EP4683973A2 - Dispersant compositions comprising hydrophobic and hydrophilic modified maleated natural oils, and applications thereof - Google Patents

Dispersant compositions comprising hydrophobic and hydrophilic modified maleated natural oils, and applications thereof

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Publication number
EP4683973A2
EP4683973A2 EP24775726.3A EP24775726A EP4683973A2 EP 4683973 A2 EP4683973 A2 EP 4683973A2 EP 24775726 A EP24775726 A EP 24775726A EP 4683973 A2 EP4683973 A2 EP 4683973A2
Authority
EP
European Patent Office
Prior art keywords
maleated
composition
dispersant composition
oils
coatings
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP24775726.3A
Other languages
German (de)
French (fr)
Inventor
Seong Gan HAN
Donald I. Prettypaul
Osama M. Musa
Hani M. Fares
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ISP Investments LLC
Original Assignee
ISP Investments LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ISP Investments LLC filed Critical ISP Investments LLC
Publication of EP4683973A2 publication Critical patent/EP4683973A2/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/062Oil-in-water emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/064Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12Face or body powders for grooming, adorning or absorbing
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00Manicure or pedicure preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/45Anti-settling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/002Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/52Natural or synthetic resins or their salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/04Fatty oil fractions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42Colour properties
    • A61K2800/43Pigments; Dyes

Definitions

  • compositions comprising modified maleated natural oils. Further, the present application provides use of these compositions as wetting agents and dispersing agents in personal care, coatings, agriculture, and pharmaceuticals. BACKGROUND OF THE INVENTION [0002] Modified natural oils can be non-dispersible in water or alcohols. As a result, these oils can be incorporated into a wide variety of compositions.
  • Natural oils are generally blends of different triglycerides, the esterification product of fatty acids and glycerol, and contain varying degrees of unsaturation (i.e., double bonds). Oils can be characterized by a hydroxyl value and the fatty acid compositions. Both natural fatty acids and natural oils must be chemically modified to make them sufficiently reactive to allow structural alterations and polymerizations to occur because the olefin functional groups are relatively unreactive. Unsaturated double bonds in these compounds have been converted to epoxide functional groups and succinic anhydride functional groups, allowing the addition of many hydroxyl containing species to be introduced into the natural oils.
  • Maleated natural oils are natural oils that have been chemically functionalized by the chemical addition of epoxide (oxirane) and succinic anhydride functional groups. Examples include epoxidized and maleated soybean oil and linseed oil, unsaturated natural oils lend themselves to this chemical functionalization.
  • Dispersing agents are commonly used to wet out the dry filler during mixing, reduce the viscosity and make the formulation more workable. Numerous dispersing agents are available in the market. One such example are pigments which are traditionally milled and sold as powders or as dispersion in solvent.
  • PCT Application WO2019/113068A1 (assigned to) and WO2005/071050A1 (assigned to) describes a technology related to metalworking fluids comprising maleated soybean oil derivatives.
  • PCT Application WO2021252426A1 assigned to Sun Chemical Corporation discloses a solid pigment dispersion comprising one or more pigments approved for cosmetic use and a combination of one or more oils and/or waxes that are plant-based wherein the dispersion is in the form of a dry powder.
  • US granted patent US10836910B2 assigned to Sherwin Williams Co.
  • concentrate for use in the manufacture of fluid colorants or finished coating compositions, wherein at least 95 wt.% of the concentrate is a mixture of (i) solid pigment particles with (ii) a non-volatilizing, reactive liquid diluent having a viscosity less than 1,000 cps, and comprising at least 60 wt.% of one or more molecular species having at least three reactive unsaturated sites and having a molar equivalent weight per reactive unsaturated site that is less than 500 grams (g), wherein when the reactive liquid diluent does not by itself stably disperse the pigment particles then the concentrate also contains (iii) one or more pigment wetting or dispersing agents.
  • the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof.
  • the present application provides a dispersant composition for personal care, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the present application provides a dispersant composition for color cosmetics, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the present application provides a dispersant composition
  • a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (B) 2 to 70 wt.% of at least one solid particulate component.
  • the present application provides a dispersant composition
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety.
  • the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base,
  • the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base,
  • the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base
  • the present application provides a dispersant composition for personal care, the composition comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (c) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (B) from about 1.0 to about 90.0 wt.% of one or more personal care active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient.
  • A from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (c)
  • the present application provides a dispersant composition for personal care application comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide and mixtures thereof; and (c) 2-octyldodecyl alcohol, glycerol, or combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the 2-octyldodecyl alcohol or glycerol; (B) from about 1.0 to about 90.0 wt.% of one or more agricultural active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient.
  • A from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil, comprising
  • the present application provides a dispersant composition
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base.
  • the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at
  • the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at
  • the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii)
  • the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base.
  • a dispersant composition for coatings the composition comprising: (a) least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base; and (b) a particulate compound.
  • the present application provides a dispersant composition for personal care, the composition comprising: (a) least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base; and (b) a particulate compound.
  • a dispersant composition for color cosmetics the composition comprising: (a) least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base; and (b) a particulate compound.
  • the present application provides a dispersant composition
  • a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (B) 2 to 70 wt.% of at least one particulate component.
  • alkyl refers to a functionalized or unfunctionalized, monovalent, straight-chain, branched-chain, or cyclic C 1 -C60 hydrocarbyl group optionally having one or more heteroatoms.
  • an alkyl is a C 1 -C45 hydrocarbyl group.
  • an alkyl is a C 1 - C30 hydrocarbyl group.
  • Non-limiting examples of alkyl include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl, isopentyl, n-hexyl, n- heptyl, n-octyl, 2-ethylhexyl, tert-octyl, iso-norbornyl, n-dodecyl, tert-dodecyl, n-tetradecyl, n- hexadecyl, n-octadecyl, n-eicosyl, cyclobutyl, cyclopentyl, cyclohexyl, and the like.
