ES2525957A1 - Method for producing synthesis gas - Google Patents

Method for producing synthesis gas Download PDF

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Publication number
ES2525957A1
ES2525957A1 ES201330975A ES201330975A ES2525957A1 ES 2525957 A1 ES2525957 A1 ES 2525957A1 ES 201330975 A ES201330975 A ES 201330975A ES 201330975 A ES201330975 A ES 201330975A ES 2525957 A1 ES2525957 A1 ES 2525957A1
Authority
ES
Spain
Prior art keywords
current
synthesis gas
producing synthesis
electrochemical cell
ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES201330975A
Other languages
Spanish (es)
Other versions
ES2525957B1 (en
Inventor
Antonio DE LUCAS CONSUEGRA
Jesús GONZÁLEZ COBOS
José Luis VALVERDE PALOMINO
Carmen JIMÉNEZ BORJA
Nuria GUTIÉRREZ GUERRA
José Luis Endrino Armenteros
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Abengoa Research SL
Original Assignee
Abengoa Research SL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abengoa Research SL filed Critical Abengoa Research SL
Priority to ES201330975A priority Critical patent/ES2525957B1/en
Priority to PCT/ES2014/070470 priority patent/WO2014207279A1/en
Publication of ES2525957A1 publication Critical patent/ES2525957A1/en
Application granted granted Critical
Publication of ES2525957B1 publication Critical patent/ES2525957B1/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

The invention relates to a method for producing synthesis gas (H2/CO), in a controllable ratio, by means of a catalytic and electrochemical process which uses an electrochemical cell formed by ionic, anionic or cationic conductive solid electrolytes. The H2/CO ratio is controlled in a single step under constant operating conditions, i.e. at a constant temperature of the electrochemical cell, and constant conditions of composition and concentration of the inflow current. In the present invention, the inflow current is selected from a current of light hydrocarbons and a water vapour current, or a gaseous current containing at least one alcohol (C1-C3).

Description

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Claims (1)

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ES201330975A 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas Expired - Fee Related ES2525957B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ES201330975A ES2525957B1 (en) 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas
PCT/ES2014/070470 WO2014207279A1 (en) 2013-06-28 2014-06-06 Method for producing synthesis gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201330975A ES2525957B1 (en) 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas

Publications (2)

Publication Number Publication Date
ES2525957A1 true ES2525957A1 (en) 2015-01-02
ES2525957B1 ES2525957B1 (en) 2015-10-21

Family

ID=51178953

Family Applications (1)

Application Number Title Priority Date Filing Date
ES201330975A Expired - Fee Related ES2525957B1 (en) 2013-06-28 2013-06-28 Procedure for obtaining synthesis gas

Country Status (2)

Country Link
ES (1) ES2525957B1 (en)
WO (1) WO2014207279A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0311307A2 (en) * 1987-10-05 1989-04-12 The Standard Oil Company Process for the electrocatalytic conversion of light hydrocarbons to synthesis gas
US5714091A (en) * 1987-03-13 1998-02-03 The Standard Oil Company Process for the partial oxydation of hydrocarbons
EP0875284A1 (en) * 1997-04-29 1998-11-04 Praxair Technology, Inc. Method of producing hydrogen using solid electrolyte membrane

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2163449B (en) 1984-07-18 1988-06-02 Shell Int Research Production of gas mixtures containing hydrogen and carbon monoxide
US6287432B1 (en) * 1987-03-13 2001-09-11 The Standard Oil Company Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions
US7276306B2 (en) * 2003-03-12 2007-10-02 The Regents Of The University Of California System for the co-production of electricity and hydrogen
FR2893033B1 (en) * 2005-11-04 2012-03-30 Inst Francais Du Petrole PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS FROM CARBONACEOUS MATERIAL AND ELECTRICAL ENERGY
WO2008033452A2 (en) * 2006-09-13 2008-03-20 Ceramatec, Inc. High purity hydrogen and electric power co-generation apparatus and method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5714091A (en) * 1987-03-13 1998-02-03 The Standard Oil Company Process for the partial oxydation of hydrocarbons
EP0311307A2 (en) * 1987-10-05 1989-04-12 The Standard Oil Company Process for the electrocatalytic conversion of light hydrocarbons to synthesis gas
EP0875284A1 (en) * 1997-04-29 1998-11-04 Praxair Technology, Inc. Method of producing hydrogen using solid electrolyte membrane

Also Published As

Publication number Publication date
ES2525957B1 (en) 2015-10-21
WO2014207279A1 (en) 2014-12-31

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