ES2162690T3 - Nanoparticulas con contenido en paladio y estabilizadas de polibetaina; procedimiento para la fabricacion de estas asi como catalizadores fabricados de las mismas para la obtencion de acetato vinilico. - Google Patents
Nanoparticulas con contenido en paladio y estabilizadas de polibetaina; procedimiento para la fabricacion de estas asi como catalizadores fabricados de las mismas para la obtencion de acetato vinilico.Info
- Publication number
- ES2162690T3 ES2162690T3 ES98108576T ES98108576T ES2162690T3 ES 2162690 T3 ES2162690 T3 ES 2162690T3 ES 98108576 T ES98108576 T ES 98108576T ES 98108576 T ES98108576 T ES 98108576T ES 2162690 T3 ES2162690 T3 ES 2162690T3
- Authority
- ES
- Spain
- Prior art keywords
- paladio
- procedure
- nanoparticles
- polibetaina
- stabilized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000002105 nanoparticle Substances 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title 1
- 230000001681 protective effect Effects 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
LA INVENCION TRATA DE UNAS NANOPARTICULAS SOLUBLES, QUE CONTIENEN SOLO PALADIO O PALADIO CON METALES DE LOS SUBGRUPOS IB Y VIIIB DEL SISTEMA PERIODICO Y QUE SON ALOJADOS EN COLOIDES PROTECTORES. LA INVENCION SE CARACTERIZA PORQUE LOS COLOIDES PROTECTORES CONTIENEN AL MENOS UN POLIMERO CON GRUPOS DE BETAINA. LA INVENCION TRATA ADEMAS DE UN PROCEDIMIENTO PARA SU PRODUCCION. LAS NANOPARTICULAS SOLUBLES SON IDONEAS PARA LA PRODUCCION DE CATALIZADORES.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19721601A DE19721601A1 (de) | 1997-05-23 | 1997-05-23 | Polybetain-stabilisierte, Palladium-haltige Nanopartikel, ein Verfahren zu ihrer Herstellung sowie daraus hergestellte Katalysatoren zur Gewinnung von Vinylacetat |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2162690T3 true ES2162690T3 (es) | 2002-01-01 |
Family
ID=7830277
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98108576T Expired - Lifetime ES2162690T3 (es) | 1997-05-23 | 1998-05-12 | Nanoparticulas con contenido en paladio y estabilizadas de polibetaina; procedimiento para la fabricacion de estas asi como catalizadores fabricados de las mismas para la obtencion de acetato vinilico. |
Country Status (6)
Country | Link |
---|---|
US (1) | US6074979A (es) |
EP (1) | EP0879642B1 (es) |
JP (1) | JP4044673B2 (es) |
CA (1) | CA2238253C (es) |
DE (2) | DE19721601A1 (es) |
ES (1) | ES2162690T3 (es) |
Families Citing this family (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19745904A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Polymerstabilisierte Metallkolloid-Lösungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren für Brennstoffzellen |
US6207392B1 (en) | 1997-11-25 | 2001-03-27 | The Regents Of The University Of California | Semiconductor nanocrystal probes for biological applications and process for making and using such probes |
DE19753464A1 (de) | 1997-12-02 | 1999-06-10 | Basf Ag | Palladium-Cluster und ihre Verwendung als Katalysatoren |
DE19754304A1 (de) * | 1997-12-08 | 1999-06-10 | Hoechst Ag | Polybetain-stabilisierte Platin-Nanopartikel, Verfahren zu ihrer Herstellung und Verwendung für Elektrokatalysatoren in Brennstoffzellen |
DE19803891A1 (de) * | 1998-01-31 | 1999-08-05 | Bayer Ag | Wäßrige Edelmetallkolloide und ihre Verwendung |
SE9803838D0 (sv) * | 1998-11-09 | 1998-11-09 | Knut Irgum | A chromatography method and a column material useful in said method |
DE19911504B4 (de) * | 1999-03-16 | 2006-02-23 | Südzucker AG Mannheim/Ochsenfurt | Verfahren zur industriellen Oxidation von Alkoholen, Aldehyden oder Polyhydroxyverbindungen |
GB9918229D0 (en) * | 1999-08-04 | 1999-10-06 | Ici Plc | Improvements relating to metal-compound catalysed processes |
US20070066480A1 (en) * | 1999-10-25 | 2007-03-22 | Moser William R | Method of preparing compounds using cavitation and compounds formed therefrom |
