EP4731736A1 - Composition comprising biosurfactant and manganese - Google Patents
Composition comprising biosurfactant and manganeseInfo
- Publication number
- EP4731736A1 EP4731736A1 EP24730384.5A EP24730384A EP4731736A1 EP 4731736 A1 EP4731736 A1 EP 4731736A1 EP 24730384 A EP24730384 A EP 24730384A EP 4731736 A1 EP4731736 A1 EP 4731736A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sodium
- sfx
- recipes
- ppm
- ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
Definitions
- the invention relates to compositions comprising biosurfactant and manganese. It further relates to a method to stabilize the colour of a composition comprising biosurfactant and to the use of manganese to stabilize the colour of a composition comprising biosurfactant.
- Prior art Surfactants are used in many different compositions and applications. Due to the need of more sustainability biosurfactants are replacing classical surfactants, which are frequently based on petrochemicals or non-renewable raw materials. Biosurfactants, being glycolipids produced by fermentation, are difficult to purify and/or concentrate in a colourless way.
- compositions according to the instant invention have a positive odour profile. 202300074 Foreign Filing 2
- compositions according to the instant invention have an improved colour stability. Colour change reactions could come from Maillard reaction, which is a chemical reaction between proteins or amino acids and sugars. Both reaction partners, proteins and sugars, are typically contained in small amounts in a fermentative produced biosurfactant like Rhamnolipids, Sophorolipids or Rubiwettin. These small concentrations are sufficient to have a colour change from light to dark.
- a further advantage is that the compositions according to the instant invention have improved cleaning properties of surfaces.
- compositions according to the instant invention have excellent foaming properties.
- a further advantage of the compositions according to the instant invention is their reduced irritation for human skin. Another advantage of the compositions according to the instant invention is their mildness and good physiological compatibility, in particular characterized by a high value in the red blood cell (RBC) test. A further advantage of t the compositions according to the instant invention is their good skin feel during and after washing. Another advantage of the compositions according to the instant invention is that they leave behind a smooth and soft skin feel after washing. Another advantage is that the compositions according to the instant invention is their outstanding microbial stability. Another advantage is that the compositions according to the instant invention have an improved ability to dissolve oils and fats. Another advantage is that the composition according to the instant invention leads to a better chemical stability of the raw materials, which increases the shelf life.
- composition according to the instant invention leads to a lower formation of side reactions and higher formulation purity.
- composition according to the instant invention shows especially good emulsification and dispersing properties.
- One advantage of the present invention is that the compositions of the instant invention have a very good cleaning performance, especially in fatty stain removal from fabrics.
- Another advantage of the present invention is that the compositions of the instant invention can be rinsed off from a surface or from fibres, that had been cleaned, very easily.
- the compositions of the instant invention support enzyme stability in terms of storage.
- One advantage of the present invention is the homogeneity of the compositions of the instant invention even at low pH values.
- compositions of the instant invention are easier to dilute, especially in aqueous media. 202300074 Foreign Filing 3
- the compositions of the instant invention are easily miscible with other surfactants.
- a further advantage of the present invention is that the compositions of the instant invention can be incorporate into cosmetic formulations more easily.
- the compositions of the instant invention allow the formulation of concentrated surfactant formulations, even at very low pH.
- the compositions of the instant invention have a reduced foam tendency due to their high concentration and the low achievable pH value, thus simplifying transport and delivery.
- compositions of the instant invention allow for easy incorporation of hydrophobic components such as oils.
- compositions of the instant invention have a high storage stability.
- compositions of the instant invention cause less contamination during their production and transport in pipelines and, moreover, allow easier cleaning.
- compositions of the instant invention have a very low freezing point, which means that the compositions remain processable even at low temperatures.
- compositions of the instant invention, especially cosmetic or cleaning formulations will remain colour stable.
- compositions of the instant invention, especially cosmetic or cleaning formulations have a lower colour intensity.
- the instant invention encompasses a composition
- a composition comprising A) 0.5 wt.-% to 90 wt.%, preferably 3.0 wt.-% to 85 wt.%, even more preferably 15 wt.-% to 80 wt.%, more preferably 25 wt.-% to 75 wt.%, most preferably 40 wt.-% to 70 wt.%, at least one biosurfactant, and B) 0.01 ppm to 500 ppm, preferably 0.1 ppm to 200 ppm, more preferably 1.0 ppm to 50 ppm, most preferably 2.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition.
- biosurfactants are understood as meaning all glycolipids produced by fermentation.
- biosurfactant also covers glycolipids that are chemically or enzymatically modified after fermentation, as long as structurally a glycolipid remains.
- Raw materials for producing the biosurfactants that can be used are carbohydrates, in particular sugars such as e.g. glucose and/or lipophilic carbon sources such as fats, oils, partial glycerides, fatty acids, fatty alcohols, long-chain saturated or unsaturated hydrocarbons.
- surfactant is understood to mean organic substances having interface-active properties that have the ability to reduce the surface tension of water at 20°C and at a concentration of 0.5% by weight based on the overall composition to below 45 mN/m. Surface tension is determined by the DuNoüy ring method at 20°C. Where average values are stated hereinbelow, then, unless stated otherwise, these are number- averaged average values. Unless stated otherwise, percentages are data in per cent by weight. Unless stated otherwise, parts per million (ppm) are data in parts per million by weight.
- biosurfactant comprised in the composition according to the instant invention preferably is an isolated biosurfactant.
- biosurfactant has the meaning of a glycolipid produced by fermentation, the term “isolated biosurfactant” has the meaning as commonly used in the field of biotechnology.
- composition according to the instant invention preferably comprises as component A) at least one biosurfactant selected from rhamnolipids, sophorolipids, glucolipids, cellulose lipids, mannosylerythritol lipids and trehalose lipids, preferably rhamnolipids, sophorolipids and glucolipids, preferably rhamnolipids and glucolipids, most preferably rhamnolipids.
- the biosurfactants can be produced e.g.
- Suitable biosurfactants can be acquired e.g. from Soliance, France.
- the composition according to the instant invention has, as biosurfactant at least one selected from rhamnolipids, in particular mono-, di- or polyrhamnolipids, glucolipids, in particular mono-, di- or polyglucolipids, and sophorolipids, in particular mono-, di- or polysophorolipids, preferably selected from rhamnolipids and glucolipids, most preferably rhamnolipids.
- rhamnolipids in particular mono-, di- or polyrhamnolipids
- glucolipids in particular mono-, di- or polyglucolipids
- sophorolipids in particular mono-, di- or polysophorolipids, preferably selected from rhamnolipids and glucolipids, most preferably rhamnolipids.
- nRL 1, the glycosidic bond between the two rhamnose units is preferably in the ⁇ -configuration.
- the optically active carbon atoms of the fatty acids are preferably present as R-enantiomers (e.g. (R)-3- ⁇ (R)-3-[2-O-( ⁇ -L-rhamnopyranosyl)- ⁇ -L-rhamnopyranosyl]oxydecanoyl ⁇ oxydecanoate).
- R-enantiomers e.g. (R)-3- ⁇ (R)-3-[2-O-( ⁇ -L-rhamnopyranosyl)- ⁇ -L-rhamnopyranosyl]oxydecanoyl ⁇ oxydecanoate.
- the nomenclature used therefore does not distinguish between “CXCY” and "CYCX”.
- Rhamnolipids produced in Pseudomonas aeruginosa cells which have been improved for higher rhamnolipid titres by genetical modification can also be used in the context of the instant invention; such cells have for example been disclosed by Lei et al. in Biotechnol Lett.2020 Jun;42(6):997-1002.
- Rhamnolipids produced by Pseudomonas aeruginosa are commercially available from Jeneil Biotech Inc., e.g. under the tradename Zonix,from Logos Technologies (technology acquired by Stepan), e.g. under the tradename NatSurFact, from Biotensidion GmbH, e.g.
- this preferred embodiment is combined with a content of soil release agents (see below), preferably of the carboxy methyl inulin type.
- the present invention further provides a composition preferably comprising as biosurfactant rhamnolipids, characterized in that the biosurfactant component A) comprises 51% by weight to 95% by weight, preferably 55% by weight to 80% by weight, particularly preferably 60% by weight to 70% by weight, of diRL-C10C10, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- the biosurfactant component A comprises 51% by weight to 95% by weight, preferably 55% by weight to 80% by weight, particularly preferably 60% by weight to 70% by weight, of diRL-C10C10, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- a preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 0.5% by weight to 15% by weight, preferably 3% by weight to 12% by weight, particularly preferably 5% by weight to 10% by weight, of diRL-C10C12:1, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- compositions according to the invention are characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 0.5 to 25% by weight, preferably 3% by weight to 15% by weight, particularly preferably 5% by weight to 12% by weight, of diRL-C10C12, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- a further preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 0.1% by weight to 25% by weight, preferably 2% by weight to 10% by weight, particularly preferably 4% by weight to 8% by weight, of diRL-C8C10, where the percentages by weight refer to the sum total of all rhamnolipids present.
- compositions comprises as biosurfactant rhamnolipids as described above with a content of 0.1% by weight to 5% by weight, preferably 0.5% by weight to 3% by weight, particularly preferably 0.5% by weight to 2% by weight, of monoRL-C8C10 and/or, preferably and 0.1% by weight to 5% by weight, preferably 0.5% by weight to 3% by weight, particularly preferably 0.5% by weight to 2% by weight, of monoRL-C10C10, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- the present invention provides a composition alternatively preferably comprising as biosurfactant rhamnolipids, characterized in that the biosurfactant component A) comprises 10% by weight to 50% by weight, preferably 20% by weight to 40% by weight, particularly preferably 25% by weight to 35% by weight, of monoRL-C10C10 and where the percentages by weight refer to the sum of all of the rhamnolipids present.
- the biosurfactant component A comprises 10% by weight to 50% by weight, preferably 20% by weight to 40% by weight, particularly preferably 25% by weight to 35% by weight, of monoRL-C10C10 and where the percentages by weight refer to the sum of all of the rhamnolipids present.
- composition according to the invention is preferably characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 10 % by weight to 30 % by weight, preferably 12% by weight to 25 % by weight, particularly preferably 15% by weight to 20% by weight, of diRL-C10C10, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 10 % by weight to 30 % by weight, preferably 12% by weight to 25 % by weight, particularly preferably 15% by weight to 20% by weight, of monoRL-C8C10, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- composition comprises as biosurfactant rhamnolipids as described above with a content of 3% by weight to 25% by weight, preferably 5% by weight to 20% by weight, particularly preferably 10% by weight to 15% by weight, of monoRL-C10C12:1, where the percentages by weight refer to the sum total of all rhamnolipids present.
- composition comprises as biosurfactant rhamnolipids as described above with a content of 202300074 Foreign Filing 8 1% by weight to 15% by weight, preferably 2% by weight to 10% by weight, particularly preferably 3% by weight to 8% by weight, of diRL-C10C12, where the percentages by weight refer to the sum of all of the rhamnolipids present.
- Sophorolipids may be used in accordance with the invention in their acid form or their lactone form.
- Preferred compositions according to the instant invention comprise a sophorolipid in which the ratio by weight of lactone form to acid form is in the range of 20:80 to 80:20, especially preferably in the ranges of 30:70 to 40:60.
- sophorolipids in the acid or lactone form in a formulation refer to EP1411111B1, page 8, paragraph [0053].
- the nomenclature used thus does not differentiate between “CXCY” and “CYCX”.
- glucolipids can be carried out as described in WO2019154970.
- the mass of the non-salt form is taken into account; thus, the weight of the corresponding cation is disregarded.
- the content of component B) refers to manganese ions in solution and not to for example solid manganese salts in the composition.
- compositions according to the instant invention can bear high concentrations of the components A) and B) to be advantageously useful, e.g. in the production of end customer formulations.
- the composition according to the instant invention is characterized in that it comprises A) 25 wt.-% to 75 wt.%, more preferably 40 wt.-% to 70 wt.%, at least one biosurfactant, and B) 0.1 ppm to 500 ppm, more preferably 0.5 ppm to 50 ppm, even more preferably 1.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition.
- the compositions according to the instant invention can bear concentrations of the components to be advantageously useful as end customer formulations.
- the composition according to the instant invention is characterized in that it comprises A) 0.5 wt.-% to 25 wt.%, more preferably 1.0 wt.-% to 20 wt.%, most preferably 3.0 wt.-% to 15 wt.%, at least one biosurfactant, and 202300074 Foreign Filing 11 B) 0.01 ppm to 500 ppm, more preferably 0.5 ppm to 50 ppm, even more preferably 1.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition.
- This alternatively preferred composition according to the instant invention is preferably a pharmaceutical, especially dermatological, or cosmetic formulation.
- composition according to the instant invention is alternatively preferably a household care formulation, for example a cleaning formulation or laundry formulation.
- the compositions according to the instant invention preferably comprise water, preferably in an amount of 5 wt.-% to 95 wt.-%, more preferably of 20 wt.-% to 80 wt.-%, more preferably of 30 wt.- % to 70 wt.-%, wherein the weight percentages refer to the total composition.
- the composition according to the instant invention preferably has a pH of 2.0 to 12.5, preferably of 5.0 to 10.0, particularly preferably of 5.5 to 9.0.
- composition according to the instant invention preferably has a pH of 7.0 to 12.5, preferably of 7.5 to 12.0, particularly preferably of 8.0 to 12.0. If the composition according to the instant invention is used, for example, in manual dishwashing or cosmetic agents, it preferably alternatively has a pH of 4 to 8, preferably of 4.5 to 7.5, particularly preferably of 5 to 6.5.
- the composition according to the instant invention preferably has a Gardner colour value in the range of from 0.01 to 15, preferably of from 0.5 to 8, more preferably 1 to 5.
- the compositions according to the instant invention preferably comprise C) at least one preservative.
- compositions according to the instant invention preferably is characterized in that said preservative is selected from the group comprising, preferably consisting of, p-anisic acid, benzoic acid, levulinic acid, sorbic acid, lactic acid, mandelic acid, salicylic acid, dehydroacetic acid, caprylhydroxamic acid, cinnamic acid, geranic acid, pelargonic acid, and the salts of the aforementioned acids, methylparaben, ethylparaben, phenylpropanol, benzyl alcohol, phenethyl alcohol, phenoxyethanol, propanediol, pentylene glycol, 1,2-hexanediol, caprylyl glycol, undecyl alcohol, methylpropanediol, 202300074 Foreign Filing 12 ethylhexylglycerin, n-octylglycerin, n-heptylglycerin,
- compositions according to the instant invention can be formulated as a cosmetic composition; preferably in this instance the following applies:
- the compositions according to the invention preferably comprise at least one additional component selected from the group of cosmetic active ingredients, emollients, emulsifiers, thickeners/viscosity regulators/stabilizers, UV light protection filters, antioxidants, hydrotropes, solids and fillers, film formers, pearlescence additives, deodorant and antiperspirant active ingredients, insect repellents, self-tanning agents, conditioning agents, perfumes, dyes, odour absorbers, superfatting agents, other solvents, preferably cosmetic active ingredients.
- Typical boundary formulations for the respective applications are known prior art and are contained for example in the brochures of the manufacturers of the particular base and active ingredients. These existing formulations can generally be adopted unchanged. However, if required, for adjustment and optimization, the desired modifications can be undertaken by simple tests without complication.
- composition according to the instant invention can be formulated as a household care composition; preferably in this instance the following applies:
- the composition according to the instant invention preferably comprises one or more auxiliary agents selected from the group consisting of bleaching systems, hydrotropes, polymers, which may be synthetic, biopolymers, anti-redeposition aids, fiber protection agents, soil release agents, dye transfer inhibitors, fabric hueing agents, opacifiers, blueing dyes, enzyme stabilizing agents, solvents, viscosity modifiers, preservatives, pH-regulators and salts like NaCl and Na2SO4.
- a further aspect of the instant invention is a method of stabilizing the colour of a composition comprising a biosurfactant comprising the steps a) providing a composition comprising a biosurfactant, and b) adding manganese to the composition to a concentration of 0.01 ppm to 500 ppm, preferably 0.10 ppm to 200 ppm, more preferably 1.0 ppm to 50 ppm, most preferably 2.0 ppm to 19 ppm, manganese ions, wherein the parts per million refer to the total composition.
- a preferred method according to the instant invention is characterized in that the manganese is added in the form of manganese oxide, manganese hydroxide and/or a manganese salt, preferably as aqueous solution, wherein the oxide is preferably selected from the group of MnO2, Mn3O4, Mn2O3, MnO, Mn2O7 and MnO3 and the salt is preferably selected from the group of MnSO4, MnCl2, Mn(CH3CO2)2, MnCO3, Mn(NO3)2,manganese gluconate and manganese permanganates, e.g. KMnO4.
- the oxide is preferably selected from the group of MnO2, Mn3O4, Mn2O3, MnO, Mn2O7 and MnO3
- the salt is preferably selected from the group of MnSO4, MnCl2, Mn(CH3CO2)2, MnCO3, Mn(NO3)2,manganese gluconate and manganese permangan
- the biosurfactant comprised in the provided composition of step a) of the method of the instant invention is an isolated biosurfactant.
- 202300074 Foreign Filing 14 A preferred method according to the instant invention is characterized in that said biosurfactant is selected from the group of rhamnolipids, glucolipids and sophorolipids, preferably rhamnolipids and glucolipids, most preferably rhamnolipids.
- a preferred method according to the instant invention is characterized in that said composition comprising a biosurfactant provided in step a) has a Gardner colour value in the range of from 0.01 to 15, preferably of from 0.5 to 8, more preferably 1 to 5.
- a suited methodology for determination of the Gardner colour value is the third edition of ISO 4630- 2015 Clear liquids — Estimation of colour by the Gardner colour scale.
- the CIELAB colour space is defined by the L*a*b values wherein the brightness L is the relevant indicator for colour.
- a preferred method according to the instant invention is characterized in that said composition comprising a biosurfactant provided in step a) has an L colour value of the CIELAB colour space in the range of from 20 to 100, preferably of from 30 to 95, more preferably 50 to 90.
- a suited methodology for determination of the L colour value of the CIELAB colour space is the measurement of surface reflexion using the spectrophotometer Konica-Minolta CM-700d.
- particularly preferred embodiments of the compositions according to the instant invention and preferred components thereof are equally preferably used in the context of the method according to the instant invention, also regarding their amounts.
- a further aspect of the instant invention is the use of manganese ions to improve the colour stability of a composition comprising at least one biosurfactant.
- a further aspect of the instant invention is the use of manganese ions to prevent malodour of a composition comprising at least one biosurfactant.
- Figure 1 Dose dependent colour stabilization of 50% rhamnolipids by MnSO4
- Figure 2 Dose dependent colour stabilization of 15% rhamnolipids by MnSO4
- Figure 3 Dose dependent colour stabilization of 15% rhamnolipids by manganese oxides
- Figure 4 Dose dependent colour de-stabilization of 15% rhamnolipids by iron and copper ions
- Figure 5 Dose dependent colour stabilization of 50% glucolipids by MnSO4 Examples: Example 1: Dose dependent colour stabilization of a 50% rhamnolipid solution by MnSO4 Rhamnolipids were prepared as described in example 1 of EP3023431.
- MnSO4xH2O was added to a 50 wt.% rhamnolipid solution in water from a 1% (w/w) pre-dilution in water to the final concentration of 1 ppm and 100 ppm Mn 2+ and mixed well.
- the sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardener) are shown in figure 1.
- Example 2 Dose dependent colour stabilization of a 15% rhamnolipid solution by MnSO 4 Rhamnolipids were prepared as described in example 1 of EP3023431.
- Manganese oxides were added to 15 wt.% rhamnolipid solution in water in concentrations of 500 and 3000 ppm and incubated under stirring for 60 min at room temperature. Subsequently, manganese oxides were separated by filtration using a pressure strainer (1 bar) with K800 filter discs (Seitz PALL). As a result, compositions with low concentrations ( ⁇ 10 ppm) of Mn 2+ are obtained. The sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardner) are shown in the following table and Figure 3.
- FeSO 4 *7H 2 O or CuSO 4 *5H 2 O was added to the di-Rhamnolipid material from a 1% (w/w) pre- dilution to the final concentration and mixed well.
- the sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardner) are shown in figure 4.
- Example 5 Dose dependent colour stabilization of a 50% glucolipid solution by MnSO4 Glucolipids were prepared as described WO2019/154970.
- MnSO4xH2O was added to a 50 wt.% glucolipid solution in water from a 1% (w/w) pre-dilution in water to the final concentration of 10 ppm and 25 ppm Mn 2+ and mixed well.
- the sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardener) are shown in figure 5.
- Example 6 The use of MnSO4 to prevent malodour of a biosurfactant composition
- Rhamnolipids were prepared as described in example 1 of EP3023431.
- MnSO4xH2O was added to a 50 wt.% rhamnolipid solution in water from a 1% (w/w) pre-dilution in water to the final concentration of 0 ppm and 10 ppm Mn 2+ and mixed well.
- the sample was then filled into an air-tight container and incubated at 45°C for 50 days.
- the impact of manganese on sensory properties of the rhamnolipid composition was tested by odour evaluation using a panel of trained panelists.
- By “trained panelists” we mean here individuals that had previously been screened for olfactive acuity and were experienced comparing biosurfactant samples. Moreover, the panelists were prior acquainted with the malodor sample before carrying out the evaluation of the samples.
- Glucolipids were produced according to example 2 of WO2019154970 via fermentation.
- MnSO4xH2O was used as manganese source MnSO4xH2O.
- the following compositions were prepared in water: SF1 SF2 SF3 SF4 SF5 SF6 SF7 SF8 SF9 SF10 RLs / wt.-% 40 40 - - - - - 16 16 mRLs / wt.-% - - 35 35 - - - - 4 4 SLs / wt.-% - - - - 40 40 - - 10 10 GLs / wt.-% - - - - - 40 40 10 10 Mn 2+ / ppm 5 400 5 400 5 400 5 400 5 400 5 400 5 400
- Each of the stock solution SF1 to SF10 is used to prepare the formulations listed below, where SFX stands for the respective stock solution; thus, 10
- Recipes 1a shower Cream Ingredients ⁇ wt.% ⁇ 1a Water ad 100.0 Sodium Laureth Sulfate (Texapon NSO, BASF, 28%) 25.0 Coco-Glucoside (Plantacare 818 UP, BASF, 51%) 8.0 Cocamidopropyl Betaine (TEGO® Betain F 50, Evonik, 38%) 8.0 SFX 2.3 PEG-18 Glyceryl Oleate/Cocoate (ANTIL® 171, Evonik) 1.5 Sorbitan Sesquicaprylate (ANTIL® Soft SC, Evonik) 0.8 202300074 Foreign Filing 19 Glyceryl Oleate (TEGIN ® O V, Evonik) 0.8 Perfume Spicy Herbs (IFF) 0.2 Polyglyceryl-4 Caprate (TEGOSOFT® PC 41, Evonik) 0.6 Helianthus Annuus Seed Oil (AEC Sunflower Oil, A & E Connock, 0.2 Perfumery & Cosmetics Ltd.) Linalool (L
- Recipes 4a Shampoo Ingredients ⁇ wt.% ⁇ 4a Water ad 100.0 Cocamidopropyl Betaine (TEGO® Betain F 50, Evonik, 22.0 38%) SFX 8.0 Sodium Cocoyl Glutamate (Plantapon ACG HC, BASF) 1.5 Sodium Cocoyl Glycinate (Hostapon SG, Clariant) 0.8 Zinc Pyrithione (Microcare ZP, Thor) 0.1 PEG-120 Methyl Glucose Dioleate (ANTIL® 120 Plus, 0.4 Evonik) Sodium Chloride 0.5 Isostearamide MIPA; Glyceryl Laurate (ANTIL® SPA 80, 0.5 Evonik) Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.3 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.3 (Jaguar C-162, Solvay Rhodia) Quaternium-80 (ABIL® Quat 3272,
- Recipes 10a Micellar Water for make-up removal Ingredients ⁇ wt.% ⁇ 10a Water ad 100.0 Perfume 0.1 SFX 2.5 Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; 1.0 Polyglyceryl-4 Caprate; Polyglyceryl-6 Ricinoleate (TEGO® Solve 61, Evonik) Betaine (TEGO® Natural Betaine, Evonik) 2.0 Glycerin (Glycerol EP, vegetable, Spiga Nord) 1.0 Preservative q.s.
- Recipes 11a Natural Micellar Water Ingredients ⁇ wt.% ⁇ 11a Phase Caprylyl/Capryl Glucoside; Aqua; Sodium Cocoyl Glutamate; Glyceryl 2.5 A Caprylate; Citric Acid; Polyglyceryl-6 Oleate; Sodium Surfactin (symbio®solv clear plus MB, Evonik) Perfume 0.3 SFXs 2 Phase Glycerin 5.0 B Betaine (TEGO® Natural Betaine; Evonik) 2.0 Phenylpropanol (dermosoft® 250 eco; Evonik) 0.4 Pentylene Glycol (dermosoft® Pentiol eco; Evonik) 2.0 Sodium Phytate; Aqua; Alcohol (dermofeel® PA-3; Evonik) 0.1 ad Water, deionized 100 202300074 Foreign Filing 24 Recipes 12a: Micellar Water Ingredients ⁇ wt.% ⁇ 12a SFXs 5 W ater ad 100 Betaine (TEGO® Natural
- Recipes 13a Skin Tonic Ingredients ⁇ wt.% ⁇ 13a Phase ad Water, deionized A 100 Sodium PCA; Aqua (Ajidew NL-50N; Ajinomoto) 0.5 Glycerin 4.0 Phase SFXs 2 B Sodium Caproyl/Lauroyl Lactylate; Triethyl Citrate (dermosoft® decalact 1.0 liquid; Evonik) Alcohol denat.
- Recipes 23a Cleansing Powder Ingredients ⁇ wt.% ⁇ 23a Phase Capryl/Capramidopropyl Betaine (TEGO® Betain 12.0 A 810 MB; Evonik) Sodium Cocoamphoacetate (REWOTERIC® AM C 15.0 MB; Evonik) Sucrose Cocoate (TEGOSOFT® LSE 65 K Soft) 3.0 Sorbitan Sesquicaprylate (ANTIL® Soft SC MB; 1.0 Evonik) Bis-(Isostearoyl/Oleoyl Isopropyl) imonium 1.0 Methosulfate (VARISOFT® EQ 100; Evonik) SFXs 6 Oleyl Erucate (TEGOSOFT® OER MB; Evonik) 2.0 Helianthus Annuus (Sunflower) Seed Oil 5.0 Citric Acid (30% sol.) 3.0 Phase Sipernat 500 LS Hydrated Silica) B Wheat Flour 29.0 Cocamidopropyl Betaine (TEGO® Betain
- Recipes 24a Cleansing Oil 202300074 Foreign Filing 29 Ingredients ⁇ wt.% ⁇ 24a SFXs 0.5 Polyglyceryl-2 Sesquioleate (dermofeel® GO soft; 5.0 Evonik) Helianthus Annuus (Sunflower) Seed Oil 36.0 Isoamyl Laurate (dermofeel® sensolv MB; Evonik) 35.0 TEGOSOFT® DC MB (Decyl Cocoate; Evonik) 5 Polyglyceryl-2 Caprate (dermosoft® DGMC MB; 2 Evonik) Tocopherol; Helianthus Annuus (Sunflower) Seed Oil 1.0 (dermofeel® Toco 70 non GMO; Evonik) Sesamum Indicum (Sesame Seed) Oil 16 Recipes 25a: Anti-Transpirant Deo Ingredients ⁇ wt.% ⁇ 25a Phase A SFX 1 Dicaprylyl Ether (Cetiol OE, BASF
- Recipes 34a Oven Cleanser for Smoking Chamber Ingredient 34a Water ad 100 Trilon A liquid 8.0 Sodium carbonate 6.0 REWOTERIC® AM KSF 40 5.0 Laureth-6 1.2 SFX 1.2 DOWANOL DPnB 1.0 202300074 Foreign Filing 32 Recipes 35a: All Purpose Cleanser (Microemulsion) Ingredient 35a Water ad 100 TEGOTENS® AM VSF 6.0 SFX 2 REWOPOL® D 510 NC 5.0 Undeceth-6 3.0 Potassium hydroxide.50 5.0 Chelating Agent.
- Recipes 43a Hard Surface Degreaser From Renewable Surfactants Ingredient 43a Water ad 100 Sodium carbonate 3.0 TEGOTENS® AM VSF 2.4 Laureth-6 0.6 SFX 0.4 TEGO® Polish Additiv Q 70 0.3 Recipes 44a: Highly Efficient Floor Cleanser Ingredient 44a Water ad 100 Desferrioxamine 4.0 Sodium carbonate 3.0 TEGOTENS® AM VSF 2.4 Laureth-6 0.6 202300074 Foreign Filing 34 SFX 0.4 TEGO® Polish Additiv Q 70 0.3 Recipes 45a: Super Natural Wash Lotion for Textile Face Masks Ingredient 45a Xanthan Gum 0.1 Glycerin 2.0 Water ad 100 SFX 1 Sophorolipid 2.0 REWOPOL® SB CS 50 5.0 C8-10 Alkylpolyglucosid 10.0 TEGO® Betain C 60 3.0 Preservative qs.
- Recipes 46 Highly Effective Presoaker Ingredient 46a Water ad 100 Sodium metasilicate 2.0 Sodium gluconate 2.0 Sodium carbonate 2.0 TEGOTENS® AM VSF 6.5 Undeceth-6 0.6 SFX 0.4 DOWANOL DPnB 1.0 Recipes 47a: Presoaker (Basic Formula) Ingredient 47a Water ad 100 Trilon A 92 3.0 Sodium metasilicate 2.0 Sodium carbonate 2.0 Bayhibit AM 1.0 REWOTERIC® AM KSF 40 4.0 C9-11 FATTY ALCOHOL ETHOXYLATE - 8 MOLES OF EO 1.2 SFX 1 DOWANOL DPnB 3.0 Recipes 48a: Good Dispersing Presoaker 202300074 Foreign Filing 35 Ingredient 48a Water ad 100 Trilon A 92 3.0 Sodium metasilicate 2.0 Sodium carbonate 2.0 Sequion 10 Na 430 2.0 TEGOTENS® 475 5.0 C9-11 FATTY ALCOHOL ETHOXYLATE - 7 MOLES
- Recipes 84 Strengthening Shampoo Ingredient % Water ad 100 Sodium Lauryl Sulfate 6.0 Sodium Laureth Sulfate 4.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Glycol Distearate 2.5 Dimethicone 2.0 Sodium Citrate 1.5 Cocamide MEA 1.0 Sodium Xylenesulfonate 1.0 Citric Acid ad pH 5.0 Sodium Benzoate 0.7 Sodium Chloride 0.8 Tetrasodium EDTA 0.3 Polyquaternium-6 0.5 Honey (Mel) 0.5 Prunus Armeniaca (Apricot) Fruit Extract 0.5 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 perfume, Dyes q.
- Recipes 103 Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Cocamidopropyl Betaine 3.0 SFX 3.0 PEG-7 Glyceryl Cocoate 2.5 Dimethicone 2.5 Prunus Armeniaca (Apricot) Kernel Oil 2.5 Panthenol 0.3 Cocodimonium Hydroxypropyl Hydrolyzed Keratin 0.7 Hydrolyzed Keratin 0.7 Sodium Chloride 0.8 Cocamide MEA 0.5 Glycol Distearate 0.2 Sodium Benzoate 0.7 Citric Acid ad pH 5.5 Polyquaternium-10 0.5 Laureth-4 0.4 PEG-40 Hydrogenated Castor Oil 0.2 Hydrogenated Castor Oil 0.7 Laureth-7 0.5 202300074 Foreign Filing 64 Hexyl Cinnamal 0.1 Propylene Glycol 0.8 Hexyl Salicylate 0.3 Glycerin 0.5 Linalool 0.2 Limonene 0.1 Dyes q.
- Recipes 104 Shampoo Ingredient % Aqua ad 100 Sodium Coco Sulfate 6.0 Lauryl Glucoside 4.0 Glycerin 3.5 Sodium Lactate 2.5 SFX 2.0 Stearamidopropyl Dimethylamine 1.0 Betaine 0.8 Sodium Chloride 0.9 Simmondsia Chinensis Seed Oil 0.8 Sodium Cocoyl Glutamate 0.7 Disodium Cocoyl Glutamate 0.5 Xanthan Gum 0.5 Hydrated Silica 0.5 perfume, Dyes q. s.
- Recipes 111 Caffeine Shampoo Ingredient % Aqua ad 100 Sodium Coco Sulfate 6.0 Glycerin 5.5 Lauryl Glucoside 4.5 Cocamidopropyl Betaine 3.0 SFX 2.5 Lauroyl Sarcosine 2.0 Caffeine 1.0 Xanthan Gum 1.0 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.3 Alcohol 0.8 Coffea Arabica Bean Extract 0.3 Panthenyl Ethyl Ether 0.4 Panthenol 0.2 Limonene 0.1 Linalool 0.1 Dyes q. s.
- Recipes 113 Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Cocamidopropyl Betaine 3.0 Sodium Chloride 2.0 Disodium Cocoamphodiacetate 2.0 SFX 2.0 Sodium Benzoate 0.7 Panthenol 0.2 Sodium Laureth-8 Sulfate 0.7 Citric Acid ad pH 5.0 Sodium Cocoyl Glutamate 0.8 Glycol Distearate 0.9 Styrene/Acrylates Copolymer 0.5 Sodium Oleth Sulfate 0.7 Coco Glucoside 0.9 Cocamide MEA 0.7 Isopropyl Alcohol 0.2 perfume, Dyes q. s.
- Recipes 120 Conditioning Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 Cocamidopropyl Betaine 1.5 SFXs 1.5 Palmitamidopropyltrimonium Chloride 1.0 Polysilicone-19 1.0 PEG-18 Glyceryl Oleate/Cocoate 2.5 Citric Acid ad pH 5.5 Perfume, Preservative q. s.
- Recipes 121 Conditioning Shampoo Ingredient % Aqua ad 100 Sodium Cocoamphoacetate 5.0 Cocamidopropyl Betaine 3.0 Disodium Lauryl Sulfosuccinate 3.0 SFXs 1.5 Palmitamidopropyltrimonium Chloride 2.0 Isostearamide MIPA, Glyceryl Laurate 1.0 PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate 1.0 Methoxy PEG/PPG-7/3 Aminopropyl Dimethicone 0.5 Starch Hydroxypropltrimonium chloride 0.3 Polyquaternium-10 0.2 Citric Acid ad pH 5.5 Perfume, Preservative q. s.
- Recipes 122 Conditioning Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 6.0 Cocamidopropyl Betaine 3.0 202300074 Foreign Filing 75 SFX 3.0 Glycol Distearate, Laureth-4, Cocamidopropyl Betaine 2.0 PEG-120 Methyl Glucose Dioleate 1.7 SFX 1.5 Sorbitan Sesquicaprylate 1.0 Isoamyl Laurate 1.0 Sodium Chloride 1.0 Silicone-Quaternium-22 0.8 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.5 Creatine 0.5 Citric Acid ad pH 5.5 Perfume, Preservative q. s.
- Recipes 130 shower Oil Ingredient % Aqua ad 100 Magnesium Laureth Sulfate 6.0 PEG-7 Glyceryl Cocoate 5.0 Hydrogenated Starch Hydrolysate 3.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Decyl Glucoside 1.0 Prunus Amygdalus Dulcis (Sweet Almond) Oil 1.0 Olive Oil 0.5 PEG-7 Esters 0.2 perfume 0.1 Polysorbate 20 0.1 Sodium Benzoate 0.2 Citric Acid 0.1 PEG-6 Caprylic/Capric Glycerides 0.1 PEG-120 Methyl Glucose Dioleate 0.1 Disodium EDTA 0.1 Recipes 131: Shower Mousse Ingredient % Aqua ad 100 Sodium Lauroyl Glutamate 15.0 Isobutane 6.0 Cocamidopropyl Betaine 4.0 Glycerin 3.0 SFX 3.0 Sodium Chloride 2.6 Sodium Lauroyl Glycinate 1.5 Propane 1.0 Butane 0.6 Citric
- Recipes 136 Exfoliating Body Scrub Ingredient % Aqua ad 100 Coco-Glucoside 7.0 Alcohol 6.0 Glycerin 5.0 Glycine Soja Oil 5.0 Hydrated Silica 4.0 Xanthan Gum 3.0 202300074 Foreign Filing 82 SFX 3.0 Disodium/Sodium Cocoyl Glutamate 1.0 Coffea Arabica (Coffee) Seed Powder 1.0 Cocos Nucifera (Coconut) Shell Powder 1.0 Citric Acid ad pH 5.2 Glyceryl Oleate 0.5 perfume 0.1 Preservative, Dyes q. s. Recipes 137: Dry Shampoo Ingredient % Butane, Propane 53.0 Alcohol Denat.
- Recipes 150 shower Cream Aqua ad 100 Ammonium Lauryl Sulfate 6.0 Coco Glucoside 3.5 202300074 Foreign Filing 90 Cocamidopropyl Betaine 2.0 Sodium Cocoamphoacetate 2.0 SFX 1.5 Argania Spinosa Kernel Oil 1.0 Butyrospermum Parkii Butter 1.0 Glycerin 1.0 Polyquaternium-7 1.0 Styrene/Acrylates Copolymer 1.0 Gelatin Crosspolymer 0.5 Sodium Chloride 0.5 Citric Acid ad pH 5.0 Sodium Benzoate 0.3 Sodium Salicylate 0.1 Linalool 0.1 Dyes q. s.
- Recipes 151 shower Cream Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 Cocamidopropyl Betaine 3.0 SFX 2.0 Sodium Chloride 1.9 Polyquaternium-7 1.5 Cocamide MEA 1.5 PEG-7 Glyceryl Cocoate 1.0 Laureth-10 1.0 Glycol Distearate 0.8 Citric Acid ad pH 5.0 Linalool 0.1 Limonene 0.1 Benzyl Salicylate 0.1 Butylphenyl Methylpropional 0.1 alpha-Isomethyl Ionone 0.1 Hexyl Cinnamal 0.1 Citronellol 0.1 Sodium Benzoate 0.7 Sodium Salicylate 0.1 Dyes q. s.
- Recipes 153 shower Gel Ingredient % Aqua ad 100 Sodium Coco Sulfate 5.0 Glycerin 5.0 Lauryl Glucoside 4.0 Sodium Lactate 2.5 SFX 2.0 Sodium Cocoyl Glutamate 2.0 Disodium Cocoyl Glutamate 2.0 Alcohol 1.0 Prunus Cerasus Fruit Extract 1.0 Limonene 0.1 Coumarin 0.2 Linalool 0.1 Citral 0.1 Dyes q. s.
- Recipes 156 shower Gel Ingredient % Aqua ad 100 Ammonium Lauryl Sulfate 6.0 Coco-Betaine 3.0 SFX 3.0 Lauroyl/Myristoyl Methyl Glucamide 1.5 Citric Acid ad pH 5.0 Benzyl Alcohol, Glycerin, Benzoic Acid, Sorbic Acid 1.0 perfume 0.8 Aloe Vera Leaf Extract 0.1 Recipes 157: showergel Ingredient % Aqua ad 100 SFX 7.0 Sesamum Indicum (Sesame) Seed Oil 4.0 Sucrose.
