ES277668A1 - Procedimiento para la fabricacion de azulenos sustituidos en la posicion 4, 6, 8 - Google Patents
Procedimiento para la fabricacion de azulenos sustituidos en la posicion 4, 6, 8Info
- Publication number
- ES277668A1 ES277668A1 ES0277668A ES277668A ES277668A1 ES 277668 A1 ES277668 A1 ES 277668A1 ES 0277668 A ES0277668 A ES 0277668A ES 277668 A ES277668 A ES 277668A ES 277668 A1 ES277668 A1 ES 277668A1
- Authority
- ES
- Spain
- Prior art keywords
- lithium
- azulene
- butyl
- methyl
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001545 azulenes Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 3
- -1 4,8-disubstituted azulene Chemical class 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- UIBRZOTWRMHYFJ-UHFFFAOYSA-N 1,2-dihydroazulene Chemical compound C1=CC=C[C]2[CH]CCC2=C1 UIBRZOTWRMHYFJ-UHFFFAOYSA-N 0.000 abstract 1
- YSKMWUCVEPTNQM-UHFFFAOYSA-N 4,8-dimethylazulene Chemical compound CC1=CC=CC(C)=C2C=CC=C12 YSKMWUCVEPTNQM-UHFFFAOYSA-N 0.000 abstract 1
- VXAIEHZGSFJIHG-UHFFFAOYSA-N 4,8-diphenylazulene Chemical compound C12=CC=CC2=C(C=2C=CC=CC=2)C=CC=C1C1=CC=CC=C1 VXAIEHZGSFJIHG-UHFFFAOYSA-N 0.000 abstract 1
- IHKJYCHIHLFCOA-UHFFFAOYSA-N 4-methyl-6,8-diphenylazulene Chemical compound C=12C=CC=C2C(C)=CC(C=2C=CC=CC=2)=CC=1C1=CC=CC=C1 IHKJYCHIHLFCOA-UHFFFAOYSA-N 0.000 abstract 1
- JDCZAOAUDAHVHY-UHFFFAOYSA-N 4-methyl-8-phenylazulene Chemical compound C1(=CC=CC=C1)C=1C2=CC=CC2=C(C=CC1)C JDCZAOAUDAHVHY-UHFFFAOYSA-N 0.000 abstract 1
- ZMTIUFVKXNJELM-UHFFFAOYSA-N 6-butyl-4,8-diphenylazulene Chemical compound C1(=CC=CC=C1)C=1C2=CC=CC2=C(C=C(C1)CCCC)C1=CC=CC=C1 ZMTIUFVKXNJELM-UHFFFAOYSA-N 0.000 abstract 1
- CUFNKYGDVFVPHO-UHFFFAOYSA-N Azulene Natural products C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003828 azulenyl group Chemical group 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- IHLVCKWPAMTVTG-UHFFFAOYSA-N lithium;carbanide Chemical group [Li+].[CH3-] IHLVCKWPAMTVTG-UHFFFAOYSA-N 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000001256 steam distillation Methods 0.000 abstract 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 abstract 1
- 238000005979 thermal decomposition reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/47—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing ten carbon atoms
- C07C13/52—Azulenes; Completely or partially hydrogenated azulenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/14—All rings being cycloaliphatic
- C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
- C07C2602/30—Azulenes; Hydrogenated azulenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEST17868A DE1204670B (de) | 1961-05-25 | 1961-05-25 | Verfahren zur Herstellung von in 4-, 6- und 8-Stellung alkylierten, arylierten oder aralkylierten Azulenen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES277668A1 true ES277668A1 (es) | 1962-08-01 |
Family
ID=7457631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES0277668A Expired ES277668A1 (es) | 1961-05-25 | 1962-05-25 | Procedimiento para la fabricacion de azulenos sustituidos en la posicion 4, 6, 8 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3155737A (es) |
| CA (1) | CA731200A (es) |
| CH (1) | CH424742A (es) |
| DE (1) | DE1204670B (es) |
| DK (1) | DK105399C (es) |
| ES (1) | ES277668A1 (es) |
| FI (1) | FI36609A (es) |
| GB (1) | GB963310A (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2291478B (en) * | 1990-03-26 | 1996-07-10 | Marconi Co Ltd | Lithium-water reactor |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2804485A (en) * | 1955-03-07 | 1957-08-27 | Ziegler Karl | Process for preparing substituted azulenes |
| US2900426A (en) * | 1956-12-20 | 1959-08-18 | Ziegler | Process for the preparation of azulenes |
-
0
- CA CA731200A patent/CA731200A/en not_active Expired
-
1961
- 1961-05-25 DE DEST17868A patent/DE1204670B/de active Pending
-
1962
- 1962-05-11 US US194150A patent/US3155737A/en not_active Expired - Lifetime
- 1962-05-21 DK DK227662AA patent/DK105399C/da active
- 1962-05-22 FI FI36609D patent/FI36609A/fi unknown
- 1962-05-25 ES ES0277668A patent/ES277668A1/es not_active Expired
- 1962-05-25 GB GB20253/62A patent/GB963310A/en not_active Expired
- 1962-05-25 CH CH637262A patent/CH424742A/de unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH424742A (de) | 1966-11-30 |
| US3155737A (en) | 1964-11-03 |
| DE1204670B (de) | 1965-11-11 |
| CA731200A (en) | 1966-03-29 |
| GB963310A (en) | 1964-07-08 |
| DK105399C (da) | 1966-09-26 |
| FI36609A (fi) | 1967-02-10 |
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