  • alkyl also includes groups obtained by combinations of straight-chain, branched- chain and/or cyclic structures.
  • aryl refers to a functionalized or unfunctionalized, monovalent, aromatic hydrocarbyl group optionally having one or more heteroatoms.
  • the definition of aryl includes carbocyclic and heterocyclic aromatic groups.
  • Non-limiting examples of aryl groups include phenyl, naphthyl, indenyl, indanyl, azulenyl, fluorenyl, anthracenyl, furyl, thienyl, pyridyl, pyrrolyl, oxazolyl, thiazolyl, imidazolyl, pyrazolyl, 2-pyrazolinyl, pyrazolidinyl, isoxazolyl, isothiazolyl, 1,2,3-oxadiazolyl, 1,2,3-triazolyl, 1,3,4-thiadiazolyl, pyridazinyl, pyrimidinyl, pyrazinyl, 1,3,5-triazinyl, 1,3,5-trithianyl, indolizinyl, indolyl, isoindolyl, 3H-indolyl, indolinyl, benzo[b]furanyl, 2,3-dihydrobenz
  • aralkyl refers to an alkyl group comprising one or more aryl substituent(s) wherein "aryl” and “alkyl” are as defined above.
  • Non-limiting examples of aralkyl groups include benzyl, 2-phenyl-ethyl, 3-phenyl-propyl, 4-phenyl-butyl, 5-phenyl-pentyl, 4-phenylcyclohexyl, 4- benzylcyclohexyl, 4-phenylcyclohexylmethyl, 4-benzylcyclohexylmethyl, and the like.
  • alkylene refers to a functionalized or unfunctionalized, divalent, straight-chain, branched-chain, or cyclic C 1 -C40 hydrocarbyl group optionally having one or more heteroatoms.
  • an alkylene is a C 1 -C30 group.
  • an alkylene is a C 1 -C20 group.
  • Non-limiting examples of alkylene groups include: [0044]
  • arylene refers to a functionalized or unfunctionalized, divalent, aromatic hydrocarbyl group optionally having one or more heteroatoms. The definition of arylene includes carbocyclic and heterocyclic groups.
  • Non-limiting examples of arylene groups include phenylene, naphthylene, pyridinylene, and the like.
  • branched and unbranched alkyl groups refers to alkyl groups, which may be straight chained or branched. Branched groups include isopropyl, tert-butyl, and the like.
  • the words “comprising” (and any form of comprising, such as “comprise” and “comprises”), “having” (and any form of having, such as “have” and “has”), “including” (and any form of including, such as “includes” and “include”) or “containing” (and any form of containing, such as “contains” and “contain”) are inclusive or open-ended and do not exclude additional, unrecited elements or method steps.
  • the term “dispersing agent” as used herein refers to a “substance added to a suspension to improve the separation of particles and to prevent settling or clumping.
  • the hydrophobic moiety and the hydrophilic moiety is a hydrocarbyl alcohol, a hydrocarbyl amine, a silicon-based compound, or a combination thereof.
  • Hydrocarbyl alcohols are classified as primary, secondary and tertiary alcohols, based on the number of carbon atoms connected to the carbon atom that bears the hydroxyl group. Each classification of alcohol may have a general formula.
  • the general formula for primary alcohols is the general formula for secondary alcohols is and the general formula for tertiary alcohols is wherein R, R′ and R′′ stand for hydrogen, different alkyl, alkylene, aryl, aralkyl, arylene, heteroatom groups.
  • hydrophilic moieties are relative terms, where a hydrophilic moiety it has a higher affinity for water than a hydrophobic moiety, but the hydrophilic moiety may or may not be completely water soluble. Likewise, hydrophobic moieties have less of an affinity for water than hydrophilic moieties, but the hydrophobic moieties may not necessarily be water-repellant. While hydrophilic moieties have an affinity for water and other polar solvents, hydrophobic moieties tend to have an affinity for oils, fats, and other non-polar solvents.
  • the term “functional ingredient” refers to any ingredient that provides pharmacological activity or other direct effect in the diagnosis, cure, mitigation, treatment, or prevention of disease, or affects the structure or any function of the body of man or animals.
  • the functional ingredient may be present either in a personal care product, a coating product, or an agriculture product.
  • the personal care ingredient includes, but is not limited to, analgesics, anesthetics, antibiotic agents, antifungal agents, antiseptic agents, antidandruff agents, antibacterial agents, vitamins, hormones, antidiarrhea agents, corticosteroids, anti-inflammatory agents, vasodilators, kerolytic agents, dry-eye compositions, wound-healing agents, anti-infection agents, as well as solvents, diluents, adjuvants and other ingredients such as water, mineral oils, preservatives, surfactants, propellants, fragrances, essential oils, and viscosifying agents.
  • analgesics such as water, mineral oils, preservatives, surfactants, propellants, fragrances, essential oils, and viscosifying agents.
  • Non-limiting examples of functionalization reactions include: alkylation, epoxidation, sulfonation, hydrolysis, amidation, esterification, hydroxylation, dihydroxylation, amination, ammonolysis, acylation, nitration, oxidation, dehydration, elimination, hydration, dehydrogenation, hydrogenation, acetalization, halogenation, dehydrohalogenation, Michael addition, aldol condensation, Cannizzaro reaction, Mannich reaction, Clasien condensation, Suzuki coupling, and the like.
  • the term “functionalized” with reference to any moiety refers to the presence of one more functional group selected from the groups consisting of alkyl, alkenyl, hydroxyl, carboxyl, halogen, alkoxy, amino, imino, and combinations thereof, in the moiety.
  • the term “maleated natural oil”, as used herein, refers to natural oil contains at least one or more maleated functionalities. Accordingly, the term “maleation” or “maleated” as used hereafter should be understood to mean “functionalization” insofar as the use of functionalizing reagents other than maleic anhydride are contemplated for use in the process of the invention.