- Recipes 161 Washing Powder Ingredient % Talc 60.0 Sodium Cocoyl Isethionate 15.0 Sodium C14-16 Olefin Sulfonate 10.0 Sodium Lauroyl Glutamate 4.0 SFX 3.0 Potassium Laurate 2.0 Sodium Myristoyl Glutamate 1.5 Chondrus Crispus 1.5 Isostearyl Alcohol 1.0 Glycerin 1.0 BHT 0.4 Butylene Glycol 0.3 Protease 0.2 Salicylic Acid 0.1 Recipes 162: Washing Powder Ingredient % Hydrates Silica ad 100 Zea Mays Starch 30.0 Sodium Cocoyl Isethionate 6.0 Amylopektin 5.0 Sodium Lauryl Sulfate 2.5 Sodium Bicarbonate 2.0 Citric Acid 1.5 Sodium Lauroyl Glutamate 1.0 Sodium Palmitate 1.0 SFX 1.0 202300074 Foreign Filing 96 Diglycerin 0.9 Sodium Lauroyl Aspartate 0.8 Titanium Dioxide 0.5 Maltodextrin 0.5 Allantoin 0.4 Aqua
- Recipes 163 Powder Cleanser Ingredient % Hydrated Silica ad 100 Tapioca Flour 10.0 Capryl/Capramidopropyl Betaine 5.0 Sodium Cocoamphoacetate 5.0 Helianthus Annuus (Sunflower) Seed Oil 4.0 Oleyl Erucate 2.0 Sucrose Cocoate 2.0 SFX 2.0 Coconut Acid 1.0 Citric Acid ad pH 6.0 Preservatives, perfume q. s.
- Recipes 164 Powder Cleanser Ingredient % Talc ad 100 Distarch Phosphate 10.0 Disodium Lauryl Sulfosuccinate 8.0 Magnesium Aluminum Silicate 5.0 Oryza Sativa Powder 5.0 Sodium Lauroyl Glutamate 2.0 SFX 2.0 Glucose 2.0 Magnesium Oxide 2.0 Maltodextrin 2.0 Titanium Dioxide 1.0 Pumice 0.5 202300074 Foreign Filing 97 Chlorella Vulgaris Powder 0.1 Soap Recipess Recipes Recipes 165: Gentle Liquid Soap Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Cocamidopropyl Betaine 3.0 SFX 2.5 PEG-7 Glyceryl Cocoate 2.5 Cocamide DEA 2.5 Glycerin 2.0 Sorbitan Sesquicaprylate 1.5 C12-15 Pareth-12 1.2 Sodium Benzoate 1.0 Potassium Sorbate 1.0 Citric Acid ad pH 5.5 PEG-200 Hydrogenated Glyceryl
- Bath Recipes Recipes 178 Bath Ingredient % Aqua ad 100 PEG-80 Sorbitan Laurate 4.0 Cocamidopropyl Betaine 4.0 Sodium Laureth Sulfate 4.0 SFX 2.0 Polysorbate 20 2.0 202300074 Foreign Filing 104 Sodium Chloride 1.5 Citric Acid ad pH 5.0 Sodium Lauroamphoacetate 1.0 PEG-150 Distearate 1.0 Disodium Lauroamphodiacetate 1.0 Sodium Benzoate 0.5 perfume, Dyes q. s.
- Recipes 182 Aroma Bath Ingredient % Aqua ad 100 Alcohol 5.0 Coco Glucoside 5.0 Sodium Coco Sulfate 4.0 SFX 2.5 Xanthan Gum 1.9 202300074 Foreign Filing 106 Glycerin 1.8 Sodium Cocoyl Glutamate 1.5 Disodium Cocoyl Glutamate 1.5 Melissa Officinalis Extract 1.0 Lavandula Angustifolia Oil 1.0 Linalool 0.1 Limonene 0.1 Geraniol 0.1 Dyes q. s. Recipes 183: Bath Bomb Ingredient % Sodium Bicarbonate 70.0 Citric Acid 8.0 Citrus Nobilis Oil 6.0 Potassium Tartrate 6.0 Sodium Laureth Sulfate 4.0 SFX 4.0 Betaine 1.5 perfume 0.5 Dyes q.
- Recipes 186 Bath Salt Ingredient % Maris Sal ad 100 Rosmarinus Officinalis Leaf Oil 3.0 perfume 1.5 Polysorbate 20 1.5 SFX 1.5 Preservative, Dyes q. s. x-in-1 Recipess Recipes 187: Shower Gel and Shampoo Ingredient % Aqua ad 100 Coco Glucoside 5.0 Sodium Coco Sulfate 3.0 Cocamidopropyl Hydroxysultaine 2.5 SFX 2.0 Lauryl Glucoside 2.0 Glyceryl Oleate 1.8 Inulin 1.5 Lecithin 1.5 Polyquaternium-39 1.5 Citric Acid ad pH 5.0 Styrene/Acrylates Copolymer 1.0 Sodium Chloride 1.0 Denatonium Benzoate 0.5 Hydrogenated Palm Glycerides Citrate 0.7 Tocopherol 0.3 Sodium Benzoate 0.7 Phenoxyethanol 0.3 perfume, Dyes q.
- Recipes 192 Hair and Body Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 10.0 Sodium Chloride 4.0 Glycerin 3.5 Coco-Betaine 2.0 SFX 2.0 Niacinamide 0.1 Saccharum Officinarum (Sugar Cane) Extract 1.0 Sodium Benzoate 1.0 Sodium Hydroxide 0.3 PPG-5-Ceteth-20 1.0 Polyquaternium-10 0.7 Salicylic Acid 0.5 Limonene 0.1 Linalool 0.2 Benzyl Salicylate 0.1 Pyrus Malus (Apple Fruit) Extract 0.3 Pyridoxine HCl 0.2 Citric Acid ad pH 5.0 Taurine 0.1 Dyes q. s.
- Citric Acid ad pH 7.0 Recipes 203: Facial Cleansing Foam Ingredient % Aqua ad 100 Glycine Soja Oil 5.0 Coco-Glucoside 4.0 Glycerin 3.5 SFX 3.0 Alcohol Denat. 2.0 Sodium Coco-Sulfate 1.5 Sodium/Disodium Cocoyl Glutamate 1.0 Glyceryl Oleate 0.5 Hamamelis Virginiana Leaf Extract 0.5 Tocopherol 0.1 Helianthus Annuus Seed Oil 0.1 Lactic Acid ad pH 6.5 Preservative q. s.
- Recipes 230 Toothpaste Ingredient % Glycerin 27.0 Hydrated Silica (Hydrated) 21.0 Sodium Hexametaphosphate 13.0 Aqua ad 100 PEG-6 5.0 Flavor 1.0 Trisodium Phosphate 1.0 202300074 Foreign Filing 128 Sodium Lauryl Sulfate 1.05 SFX 0.35 Chondrus Crispus 0.7 Cocamidopropyl Betaine 0.1 Sodium Saccharin 0.2 Polyethylene Glycol 0.5 Xanthan Gum 0.7 Sucralose 0.5 Mica 0.3 Titanium Dioxide 0.5 Sodium Fluoride 0.32 Dyes, pH adjuster, preservative q. s.
- Recipes 236 Toothpaste Ingredient % Dicalcium Phosphate Dihydrate (Dihydrate) 25.0 Aqua ad 100 Sorbitol 20.0 Glycerin 20.0 Methyl Salicylate 1.0 Sodium Lauryl Sulfate 0.9 SFX 0.9 Titanium Dioxide 0.5 Chondrus Crispus 0.8 Cellulose Gum 0.5 Sodium Silicate 0.3 Hydrated Silica (Hydrated) 1.0 Thymol 0.1 Sodium Saccharin 0.2 Sodium Hydroxide 0.5 Menthol 0.3 Dyes solution (1% FD&C Blue No.1) 0.02 pH adjuster, preservative q. s.
- Recipes 237 Toothpaste Ingredient % Aqua ad 100 Hydrated Silica (Hydrated) 21.0 Sorbitol 21.0 Glycerin 18.0 PEG-6 5.0 SFX 1.5 Xanthan Gum 0.8 Flavor 0.7 Titanium Dioxide 0.5 Sodium Citrate 0.4 Sodium Fluoride 0.32 202300074 Foreign Filing 132 Zinc Chloride 0.5 Sodium Saccharin 0.2 Chondrus Crispus 0.7 Limonene 0.1 Dyes solution (1% FD&C Blue No.1) 0.04 pH adjuster, preservative q. s.
- Recipes 239 Toothpaste Ingredient % Glycerin 33.0 PEG-8 5.0 Hydrated Silica (Hydrated), 5.0 Calcium Sodium Phosphosilicate 3.0 Cocamidopropyl Betaine 1.0 SFX 1.0 Sodium Methyl Cocoyl Taurate 0.3 Aroma 0.8 Titanium Dioxide 0.5 Carbomer 0.5 202300074 Foreign Filing 133 Sodium Saccharin 0.2 Sodium Fluoride 0.32 Limonene 0.2 Dyes, pH adjuster, preservative q. s.
- Recipes 240 Toothpaste Ingredient % Aqua ad 100 Sorbitol 63.0 Hydrated Silica (Hydrated) 14.0 Silica 7.0 SFXs 1.0 Titanium Dioxide 0.6 Maris Sal 0.5 Glycolipdis 0.5 Sodium Cocoyl Glutamate 0.5 Disodium Cocoyl Glutamate 0.5 Xanthan Gum 0.7 Sodium Fluoride 0.32 Echinacea Purpurea Extract (Extract) 0.1 Arnica Montana Flower Extract 0.1 Mentha Piperita Leaf Water 0.1 Myrtus Communis Leaf Water 0.1 Glycerin 1.0 Menthol 0.2 Aroma 1.0 L-limonene 0.2 Dyes, pH adjuster, preservative q. s.
- Recipes 244 Toothpaste Ingredient % Aqua ad 100 Sorbitol 45.0 Hydrated Silica (Hydrated) 21.0 Sodium Lauryl Sulfate 1.5 SFX xx Cellulose Gum 1.0 Aroma 1.0 Zinc Citrate 0.5 Chondrus Crispus Powder (Powdered) 0.8 Sodium Saccharin 0.2 Sodium Fluoride 0.1 Titanium Dioxide 0.5 Hydroxyethylcellulose 0.3 Sodium Citrate 0.2 Stannous Fluoride 0.4 Dyes, pH adjuster, preservative q. s.
- Recipes 251 Toothpaste Ingredient % Aqua ad 100 Calcium Carbonate 30.0 Silica 7.0 Glycerin 5.0 Hydrated Silica 2.5 SFX 1.5 Aroma 1.0 Chondrus Crispus Powder 0.5 Cellulose Gum 0.5 Chlorhexidine Gluconate 0.1 Limonene 0.15 Sodium Saccharin 0.15 Titanium Dioxide 0.1 Sodium Fluoride 0.32 Dyes, pH adjuster, preservative q. s.
- Recipes 252 Toothpaste Ingredient % Aqua ad 100 Hydrogenated Starch Hydrolysate 20.0 Hydrated Silica 15.0 PEG-32 4.0 Glycolipids 1.5 SFX 1.0 Propylene Glycol 0.9 Aroma 0.9 Sodium Lauryl Sulfat 0.5 Hydroxyethylcellulose 0.5 Olaflur 0.13 Titanium Dioxide 0.1 Sodium Fluoride 0.1 Sodium Saccharin 0.2 Chamomilla Recutita Flower Extract 0.2 202300074 Foreign Filing 140 Chlorhexidine Digluconate 0.1 Limonene 0.1 Citral 0.1 Dyes, pH adjuster, preservative q. s.
- Mouthwash Recipess 202300074 Foreign Filing 145 Recipes 262: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 11.0 Propylene Glycol 7.0 SFX 1.0 Poloxamer 407 0.75 Aroma 0.9 Cetylpyridinium Chloride 0.04 Sodium Fluoride 0.05 Sodium Saccharin 0.07 Menthol 0.1 Dyes, pH adjuster, Preservative q. s.
- Recipes 266 Mouthrinse Ingredient % Aqua ad 100 Glycerin 10.0 Sorbitol 10.0 Cocamidopropyl Betaine 1.0 202300074 Foreign Filing 147 SFX 0.5 Potassium Chloride 0.1 Propylene Glycol 0.5 Aroma 0.25 Sodium Fluoride 0.02 Olaflur 0.16 Potassium Acesulfame 0.1 Sodium Chloride 0.1 Limonene 0.03 Sodium Sulfate 0.05 Dyes, pH adjuster, Preservative q. s.
- Example Recipes 267 Mouthrinse without Alcohol Ingredient % Aqua ad 100 Sorbitol 15.0 SFX 1.0 Aloe Barbadensis Leaf Extract 0.15 Calendula Officinalis Flower Extract 0.2 Chamomilla Recutita Flower Extract 0.2 Sodium Fluoride 0.02 Calcium Glycerophosphate 0.05 Zinc Gluconate 0.8 Mentha Spicata Crispa Herb Oil 0.05 Mentha Arvensis Leaf Oil 0.05 Menthol 0.04 Dyes, pH adjuster, Preservative q. s.
- Recipes 270 Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 7.5 PEG-60 Hydrogenated Castor Oil 1.0 SFX 0.5 Sodium Citrate 0.45 Aroma 0.3 Zinc Chloride 0.15 Cetylpyridinium Chloride 0.05 Sodium Saccharin 0.08 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s.
- Recipes 271 Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 11.0 SFX 2.0 Flavor 1.0 Cetylpyridinium Chloride 0.5 Poloxamer 407 0.1 202300074 Foreign Filing 149 Sodium Saccharin 0.1 Sodium Fluoride 0.02 Sucralose 0.05 Mentha Viridis Leaf Oil 0.1 Dyes, pH adjuster, Preservative q. s.
- Recipes 275 Mouthrinse Ingredient % Aqua ad 100 Glycerin 11.0 Propylene Glycol 7.5 Sorbitol 7.5 Tetrapotassium Pyrophosphate 1.5 Polysorbate 20 0.5 SFX 0.5 Tetrasodium Pyrophosphate 0.75 Zinc Citrate 0.15 PVM/MA Copolymer 0.1 Flavor 0.2 Sodium Fluoride 0.05 Sodium Saccharin 0.07 Dyes, pH adjuster, Preservative q. s.
- Recipes 276 Mouthrinse Ingredient % Aqua ad 100 Glycerin 11.0 Alcohol 7.5 Sorbitol 7.5 202300074 Foreign Filing 151 SFX 1.0 Poloxamer 407 0.5 Sodium Phosphate, Disodium Phosphate 0.15 Flavor 0.9 Cetylpyridinium Chloride 0.05 Sodium Saccharin 0.08 Sodium Fluoride 0.05 Dyes, pH adjuster, Preservative q. s.
- Recipes 277 Mouthrinse Ingredient % Aqua ad 100 Alcohols 22.0 Sorbitol 10.0 Flavor 1.0 SFX 1.0 Sodium Saccharin 0.09 Eucalyptol 0.1 Thymol 0.06 Sucralose 0.06 Sodium Fluoride 0.05 Menthol 0.04 Dyes, pH adjuster, Preservative q. s.
- Recipes 279 Mouthrinse Ingredient % Aqua ad 100 Glycerin 11.0 Sorbitol 11.0 Propylene Glycol 3.0 Disodium Pyrophosphate 1.5 PEG-40 Hydrogenated Castor Oil 1.0 SFX 0.5 PVM/MA Copolymer 0.5 Tetrapotassium Pyrophosphate 0.25 Sodium Levulinate 0.25 Sodium Anisate 0.25 Olaflur 0.16 Aroma 0.8 Arginine 0.8 Sodium Saccharin 0.07 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s. Recipes 280: Mouthrinse Ingredient % Aqua ad 100 Alcohol Denat.
- Recipes 281 Mouthrinse Ingredient % Aqua ad 100 Sorbitol 12.5 Propylene Glycol 3.5 SFX 0.5 Sodium Lauryl Sulfate 0.5 Poloxamer 407 0.5 Flavor 0.3 Eucalyptol 0.08 Methyl Salicylate 0.1 Thymol 0.05 Stannous Fluoride 0.09 Menthol 0.1 Sodium Saccharin 0.06 Sucralose 0.7 Camellia Sinensis Leaf Extract 0.05 Dyes, pH adjuster, Preservative q. s.
- Recipes 282 Mouthrinse Ingredient % Aqua ad 100 SFX 1.0 Eucalyptol 0.9 Zinc Chloride 0.25 Methyl Salicylate 0.05 Thymol 0.05 202300074 Foreign Filing 154 Levomenthol 0.07 Stannous Fluoride 0.09 Dyes, pH adjuster, Preservative q. s. Recipes 283: Mouthrinse Ingredient % Aqua ad 100 Alcohol Denat. 15.0 Sorbitol 5.0 Glycine 1.0 SFX 1.0 Aroma 0.2 Zinc Sulfate 0.2 Sodium Fluoride 0.02 Sodium Saccharin 0.07 Dyes, pH adjuster, Preservative q. s.
- Recipes 290 Mouthrinse Concentrate Ingredient % 202300074 Foreign Filing 157 Propylene Glycol 55.0 Aqua ad 100 Aroma 2.0 Sodium Saccharin 0.4 SFX 0.75 Polysorbate 20 0.25 Commiphora Myrrha Oil 2.0 Salvia Officinalis Oil 0.2 Mentha Piperita Oil 0.2 Chamomilla Recutita Flower Extract 0.2 Limonene 0.1 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s.
- Recipes 296 Dental Floss Ingredient % PTFE ad 100 Aroma 1.0 Acacia Senegal Gum 0.7 Cera Alba 0.7 Potassium Acesulfame 0.5 Sodium Lauryl Sulfate 0.25 SFX 0.25 Glycerin 0.7 Silica 0.5 Sodium Fluoride 0.22 Recipes 297: Teeth Wipe Ingredient % 202300074 Foreign Filing 160 Aqua q. s.100 Alcohol Denat. 30.00 Glycerin 20.00 Stevia 1.0 Polysorbate 20 0.5 SFX 0.5 Aroma 1.0 Dyes, pH adjuster, Preservatives q. s.
- Recipes 300 Tooth Tab Ingredient % Dicalcium Phosphate Anhydrous ad 100 Potassium Bitartrate 15.0 Sorbitol 15.0 SFX 6.0 Lauroyl Sarcosine 0.8 Kaolin 0.5 Sodium Saccharin 0.5 Aroma 0.2 Dyes, pH adjuster, Preservative q. s. Recipes 301: Powder Toothpaste Ingredient % Calcium Carbonate ad 100 Sorbitol 15.0 Kaolin 15.0 Sodium Bicarbonate 15.0 SFX 1.5 Aroma 1.0 Citrus Limon Peel Oil 1.0 Stevia Rebaudiana Extract 0.5 Xylitol 0.5 Citral 0.1 Geraniol 0.1 Limonene 0.1 Dyes, pH adjuster, Preservative q. s.
- Benzoate pH adjuster (Citric Acid ad pH or NaOH) Preservatives, perfume q. s.
- Ingredient Pouch 1 Pouch 2 Pouch 3 SFX 15 10 20 Sodium laureth sulfate 0 0 10 Fatty alcohol ethoxylate (C12-14, 7EO) 14 14 14 Fatty acid (C8-C18) 13 13 13 1,2-propane diol 22 22 22 Glycerine 22 22 22 22 Sodium Hydroxide 4 4 4 4 Citric acid to pH 8 to pH 8 to pH 8 Medley® Brilliant 300 L 3 3 3 Water Add to 100% Add to 100% Add to 100% 202300074 Foreign Filing 167 Ingredient Pouch 4 Pouch 5 Pouch 6 SFX 15 10 5 Persicomycin 0.1 0.1 0.1 Sodium laureth sulfate 0 0 10 Fatty alcohol ethoxylate (C12-14, 3EO) 14 14 14 Fatty acid (C8-C18) 13 13 13 1,2-propane diol 22 22 22 Glycerine 22
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Abstract
The invention relates to compositions comprising biosurfactant and manganese. It further relates to a method to stabilize the colour of a composition comprising biosurfactant and to the use of manganese to stabilize the colour of a composition comprising biosurfactant.
Description
202300074 Foreign Filing 1 Composition comprising biosurfactant and manganese Field of the invention The invention relates to compositions comprising biosurfactant and manganese. It further relates to a method to stabilize the colour of a composition comprising biosurfactant and to the use of manganese to stabilize the colour of a composition comprising biosurfactant. Prior art Surfactants are used in many different compositions and applications. Due to the need of more sustainability biosurfactants are replacing classical surfactants, which are frequently based on petrochemicals or non-renewable raw materials. Biosurfactants, being glycolipids produced by fermentation, are difficult to purify and/or concentrate in a colourless way. They also have the disadvantage, that they suffer from colour instability and tend to become darker and or brownish during storage. While not necessarily a major issue in technical applications like oil field or fracking applications, this colour instability can prevent biosurfactants to win recognition in the technical field of for example cosmetics or household care. It is thus an object of the invention to provide for colour stable biosurfactant compositions. Description of the invention that, surprisingly, addition of low amounts of manganese can stabilize compositions comprising biosurfactants in terms of colour. The present invention therefore provides compositions comprising biosurfactant and manganese at certain amounts. The invention further provides a method to stabilize the colour of a composition comprising biosurfactant and the use of manganese to stabilize the colour of a composition comprising biosurfactant. One advantage of the present invention is that the compositions according to the instant invention have a positive odour profile.
202300074 Foreign Filing 2 Another advantage of the present invention is that the compositions according to the instant invention have an improved colour stability. Colour change reactions could come from Maillard reaction, which is a chemical reaction between proteins or amino acids and sugars. Both reaction partners, proteins and sugars, are typically contained in small amounts in a fermentative produced biosurfactant like Rhamnolipids, Sophorolipids or Rubiwettin. These small concentrations are sufficient to have a colour change from light to dark. A further advantage is that the compositions according to the instant invention have improved cleaning properties of surfaces. Another advantage is that the compositions according to the instant invention have excellent foaming properties. A further advantage of the compositions according to the instant invention is their reduced irritation for human skin. Another advantage of the compositions according to the instant invention is their mildness and good physiological compatibility, in particular characterized by a high value in the red blood cell (RBC) test. A further advantage of t the compositions according to the instant invention is their good skin feel during and after washing. Another advantage of the compositions according to the instant invention is that they leave behind a smooth and soft skin feel after washing. Another advantage is that the compositions according to the instant invention is their outstanding microbial stability. Another advantage is that the compositions according to the instant invention have an improved ability to dissolve oils and fats. Another advantage is that the composition according to the instant invention leads to a better chemical stability of the raw materials, which increases the shelf life. Another advantage is that the composition according to the instant invention leads to a lower formation of side reactions and higher formulation purity. Another advantage of the present invention is that the composition according to the instant invention shows especially good emulsification and dispersing properties. One advantage of the present invention is that the compositions of the instant invention have a very good cleaning performance, especially in fatty stain removal from fabrics. Another advantage of the present invention is that the compositions of the instant invention can be rinsed off from a surface or from fibres, that had been cleaned, very easily. A further advantage is that the compositions of the instant invention support enzyme stability in terms of storage. One advantage of the present invention is the homogeneity of the compositions of the instant invention even at low pH values. Another advantage of the present invention is that the compositions of the instant invention are easier to dilute, especially in aqueous media.
202300074 Foreign Filing 3 Another advantage of the present invention is that the compositions of the instant invention are easily miscible with other surfactants. A further advantage of the present invention is that the compositions of the instant invention can be incorporate into cosmetic formulations more easily. Another advantage of the present invention is that the compositions of the instant invention allow the formulation of concentrated surfactant formulations, even at very low pH. Another advantage of the present invention is that the compositions of the instant invention have a reduced foam tendency due to their high concentration and the low achievable pH value, thus simplifying transport and delivery. Another advantage of the present invention is that the compositions of the instant invention allow for easy incorporation of hydrophobic components such as oils. Another advantage of the present invention is that the compositions of the instant invention have a high storage stability. A further advantage of the present invention is that the compositions of the instant invention cause less contamination during their production and transport in pipelines and, moreover, allow easier cleaning. Another advantage of the present invention is that the compositions of the instant invention have a very low freezing point, which means that the compositions remain processable even at low temperatures. Another advantage of the present invention is that the compositions of the instant invention, especially cosmetic or cleaning formulations, will remain colour stable. Another advantage of the present invention is that the compositions of the instant invention, especially cosmetic or cleaning formulations, have a lower colour intensity. The instant invention encompasses a composition comprising A) 0.5 wt.-% to 90 wt.%, preferably 3.0 wt.-% to 85 wt.%, even more preferably 15 wt.-% to 80 wt.%, more preferably 25 wt.-% to 75 wt.%, most preferably 40 wt.-% to 70 wt.%, at least one biosurfactant, and B) 0.01 ppm to 500 ppm, preferably 0.1 ppm to 200 ppm, more preferably 1.0 ppm to 50 ppm, most preferably 2.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition. Within the context of the present invention, “biosurfactants” are understood as meaning all glycolipids produced by fermentation. The term “biosurfactant” also covers glycolipids that are chemically or enzymatically modified after fermentation, as long as structurally a glycolipid remains. Raw materials for producing the biosurfactants that can be used are carbohydrates, in particular sugars such as e.g. glucose and/or lipophilic carbon sources such as fats, oils, partial glycerides, fatty acids, fatty alcohols, long-chain saturated or unsaturated hydrocarbons.
202300074 Foreign Filing 4 In the context of the present invention, the terms “surfactant” is understood to mean organic substances having interface-active properties that have the ability to reduce the surface tension of water at 20°C and at a concentration of 0.5% by weight based on the overall composition to below 45 mN/m. Surface tension is determined by the DuNoüy ring method at 20°C. Where average values are stated hereinbelow, then, unless stated otherwise, these are number- averaged average values. Unless stated otherwise, percentages are data in per cent by weight. Unless stated otherwise, parts per million (ppm) are data in parts per million by weight. Wherever measurement values are stated hereinbelow, then, unless stated otherwise, these have been determined at a temperature of 25°C and a pressure of 1013 mbar. The “pH” in connection with the present invention – unless stated otherwise – is defined as the value which is measured for the relevant composition at 25°C after stirring for five minutes using a pH electrode calibrated in accordance with ISO 4316 (1977). The biosurfactant comprised in the composition according to the instant invention preferably is an isolated biosurfactant. As in the context of the instant invention the term “biosurfactant” has the meaning of a glycolipid produced by fermentation, the term “isolated biosurfactant” has the meaning as commonly used in the field of biotechnology. The composition according to the instant invention preferably comprises as component A) at least one biosurfactant selected from rhamnolipids, sophorolipids, glucolipids, cellulose lipids, mannosylerythritol lipids and trehalose lipids, preferably rhamnolipids, sophorolipids and glucolipids, preferably rhamnolipids and glucolipids, most preferably rhamnolipids. The biosurfactants can be produced e.g. as in EP 0499434, US 7,985,722, WO 03/006146, DE 19648439, DE 19600743, JP 01304034, CN 1337439, JP 2006274233, JP 2006083238, JP 2006070231, WO 03/002700, FR 2740779, DE 2939519, US 7.556,654, FR 2855752, EP 1445302, JP 2008062179 and JP 2007181789 or the documents cited therein. Suitable biosurfactants can be acquired e.g. from Soliance, France. Preferably, the composition according to the instant invention has, as biosurfactant at least one selected from rhamnolipids, in particular mono-, di- or polyrhamnolipids, glucolipids, in particular mono-, di- or polyglucolipids, and sophorolipids, in particular mono-, di- or polysophorolipids, preferably selected from rhamnolipids and glucolipids, most preferably rhamnolipids. The term "rhamnolipids" in the context of the present invention preferably is understood to mean particularly compounds of the general formula (I) and salts thereof,
202300074 Foreign Filing 5 Formula (I)
where mRL = 2, 1 or 0, nRL = 1 or 0, R1RL and R2RL = mutually independently, identical or different, organic residues having 2 to 24, preferably 5 to 13 carbon atoms, in particular optionally branched, optionally substituted, particularly hydroxy-substituted, optionally unsaturated, in particular optionally mono-, bi- or tri- unsaturated alkyl residues, preferably those selected from the group consisting of pentenyl, heptenyl, nonenyl, undecenyl and tridecenyl and (CH2)o-CH3 where o = 1 to 23, preferably 4 to 12. If nRL = 1, the glycosidic bond between the two rhamnose units is preferably in the α-configuration. The optically active carbon atoms of the fatty acids are preferably present as R-enantiomers (e.g. (R)-3-{(R)-3-[2-O-(α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl]oxydecanoyl}oxydecanoate). The term "di-rhamnolipid" in the context of the present invention is understood to mean compounds of the general formula (I) or salts thereof, where nRL = 1. The term "mono-rhamnolipid" in the context of the present invention is understood to mean compounds of the general formula (I) or salts thereof, where nRL = 0. Distinct rhamnolipids are abbreviated according to the following nomenclature: "diRL-CXCY" are understood to mean di-rhamnolipids of the general formula (I) where nRL = 1, in which one of the residues R1RL and R2RL = (CH2)o-CH3 where o = X-4 and the remaining residue R1RL or R2RL = (CH2)o-CH3 where o = Y-4. "monoRL-CXCY" are understood to mean mono-rhamnolipids of the general formula (I), in which one of the residues R1RL and R2RL = (CH2)o-CH3 where o = X-4 and the remaining residue R1RL or R2RL = (CH2)o-CH3 where o = Y-4. The nomenclature used therefore does not distinguish between "CXCY" and "CYCX". For rhamnolipids where mRL=0, monoRL-CX or diRL-CX is used accordingly.
202300074 Foreign Filing 6 If one of the abovementioned indices X and/or Y is provided with ":Z", this signifies that the respective residue R1RL and/or R2RL is equal to an unbranched, unsubstituted hydrocarbon residue having X-3 or Y-3 carbon atoms having Z double bonds. Methods for preparing the relevant rhamnolipids are disclosed, for example, in EP2786743 and EP2787065. Rhamnolipids applicable in the context of the instant invention can also be produced by fermentation of Pseudomonas, especially Pseudomonas aeruginosa, which are preferably non genetically modified cells, a technology already disclosed in the eighties, as documented e.g. in EP0282942 and DE4127908. Rhamnolipids produced in Pseudomonas aeruginosa cells which have been improved for higher rhamnolipid titres by genetical modification can also be used in the context of the instant invention; such cells have for example been disclosed by Lei et al. in Biotechnol Lett.2020 Jun;42(6):997-1002. Rhamnolipids produced by Pseudomonas aeruginosa are commercially available from Jeneil Biotech Inc., e.g. under the tradename Zonix,from Logos Technologies (technology acquired by Stepan), e.g. under the tradename NatSurFact, from Biotensidion GmbH, e.g. under the tradename Rhapynal, from AGAE technologies, e.g. under the name R90, R95, R95Md, R95Dd, from Locus Bio-Energy Solutions and from Shanghai Yusheng Industry Co. Ltd., e.g. under the tradename Bio- 201 Glycolipids. The present invention provides a composition preferably comprising as biosurfactant rhamnolipids, characterized in that the biosurfactant component A) comprises 51% by weight to 100% by weight, preferably 60% by weight to 95% by weight, particularly preferably 80% by weight to 90% by weight, of mono-rhamnolipids, especially those of formula (I) with nRL=0, where the percentages by weight refer to the sum of all of the rhamnolipids present. This surprisingly elevates the viscosity of the composition according to the instant invention. Preferably this preferred embodiment is combined with a content of soil release agents (see below), preferably of the carboxy methyl inulin type. The present invention further provides a composition preferably comprising as biosurfactant rhamnolipids, characterized in that the biosurfactant component A) comprises 51% by weight to 95% by weight, preferably 55% by weight to 80% by weight, particularly preferably 60% by weight to 70% by weight, of diRL-C10C10, where the percentages by weight refer to the sum of all of the rhamnolipids present. A preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 0.5% by weight to 15% by weight, preferably 3% by weight to 12% by weight, particularly preferably 5% by weight to 10% by weight, of diRL-C10C12:1, where the percentages by weight refer to the sum of all of the rhamnolipids present.
202300074 Foreign Filing 7 A further preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 0.5 to 25% by weight, preferably 3% by weight to 15% by weight, particularly preferably 5% by weight to 12% by weight, of diRL-C10C12, where the percentages by weight refer to the sum of all of the rhamnolipids present. A further preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 0.1% by weight to 25% by weight, preferably 2% by weight to 10% by weight, particularly preferably 4% by weight to 8% by weight, of diRL-C8C10, where the percentages by weight refer to the sum total of all rhamnolipids present. An even further preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 0.1% by weight to 5% by weight, preferably 0.5% by weight to 3% by weight, particularly preferably 0.5% by weight to 2% by weight, of monoRL-C8C10 and/or, preferably and 0.1% by weight to 5% by weight, preferably 0.5% by weight to 3% by weight, particularly preferably 0.5% by weight to 2% by weight, of monoRL-C10C10, where the percentages by weight refer to the sum of all of the rhamnolipids present. The present invention provides a composition alternatively preferably comprising as biosurfactant rhamnolipids, characterized in that the biosurfactant component A) comprises 10% by weight to 50% by weight, preferably 20% by weight to 40% by weight, particularly preferably 25% by weight to 35% by weight, of monoRL-C10C10 and where the percentages by weight refer to the sum of all of the rhamnolipids present. The alternatively preferred composition according to the invention is preferably characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 10 % by weight to 30 % by weight, preferably 12% by weight to 25 % by weight, particularly preferably 15% by weight to 20% by weight, of diRL-C10C10, where the percentages by weight refer to the sum of all of the rhamnolipids present. The alternatively preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 10 % by weight to 30 % by weight, preferably 12% by weight to 25 % by weight, particularly preferably 15% by weight to 20% by weight, of monoRL-C8C10, where the percentages by weight refer to the sum of all of the rhamnolipids present. The alternatively preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of 3% by weight to 25% by weight, preferably 5% by weight to 20% by weight, particularly preferably 10% by weight to 15% by weight, of monoRL-C10C12:1, where the percentages by weight refer to the sum total of all rhamnolipids present. The alternatively preferred composition according to the invention is characterized in that the composition comprises as biosurfactant rhamnolipids as described above with a content of
202300074 Foreign Filing 8 1% by weight to 15% by weight, preferably 2% by weight to 10% by weight, particularly preferably 3% by weight to 8% by weight, of diRL-C10C12, where the percentages by weight refer to the sum of all of the rhamnolipids present. In the context of the present invention, the term “sophorolipids” preferably is understood as meaning compounds of the general formulae (IIa) and (IIb) and salts thereof
202300074 Foreign Filing 9 where R1SL = H or CO-CH3, R2SL = H or CO-CH3, R3SL = a divalent organic moiety which comprises 6 to 32 carbon atoms and which is unsubstituted or substituted by hydroxyl functions, is unbranched and optionally comprises one to three double or triple bonds, R4SL = H, CH3 or a monovalent organic radical which comprises 2 to 10 carbon atoms and which is unsubstituted or substituted by hydroxyl functions, which is unbranched and which optionally comprises one to three double or triple bonds, and nSL = 1 or 0. Sophorolipids may be used in accordance with the invention in their acid form or their lactone form. Preferred compositions according to the instant invention comprise a sophorolipid in which the ratio by weight of lactone form to acid form is in the range of 20:80 to 80:20, especially preferably in the ranges of 30:70 to 40:60. To determine the content of sophorolipids in the acid or lactone form in a formulation, refer to EP1411111B1, page 8, paragraph [0053]. In connection with the present invention, the term “glucolipids” preferably is understood as meaning compounds of the general formula (III) and salts thereof,
mGL = 3, 2, 1 or 0, preferably 1 or 0, R1GL and R2GL = independently of one another identical or different organic radical having 2 to 24 carbon atoms, in particular optionally branched, optionally substituted, in particular hydroxy- substituted, optionally unsaturated, in particular optionally mono-, di- or triunsaturated, alkyl radical, preferably one selected from the group consisting of pentenyl, heptenyl, nonenyl, undecenyl and tridecenyl and (CH2)o-CH3 where o = 1 to 23, preferably 4 to 12. Distinct glucolipids are abbreviated according to the following nomenclature:
202300074 Foreign Filing 10 “GL-CXCY” is understood as meaning glucolipids of the general formula (III) in which one of the radicals R1GL and R2GL = (CH2)o-CH3 where o = X-4 and the remaining radical R1GL or R2GL = (CH2)o- CH3 where o = Y-4. The nomenclature used thus does not differentiate between “CXCY” and “CYCX”. If one of the aforementioned indices X and/or Y is provided with “:Z”, then this means that the respective radical R1GL and/or R2GL = an unbranched, unsubstituted hydrocarbon radical with X-3 or Y-3 carbon atoms having Z double bonds. Methods for production of glucolipids can be carried out as described in WO2019154970. When determining the content of component A) in the context of the present invention, the mass of the non-salt form is taken into account; thus, the weight of the corresponding cation is disregarded. Within the context of the present invention, the content of component B) refers to manganese ions in solution and not to for example solid manganese salts in the composition. To determine the content of manganese ions in the composition according to the instant invention preferably the methodology of inductively coupled plasma mass spectrometry (ICP-MS) is used. The compositions according to the instant invention can bear high concentrations of the components A) and B) to be advantageously useful, e.g. in the production of end customer formulations. In this context it is preferred in the instant invention, that the composition according to the instant invention is characterized in that it comprises A) 25 wt.-% to 75 wt.%, more preferably 40 wt.-% to 70 wt.%, at least one biosurfactant, and B) 0.1 ppm to 500 ppm, more preferably 0.5 ppm to 50 ppm, even more preferably 1.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition. The compositions according to the instant invention can bear concentrations of the components to be advantageously useful as end customer formulations. In this context it is alternatively preferred in the instant invention, that the composition according to the instant invention is characterized in that it comprises A) 0.5 wt.-% to 25 wt.%, more preferably 1.0 wt.-% to 20 wt.%, most preferably 3.0 wt.-% to 15 wt.%, at least one biosurfactant, and
202300074 Foreign Filing 11 B) 0.01 ppm to 500 ppm, more preferably 0.5 ppm to 50 ppm, even more preferably 1.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition. This alternatively preferred composition according to the instant invention is preferably a pharmaceutical, especially dermatological, or cosmetic formulation. These alternatively preferred composition according to the instant invention is alternatively preferably a household care formulation, for example a cleaning formulation or laundry formulation. The compositions according to the instant invention preferably comprise water, preferably in an amount of 5 wt.-% to 95 wt.-%, more preferably of 20 wt.-% to 80 wt.-%, more preferably of 30 wt.- % to 70 wt.-%, wherein the weight percentages refer to the total composition. The composition according to the instant invention preferably has a pH of 2.0 to 12.5, preferably of 5.0 to 10.0, particularly preferably of 5.5 to 9.0. If the composition according to the instant invention is used, for example, in laundry detergents, it preferably has a pH of 7.0 to 12.5, preferably of 7.5 to 12.0, particularly preferably of 8.0 to 12.0. If the composition according to the instant invention is used, for example, in manual dishwashing or cosmetic agents, it preferably alternatively has a pH of 4 to 8, preferably of 4.5 to 7.5, particularly preferably of 5 to 6.5. The composition according to the instant invention preferably has a Gardner colour value in the range of from 0.01 to 15, preferably of from 0.5 to 8, more preferably 1 to 5. The compositions according to the instant invention preferably comprise C) at least one preservative. The compositions according to the instant invention preferably is characterized in that said preservative is selected from the group comprising, preferably consisting of, p-anisic acid, benzoic acid, levulinic acid, sorbic acid, lactic acid, mandelic acid, salicylic acid, dehydroacetic acid, caprylhydroxamic acid, cinnamic acid, geranic acid, pelargonic acid, and the salts of the aforementioned acids, methylparaben, ethylparaben, phenylpropanol, benzyl alcohol, phenethyl alcohol, phenoxyethanol, propanediol, pentylene glycol, 1,2-hexanediol, caprylyl glycol, undecyl alcohol, methylpropanediol,
202300074 Foreign Filing 12 ethylhexylglycerin, n-octylglycerin, n-heptylglycerin, n-hexylglycerin, methylheptylglycerin, undecylenamidopropyltrimonium methosulfate, isothiazolinones, preferably selected from chloromethylisothiazolinone (CIT), methylisothiazolinone (MIT), benzisothiazolinone (BIT) , butylbenzisothiazolinone (BBIT), triethyl citrate, citral, hydroxymethylglycinate, glyceryl caprylate, iodopropynyl butylcarbamat (IPBC), and Sodium Caproyl/Lauroyl Lactylate. The composition according to the instant invention can be formulated as a cosmetic composition; preferably in this instance the following applies: The compositions according to the invention preferably comprise at least one additional component selected from the group of cosmetic active ingredients, emollients, emulsifiers, thickeners/viscosity regulators/stabilizers, UV light protection filters, antioxidants, hydrotropes, solids and fillers, film formers, pearlescence additives, deodorant and antiperspirant active ingredients, insect repellents, self-tanning agents, conditioning agents, perfumes, dyes, odour absorbers, superfatting agents, other solvents, preferably cosmetic active ingredients. Substances which can be used as exemplary representatives of the individual groups are known to those skilled in the art and can be found for example in German application DE 102008001788.4. This patent application is hereby incorporated as reference and thus forms part of the disclosure.