US20020009414A1 (en) * | 1999-10-25 | 2002-01-24 | Moser William R. | Method of preparing compounds using cavitation and compounds formed therefrom |
US6797669B2 (en) * | 2000-12-29 | 2004-09-28 | China Petroleum & Chemical Corporation | Catalyst for selective hydrogenation, its preparation process and application |
US6867275B2 (en) * | 2001-03-30 | 2005-03-15 | Rohm And Haas Company | Solid media |
US7153703B2 (en) * | 2001-05-14 | 2006-12-26 | Board Of Trustees Of The University Of Arkansas N. A. | Synthesis of stable colloidal nanocrystals using organic dendrons |
US20030198290A1 (en) * | 2002-04-19 | 2003-10-23 | Dynamic Digital Depth Pty.Ltd. | Image encoding system |
US20040115345A1 (en) * | 2002-07-23 | 2004-06-17 | Xueying Huang | Nanoparticle fractionation and size determination |
US7413770B2 (en) * | 2002-08-01 | 2008-08-19 | E.I. Du Pont De Nemours And Company | Ethylene glycol monolayer protected nanoparticles |
US7507530B2 (en) * | 2002-08-27 | 2009-03-24 | E. I. Du Pont De Nemours And Company | Nanoparticle complexes having a defined number of ligands |
US20040058457A1 (en) * | 2002-08-29 | 2004-03-25 | Xueying Huang | Functionalized nanoparticles |
US20040101454A1 (en) * | 2002-09-05 | 2004-05-27 | Johnson D. Lynn | Supported metallic catalyst and method of making same |
US7273904B2 (en) | 2002-10-03 | 2007-09-25 | The Board Of Trustees Of The University Of Arkansas | Nanocrystals in ligand boxes exhibiting enhanced chemical, photochemical, and thermal stability, and methods of making the same |
US6649469B1 (en) * | 2002-10-11 | 2003-11-18 | Micron Technology, Inc. | Methods of forming capacitors |
US6992039B2 (en) * | 2003-03-13 | 2006-01-31 | General Motors Corporation | Method for making monodispersed noble metal nanoparticles supported on oxide substrates |
JP4297716B2 (ja) * | 2003-03-31 | 2009-07-15 | カウンシル オブ サイエンティフィク アンド インダストリアル リサーチ | C−c結合の形成方法 |
US7825064B2 (en) | 2003-06-03 | 2010-11-02 | William Marsh Rice University | Supported catalysts using nanoparticles as the support material |
US7152609B2 (en) * | 2003-06-13 | 2006-12-26 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide and nitric oxide from the mainstream smoke of a cigarette |
US9107452B2 (en) * | 2003-06-13 | 2015-08-18 | Philip Morris Usa Inc. | Catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
US7165553B2 (en) * | 2003-06-13 | 2007-01-23 | Philip Morris Usa Inc. | Nanoscale catalyst particles/aluminosilicate to reduce carbon monoxide in the mainstream smoke of a cigarette |
US7243658B2 (en) * | 2003-06-13 | 2007-07-17 | Philip Morris Usa Inc. | Nanoscale composite catalyst to reduce carbon monoxide in the mainstream smoke of a cigarette |
US7276409B2 (en) | 2003-06-24 | 2007-10-02 | Micron Technology, Inc. | Method of forming a capacitor |
WO2005003070A1 (en) | 2003-07-03 | 2005-01-13 | Lucite International Uk Limited | Process for the hydroformylation of ethylenically unsaturated compounds |
GB0403592D0 (en) | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
US7153778B2 (en) * | 2004-02-20 | 2006-12-26 | Micron Technology, Inc. | Methods of forming openings, and methods of forming container capacitors |
CN1946628A (zh) * | 2004-03-29 | 2007-04-11 | 科学与工业研究委员会 | 量子阱大小的铂和钯纳米颗粒的合成 |
JP4426379B2 (ja) * | 2004-05-24 | 2010-03-03 | Tanakaホールディングス株式会社 | 触媒前駆体及び触媒、並びに、触媒前駆体及び触媒の製造方法 |
GB0411951D0 (en) | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
US7743772B2 (en) * | 2004-06-16 | 2010-06-29 | Philip Morris Usa Inc. | Silver and silver oxide catalysts for the oxidation of carbon monoxide in cigarette smoke |
GB0516556D0 (en) | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
FR2893262A1 (fr) * | 2005-11-14 | 2007-05-18 | Inst Francais Du Petrole | Procede de synthese en presence de reducteur d'un catalyseur a base de nanoparticules metalliques anisotropes. |