  • the term “moiety” or “moieties” refer to a part or a functional group(s) of a molecule.
  • the term “natural oil” refers to compounds comprising triglycerides and may contain varying levels of fatty acids, monoglycerides, diglycerides and triglycerides refer to oil derived from plants or animal sources. Natural oils also include fatty acid glyceryl esters, which are synthesized by reacting glycerol with 1, 2, or 3 molar equivalents of a fatty acid or a mixture of fatty acids. These compounds can be mono, di or triglycerides of a single fatty acid or a mixture of fatty acids.
  • polymer refers to a compound comprising repeating structural units (monomers) connected by covalent chemical bonds. Polymers may be further derivatized, crosslinked, grafted or end-capped. Non-limiting examples of polymers include copolymers, terpolymers, tetrapolymers, quaternary polymers, and homologues.
  • copolymer refers to a polymer consisting essentially of two or more different types of monomers polymerized to obtain said copolymer.
  • reaction product refers to a substance or substances produced from a chemical reaction of one or more reactant substances.
  • the term “soybean oil ester” as used herein refers to a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol.
  • the term "sequestering agent” or “chelating agent” as used herein relates to a compound which is capable of bonding or complexing a metal ion between two or more atoms of the compound, thereby neutralizing, or controlling harmful effects of such metal ions. Wherein holding or bonding of a metal ion is through combination of one or more different types of bonds including coordination and/or ionic bonds.
  • the term “unreacted maleated functionality” refers to refers to present of an unreacted maleic anhydride compound or functionality in the reaction product of this invention, wherein, the maleated functionality are completely unreacted and intact.
  • the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof.
  • the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated almond oils, maleated coconut oils, maleated corn oils, maleated canola oils, maleated cottonseed oils, maleated flaxseed oils, maleated grapeseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated walnut oils, and mixtures thereof.
  • the maleated natural oil is a maleated soybean oil.
  • the hydrophobic alcohol is selected from the group consisting of heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tertradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2-propyl-1- pentanol, 4-methyl-1-pentanol, and mixtures thereof
  • hydrophobic amine is selected from the group consisting of benzylamine, cyclohexylamine, hexylamine, methylhexylamine, phenethylamine, octylamine, oleylamine, decylamine, dodecylamine, octadecylamine, undecyl amine
  • the hydrophilic moiety is a moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C 1 to about C5 atoms, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl amines, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C 1 to about C 5 atoms, unsubstituted or substituted polyols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C 2 to about C 36 atoms, silanes, and combinations thereof.
  • the hydrophilic alcohol is selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxy polyethylene glycol, polypropylene glycol, hexylene glycol, sorbitol, neopentylglycol, eythritol, mannitol, xylitol, threitol, pentaerythritol, beta-cyclodextrin, L-Ribose, 2-deoxy-D-galactose, and mixtures thereof, and the hydrophilic amine is selected from the group consisting of 2-methylpentane-1,5-diamine, diethanol amine, diisopropanol amine, serinol hydrochloride, 2-amino-2-ethyl, 2-methylp
  • the silane is functionalized with an alcohol or an amine, and combinations thereof.
  • the hydrophobic alcohol is selected from the group consisting of heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tertradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2- propyl-1-pentanol, 4-methyl-1-pentanol, and mixtures thereof.
  • the hydrophilic alcohol is selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxypolyethylene glycol, polypropylene glycol, hexylene glycol, sorbitol, neopentylglycol, eythritol, mannitol, xylitol, threitol, pentaerythritol, beta-cyclodextrin, L-Ribose, 2-deoxy-D-galactose, and mixtures thereof.
  • the second one is a radical addition, which consumes a double bond in the fatty acid, incorporating the succinic anhydride into the natural oil structure.
  • the maleinized natural oil can be reacted with hydrophobic moiety and the hydrophilic moiety of a hydrocarbyl alcohol, a hydrocarbyl amine, a silicon-based compound forming a reticulated structure (see examples). This kind of reaction has been applied at the reaction occurred by heating 6-10 hours at 210 o C.
  • the suitable range of a reaction product of a maleated natural oil and one or more functionalized or unfunctionalized moieties selected from a hydrophobic moiety, a hydrophilic moiety or a combination can be varied from about 0.01 wt.% to about 0.1 wt.%, from about 0.1 wt.% to about 1 wt.%, or from about 1 wt.% to about 5wt.%, or from about 5 wt.% to about 10 wt.% based on the total weight of the aqueous personal care composition.
  • the dispersing agent / wetting agent for the current composition can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.
  • the dispersing agent is present in an amount of from 0.1 to 90 wt.% of the total dispersant composition.
  • the dispersant composition further comprises at least one particulate component.
  • the particulate component is a solid selected from the group consisting of pigments for personal care, architectural and industrial coatings; extenders and fillers for paints and plastics materials; optical brightening agents for paper; textile auxiliaries for solvent dyebaths and inks; particulate ceramic materials; magnetic particles for use in magnetic recording media; organic solid biocides for agrochemicals and pharmaceuticals; solid particulates for food and preservatives; and solid polymeric surfactants for home care.
  • particulate components include graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
  • the particulate component can be an organic solid biocide selected from the group consisting of fungicides, insecticides, bactericides, and herbicides.
  • the suitable range of solid particulate component for the current composition can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.
  • the particulate component is present in an amount of from 0.1 to 70 wt.% of the total dispersant composition.
  • the particulate component is selected from the group consisting of pigments for personal care, architectural and industrial coatings; extenders and fillers for paints and plastics materials; optical brightening agents for paper; textile auxiliaries for solvent dyebaths and inks; particulate ceramic materials; magnetic particles for use in magnetic recording media; organic solid biocides for agrochemicals and pharmaceuticals; solid particulates for food and preservatives; and solid polymeric surfactants for home care.