202300074 Foreign Filing 13 As regards further optional components and the amounts used of these components, reference is made expressly to the relevant handbooks known to those skilled in the art, for example K. Schrader, "Grundlagen und Rezepturen der Kosmetika [Cosmetics - fundamentals and formulations]", 2nd edition, pages 329 to 341, Hüthig Buch Verlag Heidelberg. The amounts of the particular additives are determined by the intended use. Typical boundary formulations for the respective applications are known prior art and are contained for example in the brochures of the manufacturers of the particular base and active ingredients. These existing formulations can generally be adopted unchanged. However, if required, for adjustment and optimization, the desired modifications can be undertaken by simple tests without complication. The composition according to the instant invention can be formulated as a household care composition; preferably in this instance the following applies: The composition according to the instant invention preferably comprises one or more auxiliary agents selected from the group consisting of bleaching systems, hydrotropes, polymers, which may be synthetic, biopolymers, anti-redeposition aids, fiber protection agents, soil release agents, dye transfer inhibitors, fabric hueing agents, opacifiers, blueing dyes, enzyme stabilizing agents, solvents, viscosity modifiers, preservatives, pH-regulators and salts like NaCl and Na2SO4. A further aspect of the instant invention is a method of stabilizing the colour of a composition comprising a biosurfactant comprising the steps a) providing a composition comprising a biosurfactant, and b) adding manganese to the composition to a concentration of 0.01 ppm to 500 ppm, preferably 0.10 ppm to 200 ppm, more preferably 1.0 ppm to 50 ppm, most preferably 2.0 ppm to 19 ppm, manganese ions, wherein the parts per million refer to the total composition. A preferred method according to the instant invention is characterized in that the manganese is added in the form of manganese oxide, manganese hydroxide and/or a manganese salt, preferably as aqueous solution, wherein the oxide is preferably selected from the group of MnO2, Mn3O4, Mn2O3, MnO, Mn2O7 and MnO3 and the salt is preferably selected from the group of MnSO4, MnCl2, Mn(CH3CO2)2, MnCO3, Mn(NO3)2,manganese gluconate and manganese permanganates, e.g. KMnO4. Preferably the biosurfactant comprised in the provided composition of step a) of the method of the instant invention is an isolated biosurfactant.
202300074 Foreign Filing 14 A preferred method according to the instant invention is characterized in that said biosurfactant is selected from the group of rhamnolipids, glucolipids and sophorolipids, preferably rhamnolipids and glucolipids, most preferably rhamnolipids. A preferred method according to the instant invention is characterized in that said composition comprising a biosurfactant provided in step a) has a Gardner colour value in the range of from 0.01 to 15, preferably of from 0.5 to 8, more preferably 1 to 5. A suited methodology for determination of the Gardner colour value is the third edition of ISO 4630- 2015 Clear liquids — Estimation of colour by the Gardner colour scale. In the case of turbid material, such as for example an emulsion, a different methodology for colour determination needs to be utilized. The CIELAB colour space is defined by the L*a*b values wherein the brightness L is the relevant indicator for colour. A preferred method according to the instant invention is characterized in that said composition comprising a biosurfactant provided in step a) has an L colour value of the CIELAB colour space in the range of from 20 to 100, preferably of from 30 to 95, more preferably 50 to 90. A suited methodology for determination of the L colour value of the CIELAB colour space is the measurement of surface reflexion using the spectrophotometer Konica-Minolta CM-700d. In the method according to the instant invention, particularly preferred embodiments of the compositions according to the instant invention and preferred components thereof are equally preferably used in the context of the method according to the instant invention, also regarding their amounts. A further aspect of the instant invention is the use of manganese ions to improve the colour stability of a composition comprising at least one biosurfactant. A further aspect of the instant invention is the use of manganese ions to prevent malodour of a composition comprising at least one biosurfactant.
202300074 Foreign Filing 15 In the case of the uses according to the instant invention, particularly preferred embodiments of the compositions and method according to the instant invention and preferred components thereof are equally preferably used in the context of the uses according to the instant invention, also regarding their amounts. The examples adduced hereinafter describe the present invention by way of example, without any intention that the invention, the scope of application of which is apparent from the entirety of the description and the claims, be restricted to the embodiments specified in the examples. Brief description of the figures: Figure 1: Dose dependent colour stabilization of 50% rhamnolipids by MnSO4 Figure 2: Dose dependent colour stabilization of 15% rhamnolipids by MnSO4 Figure 3: Dose dependent colour stabilization of 15% rhamnolipids by manganese oxides Figure 4: Dose dependent colour de-stabilization of 15% rhamnolipids by iron and copper ions Figure 5: Dose dependent colour stabilization of 50% glucolipids by MnSO4 Examples: Example 1: Dose dependent colour stabilization of a 50% rhamnolipid solution by MnSO4 Rhamnolipids were prepared as described in example 1 of EP3023431. MnSO4xH2O was added to a 50 wt.% rhamnolipid solution in water from a 1% (w/w) pre-dilution in water to the final concentration of 1 ppm and 100 ppm Mn2+ and mixed well. The sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardener) are shown in figure 1. Example 2: Dose dependent colour stabilization of a 15% rhamnolipid solution by MnSO4 Rhamnolipids were prepared as described in example 1 of EP3023431.
202300074 Foreign Filing 16 MnSO4xH2O was added to a 15 wt.% rhamnolipid solution in water from a 1% (w/w) pre-dilution in water to the final concentration of 1 ppm and 100 ppm Mn2+ and mixed well. The sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardner) are shown in figure 2. Example 3: Colour stabilization of a 15% rhamnolipid solution by different manganese oxides Rhamnolipids were prepared as described in example 1 of EP3023431. Manganese oxides were added to 15 wt.% rhamnolipid solution in water in concentrations of 500 and 3000 ppm and incubated under stirring for 60 min at room temperature. Subsequently, manganese oxides were separated by filtration using a pressure strainer (1 bar) with K800 filter discs (Seitz PALL). As a result, compositions with low concentrations (< 10 ppm) of Mn2+ are obtained. The sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardner) are shown in the following table and Figure 3. days Variant manganese added 0 4 7 11 14 22 28 43 52 64 70 oxide amount of added manganese oxide (ppm) Control none 3,6 3,2 3,6 4,1 4,5 5,2 5,5 6 6,1 6,3 6,4 500ppm Mn2O3 500 3,8 3,7 4 4,2 4,4 4,6 4,8 5 5,2 5,4 5,4 Mn2O3 3000ppm Mn2O3 3000 3,7 3,9 4 4,2 4,3 4,6 4,8 5 5,1 5,3 5,3 Mn2O3 500ppm Mn3O4 500 3,4 3,4 3,9 4,1 4,3 4,6 4,7 5 5,1 5,2 5,3 Mn3O4 3000ppm Mn3O4 3000 3,6 3,6 3,9 4,1 4,2 4,5 4,7 5 5,2 5,3 5,4 Mn3O4
202300074 Foreign Filing 17 Example 4 (not according to the invention): Dose dependent colour impact of iron and copper salts on a 15% rhamnolipid solution Rhamnolipids were prepared as described in example 1 of EP3023431. FeSO4*7H2O or CuSO4*5H2O was added to the di-Rhamnolipid material from a 1% (w/w) pre- dilution to the final concentration and mixed well. The sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardner) are shown in figure 4. Example 5: Dose dependent colour stabilization of a 50% glucolipid solution by MnSO4 Glucolipids were prepared as described WO2019/154970. MnSO4xH2O was added to a 50 wt.% glucolipid solution in water from a 1% (w/w) pre-dilution in water to the final concentration of 10 ppm and 25 ppm Mn2+ and mixed well. The sample was filled into an air-tight container and incubated at 45°C. At the indicated timepoints, samples were taken and measured spectrophotometrically according to ISO 4630. The results (Gardener) are shown in figure 5. Example 6: The use of MnSO4 to prevent malodour of a biosurfactant composition Rhamnolipids were prepared as described in example 1 of EP3023431. MnSO4xH2O was added to a 50 wt.% rhamnolipid solution in water from a 1% (w/w) pre-dilution in water to the final concentration of 0 ppm and 10 ppm Mn2+ and mixed well. The sample was then filled into an air-tight container and incubated at 45°C for 50 days. The impact of manganese on sensory properties of the rhamnolipid composition was tested by odour evaluation using a panel of trained panelists. By “trained panelists” we mean here individuals that had previously been screened for olfactive acuity and were experienced comparing biosurfactant samples. Moreover, the panelists were prior acquainted with the malodor sample before carrying out the evaluation of the samples. The results are shown in the following table on a scale from 1 to 5 concerning the odor property “rancid”.
202300074 Foreign Filing 18 t=0 days t=50 days 0 ppm Mn2+ 1.5 3.2 10 ppm Mn2+ 1.6 2.2 Example 7: Formulation examples Rhamnolipids (RLs)were prepared as described in example 1 of EP3023431. Mono-Rhamnolipids (mRLs)were prepared as described in example 2 of EP3672690. The sophorolipid (SLs) used is a sophorolipid REWOFERM® SL ONE from Evonik, which has a lactone to acid ratio of 40:60. Glucolipids (GLs) were produced according to example 2 of WO2019154970 via fermentation. As manganese source MnSO4xH2O was used. The following compositions were prepared in water: SF1 SF2 SF3 SF4 SF5 SF6 SF7 SF8 SF9 SF10 RLs / wt.-% 40 40 - - - - - - 16 16 mRLs / wt.-% - - 35 35 - - - - 4 4 SLs / wt.-% - - - - 40 40 - - 10 10 GLs / wt.-% - - - - - - 40 40 10 10 Mn2+ / ppm 5 400 5 400 5 400 5 400 5 400 Each of the stock solution SF1 to SF10 is used to prepare the formulations listed below, where SFX stands for the respective stock solution; thus, 10 different formulations are explicitly disclosed in each recipe below. Recipes 1a: Shower Cream Ingredients ^wt.% ^ 1a Water ad 100.0 Sodium Laureth Sulfate (Texapon NSO, BASF, 28%) 25.0 Coco-Glucoside (Plantacare 818 UP, BASF, 51%) 8.0 Cocamidopropyl Betaine (TEGO® Betain F 50, Evonik, 38%) 8.0 SFX 2.3 PEG-18 Glyceryl Oleate/Cocoate (ANTIL® 171, Evonik) 1.5 Sorbitan Sesquicaprylate (ANTIL® Soft SC, Evonik) 0.8
202300074 Foreign Filing 19 Glyceryl Oleate (TEGIN ® O V, Evonik) 0.8 Perfume Spicy Herbs (IFF) 0.2 Polyglyceryl-4 Caprate (TEGOSOFT® PC 41, Evonik) 0.6 Helianthus Annuus Seed Oil (AEC Sunflower Oil, A & E Connock, 0.2 Perfumery & Cosmetics Ltd.) Linalool (Lipofresh, Lipo Chemicals, Inc.) 0.1 Coumarin (Rhodiascent extra pure, Solvay Rhodia) 0.1 Glycerin (Glycerol EP, vegetable, Spiga Nord) 0.4 Hydroxypropyl Methylcellulose (TEGOCEL ® HPM 50, Evonik) 0.2 Glycol Distearate (TEGIN ® G 1100 Pellets, Evonik) 0.4 Sodium Chloride 0.5 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride (Jaguar C- 0.2 162, Solvay Rhodia) dermofeel TOCO 70 non GMO 0.1 Preservative q.s. Citric Acid ad pH 5.2 Recipes 2a, 2b: Body Shampoo Ingredients ^wt.% ^ 2a 2b Phase A SFX 8 4 Lavandula Angustifolia (Lavender) Oil (AEC 0.2 0.2 Lavender Oil, A&E Connock Ltd.) Perfume 0.1 0.1 Phase B Sodium Cocoamphoacetate (REWOTERIC® AM C, 10.0 10.0 Evonik, 32%) Phase C Water ad 100.0 ad 100.0 Xanthan Gum (Keltrol CG-SFT, CP Kelco) 1.2 1.2 Phase D Sodium Lauroyl Methyl Isethionate (Iselux, 4.5 4.5 Innospec Active Chemicals) Capryl/Capramidopropyl Betaine (TEGO® Betaine 4.5 4.5 810, Evonik, 38%) Citric Acid 1.2 1.2 Phase E Water 10.0 10.0 Polyquaternium-7 (Merquat 550, Nalco) 0.4 0.4 Preservative q.s. q.s. Recipes 3a: Shampoo Ingredients ^wt.% ^ 3a
202300074 Foreign Filing 20 Phase A SFX 2.0 Isopropyl Myristate (TEGOSOFT® M, Evonik) 0.2 Perfume 0.1 Phase B Water ad 100.0 Phase C Sodium Lauryl Sulfate (Texapon LS 35, BASF, 30%) 28.0 Phase D Cocamidopropyl Betaine (TEGO® Betain F 50, Evonik, 38%) 9.0 Phase E Cocamide MEA (REWOMID® C 212, Evonik) 2.0 Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.3 Water 10.0 Phase F Water 10.0 Polyquaternium-10 (Polymer JR 400, Amerchol) 0.2 Phase G Citric Acid ad pH 5.0 Preservative q.s. Recipes 4a: Shampoo Ingredients ^wt.% ^ 4a Water ad 100.0 Cocamidopropyl Betaine (TEGO® Betain F 50, Evonik, 22.0 38%) SFX 8.0 Sodium Cocoyl Glutamate (Plantapon ACG HC, BASF) 1.5 Sodium Cocoyl Glycinate (Hostapon SG, Clariant) 0.8 Zinc Pyrithione (Microcare ZP, Thor) 0.1 PEG-120 Methyl Glucose Dioleate (ANTIL® 120 Plus, 0.4 Evonik) Sodium Chloride 0.5 Isostearamide MIPA; Glyceryl Laurate (ANTIL® SPA 80, 0.5 Evonik) Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.3 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.3 (Jaguar C-162, Solvay Rhodia) Quaternium-80 (ABIL® Quat 3272, Evonik) 0.4 Palmitamidopropyltrimonium Chloride (VARISOFT® PATC, 0.4 Evonik) Argania Spinosa Oil (Argan Oil, DSM Nutritional Products 0.1 Ltd.) Glycerin (Glycerol EP, vegetable, Spiga Nord) 0.6 Tetrasodium EDTA (Versene 100, The Dow Chemical 0.1 Company)
202300074 Foreign Filing 21 Caffeine (Merck KGaA /EMD Chemicals, Inc.) 0.1 Hydrolyzed Wheat Protein (Gluadin WLM, BASF) 0.1 Limonene (Dipentene No.122, Hercules Inc.) 0.1 Citric Acid ad pH 5.5 Sodium Phytate; Aqua; Alcohol (dermofeel® PA-3; Evonik Dr. Straetmans GmbH (PA-3) Perfume 0.2 Aqua; Sodium Levulinate; Sodium Benzoate (Verstatil® BL non GMO; Evonik Dr. Straetmans GmbH) Recipes 5a: Liquid Soap Ingredients ^wt.% ^ 5a Water ad 100 Glycerin (Glycerol EP, vegetable, Spiga Nord) 4.0 Alcohol 4.0 Sodium Coco-Sulfate (Texapon HC G, BASF) 3.0 SFX 4 Xanthan Gum (Keltrol CG-SFT, CP Kelco) 1.5 Mangifera Indica (Mango) Fruit Extract (Mango Extract, Draco Natural Products) 0.5 Limonene (Dipentene No.122, Hercules Inc.) 0.1 Linalool (Lipofresh, Lipo Chemicals, Inc.) 0.1 Citric Acid ad pH 4.9 Preservative q.s. Dyes q.s. Recipes 6a: Liquid Soap Ingredients ^wt.% ^ 6a Phase Zinc Ricinoleate; Tetrahydroxyproyl Ethylenediamine; Laureth-3; Propylene 0.80 A Glycol (TEGODEO® CW 90 E MB, Evonik) Polyglyceryl-3 Caprylate (TEGO® Cosmo P 813 MB, Evonik) 0.50 Aqua; Sodium Laureth Sulfate (Emal 228HP, Kao) 26.00 Perfume 0.30 ad Water, deionized 100 Cocamidopropyl Betaine (TEGO® Betain F 50, Evonik) 8.50 Lauryl Glucoside, 50% (Plantacare 1200 UP, BASF) 3.25 Aqua; Sodium Levulinate; Potassium Sorbate (Verstatil® SL; Evonik) 2.00
202300074 Foreign Filing 22 SFXs 0.80 Phase Sodium Chloride B Recipes 7a: Cream Soap Ingredients ^wt.% ^ 7a Water ad 100 Propylene Glycol (Euxyl K 320, Schülke & Mayr GmbH) 2.0 Coco-Glucoside (Plantacare 818 UP, BASF, 51) 10.0 Glycerin (Glycerol EP, vegetable, Spiga Nord) 5.0 SFX 1.25 Disodium Cocoyl Glutamate (Planatpon ACG LC, BASF) 2.5 Xanthan Gum (Keltrol CG-SFT, CP Kelco) 1.2 Stearic Acid (Pristerene 4922, Croda Europe, Ltd.) 1.2 Citric Acid ad pH 5.5 Olea Europaea Fruit Oil (Cropure Olive, Croda Europe, Ltd.) 0.2 Glyceryl Oleate (TEGIN ® O V, Evonik) 1.0 Sodium Cocoyl Glutamate (Plantapon ACG HC, BASF) 0.8 Perfume 0.1 Preservative q.s. Recipes 8a: Oil Bath Ingredients ^wt.% ^ 8a ad Water 100.0 Glycine Soja Oil (Cropure Soybean, Croda Europe, Ltd.) 20.0 SFX 6.0 Polyglyceryl-3 Palmitate (Dermofeel® PP, Evonik Dr. Straetmans) 4.5 Glyceryl Caprylate (Dermosoft® GMCY, Evonik Dr. Straetmans) 3.0 Simmondsia Chinensis Seed Oil (AEC Jojoba Oil Refined, A & E Connock, Perfumery 1.2 & Cosmetics Ltd.) Prunus Amygdalus Dulcis (Sweet Almond) Oil (Cropure Almond, Croda Europe, Ltd.) 1.0 Triticum Vulgare Germ Oil (Cropure Wheatgerm, Croda Europe, Ltd.) 0.5 Tocopherol (Euxyl K 700, Schülke & Mayr GmbH) 0.2 Limonene (Dipentene No.122, Hercules Inc.) 0.1 Citral 0.1 Preservative q.s. Dyes q.s.
202300074 Foreign Filing 23 Recipe 9a, 9b: Oil Bath Ingredients ^wt.% ^ 9 Phase A C12-C15 Alkyl Benzoate (TEGOSOFT® TN, Evonik) 29.5 Helianthus Annuus (Sunflower) Seed Oil 26.0 Paraffinum Perliquidum 30.0 Diethylhexyl Sodium Sulfosuccinate (TEGO® Sulfosuccinate 9.0 DO 75; Evonik SFX 2 Polyglyceryl-3 Caprate (TEGOSOFT® PC 31 MB; Evonik) 5.0 Phase B Water ad 100 Phase Z Preservative q.s. Recipes 10a: Micellar Water for make-up removal Ingredients ^wt.% ^ 10a Water ad 100.0 Perfume 0.1 SFX 2.5 Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; 1.0 Polyglyceryl-4 Caprate; Polyglyceryl-6 Ricinoleate (TEGO® Solve 61, Evonik) Betaine (TEGO® Natural Betaine, Evonik) 2.0 Glycerin (Glycerol EP, vegetable, Spiga Nord) 1.0 Preservative q.s. Recipes 11a: Natural Micellar Water Ingredients ^wt.% ^ 11a Phase Caprylyl/Capryl Glucoside; Aqua; Sodium Cocoyl Glutamate; Glyceryl 2.5 A Caprylate; Citric Acid; Polyglyceryl-6 Oleate; Sodium Surfactin (symbio®solv clear plus MB, Evonik) Perfume 0.3 SFXs 2 Phase Glycerin 5.0 B Betaine (TEGO® Natural Betaine; Evonik) 2.0 Phenylpropanol (dermosoft® 250 eco; Evonik) 0.4 Pentylene Glycol (dermosoft® Pentiol eco; Evonik) 2.0 Sodium Phytate; Aqua; Alcohol (dermofeel® PA-3; Evonik) 0.1 ad Water, deionized 100
202300074 Foreign Filing 24 Recipes 12a: Micellar Water Ingredients ^wt.% ^ 12a SFXs 5 Water ad 100 Betaine (TEGO® Natural Betaine; Evonik) 2.0 Pentylene Glycol (dermosoft® Pentiol eco; Evonik) 4.0 Sodium Anisate (dermosoft® anisate eco; Evonik) 0.3 Glycerin 1.0 Perfume q.s. Recipes 13a: Skin Tonic Ingredients ^wt.% ^ 13a Phase ad Water, deionized A 100 Sodium PCA; Aqua (Ajidew NL-50N; Ajinomoto) 0.5 Glycerin 4.0 Phase SFXs 2 B Sodium Caproyl/Lauroyl Lactylate; Triethyl Citrate (dermosoft® decalact 1.0 liquid; Evonik) Alcohol denat. 25.0 Perfume 0.3 Triethyl Citrate (dermofeel® TEC eco; Evonik) 2.0 Recipes 14a: Scalp Serum Ingredients ^wt.% ^ 14a Phase ad Water A 100 Propylene Glycol 1.0 Xanthan Gum (Keltrol CG-SFT) 0.2 Phase SFXs 0.6 B Ceramide NG; Olea Europaea (Olive) Fruit Oil; Ricinus 1.0 Phase Communis (Castor) Seed Oil; Evonik) C Phenoxyethanol; Caprylyl Glycol (Verstatil® PC; Evonik) 1.0 Polyglyceryl-3 Caprylate (TEGO® Cosmo P 813 MB; 1.0 Evonik)
202300074 Foreign Filing 25 Phase Citric Acid (10% sol.) q.s. D Recipes 15a: Micellar Cleansing Foam Ingredients ^wt.% ^ 15a Phase Polyglyceryl-Caprylate; Polyglyceryl-3 Cocoate; Polyglyceryl- 4.0 A 4 Caprtar; Polyglyceryl-6 Ricinoleate (TEGO® Solve 61 MB, Evonik SFX 1 Prunus Amygdalus Dulcis (Sweet Almond) Oil 0.2 Caprylyl/Capryl Glucoside; Aqua; Sodium Cocoyl Glutamate; 1.67 Glyceryl Caprylate; Citric Acid; Polyglyceryl-6 Oleate; Sodium Surfactin (symbio®solv clear plus MB, Evonik) Phase Bisabolol 0.1 B ad Water 100 Glycerin 3.0 Benzyl Alcohol; Caprylyl Glycol; Benzoic Acid (Verstatil® 1.0 BOB, Evonik) Ad NaOH (10%) pH 5.5 Recipes 16a: Liquid Facial Cleanser Ingredients ^wt.% ^ 16a SFXs 3 Polyglyceryl-4 Caprate (TEGOSOFT® PC 41 MB; Evonik) 2.0 Benzyl Alcohol; Caprylyl Glycol; Benzoic Acid (Verstatil® BOB, 2.0 Evonik) Water ad 100 Glycerin 2.0 1,2-Hexanediol (dermosoft® Hexiol) 1.4 Sodium Hydroxide (25% sol) q.s. Recipes 17a: Biphasic Make-up Remover Ingredients ^wt.% ^ 17a Phase Water, deionized ad 100 A Glycerin (Glycerin 99,5%, Ph. Eur.; Cremer Oleo) 10.0
202300074 Foreign Filing 26 Glycerin; Aqua; Sodium Levulinate; Sodium Anisate 3.5 (dermosoft® 1388 eco) Polyglyceryl-10 Laurate; Aqua; Citric Acid 0.45 (dermofeel® G 10 L 70 MB; Evonik) SFXs 1 Sodium Chloride 1.0 Phase Glyceryl Caprylate (dermosoft® GMCY MB; Evonik) 0.25 B Helianthus annuus seed oil (Sunflower oil) (Henry 42.0 Lamotte Oils GmbH) Tocopherol; Helianthus Annuus (Sunflower) Seed 0.1 Oil (derrmofeel Toco 70 non GMO; Evonik) Seabuckthorn Pulp Oil (Hippophae Rhamnoides 0.1 Fruit Oil (Henry Lamotte Oils GmbH) Recipes 18a: Facial Cleansing Gel Ingredients ^wt.% ^ 18a Water ad 100 Xanthan Gum (Keltrol CG-SFT) 1.5 Sodium Cocoamphoacetate (REWOTERIC® AM C 10.0 MB; Evonik) Citric Acid (30% sol.) 1.6 Capryl/Capramidopropyl Betaine (TEGO® Betain 810 6.6 MB; Evonik) SFX 5 Sodium Chloride q.s Sorbitan Caprylate, Glyceryl Oleate (TEGO® Remo 1.5 95 MB) Phenoxyethanol; Benzoic Acid (Verstatil® BP; Evonik) 0.8 Recipes 19a: Wet Wipe solution Ingredients ^wt.% ^ 19a SFX 8 Aloe Barbadensis Leaf Extract (Aloe-Con UP 40, Florida Food Products Inc.) 0.2 Isopropyl Myristate (TEGOSOFT® M, Evonik) 0.2 Disodium Cocoamphodiacetate (REWOTERIC® AM 2 C NM, Evonik, 39%) 1.5 Perfume 0.2 Propylene Glycol (Euxyl K 320, Schülke & Mayr GmbH) 2.5
202300074 Foreign Filing 27 Hydrolyzed Silk (Crosilk 10000, Croda Inc.) 0.2 Caprylyl/Capryl Glucoside (Plantacare 810 UP, BASF) 0.7 Water ad 100.0 Citric Acid ad pH 5.0 Phenoxyethanol (S&M Phenoxyethanol, Schülke & Mayr GmbH) 0.5 Dehydroacetic Acid (Unisept DHA (Universal Preserv-A-Chem, Inc.) 0.1 Sodium Benzoate (Euxyl K 712, Schülke & Mayr GmbH) 0.4 Salicylic Acid (Salicylic acid nat.; Evonik Dr. Straetmans GmbH) 0.5 Recipes 20a Cleansing Bar Ingredients ^wt.% ^ 20a Sorbitan Oleate (TEGO® SMO V; Evonik) 1.00 Theobrom Cacao (Cocoa) Seed Butter 6.80 Hydrogenated Palm Oil; Hydrogenated Rapeseed Oil 2.50 (dermofeel® viscolid MB; Evonik) Cetearyl Alcohol (TEGO® Alkanol 1618 MB; Evonik) 24.5 Sorbitan Caprylate; Glyceryl Oleate (TEGO® Remo 95 3.00 MB; Evonik) Cellulose (TEGO® Feel C 10; Evonik) 2.50 Sodium Coco-Sulfate, 94% 25.0 Cocamidopropyl Betaine (TEGO® Betain CK D MB; 25.0 Evonik) SFX 0.8 Tocopherol; Helianthus Annuus (Sunflower) Seed Oil 0.2 (dermofeel® Toco 70 non GMO; Evonik) Glyceryl Caprylate (dermosoft® GMCY MB; Evonik) 0.5 Oleyl Erucate (TEGOSOFT® OER MB; Evonik) 6.0 Zinc Oxide 2.0 Perfume 1.0 Recipes 21a: Cleansing Cream Ingredients ^wt.% ^ 21 Phase A Helianthus Annuus (Sunflower) Seed Oil 50.0 Sorbitan Sesquicaprylate (ANTIL® Soft SC; Evonik) 7.0 Phase B Sodium Laureth Sulfate, 28% 10.7 SFXs 3.5 Glycerin 1.0 Water ad 100 Phase C Preservative, perfume q.s.
202300074 Foreign Filing 28 Recipes 22a: Body Wash Peeling Ingredients ^wt.% ^ 22a Phase Helianthus Annuus (Sunflower) Seed Oil 50.0 A Diethylhexyl Sodium Sulfosuccinate (TEGO® 9.0 Sulfosuccinate DO 75; Evonik) Phase Disodium Laureth Sulfate (REWOPOL® SB FA 30 7.0 B B MB; Evonik) Cocamidopropyl Betaine (TEGO® Betain F 50 MB; 5.0 Evonik) SFXs 4 Glycerin 2.0 Water ad 100 Phase Hydrated Silica (Sipernat 2200 PC; Evonik) q.s. C Preservative, perfume q.s. Recipes 23a: Cleansing Powder Ingredients ^wt.% ^ 23a Phase Capryl/Capramidopropyl Betaine (TEGO® Betain 12.0 A 810 MB; Evonik) Sodium Cocoamphoacetate (REWOTERIC® AM C 15.0 MB; Evonik) Sucrose Cocoate (TEGOSOFT® LSE 65 K Soft) 3.0 Sorbitan Sesquicaprylate (ANTIL® Soft SC MB; 1.0 Evonik) Bis-(Isostearoyl/Oleoyl Isopropyl) imonium 1.0 Methosulfate (VARISOFT® EQ 100; Evonik) SFXs 6 Oleyl Erucate (TEGOSOFT® OER MB; Evonik) 2.0 Helianthus Annuus (Sunflower) Seed Oil 5.0 Citric Acid (30% sol.) 3.0 Phase Sipernat 500 LS Hydrated Silica) B Wheat Flour 29.0 Cocamidopropyl Betaine (TEGO® Betain CK D MB; 12.5 Evonik) Preservative, Perfume q.s. Recipes 24a: Cleansing Oil
202300074 Foreign Filing 29 Ingredients ^wt.% ^ 24a SFXs 0.5 Polyglyceryl-2 Sesquioleate (dermofeel® GO soft; 5.0 Evonik) Helianthus Annuus (Sunflower) Seed Oil 36.0 Isoamyl Laurate (dermofeel® sensolv MB; Evonik) 35.0 TEGOSOFT® DC MB (Decyl Cocoate; Evonik) 5 Polyglyceryl-2 Caprate (dermosoft® DGMC MB; 2 Evonik) Tocopherol; Helianthus Annuus (Sunflower) Seed Oil 1.0 (dermofeel® Toco 70 non GMO; Evonik) Sesamum Indicum (Sesame Seed) Oil 16 Recipes 25a: Anti-Transpirant Deo Ingredients ^wt.% ^ 25a Phase A SFX 1 Dicaprylyl Ether (Cetiol OE, BASF) 0.3 Geraniol (Nerol 800, International Flavors & Fragrances Inc.) 0.1 Linalool (Lipofresh, Lipo Chemicals, Inc.) 0.1 Perfume 0.1 Phase B Propylene Glycol (Euxyl K 320, Schülke & Mayr GmbH) 1.0 Butylene Glycol (Oxea Corparation) 0.2 Water 5.0 Palmitamidopropyltrimonium Chloride (VARISOFT® PATC, Evonik) 1.0 Phase C Water 50.0 Hydroxethyl Ethylcellulose (Structure Cel 4400 E, AkzoNobel) 0.8 Sodium Hydroxide (10% in water) 0.3 Phase D Aluminium Chlorohydrate (Locron L, Clariant) 15.0 Phase E Preservative q.s. Water ad 100.0 Recipes 26a: Mouthwash Ingredients ^wt.% ^ 26a SFX 1 Flavor 0.2 Water ad 100.0 Sorbitol (Karion FP Liquid , Merck) 3.0 Preservative q.s. Dyes q.s.