ES2700427T3 (es) | 2005-11-17 | 2019-02-15 | Lucite Int Uk Ltd | Carbonilación de compuestos etilénicamente insaturados |
WO2008011198A2 (en) * | 2006-01-18 | 2008-01-24 | Vanderbilt University | Method of preparing vanadium dioxide nanoparticles |
GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
CA2671409C (en) | 2006-12-02 | 2016-07-26 | Lucite International Uk Limited | Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds |
WO2008074702A1 (de) * | 2006-12-19 | 2008-06-26 | Basf Se | Verfahren zur kreuzkupplung unter verwendung metallischer nanopartikel als katalysator |
DE102007025315A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung |
DE102007025442B4 (de) * | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025223A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025362A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025443A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
CN100500938C (zh) * | 2007-09-28 | 2009-06-17 | 钢铁研究总院 | 一种用于镀锌板纳米改性丙烯酸树脂乳液及其制备方法 |
CN102105554A (zh) * | 2008-06-10 | 2011-06-22 | 阿肯色大学托管委员会 | 砷化铟纳米晶体及其制备方法 |
GB0812297D0 (en) | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
DE202008017277U1 (de) | 2008-11-30 | 2009-04-30 | Süd-Chemie AG | Katalysatorträger |
JP2009175161A (ja) * | 2009-05-11 | 2009-08-06 | Regents Of The Univ Of California | 生物学的用途のための有機発光半導体ナノクリスタルプローブ、およびこのようなプローブを製造および使用するプロセス |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
US8450236B2 (en) * | 2010-04-13 | 2013-05-28 | Cristal Usa Inc. | Supported precious metal catalysts via hydrothermal deposition |
JP6558566B2 (ja) * | 2015-03-31 | 2019-08-14 | 国立研究開発法人日本原子力研究開発機構 | 白金族元素の収集方法 |
KR101852153B1 (ko) * | 2016-03-08 | 2018-04-25 | 서강대학교산학협력단 | 프로그래밍기법을 이용한 금속-리포좀 복합 구조체 제조 방법 및 이에 따라 제조된 금속-리포좀 복합 구조체 |
CN108283936A (zh) * | 2018-01-11 | 2018-07-17 | 安徽大学 | 一种水溶性高分子负载的可回收钯催化剂的制备方法及其应用 |
CN112517063B (zh) * | 2019-09-18 | 2023-08-04 | 中国石油化工股份有限公司 | 醋酸乙烯催化剂的制备方法 |
CN112517065B (zh) * | 2019-09-18 | 2023-05-02 | 中国石油化工股份有限公司 | 乙烯气相法醋酸乙烯工艺催化剂制备方法 |
CN115645814B (zh) * | 2022-10-27 | 2024-04-05 | 浙江工业大学 | 一种超低载量钯纳米晶体修饰电极及其制备方法与其在电化学脱氯中的应用 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5419954A (en) * | 1993-02-04 | 1995-05-30 | The Alpha Corporation | Composition including a catalytic metal-polymer complex and a method of manufacturing a laminate preform or a laminate which is catalytically effective for subsequent electroless metallization thereof |
DE4443705A1 (de) * | 1994-12-08 | 1996-06-13 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von tensidstabilisierten Mono- und Bimetallkolloiden der Gruppe VIII und Ib des Periodensystems als isolierbare und in hoher Konzentration wasserlösliche Precursor für Katalysatoren |
DE19500366C1 (de) * | 1995-01-09 | 1996-05-02 | Basf Ag | Palladium-Trägerkatalysator und seine Verwendung |
-
1997
- 1997-05-23 DE DE19721601A patent/DE19721601A1/de not_active Withdrawn
-
1998
- 1998-05-12 ES ES98108576T patent/ES2162690T3/es not_active Expired - Lifetime
- 1998-05-12 EP EP98108576A patent/EP0879642B1/de not_active Expired - Lifetime
- 1998-05-12 DE DE59801238T patent/DE59801238D1/de not_active Expired - Lifetime
- 1998-05-21 US US09/083,008 patent/US6074979A/en not_active Expired - Lifetime
- 1998-05-22 CA CA002238253A patent/CA2238253C/en not_active Expired - Fee Related
- 1998-05-25 JP JP14288598A patent/JP4044673B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE19721601A1 (de) | 1998-11-26 |
JPH10328571A (ja) | 1998-12-15 |
EP0879642A2 (de) | 1998-11-25 |
EP0879642B1 (de) | 2001-08-22 |
DE59801238D1 (de) | 2001-09-27 |
CA2238253A1 (en) | 1998-11-23 |
JP4044673B2 (ja) | 2008-02-06 |
US6074979A (en) | 2000-06-13 |
EP0879642A3 (de) | 1999-01-27 |
CA2238253C (en) | 2006-11-14 |
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