  • the particulate component is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
  • the present dispersant composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
  • esters include isotridecyl isononanoate, polyethylene glycol diheptanoate, isostearyl neopentanoate, tridecyl neopentanoate, cetyl octanoate, cetyl palmitate, cetyl ricinoleate, cetyl stearate, cetyl myristate, isopropyl myristate, coco-dicaprylate/caprate, decyl isostearate, isodecyl oleate, isodecyl neopentanoate, isohexyl neopentanoate, octyl palmitate, dioctyl malate, tridecyl octanoate, myristyl myristate, octododecanol, and fatty alcohols such as oleyl alcohol, isocetyl alcohol.
  • Non-limiting examples of oils include glyceryl esters of fatty acids, or triglycerides, such as castor oil, lanolin oil, triisocetyl citrate, C10-18 triglycerides, caprylic/capric/triglycerides, coconut oil, mineral oil, almond oil, apricot kernel oil, avocado oil, babassu oil, evening primrose oil, camelina sativa seed oil, grape seed oil, macadamia ternifolia seed oil, com oil, meadowfoam seed oil, mink oil, olive oil, palm kernel oil, safflower oil, sesame oil, soybean oil, sunflower oil, wheat germ oil and camellia reticulata seed oil.
  • glyceryl esters of fatty acids such as castor oil, lanolin oil, triisocetyl citrate, C10-18 triglycerides, caprylic/capric/triglycerides, coconut oil, mineral oil, almond oil, apricot kernel oil
  • glyceryl esters (excluding fats and oils which are glyceryl esters of fatty acids) which are primarily fatty acid mono-, di-, and triglycerides which are modified by reaction with other alcohols, for example, acetylated castor oil, glyceryl stearate, glyceryl dioleate, glyceryl distearate, glyceryl trioctanoate, glyceryl distearate, glyceryl linoleate, glyceryl myristate, glyceryl isostearate, PEG castor oils, PEG glyceryl oleates, PEG glyceryl stearates and PEG glyceryl tallowates.
  • acetylated castor oil glyceryl stearate, glyceryl dioleate, glyceryl distearate, glyceryl trioctanoate, glyce
  • non-volatile hydrocarbons such as isoparaffins, hydrogenated polyisobutene, mineral oil and squalene.
  • various lanolin derivatives such as acetylated lanolin, acetylated lanolin alcohol, and various fluorinated oils, such as fluoro Guerbet esters or perfluropolyethers.
  • Suitable oils include sorbitan derivatives such as PEG sorbitan beeswax, PEG sorbitan isostearate, PEG sorbitan lanolate, PEG sorbitan laurate, PEG sorbitan oleate, PEG sorbitan palmitate, PEG sorbitan stearate, polysorbates, sorbitan trioleates, sorbitan sesquioleates, sorbitan stearates, and sorbitan tristearates.
  • PEG sorbitan derivatives such as PEG sorbitan beeswax, PEG sorbitan isostearate, PEG sorbitan lanolate, PEG sorbitan laurate, PEG sorbitan oleate, PEG sorbitan palmitate, PEG sorbitan stearate, polysorbates, sorbitan trioleates, sorbitan sesquioleates, sorbitan stearates, and sorbit
  • Non-limiting examples of alcohols include isostearyl alcohol, oleyl alcohol, octyl dodecanol, octyl alcohol, decyl alcohol, arachyl alcohol, hexyl decanol, chimyl alcohol, ⁇ -glucan, cholesterol, sitosterol, dihydrocholesterol, stearyl alcohol, cetanol, cetostearyl alcohol, phytosterol, hexyl decanol, behenyl alcohol, lauryl alcohol, lanolin alcohol, and myristyl alcohol, polyhydric alcohols such as erythritol, glycerol, xylitol, diglycerol, dipropylene glycol, sorbitol, trehalose, 1,3-butylene glycol, propylene glycol, 1,2-pentanediol, polyethylene glycol, polyoxyethylene glycerol, polypropylene, polyoxypropylene glyceryl
  • the liquid component is selected from the group consisting of soya methyl ester, rapeseed oil methyl ester, methyl tallowate, methyl oleate, butyl stearate, butyl oleate, 2-ethylhexyl oleate, ethylhexyl palmitate, ethylhexyl stearate, ethylhexyl cocoate, isotridecyl stearate, isodecyl neopentanoate, tridecyl neopentanoate, octyl dodecyl stearoyl stearate, castor oil, polyhydroxy stearic acid, and C12-15 alkyl benzoate.
  • the suitable range of liquid component for the current dispersant composition can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.
  • the liquid component is present in an amount of from about 2% to about 90 wt.% of the total weight of the dispersant agent.
  • the dispersant composition find its application in agricultural compositions, biocidal compositions, cleaning compositions, coating compositions, cosmetic compositions, construction compositions, disinfecting compositions, energy compositions, food compositions, hair care compositions, homecare compositions, industrial and institutional compositions, laundry compositions, nutraceutical composition, oral care compositions, pharmaceuticals compositions, preservative compositions, skin care compositions, textile compositions.
  • the dispersant composition is a personal care composition, an industrial coating composition, a food coating composition, a pharmaceutical coating composition, and an agricultural coating composition.
  • the dispersant composition is a used for lacquer coating, primer coating, ink jet printing, top coating, varnish coating, architectural coating, wood coating, printing inks or metallic or non-metallic coating.
  • the dispersant composition is a the composition is coated on a substrate selected from the group consisting of porous and non-porous substrates, papers, non-woven materials, textiles, leather, wood, concrete, masonry, metals, non-metals, house wrap, building materials, fiberglass, polymeric articles, face masks, medical drapes and gowns, carpets, upholstery, tents, awnings, air bags, fabrics, ceramics, yarns, and blends, woven, knitted, natural, synthetic, and regenerated substrates.
  • the dispersant composition for personal care may be a formulation selected from the group consisting of sprays, lotions, mousses, fluids, serums, solutions, suspensions, perms, emulsions, gels, mists, vesicles, dispersions, pastes, creams, solid sticks, shampoos, balms, wipes, milks, foams, jellies, liquids, a foundation, a long wear intense lipstick, a clay mask, a volume curling mascara, a carbon black mascara, a pressed powder, a blush, a lip gloss, an eye shadow, a SPF fluid shake.