202300074 Foreign Filing 30 Recipes 27a: Toothpaste Ingredients ^wt.% ^ 27a Phase A Sorbitol (Karion FP Liquid , Merck) 50.0 Water ad 100.0 SFX 2 Sodium Carboxymethylcelluslose (Blanose 7MXF, Ashland) 1.2 Phase B Sodium Saccharine (Sigma Aldrich) 0.1 Sodium Fluoride (Sigma Aldrich) 0.1 Phase C Titanium Dioxide (Caesar & Loretz) 0.4 Hydrated Silica (Zeodent® 113, Evonik) 14.0 Hydrated Silica (Zeodent® 165, Evonik) 8.0 Phase D Flavor oil 1.0 Phase E Glyceryl Caprylate (dermosoft® GMCY, Evonik) 0.3 Recipes 28a: Kitchen Cleaning Spray Ingredient 28a REWOTERIC® AM V 0.5 SFX 1 TOMAKLEEN® G-14 2.0 Water (Dye. Perfume) ad 100 Triethanolamine 4.0 Recipes 29a: Extra Mild Dish Wash Foam Ingredient 29a C10-16 Alkylpolyglucoside.50 10.0 Xanthan Gum 0.1 Glycerin 2.0 Water ad 100 SFX 0.8 Sophorolipid 2.0 REWOPOL® SB CS 50 5.0 TEGO® Betain C 60 3.0 Preservative qs. Recipes 30a: Automatic Rinse Aid for Direct Use 1
202300074 Foreign Filing 31 Ingredient 30a TEGOTENS® EC 11 5.0 SFX 5 Citric acid monohydrate 5.0 Water (Dye. Perfume) ad 100 Recipes 31a: Automatic Rinse Aid for Direct Use 2 Ingredient 31a Citric acid monohydrate 5.0 Sodium Cumene Sulfonate.92 1.5 Water (Dye;Perfume) ad 100 TEGOTENS® EC 11 6.0 SFX 4 Recipes 32a: Automatic Rinse Aid for Direct Use 3 Ingredient 32a Citric acid monohydrate 5.0 Sodium Cumene Sulfonate.92 1.5 Water (Dye. Perfume) ad 100 TEGOTENS® EC 11 7.0 SFX 3 Recipes 33a: Glass Cleaner With Optimized Antifogging Efficiency Ingredient 33a REWOPOL® TS 35 1.0 SFX 0.5 Isopropanol 15.0 EDTA 1.0 Water (Dye. Perfume) ad 100 Recipes 34a: Oven Cleanser for Smoking Chamber Ingredient 34a Water ad 100 Trilon A liquid 8.0 Sodium carbonate 6.0 REWOTERIC® AM KSF 40 5.0 Laureth-6 1.2 SFX 1.2 DOWANOL DPnB 1.0
202300074 Foreign Filing 32 Recipes 35a: All Purpose Cleanser (Microemulsion) Ingredient 35a Water ad 100 TEGOTENS® AM VSF 6.0 SFX 2 REWOPOL® D 510 NC 5.0 Undeceth-6 3.0 Potassium hydroxide.50 5.0 Chelating Agent. MGDA 5.0 Recipes 36a: Low Foaming Hard Surface Degreaser Ingredient 36a C9-11 FATTY ALCOHOL ETHOXYLATE - 8 MOLES OF EO 2.0 SFX 1 TEGOTENS® G 826 C 4.0 Chelating Agent. MGDA 7.5 Water (Dye. Perfume) ad 100 Recipes 37a: Low Foaming Hard Surface Degreaser (101630-23) Ingredient 37a C9-11 FATTY ALCOHOL ETHOXYLATE - 8 MOLES OF EO 2.0 SFX 1 TEGOTENS® G 826 C 4.0 Water (Dye. Perfume) ad 100 Recipes 38a: Foaming Hard Surface Degreaser 1 Ingredient 38a C9-11 FATTY ALCOHOL ETHOXYLATE - 8 MOLES OF EO 2.0 TEGOTENS® AM VSF 6.0 SFX 1 Water (Dye. Perfume) ad 100 Recipes 39a: Foaming Hard Surface Degreaser 2 Ingredient 39a C9-11 FATTY ALCOHOL ETHOXYLATE - 8 MOLES OF EO 3.0 REWOTERIC® AM KSF 40 2.5 SFX 1 Water (Dye. Perfume) ad 100
202300074 Foreign Filing 33 Recipes 40a: Low Foaming Hard Surface Degreaser 3 Ingredient 40a SFX 0.5 C8-10 Alkylpolyglucosid 4.0 Sodium C13-17 Alkane Sulfonate.30 2.0 Water (Dye. Perfume) ad 100 Recipes 41a: Low Foaming Hard Surface Degreaser 4 Ingredient 41a SFX 1 C8-10 Alkylpolyglucosid 4.0 Sodium C13-17 Alkane Sulfonate.30 2.0 Chelating Agent. MGDA 7.0 Water (Dye. Perfume) ad 100 Recipes 42a: Low Foaming Hard Surface Degreaser 4 Ingredient 42a SFX 1 C8-10 Alkylpolyglucosid 4.0 Sodium C13-17 Alkane Sulfonate.30 2.0 Water (Dye. Perfume) ad 100 Recipes 43a: Hard Surface Degreaser From Renewable Surfactants Ingredient 43a Water ad 100 Sodium carbonate 3.0 TEGOTENS® AM VSF 2.4 Laureth-6 0.6 SFX 0.4 TEGO® Polish Additiv Q 70 0.3 Recipes 44a: Highly Efficient Floor Cleanser Ingredient 44a Water ad 100 Desferrioxamine 4.0 Sodium carbonate 3.0 TEGOTENS® AM VSF 2.4 Laureth-6 0.6
202300074 Foreign Filing 34 SFX 0.4 TEGO® Polish Additiv Q 70 0.3 Recipes 45a: Super Natural Wash Lotion for Textile Face Masks Ingredient 45a Xanthan Gum 0.1 Glycerin 2.0 Water ad 100 SFX 1 Sophorolipid 2.0 REWOPOL® SB CS 50 5.0 C8-10 Alkylpolyglucosid 10.0 TEGO® Betain C 60 3.0 Preservative qs. Recipes 46: Highly Effective Presoaker Ingredient 46a Water ad 100 Sodium metasilicate 2.0 Sodium gluconate 2.0 Sodium carbonate 2.0 TEGOTENS® AM VSF 6.5 Undeceth-6 0.6 SFX 0.4 DOWANOL DPnB 1.0 Recipes 47a: Presoaker (Basic Formula) Ingredient 47a Water ad 100 Trilon A 92 3.0 Sodium metasilicate 2.0 Sodium carbonate 2.0 Bayhibit AM 1.0 REWOTERIC® AM KSF 40 4.0 C9-11 FATTY ALCOHOL ETHOXYLATE - 8 MOLES OF EO 1.2 SFX 1 DOWANOL DPnB 3.0 Recipes 48a: Good Dispersing Presoaker
202300074 Foreign Filing 35 Ingredient 48a Water ad 100 Trilon A 92 3.0 Sodium metasilicate 2.0 Sodium carbonate 2.0 Sequion 10 Na 430 2.0 TEGOTENS® 475 5.0 C9-11 FATTY ALCOHOL ETHOXYLATE - 7 MOLES OF EO 1.5 SFX 3 DOWANOL PnB 3.0 Recipes 49a: Cost Efficient Presoaker Ingredient 49a Water ad 100 Chelating Agent. M 8.0 Sodium carbonate 6.0 TEGOTENS® AM VSF 3.5 Laureth-6 0.6 SFX 0.4 DOWANOL DPnB 1.0 Recipes 50a: Rinse Aid to minimize remaining water Ingredient 50a REWOPAL® MPG 40 6.0 Butyl Cellusolve (BG) 14.0 SFX 3 REWOQUAT® CR 3099 10.0 TEGOSOFT® OP 5.0 Water ad 100 Recipes 51a: Rinse Aid with Optimal Oil Content Ingredient 51a DOWANOL DPnB 8.6 REWOPAL® MPG 40 6.2 REWOQUAT® CR 3099 10.0 REWOCARE® DOC 4.0 TEGOSOFT® OP 3.0 SFX 1 Water ad 100
202300074 Foreign Filing 36 TEGOPREN® 6923 0.4 Recipes 52a: Low Foaming All Purpose Cleaner Ingredient 52a Water ad 100 Trilon A 92 3.0 Sodium metasilicate 2.0 Sodium carbonate 2.0 Sequion 10 Na 430 2.0 TEGOTENS® 475 5.0 C9-11 FATTY ALCOHOL ETHOXYLATE - 7 MOLES OF EO 1.5 SFX 1.5 DOWANOL PnB 1.0 Recipes 53a: Low Foaming Alkaline Cleanser Ingredient 53a Water ad 100 Chelating Agent. M 4.0 Sodium carbonate 6.0 TEGOTENS® AM VSF 3.5 Laureth-6 0.6 SFX 1 Recipes 54a: Low Foaming Alkaline Cleaner Ingredient 54a Water ad 100 TOMAKLEEN G-14 0.75 TEGOTENS® AM VSF 3.5 SFX 1.8 Sodium carbonate 6.0 Recipes 55a: Alkaline Cleanser (Automatic Wash) Ingredient 55a Water ad 100 Tetra Potassium Pyrophosphate (TKPP) 15.0 Trilon A liquid 5.0 KOH.45 4.0 Sequion 10 Na 430 10.0 Sodium metasilicate 6.0
202300074 Foreign Filing 37 SFX 1
Ingredient 56a Water ad 100 TOMAKLEEN® G-14 12.0 REWOTERIC® AM V 1.5 SFX 3 Triethanolamine 1.5 Recipes 57a: Metal Cleanser Ingredient 67a Water (Dye. Perfume) ad 100 Triethanolamine 1.5 DOWANOL PnP 6.0 REWOTERIC® AM V 1.5 SFX 3 C8-10 Fatty alcohol · 5 EO 6.0 Recipes 58a: Cost Efficient Facade Cleanser Ingredient 58a Water ad 100 Chelating Agent. MGDA 4.0 Sodium carbonate 6.0 TEGOTENS® AM VSF 2.4 Laureth-6 0.6 SFX 0.8 Recipes 59a: Anti-dust Glass and Window Cleaner 1 Ingredient 59a Water ad 100 Ethanol 15 Rewocare® 755 0.5 SFX 2 2-Phenoxyethanol 0.1 pH value (adjust to) 8 Recipes 60a: Anti-dust Glass and Window Cleaner 2
202300074 Foreign Filing 38 Ingredient 60a Water ad 100 Ethanol 15 Rewocare® 755 0.5 SFX 1 Tegotens® AM VSF 1 2-Phenoxyethanol 0.1 pH value (adjust to) 8.00 Recipes 61a: Anti-dust Glass and Window Cleaner 3 Ingredient 61a Water ad 100 Ethanol 3 SFX 1.5 Tegotens® DO 40 1 Tegopren® 5840 0.05 2-Phenoxyethanol 0.1 pH value (adjust to) 6.0-7.0 Recipes 62a: All-purpose Cleaner concentrate Ingredient 62a Water ad 100 Ethanol 3 SFX 2 Rewocare® 755 0.5 Rewopol® SB DO 75 3 2-Phenoxyethanol 0.1 pH value (adjust to) 8 Recipes 63a: All-purpose Cleaner Cleaner Trigger spray Ingredient 63a Water ad 100 Ethanol 3 SFX 1.5 Tego® Betain Powder MB 1 Rewocare® 755 0.5 2-Phenoxyethanol 0.1
202300074 Foreign Filing 39 pH value (adjust to) 8.00 Recipes 64a: Floor Cleaner Ingredient 64a Water ad 100 SFX 1 Tego® PP 1027 0.5 Tego® Betain Powder MB 1 Tomadol 91-6 4 2-Phenoxyethanol 0.1 pH value (adjust to) 8.00 Recipes 65a: Bathroom Cleaner Ingredient 65a Water ad 100 SFX 3 Tego® Betain Powder MB 1.5 Rewocare® 755 0.5 Tegotens® AM VSF 1.5 2-Phenoxyethanol 0.1 pH value (adjust to) 5.5 Recipes 66a, 66b, 66c: Handdishwash Liquid Ingredient 66a 66b 66c Water ad 100 ad 100 ad 100 Texapon 70 15 5 TEGO® Betain C 60 4.8 3 3 SFX 3 2 2 Sophorolipid 1.3 Glucolipid 2.6 C10-16 APG, 50 10 10 NaCl 1.25 Xanthan Gum 0.3 0.3 Glycerin 2 2 Rewopol® SB CS 50 5 Preservative q.s. q.s. q.s. pH value 5.5 5.5 5.5 Recipes 67a: Cleaner for Plastic furniture and interieur Ingredient 67a Water ad 100
202300074 Foreign Filing 40 SFX 1 Tego® Betain C 60 1.5 Tomakleen 91-6 1.5 Rewoquat® Q 70 0.5 pH value (adjust to) 9 Recipes 68a: Grill and Oven Cleaner Ingredient 68a Water ad 100 MGDA 5 Sodium Carbonate 5 Rewoteric® AM KSF 40 MB 5 Tomadol 91-6 1.5 SFX 1.5 Dowanol DPnB 1 pH (adjust to) 12 Recipes 69a, 69b, 69c: Cleaner for Food&Beverage Fatsolve Ingredient 69a 69b 69c Water ad 100 ad 100 ad 100 Rewoquat® CQ 200 20 12 12 Rewoteric® AM KSF 40 MB 10 SFX 5 5 5 MGDA 5 5 Sodium Carbonate 3 3 Tomadol 91-8 5 Tomadol 1-5 3 2 pH value (adjust to) 12 12 12 Recipes 70a, 70b: Car Shampoo Ingredient 70a 70b Water ad 100 ad 100 Tomakleen G-14 5 MGDA 2 3 Sodium Carbonate 2 SFX 0.5 3 Sophorolipid 1.5 1.5 Tomadol 91-6 3 Rewocare® 755 0.5 0.5
202300074 Foreign Filing 41 Tego® Betain C 60 2 3 pH value (adjust to) 10 9 Recipes 70a, 70b, 70c: Car Rinse Ingredient 70a 70b 70c Water ad 100 ad 100 ad 100 Carspray 90 MB 20 - - Rewopol® MPG 40 - 5 5 SFX 0.5 0.5 1 Rewoquat® CR 3099 - 15 - Tegopren® 6922 - - 20 Isopropanol 2 2 2 pH value (adjust to) 8 8 8 Recipes 71a, 71b, Automatic Dish Wash Powder Ingredient 71a 71b Sodium carbonate 42.0 42.0 Sodium sulphate 20.0 20.0 Sodium citrate 15.0 15.0 Sodium percarbonate 10.0 10.0 Polymer 3.0 3.0 Phosphonate (HEDP) 2.5 2.5 Sodium metasilicate 2.0 2.0 Tomakleen G-14 1.0 1.0 SFX 1 1 TAED 2.0 2.0 Protease 1.0 - Amylase 0.5 - Recipes 72a: Automatic Dish Wash Gel Ingredient 72a Water ad 100 Tetrasodium Glutamare diacetate / GLDA 14 Glycerol 9.0 Polyacrylate polymer 2.0 Protease 1.0 Formic acid 0.2 PPG-1 C6-10 Pareth-20 2.0 Amylase 0.50
202300074 Foreign Filing 42 SFX 0.5 Xanthan Gum 0.50 Perfumes 0.20 Zinc acetate dihydrate 0.10 Calcium Chloride 0.10 Limonen 0.050 Colorant 0.050 CIT/MIT 0.050 Recipes 73a, 73b, 73c, 73d, 73e, 73f: Laundry pre-spotter Ingredient 73a 73b 73c 73d 73e 73f SFXs 5 5 12 12 5 5 Sophorolipids 6 6 2.5 2.5 0.5 0.5 Lauryl/Myristil 12 12 Glucoside Propylene Glycol 2 2 2 2 2 2 Na citrate 2 2 2 2 2 2 Na formate 0.5 0.5 0.5 0.5 0.5 0.5 CaCl2 0.1 0.1 0.1 0.1 0.1 0.1 NaOH 0.05 0.05 0.05 0.05 0.05 0.05 Protease 1 1 0.4 Amylase 0.4 0.4 0.4 0.4 0.2 Mannanase 0.2 0.2 0.2 0.2 0.2 Pectinase 0.2 0.2 0.2 0.2 0.2 Cellulase 0.2 0.2 0.2 0.2 0.2 Water ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 Recipes 74a, 74, 74c, 74d: Laundry pre-spotter Ingredient 74a 74b 74c 74d SFXs 5 5 3 3 Lauryl/Myristil 12 12 9 9 Glucoside Propylene Glycol 2 2 2 2 Na citrate 2 2 2 2 Na formate 0.5 0.5 0.5 0.5 CaCl2 0.1 0.1 0.1 0.1 NaOH 0.05 0.05 0.05 0.05 Protease 1 - 1 - Amylase 0.4 - 0.4 -
202300074 Foreign Filing 43 Mannanase 0.2 - 0.2 - Pectinase 0.2 - 0.2 - Cellulase 0.2 - 0.2 - Water ad 100 ad 100 ad 100 ad 100 Recipes 75a, 75, 75c, 75d: Laundry pre-spotter Ingredient 75a 75b 75c 75d SFXs 5 5 1 1 Propylene Glycol 2 2 2 2 Na citrate 2 2 2 2 Na formate 0.5 0.5 0.5 0.5 CaCl2 0.1 0.1 0.1 0.1 NaOH 0.05 0.05 0.05 0.05 Protease 1 1 1 1 Amylase 0.4 0.4 0.4 0.4 Mannanase 0.2 0.2 0.2 0.2 Pectinase 0.2 0.2 0.2 0.2 Cellulase 0.2 0.2 0.2 0.2 Water ad 100 ad 100 ad 100 ad 100 Recipes 76a, 76b, 76c, 76d, 76e, 76f: laundry detergents Ingredient 76a 76b 76c 76d 76e 76f SFXs 14 7 7 7 7 7 C12/147EO (Dehydol® LT7) - 5.0 5.0 2.5 - 5.0 SLES 2EO (Texapon® N70) - 7.0 5.0 2.5 5.0 .0 Linear alkylbenzene Sulfonates (LAS) - - 0.5 5 - - C8C16 Alkyl polyglucosid (Glucopon® - - - - 2.5 - 650 EC) Amine oxide - - - 1 - - Sodium xylene sulfonate (Eltesol® 1.0 1.0 1.0 1.0 1.0 1.0 SX40) Na soap from palm kernel oil 5.00 5.00 5.00 5.00 5.00 5.00 Amide polyglycol ether (Amidet® N) - - - - - 1.0 Polyethyleneimine PEI, 20 EO 1.0 1.0 1.0 1.0 1.0 1.0 (Sokalan® HP20) Sodium citrate 3.50 3.50 3.50 3.50 3.50 3.50 Sodium Phosphonate (Dequest® 2.0 2.0 2.0 2.0 2.0 2.0 2066) Ethanol 2.50 2.50 2.50 2.50 2.50 2.50
202300074 Foreign Filing 44 MPG 1.0 1.0 1.0 1.0 1.0 1.0 Boric acid 1.0 1.0 1.0 1.0 1.0 1.0 Phenoxyethanol (Acticide® SR150) 0.45 0.45 0.45 0.45 0.45 0.45 Liquanase® 3.5 L 1.0 1.0 1.0 1.0 1.0 1.0 Amplify® Prime 100 L 0.4 0.4 0.4 0.4 0.4 0.4 Mannaway® 200 L 0.2 0.2 0.2 0.2 0.2 0.2 Carezyme® Premium 4500 L 0.2 0.2 0.2 0.2 0.2 0.2 XPect® 1000 L 0.2 0.2 0.2 0.2 0.2 0.2 Celluclean® 5000 L 0.2 0.2 0.2 0.2 0.2 0.2 Pristine® 100 L 0.1 0.1 0.1 0.1 0.1 0.1 NaOH 1.0 1.0 1.0 1.0 1.0 1.0 Water ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 pH 8.4 8.4 8.4 8.4 8.4 8.4 Recipes 77a, 77b, 77c, 77d, 77e, 77f: laundry detergents Ingredient 77a 77b 77c 77d 77e 77f SFXs 15 8 8 8 8 8 C12/147EO (Dehydol® LT7) - 5.0 5.0 2.5 5.0 SLES 2EO (Texapon® N70) - 7.0 5.0 2.5 5.0 5.0 Linear alkylbenzene Sulfonates (LAS) - - 2.5 2.5 - - C8C16 Alkyl polyglucosid (Glucopon® 650 - - - - 2.5 - EC) Amine oxide - - - 1 - - Sodium xylene sulfonate (Eltesol® SX40) 1.0 1.0 1.0 1.0 1.0 1.0 Na soap from palm kernel oil 5.0 5.0 5.0 5.0 5.0 5.0 Amide polyglycol ether (Amidet® N) - - - - - 1.0 Vinylpyrrolidone/Vinylimidazole copolymer 2.0 2.0 2.0 2.0 2.0 2.0 (Sokalan® HP 56) Sodium citrate 3.5 3.5 3.5 3.5 3.5 3.5 Sodium Phosphonate (Dequest® 2066) 2.0 2.0 2.0 2.0 2.0 2.0 Ethanol 2.5 2.5 2.5 2.5 2.5 2.5 MPG 1.0 1.0 1.0 1.0 1.0 1.0 Boric acid 1.0 1.0 1.0 1.0 1.0 1.0 Phenoxyethanol (Acticide® SR150) 0.45 0.45 0.45 0.45 0.45 0.45 Liquanase® 3.5 L 1.0 1.0 1.0 1.0 1.0 1.0 Amplify® Prime 100 L 0.4 0.4 0.4 0.4 0.4 0.4 Mannaway® 200 L 0.2 0.2 0.2 0.2 0.2 0.2 Carezyme® Premium 4500 L 0.2 0.2 0.2 0.2 0.2 0.2 XPect® 1000 L 0.2 0.2 0.2 0.2 0.2 0.2
202300074 Foreign Filing 45 Celluclean® 5000 L 0.2 0.2 0.2 0.2 0.2 0.2 Pristine® 100 L 0.1 0.1 0.1 0.1 0.1 0.1 NaOH 1.0 1.0 1.0 1.0 1.0 1.0 Water ad ad ad ad ad ad 100 100 100 100 100 100 pH 8.4 8.4 8.4 8.4 8.4 8.4 Recipes 78a, 78b, 78c, 78d, 78e, 78f: laundry detergents Ingredient 78a 78b 78c 78d 78e 78f SFXs 15 8 8 8 8 8 C12/147EO (Dehydol® LT7) - 5.0 5.0 2.5 - 5.0 SLES 2EO (Texapon® N70) - 7.0 5.0 2.5 5.0 5.0 Linear alkylbenzene Sulfonates (LAS) - - .5 5 - - C8C16 Alkyl polyglucosid (Glucopon® - - - - 2.5 - 650 EC) Sodium xylene sulfonate (Eltesol® 1.0 1.0 1.0 1.0 1.0 1.0 SX40) Na soap from palm kernel oil 5.0 5.0 5.0 5.0 5.0 5.0 Amide polyglycol ether (Amidet® N) - - - - - 1.0 Texcare® SRN 170 2.0 2.0 2.0 2.0 2.0 2.0 Sodium citrate 3.5 3.5 3.5 3.5 3.5 3.5 Sodium Phosphonate (Dequest® 2.0 2.0 2.0 2.0 2.0 2.0 2066) Ethanol 2.5 2.5 2.5 2.5 2.5 2.5 MPG 1.0 1.0 1.0 1.0 1.0 1.0 Boric acid 1.0 1.0 1.0 1.0 1.0 1.0 Phenoxyethanol (Acticide® SR150) 0.45 0.45 0.45 0.45 0.45 0.45 Liquanase® 3.5 L 1.0 1.0 1.0 1.0 1.0 1.0 Amplify® Prime 100 L 0.4 0.4 0.4 0.4 0.4 0.4 Mannaway® 200 L 0.2 0.2 0.2 0.2 0.2 0.2 Carezyme® Premium 4500 L 0.2 0.2 0.2 0.2 0.2 0.2 XPect® 1000 L 0.2 0.2 0.2 0.2 0.2 0.2 Celluclean® 5000 L 0.2 0.2 0.2 0.2 0.2 0.2 Pristine® 100 L 0.1 0.1 0.1 0.1 0.1 0.1 NaOH 1.0 1.0 1.0 1.0 1.0 1.0 Water ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 pH 8.4 8.4 8.4 8.4 8.4 8.4 Recipes 79a, 79b, 79c, 79d, 79e, 79f: laundry detergents
202300074 Foreign Filing 46 Ingredient 79a 79b 79c 79d 79e 79f SFXs 15 8 8 8 8 8 C12/147EO (Dehydol® LT7) - 5.0 5.0 2.5 - 5.0 SLES 2EO (Texapon® N70) - 7.0 5.0 2.5 5.0 5.0 Linear alkylbenzene Sulfonates (LAS) - - .5 5 - - C8C16 Alkyl polyglucosid (Glucopon® - - - - 2.5 - 650 EC) Amine oxide - - - 1 - - Sodium xylene sulfonate (Eltesol® 1.0 1.0 1.0 1.0 1.0 1.0 SX40) Na soap from palm kernel oil 5.0 5.0 5.0 5.0 5.0 5.0 Amide polyglycol ether (Amidet® N) - - - - - 1.0 Texcare® SRN 170 2.0 2.0 2.0 2.0 2.0 2.0 Sodium citrate 3.5 3.5 3.5 3.5 3.5 3.5 Sodium Phosphonate (Dequest® 2.0 2.0 2.0 2.0 2.0 2.0 2066) Ethanol 2.5 2.5 2.5 2.5 2.5 2.5 MPG 1.0 1.0 1.0 1.0 1.0 1.0 Phenoxyethanol (Acticide® SR150) 0.45 0.45 0.45 0.45 0.45 0.45 Liquanase® 3.5 L 1.0 1.0 1.0 1.0 1.0 1.0 Amplify® Prime 100 L 0.4 0.4 0.4 0.4 0.4 0.4 Mannaway® 200 L 0.2 0.2 0.2 0.2 0.2 0.2 Carezyme® Premium 4500 L 0.2 0.2 0.2 0.2 0.2 0.2 XPect® 1000 L 0.2 0.2 0.2 0.2 0.2 0.2 Celluclean® 5000 L 0.2 0.2 0.2 0.2 0.2 0.2 Pristine® 100 L 0.1 0.1 0.1 0.1 0.1 0.1 NaOH 1.0 1.0 1.0 1.0 1.0 1.0 Water ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 pH 8.4 8.4 8.4 8.4 8.4 8.4 Recipes 80a, 80b, 80c, 80d, 80e, 80f: laundry detergents Ingredient 80a 80b 80c 80d 80e 80f SFXs 14 8 8 8 8 8 C12/147EO (Dehydol® LT7) - 5.0 5.0 2.5 5.0 SLES 2EO (Texapon® N70) - 7.0 5.0 2.5 5.0 5.0 Linear alkylbenzene Sulfonates - - 0.5 5 - - (LAS) Sodium xylene sulfonate (Eltesol® 1.0 1.0 1.0 1.0 1.0 1.0 SX40)
202300074 Foreign Filing 47 Na soap from palm kernel oil 5.00 5.00 5.00 5.00 5.00 5.00 Texcare® SRN 170 1 1 1 1 1 - Sodium citrate 6 6 6 6 6 6 Phenoxyethanol (Acticide® SR150) 0.45 0.45 0.45 0.45 0.45 0.45 Liquanase® 3.5 L 1.0 1.0 1.0 1.0 1.0 1.0 Amplify® Prime 100 L 0.4 0.4 0.4 0.4 0.4 0.4 Mannaway® 200 L 0.2 0.2 0.2 0.2 0.2 0.2 Carezyme® Premium 4500 L 0.2 0.2 0.2 0.2 0.2 0.2 XPect® 1000 L 0.2 0.2 0.2 0.2 0.2 0.2 Celluclean® 5000 L 0.2 0.2 0.2 0.2 0.2 0.2 Pristine® 100 L 0.1 0.1 0.1 0.1 0.1 0.1 NaOH 1.0 1.0 1.0 1.0 1.0 1.0 Desferrioxamine 1.0 1.0 1.0 1.0 1.0 1.0 Water ad 100 ad 100 ad 100 ad 100 ad 100 ad 100 pH 8.4 8.4 8.4 8.4 8.4 8.4
202300074 Foreign Filing 48 Shampoo Recipess: Recipes 81: Volume and Body Shampoo Ingredient % Aqua ad 100 Sodium Lauryl Sulfate 7.0 Sodium Laureth Sulfate 5.0 Cocamidopropyl Betaine 2.0 SFX 2.0 Sodium Citrate 1.5 Sodium Xylenesulfonate 1.5 Sodium Chloride 1.4 Citric Acid ad pH 5.5 Sodium Levulinate, Sodium Benzoate 1.0 Hydroxypropyl Methylcellulose 1.0 Tetrasodium EDTA 0.8 Butylphenyl Methylpropional 0.5 Panthenol 0.5 Panthenyl Ethyl Ether 0.3 Starch Hydroxypropltrimonium chloride 0.2 Linalool 0.1 Hexyl Cinnamal 0.1 Limonene 0.1 Benzyl Salicylate 0.2 Magnesium Nitrate 0.1 Magnesium Chloride 0.1 Methylchloroisothiazolinone 0.1 Dyes q. s. Recipes 82: Repair Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 SFX 3.0 Glycol Distearate 2.5 Cocamidopropyl Betaine 2.0 Sodium Citrate 1.8
202300074 Foreign Filing 49 Cocamide MEA 1.8 Sodium Xylenesulfonate 1.5 Dimethicone 1.5 Citric Acid ad pH 5.0 Sodium Benzoate 0.7 Polyquaternium-76 0.5 Sodium Chloride 0.9 Glycerin 0.5 Tetrasodium EDTA 0.3 Butylphenyl Methylpropional 0.2 Hexyl Cinnamal 0.1 Linalool 0.1 alpha-Isomethyl Ionone 0.1 Geraniol 0.2 Hydrochloric Acid 0.1 Magnesium Nitrate 0.1 Methylchloroisothiazolinone 0.1 Magnesium Chloride 0.1 Methylisothiazolinone 0.1 Dyes q. s. Recipes 83: Anti-Dandruff Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 6.0 Sodium Lauryl Sulfate 5.0 SFX 4.0 Cocamide MEA 4.0 Zinc Carbonate 3.0 Glycol Distearate 2.5 Dimethicone 1.0 Zinc Pyrithione 1.0 Sodium Chloride 0.6 Cetyl Alcohol 0.8 Guar Hydroxypropyltrimonium Chloride 0.3 Sodium Xylenesulfonate 0.5 Magnesium Sulfate 0.7 Sodium Benzoate 0.7 Ammonium Laureth Sulfate 0.3
202300074 Foreign Filing 50 Citric Acid ad pH 4.5 Benzyl Alcohol 0.2 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 Parfum, Dyes q. s. Recipes 84: Strengthening Shampoo Ingredient % Water ad 100 Sodium Lauryl Sulfate 6.0 Sodium Laureth Sulfate 4.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Glycol Distearate 2.5 Dimethicone 2.0 Sodium Citrate 1.5 Cocamide MEA 1.0 Sodium Xylenesulfonate 1.0 Citric Acid ad pH 5.0 Sodium Benzoate 0.7 Sodium Chloride 0.8 Tetrasodium EDTA 0.3 Polyquaternium-6 0.5 Honey (Mel) 0.5 Prunus Armeniaca (Apricot) Fruit Extract 0.5 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 Parfum, Dyes q. s. Recipes 85: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 9.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Glycerin 2.5 Sodium Chloride 1.7 Glycol Distearate 1.5 Panthenol 0.2
202300074 Foreign Filing 51 Propylene Glycol 0.3 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.3 Sodium Benzoate 0.7 PEG-55 Propylene Glycol Oleate 0.5 Citric Acid ad pH 5.5 Hydrolyzed Wheat Protein 0.3 Argania Spinosa Kernel Oil 0.1 Laureth-4 0.5 Potassium Sorbate 0.2 Parfum, Dyes q. s. Recipes 86: Moisturising Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Cocamidopropyl Betaine 3.0 Sodium Chloride 2.2 SFX 2.0 Hydrolyzed Keratin 2.0 Water Lily 1.8 Nymphaea Odorata Root Extract 1.5 Glyceryl Glucoside 1.0 Panthenol 1.0 Decyl Glucoside 1.0 Polyquaternium-10 0.2 Guar Hydroxypropyltrimonium Chloride 0.3 PEG-40 Hydrogenated Castor Oil 0.7 Glycerin 0.5 Citric Acid ad pH 5.0 Sodium Benzoate 1.2 Propylene Glycol 1.0 Citronellol 0.1 Limonene 0.1 alpha-Isomethyl Ionone 0.1 Benzyl Alcohol 0.2 Dyes q. s. Recipes 87: Shampoo
202300074 Foreign Filing 52 Aqua ad 100 Decyl Glucoside 6.0 Sodium Myreth Sulfate 5.5 SFX 3.0 PEG-200 Hydrogenated Glyceryl Palmate 2.5 PEG-80 Sorbitan Laurate 2.0 PEG-90 Glycol Isostearate 2.0 Disodium PEG-5 Laurylcitrate Sulfosuccinate 1.5 Polyquaternium-10 1.2 Hydrolyzed Silk 1.2 Laureth-2 1.2 Citric Acid ad pH 5.5 Sodium Laureth Sulfate 1.0 PEG-40 Hydrogenated Castor Oil 0.9 Sodium Benzoate 0.5 Parfum, Dyes q. s. Recipes 88: Cleansing Oil Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 MIPA-Laureth Sulfate 4.0 Sodium Chloride 3.2 Cocamidopropyl Betaine 3.0 SFX 3.0 Glycerin 2.5 PEG-18 Castor Oil Dioleate 2.0 Propylene Glycol 2.0 PEG-55 Propylene Glycol Oleate 1.7 Behenamidopropyl Dimethylamine 1.2 Laureth-5 Carboxylic Acid 1.0 Persea Gratissima (Avocado) Oil 1.0 PPG-5-Ceteth-20 1.0 Sodium Benzoate 0.7 Laureth-2 0.5 Salicylic Acid 0.3 Linalool 0.2 alpha-Isomethyl Ionone 0.1 Limonene 0.1
202300074 Foreign Filing 53 Zea Mays (Corn) Germ Oil 0.2 Argania Spinosa Oil Kernel Oil 0.1 Camellia Oleifera Seed Oil 0.1 Sodium Hydroxide 0.3 Citric Acid ad pH 5.0 Parfum, Dyes q. s. Recipes 89: Shine Shampoo Ingredient % Aqua ad 100 Ammonium Lauryl Sulfate 5.5 SFX 2.0 Cocamidopropyl Betaine 2.0 Sodium Chloride 2.0 Cocamide MEA 2.0 Nacre Powder 1.0 Sodium Benzoate 0.7 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.7 Hydroxypropyltrimonium Hydrolyzed Wheat Protein 0.7 Sodium Hydroxide 0.2 Salicylic Acid 0.5 Limonene 0.1 Benzoic Acid 0.5 Linalool 0.3 Benzyl Alcohol 0.5 Tin Oxide 0.2 alpha-Isomethyl Ionone 0.1 Acrylates Copolymer 0.1 Citric Acid ad pH 5.5 Citronellol 0.1 Hexyl Cinnamal 0.1 Dyes q. s. Recipes 90: Shampoo Ingredient % Aqua ad 100 Sodium Cocoyl Isethionate 3.5 Sodium Lauryl Sulfoacetate 3.5 Disodium Laureth Sulfosuccinate 3.5
202300074 Foreign Filing 54 Cocamidopropyl Betaine 3.0 SFX 3.0 Behenamidopropyl Dimethylamine 0.9 Sodium Lauroyl Sarcosinate 1.0 Glycol Distearate 1.0 C11-15 Pareth-7 1.0 C12-13 Pareth-23 1.0 C12-13 Pareth-3 1.0 Decyl Glucoside 1.0 Tocopherol 1.0 Hydrogenated Coconut Acid 1.0 Sodium Chloride 0.8 Sodium Isethionate 0.7 Sodium Benzoate 0.7 Sodium Hydroxide 0.3 Phenoxyethanol 0.6 PPG-5 Ceteth-20 0.5 PEG-55 Propylene Glycol Oleate 0.5 Trideceth-12 0.5 Polyquaternium-7 0.5 Polyquaternium-10 0.3 Limonene 0.1 Benzoic Acid 0.3 Benzophenone-4 0.3 Benzyl Salicylate 0.2 Linalool 0.6 Benzyl Alcohol 0.6 Amodimethicone 0.5 Propylene Glycol 0.5 Carbomer 0.7 Rosmarinus Officinalis (Rosemary) Leaf Oil 0.7 Methylparaben 0.3 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 Citric Acid ad pH 5.0 Laureth-9 0.5 Divinyldimethicone/Dimethicone Copolymer 0.2 Glycerin 0.2 Parfum, Dyes q. s.
202300074 Foreign Filing 55 Recipes 91: Reinforcing Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 6.0 Dimethicone 3.0 Sodium Chloride 3.0 Coco-Betaine 3.0 SFX 2.0 Glycol Distearate 1.0 Guar Hydroxypropyltrimonium Chloride 0.3 Cocamide MIPA 0.5 Hydrolyzed keratin 0.7 Sodium Benzoate 0.7 Hydroxypropyltrimonium Hydrolyzed Wheat Protein 0.3 Sodium Cocoate 0.7 Sodium Hydroxide 0.6 Arginine 0.7 Salicylic Acid 0.5 Limonene 0.2 Linalool 0.2 2-Oleamido-1.3-Octadecanediol 0.1 Carbomer 0.5 Methyl Cocoate 0.5 Citric Acid ad pH 5.0 Hexylene Glycol 0.2 Hexyl Cinnamal 0.1 Glyceryl Linoleate 0.1 Glyceryl Oleate 0.2 Glyceryl Linolenate 0.2 Dyes q. s. Recipes 92: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 9.0 Dimethicone 3.5
202300074 Foreign Filing 56 Sodium Chloride 3.2 Coco-Betaine 3.0 Glycol Distearate 3.0 SFX 2.0 Guar Hydroxypropyltrimonium Chloride 0.3 Niacinamide 0.1 Cocamide MIPA 2.0 Saccharum Officinarum (Sugar Cane) Extract 2.0 Sodium Benzoate 1.0 Sodium Cocoate 1.5 Sodium Hydroxide 0.6 Salicylic Acid 0.5 Camellia Sinensis Extract/Camellia Sinensis Leaf Extract 0.5 Linalool 0.2 Benzyl Salicylate 0.2 Pyrus Malus (Apple) Fruit Extract 0.3 Carbomer 0.5 Pyridoxine HCl 0.3 Persea Gratissima (Avocado) Oil 0.2 Citric Acid ad pH 5.5 Butylphenyl Methylpropional 0.1 Methyl Cocoate 0.3 Hexylene Glycol 0.1 Hexyl Cinnamal 0.1 Dyes q. s. Recipes 93: Fortifying Shampoo Ingredient % Aqua ad 100 Ammonium Lauryl Sulfate 6.0 Cocamidopropyl Betaine 3.0 Sodium Chloride 2.7 SFX 2.0 Niacinamide 0.1 Saccharum Officinarum (Sugar Cane) Extract 0.9 Cocos Nucifera (Coconut) Oil 0.9 Sodium Benzoate 0.9 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.1 Sodium Hydroxide ad pH
202300074 Foreign Filing 57 Salicylic Acid 0.4 Limonene 0.1 Benzoic Acid 0.4 Linalool 0.3 Cinnamyl Alcohol 0.2 Pyrus Malus (Apple) Fruit Extract 0.5 Pyridoxine HCl 0.2 Bisabolol 0.2 Citric Acid ad pH 5.0 Citronellol 0.1 Hexylene Glycol 0.2 Dyes q. s. Recipes 94: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 9.0 Cocamidopropyl Betaine 2.5 SFX 2.5 Sodium Chloride 2.5 Camellia Sinensis Leaf Extract 2.0 Guar Hydroxypropyltrimonium Chloride 0.3 Maltodextrin 1.2 Disodium EDTA 1.0 PPG-12 0.7 Citric Acid ad pH 5.0 Sodium Hydroxide 0.3 Sodium Benzoate 0.7 Butylphenyl Methylpropional 0.2 Geraniol 0.2 Hexyl Cinnamal 0.1 Limonene 0.1 Linalool 0.1 Dyes q. s. Recipes 95: Brunette Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5
202300074 Foreign Filing 58 Cocamidopropyl Betaine 4.0 Sodium Chloride 3.5 SFX 2.0 Selaginella Lepidophylla Aerial Extract 2.0 Gluconolactone 1.8 Glycerin 1.8 Dimethiconol 1.0 Guar Hydroxypropyltrimonium Chloride 0.5 TEA-Dodecylbenzenesulfonate 1.0 Maltodextrin 1.0 Disodium EDTA 0.7 Carbomer 0.9 PPG-12 0.7 Citric Acid ad pH 5.5 Sodium Hydroxide 0.9 TEA-Sulfate 0.7 Triethanolamine 0.5 DMDM Hydantoin 0.1 Sodium Benzoate 0.7 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 alpha-Isomethyl Ionone 0.1 Butylphenyl Methylpropional 0.2 Hexyl Cinnamal 0.1 Limonene 0.1 Linalool 0.1 Dyes q. s. Recipes 96: 2 in 1 Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 PEG-200 Hydrogenated Glyceryl Palmate 3.0 SFX 3.0 Disodium Cocoamphodiacetate 3.0 Polysorbate 20 2.5 Glycerin 2.5 Sodium Chloride 2.0 PEG-7 Glyceryl Cocoate 2.0
202300074 Foreign Filing 59 Sodium Benzoate 1.0 Sodium Laureth-8 Sulfate 1.0 Sodium Oleth Sulfate 1.0 Sodium Hydroxide 0.3 PPG-5 Ceteth-20 1.0 PEG-55 Propylene Glycol Oleate 0.5 Polyquaternium-10 0.2 Salicylic Acid 0.3 Maltodextrin 0.2 Propylene Glycol 0.2 Disodium Ricinoleamido MEA-Sulfosuccinate 0.1 Citric Acid ad pH 5.5 Prunus Armeniaca (Apricot) Kernel Oil 0.1 Parfum, Dyes q. s. Recipes 97: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 9.0 Cocamidopropyl Betaine 3.0 Sodium Chloride 2.5 Glycol Distearate 2.5 Hydrolyzed Keratin 2.0 Simmondsia Chinensis (Jojoba) Seed Oil 2.0 SFX 2.0 Argania Spinosa Kernel Oil 0.5 Persea Gratissima (Avocado) Oil 0.5 Rosmarinus Officinalis (Rosemary) Leaf Extract 0.3 Helianthus Annuus (Sunflower) Seed Oil 0.3 Cocamide MEA 0.4 Guar Hydroxypropyltrimonium Chloride 0.2 Polyquaternium-47 0.2 PEG-20 Castor Oil 0.5 Phenethyl Benzoate 0.7 Disodium EDTA 0.2 Methylchloroisothiazolinone 0.3 Methylisothiazolinone 0.3 Benzyl Salicylate 0.1 Hexyl Cinnamal 0.1
202300074 Foreign Filing 60 Citronellol 0.1 Dyes q. s. Recipes 98: Foam Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 5.0 Isobutane 5.0 Decyl Glucoside 5.0 Propane 3.5 Sodium Cocoamphoacetate 3.5 SFX 3.5 Panthenol 0.2 Polyquaternium-10 0.2 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.1 Sodium PCA 0.5 Octyldodecyl PCA 0.5 Maltodextrin 0.5 Tilia Cordata Flower Extract 0.7 Sodium Chloride 0.9 Citric Acid ad pH 5.0 Glycerin 0.9 Propylene Glycol 0.3 Butane 0.7 Sodium Acetate 0.7 Sorbitol 0.5 Isopropyl Alcohol 0.5 Dyes q. s. Recipes 99: Anti-Dandruff Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 10.0 Cocamidopropyl Betaine 3.0 Acrylates Copolymer 2.5 Sodium Lauroyl Glutamate 2.5 Zinc Pyrithione 2.0 SFX 2.0
202300074 Foreign Filing 61 Stearamidopropyl Dimethylamine 1.0 Piroctone Olamine 0.7 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.2 Propylene Glycol 0.5 Sodium PCA 0.2 Citrus Medica Limonum (Lemon) Peel Extract 0.5 Citric Acid ad pH 5.0 Glycol Distearate 0.8 PPG-9 0.2 Laureth-4 0.2 Sodium Chloride 0.9 Sodium Hydroxide 0.3 Sodium Naphthalenesulfonate 0.7 Sorbitol 0.7 DMDM Hydantoin 0.1 Sodium Benzoate 0.8 Limonene 0.1 Linalool 0.1 Butylphenyl Methylpropional 0.1 alpha-Isomethyl Ionone 0.1 Parfum, Dyes q. s. Recipes 100: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 5.0 Disodium Cocoamphodiacetate 2.0 SFX 2.0 Laureth-2 0.3 Panthenol 0.2 Niacinamide 0.1 Sodium Chloride 0.7 Citric Acid ad pH 5.0 PEG-7 Glyceryl Cocoate 0.5 Sodium Benzoate 0.5 Polyquaternium-10 0.7 Salicylic Acid 0.5 Hexyl Salicylate 0.2 Benzyl Salicylate 0.1
202300074 Foreign Filing 62 Hexyl Cinnamal 0.1 Linalool 0.1 Limonene 0.1 Propylene Glycol 0.2 Dyes q. s. Recipes 101: Intensive Care Oil-Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Disodium Cocoamphodiacetate 3.0 SFX 0.5 Prunus Armeniaca (Apricot) Kernel Oil 2.5 Hydrolyzed Keratin 2.5 Panthenol 2.4 Sodium Chloride 2.2 Citric Acid ad pH 5.5 Stearamidopropyl Dimethylamine 1.2 Polyquaternium-10 0.5 Sodium Benzoate 0.5 PEG-7 Glyceryl Cocoate 0.7 Laureth-2 0.4 PEG-40 Hydrogenated Castor Oil 0.4 Propylene Glycol 0.8 PEG-55 Propylene Glycol Oleate 0.7 Hexyl Cinnamal 0.1 Butylphenyl Methylpropional 0.2 Benzyl Salicylate 0.1 Linalool 0.2 Benzyl Alcohol 0.5 Limonene 0.1 Sodium Acetate 0.2 Dyes q. s. Recipes 102: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Disodium Cocoamphodiacetate 3.5
202300074 Foreign Filing 63 Sodium Chloride 3.5 SFX 3.0 Hydrolyzed Collagen 1.0 Panthenol 0.4 Cocodimonium Hydroxypropyl Hydrolyzed Keratin 0.3 Hydrolyzed Keratin 0.3 Citric Acid ad pH 5.5 Sodium Benzoate 0.7 Polyquaternium-10 0.2 Hexyl Cinnamal 0.1 Limonene 0.1 Linalool 0.1 Benzyl Salicylate 0.1 Benzyl Alcohol 0.2 Propylene Glycol 0.2 Dyes q. s. Recipes 103: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Cocamidopropyl Betaine 3.0 SFX 3.0 PEG-7 Glyceryl Cocoate 2.5 Dimethicone 2.5 Prunus Armeniaca (Apricot) Kernel Oil 2.5 Panthenol 0.3 Cocodimonium Hydroxypropyl Hydrolyzed Keratin 0.7 Hydrolyzed Keratin 0.7 Sodium Chloride 0.8 Cocamide MEA 0.5 Glycol Distearate 0.2 Sodium Benzoate 0.7 Citric Acid ad pH 5.5 Polyquaternium-10 0.5 Laureth-4 0.4 PEG-40 Hydrogenated Castor Oil 0.2 Hydrogenated Castor Oil 0.7 Laureth-7 0.5
202300074 Foreign Filing 64 Hexyl Cinnamal 0.1 Propylene Glycol 0.8 Hexyl Salicylate 0.3 Glycerin 0.5 Linalool 0.2 Limonene 0.1 Dyes q. s. Recipes 104: Shampoo Ingredient % Aqua ad 100 Sodium Coco Sulfate 6.0 Lauryl Glucoside 4.0 Glycerin 3.5 Sodium Lactate 2.5 SFX 2.0 Stearamidopropyl Dimethylamine 1.0 Betaine 0.8 Sodium Chloride 0.9 Simmondsia Chinensis Seed Oil 0.8 Sodium Cocoyl Glutamate 0.7 Disodium Cocoyl Glutamate 0.5 Xanthan Gum 0.5 Hydrated Silica 0.5 Parfum, Dyes q. s. Recipes 105: Shampoo for Children Ingredient % Aqua ad 100 Sodium Coco Sulfate 7.0 Decyl Glucoside 5.0 Lactis Proteinum 3.5 Sorbitan Caprylate 3.0 SFX 3.0 Glycerin 2.5 Sodium Lactate 2.5 Alcohol 2.0 Hydrolyzed Wheat Protein 0.7 Hydrolyzed Wheat Starch 0.7
202300074 Foreign Filing 65 Sodium Chloride 0.9 Limonene 0.1 Citral 0.1 Phenethyl Alcohol 0.1 Dyes q. s. Recipes 106: Intensive Cream Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Cocamidopropyl Betaine 3.0 SFX 2.5 Sodium Chloride 2.5 Panthenol 0.5 Hydrolyzed Keratin 0.8 Argania Spinosa Kernel Oil 0.5 Cocamide MEA 0.5 Glycol Distearate 0.5 PEG-7 Glyceryl Cocoate 0.4 Sodium Benzoate 0.7 Citric Acid ad pH 5.0 Laureth-4 0.3 PEG-40 Hydrogenated Castor Oil 0.4 Hydrogenated Castor Oil 0.4 Styrene/Acrylates Copolymer 0.5 Dimethicone 0.8 Polyquaternium-7 0.9 PEG-12 Dimethicone 0.5 Guar Hydroxypropyltrimonium Chloride 0.3 Benzyl Salicylate 0.1 Propylene Glycol 0.8 Glycerin 0.5 Limonene 0.1 Linalool 0.1 PEG-14m 0.1 Dyes q. s. Recipes 107: Shampoo Ingredient %
202300074 Foreign Filing 66 Aqua ad 100 Sodium Laureth Sulfate 7.5 Cocamidopropyl Betaine 3.0 SFX 2.5 Sodium Chloride 2.0 Sodium Xylenesulfonate 1.7 Cocamide MEA 1.5 Sodium Citrate 1.5 Citric Acid ad pH 5.0 Dimethiconol 1.0 Cassia Hydroxypropyltrimonium Chloride 0.3 Sodium Benzoate 0.9 Disodium EDTA 0.7 Panthenol 0.7 Panthenyl Ethyl Ether 0.3 Persea Gratissima (Avocado) Oil 0.2 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 Parfum, Dyes q. s. Recipes 108: Caffeine Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 6.0 Laureth-2 4.0 Disodium Laureth Sulfosuccinate 2.5 Sodium Lauroyl Glutamate 2.5 SFX 2.0 Sodium Chloride 2.0 Caffeine 1.5 Panthenol 0.2 PEG-120 Methyl Glucose Dioleate 0.5 Hydrolysed Wheat Protein 0.7 Citric Acid ad pH 5.5 Sodium Citrate 0.5 Menthol 0.7 PEG-40 Hydrogenated Castor Oil 0.4 Potassium Sorbate 0.3 Polyquaternium-7 0.4
202300074 Foreign Filing 67 Disodium EDTA 0.5 Sodium Benzoate 0.7 Zinc PCA 0.3 Niacinamide 0.1 Limonene 0.1 Tocopherol 0.1 Phenoxyethanol 0.5 Methylparaben 0.3 Propylparaben 0.3 Dyes q. s. Recipes 109: Power Grey Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 6.5 Sodium Cocoamphoacetate 4.5 PEG-3 Distearate 3.0 Cocamidopropyl Betaine 3.0 SFX 2.5 Sodium Chloride 2.5 Caffeine 1.5 Panthenol 0.2 Phenoxyethanol 0.7 Coco Glucoside 0.9 Glyceryl Oleate 0.4 Phosphoric Acid 0.2 PEG-120 Methyl Glucose Dioleate 0.9 Menthol 0.9 Polyquaternium-7 0.7 Sodium Hydroxide 0.3 Citric Acid ad pH 5.5 Niacinamide 0.1 Zinc PCA 0.5 Limonene 0.1 Sodium Benzoate 0.2 Methylparaben 0.3 Propylparaben 0.3 Dyes q. s.
