intermediário, e, agente de agro-horticultura ou um agente protetor de material industrial.
RU2013133873A (ru) 2010-12-21 2015-01-27 БАЙЕР КРОПСАЙЕНС ЭлПи ШЕРОХОВАТЫЕ МУТАНТЫ Bacillus И СПОСОБЫ ИХ ПРИМЕНЕНИЯ ДЛЯ УСКОРЕНИЯ РОСТА РАСТЕНИЙ, УЛУЧШЕНИЯ ЗДОРОВЬЯ РАСТЕНИЙ И БОРЬБЫ С БОЛЕЗНЯМИ И ВРЕДИТЕЛЯМИ
EP2716634A4 (en) 2011-05-31 2014-10-29 Kureha Corp TRIAZOLE COMPOUND AND USE THEREOF
WO2012165498A1 (ja) * 2011-06-03 2012-12-06 株式会社クレハ トリアゾール化合物、およびその利用
JP5858999B2 (ja) 2011-06-07 2016-02-10 株式会社クレハ 農園芸用薬剤、植物病害防除組成物、植物病害防除方法および植物病害防除用製品
BR112014005654A2 (pt) 2011-09-12 2017-03-28 Bayer Cropscience Lp métodos para melhorar a saúde e promover o crescimento de uma planta e/ou de melhorar o amadurecimento da fruta
CA2856711A1 (en) * 2011-11-25 2013-05-30 Bayer Intellectual Property Gmbh Novel heterocyclic alkanol-derivatives
JP6404235B2 (ja) * 2013-02-04 2018-10-10 シンジェンタ パーティシペーションズ アーゲー 新規な殺微生物剤
EA201692525A1 (ru) * 2014-06-10 2017-05-31 Басф Се Замещенные соединения [1,2,4]триазола и имидазола в качестве фунгицидов
DE102014226196A1 (de) * 2014-12-17 2016-06-23 Henkel Ag & Co. Kgaa Photolabile Duftstoffvorläuferverbindung
WO2016156314A1 (en) * 2015-04-02 2016-10-06 Bayer Cropscience Aktiengesellschaft Triazole derivatives as pesticides and plant growth regulators
WO2016156282A1 (en) 2015-04-02 2016-10-06 Bayer Cropscience Aktiengesellschaft Novel triazole compounds for controlling phytopathogenic harmful fungi
JP2018516235A (ja) * 2015-04-02 2018-06-21 バイエル・クロップサイエンス・アクチェンゲゼルシャフト 殺有害生物剤および植物成長調節剤としてのトリアゾール誘導体
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WO2018060071A1 (en) 2016-09-29 2018-04-05 Bayer Cropscience Aktiengesellschaft Novel triazole derivatives
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EP0086173B1 (de) 1982-01-15 1986-09-03 Ciba-Geigy Ag Fungizid wirkende und den Pflanzenwuchs regulierende Triazolcarbinolderivate
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DE3237400A1 (de) * 1982-10-08 1984-04-12 Bayer Ag, 5090 Leverkusen Substituierte 1-hydroxyethyl-triazolyl-derivate
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CH658654A5 (de) * 1983-03-04 1986-11-28 Sandoz Ag Azolderivate, verfahren zu ihrer herstellung und mittel die diese verbindungen enthalten.

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ES548445A0 (es) 1986-12-01
DK504485A (da) 1986-05-03
EP0180136A3 (en) 1987-08-12
HU198118B (en) 1989-08-28
CA1257263A (en) 1989-07-11
HUT39328A (en) 1986-09-29
ES8703853A1 (es) 1987-03-01
PT81368A (en) 1985-11-01
DK504485D0 (da) 1985-11-01
BR8505476A (pt) 1986-08-05
PT81368B (en) 1987-08-05
IL76896A (en) 1989-09-28
ES555047A0 (es) 1987-03-01
ES8703854A1 (es) 1987-03-01
US5089640A (en) 1992-02-18
ES8703851A1 (es) 1987-03-01
DE3581051D1 (de) 1991-02-07
US4921528A (en) 1990-05-01
EP0180136A2 (de) 1986-05-07
US4988382A (en) 1991-01-29
CN1008735B (zh) 1990-07-11
NZ214013A (en) 1988-07-28
ES555048A0 (es) 1987-03-01
IL76896A0 (en) 1986-02-28
CN85108725A (zh) 1986-05-10
EP0180136B1 (de) 1991-01-02
JPH0662582B2 (ja) 1994-08-17
CA1257869A (en) 1989-07-25
JPS61126049A (ja) 1986-06-13
KR860004034A (ko) 1986-06-16
ES555049A0 (es) 1987-03-01
ES555050A0 (es) 1987-03-01
ES8703852A1 (es) 1987-03-01

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