  • the present application provides a dispersant composition for coatings, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
  • the dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol.
  • the solid particulate is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
  • the present application provides a dispersant composition
  • a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (B) 2 to 70 wt.% of at least one particulate component.
  • the silicon-based compound is a hydrophobic compound selected from the group consisting of aminopropyl methylsiloxane–dimethylsiloxane, N-ethylamino isobutyl terminated polydimethyl siloxane, poly(1,1-dimethylsilazane) telomer, aminopropyl terminated polydimethyl siloxane, monoamino propyl terminated polydimethyl siloxane, (tetramethyl piperidinyloxy) propylmethyl siloxane]-dimethyl siloxane copolymer, polydimethylsiloxane, carbinol (hydroxyl) terminated polydimethylsiloxane, monocarbinol terminated polydimethylsiloxane, monocarbinol terminated functional polydimethylsiloxane, [Bis(hydroxyethyl)amine] terminated polydimethylsiloxane, silanol terminated polyd
  • the preferences listed for the invention set out above for a “dispersant composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention.
  • the dispersant compositions may be selected from the group consisting of skin care compositions, oral care compositions, hair care compositions, energy compositions, construction compositions, biocidal compositions, preservative compositions, nutraceutical compositions, food compositions, agricultural compositions, coating compositions, cosmetic compositions, homecare compositions, industrial and institutional compositions, textile compositions, laundry compositions, cleaning compositions, and disinfecting compositions.
  • the present application provides a dispersant composition for personal care, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the invention provides a skin care composition
  • a skin care composition comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a functionalized or unfunctionalized hydrophobic moiety; and (c) a glycerol moiety; and (B) a skin care functional ingredient.
  • a “composition comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a functionalized or unfunctionalized hydrophobic moiety; (c) a glycerol moiety; and (B) a functional ingredient” also apply to this aspect of the invention.
  • composition may be present in an amount of (A) in an amount of from about 0.01% to about 10% and (B) is present in an amount of from about 90% to about 99.99%.
  • the skin care functional ingredient is selected from the group consisting of color agents, hair care agents, skin care agents, and sun care agents.
  • the present application provides a dispersant composition for color cosmetics, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • the skin care functional ingredient is a formulation selected from the group consisting of sprays, lotions, mousses, fluids, serums, solutions, suspensions, perms, emulsions, gels, mists, vesicles, dispersions, pastes, creams, solid sticks, shampoos, balms, wipes, milks, foams, jellies, and liquids.
  • the present application provides compositions comprising a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) two functionalized or unfunctionalized hydrophilic moieties.
  • compositions comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) two functionalized or unfunctionalized hydrophilic moieties; and (B) a functional ingredient.
  • the hydrophobic moiety hydrocarbyl alcohol contains C 2 to C36 carbon atoms and is linear, branched, saturated, unsaturated, aliphatic, aromatic, monofunctional or multifunctional.
  • the hydrocarbyl alcohol is selected from the group consisting of monohydric alcohols, dihydric alcohols, polyhydric alcohols, and combinations thereof.
  • the hydrocarbyl amine is selected from the group consisting of primary amines, secondary amines, and combinations thereof.
  • Hydrocarbyl amines are classified as primary, secondary and tertiary alcohols, based on the number of carbon atoms connected to the carbon atom that bears the hydroxyl group.
  • Each classification of alcohol may have a general formula.
  • the general formula for primary amine is and the general formula for secondary amine is wherein R, R′ stand for hydrogen, different alkyl, alkylene, aryl, aralkyl, arylene, heteroatom groups.
  • the hydrophobic moiety hydrocarbyl amine contains C 2 to C36 carbon atoms and is linear, branched, saturated, unsaturated, aliphatic, aromatic, monofunctional or multifunctional.
  • the silicon-base compound is a wherein R stands for different alkyl, alkylene, aryl, aralkyl, arylene, hetero groups functionalized with at least one or more alcohol, an amine, or a combination thereof and n has the value of 1 to 10.
  • the silicon-base compound is a siloxane, or a silane functionalized with an alcohol, an amine, or a combination thereof.
  • the silicon-based compound is a linear, branched, saturated, unsaturated, aliphatic, aromatic, monofunctional or multifunctional compound.
  • the hydrocarbyl alcohol is selected from the group consisting of monohydric alcohols, dihydric alcohols, polyhydric alcohols, and combinations thereof.
  • the hydrocarbyl alcohol is a hydrophobic alcohol selected from the group consisting of propanol, butanol, pentanol, heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tertradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2-propyl-1-pentanol, 4-methyl-1- pentanol and mixtures thereof.
  • the hydrocarbyl alcohol is a hydrophilic alcohol selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxypolyethylene glycol, polypropylene glycol, hexylene glycol, glycerol, sorbitol, octanol, methyl ethyl pentanol, trimethyl pentanol, ethyl hexanol, methyl heptanol, nonanol, methyl octanol, ethyl heptanol, methyl ethyl hexanol, cyclohexanol, dimethyl heptanol, decanol, methyl nonanol, ethyl oc
  • the hydrocarbyl amine is hydrophobic amine selected from the group consisting of benzylamine, cyclohexylamine, hexylamine, methylhexylamine, phenethylamine, octylamine, oleylamine, decylamine, dodecylamine, octadecylamine, undecyl amine, pentadecyl amine, 2-methyl butyl amine, dimethyl amine, and mixtures thereof.
  • the hydrocarbyl amine is hydrophilic amine selected from the group consisting of 2-methylpentane-1,5-diamine, diethanol amine, diisopropanolamine, serinol hydrochloride, 2-amino-2-ethyl-1, 3-propanediol, N-methyl-D-glucosamine, D- galactosamine hydrochloride, D-glucosamine hydrochloride, D-mannosamine hydrochloride and mixtures thereof.