202300074 Foreign Filing 68 Recipes 110: Shampoo Ingredient % Aqua ad 100 Lauryl Glucoside 6.5 Cocamidopropyl Betaine 3.0 Coco Glucoside 2.5 SFX 2.0 Glyceryl Oleate 1.5 Sodium Cocoyl Glutamate 1.0 Panthenol 0.5 Polyquaternium-10 0.3 Chamomilla Recutita Extract 0.5 Glyceryl Caprylate 0.3 p-Anisic Acid 0.05 Citric Acid ad pH 5.0 Parfum, Dyes q. s. Recipes 111: Caffeine Shampoo Ingredient % Aqua ad 100 Sodium Coco Sulfate 6.0 Glycerin 5.5 Lauryl Glucoside 4.5 Cocamidopropyl Betaine 3.0 SFX 2.5 Lauroyl Sarcosine 2.0 Caffeine 1.0 Xanthan Gum 1.0 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.3 Alcohol 0.8 Coffea Arabica Bean Extract 0.3 Panthenyl Ethyl Ether 0.4 Panthenol 0.2 Limonene 0.1 Linalool 0.1 Dyes q. s. Recipes 112: Shampoo Ingredient %
202300074 Foreign Filing 69 Aqua ad 100 Sodium Laureth Sulfate 6.5 Cocamidopropyl Betaine 3.0 Sodium Chloride 3.0 SFX 2.0 Panthenol 0.2 Benzophenone-4 0.9 Glycol Distearate 0.7 Laureth-4 0.8 Glycerin 0.9 Formic Acid 0.2 Decyl Glucoside 0.9 Polyquaternium-10 0.4 Niacinamide 0.1 Sodium Benzoate 0.1 Potassium Sorbate 0.2 Citric Acid ad pH 5.0 Parfum, Dyes q. s. Recipes 113: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Cocamidopropyl Betaine 3.0 Sodium Chloride 2.0 Disodium Cocoamphodiacetate 2.0 SFX 2.0 Sodium Benzoate 0.7 Panthenol 0.2 Sodium Laureth-8 Sulfate 0.7 Citric Acid ad pH 5.0 Sodium Cocoyl Glutamate 0.8 Glycol Distearate 0.9 Styrene/Acrylates Copolymer 0.5 Sodium Oleth Sulfate 0.7 Coco Glucoside 0.9 Cocamide MEA 0.7 Isopropyl Alcohol 0.2 Parfum, Dyes q. s.
202300074 Foreign Filing 70 Recipes 114: Volume Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 Cocamidopropyl Betaine 3.0 Coco Glucoside 3.0 SFX 2.0 Nymphaea Coerulea Flower Extract 2.0 Hydrolyzed Rice Protein 2.0 Cocamide MEA 2.0 Polyquaternium-10 0.5 Malic Acid ad pH 5.5 Disodium EDTA 0.5 Propylene Glycol 0.5 Benzophenone-4 0.3 Ethylhexyl Methoxycinnamate 0.3 Sodium Chloride 0.9 Benzyl Alcohol 0.9 PPG-9 0.2 Methylisothiazolinone 0.1 Methylparaben 0.1 Propylparaben 0.1 Parfum, Dyes q. s. Recipes 115: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 6.5 Coco Glucoside 5.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Glycol Distearate 2.8 Dimethicone 1.7 Laureth-23 1.5 Laureth-4 1.5 Polyquaternium-7 0.5 Cocamide MEA 0.7 Cetyl Alcohol 0.4 Simmondsia Chinensis Seed Oil 0.8
202300074 Foreign Filing 71 Panthenol 0.3 Malic Acid ad pH 5.5 Glycine 0.7 Benzyl Alcohol 0.7 Disodium EDTA 0.5 Sodium Hydroxide 0.2 Guar Hydroxypropyltrimonium Chloride 0.5 Ethylhexyl Methoxycinnamate 0.7 Methylparaben 0.3 Propylparaben 0.3 PPG-9 0.2 Benzophenone-4 0.3 Sodium Chloride 0.8 DMDM Hydantoin 0.1 Hexyl Cinnamal 0.1 Limonene 0.1 Dyes q. s. Recipes 116: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 5.0 Sodium Lauryl Sulfate 5.0 Cocamidopropyl Betaine 3.0 SFX 2.5 Olea Europaea Fruit Oil 2.0 Cocamide MEA 2.0 Sodium Chloride 1.9 Glycol Distearate 1.7 Benzyl Alcohol 1.0 Polyquaternium-10 0.5 Hydroxypropyl Methylcellulose 0.5 Silicone Quaternium-18 0.9 Malic Acid ad pH 5.5 Disodium EDTA 0.5 Sodium Xylenesulfonate 0.7 Trideceth-6 0.7 Trideceth-12 0.5 DMDM Hydantoin 0.2
202300074 Foreign Filing 72 Methylparaben 0.3 Propylparaben 0.3 Linalool 0.1 Hexyl Cinnamal 0.1 Butylphenyl Methylpropional 0.1 Limonene 0.1 Dyes q. s. Recipes 117: Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 3.0 Sodium Lauryl Sulfate 3.5 Glycol Distearate 3.3 Dimethicone 3.0 Cocamidopropyl Betaine 2.5 SFX 2.0 Benzyl Alcohol 0.7 Betaine 0.4 Cetyl Alcohol 0.7 Cocamide MEA 0.7 Glyceryl Oleate 0.5 Propylene Glycol 0.6 Menthol 0.7 Guar Hydroxypropyltrimonium Chloride 0.4 Butylene Glycol 0.5 Menthyl Lactate 0.2 Disodium EDTA 0.5 Tocopheryl Acetate 0.1 Laureth-4 0.7 Niacinamide 0.1 Maltodextrin 0.2 Sodium Ascorbyl Phosphate 0.1 PPG-9 0.2 Salicylic Acid 0.7 Pyridoxine HCl 0.1 Malic Acid ad pH 5.0 Laureth-23 0.5 Silica 0.7
202300074 Foreign Filing 73 Sodium Chloride 0.7 Sodium Hydroxide 0.3 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 Parfum, Dyes q. s. Recipes 118: Shampoo Ingredient % Aqua ad 100 Cocamidopropyl Betaine 7.0 Sodium Methyl Cocoyl Taurate 4.0 SFX 1.0 Sodium Chloride 2.0 Sodium C14-16 Olefin Sulfonate 1.0 PEG-120 Methyl Glucose Dioleate 1.0 Glycol Distearate 1.0 Sodium Benzoate 1.0 Caprylyl/Capryl Glucoside 0.7 PEG-7 Glyceryl Cocoate 0.7 Citric Acid ad pH 5.3 Parfum 0.2 Polyquaternium-10 0.2 Coconut Acid 0.1 Laureth-4 0.1 Hydrogenated Castor Oil 0.1 Glycerin 0.1 Lactic Acid 0.1 Propylene Glycol 0.1 Hydrolyzed Keratin 0.1 Ceramide NP 0.05 Panthenol 0.05 Recipes 119: Conditioning Shampoo Ingredient % Aqua ad 100 Sodium Cocoamphoacetate 5.0 Cocamidopropyl Betaine 4.0 SFX 1.5 Starch Hydroxypropltrimonium chloride 1.2
202300074 Foreign Filing 74 Isostearamide MIPA; Glyceryl Laurate 1.2 Isoamyl Laurate 1.0 Bis-(Isostearoyl/Oleoyl Isopropyl) Dimonium Methosulfate 0.5 Citric Acid 3.0 Perfume, Preservative, Dyes q. s. Recipes 120: Conditioning Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 Cocamidopropyl Betaine 1.5 SFXs 1.5 Palmitamidopropyltrimonium Chloride 1.0 Polysilicone-19 1.0 PEG-18 Glyceryl Oleate/Cocoate 2.5 Citric Acid ad pH 5.5 Perfume, Preservative q. s. Recipes 121: Conditioning Shampoo Ingredient % Aqua ad 100 Sodium Cocoamphoacetate 5.0 Cocamidopropyl Betaine 3.0 Disodium Lauryl Sulfosuccinate 3.0 SFXs 1.5 Palmitamidopropyltrimonium Chloride 2.0 Isostearamide MIPA, Glyceryl Laurate 1.0 PEG-200 Hydrogenated Glyceryl Palmate; PEG-7 Glyceryl Cocoate 1.0 Methoxy PEG/PPG-7/3 Aminopropyl Dimethicone 0.5 Starch Hydroxypropltrimonium chloride 0.3 Polyquaternium-10 0.2 Citric Acid ad pH 5.5 Perfume, Preservative q. s. Recipes 122: Conditioning Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 6.0 Cocamidopropyl Betaine 3.0
202300074 Foreign Filing 75 SFX 3.0 Glycol Distearate, Laureth-4, Cocamidopropyl Betaine 2.0 PEG-120 Methyl Glucose Dioleate 1.7 SFX 1.5 Sorbitan Sesquicaprylate 1.0 Isoamyl Laurate 1.0 Sodium Chloride 1.0 Silicone-Quaternium-22 0.8 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.5 Creatine 0.5 Citric Acid ad pH 5.5 Perfume, Preservative q. s. Recipes 123: Natural Shampoo Ingredient % Aqua ad 100 Sodium Coco-Sulfate 9.0 Glycerin 5.0 Lauryl Glucoside 2.5 SFX 2.5 Sodium Lactate 1.0 Betaine 1.0 Hamamelis Virginiana Leaf Extract 1.0 Alcohol Denat. 1.0 Sodium/Disodium Cocoyl Glutamate 0.8 Maris Sal 0.5 Dipotassium Glycyrrhizate 0.5 Glycerophosphocholine 0.1 Parfum, Preservative q. s. Recipes 124: Natural Shampoo Ingredient % Aqua ad 100 Sodium Coco-sulfate 6.0 Glycerin 5.0 Coco-glucoside 4.0 Lauryl Glucoside 3.0
202300074 Foreign Filing 76 SFX 2.0 Glyceryl Oleate 1.5 Sodium Chloride 1.0 Calendula Officinalis Flower Extract 0.5 Parfum 0.5 Starch Hydroxypropyltrimonium chloride 0.3 Glyceryl Undecylenate 0.3sarch Polyglyceryl-4 Caprate 0.3 Xanthan Gum 0.3 Locust bean Gum Lysolecithin 0.2 Coco-Caprylate 0.1 Magnolia Officinalis Bark Extract 0.1 Tocopherol 0.1 Squalene 0.1 Recipes 125: Natural Shampoo Ingredient % Aqua ad 100 Sodium Lauroyl Methyl Isethionate 5.0 Disodium Cocoamphodipropionate 4.0 Acrylates Copolymer 2.0 Hydroxyethylcellulose 2.0 SFX 2.0 Cocos Nucifera Oil 0.8 Panthenol 0.4 Tocopherol 0.4 Tocopheryl Acetate 0.2 Cetyl Triethylmonium Dimethicone PEG-8 Succinate 0.2 Glycol Distearate 0.2 Laureth-4 0.2 Cocamidopropyl Betaine 0.2 Ethylhexyl Salicylate 0.1 Disodium EDTA 0.1 Ethylhexylglycerin 0.1 Glycerin 0.1 Hexylene Glycol 0.1 Sodium Coco PG-dimonium Chloride Phosphate 0.1 BHT 0.1
202300074 Foreign Filing 77 Citric Acid 0.1 Phenoxyethanol 0.1 Formic Acid 0.1 Parfum q.s. Recipes 126: Natural Shampoo Ingredient % Aqua ad 100 Moroccan Lava Clay 5.0 Behenyl Alcohol 3.0 Glycerin 2.5 Glyceryl Stearate Citrate 2.0 Lauryl Glucoside 2.0 Coco-glucoside 2.0 Helianthus Annuus Hybrid Oil 1.5 Prunus Armeniaca Kernel Oil 1.5 SFX 1.0 Argania Spinosa Kernel Oil 1.0 Magnolia Officinalis Bark Extract 1.0 Triethyl Citrate, Glyceryl Caprylate Benzoic Acid 1.0 Xanthan Gum 0.8 Sodium Lactate 0.5 Benzyl Alcohol 0.3 Lactic Acid 0.2 Parfum q.s. Recipes 127: Natural Shampoo Ingredient % Aqua ad 100 Cocamidopropyl Betaine 7.0 Cetrimonium Chloride 5.0 Decyl Glucoside 5.0 Sodium Chloride 2.0 SFX 1.0 Sorbitan Caprylate 0.8 Cocos Nucifera Oil 0.8 Inulin 0.5 Benzyl Alcohol 0.2 Cetearyl Alcohol 0.2
202300074 Foreign Filing 78 Xanthan Gum 0.2 Sodium Cocoyl Glutamate 0.1 Parfum 0.1 Glycerin 0.2 Argania Spinosa Kernel Oil 0.1 Titanium Dioxide 0.1 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.1 Lactic Acid 0.1 Hexyl Cinnamal 0.1 Sodium Hydroxide 0.1 Ascorbyl Palmitate 0.1 Tocopherol 0.1 Recipes 128: Natural Shampoo Ingredient % Aqua ad 100 Glycerin 5.0 Sodium Coco-sulfate 5.0 Lauryl Glucoside 4.0 SFX 4.0 Betaine 3.0 Maris Sal 2.0 Camellia Oleifera Leaf Extract 1.5 Pisum Sativum Peptide 1.5 Oryza Sativa Extract 1.0 Pisum Sativum Seed Extract 0.5 Disodium Cocoyl Glutamate 0.4 Sodium Cocoyl Glutamate 0.4 PCA Glyceryl Oleate 0.2 Alcohols 0.1 Parfum q.s. Recipes 129: Anti-Hair Loss Tonic Ingredient % Aqua ad 100 Alcohol Denat. 50.0 PEG-40 Hydrogenated Castor Oil 2.5 SFX 1.5 PEG-7 Glyceryl Cocoate 2.0
202300074 Foreign Filing 79 Sphinganine 0.1 Parfum, Preservative q. s. Recipes 130: Shower Oil Ingredient % Aqua ad 100 Magnesium Laureth Sulfate 6.0 PEG-7 Glyceryl Cocoate 5.0 Hydrogenated Starch Hydrolysate 3.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Decyl Glucoside 1.0 Prunus Amygdalus Dulcis (Sweet Almond) Oil 1.0 Olive Oil 0.5 PEG-7 Esters 0.2 Parfum 0.1 Polysorbate 20 0.1 Sodium Benzoate 0.2 Citric Acid 0.1 PEG-6 Caprylic/Capric Glycerides 0.1 PEG-120 Methyl Glucose Dioleate 0.1 Disodium EDTA 0.1 Recipes 131: Shower Mousse Ingredient % Aqua ad 100 Sodium Lauroyl Glutamate 15.0 Isobutane 6.0 Cocamidopropyl Betaine 4.0 Glycerin 3.0 SFX 3.0 Sodium Chloride 2.6 Sodium Lauroyl Glycinate 1.5 Propane 1.0 Butane 0.6 Citric Acid 0.4 Iodopropynyl Butylcarbamate 0.3 Lauric Acid 0.3 Parfum 0.1
202300074 Foreign Filing 80 Polysorbate 20 0.1 Sodium Benzoate 0.1 Sodium Hydroxide 0.1 Stearic Acid 0.1 Tetrasodium EDTA 0.1 Recipes 132: Shower Jelly Ingredient % Glycerin 3.5 Sodium Laureth Sulfate 3.5 SFX 3.0 Propylene Glycol 2.0 Chondrus Crispus Extract 2.0 Pyrus Malus Juice 1.0 Vitis Vinifera Juice 0.5 Parfum 0.2 Butylphenyl Methylpropional 0.1 Recipes 133: Shower Jelly Ingredient % Aqua ad 100 Glycerin 9.0 Coco-Glucoside 5.0 Decyl Glucoside 5.0 SFX 2.0 Chondrus crispus extract 1.0 Parfum 0.2 Citric Acid 0.2 Sodium Anisate 0.1 Sodium Levulinate 0.1 Recipes 134: Shower Scrub Ingredient % Aqua ad 100 Maris Sal 15.0 Sodium Laureth Sulfate 9.0 SFX 2.0 Sodium Cocoamphoacetate 1.0 Betaine 1.0
202300074 Foreign Filing 81 Citrus Limon (Lemon) Peel Powder 0.5 Lactic Acid ad pH 5.5 Parfum, Dyes q s. Recipes 135: Cellulose Scrub Ingredient % Aqua ad 100 SFX 7.0 Coco Glucoside 6.0 Glycerin 5.0 Glyceryl Stearate 5.0 Citrus Aurantium Dulcis Fruit Water 4.5 Helianthus Annuus Hybrid Oil 4.0 Cellulose 2.0 Jojoba Esters 2.0 Cetyl Alcohol 2.0 Simmondsia Chinensis (Jojoba) Seed Oil 2.0 Olea Europaea (Olive) Fruit Oil 2.0 Hydrogenated Castor Oil 0.8 Prunus Armeniaca (Apricot) Kernel Oil 0.5 Leontopodium Alpinum Extract 0.1 Xanthan Gum 0.3 Benzyl Alcohol 0.2 Parfum 0.1 Dehydroacetic Acid 0.1 Citric acid ad pH 5.0 Lactic acid 0.1 Sodium Hydroxide 0.1 Parfum, Dyes q. s. Recipes 136: Exfoliating Body Scrub Ingredient % Aqua ad 100 Coco-Glucoside 7.0 Alcohol 6.0 Glycerin 5.0 Glycine Soja Oil 5.0 Hydrated Silica 4.0 Xanthan Gum 3.0
202300074 Foreign Filing 82 SFX 3.0 Disodium/Sodium Cocoyl Glutamate 1.0 Coffea Arabica (Coffee) Seed Powder 1.0 Cocos Nucifera (Coconut) Shell Powder 1.0 Citric Acid ad pH 5.2 Glyceryl Oleate 0.5 Parfum 0.1 Preservative, Dyes q. s. Recipes 137: Dry Shampoo Ingredient % Butane, Propane 53.0 Alcohol Denat. 36.0 Aluminum Starch Octenylsuccinate 3.0 Panthenol 1.5 Tocopherol 1.0 Cocos Nucifera Oil 1.0 Curcuma Longa (Turmeric) Root Extract 0.6 Silica 0.5 Sodium Bicarbonate 0.5 Charcoal Powder 0.4 Hydrolyzed Rice Protein 0.4 Aminopropyl Phenyl Trimethicone 0.4 Benzophenone-4 0.3 Polysorbate 20 0.3 SFX 0.3 Cyclopentasiloxane 0.2 Cyclohexasiloxane 0.2 Glycerin 0.2 Aqua 0.2 Parfum q.s. Recipes 138: Dry Shampoo % Butane, Isobutane, Propane 55.0 Oryza Sativa (Rice) Starch 25.0 Alcohol denat. 18.0 Parfum 1.0 SFX 0.5
202300074 Foreign Filing 83 Distearyldimonium Chloride 0.3 Cetrimonium Chloride 0.2 Shower Recipess Recipes 139: Shower Gel Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Cocamidopropyl Betaine 3.0 Sodium Chloride 2.7 SFX 2.5 Guar Gum 0.5 Polyquaternium-7 0.5 Bisabolol 0.2 Trideceth-9 0.5 Sodium Sulfate 0.9 Tetrasodium EDTA 0.2 Citric Acid ad pH 5.5 Sodium Benzoate 0.7 Benzyl Alcohol 0.7 Benzyl Salicylate 0.1 Geraniol 0.2 Hexyl Cinnamal 0.1 Limonene 0.1 Linalool 0.1 Dyes q. s. Recipes 140: Body Wash Ingredient % Water ad 100 Sodium Laureth Sulfate 4.0 Sodium Lauryl Sulfate 4.0 Sodium Chloride 3.3 Cocamidopropyl Betaine 3.0 SFX 3.0 Sodium Benzoate 1.5 Citric Acid ad pH 5.5 Disodium EDTA 0.5
202300074 Foreign Filing 84 Zea Mays (Corn) Silk Extract 0.5 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 Potassium Sorbate 0.2 Parfum, Dyes q. s. Recipes 141: Cool Down Shower Gel Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Glycerin 2.7 Acrylates Copolymer 2.5 Sodium Chloride 2.2 Phenoxyethanol 1.5 Taurine 1.5 Benzyl Alcohol 1.0 Sodium Hydroxide 0.5 PEG-40 Hydrogenated Castor Oil 0.7 Citric Acid ad pH 5.0 Mannitol 0.7 Benzophenone-4 0.3 Ethylhexyl Salicylate 0.5 Cellulose 0.5 Linalool 0.1 Butyl Methoxydibenzoylmethane 0.2 Hydroxypropyl Methylcellulose 0.2 Dyes q. s. Recipes 142: Shower Gel Ingredient % Aqua ad 100 Cocamidopropyl Betaine 5.0 Sodium Myreth Sulfate 4.5 Sodium Laureth Sulfate 4.0 SFX 3.5 PEG-7 Glyceryl Cocoate 3.2 Glycerin 3.0
202300074 Foreign Filing 85 Glyceryl Glucoside 2.5 Bisabolol 2.0 Chamomilla Recutita (Matricaria) Flower Extract 2.2 Sodium Chloride 2.2 PEG-40 Hydrogenated Castor Oil 2.0 Citric Acid ad pH 5.0 PEG-90 Glyceryl Isostearate 1.2 PEG-200 Hydrogenated Glyceryl Palmate 1.2 Benzophenone-4 1.0 Laureth-2 0.7 Polyquaternium-7 0.5 BHT 0.2 Sodium Benzoate 0.2 Methylparaben 0.2 Benzyl Alcohol 0.2 Citronellol 0.1 Limonene 0.1 Dyes q. s. Recipes 143: Shower Gel Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Cocamidopropyl Betaine 3.0 Acrylates Copolymer 3.0 PEG-7 Glyceryl Cocoate 2.7 SFX 2.5 Helianthus Annuus Seed Oil 1.5 Glycerin 1.5 Sodium Chloride 1.0 PEG-40 Hydrogenated Castor Oil 1.0 Disodium Cocoyl Glutamate 1.0 Trisodium EDTA 1.0 Propylene Glycol 1.0 Microcrystalline Cellulose 0.9 Benzophenone-4 0.5 Sodium Sulfate 0.7 Phenoxyethanol 0.7 Acacia Gum
202300074 Foreign Filing 86 Propylparaben 0.1 Methylparaben 0.1 Benzyl Alcohol 0.2 Parfum, Dyes q. s. Recipes 144: Body Wash Ingredient % Aqua ad 100 Sodium Hydroxypropyl Starch Phosphate 6.0 Sodium Laureth Sulfate 5.5 Cocamidopropyl Betaine 3.0 SFX 3.0 Lauric Acid 2.5 Petrolatum 2.0 Sodium Cocoyl Glycinate 2.0 Glycerin 1.7 Sodium Lauroyl Isethionate 1.5 Glycine Soja (Soybean) Oil 1.0 Helianthus Annuus (Sunflower) Oil 1.0 Sodium Chloride 1.0 Stearic Acid 0.7 Guar Hydroxypropyltrimonium Chloride 0.3 DMDM Hydantoin 0.1 Tallow Acid 0.2 Palmitic Acid 0.1 Sodium Isethionate 0.2 BHT 0.1 Tetrasodium EDTA 0.2 Methylisothiazolinone 0.3 Iodopropynyl Butylcarbamate 0.1 Titanium Dioxide 0.1 Parfum, Dyes q. s. Recipes 145: Anti-Aging Body Wash Ingredient % Aqua ad 100 Petrolatum 5.0 Mineral (Paraffinum Liquidum) Oil 4.0 Sodium Trideceth Sulfate 3.5
202300074 Foreign Filing 87 Sodium Lauryl Sulfate 3.0 Sodium Lauroamphoacetate 3.0 Sodium Chloride 2.3 SFX 2.0 Trideceth-3 1.0 Simmondsia Chinensis (Jojoba) Butter 0.7 Niacinamide 0.1 Panthenol 0.3 Soluble Collagen 0.5 Citric Acid ad pH 5.5 Disodium EDTA 0.3 Guar Hydroxypropyltrimonium Chloride 0.3 Methylchloroisothiazolinone 0.1 Methylisothiazolinone 0.1 PEG-90m 0.7 Sodium Benzoate 0.3 Sodium Hydroxide 0.1 Xanthan Gum 0.5 Calcium Alginate .1 Parfum, Dyes q. s. Recipes 146: Shower Gel Ingredient % Aqua ad 100 Sodium Laureth Sulfate 9.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Glycerin 3.0 Sodium Chloride 2.8 PEG-7 Glyceryl Cocoate 2.5 PEG-40 Hydrogenated Castor Oil 2.5 Citric Acid ad pH 5.5 Sodium Benzoate 1.0 Potassium Sorbate 0.7 Alcohol 0.5 Citronellol 0.2 Benzyl Alcohol 0.7 Limonene 0.1 Linalool 0.2
202300074 Foreign Filing 88 Geraniol 0.2 Hexyl Cinnamal 0.1 Ethylhexyl Salicylate 0.1 Octocrylene 0.3 Butyl Methoxydibenzoylmethane 0.2 Dyes q. s. Recipes 147: Shower Gel Ingredient % Aqua ad 100 Alcohol 6.0 Coco Glucoside 6.0 Glycerin 3.0 SFX 3.0 Xanthan Gum 1.5 Disodium Cocoyl Glutamate 2.0 Citric Acid ad pH 5.5 Citrus Aurantifolia (Lime) Oil 0.5 Sodium Cocoyl Glutamate 0.7 Glyceryl Oleate 0.3 Sodium Lauroyl Lactylate 0.8 Limonene 0.1 Linalool 0.1 Dyes q. s. Recipes 148: Shower Gel for Men Ingredient % Aqua ad 100 Sodium Laureth Sulfate 9.5 Cocamidopropyl Betaine 3.0 Cocamide MEA 3.0 SFX 3.0 Glycerin 2.5 PPG-12 2.0 Sodium Chloride 2.0 Citric Acid ad pH 5.5 Sodium Benzoate 1.0 Phenoxyethanol 0.7 Benzyl Alcohol 0.7
202300074 Foreign Filing 89 Butylphenyl Methylpropional 0.1 Citronellol 0.1 Geraniol 0.2 Hexyl Cinnamal 0.1 Limonene 0.1 Linalool 0.1 Dyes q. s. Recipes 149: Moisturising Shower Cream Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Cocamidopropyl Betaine 3.0 Glycerin 2.5 SFX 2.0 Sodium Chloride 1.7 Cocamide MEA 1.5 Styrene/Acrylates Copolymer 1.5 Sodium Salicylate 1.0 Sodium Benzoate 1.0 Polyquaternium-7 1.0 Citric Acid ad pH 5.0 Tetrasodium EDTA 1.0 Glycol Distearate 0.9 Laureth-4 0.5 Magnolia Officinalis Flower Extract 0.2 Butyrospermum Parkii Butter Extract 0.2 Prunus Amygdalus Dulcis (Sweet Almond) Extract 0.1 Tapioca Starch polymethylsilsesquioxane 0.5 Benzyl Benzoate 0.1 Cinnamyl Alcohol 0.1 Hexyl Cinnamal 0.1 Parfum, Dyes q. s. Recipes 150: Shower Cream Aqua ad 100 Ammonium Lauryl Sulfate 6.0 Coco Glucoside 3.5
202300074 Foreign Filing 90 Cocamidopropyl Betaine 2.0 Sodium Cocoamphoacetate 2.0 SFX 1.5 Argania Spinosa Kernel Oil 1.0 Butyrospermum Parkii Butter 1.0 Glycerin 1.0 Polyquaternium-7 1.0 Styrene/Acrylates Copolymer 1.0 Gelatin Crosspolymer 0.5 Sodium Chloride 0.5 Citric Acid ad pH 5.0 Sodium Benzoate 0.3 Sodium Salicylate 0.1 Linalool 0.1 Dyes q. s. Recipes 151: Shower Cream Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 Cocamidopropyl Betaine 3.0 SFX 2.0 Sodium Chloride 1.9 Polyquaternium-7 1.5 Cocamide MEA 1.5 PEG-7 Glyceryl Cocoate 1.0 Laureth-10 1.0 Glycol Distearate 0.8 Citric Acid ad pH 5.0 Linalool 0.1 Limonene 0.1 Benzyl Salicylate 0.1 Butylphenyl Methylpropional 0.1 alpha-Isomethyl Ionone 0.1 Hexyl Cinnamal 0.1 Citronellol 0.1 Sodium Benzoate 0.7 Sodium Salicylate 0.1 Dyes q. s.
202300074 Foreign Filing 91 Recipes 152: Shower Cream Ingredient % Aqua ad 100 Glycerin 7.5 Glycine Soja Oil 3.0 Lauryl Glucoside 3.0 Sodium Coco Sulfate 3.0 SFX 2.5 Alcohol 1.5 Xanthan Gum 1.5 Butyrospermum Parkii Butter 1.2 Sodium Cetearyl Sulfate 1.0 Sodium Cocoyl Glutamate 1.0 Disodium Cocoyl Glutamate 1.0 Tocopherol 0.1 Helianthus Annuus Seed Oil 0.3 Limonene 0.1 Benzyl Salicylate 0.1 Linalool 0.1 Dyes q. s. Recipes 153: Shower Gel Ingredient % Aqua ad 100 Sodium Coco Sulfate 5.0 Glycerin 5.0 Lauryl Glucoside 4.0 Sodium Lactate 2.5 SFX 2.0 Sodium Cocoyl Glutamate 2.0 Disodium Cocoyl Glutamate 2.0 Alcohol 1.0 Prunus Cerasus Fruit Extract 1.0 Limonene 0.1 Coumarin 0.2 Linalool 0.1 Citral 0.1 Dyes q. s.
202300074 Foreign Filing 92 Recipes 154: Shower Gel Ingredient % Aqua ad 100 Alcohol 5.0 Coco-Glucoside 5.0 Glycerin 5.0 SFX 2.5 Xanthan Gum 2.5 Disodium Cocoyl Glutamate 2.0 Citric Acid ad pH 5.0 Citrus Aurantifolia (Lime) Oil 1.0 Sodium Cocoyl Glutamate 1.0 Glyceryl Oleate 1.0 Sodium Lauroyl Lactylate 0.7 Limonene 0.1 Citral 0.1 Linalool 0.1 Dyes q. s. Recipes 155: Oil Shower Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Cocamidopropyl Betaine 3.0 SFX 2.0 Acrylates Copolymer 2.0 Tocopheryl Acetate 0.5 PEG-7 Glyceryl Cocoate 0.5 Disodium EDTA 0.4 Benzophenone-4 0.3 PEG-40 Hydrogenated Castor Oil 0.7 Cellulose 0.7 Hydroxypropyl Methylcellulose 0.7 Sodium Chloride 0.9 Ethylhexylglycerin 0.2 Phenoxyethanol 0.7 Methylisothiazolinone 0.3 Sodium Benzoate 0.3
202300074 Foreign Filing 93 Sodium Hydroxide 0.3 Citric Acid ad pH 5.5 Parfum, Dyes q. s. Recipes 156: Shower Gel Ingredient % Aqua ad 100 Ammonium Lauryl Sulfate 6.0 Coco-Betaine 3.0 SFX 3.0 Lauroyl/Myristoyl Methyl Glucamide 1.5 Citric Acid ad pH 5.0 Benzyl Alcohol, Glycerin, Benzoic Acid, Sorbic Acid 1.0 Parfum 0.8 Aloe Vera Leaf Extract 0.1 Recipes 157: Showergel Ingredient % Aqua ad 100 SFX 7.0 Sesamum Indicum (Sesame) Seed Oil 4.0 Sucrose. Alcohol 2.0 Amino Acids 1.0 Glycerin 1.0 Carrageenan 0.3 Lavandula Officinalis Flower Oil 0.3 Xanthan Gum 0.3 Lactic Acid 0.1 Recipes 158: Shower Scrub Ingredient % Aqua ad 100 Maris Sal 15.0 Sodium Laureth Sulfate 9.0 SFX 2.0 Sodium Cocoamphoacetate 1.0 Betaine 1.0
202300074 Foreign Filing 94 Citrus Limon (Lemon) Peel Powder 0.5 Lactic Acid ad pH 5.5 Parfum, Dyes q s. Recipes 159: Cellulose Scrub Ingredient % Aqua ad 100 SFX 7.0 Coco Glucoside 6.0 Glycerin 5.0 Glyceryl Stearate 5.0 Citrus Aurantium Dulcis Fruit Water 4.5 Helianthus Annuus Hybrid Oil 4.0 Cellulose 2.0 Jojoba Esters 2.0 Cetyl Alcohol 2.0 Simmondsia Chinensis (Jojoba) Seed Oil 2.0 Olea Europaea (Olive) Fruit Oil 2.0 Hydrogenated Castor Oil 0.8 Prunus Armeniaca (Apricot) Kernel Oil 0.5 Leontopodium Alpinum Extract 0.1 Xanthan Gum 0.3 Benzyl Alcohol 0.2 Parfum 0.1 Dehydroacetic Acid 0.1 Citric acid ad pH 5.0 Lactic acid 0.1 Sodium Hydroxide 0.1 Parfum, Dyes q. s. Recipes 160: Exfoliating Body Scrub Ingredient % Aqua ad 100 Coco-Glucoside 7.0 Alcohol 6.0 Glycerin 5.0 Glycine Soja Oil 5.0 Hydrated Silica 4.0 Xanthan Gum 3.0
202300074 Foreign Filing 95 SFX 3.0 Disodium/Sodium Cocoyl Glutamate 1.0 Coffea Arabica (Coffee) Seed Powder 1.0 Cocos Nucifera (Coconut) Shell Powder 1.0 Citric Acid ad pH 5.2 Glyceryl Oleate 0.5 Parfum 0.1 Preservative, Dyes q. s. Recipes 161: Washing Powder Ingredient % Talc 60.0 Sodium Cocoyl Isethionate 15.0 Sodium C14-16 Olefin Sulfonate 10.0 Sodium Lauroyl Glutamate 4.0 SFX 3.0 Potassium Laurate 2.0 Sodium Myristoyl Glutamate 1.5 Chondrus Crispus 1.5 Isostearyl Alcohol 1.0 Glycerin 1.0 BHT 0.4 Butylene Glycol 0.3 Protease 0.2 Salicylic Acid 0.1 Recipes 162: Washing Powder Ingredient % Hydrates Silica ad 100 Zea Mays Starch 30.0 Sodium Cocoyl Isethionate 6.0 Amylopektin 5.0 Sodium Lauryl Sulfate 2.5 Sodium Bicarbonate 2.0 Citric Acid 1.5 Sodium Lauroyl Glutamate 1.0 Sodium Palmitate 1.0 SFX 1.0
202300074 Foreign Filing 96 Diglycerin 0.9 Sodium Lauroyl Aspartate 0.8 Titanium Dioxide 0.5 Maltodextrin 0.5 Allantoin 0.4 Aqua 0.3 Butylene Glycol 0.3 Aloe Vera Leaf Extract 0.1 Citrus Limon (Lemon) Peel Powder 0,1 Parfum, Preservatives, Dyes q. s. Recipes 163: Powder Cleanser Ingredient % Hydrated Silica ad 100 Tapioca Flour 10.0 Capryl/Capramidopropyl Betaine 5.0 Sodium Cocoamphoacetate 5.0 Helianthus Annuus (Sunflower) Seed Oil 4.0 Oleyl Erucate 2.0 Sucrose Cocoate 2.0 SFX 2.0 Coconut Acid 1.0 Citric Acid ad pH 6.0 Preservatives, parfum q. s. Recipes 164: Powder Cleanser Ingredient % Talc ad 100 Distarch Phosphate 10.0 Disodium Lauryl Sulfosuccinate 8.0 Magnesium Aluminum Silicate 5.0 Oryza Sativa Powder 5.0 Sodium Lauroyl Glutamate 2.0 SFX 2.0 Glucose 2.0 Magnesium Oxide 2.0 Maltodextrin 2.0 Titanium Dioxide 1.0 Pumice 0.5
202300074 Foreign Filing 97 Chlorella Vulgaris Powder 0.1 Soap Recipess Recipes 165: Gentle Liquid Soap Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Cocamidopropyl Betaine 3.0 SFX 2.5 PEG-7 Glyceryl Cocoate 2.5 Cocamide DEA 2.5 Glycerin 2.0 Sorbitan Sesquicaprylate 1.5 C12-15 Pareth-12 1.2 Sodium Benzoate 1.0 Potassium Sorbate 1.0 Citric Acid ad pH 5.5 PEG-200 Hydrogenated Glyceryl Palmate 1.0 Sodium Lactate 1.0 Sodium Chloride 0.7 Tetrasodium Glutamate Diacetate 0.2 Linalool 0.1 Limonene 0.1 Citronellol 0.1 Dyes q. s. Recipes 166: Soap Ingredient % Aqua ad 100 Cocamidopropyl Betaine 5.0 SFX 4.0 Glycerin 2.7 PEG-7 Glyceryl Cocoate 2.5 Simmondsia Chinensis (Jojoba) Seed Oil 2.5 Glyceryl Glucoside 2.3 Mel 2.0 Sodium Laureth Sulfate 3.0 Sodium Chloride 2.1
202300074 Foreign Filing 98 Citric Acid ad pH 5.0 PEG-40 Hydrogenated Castor Oil 1.8 PEG-120 Methyl Glucose Dioleate 1.7 Trisodium EDTA 1.0 Glycol Distearate 1.0 Polyquaternium-10 0.3 Laureth-10 0.7 Benzophenone-4 0.5 Cocamide MEA 0.8 Maltodextrin 0.5 Sodium Benzoate 0.7 Sodium Salicylate 0.6 Benzoic Acid 0.4 Linalool 0.1 Parfum, Dyes q. s. Recipes 167: Caring Liquid Soap Ingredient % Aqua ad 100 Aloe Barbadensis Leaf Juice 5.0 Ammonium Lauryl Sulfate 5.0 Coco Glucoside 4.0 Cocamidopropyl Betaine 4.0 Sodium Cocoamphoacetate 1.5 SFX 1.5 Glycerin 1.5 Sodium Chloride 1.5 Citric Acid ad pH 5.5 Sodium Benzoate 1.0 Sodium Salicylate 0.5 Methylisothiazolinone 0.3 Linalool 0.1 Butylphenyl Methylpropional 0.2 Limonene 0.1 Dyes q. s. Recipes 168: Cream Soap Ingredient % Aqua ad 100
202300074 Foreign Filing 99 Alcohol 5.0 Coco Glucoside 5.0 Glycerin 5.0 SFX 2.5 Disodium Cocoyl Glutamate 2.0 Xanthan Gum 1.5 Citric Acid ad pH 5.5 Malva Sylvestris Leaf Extract 1.0 Sodium Lauroyl Lactylate 1.0 Glyceryl Oleate 1.0 Sodium Cocoyl Glutamate 0.7 Linalool 0.1 Limonene 0.1 Dyes q. s. Recipes 169: Liquid Soap Ingredient % Aqua ad 100 Sodium Laureth Sulfate 5.0 Sodium Chloride 3.5 Cocamidopropyl Betaine 3.5 Coco Glucoside 3.0 SFX 2.0 Glyceryl Oleate 1.0 Hibiscus Sabdariffa Flower Extract 1.0 Alcohol 1.0 Sodium Lactate 1.0 Citric Acid ad pH 5.0 Sodium Benzoate 0.7 Potassium Sorbate 0.1 Parfum, Dyes q. s. Recipes 170: Liquid Soap Ingredient % Aqua ad 100 Glycerin 7.0 Alcohol 4.0 Sodium Coco Sulfate 3.0 Lauryl Glucoside 2.5
202300074 Foreign Filing 100 SFX 2.0 Xanthan Gum 1.5 Mangifera Indica (Mango) Fruit Extract 0.7 Limonene 0.1 Linalool 0.1 Dyes q. s. Recipes 171: Liquid Soap Ingredient % Aqua ad 100 Sodium Lauryl Sulfate 6.0 Cocamidopropyl Betaine 3.0 SFX 3.0 Triethylcitrate; Caprylyl Glycol; Benzoic Acid 1.0 Lactic Acid ad pH 5.0 Chamomilla Recutita Extract 0.5 Sodium Chloride 0.9 Sodium Lactate 0.7 Styrene/Acrylates Copolymer 0.5 Glycerin 0.5 Polyquaternium-7 0.3 Hexyl Cinnamal 0.1 Sorbitol 0.2 Trisodium Ethylenediamine Disuccinate 0.2 Propylene Glycol 0.3 PEG-40 Hydrogenated Castor Oil 0.9 1,2-Hexandiol 0.5 Parfum, Dyes q. s. Recipes 172: Cream Soap Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.0 Cocamidopropyl Betaine 3.0 Sodium Chloride 2.6 SFX 2.5 Polyquaternium-7 0.4 Glycerin 0.9
202300074 Foreign Filing 101 Glycol Distearate 0.7 Laureth-4 0.5 Laureth-2 0.8 PEG-55 Propylene Glycol Oleate 0.4 Propylene Glycol 0.5 Citric Acid ad pH 5.5 Hexyl Cinnamal 0.1 Benzyl Salicylate 0.1 Linalool 0.1 Limonene 0.1 Butylphenyl Methylpropional 0.1 Sodium Benzoate 0.1 Dyes q. s. Recipes 173: Jelly Soap Ingredient % Glycerin 50.0 Decyl Glucoside 5.0 SFX 2.5 Chondrus Crispus Powder 2.0 Methylpropanediol 1.0 Caprylyl Glycol 1.0 Phenylpropanol 0.5 Parfum 0.2 Helianthus Annuus (Sunflower) Seed Oil 0.2 Hydrogenated Coconut Oil 0.2 Olea Europea (Olive) Fruti Oil 0.2 Oryza Sativa (Rice) Bran Oil 0.2 Vitis Vinifera (Grape) Seed Oil 0.1 Prunus Amygdalus Dulcis (Sweet Almond) Oil 0.1 Aqua ad 100 Sodium Benzoate 0.1 Citric Acid 0.1 Recipes 174: Soap Ingredient % Talc 65.0 SFX 10.0 Corn (Zea Mays) Flour 9.0
202300074 Foreign Filing 102 Glycerin 7.0 Sodium Laureth Sulfate 4.5 Citrus Aurantium Bergamia Fruit Oil 3.5 Benzyl Benzoate 0.5 Butylphenyl Methylpropional 0.2 Parfum 0.2 Recipes 175: Soap Ingredient % Aqua ad 100 SFX 6.0 Propylene Glycol 5.0 Helianthus Annuus Seed Oil 4.0 Cocos Nucifera Oil 4.0 Titanium Dioxide 0.2 Sodium Hydroxide 0.2 Sodium Coco-sulfate 0.2 Parfum 0.1 Sodium Chloride 0.1 L-limonene 0.1 Recipes 176: Painting Soap Ingredient % Aqua ad 100 Mica 7.0 Glycine Soja Oil 5.0 Glycerin 4.0 Alcohol 3.0 Cocamidopropyl Betaine 3.0 SFX 2.0 Cetearyl Alcohol 1.5 Myristyl Alcohol 1.0 Glyceryl Stearate Citrate 1.0 Parfum 0.4 Xanthan Gum 0.3 Helianthus Annuus Seed Oil 0.2 Simmondsia Chinensis Seed Oil 0.2
202300074 Foreign Filing 103 Rubus Idaeus Fruit Extract 0.2 Tocopherol 0.1 Recipes 177: Painting Soap Ingredient % Aqua ad 100 Glycerin 10.0 Zea Starch 9.0 Lauryl Glucoside 4.0 Methylpropanediol 3.0 Stearyl Alcohol 3.0 Cocamidopropyl Betaine 2.0 SFX 2.0 Glycine Soja Oil 1.0 Tocopherol 0.5 Coco-Glucoside 0.4 Panthenol 0.2 Glycerin Oleate 0.2 Caprylyl Glycol 0.2 Phenlypropanol 0.2 Sodium Hydroxide 0.1 Sodium Chloride 0.1 Xanthan Gum 0.1 Citric Acid 0.1 Parfum 0.1 Beta Carotene 0.1 Dyes q. s. Bath Recipes Recipes 178: Bath Ingredient % Aqua ad 100 PEG-80 Sorbitan Laurate 4.0 Cocamidopropyl Betaine 4.0 Sodium Laureth Sulfate 4.0 SFX 2.0 Polysorbate 20 2.0
202300074 Foreign Filing 104 Sodium Chloride 1.5 Citric Acid ad pH 5.0 Sodium Lauroamphoacetate 1.0 PEG-150 Distearate 1.0 Disodium Lauroamphodiacetate 1.0 Sodium Benzoate 0.5 Parfum, Dyes q. s. Recipes 179: Creme Oil Bath Ingredient % Aqua ad 100 Sodium Laureth Sulfate 5.0 Cocamidopropyl Betaine 3.0 Decyl Glucoside 2.8 SFX 2.5 Glycerin 2.5 Glyceryl Glucoside 2.0 Diamond Powder 2.0 Helianthus Annuus (Sunflower) Seed Oil 1.7 Sodium Chloride 1.5 Glycol Distearate 1.5 PEG-40 Hydrogenated Castor Oil 1.5 Citric Acid ad pH 5.5 PEG-90 Glyceryl Isostearate 1.2 Laureth-4 1.0 PEG-200 Hydrogenated Glyceryl Palmate 1.0 PEG-7 Glyceryl Cocoate 1.0 Benzophenone-4 0.9 Laureth-2 0.7 Sodium Benzoate 0.7 Butylphenyl Methylpropional 0.1 Linalool 0.1 Limonene 0.1 alpha-Isomethyl Ionone 0.1 Dyes q. s. Recipes 180: Relaxing Good Sleep Bath Ingredient % Aqua ad 100
202300074 Foreign Filing 105 Cocamidopropyl Betaine 3.0 Coco Glucoside 2.5 Sodium Chloride 2.5 Disodium Lauryl Sulfosuccinate 2.0 SFX 2.0 Glycerin 1.7 Sodium PCA 0.5 Glyceryl Oleate 0.4 Sodium Hydroxide 0.3 Citric Acid ad pH 5.5 Linalool 0.1 Limonene 0.1 Geraniol 0.1 Dyes q. s. Recipes 181: Pampering Oil Bath Ingredient % Aqua ad 100 Glycine Soja Oil 20.0 SFX 5.0 Polyglyceryl-3 Palmitate 4.5 Glyceryl Caprylate 1.5 Simmondsia Chinensis Oil 1.5 Prunus Amygdalus Dulcis (Sweet Almond) Oil 1.0 Triticum Vulgare Germ Oil 1.0 Tocopherol 0.2 Limonene 0.1 Linalool 0.1 p-Anisic Acid 0.1 Dyes q. s. Recipes 182: Aroma Bath Ingredient % Aqua ad 100 Alcohol 5.0 Coco Glucoside 5.0 Sodium Coco Sulfate 4.0 SFX 2.5 Xanthan Gum 1.9
202300074 Foreign Filing 106 Glycerin 1.8 Sodium Cocoyl Glutamate 1.5 Disodium Cocoyl Glutamate 1.5 Melissa Officinalis Extract 1.0 Lavandula Angustifolia Oil 1.0 Linalool 0.1 Limonene 0.1 Geraniol 0.1 Dyes q. s. Recipes 183: Bath Bomb Ingredient % Sodium Bicarbonate 70.0 Citric Acid 8.0 Citrus Nobilis Oil 6.0 Potassium Tartrate 6.0 Sodium Laureth Sulfate 4.0 SFX 4.0 Betaine 1.5 Parfum 0.5 Dyes q. s. Recipes 184: Bath Bomb Ingredient % Sodium Bicarbonate 67.0 Citric Acid 9.0 Zea Mays Starch 8.0 Butyrospermum Parkii Butter 5.0 Sodium Lauryl Sulfoacetate 4.0 SFX 4.0 Theobroma Cacao Seed Butter 2.0 Theobroma Cacao (Cocoa) Fruit Powder 1.0 Parfum, Dyes q.s. Recipes 185: Bath Salt Ingredient % Maris Sal ad 100 Parfum 2.0
202300074 Foreign Filing 107 SFX 1.0 Silica 0.5 Simmondsia Chinensis Seed Oil 0.1 Preservative, Dyes q. s. Recipes 186: Bath Salt Ingredient % Maris Sal ad 100 Rosmarinus Officinalis Leaf Oil 3.0 Parfum 1.5 Polysorbate 20 1.5 SFX 1.5 Preservative, Dyes q. s. x-in-1 Recipess Recipes 187: Shower Gel and Shampoo Ingredient % Aqua ad 100 Coco Glucoside 5.0 Sodium Coco Sulfate 3.0 Cocamidopropyl Hydroxysultaine 2.5 SFX 2.0 Lauryl Glucoside 2.0 Glyceryl Oleate 1.8 Inulin 1.5 Lecithin 1.5 Polyquaternium-39 1.5 Citric Acid ad pH 5.0 Styrene/Acrylates Copolymer 1.0 Sodium Chloride 1.0 Denatonium Benzoate 0.5 Hydrogenated Palm Glycerides Citrate 0.7 Tocopherol 0.3 Sodium Benzoate 0.7 Phenoxyethanol 0.3 Parfum, Dyes q. s. Recipes 188: Shower, Shampoo and Shave
202300074 Foreign Filing 108 Ingredient % Aqua ad 100 Cocamidopropyl Betaine 5.0 Sodium Laureth Sulfate 4.0 PEG-7 Glyceryl Cocoate 4.0 Sodium Chloride 3.5 SFX 2.0 PEG-3 Distearate 3.0 Glycerin 2.5 Glyceryl Glucoside 1.2 Helianthus Annuus (Sunflower) Seed Oil 1.0 Persea Gratissima (Avocado) Oil 1.0 Polyquaternium-7 1.0 PEG-90m 1.0 PEG-40 Hydrogenated Castor Oil 1.0 Citric Acid ad pH 5.0 Benzophenone-4 0.5 PEG-200 Hydrogenated Glyceryl Palmate 0.5 Silica 0.7 Sodium Benzoate 0.6 Methylparaben 0.4 Propylparaben 0.4 Limonene 0.1 Butylphenyl Methylpropional 0.1 Benzyl Alcohol 0.1 Dyes q. s. Recipes 189: 2-in-1 Body Wash and Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 8.5 Glycerin 2.5 Sodium Cocoyl Isethionate 2.5 Ammonium Lauryl Sulfate 2.5 Lauryl Betaine 2.5 Lauryl Glucoside 1.5 Sodium Chloride 1.0 SFX 1.0 Polyquaternium-39 0.5
202300074 Foreign Filing 109 Polyquaternium-7 0.5 Panthenol 0.1 Citric Acid ad pH 5.5 Sodium Citrate 0.2 Propylene Glycol 0.3 PEG-55 Propylene Glycol Oleate 0.7 Styrene/Acrylates Copolymer 0.2 Phenoxyethanol 0.7 Sodium Benzoate 0.3 Tetrasodium EDTA 0.1 Parfum, Dyes q. s. Recipes 190: 2-in-1 Bubble Bath and Wash Ingredient % Aqua ad 100 Cocamidopropyl Betaine 4.0 Glycerin 4.0 Sodium Lauroamphodiacetate 2.0 Sodium Chloride 2.0 Coco Glucoside 1.5 Hydroxypropyl Starch Phosphate 1.0 Disodium Lauroamphodiacetate 1.0 SFX 1.0 Lauric Acid 1.0 Acrylates/C10-30 Alkyl Acrylate Crosspolymer 1.0 Polyquaternium-7 1.0 Styrene/Acrylates Copolymer 0.5 Citric Acid ad pH 5.5 Sodium Hydroxide 0.3 Sodium Benzoate 0.2 Benzoic Acid 0.1 Parfum, Dyes q. s. Recipes 191: Body and Face Wash Ingredient % Aqua ad 100 Sodium Laureth Sulfate 4.5
202300074 Foreign Filing 110 Petrolatum 3.0 Acrylates Copolymer 2.5 Cocamide MEA 2.5 SFX 2.0 PPG-9 2.0 Guar hydroxypropyltrimonium chloride 0.2 Menthol 0.2 DMDM Hydantoin 0.1 Tetrasodium EDTA 0.2 Methylisothiazolinone 0.1 BHT 0.1 Parfum, Dyes q. s. Recipes 192: Hair and Body Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 10.0 Sodium Chloride 4.0 Glycerin 3.5 Coco-Betaine 2.0 SFX 2.0 Niacinamide 0.1 Saccharum Officinarum (Sugar Cane) Extract 1.0 Sodium Benzoate 1.0 Sodium Hydroxide 0.3 PPG-5-Ceteth-20 1.0 Polyquaternium-10 0.7 Salicylic Acid 0.5 Limonene 0.1 Linalool 0.2 Benzyl Salicylate 0.1 Pyrus Malus (Apple Fruit) Extract 0.3 Pyridoxine HCl 0.2 Citric Acid ad pH 5.0 Taurine 0.1 Dyes q. s.
202300074 Foreign Filing 111 Recipes 193: After-Sun Hair and Body Shampoo Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 Cocamidopropyl Betaine 5.0 PEG-18 Glyceryl Oleate/Cocoate 2.5 SFX 2.0 Glycol Distearate 2.0 Coco Glucoside 2.0 Laureth-4 1.5 Sodium Chloride 0.9 Panthenol 0.1 Sodium PCA 0.7 Polyquaternium-10 0.3 Octyldodecyl PCA 0.2 Glycerin 0.9 PPG-9 0.7 Citric Acid ad pH 5.5 Tetrasodium EDTA 0.3 Quaternium-80 0.2 Propylene Glycol 0.3 Isopropyl Alcohol 0.3 Sodium Benzoate 0.7 Limonene 0.1 Linalool 0.1 Benzyl Salicylate 0.1 Butylphenyl Methylpropional 0.1 Ceramide NP 0.05 Dyes q. s. Recipes 194: Hair and Body Shampoo & Shower Gel Ingredient % Aqua ad 100 Sodium Laureth Sulfate 7.0 Sodium Chloride 3.8 Cocamidopropyl Betaine 3.5 SFX 3.0 Panthenol 0.3 Hydrolyzed Keratin 0.7
202300074 Foreign Filing 112 Taurine 0.5 Simmondsia Chinensis Seed Oil 0.5 Disodium Cocoamphodiacetate 0.5 Citric Acid ad pH 5.0 Sodium Benzoate 0.7 Cocamide MEA 0.4 PEG-7 Glyceryl Cocoate 0.3 Polyquaternium-10 0.2 Propylene Glycol 0.3 PEG-40 Hydrogenated Castor Oil 0.4 Linalool 0.2 Geraniol 0.1 Butylphenyl Methylpropional 0.1 Dyes q. s. Facial cleansing Recipes Recipes 195: Eye Make-Up Remover Ingredient % Aqua ad 100 Butylene Glycol 6.0 Propanediol 2.0 Decyl Glucoside 1.0 SFX 1.0 Glycerin 1.0 Aloe Barbadensis Leaf Extract 0.5 Citric Acid ad pH 7 Bioflavonoids 0.1 Pantolactone 0.1 Recipes 196: Eye Make-Up Remover Ingredient % Aqua ad 100 Cyclopentasiloxane 8.0 Glycerin 6.0 Isohexadecane 6.0 Butylene Glycol 4.0 Panthenol 3.0
202300074 Foreign Filing 113 SFX 3.0 Sodium Chloride 2.0 Disodium EDTA 1.0 Sodium Hydroxide 0.2 Citric Acid ad pH 7 Phenoxyethanol 0.2 Methylparaben 0.1 Recipes 197: Micellar Lotion Ingredient % Aqua ad 100 Poloxamer 124 2.0 SFX 2.0 Glyceryl Glucoside 1.5 Glycerin 1.0 Polyglyceryl-10 Laurate 1.0 1,2-Hexandiol 1.0 Decyl Glucoside 0.5 Arginine HCl 0.3 Sodium Cocoamphoacetate 0.5 Trisodium EDTA 0.2 Citric Acid ad pH 6.5 Phenoxyethanol 0.1 Sodium Hyaluronate 0.05 Recipes 198: Waterproof Eye Make-Up Removal Ingredient % Aqua ad 100 Aloe Barbadensis Leaf Juice 5.0 Sorbitol 3.0 Glycerin 3.0 Panthenol 2.2 Sodium Lauryl Glucose Carboxylate 2.0 Biosaccharide Gum-1 1.5 Lauryl Glucoside 1.0 SFX 0.5 Allantoin 0.2 Phenoxyethanol 0.2 Sodium Benzoate 0.2
202300074 Foreign Filing 114 Sorbic Acid q.s. Citric Acid ad pH 6 Recipes 199: Waterproof Eye Make-Up Removal Ingredient % Aqua ad 100 Isododecane 6.0 Isopropyl Palmitate 4.0 Dimethicone 3.0 Sodium Ascorbyl Phosphate 2.0 Sodium Chloride 2.0 SFX 1.5 Caprylyl/Capryl Glucoside 1.5 Trisodium EDTA 1.0 Citric Acid ad pH 7 Sodium Hydroxide 0.2 Phenoxyethanol 0.2 Benzethonium Chloride 0.2 Recipes 200: Micellar Gel Ingredient % Aqua ad 100 Propanediol 5.0 SFX 3.0 Glycerin, Aqua, Sodium Levulinate, Sodium Anisate 3.0 Polyglyceryl-4 Caprate 2.0 Xanthan Gum 1.5 Lactobacillus Ferment 0.05 Lactic Acid ad pH 5.5 Recipes 201: Micellar Gel Ingredient % Aqua ad 100 Propylene Glycol 4.0 Glycerin 4.0 Poloxamer 124 2.5 SFX 2.5 1,2-Hexandiol 2.0 Pentylene Glycol 1.0
202300074 Foreign Filing 115 Acrylates/C10-30 Alkyl Acrylate Crosspolymer 0.5 Sodium Hyaluronate 0.2 Trisodium EDTA 0.1 Sodium Hydroxide ad pH 6 Cetrimonium Chloride 0.1 Phenoxyethanol 0.1 Recipes 202: Micellar Make-Up Remover Ingredient % Aqua ad 100 Aloe Barbadensis Leaf Juice 4.0 Caprylyl/Capryl Glucoside 2.0 SFX 1.5 Betaine 1.0 Glycerin 1.0 Benzyl Alcohol, Caprylyl Glycol, Benzoic Acid 1.0 Decyl Glucoside 0.5 Parfum q. s. Citric Acid ad pH 7.0 Recipes 203: Facial Cleansing Foam Ingredient % Aqua ad 100 Glycine Soja Oil 5.0 Coco-Glucoside 4.0 Glycerin 3.5 SFX 3.0 Alcohol Denat. 2.0 Sodium Coco-Sulfate 1.5 Sodium/Disodium Cocoyl Glutamate 1.0 Glyceryl Oleate 0.5 Hamamelis Virginiana Leaf Extract 0.5 Tocopherol 0.1 Helianthus Annuus Seed Oil 0.1 Lactic Acid ad pH 6.5 Preservative q. s. Recipes 204: Facial cleansing Foam
202300074 Foreign Filing 116 Ingredient % Aqua ad 100 Sodium/Disodium Cocoyl Glutamate 4.0 SFX 4.0 Sodium Lauryl Sulfate 3.0 Parfum 1.0 Benzyl Alcohol, Caprylyl Glycol, Benzoic Acid 1.0 Glycerin 0.8 Sodium Lauryl Glucose Carboxylate 0.7 Sodium Cottonseedamphoacetate 0.7 Lauryl Glucoside 0.5 Citric Acid ad pH 7.0 Capryloyl Glycine 0.2 Sodium Hydroxide 0.2 1,2-Hexandiol 0.2 Allantoin 0.1 Hydroxypropyl Guar Hydroxypropyltrimonium Chloride 0.1 Tetrasodium EDTA 0.1 Dehydroacetic Acid 0.1 Sorbic Acid 0.1 Tropolone 0.1 Recipes 205: Cleansing Foam Ingredient % Aqua ad 100 Coco-Glucoside 2.0 Glycerin 1.5 Sodium Coco-Sulfate 1.5 Glyceryl Oleate 1.0 Decyl Glucoside 0.5 Sodium Benzoate 0.5 Citric Acid ad pH 5.0 Panthenol 0.4 SFX 0.2 Albumen 0.1 Potassium Sorbate 0.1 Tocopherol 0.1 Hydrogenated Palm Glycerides Citrate 0.1
202300074 Foreign Filing 117 Recipes 206: Cleansing Foam Ingredient % Aqua ad 100 Aloe Barbadensis Leaf Juice 28.0 Glycerin 7.0 Decyl Glucoside 5.0 Ammonium Lauryl Sulfate 2.0 Benzyl Alcohol, Caprylyl Glocol, Benzoic Acid 2.0 Parfum 0.8 SFX 0.1 Phytic Acid 0.1 Sodium Hydroxide ad pH 7.0 Gluconolactone 0.1 Recipes 207: Cleansing Foam Ingredient % Aqua ad 100 Glycerin 3.0 Decyl Glucoside 3.0 Pentylene Glycol 2.0 SFX 1.0 Citric Acid ad pH 6.0 Papain 0.1 Recipes 208: Pump Foam for Facial Cleansing Ingredient % Aqua ad 100 Sorbitol 9.0 Glycerin 5.0 Decyl Glucoside 4.0 Disodium Cocoyl Glutamate 4.0 Glyceryl Glucoside 2.0 SFX 2.0 Propylene Glycol 2.0 Prunus Amygdalus Dulcis Oil 2.0 PEG-40 Hydrogenated Castor Oil 1.5
202300074 Foreign Filing 118 Sodium Sulfate 0.5 Citric Acid ad pH Polyquaternium-10 0.5 Sodium Benzoate 0.2 Aminopeptidase 0.1 Panthenol 0.1 Recipes 209: Pump Foam for Facial Cleansing Ingredient % Aqua ad 100 Sucrose 12.0 Glycerin 6.0 Rosa Damascena Flower Water 5.0 Coco-Glucoside 4.5 SFX 2.5 Aqua, Sodium Levulinate, Potassium Sorbate 2.0 Sodium Cocoyl Glutamate 3.0 Polyglyceryl-4 Caprate 3.0 Betaine 1.0 Citric Acid ad pH 5.0 Parfum 0.8 Sodium Chloride 0.5 Recipes 210: Micellar Water Ingredient % Aqua ad 100 PEG-6 Caprylic/capric Glycerides 3.0 Polysorbate 20 2.0 SFX 0.8 Butylene Glycol 0.5 PEG-8 0.4 Poloxamer 407 0.4 Disodium EDTA 0.3 Citric Acid ad pH 6.5 BHT 0.2 Sodium Benzoate 0.2 Recipes 211: Refreshing Micellar Water Ingredient %
202300074 Foreign Filing 119 Aqua ad 100 Methylpropanediol 3.0 Propylene Glycol 2.5 Glycerin 2.5 Sodium Cocoamphoacetate 2.0 Parfum 0.8 SFX 0.5 Sodium Salicylate 0.5 Sodium Benzoate 0.5 Citric Acid ad pH Sodium Chloride 0.2 Tetrasodium EDTA 0.1 Recipes 212: Oil-infused Micellar Water Ingredient % Aqua ad 100 Isododecane 7.5 Dimethicone 7.5 Dicaprylyl Ether 5.0 Hexylene Glycol 1.4 Propanediol 1.0 SFX 1.0 Sodium Chloride 1.0 Trisiloxane 0.8 Alcohol Denat. 0.8 Glycerin 0.8 Propylene Glycol Dicaprylate/Dicaprate 0.8 Disodium EDTA 0.5 Hydroxyethylcellulose 0.5 Phenoxyethanol, Benzoic Acid 0.5 Decyl Glucoside 0.5 Caprylyl Glycol 0.5 Sodium Citrate 0.3 Citric Acid ad pH 6 Panthenol 0.2 Benzophenone-3 0.1 Tocopheryl Acetate 0.1 Tocopherol 0.1 Zea Mays Oil 0.1
202300074 Foreign Filing 120 Chlorphenesin 0.1 Recipes 213: Facial Tonic Ingredient % Aqua ad 100 Glycerin. 2.5 Propanediol 2.0 Arginine 1.0 SFX 1.0 Salicylic Acid 1.0 Coco-Betaine 1.0 Caprylyl/Capryl Glucoside 0.8 Disodium Cocoyl Glutamate 0.8 Xanthan Gum 0.5 Phytic Acid 0.5 Sodium Chloride 0.5 Sodium Cocoyl Glutamate 0.4 Citric Acid ad pH 5.5 Recipes 214: Facial Tonic Ingredient % Aqua ad 100 Glycerin 5.0 Caprylyl/Capryl Glucoside 2.0 SFX 1.5 Glyceryl Caprylate 1.5 Parfum 1.0 Sodium Levulinate 1.0 Sodium Anisate 1.0 Sodium Salicylate 1.0 Sodium Cocoyl Glutamate 0.1 Polyglyceryl-6 Oleate 0.1 Disodium Cocoyl Glutamate 0.1 Citric Acid ad pH 5.5 Sodium Surfactin 0.05 Recipes 215: Facial Tonic Ingredient % Aqua ad 100
202300074 Foreign Filing 121 PEG-6 Caprylic/Capric Glycerides 4.0 SFX 3.0 Fructooligosaccharides 1.0 Mannitol 1.0 Xylitol 1.0 Propylene Glycol 1.0 Cetrimonium Bromide 1.0 Disodium EDTA 0.4 Rhamnose 0.1 Recipes 216: Micellar Water Ingredient % Aqua ad 100 Glycerin 5.0 Polyglyceryl-4 Caprate 5.0 Betaine 3.0 SFX 2.0 Sodium Levulinate 2.0 Lactobacillus Ferment 0.2 Sodium Benzoate 0.2 Sodium Hydroxide 0.2 Parfum 0.1 Lactic Acid ad pH 5.8 Recipes 217: Micellar Water Ingredient % Aqua ad 100 Glycerin 6.0 Poloxamer 184 2.5 Phenoxyethanol 1.0 PEG-40 Hydrogenated Castor Oil 1.0 Lactobacillus Extract, Propylene Glycol 0.8 SFX 0.5 Parfum 0.5 Citric Acid ad pH 6.4 Sodium Hydroxide 0.2 Disodium EDTA 0.1 Recipes 218: Micellar Water
202300074 Foreign Filing 122 Ingredient % Aqua ad 100 SFX 5.0 PEG-40 Hydrogenated Castor Oil 2.5 Glycerin 2.5 Prunus Amygdalus Dulcis Oil 1.0 Sorbitol 1.0 Decyl Glucoside 1.0 1,2-Hexandiol 0.1 Glyceryl Glucoside 0.5 Poloxamer 124 0.5 Propylene Glycol 0.5 Disodium Cocoyl Glutamate 0.5 Sodium Chloride 0.2 Trisodium EDTA 0.2 Polyquaternium-10 0.2 Citric Acid ad pH 6.2 Sodium Acetate 0.1 Phenoxyethanol 0.1 Recipes 219: Micellar Water Ingredient % Aqua ad 100 SFX 5.0 Glycerin 4.0 Coco-Glucoside 2.0 Polysorbate 80 0.2 Calendula Officinalis Flower Extract 2.0 Caprylyl Glycol 1.5 Citric Acid ad pH Sodium Benzoate 0.9 Parfum 0.6 Isoleucine 0.2 Panthenol 0.2 PPG-1-PEG-9 Lauryl Glycol Ether 0.2 Propylene Glycol 0.2 Phytosphingosine 0.1 Sodium Chloride 0.2
202300074 Foreign Filing 123 Recipes 220: Micellar Water Ingredient % Aqua ad 100 Hexylene Glycol 1.4 Glycerin 1.2 SFX 1.0 Poloxamer 184 1.0 Disodium Cocoamphodiacetate 1.0 Disodium EDTA 0.5 Polyaminopropyl Biguanide 0.2 Lactic Acid ad pH 5.4 Recipes 221: Micellar Water Ingredient % Aqua ad 100 Glycerin 5.0 Alcohol Denat. 2.0 Sodium Lactate 2.0 Sodium PCA 1.0 SFX 0.5 Parfum 0.3 Aloe Barbadensis Leaf Juice 0.3 Cocoyl Glutamic Acid 0.2 Sodium Cocoyl Glutamate 0.2 Glycolipids 0.1 Citric Acid 0.1 Lactic Acid 0.1 Sodium Hyaluronate 0.1 Phytosphingosine HCl 0.1 Benzyl Alcohol 0.1 Recipes 222: Face Cleanser and Scrub Ingredient % Aqua ad 100 Sodium Coco-Sulfate 4.0 SFX 2.0 Glycerin 2.0 Sodium Cocoyl Glycinate 1.5 Silica 1.5
202300074 Foreign Filing 124 Acrylates Copolymer 0.8 PEG-7 Glyceryl Cocoate 0.7 Sodium Chloride 0.5 Polysorbate 20 0.5 Cocamidopropyl Betaine 0.5 Panthenol 0.2 Parfum 0.2 Charcoal Powder 0.2 Salix Alba (Willow) Bark Extract 0.2 Glycol Distearate 0.1 Lecithin 0.1 Laureth-4 0.1 Citric Acid ad pH 5.6 Lactic Acid 0.1 Tocopherol 0.1 Ascorbyl Palmitate 0.1 Disodium EDTA 0.1 Phenoxyethanol 0.1 Ethylhexylglycerin 0.1 Sodium Benzoate 0.1 Benzyl Alcohol 0.1 Potassium Sorbate 0.1 Microemulsion Recipess Recipes 223: Microemulsion for Make-Up Removal Ingredient % Water ad 100 1,3-Butanediol 15.0 Polyglyceryl-4 Caprate 6.0 Polyglyceryl-3 Caprate 6.0 SFX 6.0 Glycerin 6.0 Isohexadecane 3.0 Sodium Benzoate 0.8 Citric Acid ad pH 5.0 Recipes 224: Microemulsion for Make-Up Removal
202300074 Foreign Filing 125 Ingredient % Water ad 100 1,3-Butanediol 7.5 Polyglyceryl-4 Caprate 5.5 Glycolipids 3.0 SFX 1.5 Glycerin 5.0 Sodium Benzoate 0.8 Citric Acid Ad pH 5.0 Toothpaste Recipess Recipes 225: Toothpaste Ingredient % Aqua ad 100 Glycerin 29.0 Sodium Metaphosphate 12.0 Hydrated Silica (Hydrated) 10.0 Xylitol 10.0 SFX 1.0 Olaflur 0.13 Cocamidopropyl Betaine 0.5 Propylene Glycol 1.0 Chamomilla Recutita Flower Extract 0.4 Alcohol Denat 0.5 Panthenol 0.1 Sodium Fluoride 0.1 Hydroxyethylcellulose 1.0 Titanium Dioxide 0.4 Aroma 1.0 Citronellol 0.0 Eucalyptol 0.2 Eugenol 0.1 Menthol 0.15 Dyes, pH adjuster, preservative q. s. Recipes 226: Toothpaste Ingredient % Aqua ad 100
202300074 Foreign Filing 126 Hydrated Silica (Hydrated) 22.0 Sorbitol 30.0 Hydroxyethylcellulose 1.5 SFX 1.0 Olaflur 0.19 Aroma 1.0 Limonene 0.1 Titanium Dioxide 0.3 Saccharin 0.2 Dyes, pH adjuster, preservative q. s. Recipes 227: Toothpaste Ingredient % Sorbitol 45.0 Aqua ad 100 Hydrated Silica (Hydrated) 18.0 Sodium Lauryl Sulfate 1.05 SFX 0.75 PEG-32 1.0 Flavor 1.0 Cellulose Gum 0.8 Cocamidopropyl Betaine 0.35 Sodium Saccharin 0.2 Sodium Fluoride 0.23 Zinc Sulfate 0.3 Mica 0.5 Dyes solution (1% FD&C Blue No.1) 0.02 Titanium Dioxide 0.3 Eugenol 0.2 pH adjuster, preservative q. s. Recipes 228: Toothpaste Ingredient % Glycerin 35.0 Hydrated Silica (Hydrated) 22.0 Aqua ad 100 Sodium Bicarbonate 20.0 PEG-12 3.0 SFX 1.5
202300074 Foreign Filing 127 Sodium Lauryl Sulfate 1.0 Flavor 1.0 Sodium Hydroxide 0.9 Cellulose Gum 0.9 Chondrus Crispus 0.5 Sodium Saccharin 0.1 Calcium Peroxide 0.1 Titanium Dioxide 0.4 Sodium monofluorophosphate 0.76 PH adjuster, preservative q. s. Recipes 229: Toothpaste Ingredient % Aqua ad 100 Glycerin 33.0 Hydrated Silica (Hydrated) 24.0 SFX 1.5 Cellulose Gum 0.8 Aroma 0.9 Sodium Fluoride 0.23 Sodium Saccharin 0.2 Commiphora Myrrha Oil 0.05 Salvia Officinalis Oil 0.05 Mentha Piperita Oil 0.2 Chamomilla Recutita Flower Extract 0.2 Limonene 0.1 Titanium Dioxide 0.3 Dyes solution (1% FD&C Blue No.1) 0.05 pH adjuster, preservative q. s. Recipes 230: Toothpaste Ingredient % Glycerin 27.0 Hydrated Silica (Hydrated) 21.0 Sodium Hexametaphosphate 13.0 Aqua ad 100 PEG-6 5.0 Flavor 1.0 Trisodium Phosphate 1.0
202300074 Foreign Filing 128 Sodium Lauryl Sulfate 1.05 SFX 0.35 Chondrus Crispus 0.7 Cocamidopropyl Betaine 0.1 Sodium Saccharin 0.2 Polyethylene Glycol 0.5 Xanthan Gum 0.7 Sucralose 0.5 Mica 0.3 Titanium Dioxide 0.5 Sodium Fluoride 0.32 Dyes, pH adjuster, preservative q. s. Recipes 231: Toothpaste Ingredient % Aqua ad 100 Sorbitol 29.0 Hydrated Silica (Hydrated) 22.0 Disodium Pyrophosphate 5.0 SFX 1.0 Glycolipids 1.0 Cellulose Gum 1.0 Aroma 0.9 Sodium Bicarbonate 0.8 Carbomer 0.8 Sodium Fluoride 0.32 Sodium Saccharin 0.1 Xanthan Gum 0.5 Titanium Dioxide 0.5 Limonene 0.2 Dyes, pH adjuster, preservative q. s. Recipes 232: Toothpaste Ingredient % Aqua ad 100 Hydrated Silica (Hydrated) 21.0 Sorbitol 19.0 Glycerin 15.0 Propylene Glycol 5.0
202300074 Foreign Filing 129 Tetrapotassium Pyrophosphate 5.0 Pentasodium Triphosphate 5.0 Sodium C14-16 Olefin Sulfonate 0.5 Glycolipids 0.5 SFX 0.5 Disodium Pyrophosphate 0.7 Aroma 0.3 Titanium Dioxide 0.4 Xanthan Gum 0.7 Sodium Fluoride 0.32 Sodium Saccharin 0.15 Allantoin 0.2 Chamomilla Recutita Flower Extract 0.1 Salvia Officinalis Leaf Extract 0.2 Zinc Chloride 0.3 Dyes solution (1% FD&C Blue No.1) 0.05 pH adjuster, preservative q. s. Recipes 233: Toothpaste Ingredient % Aqua ad 100 Hydrated Silica (Hydrated) 21.0 Xylitol 10.0 Sorbitol 10.0 SFX 1.5 Betaine 0.5 Aloe Barbadensis Leaf Juice Powder 0.3 Xanthan Gum 0.5 Zinc Gluconate 0.5 Sodium Coco-sulfate 0.5 Mentha Spicata Crispa Herb Oil 0.1 Calendula Officinalis Flower Extract 0.2 Chamomilla Recutita Flower Extract 0.2 L-limonene 0.1 Mentha Arvensis Leaf Oil 0.1 Sodium Fluoride 0.32 Titanium Dioxide 0.4 PH adjuster, preservative q. s.