  • the silicon-based compound is hydrophilic compound selected from the group consisting of 3-aminopropylsilanetriol, N-(2-aminoethyl)-3- aminopropylsilanetriol and mixtures thereof.
  • the maleated natural oil is selected from the group consisting of a maleated avocado oil, a maleated coconut oil, a maleated corn oil, a maleated cottonseed oil, a maleated jojoba oil, a maleated linseed oil, a maleated nut oil, a maleated olive oil, a maleated palm oil, a maleated raisin oil, a maleated rapeseed oil, a maleated safflower oil, a maleated sesame oil, a maleated soybean oil, a maleated squash oil, a maleated sunflower oil, a maleated almond oil, a maleated canola oil, a maleated flaxseed oil, a maleated grapeseed oil, a maleated palm oil, a maleated palm kernel oil, a maleated peanut oil, and a maleated walnut oil thereof.
  • a maleated avocado oil a maleated coconut oil, a maleated corn oil, a maleated cottonseed oil, a maleated jojoba oil,
  • the present application provides a dispersant composition for coatings comprising (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention.
  • the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
  • the dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol.
  • the dispersant composition for coatings can be used in architectural coatings, metal coatings, marine coatings, paints, decorative paints, interior paints, exterior paints, non-woven coatings, ceramic coatings, anti-corrosion coatings, flame retardant coatings, glass coatings, protective coatings, powder coatings, wood coatings, industrial coatings, anti-fouling coatings, thermal insulation coatings, water-based coatings, and solvent based coatings.
  • the present application provides a dispersant composition for personal care comprising (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component.
  • composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention.
  • the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
  • the dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol.
  • the dispersant composition for personal care can an emulsion selected from oil-in-water emulsion and water-in-oil emulsion.
  • at least one personal care functional ingredient selected from the group consisting of surfactants, water-insoluble ingredients, oxidizing agents, conditioning agents, humectants, pH adjusting buffers, waxes, mineral oils, emulsifiers, fatty substances, gelling agents, thickeners, emollients, hydrophilic or lipophilic active agent, antioxidants, sequestering agents, preserving agents, acidifying or basifying agents, fragrances, fillers, dyestuffs, plant extracts, moisturizers, proteins, peptides, neutralizing agents, solvents, anti-dandruff ingredients, reducing agents and combinations thereof.
  • the suitable range of personal care ingredient for the present application can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.%;
  • Preferably personal care composition is a cosmetic care composition specifically applied to skin, nail and hair.
  • at least one primary surfactant, co-surfactant or a system of surfactants comprising at least one primary surfactant and at least one co-surfactant are employed to prepare sun care or skin care compositions, and wherein said primary surfactants, co-surfactants or a system surfactant can be selected from the group consisting of anionic surfactants, cationic surfactants, non-ionic surfactants, zwitterionic surfactants and amphoteric surfactants.
  • the range of surfactants can be from 0.1 wt.% to 20 wt.% based on the total weight of the composition.
  • Anionic surfactants are particularly useful in accordance with certain embodiments of the present application.
  • Surfactants of the anionic type include: (1) Sulfonates and Sulfates: Suitable anionic surfactants include sulfonates and sulfates such as alkyl sulfates, alkylether sulfates, alkyl sulfonates, alkylether sulfonates, alkylbenzene sufonates, alkylbenzene ether sulfates, alkylsulfoacetates, secondary alkane sulfonates, secondary alkylsulfates, alkyl sulfosuccinates and the like.
  • sulfonates and sulfates such as alkyl sulfates, alkylether sulfates, alkyl sulfonates, alkylether sulfonates, alkylbenzene sufonates, alkylbenzene ether sulfates, alkylsulfoacetates, secondary alkane s
  • anionic surfactants include water-soluble salts of higher fatty acid monoglyceride monosulfates, such as the sodium salt of the monosulfated monoglyceride of hydrogenated coconut oil fatty acids, higher alkyl sulfates such as sodium lauryl sulfate, alkyl aryl sulfonates such as sodium dodecyl benzene sulfonate, higher alkyl sulfoacetates, higher fatty acid esters of 1,2-dihydroxy propane sulfonate, and the substantially saturated higher aliphatic acyl amides of lower aliphatic amino carboxylic acid compounds, such as those having 12 to 16 carbons in the fatty acid, alkyl or acyl radicals, and the like.
  • higher alkyl sulfates such as sodium lauryl sulfate
  • alkyl aryl sulfonates such as sodium dodecyl benzene sulfonate
  • Suitable anionic surfactants also include phosphates such as alkyl phosphates, alkylether phosphates, aralkylphosphates, and aralkylether phosphates.
  • phosphates such as alkyl phosphates, alkylether phosphates, aralkylphosphates, and aralkylether phosphates.
  • examples include a mixture of mono-, di- and tri-(alkyltetraglycolether)-o-phosphoric acid esters generally referred to as trilaureth-4-phosphate commercially available under the trade designation HOSTAPHAT 340KL from Clariant Corp., as well as PPG-5 ceteth 10 phosphate available under the trade designation CRODAPHOS SG from Croda Inc., Parsipanny, NJ.
  • amphoterics examples include but are not limited to certain betaines such as cocobetaine and cocamidopropyl betaine; monoacetates such as sodium lauroamphoacetate; diacetates such as disodium lauroamphoacetate; amino- and alkylamino-propionates such as lauraminopropionic acid.
  • Ammonium Sulfonate Amphoterics These classes of amphoteric surfactants are often referred to as "sultaines" or "sulfobetaines” for example, cocamidopropylhydroxysultaine.
  • Acidic pH adjusting agents can be organic acids, including amino acids, and inorganic mineral acids.
  • Non-limiting examples of acidic pH adjusting agents include acetic acid, citric acid, fumaric acid, glutamic acid, glycolic acid, hydrochloric acid, lactic acid, nitric acid, phosphoric acid, sodium bisulfate, sulfuric acid, tartaric acid, and the like, and mixtures thereof.
  • the desired pH of the personal care composition is in the range of from about 2 to about 13, and in some embodiment, it is preferably between about 4 to about 8.
  • the utility levels of the pH modifying agent can be present in an effective amount required to achieve the desired pH level.
  • the coloring agents, colorants or dyes used herein include natural foods colors and dyes suitable for food, drug and cosmetic applications.
  • colorants are also known as FD & C, and D&C dyes and lakes and are preferably water-soluble in nature.
  • FD&C and D&C dyes and lakes are preferably water-soluble in nature.
  • These coloring agents may be incorporated in amount up to about 3%, more particularly up to about 2%, and in some cases less than about 1% by weight of the personal care compositions.
  • a perfume or fragrance obtained from natural or synthetic source can be employed in the present skin/sun care composition.
  • the fragrance can be used along with a suitable solvent, diluents or carrier.
  • Fragrances may be added in any conventionally known method, for example, admixing to a composition or blending with other ingredients used to form a composition, in amounts which are found to be useful to increase or impart the desired scent characteristics to the disinfectant or cleaning compositions.
  • Fragrances for the present application can be one or more selected from the following non-limiting group of compounds such as essential oils, absolutes, resinoids, resins, concretes, hydrocarbons, alcohols, aldehydes, ketones, ethers, acids, esters, acetals, ketals, nitriles, including saturated and unsaturated compounds and aliphatic, carbocyclic, and heterocyclic compounds.
  • Suitable sunscreens which can be formulated into the compositions of the instant invention are those selected from among: methoxydibenzoyl methane; octyl salicylate; pentyl dimethyl PABA; octyl dimethyl PABA; benzophenone-1; benzophenone-6; 2-(2H-benzotriazole-2-yl)-4,6- di-tert- pentylphenol; ethyl-2-cyano-3,3-diphenylacrylate; homomethyl salicylate (homosalate); bis-ethylhexyloxyphenol methoxyphenyl triazine; methyl-(l,2,2,6,6-pentamethyl-4- piperidyl)- sebacate; 2-(2H-benzotriazole-2-yl)-4-methylphenol; diethylhexyl butamido triazone; amyl dimethyl PABA; 4,6-bis(octylthiomethyl)-o-
  • Suitable sunscreens which can be formulated into the compositions of the instant invention are those selected from among: aminobenzoic acid, amyldimethyl PABA, cinoxate, diethanolamine p-methoxycinnamate, digalloyl trioleate, dioxybenzone, 2-ethoxyethyl p- methoxycinnamate, ethyl 4-bis(hydroxypropyl)aminobenzoate, 2-ethylhexyl-2-cyano-3,3- diphenylacrylate, ethylhexyl p-methoxycinnamate, 2-ethylhexyl salicylate, glyceryl aminobenzoate, homomenthyl salicylate, homosalate, 3-imidazol-4-ylacrylic acid and ethyl ester, methyl anthranilate, octyldimethyl PABA, 2-phenylbenzimidazole-5-sulfonic acid and salts
  • composition may also contain additional materials such as, for example, fillers such as nylon, electrolytes such as sodium chloride, proteins, antioxidants, and chelating agents as appropriate.
  • Synthetic essential oils may include, for example, esters, such as acetylated castor oil, cetyl octanoate, cetyl palmitate, cetyl ricinoleate, cetyl stearate, cetyl myristate, coco- dicaprylate/caprate, decyl isostearate, dioctyl malate, glyceryl stearate, glyceryl dioleate, glyceryl distearate, glyceryl trioctanoate, glyceryl distearate, glyceryl linoleate, glyceryl myristate, glyceryl isostearate, hydrogenated castor oil, PEG castor oils, PEG glyceryl oleates, PEG
  • the present dispersant composition can be used in color cosmetic application selected from the group consisting of a facial foam/cream, cleansing, massage cream, pack, lotion, milky lotion, cream, serum, makeup base, and sunscreen, and finishing cosmetics including foundation, white powder, eye shadow, eyeliner, mascara, eyebrow, concealer, lipstick, lip gloss, and lip balm.
  • the present application provides a dispersant composition
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety.
  • the reaction product is selected from the group of structures represented by the following structures:
  • the base is selected from the group consisting of inorganic bases, organic bases, and mixtures thereof.
  • the inorganic base is selected from the group consisting of oxides of alkali metals and alkaline earth metals, hydroxides of alkali metals and alkaline earth metals, carbonates of alkali metals and alkaline earth metals, bicarbonates of alkali metals and alkaline earth metals, oxides of transition metals, hydroxides of transition metals, carbonates of transition metals, bicarbonates of transition metals, and combinations thereof.
  • the inorganic base is selected from the group consisting of oxides, hydroxides, carbonates and bicarbonates of sodium, calcium, and combinations thereof.
  • the transition metal is selected from the group consisting of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, rutherfordium, dubnium, seaborgium, bohrium, hassium, meitnerium, darmstadtium, roentgenium, and mixtures thereof.
  • the organic base is selected from the group consisting of ammonia, primary amines, secondary amines, pyridine, imidazole, benzimidazole, histidine, guanidine, and mixtures thereof.
  • the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component.
  • the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base,
  • the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base
  • the present application provides a dispersant composition for personal care, the composition comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (c) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (B) from about 1.0 to about 90.0 wt.% of one or more personal care active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient.
  • A from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (c)
  • the present application provides a dispersant composition for personal care application comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide and mixtures thereof; and (c) 2-octyldodecyl alcohol, glycerol, or combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the 2-octyldodecyl alcohol or glycerol; (B) from about 1.0 to about 90.0 wt.% of one or more agricultural active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient.
  • A from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil, comprising
  • the present application provides a dispersant composition
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base.