202300074 Foreign Filing 130 Recipes 234: Toothpaste Ingredient % Aqua ad 100 Hydroxyapatite 20.0 Propylene Glycol 10.0 Glycerin 10.0 Sorbitol 10.0 Tetrapotassium Pyrophosphate 7.0 Silica 7.0 SFX 1.0 Aroma 1.0 Cellulose Gum 1.0 Sodium C14-16 Olefin Sulfonate 1.0 Sodium Fluoride 0.32 Sodium Cocoyl Isethionate 0.5 Sodium Saccharin 0.15 Limonene 0.2 Titanium Dioxide 0.4 Dyes, pH adjuster, preservative q. s. Recipes 235: Toothpaste Ingredient % Aqua ad 100 Hydrogenated Starch Hydrolysate (Hydrogenated, Hydrolysed) 20.0 Hydrated Silica (Hydrated), 15.0 Glycerin 15.0 Alumina 10.0 Sodium Lauryl Sulfate 1.05 PEG-12 1.0 SFX 0.75 Perlite 0.5 Pentapotassium Triphosphate 0.8 Pentasodium Triphosphate 0.8 Sodium Monofluorophosphate 0.76 Cellulose Gum 0.9 Sodium Saccharin 0.2 Cocamidopropyl Betaine 0.35 Aroma 1.0
202300074 Foreign Filing 131 Limonene 0.1 Dyes solution (1% FD&C Blue No.1) 0.05 Titanium Dioxide 0.3 pH adjuster, preservative q. s. Recipes 236: Toothpaste Ingredient % Dicalcium Phosphate Dihydrate (Dihydrate) 25.0 Aqua ad 100 Sorbitol 20.0 Glycerin 20.0 Methyl Salicylate 1.0 Sodium Lauryl Sulfate 0.9 SFX 0.9 Titanium Dioxide 0.5 Chondrus Crispus 0.8 Cellulose Gum 0.5 Sodium Silicate 0.3 Hydrated Silica (Hydrated) 1.0 Thymol 0.1 Sodium Saccharin 0.2 Sodium Hydroxide 0.5 Menthol 0.3 Dyes solution (1% FD&C Blue No.1) 0.02 pH adjuster, preservative q. s. Recipes 237: Toothpaste Ingredient % Aqua ad 100 Hydrated Silica (Hydrated) 21.0 Sorbitol 21.0 Glycerin 18.0 PEG-6 5.0 SFX 1.5 Xanthan Gum 0.8 Flavor 0.7 Titanium Dioxide 0.5 Sodium Citrate 0.4 Sodium Fluoride 0.32
202300074 Foreign Filing 132 Zinc Chloride 0.5 Sodium Saccharin 0.2 Chondrus Crispus 0.7 Limonene 0.1 Dyes solution (1% FD&C Blue No.1) 0.04 pH adjuster, preservative q. s. Recipes 238: Toothpaste Ingredient % Aqua ad 100 Sorbitol 36.0 Hydrated Silica (Hydrated), 18.0 Glycerin 18.0 Potassium Nitrate 1.0 Aroma 1.0 Cocamidopropyl Betaine 1.0 SFX 1.0 Xanthan Gum 0.7 Sodium Saccharin 0.2 Sodium Fluoride 0.32 Mica 0.4 Titanium Dioxide 0.4 Sodium Hydroxide 0.5 Limonene 0.1 Eugenol 0.1 Dyes, pH adjuster, preservative q. s. Recipes 239: Toothpaste Ingredient % Glycerin 33.0 PEG-8 5.0 Hydrated Silica (Hydrated), 5.0 Calcium Sodium Phosphosilicate 3.0 Cocamidopropyl Betaine 1.0 SFX 1.0 Sodium Methyl Cocoyl Taurate 0.3 Aroma 0.8 Titanium Dioxide 0.5 Carbomer 0.5
202300074 Foreign Filing 133 Sodium Saccharin 0.2 Sodium Fluoride 0.32 Limonene 0.2 Dyes, pH adjuster, preservative q. s. Recipes 240: Toothpaste Ingredient % Aqua ad 100 Sorbitol 63.0 Hydrated Silica (Hydrated) 14.0 Silica 7.0 SFXs 1.0 Titanium Dioxide 0.6 Maris Sal 0.5 Glycolipdis 0.5 Sodium Cocoyl Glutamate 0.5 Disodium Cocoyl Glutamate 0.5 Xanthan Gum 0.7 Sodium Fluoride 0.32 Echinacea Purpurea Extract (Extract) 0.1 Arnica Montana Flower Extract 0.1 Mentha Piperita Leaf Water 0.1 Myrtus Communis Leaf Water 0.1 Glycerin 1.0 Menthol 0.2 Aroma 1.0 L-limonene 0.2 Dyes, pH adjuster, preservative q. s. Recipes 241: Toothpaste Ingredient % Sorbitol 33.0 Aqua ad 100 Hydrated Silica (Hydrated) 18.0 Glycerin 15.0 PEG-32 4.0 Sodium Lauryl Sulfate 1.5 Cellulose Gum 1.0 SFX 1.0
202300074 Foreign Filing 134 Sodium Saccharin 0.3 Eucalyptol 0.2 Methyl Salicylate 0.5 Thymol 0.1 Phosphoric Acid 0.3 Menthol 0.4 Zinc Citrate 0.5 Sodium Phosphate 0.2 Xanthan Gum 0.5 Benzoic Acid 0.2 Sodium Monofluorophosphate 0.76 Flavor 1.0 Dyes solution (1% FD&C Blue No.1) 0.05 pH adjuster, preservative q. s. Recipes 242: Toothpaste Ingredient % Hydrogenated Starch Hydrolysate (Hydrogenated, Hydrolysed) 30.0 Aqua ad 100 Hydrated Silica (Hydrated) 22.0 PEG-32 4.0 SFX 1.0 Aroma 1.0 Cellulose Gum 1.0 Sodium Fluoride 0.32 Sodium Saccharin 0.25 PVM/MA Copolymer 0.7 Trisodium Phosphate 0.8 Calcium Aluminum Borosilicate 0.4 Glycerin 0.9 Lecithin 0.2 Tin Oxide 0.2 Limonene 0.1 Dyes solution (1% FD&C Blue No.1) 0.04 Titanium Dioxide 0.3 pH adjuster, preservative q. s. Recipes 243: Toothpaste Ingredient %
202300074 Foreign Filing 135 Aqua ad 100 Sorbitol 50.0 Hydrated Silica (Hydrated), 14.0 Silica Dimethyl Silylate 3.5 Hydroxyethylcellulose 3.5 SFX 1.05 PEG-40 Hydrogenated Castor Oil (Hydrogenated) 0.8 Aroma 0.9 Sodium Gluconate 0.4 Limonene 0.1 PEG-3 tallow aminopropyl amine 0.5 Olaflur 0.06 Stannous Fluoride 0.4 Sodium Saccharin 0.2 Potassium Hydroxide 0.4 Hydrochloric Acid 0.2 Dyes solution (1% FD&C Blue No.1) 0.04 pH adjuster, preservative q. s. Recipes 244: Toothpaste Ingredient % Aqua ad 100 Sorbitol 45.0 Hydrated Silica (Hydrated) 21.0 Sodium Lauryl Sulfate 1.5 SFX xx Cellulose Gum 1.0 Aroma 1.0 Zinc Citrate 0.5 Chondrus Crispus Powder (Powdered) 0.8 Sodium Saccharin 0.2 Sodium Fluoride 0.1 Titanium Dioxide 0.5 Hydroxyethylcellulose 0.3 Sodium Citrate 0.2 Stannous Fluoride 0.4 Dyes, pH adjuster, preservative q. s.
202300074 Foreign Filing 136 Recipes 245: Toothpaste Ingredient % Sodium Bicarbonate 35.00 PEG-8 5.0 Hydrated Silica (Hydrated 18.0 Glycerin 18.0 SFX 1.0 Sodium Lauryl Sulfate 0.5 Sodium Saccharin 0.5 Aroma 0.9 Dipotassium Phosphate 0.8 Sodium Carbonate 0.5 Sodium Fluoride 0.32 PEG/PPG-116/66 Copolymer 0.8 Calcium Peroxide 0.5 Calcium Hydroxide 0.4 Dyes solution (1% FD&C Blue No.1) 0.04 Sodium Silicate 0.5 Limonene 0.1 Silica 0.9 Titanium Dioxide 0.3 Dyes, pH adjuster, preservative q. s. Recipes 246: Toothpaste Ingredient % Glycerin 33.0 Hydrated Silica 22.0 Aqua ad 100 Sorbitol 15.0 Tetrapotassium Pyrophosphate 3.5 SFX 1.5 Titanium Dioxide 0.4 Sodium Lauroyl Sarcosinate 0.5 Cellulose Gum 0.8 Lauryl Glucoside 0.5 PVP 0.5 Cocamidopropyl Betaine 0.5 Xanthan Gum 0.5 Stannous Fluoride 0.4
202300074 Foreign Filing 137 Dyes, pH adjuster, preservative q. s. Recipes 247: Toothpaste Ingredient % Aqua ad 100 Hydrated Silica (Hydrated) 20.0 Sorbitol 18.0 Xylitol 14.0 SFX 1.2 Propylene Glycol 1.0 Glycerin 1.0 Sodium C14-16 Olefin Sulfonate 0.3 Aroma 1.0 Xanthan Gum 0.5 Disodium Phosphate 0.4 Sodium Fluoride 0.32 Zinc Chloride 0.5 Sodium Saccharin 0.2 Citric Acid 0.2 Titanium Dioxide 0.4 Dyes, pH adjuster, preservative q. s. Recipes 248: Toothpaste Ingredient % Aqua ad 100 Hydrogenated Starch Hydrolysate (Hydrogenated, Hydrolysed) 25.0 Hydrated Silica (Hydrated) 21.0 Hydroxyapatite 4.5 PEG-32 4.5 SFX 1.0 Sodium Lauryl Sulfate 0.5 Aroma 0.9 Sodium Monofluorophosphate 0.76 Trisodium Phosphate 0.5 Cellulose Gum 1.0 Sodium Saccharin 0.2 Sodium Hydroxide 0.3 Limonene 0.1 Dyes solution (1% FD&C Blue No.1) 0.05
202300074 Foreign Filing 138 Titanium Dioxide 0.4 pH adjuster, preservative q. s. Recipes 249: Toothpaste Ingredient % Glycerin 32.0 Hydrated Silica (Hydrated) 21.0 Aqua ad 100 Sodium Bicarbonate 30.0 PEG-12 3.0 SFX 1.5 Sodium Lauryl Sulfate 1.0 Flavor 1.0 Sodium Hydroxide 1.0 Cellulose Gum 1.0 Chondrus Crispus 0.7 Sodium Saccharin 0.15 Calcium Peroxide 0.5 Titanium Dioxide 0.5 Sodium Monofluorophosphate 0.76 Dyes, pH adjuster, preservative q. s. Recipes 250: Toothpaste Ingredient % Aqua ad 100 Sorbitol 63.0 Hydrated Silica (Hydrated) 22.0 Propylene Glycol 1.5 Cellulose Gum 1.5 SFX 1.0 Sodium C 14-16 Olefin Sulfonate 0.5 Aroma 0.8 Calcium Glycerophosphate 0.4 Sodium Fluoride 0.11 Sodium Saccharin 0.4 Cocamidopropyl Betaine 0.5 Citral 0.1 Geraniol 0.1 Limonene 0.1
202300074 Foreign Filing 139 Linalool 0.1 Titanium Dioxide 0.2 Dyes, pH adjuster, preservative q. s. Recipes 251: Toothpaste Ingredient % Aqua ad 100 Calcium Carbonate 30.0 Silica 7.0 Glycerin 5.0 Hydrated Silica 2.5 SFX 1.5 Aroma 1.0 Chondrus Crispus Powder 0.5 Cellulose Gum 0.5 Chlorhexidine Gluconate 0.1 Limonene 0.15 Sodium Saccharin 0.15 Titanium Dioxide 0.1 Sodium Fluoride 0.32 Dyes, pH adjuster, preservative q. s. Recipes 252: Toothpaste Ingredient % Aqua ad 100 Hydrogenated Starch Hydrolysate 20.0 Hydrated Silica 15.0 PEG-32 4.0 Glycolipids 1.5 SFX 1.0 Propylene Glycol 0.9 Aroma 0.9 Sodium Lauryl Sulfat 0.5 Hydroxyethylcellulose 0.5 Olaflur 0.13 Titanium Dioxide 0.1 Sodium Fluoride 0.1 Sodium Saccharin 0.2 Chamomilla Recutita Flower Extract 0.2
202300074 Foreign Filing 140 Chlorhexidine Digluconate 0.1 Limonene 0.1 Citral 0.1 Dyes, pH adjuster, preservative q. s. Recipes 253: Toothpaste Ingredient % Aqua ad 100 Sorbitol 20.0 Hydrated Silica 15.0 Silica 2.0 SFX 1.0 Cocamidopropyl Betaine 0.75 Titanium Dioxide 0.15 Flavor 0.8 Linalool 0.2 Sodium Monofluorophosphate 0.76 Sodium Fluoride 0.1 Sodium Saccharin 0.25 Cellulose Gum 0.5 Limonene 0.1 Chlorhexidine Digluconate 0.12 Dyes, pH adjuster, preservative q. s. Recipes 254: Toothpaste Ingredient % Aqua ad 100 Hydrated Silica 15.0 Glycerin 15.0 Potassium Nitrate 5.0 Sorbitol 4.5 Sodium Cocoamphoacetate 0.5 SFX 0.5 PEG-40 Hydrogenated Castor Oil 0.5 Carboxymethyl Cellulose 0.5 Titanium Dioxide 0.1 Sodium Fluoride 0.32 Sodium Saccharin 0.2 Aroma 0.2
202300074 Foreign Filing 141 Chlorhexidine Digluconate 0.12 Dyes, pH adjuster, preservative q. s. Recipes 255: Toothpaste for Kids Ingredient % Aqua ad 100 Sorbitol 28.0 Hydrated Silica (Hydrated) 18.0 Hydroxyethylcellulose 1.5 Titanium Dioxide 0.5 Cocamidopropyl Betaine 0.5 SFX 0.5 Olaflur 0.07 Aroma 0.8 Limonene 0.1 Sodium Saccharin 0.2 Hydrochloric Acid 0.7 Dyes, pH adjuster, preservative q. s. Recipes 256: Toothpaste for Children Ingredient % Sorbitol 33.0 Aqua ad 100 Hydrated Silica (Hydrated) 22.0 SFX 1.0 Sodium C14-16 Olefin Sulfonate 1.0 Aroma 0.8 Cellulose Gum 0.8 Calcium Glycerophosphate 0.5 Olaflur 0.07 Sodium Fluoride 0.1 Propylene Glycol 0.5 Sodium Saccharin 0.2 Cocamidopropyl Betaine 0.35 Mica 0.5 Citral 0.1 Limonene 0.1
202300074 Foreign Filing 142 Linalool 0.1 Titanium Dioxide 0.4 Dyes solution (1% FD&C Blue No.1) 0.05 Olaflur 0.07 pH adjuster, preservative q. s. Recipes 257: Baby Toothpaste Ingredient % Aqua ad 100 Hydrogenated Starch Hydrolysate (Hydrogenated, Hydrolysed) 14.0 Hydrated Silica (Hydrated) 14.0 PEG-32 3.5 Silica 7.0 SFX 1.5 Cellulose Gum 1.0 Aroma 1.0 Propylene Glycol 0.7 PEG-40 Hydrogenated Castor Oil (Hydrogenated), 0.8 Olaflur 0.06 Sodium Chloride 0.2 Sodium Saccharin 0.15 Tocopheryl Acetate 0.1 Glycerin 1.0 Retinyl Palmitate 0.1 Dyes solution (1% FD&C Blue No.1) 0.02 pH adjuster, preservative q. s. Recipes 258: Toothpaste for Children Ingredient % Aqua ad 100 Hydrated Silica (Hydrated) 22.0 Glycerin 20.0 Xylitol 10.0 SFX 1.5 Propylene Glycol 0.7 Xanthan Gum 0.5 Titanium Dioxide 0.5 Flavor 0.9 Sodium Lauroyl Sarcosinate 0.5
202300074 Foreign Filing 143 Disodium EDTA 0.3 Sodium Monofluorophosphate 0.76 Sodium Chloride 0.2 Dyes, pH adjuster, preservative q. s. Recipes 259: Kids Toothpaste Ingredient % Aqua ad 100 Sorbitol 40.0 Hydrated Silica (Hydrated) 17.0 Glycerin 26.0 SFX 1.5 Xanthan Gum 1.0 Steareth-30 1.0 Chondrus Crispus 1.0 Aroma 1.0 Disodium Phosphate 0.5 Sodium Benzoate 0.2 Amyloglucosidase 0.1 Citric Acid 0.3 Zinc Gluconate 0.5 Glucose Oxidase 0.1 Sodium Fluoride 0.22 Sodium Saccharin 0.15 Potassium Thiocyanate 0.1 Lactoperoxidase 0.1 Titanium Dioxide 0.3 Dyes, pH adjuster, preservative q. s. Recipes 260: 2 in 1 Toothpaste + Mouthwash Ingredient % Sorbitol 38.0 Aqua ad 100 Hydrated Silica (Hydrated) 21.0 Pentasodium Triphosphate 5.0 Sodium Lauryl Sulfate 0.35 SFX 1.05 PEG-32 1.0 Aroma 1.0
202300074 Foreign Filing 144 Alumina 0.5 Alcohols 0.7 Xanthan Gum 0.8 Sodium Fluoride 0.23 Sodium Saccharin 0.2 Disodium Phosphate 0.5 Cocamidopropyl Betaine 0.35 Zinc Sulfate 0.5 Trisodium Phosphate 0.3 Sodium Chloride 0.4 Sodium Sulfate 0.2 Limonene 0.1 Titanium Dioxide 0.5 Dyes, pH adjuster, preservative q. s. Recipes 261: 2 in 1 Toothpaste + Mouthwash Ingredient % Sorbitol 29.0 Aqua ad 100 Hydrated Silica 15.0 PEG-32 3.0 Sodium Lauryl Sulfate 0.5 SFX 0.5 Glycolipids 0.5 Aroma 0.9 Alcohols 0.7 Xanthan Gum 0.5 PEG-30 Glyceryl Stearate 0.5 Sodium Fluoride 0.05 Sodium Saccharin 0.7 Disodium Phosphate 0.3 Cocamidopropyl Betaine 0.5 Zinc Sulfate 0.3 Trisodium Phosphate 0.5 Sodium Chloride 0.1 Sodium Sulfate 0.2 Limonene 0.02 Dyes, pH adjuster, Preservative q. s. Mouthwash Recipess
202300074 Foreign Filing 145 Recipes 262: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 11.0 Propylene Glycol 7.0 SFX 1.0 Poloxamer 407 0.75 Aroma 0.9 Cetylpyridinium Chloride 0.04 Sodium Fluoride 0.05 Sodium Saccharin 0.07 Menthol 0.1 Dyes, pH adjuster, Preservative q. s. Recipes 263: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Sorbitol 15.0 Glycerin 7.5 SFX 1.0 Xylitol 1.0 Cellulose Gum 0.5 Zinc PCA 0.5 Zinc Hydroxyapatite 0.05 Aroma 0.9 Silica 0.05 Ricinus Communis Seed Oil 0.1 Ammonium Acryloyldimethyltaurate/VP Copolymer 0.05 Mentha Arvensis Leaf Oil 0.01 Sodium Myristoyl Sarcosinate 0.2 Sodium Methyl Cocoyl Taurate 0.2 Sodium Saccharin 0.5 Sodium Fluoride 0.05 Limonene 0.1 Dyes, pH adjuster, Preservative q. s. Recipes 264: Mouthrinse without Alcohol Ingredient %
202300074 Foreign Filing 146 Aqua ad 100 Sorbitol 20.0 PEG-40 0.5 SFX 0.5 Flavor 0.05 Xanthan Gum 0.1 Zinc Sulfate 0.15 Sodium Saccharin 0.05 Sodium Fluoride 0.05 Gellan Gum 0.2 Calcium Aluminum Borosilicate 0.1 Silica 0.05 Titanium Dioxide 0.05 Tin Oxide 0.07 Eugenol 0.15 Limonene 0.05 Linalool 0.05 Dyes, pH adjuster, Preservative q. s. Recipes 265: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 7.5 SFX 0.5 Glycolipids 0.5 Flavor 0.3 Cetylpyridinium Chloride 0.04 Sodium Saccharin 0.05 Sucralose 0.05 Sodium Fluoride 0.02 Disodium Phosphate 0.25 Dyes, pH adjuster, Preservative q. s. Recipes 266: Mouthrinse Ingredient % Aqua ad 100 Glycerin 10.0 Sorbitol 10.0 Cocamidopropyl Betaine 1.0
202300074 Foreign Filing 147 SFX 0.5 Potassium Chloride 0.1 Propylene Glycol 0.5 Aroma 0.25 Sodium Fluoride 0.02 Olaflur 0.16 Potassium Acesulfame 0.1 Sodium Chloride 0.1 Limonene 0.03 Sodium Sulfate 0.05 Dyes, pH adjuster, Preservative q. s. Example Recipes 267: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Sorbitol 15.0 SFX 1.0 Aloe Barbadensis Leaf Extract 0.15 Calendula Officinalis Flower Extract 0.2 Chamomilla Recutita Flower Extract 0.2 Sodium Fluoride 0.02 Calcium Glycerophosphate 0.05 Zinc Gluconate 0.8 Mentha Spicata Crispa Herb Oil 0.05 Mentha Arvensis Leaf Oil 0.05 Menthol 0.04 Dyes, pH adjuster, Preservative q. s. Recipes 268: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 15.0 Sodium Gluconate 1.5 SFX 0.5 PEG-40 Hydrogenated Castor Oil 0.5 Olaflur 0.16 Aroma 0.25 Stannous Chloride 0.05 Sodium Fluoride 0.02
202300074 Foreign Filing 148 Cocamidopropyl Betaine 0.35 Sodium Saccharin 0.07 Dyes, pH adjuster, Preservative q. s. Recipes 269: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 10.0 Sorbitol 8.0 SFX 1.0 Glycolipids 0.5 Tetrasodium Pyrophosphate 0.25 Aroma 0.04 Limonene 0.1 Sodium Fluoride 0.02 Sodium Saccharin 0.08 Dyes, pH adjuster, Preservative q. s. Recipes 270: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 7.5 PEG-60 Hydrogenated Castor Oil 1.0 SFX 0.5 Sodium Citrate 0.45 Aroma 0.3 Zinc Chloride 0.15 Cetylpyridinium Chloride 0.05 Sodium Saccharin 0.08 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s. Recipes 271: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 11.0 SFX 2.0 Flavor 1.0 Cetylpyridinium Chloride 0.5 Poloxamer 407 0.1
202300074 Foreign Filing 149 Sodium Saccharin 0.1 Sodium Fluoride 0.02 Sucralose 0.05 Mentha Viridis Leaf Oil 0.1 Dyes, pH adjuster, Preservative q. s. Recipes 272: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 12.0 Sorbitol 8.0 Potassium Nitrate 0.15 PEG-60 Hydrogenated Castor Oil 0.5 SFX 0.25 Poloxamer 407 0.25 Aroma 0.2 Disodium Phosphate, Sodium Phosphate 0.25 Sodium Fluoride 0.05 Sodium Saccharin 0.08 Dyes, pH adjuster, Preservative q. s. Recipes 273: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Sorbitol 10.0 PEG-40 Hydrogenated Castor Oil 1.0 Potassium Citrate 1.0 SFX 0.25 Glycerin 0.9 Aroma 0.4 Zinc Sulfate 0.15 Sodium Saccharin 0.1 Propylene Glycol 0.3 Citrus Limon Juice 0.05 Aloe Barbadensis Leaf Extract 0.1 Limonene 0.05 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s.
202300074 Foreign Filing 150 Recipes 274: Mouthrinse without Alcohol Ingredient % Aqua ad 100 Glycerin 12.0 SFX 1.2 Gycolipids 1.0 Hydrogenated Starch Hydrolysate 1.0 Xylitol 1.0 Steareth-30 0.2 Amyloglucosidase 0.5 Allantoin 0.1 Glucose Oxidase 0.5 Sodium Fluoride 0.05 Limonene 0.1 Dyes, pH adjuster, Preservative q. s. Recipes 275: Mouthrinse Ingredient % Aqua ad 100 Glycerin 11.0 Propylene Glycol 7.5 Sorbitol 7.5 Tetrapotassium Pyrophosphate 1.5 Polysorbate 20 0.5 SFX 0.5 Tetrasodium Pyrophosphate 0.75 Zinc Citrate 0.15 PVM/MA Copolymer 0.1 Flavor 0.2 Sodium Fluoride 0.05 Sodium Saccharin 0.07 Dyes, pH adjuster, Preservative q. s. Recipes 276: Mouthrinse Ingredient % Aqua ad 100 Glycerin 11.0 Alcohol 7.5 Sorbitol 7.5
202300074 Foreign Filing 151 SFX 1.0 Poloxamer 407 0.5 Sodium Phosphate, Disodium Phosphate 0.15 Flavor 0.9 Cetylpyridinium Chloride 0.05 Sodium Saccharin 0.08 Sodium Fluoride 0.05 Dyes, pH adjuster, Preservative q. s. Recipes 277: Mouthrinse Ingredient % Aqua ad 100 Alcohols 22.0 Sorbitol 10.0 Flavor 1.0 SFX 1.0 Sodium Saccharin 0.09 Eucalyptol 0.1 Thymol 0.06 Sucralose 0.06 Sodium Fluoride 0.05 Menthol 0.04 Dyes, pH adjuster, Preservative q. s. Recipes 278: Mouthrinse Ingredient % Aqua ad 100 Glycerin 12.0 Xylitol 7.0 Disodium Phosphate 1.5 SFX 1.0 Cocamidopropyl Betaine 0.5 Propylene Glycol 0.5 Stannous Fluoride 0.09 Aroma 0.3
202300074 Foreign Filing 152 Mentha Piperita Leaf Extract 0.1 Chamomilla Recutita Flower Extract 0.2 Salvia Officinalis Leaf Extract 0.25 Commiphora Myrrha Resin Extract 0.15 Sodium Saccharin 0.1 Citral 0.05 Limonene 0.02 Linalool 0.02 Dyes, pH adjuster, Preservative q. s. Recipes 279: Mouthrinse Ingredient % Aqua ad 100 Glycerin 11.0 Sorbitol 11.0 Propylene Glycol 3.0 Disodium Pyrophosphate 1.5 PEG-40 Hydrogenated Castor Oil 1.0 SFX 0.5 PVM/MA Copolymer 0.5 Tetrapotassium Pyrophosphate 0.25 Sodium Levulinate 0.25 Sodium Anisate 0.25 Olaflur 0.16 Aroma 0.8 Arginine 0.8 Sodium Saccharin 0.07 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s. Recipes 280: Mouthrinse Ingredient % Aqua ad 100 Alcohol Denat. 33.0 Glycerin 10.0 Sorbitol 8.0 PEG-40 Hydrogenated Castor Oil 1.0
202300074 Foreign Filing 153 SFX 1.0 Glycolipids 0.5 Aroma 0.6 Menthol 0.05 Sodium Saccharin 0.07 Aluminum Lactate 0.2 Thymol 0.06 Curcuma Xanthorrhiza Root Extract 0.05 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s. Recipes 281: Mouthrinse Ingredient % Aqua ad 100 Sorbitol 12.5 Propylene Glycol 3.5 SFX 0.5 Sodium Lauryl Sulfate 0.5 Poloxamer 407 0.5 Flavor 0.3 Eucalyptol 0.08 Methyl Salicylate 0.1 Thymol 0.05 Stannous Fluoride 0.09 Menthol 0.1 Sodium Saccharin 0.06 Sucralose 0.7 Camellia Sinensis Leaf Extract 0.05 Dyes, pH adjuster, Preservative q. s. Recipes 282: Mouthrinse Ingredient % Aqua ad 100 SFX 1.0 Eucalyptol 0.9 Zinc Chloride 0.25 Methyl Salicylate 0.05 Thymol 0.05
202300074 Foreign Filing 154 Levomenthol 0.07 Stannous Fluoride 0.09 Dyes, pH adjuster, Preservative q. s. Recipes 283: Mouthrinse Ingredient % Aqua ad 100 Alcohol Denat. 15.0 Sorbitol 5.0 Glycine 1.0 SFX 1.0 Aroma 0.2 Zinc Sulfate 0.2 Sodium Fluoride 0.02 Sodium Saccharin 0.07 Dyes, pH adjuster, Preservative q. s. Recipes 284: Mouthrinse Ingredient % Aqua ad 100 Sorbitol 11.0 Alcohol Denat. 11.0 Xylitol 5.0 PEG-40 Hydrogenated Castor Oil 0.75 SFX 0.5 Isopropyl Alcohol 0.5 Menthol 0.05 Sodium Citrate 0.15 Mentha Piperita Herb Oil 0.25 Sodium Saccharin 0.08 Methyl Diisopropyl Propionamide 0.05 Thymol 0.07 Glycolipids 0.1 Sodium Fluoride 0.05 O-cymen-5-ol 0.05 Cyclodextrin 0.07 Eugenia Caryophyllus Leaf Oil 0.1 Propylene Glycol 0.25 Butylene Glycol 0.25
202300074 Foreign Filing 155 Psidium Guajava Leaf Extract 0.08 Phyllanthus Emblica Fruit Extract 0.08 Echinacea Purpurea Root Extract 0.08 Salvia Officinalis Leaf Extract 0.2 Dyes, pH adjuster, Preservative q. s. Recipes 285: Mouthrinse Ingredient % Aqua ad 100 Alcohols 15.0 Sorbitol 7.0 Sodium Lauroyl Sarcosinate 1.0 SFX 0.25 PEG-40 Hydrogenated Castor Oil 0.25 Aroma 0.4 Cetylpyridinium Chloride 0.04 Sodium Citrate 0.15 Sodium Saccharin 0.08 Sodium Fluoride 0.05 Limonene 0.05 Dyes, pH adjuster, Preservative q. s. Recipes 286: Mouthrinse Ingredient % Aqua ad 100 Alcohol denat. 18.0 Sorbitol 8.0 Aroma 1.0 Poloxamer 407 0.9 Methyl salicylate 0.2 Sodium Saccharin 0.2 Sodium Fluoride 0.05 SFX 0.9 Chlorhexidine Digluconate 0.2 PEG-40 Hydrogenated Castor Oil 0.2 Dyes, pH adjuster, Preservative q. s. Recipes 287: Mouthrinse Ingredient %
202300074 Foreign Filing 156 Aqua ad 100 Glycerin 10.0 Hydrogenated Starch Hydrolysate 1.0 PVP 0.5 SFX 0.5 Aroma 0.4 Zinc Acetate 0.2 Sodium Fluoride 0.32 Potassium Acesulfame 0.15 Chlorhexidine Digluconate 0.2 Dyes, pH adjuster, Preservative q. s. Recipes 288: Mouthrinse Ingredient % Aqua ad 100 Glycerin 12.0 Sorbitol 7.0 SFX 0.75 PEG-40 Hydrogenated Castor Oil 0.5 Chlorhexidine Gluconate 0.2 Mentha Piperita Oil 0.2 Sodium Fluoride 0.05 Sodium Saccharin 0.2 Dyes, pH adjuster, Preservative q. s. Recipes 289: Mouthrinse Ingredient % Aqua ad 100 Glycerin 15.0 Macrogolglycerol Hydroxystearate 7.0 Sorbitol 7.0 SFX 0.5 Cocamidopropyl Betaine 0.2 Sodium Fluoride 0.02 Chlorhexidine Digluconate 0.2 Flavor 0.5 Dyes, pH adjuster, Preservative q. s. Recipes 290: Mouthrinse Concentrate Ingredient %
202300074 Foreign Filing 157 Propylene Glycol 55.0 Aqua ad 100 Aroma 2.0 Sodium Saccharin 0.4 SFX 0.75 Polysorbate 20 0.25 Commiphora Myrrha Oil 2.0 Salvia Officinalis Oil 0.2 Mentha Piperita Oil 0.2 Chamomilla Recutita Flower Extract 0.2 Limonene 0.1 Sodium Fluoride 0.02 Dyes, pH adjuster, Preservative q. s. Recipes 291: Mouthrinse Concentrate Ingredient % Propylene Glycol 45.0 PEG-6 5.0 Aqua ad 100 SFX 1.0 Bisabolol 0.2 Zinc Chloride 0.25 Cetylpyridinium Chloride 0.1 Sodium Saccharin 0.5 Sodium Fluoride 0.05 Salvia Officinalis Oil 2.5 Eugenol 0.2 Limonene 0.1 Linalool 0.1 Citronellol 0.1 Dyes, pH adjuster, Preservative q. s. Recipes 292: Mouthrinse Concentrate Ingredient % Alcohols 55.0 Aqua ad 100
202300074 Foreign Filing 158 Aroma 1.5 SFX 0.7 Sodium C14-17 Alkyl Sulfonate 0.7 Mentha Arvensis Leaf Oil 2.0 Sodium Saccharin 0.5 Chamomilla Recutita Flower Extract 0.5 Commiphora Myrrha Resin Extract 0.2 Salvia Officinalis Leaf Extract 0.2 Sodium Fluoride 0.02 Limonene 0.1 Dyes, pH adjuster, Preservative q. s. Recipes 293: Peroxide Mouthrinse Ingredient % Aqua ad 100 Glycerin 11.0 Alcohol 5.0 H2O235% 4.30 Polyphosphate 1.0 Menthol 0.05 Coolant 0.02 Flavor 0.15 Calcium Chloride 0.03 SFX 0.50 Sodium Saccharin 0.1 Sodium Fluoride 0.22 Dyes, pH adjuster, Preservative q. s. Recipes 294: Fluoride Gel Ingredient % Aqua ad 100 Propylene Glycol 30.0 Hydroxyethylcellulose 3.0 Saccharin 1.0 SFX 0.5 Pyrus Malus Fruit 0.2 Mentha Piperita Oil 0.2 Flavor 0.5 Aminofluoride Dectafluor 0.29
202300074 Foreign Filing 159 Olaflur 3.03 Sodium Fluoride 2.21 Dyes, pH adjuster, Preservative q. s. Recipes 295: Fluoride Gel Ingredient % Aqua ad 100 Sorbitol 15.00 Silica 5.0 PEG 600 3.5 Tetrapotassium Pyrophosphate 1.5 Xanthan Gum 0.5 Sodium Lauryl Sulfate 0.75 SFX 0.75 Aroma 0.9 Methol 0.05 Anethol 0.05 Citronellol 0.2 Sodium Fluoride 5.0 Dyes, pH adjuster, Preservative q. s. Recipes 296: Dental Floss Ingredient % PTFE ad 100 Aroma 1.0 Acacia Senegal Gum 0.7 Cera Alba 0.7 Potassium Acesulfame 0.5 Sodium Lauryl Sulfate 0.25 SFX 0.25 Glycerin 0.7 Silica 0.5 Sodium Fluoride 0.22 Recipes 297: Teeth Wipe Ingredient %
202300074 Foreign Filing 160 Aqua q. s.100 Alcohol Denat. 30.00 Glycerin 20.00 Stevia 1.0 Polysorbate 20 0.5 SFX 0.5 Aroma 1.0 Dyes, pH adjuster, Preservatives q. s. Recipes 298: Chewing Gum Ingredient % Gum Base ad 100 Sorbit 40.0 Isomalt 9.0 Xylitol 2.5 Mannit D 2.5 Aspartame 0.1 Acesulfam K 0.05 Emulgum 0.2 Sorbitol 12.00 Glycerin 1.0 SFX 1.0 Flavor 1.0 Sodium Fluoride 0.05 Dyes, pH adjuster, Preservative q. s. Recipes 299: Mouthwash Tabs Ingredient % Dicalcium Phosphate Anhydrous ad 100 Sodium Bicarbonate 35.0 Silica 7.0 Citric Acid 4.0 SFX 3.0 Sorbitol 1.0 Glycerin 1.0 Stevia Rebaudiana Extract (Stevia) 0.2 Xylitol 0.5 Aroma 0.1 Mentha Piperita Oil 0.1
202300074 Foreign Filing 161 Dyes, pH adjuster, Preservative q. s. Recipes 300: Tooth Tab Ingredient % Dicalcium Phosphate Anhydrous ad 100 Potassium Bitartrate 15.0 Sorbitol 15.0 SFX 6.0 Lauroyl Sarcosine 0.8 Kaolin 0.5 Sodium Saccharin 0.5 Aroma 0.2 Dyes, pH adjuster, Preservative q. s. Recipes 301: Powder Toothpaste Ingredient % Calcium Carbonate ad 100 Sorbitol 15.0 Kaolin 15.0 Sodium Bicarbonate 15.0 SFX 1.5 Aroma 1.0 Citrus Limon Peel Oil 1.0 Stevia Rebaudiana Extract 0.5 Xylitol 0.5 Citral 0.1 Geraniol 0.1 Limonene 0.1 Dyes, pH adjuster, Preservative q. s.
202300074 Foreign Filing 162 Further Recipess (in wt.-%):
I II III IV V VI VII VIII IX X Water ad 100 SFX 9.0 15.0 5.5 5.0 7.0 3.0 6.0 4.0 3.5 3.0 Sodium Laureth Sulfate - - - 7.0 - - - 4.5 - - Sodium Lauryl Sulfate - - - - 5.0 - - - 3.5 1.0 Cocamidopropyl Betaine - - - - - 6.0 - 3.0 2.0 4.5 Sodium Cocoamphoacetate - - - - - - 2.0 - 3.5 - Coco-Glucoside - - - - - - 5.5 1.5 - - Sodium Cocoyl Glutamate - - - - - - 0.7 - - - Stearic Acid - - - - - - - 1.0 - 3.5 Glyceryl Glucoside - 0.5 - - 0.3 - 0.2 - - - Sucrose Cocoate 0.5 - 1.0 1.0 1.0 0.5 - 1.0 1.0 1.0 Glycerin - 1.0 0.5 - - 0.3 1.5 1.0 - 1.0 PEG-7 Glyceryl Cocoate - 0.7 - 0.5 - - - - - 0.5 Trideceth-9 - - - 0.2 - - - 0.3 - - Polyglyceryl-4 Caprate - - 1.0 - 0.4 - 0.5 - - - Polyquaternium-10 - 0.2 - 0.1 - - - 0.2 - - Hydroxypropyl Guar 0.2 - 0.3 0.2 0.2 0.2 0.3 0.1 0.2 - Hydroxypropyltrimonium Chloride Silicone Quaternium-22 - - - 0.5 - - - 0.5 - - Dimethicone - 0.5 - - - - - 1.0 - - Amodimethicone - 0.1 - - 1.0 0.3 - - 0.5 - Argania Spinosa Oil - - 0.2 0.1 - 0.1 0.2 - - - Glycol Distearate 0.5 0.5 - - 0.5 - 0.3 0.5 0.5 0.5 Acrylates/C10-30 Alkyl Acrylate 1.0 - - - 0.5 - - - 0.5 - Crosspolymer Sodium Hydroxide, 25% 1.5 - - - 0.8 - - - 0.7 - Isostearamide MIPA; Glyceryl - - - - - 2.5 - - 1.0 0.5 Laurate Cocamide DEA - - - 1.0 0.5 - - - - - Sodium Chloride 0.1 1.2 - 0.5 - 1.5 - 2.0 - 1.2 PEG-120 Methyl Glucose Dioleate - 3.5 - 0.2 - - - 0.6 - - Xanthan Gum - - 1.2 - - 0.2 1.5 - - - Cellulose - - - 0.1 - 0.1 0.1 - 0.1 - Zinc Pyrithione - 0.1 - 1.1 - - - 0.5 - - Benzophenone-4 - 0.1 - 0.2 - - - 0.2 0.1 - Tetrasodium EDTA 0.1 0.1 - 0.1 - - - 0.1 0.1 -
202300074 Foreign Filing 163 Caffeine - - 0.1 - - - - 0.1 0.1 - Hydrolyzed Keratin - - 0.1 0.1 - 0.1 0.2 - 0.1 - Panthenol 0.1 0.1 0.1 0.1 0.1 0.1 - 0.1 0.1 0.1 Citric Acid ad pH Parfums, Dyes, Preservatives q. s. XI XII XIII XIV XV XVI XVII XVIII XIX XX Water ad 100 SFX 10.0 7,0 5,0 4,0 7,0 2,5 6,0 4,0 2,0 1,0 Sodium Laureth Sulfate - - 8,0 - - - - 3,5 - - Coco-Betaine - - - 5,5 5,0 - - 3,0 - - Cocamidopropyl Betaine - - - - - 6,0 - - 3,0 4,0 Sodium Cocoamphoacetate - - - - 2,0 - - - - - Coco Glucoside - - - - 2,0 - 4,0 1,5 6,0 - Glycolipids - - - - - - 2,5 0,5 2,5 0,3 Stearic Acid - 8,0 - - - - - - - 4,5 Sodium Cocoyl Glycinate - - - - - 3,0 0,5 - - 0,3 Sodium Lauroyl Methyl Isethionate - - - - - 1,0 - 1,0 2,0 0,5 Sucrose Cocoate 0.5 1,1 - 1,0 1,0 - - 0,3 1,0 0,3 Glycerin 1.5 0,3 0,5 - 0,3 0,5 1,0 0,5 - 1,0 PEG-7 Glyceryl Cocoate - - 0,5 - - 0,8 - 0,5 - 0,5 PEG-40 Hydrogenated Castor Oil - - 0,5 - - 1,5 - 0,3 - - Polyglyceryl-4 Caprate 0.5 - - - 0,4 - 0,5 - 1,1 - Polyquaternium-11 - 0,2 - - 0,1 0,3 - 0,2 - - Guar Hydroxypropyltrimonium 0.3 - 0,3 0,2 0,2 - 0,3 0,1 0,4 0,2 Chloride Silicone Quaternium-22 - - 0,5 - - - - 1,5 - - PEG-12 Dimethicone - - - - - 1,5 - - - - Dimethicone - - 1,0 - 0,5 - - - - - Aminopropyl Dimethicone - - - - 0,3 - - - - - Helianthus Annuus Oil 0.1 - 0,2 0,1 - 0,1 0,3 0,2 - 0,1 PEG-3 Distearate - - 0,5 - - 0,8 - 0,5 - - Acrylates/C10-30 Alkyl Acrylate - - 0,2 - 0,5 - - - - - Crosspolymer Sodium Hydroxide, 25% - - 0,3 - 0,8 - - - - - Cocamide DEA - - - - - 2,5 - - - 0,5 Cocamide MEA - - - 1,0 - - - 1,0 - - Sodium Chloride 0.4 0,7 0,1 - - 1,5 - 2,0 - 1,2
202300074 Foreign Filing 164 Propylene Glycol (and) PEG-55 - 2,5 2,0 - - 0,3 - 0,6 - 0,2 Propylene Glycol Oleate Xanthan Gum 1.2 - - 1,0 0,2 - 1,5 0,1 1,1 - Hydroxyethyl Cellulose 0.1 - - 0,1 - 0,1 0,1 - - - Benzophenone-4 - 0,1 0,2 - - 0,2 - 0,2 - 0,1 Menthol 0.1 - - - - - - - - 0,1 Tetrasodium Glutamate Diacetate - 0,1 - 0,1 0,1 - 0,1 0,1 - 0,1 Caffeine 0.1 - 0,1 - - - - 0,1 - - Coumarin 0.1 - - 0,1 0,1 - 0,1 0,1 - 0,1 Hydrolyzed Wheat Protein 0.1 - 0,1 0,1 - - 0,2 0,1 0,1 0,1 Panthenol 0.1 0,1 - 0,1 0,1 0,1 0,1 - 0,1 0,1 Citric Acid ad pH Parfums, Dyes, Preservatives q. s. XXI XXII XXIII XIV XXV XXVI XXVII XXVIII XXIX XXX Water ad 100 SFX 6.0 4.0 3.5 1.0 3.0 3.0 4.0 2.0 2.5 5.0 Sodium Coco-Sulfate 3.0 1.0 - 5.0 3.0 3.0 2.0 - 2.5 3.0 Glycolipids 1.0 1.5 1.0 2.0 - 2.0 - Lauryl Glucoside - 2.0 - - - - 2.0 3.5 2.0 Sodium Cocoyl Glutamate 1.0 - - - 3.0 - - - - Sodium Cocoyl Glycinate - - 1.5 - - - - 2.5 1.5 - Sodium C14-16 Olefin Sulfonate 3.0 2.0 - - 2.0 Lauroyl/Myristoyl Methyl Glucamide - 1.0 - 2.0 - - - - - Cocamidopropyl Betaine - 2.0 1.5 4.0 - 2.0 - 7.5 - - Sodium Cocoamphoacetate - 2.0 5.0 - 2.0 2.0 4.0 - - - Sucrose Cocoate 1.0 - 1.5 - 1.5 1.0 - 1.0 - 3.5 Glycerin 0.5 0.5 - - 0.3 - 0.2 - 0.5- - Alcohol Denat. - - 3.0 - - 2.0 - - - - Sorbitan Sesquicaprylate 1.0 - 0.7 1.0 0.5 - 0.5 - 1.0 Isostearamide MIPA; Glyceryl - 1.0 - - - 2.0 - - - 0.5 Laurate Xanthan Gum 1.0 0.7 0.5 - 0.7 0.3 0.7 0.5 - 0.5 Chondrus Crispus - - 1.5 2.0 1.5 0.7 - - 0.5 Carrageenan - - - 1.0 - - - 0.3 - 0.5 Hydroxypropyl Starch Phosphate - - - - - - - 4.5 5.5 - Guar Hydroxpropyltrimonium 0.2 - 0.5 0.2 0.2 0.5 0.3 0.1 - - Chloride
202300074 Foreign Filing 165 Bis-(Isostearoyl/Oleyl Isopropyl) 0.5 0.5 - - 0.5 - - - 0.5 - Dimonium Methosulfate Prunus Amygdalus Dulcis (Almond) - 0.1 - 0.1 - 0.05 - - - - Oil Lemon Oil - 0.2 - 0.1 0.2 Cellulose 0.5 - - - 0.7 - 0.3 0.1 - 0.5 Charcoal Powder 1.0 - - - - - - - - - Saccharum Officinarum (Sugar - - - 0.1 - 0.2 - - - - Cane) Extract Sodium Chloride 0.7 - - 0.5 1.0 0.7 - 2.0 - 1.2 Polyglyceryl-6 Caprylate; Polyglyceryl-3 Cocoate; 3.0 - 4.0 2.5 - Polyglyceryl-4 Caprate; Polyglyceryl- 6 Ricinoleate Caprylyl/Capryl Glucoside; Aqua, Sodium Cocoyl Glutamate; Glyceryl - 3.0 - 1.0 2.0 Caprylate;Ccitric Acid; Polyglyceryl-6 Oleate, Sodium Surfactin Tocopherol - 0.1 - 0.1 - 0.1 0.1 - 0.1 - Phytic Acid 0.1 0.1 - - - - - 0.1 0.1 - Citric Acid ad pH Parfums, Dyes, Preservatives q. s. XXXI XXXII XXXIII XXXIV XXXV XXXVI XXXVII XXXVIII Water ad 100 SFX 1.0 1.5 2.0 1.5 3.0 2.5 4.0 5.0 Capryl/Capramidopropyl - 2.0 - - 1.0 - 2.0 Betaine Glycolipids 1.0 - - - 1.0 - - Decyl Glucoside 1.0 - - - - 2.0 - Disodium - - 3.0 2.0 - - 2.0 Cocoamphodiacetate PEG-6 Caprylic/Capric 3.0 1.5 - - - - - 2.0 Glycerides Polyglyceryl-6 Caprylate; - 2.0 - - 3.5 - Polyglyceryl-4 Caprate Polyglyceryl-6 Caprylate; - 3.0 - 4.0 - - Polyglyceryl-3 Cocoate;
202300074 Foreign Filing 166 Polyglyceryl-4 Caprate; Polyglyceryl-6 Ricinoleate Polyglyceryl-4 Caprate - - 2.5 - - Persea Gratissima - 0.1 - 0.2 - 0.1 0.05 (Avocado) Oil Rosemary Oil 0.1 - 0.05 - 0.1 - - Hydroxypropyl - 0.5 - - - 0.5 Methylcellulose Sorbitan Sesquicaprylate 0.3 - 0.5 - 0.3 0.5 0.1 Betaine - 0.5 1.0 - 1.0 - 1.0 Allantoin - - 0.1 - 0.1 - Starch - - - 0.1 0.05 - 0.1 Glycerin 3.0 1.0 - - - 1.0 1.0 - Hexylene Glycol 1.0 - 1.0 - 1.0 1.0 - - Methylpropanediol; Caprylyl Glycol; Benzoic 1.2 - - - - - - - Acid Benzyl Alcohol, Caprylyl - 1.0 1.0 1.0 1.0 - - - Glycol, Benzoic Acid Aqua, Sodium Levulinate, Sodium - - - - - 1.0 1.0 1. Benzoate pH adjuster (Citric Acid ad pH or NaOH) Preservatives, Parfum q. s. Ingredient Pouch 1 Pouch 2 Pouch 3 SFX 15 10 20 Sodium laureth sulfate 0 0 10 Fatty alcohol ethoxylate (C12-14, 7EO) 14 14 14 Fatty acid (C8-C18) 13 13 13 1,2-propane diol 22 22 22 Glycerine 22 22 22 Sodium Hydroxide 4 4 4 Citric acid to pH 8 to pH 8 to pH 8 Medley® Brilliant 300 L 3 3 3 Water Add to 100% Add to 100% Add to 100%
202300074 Foreign Filing 167 Ingredient Pouch 4 Pouch 5 Pouch 6 SFX 15 10 5 Persicomycin 0.1 0.1 0.1 Sodium laureth sulfate 0 0 10 Fatty alcohol ethoxylate (C12-14, 3EO) 14 14 14 Fatty acid (C8-C18) 13 13 13 1,2-propane diol 22 22 22 Glycerine 22 22 22 Sodium Hydroxide 4 4 4 Citric acid to pH 8 to pH 8 to pH 8 Medley® Brilliant 300 L 3 3 3 Water Add to 100% Add to 100% Add to 100% Ingredient Pouch 7 Pouch 8 Pouch 9 SFX 15 10 5 Sodium laureth sulfate 0 0 10 Fatty alcohol ethoxylate (C12-14, 3EO) 14 14 14 Fatty acid (C8-C18) 13 13 13 1,2-propane diol 22 22 22 Glycerine 22 22 22 Sodium Hydroxide 4 4 4 Citric acid to pH 8 to pH 8 to pH 8 Medley® Brilliant 300 L 3 3 3 Water Add to 100% Add to 100% Add to 100% Ingredient Pouch 10 Pouch 11 Pouch 12 SFX 15 10 5 Sodium laureth sulfate 0 0 10 Fatty alcohol ethoxylate (C12-14, 7EO) 14 14 14 Fatty acid (C8-C18) 13 13 13 1,2-propane diol 22 22 22 Glycerine 22 22 22
202300074 Foreign Filing 168 Sodium Hydroxide 4 4 4 Citric acid to pH 8 to pH 8 to pH 8 Medley® Brilliant 300 L 3 3 3 Water Add to 100% Add to 100% Add to 100% Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 15 15 SLES 3EO 5 5 FAEO C12-18, 7 EO 5 5 Dissolvine® GLDA 1 1 1 FAEO C12-18, 3 EO 5 6 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 6 6 6 Sodium Citrate 6 6 6 SFX 15 10 20 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45
202300074 Foreign Filing 169 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Polymers (soil release, dye transfer inhibitors, rheology polymers, anti-redeposition, polycarboxylates, polyacrylates, polyvinyl alcohol, 1 1 1 polyethylene glycol, Polyethyleneimine Ethoxylated) Medley® Brilliant 300 L 2 2 2 Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Miscellaneous (fragrances, preservatives, dyes, pigments, Bitrex, sodium formate, sorbitol, ethoxylated M-toluidyne, antifoaming agent, defoamers, solvents, trimethylsiloxysilicate, 1 1 1 etylhexyl stearate, sulfated ethoxylated hexamethylenediamine quaternized, 2-aminoethanol sulfate (salt))
202300074 Foreign Filing 170 Medley® Brilliant 300 L 2 2 2 Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 C8C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 C10C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 C8C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95
202300074 Foreign Filing 171 Trilon M 2 2 2 WeylClean PLA 1 1 1 1 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 REWOTERIC AM C 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 WeylClean PLA 1 1 1 1 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1
202300074 Foreign Filing 172 Ingredients Detergent 1 Detergent 2 Detergent 3 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 4 Detergent 5 Detergent 6 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 persicomycin 0,1 0,1 0,1 SLES 3EO 5 5 5 FAEO C12-18, 3 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 7 Detergent 8 Detergent 9 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20
202300074 Foreign Filing 173 SLES 3EO 5 5 5 FAEO C12-18, 4 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 10 Detergent 11 Detergent 12 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 FAEO C12-18, 4 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 13 Detergent 14 Detergent 15 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 Glucopon USP 600 (APG) 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 16 Detergent 17 Detergent 18 Na soap from palm kernel oil 2 2 2
202300074 Foreign Filing 174 Sodium Citrate 6 6 6 SFX 15 10 20 Glucopon USP 600 (APG) 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 19 Detergent 20 Detergent 21 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Myristic acid 2,5 2,5 2,5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 22 Detergent 23 Detergent 24 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Lauric acid 2,5 2,5 2,5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 25 Detergent 26 Detergent 27 Na soap from palm kernel oil 2 2 2
202300074 Foreign Filing 175 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 5 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 28 Detergent 29 Detergent 30 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 REWOTERIC AM V 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 31 Detergent 32 Detergent 33 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 REWOTERIC AM V 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1
202300074 Foreign Filing 176 Ingredients Detergent 34 Detergent 35 Detergent 36 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 Neutrol® MGDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 34 Detergent 35 Detergent 36 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 4 EO 3 3 3 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 37 Detergent 38 Detergent 39 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 Glucopon®215P 3 3 3 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1
202300074 Foreign Filing 177 Ingredients Detergent 40 Detergent 41 Detergent 42 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Glucopon®215P 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 43 Detergent 44 Detergent 45 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Pelargonic acid 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 46 Detergent 47 Detergent 48 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Oleic acid 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1
202300074 Foreign Filing 178 Ingredients Detergent 49 Detergent 50 Detergent 51 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 Palmitic acid 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 49 Detergent 50 Detergent 51 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 SLES 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 Monoethanol amine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 52 Detergent 53 Detergent 54 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 SLES 5 5 5 FAEO C12-18, 4 EO 3 3 3 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 Monoethanol amine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2
202300074 Foreign Filing 179 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 52 Detergent 53 Detergent 54 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 SLES 5 5 5 Myristic acid 3 3 3 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 Monoethanol amine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 55 Detergent 56 Detergent 57 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 SLES 5 5 5 Glucopon 600 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 Monoethanol amine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 58 Detergent 59 Detergent 60
202300074 Foreign Filing 180 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 Glucopon 600 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 Monoethanol amine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 ^ Ingredients Detergent 61 Detergent 62 Detergent 63 MEA soap from palm kernel 2 2 2 oil MEA Citrate 6 6 6 SFX 15 10 20 Glucopon 600 5 5 5 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 Monoethanol amine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 64 Detergent 65 Detergent 66 Hydrogen peroxide 5 5 5 Citric Acid 2 2 2 SFX 15 10 20 DIETHYLENETRIAMINE 0,1 0,1 0,1 PENTAMETHYLPHOSPHONATE DISODIUM DISTYRYL BIPHENYL 0,2 0,2 0,2 DISULFONATE Add water to Add water to Add water to 100 % 100 % 100 % pH 5.0 5.0 5.0
202300074 Foreign Filing 181 Ingredients Detergent 67 Detergent 68 Detergent 69 Hydrogen peroxide 5 5 5 Citric Acid 2 2 2 di-rhamnolipids 10 - - FAEO C12-18, 3 EO 2 2 2 Glucopon 600 2 2 2 SLES 2 2 2 DIETHYLENETRIAMINE 0,1 0,1 0,1 PENTAMETHYLPHOSPHONATE DISODIUM DISTYRYL BIPHENYL 0,2 0,2 0,2 DISULFONATE Add water to Add water to Add water to 100 % 100 % 100 % pH 5.0 5.0 5.0 Ingredients Detergent 70 Detergent 71 Detergent 72 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 persicomycin 0,1 0,1 0,1 SLES 5 5 5 FAEO C12-18, 4 EO 3 3 3 Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 KOH (aqueous solution) 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 73 Detergent 74 Detergent 75 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 SLES 5 5 5 FAEO C12-18, 4 EO 3 3 3 Trilon® M 1 1 1
202300074 Foreign Filing 182 Phenoxyethanol 0.45 0.45 0.45 Triathanolamine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 74 Detergent 75 Detergent 76 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 5 5 5 5 SLES 3EO FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Enzymes cocktail (proteases, amylases, lipases, mannanases, 2 2 2 pecktinases, cellulalase, phosphodiesterases) Add water to Add water to Add water to 100 % 100 % 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent 77 78 79 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Polymers (soil release, dye transfer inhibitors, rheology polymers, anti-redeposition, polycarboxylates, polyacrylates, polyvinyl alcohol, 1 1 1 polyethylene glycol, Polyethyleneimine Ethoxylated) Phenoxyethanol 0.45 0.45 0.45
202300074 Foreign Filing 183 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 80 Detergent 81 Detergent 82 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Solvents (ethanol, glycerine, 10 10 10 1,2-propanediol) Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent 83 84 85 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Builders (phosphonates, Tetrasodium glutamate diacetate, Trisodium dicarboxymethyl alaninate, 1 1 1 monoethanolamine etidronate) Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to Add water to Add water to 100 % 100 % 100 % pH 8.0 8.2 8.1
202300074 Foreign Filing 184 Ingredients Detergent Detergent Detergent 86 87 88 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Miscellaneous (fragrances, preservatives, dyes, pigments, Bitrex, sodium formate, sorbitol, ethoxylated M-toluidyne, antifoaming agent, trimethylsiloxysilicate, defoamers, solvents, Ethanol, 1 1 1 porpylene glycol, monopropalene glycol, etylhexyl stearate, sulfated ethoxylated hexamethylenediamine quaternized, 2-aminoethanol sulfate (salt)) Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.0 8.0 Ingredients Detergent Detergent Detergent 89 90 91 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 5 5 5 SLES 3EO FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Inorganic salts (sodium chloride, magnesium chloride, potassium chloride, potassium sulfite, 0,2 0,2 0,2 sodium sulfite, calcium chloride)
202300074 Foreign Filing 185 Add water to Add water to Add water to 100 % 100 % 100 % pH 8.0 8.2 8.1 Ingredients Detergent 92 Detergent 93 Detergent 94 MEA soap from palm kernel 2 2 2 oil Sodium Citrate 6 6 6 SFX 15 10 20 5 5 5 SLES Trilon® M 1 1 1 Phenoxyethanol 0.45 0.45 0.45 Diethanol amine 1,1 1,1 1,1 Medley® Brilliant 300 L 2 2 2 Add water to 100 Add water to 100 Add water to 100 % % % pH 8.0 8.2 8.1 Ingredients Detergent 95 Detergent 96 Detergent 97 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 Sorbitan Sesquioctanoate 1 1 1 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent 98 99 100 Fatty acid, saturated (Propanoic acid, Butanoic acid, Pentanoic acid, Hexanoic acid, Heptanoic acid, 2 2 2 Octanoic acid, Nonanoic acid, Decanoic acid, Undecanoic acid, Dodecanoic acid, Tridecanoic acid,
202300074 Foreign Filing 186 Tetradecanoic acid, Pentadecanoic acid, Hexadecanoic acid, Heptadecanoic acid, Nonadecanoic acid, Eicosanoic acid) Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 Sorbitan Sesquioctanoate 1 1 1 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent 101 102 103 Fatty acid, unsaturated (myristoleic acid, palmitoleic acid, sapienic acid, oleic acid, elaidic acid, vaccenic acid, linoleic acid, linoelaidic acid, alpha-linolenic 2 2 2 acid, arachidonic acid, erucic acid, docosahexaenoic acid, and eicosapentaenoic acid) Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 104 Detergent 105 Detergent 106 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6
202300074 Foreign Filing 187 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 3 3 3 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 9,5 9,5 9,5 Ingredients Detergent Detergent Detergent 104 105 106 Fatty acid, unsaturated (myristoleic acid, palmitoleic acid, sapienic acid, oleic acid, elaidic acid, vaccenic acid, linoleic acid, linoelaidic acid, alpha-linolenic 6 6 6 acid, arachidonic acid, erucic acid, docosahexaenoic acid, and eicosapentaenoic acid) Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent 107 108 109 Fatty acid, unsaturated (myristoleic acid, palmitoleic acid, sapienic acid, oleic acid, elaidic acid, vaccenic acid, linoleic acid, linoelaidic acid, alpha-linolenic 2 2 2 acid, arachidonic acid, erucic acid, docosahexaenoic acid, and eicosapentaenoic acid) Sodium Citrate 6 6 6
202300074 Foreign Filing 188 SFX 15 10 20 persicomycin 0,1 0,1 0,1 SLES 3EO 5 5 5 FAEO C12-18, 4 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water Add water Add water to 100 % to 100 % to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 110 Detergent 111 Detergent 112 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 FAEO C12-18, 3 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 113 Detergent 114 Detergent 115 Na soap from palm kernel oil 3,85 3,85 3,85 Sodium Citrate 6 6 6 di-rhamnolipids SFX 15 10 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 %
202300074 Foreign Filing 189 pH 8.0 8.2 8.1 Ingredients Detergent 116 Detergent 117 Detergent 118 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 119 Detergent 120 Detergent 121 Na soap from palm kernel oil 3,85 3,85 3,85 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 WeylClean PLA 1 1 1 1 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 122 Detergent 123 Detergent 124 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Texacare SRN 170 Terra 1 1 1 Citric acid 3 3 3
202300074 Foreign Filing 190 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 125 Detergent 126 Detergent 127 Na soap from palm kernel oil 3,85 3,85 3,85 di-rhamnolipids 15 - - mono-rhamnolipids - 15 - glucolipids - - 15 persicomycin 0,1 0,1 0,1 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Na-Carboxymethylinnulin 1 1 1 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 128 Detergent 129 Detergent 130 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 FAEO C12-18, 4 EO 5 5 5 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 131 Detergent 132 Detergent 133 Na soap from palm kernel oil 3,85 3,85 3,85
202300074 Foreign Filing 191 SFX 15 10 20 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 FAEO C12-18, 7 EO 5 5 5 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 134 Detergent 135 Detergent 136 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 137 Detergent 138 Detergent 139 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 6 6 6 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 140 Detergent 141 Detergent 142
202300074 Foreign Filing 192 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 Sophorolipids 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 143 Detergent 144 Detergent 145 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 REWOTERIC AM C 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 146 Detergent 147 Detergent 148 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 Na-Laurylsulfat (C12-18) 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 %
202300074 Foreign Filing 193 pH 8.0 8.2 8.1 Ingredients Detergent 146 Detergent 147 Detergent 148 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 C10C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 149 Detergent 150 Detergent 151 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 C8C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 149 Detergent 150 Detergent 151 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 C8C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 WeylClean PLA 1 1 1 1
202300074 Foreign Filing 194 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 152 Detergent 153 Detergent 154 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 C8C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Aluminium chloride 0,1 0,1 0,1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 152 Detergent 153 Detergent 154 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 10 10 10 C8C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 155 Detergent 156 Detergent 157 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5
202300074 Foreign Filing 195 C10C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Propylene glycol 2 2 2 Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 158 Detergent 159 Detergent 160 MEA cocoate 10 10 10 SFX 15 10 20 SLES 3EO 10 10 10 C10C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Propylene glycol 2 2 2 Trilon M 2 2 2 MEA citrate 5 5 5 Medley® Brilliant 300 L 2 2 2 Phenoxyethanol 1 1 1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent Detergent Detergent 161 162 163 Na soap from palm kernel oil 3,85 3,85 3,85 SFX 15 10 20 SLES 3EO 5 5 5 C10C16-Alkyl polyglucoside 5 5 5 Monoethanolamine 5.95 5.95 5.95 Solvents (rthabnols, mono propylene glycol, 3 3 3 propylene glycol, dipropylene glycol) Trilon M 2 2 2 Citric acid 3 3 3 Medley® Brilliant 300 L 2 2 2
202300074 Foreign Filing 196 Phenoxyethanol 1 1 1 Add water to Add water to Add water to 100 % 100 % 100 % pH 8.0 8.2 8.1 Ingredients Detergent 164 Detergent 165 Detergent 166 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 10 20 SLES 3EO 10 10 10 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.2 8.1 Ingredients Detergent 167 Detergent 168 Detergent 169 Na soap from palm kernel oil 2 2 2 Sodium Citrate 6 6 6 SFX 15 0 10 SLES 3EO 10 10 10 FAEO C12-18, 7 EO 5 5 5 Dissolvine® GLDA 1 1 1 Phenoxyethanol 0.45 0.45 0.45 NaOH (water solution) 1 1 1 Medley® Brilliant 300 L 2 2 2 Manganese sulfate 1 0 1 Aluminium chloride 0 0.1 0.1 Add water to 100 % Add water to 100 % Add water to 100 % pH 8.0 8.1 8.2
Claims
202300074 Foreign Filing 197 Claims 1. Composition comprising A) A) 0.5 wt.-% to 90 wt.%, preferably 3.0 wt.-% to 85 wt.%, even more preferably 15 wt.- % to 80 wt.%, more preferably 25 wt.-% to 75 wt.%, most preferably 40 wt.-% to 70 wt.%, at least one biosurfactant, and B) 0.01 ppm to 500 ppm, preferably 0.1 ppm to 200 ppm, more preferably 1.0 ppm to 50 ppm, most preferably 2.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition. 2. Composition according to claim 1 characterized in that it comprises A) 25 wt.-% to 75 wt.%, more preferably 40 wt.-% to 70 wt.%, at least one biosurfactant, and B) 0.1 ppm to 500 ppm, more preferably 0.5 ppm to 50 ppm, even more preferably 1.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition. 3. Composition according to claim 1 characterized in that it comprises A) 0.5 wt.-% to 25 wt.%, more preferably 1.0 wt.-% to 20 wt.%, most preferably 3.0 wt.-% to 15 wt.%, at least one biosurfactant, and B) 0.01 ppm to 500 ppm, more preferably 0.5 ppm to 50 ppm, even more preferably 1.0 ppm to 19 ppm, manganese ions, wherein the percentages by weight and the parts per million refer to the total composition. 4. Composition according to any of the preceding claims characterized in that said biosurfactant is selected from the group of rhamnolipids, glucolipids and sophorolipids, preferably rhamnolipids and glucolipids, most preferably rhamnolipids. 5. Composition according to any of the preceding claims characterized in that it comprises C) at least one preservative. 6. Composition according to any of the preceding claims characterized in that said preservative is selected from the group comprising, preferably consisting of, p-anisic acid, benzoic acid, levulinic acid, sorbic acid, lactic acid, mandelic acid, salicylic acid, dehydroacetic acid, caprylhydroxamic acid, cinnamic acid, geranic acid, pelargonic acid, and the salts of the aforementioned acids, methylparaben, ethylparaben, phenylpropanol, benzyl alcohol, phenethyl alcohol, phenoxyethanol, propanediol, pentylene glycol, 1,2-hexanediol, caprylyl glycol, undecyl alcohol, methylpropanediol,
202300074 Foreign Filing 198 ethylhexylglycerin, n-octylglycerin, n-heptylglycerin, n-hexylglycerin, methylheptylglycerin, undecylenamidopropyltrimonium methosulfate, isothiazolinones, triethyl citrate, citral, hydroxymethylglycinate, glyceryl caprylate, iodopropynyl butylcarbamat and Sodium Caproyl/Lauroyl Lactylate. 7. A method of stabilizing the colour of a composition comprising a biosurfactant comprising the steps a) providing a composition comprising a biosurfactant, and b) adding manganese to the composition to a concentration of 0.01 ppm to 500 ppm, preferably 0.10 ppm to 200 ppm, more preferably 1.0 ppm to 50 ppm, most preferably 2.0 ppm to 19 ppm, manganese ions, wherein the parts per million refer to the total composition. 8. Method according to claim 7 characterized in that the manganese is added in the form of manganese oxide and/or a manganese salt, preferably as aqueous solution, wherein the oxide is preferably selected from the group of MnO2, Mn3O4, Mn2O3, MnO, Mn2O7 and MnO3 and the salt is preferably selected from the group of MnSO4, MnCl2, Mn(CH3CO2)2, MnCO3, Mn(NO3)2 and manganese gluconate. 9. Method according to claim 7 or 8 characterized in that said biosurfactant is selected from the group of rhamnolipids, glucolipids and sophorolipids, preferably rhamnolipids and glucolipids, most preferably rhamnolipids. 10. Method according to any of the claims 7 to 9 characterized in that said composition comprising a biosurfactant provided in step a) has a Gardner colour value in the range of from 0.01 to 15, preferably of from 0.5 to 8, more preferably 1 to 5. 11. Method according to any of the claims 7 to 10 characterized in that said composition comprising a biosurfactant provided in step a) has an L colour value of the CIELAB colour space in the range of from 20 to 100, preferably of from 30 to 95, more preferably 50 to 90. 12. Use of manganese ions to improve the colour stability of a composition comprising at least one biosurfactant.
202300074 Foreign Filing 199 13. Use of manganese ions to prevent malodour of a composition comprising at least one biosurfactant.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP23180910 | 2023-06-22 | ||
| PCT/EP2024/065749 WO2024260751A1 (en) | 2023-06-22 | 2024-06-07 | Composition comprising biosurfactant and manganese |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4731736A1 true EP4731736A1 (en) | 2026-04-29 |
Family
ID=86942530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP24730384.5A Pending EP4731736A1 (en) | 2023-06-22 | 2024-06-07 | Composition comprising biosurfactant and manganese |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP4731736A1 (en) |
| KR (1) | KR20260027926A (en) |
| CN (1) | CN121399236A (en) |
| WO (1) | WO2024260751A1 (en) |
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| US4933281A (en) | 1987-03-17 | 1990-06-12 | The University Of Iowa Research Foundation | Method for producing rhamnose |
| CA2060698C (en) | 1991-02-12 | 1997-09-30 | Peter J. Hall | Detergent compositions |
| DE4127908A1 (en) | 1991-08-23 | 1993-02-25 | Hoechst Ag | Inducing rhamno:lipid synthesis in Pseudomonas aeruginosa - with glyceric acid ether lipid, to form intermediate for rhamnose which is used in synthesis of chiral cpds. |
| DE19716094A1 (en) * | 1997-04-17 | 1998-10-22 | Henkel Kgaa | Anti-corrosion detergent |
| JP2003013093A (en) | 2001-06-27 | 2003-01-15 | Saraya Kk | Low foaming detergent composition |
| FR2827192B1 (en) | 2001-07-13 | 2004-06-04 | Cognis France Sa | PREPARATIONS CONTAINING NON-IONIC SURFACTANTS AS EXTRACTING AGENTS |
| DE60305861T2 (en) | 2003-01-28 | 2007-01-04 | Ecover N.V. | Detergent compositions |
| JP4858946B2 (en) | 2006-01-10 | 2012-01-18 | 独立行政法人産業技術総合研究所 | Emulsifier or solubilizer |
| US7985722B2 (en) | 2006-07-27 | 2011-07-26 | Aurora Advanced Beauty Labs | Rhamnolipid-based formulations |
| JP5294226B2 (en) | 2006-09-07 | 2013-09-18 | 独立行政法人産業技術総合研究所 | W / O type microemulsion |
| FR2939644B1 (en) * | 2008-12-12 | 2011-02-11 | Oreal | COSMETIC COMPOSITION COMPRISING AT LEAST ONE ORTHODIPHENOL, A METAL SALT, HYDROGEN PEROXIDE, (BI) CARBONATE, A SURFACTANT, METHOD FOR COLORING FROM THE COMPOSITION |
| FR2961398B1 (en) * | 2010-06-16 | 2013-02-15 | Oreal | COSMETIC USE OF A NATURAL EXTRACT FROM RED BEET PEEL, COMPOSITION COMPRISING THE EXTRACT AND A METAL DERIVATIVE, AN OXIDIZING AGENT AND AN ALKALINIZING AGENT |
| DE102013205756A1 (en) | 2013-04-02 | 2014-10-02 | Evonik Industries Ag | Mixture composition containing rhamnolipids |
| DE102013205755A1 (en) | 2013-04-02 | 2014-10-02 | Evonik Industries Ag | Detergent formulation for textiles containing rhamnolipids with a predominant content of di-rhamnolipids |
| EP3023431B1 (en) | 2014-11-19 | 2017-01-04 | Evonik Degussa GmbH | Concentrated, low viscosity rhamnolipid compounds |
| US11696885B2 (en) | 2017-08-24 | 2023-07-11 | Evonik Operations Gmbh | Rhamnolipid derivatives as emulsifiers and dispersing aids |
| WO2019154970A1 (en) | 2018-02-09 | 2019-08-15 | Evonik Degussa Gmbh | Mixture composition comprising glucolipids |
| US20250073149A1 (en) * | 2021-05-05 | 2025-03-06 | Evonik Operations Gmbh | Compositions containing at least one biosurfactant and at least one sulfonic or sulfinic acid derivative |
-
2024
- 2024-06-07 CN CN202480041371.6A patent/CN121399236A/en active Pending
- 2024-06-07 WO PCT/EP2024/065749 patent/WO2024260751A1/en not_active Ceased
- 2024-06-07 EP EP24730384.5A patent/EP4731736A1/en active Pending
- 2024-06-07 KR KR1020257042329A patent/KR20260027926A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2024260751A1 (en) | 2024-12-26 |
| KR20260027926A (en) | 2026-03-03 |
| CN121399236A (en) | 2026-01-23 |
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