  • reaction product is represented by the following structure: wherein R is one or more hydrophilic or hydrophobic moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, aryl and alkaryl moieties containing from about 1 to about 36 carbon atoms; and wherein each Q is independently selected from the group consisting of H, Li, Na, K, Rb, Cs, Fr, 1 ⁇ 2 Mg, 1 ⁇ 2 Ca, 1 ⁇ 2 Co, 1 ⁇ 2 Cu, 1 ⁇ 2 Zn, ammonium, alkylammonium, dialkylammonium, trialkylammonium and tetraalkylammonium.
  • R is one or more hydrophilic or hydrophobic moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, aryl and alkaryl moieties containing from about 1 to about 36 carbon atoms
  • each Q is independently selected from the group consist
  • the reaction product is a polymer represented by the following structure: wherein n is greater than 1; wherein R is one or more hydrophilic or hydrophobic moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, aryl and alkaryl moieties containing from about 1 to about 36 carbon atoms; and wherein each Q is independently selected from the group consisting of H, Li, Na, K, Rb, Cs, Fr, 1 ⁇ 2 Mg, 1 ⁇ 2 Ca, 1 ⁇ 2 Co, 1 ⁇ 2 Cu, 1 ⁇ 2 Zn, ammonium, alkylammonium, dialkylammonium, trialkylammonium and tetraalkylammonium.
  • the reaction product is selected from the group of structures represented by the following structures:
  • the reaction product is a polymer selected from the group of structures represented by the following structures: wherein 1 ⁇ n ⁇ 30.
  • the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component.
  • the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at
  • the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component.
  • a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii)
  • the present application provides a dispersant composition
  • a dispersant composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base.
  • the reaction product comprises a maleated functionality fully or partially reacted with the base.
  • the base is selected from the group consisting of inorganic bases, organic bases, and mixtures thereof.
  • the inorganic base is selected from the group consisting of oxides of alkali metals and alkaline earth metals, hydroxides of alkali metals and alkaline earth metals, carbonates of alkali metals and alkaline earth metals, bicarbonates of alkali metals and alkaline earth metals, oxides of transition metals, and combinations thereof.
  • the organic base is selected from the group consisting of ammonia, primary amines, secondary amines, pyridine, imidazole, benzimidazole, histidine, guanidine, and mixtures thereof.
  • the alkali metal is selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, francium, and mixtures thereof.
  • the alkaline earth metal is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, and mixtures thereof.
  • the transition metal is selected from the group consisting of oxides, hydroxides, carbonates or bicarbonates of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, rutherfordium, dubnium, seaborgium, bohrium, hassium, meitnerium, darmstadtium, roentgenium, and mixtures thereof.
  • the inorganic base is selected from the group consisting of oxides, hydroxides, carbonates and bicarbonates of sodium, calcium, and combinations thereof.
  • the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated coconut oils, maleated corn oils, maleated cottonseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated almond oils, maleated canola oils, maleated flaxseed oils, maleated grapeseed oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated walnut oils, and mixture thereof.
  • the maleated natural oil is a maleated soybean oil and the base is sodium hydroxide.
  • the reaction product is selected from the group of structures comprising a maleated functionality fully or partially reacted with the base. consisting of the following structures: , ,
  • the present application provides a dispersant composition for coatings, the composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base.
  • the present application provides a dispersant composition for personal care, the composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base.
  • the present application provides a dispersant composition for color cosmetics, the composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base.
  • the present application provides a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (B) 2 to 70 wt.% of at least one particulate component.
  • the present application provides a method for preparing a dispersant composition for personal care, the method comprising: (a) adding dispersing agent into a glass jar; (b) sprinkling solid particulate component slowly onto the contents of step (a), (c) mixing the contents of step (b) until homogenous; and (d) obtaining the dispersant composition; wherein, said dispersant composition is characterized by an enhanced resistance to cracking, flaking, or breaking of the particulate component.
  • the reactions and compositions according to the application may be analyzed by known techniques.
  • NMR 13C nuclear magnetic resonance
  • GC gas chromatography
  • IR Infra-red
  • LC Liquid Chromatography
  • GPC gel permeation chromatography
  • the currently disclosed dispersant composition brings about unique features to the end user formulations in that the primary dispersing agent (i) reduces the viscosity of the mixture during solid particulate blending, (ii) enhances the dispersion of powder particulates, (iii) increases the solid loading since it drastically reduces the viscosity of the blend allowing one to add more solid particulates like pigments, (iv) are highly stable with good affinity for skin, (v) highly compatible to be used in emulsions, anhydrous and non-volatile systems, (vi) show improved wear and pleasing aesthetics such as better skin feel, high solid content, enhanced color strength, and (vii) are easy to incorporate with mixing and homogenizing offering stability and color consistency.
  • the primary dispersing agent reduces the viscosity of the mixture during solid particulate blending, (ii) enhances the dispersion of powder particulates, (iii) increases the solid loading since it drastically reduces the viscosity of the blend allowing one to add more solid particul
  • Example A Grafting of maleic anhydride onto natural oils.
  • Example A1 Grafting of 1 mole of maleic anhydride onto soybean oil.
  • 600 g of yellow color Soybean oil and 67 g (1 mole eq. based on SBO) of maleic anhydride were charged.
  • Example A3 Grafting of 3 moles of maleic anhydride onto soybean oil.
  • 600 g of yellow color soybean oil and 204 g (3 mole eq. based on SBO) of maleic anhydride were charged.
  • the mixture was sparged with nitrogen for 15 min at RT only.
  • the mixture was slowly heated from room temperature to 210 ⁇ C and was held isothermally at 210 ⁇ C for about 6-8 hours.
  • the one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 1% residual maleic anhydride.
  • Example A4 Grafting of maleic anhydride onto palm oil.
  • 100 g of palm oil and 23 g (2 mole eq. based on palm oil) of maleic anhydride was charged.
  • the mixture was sparged with nitrogen for 15 min at RT only.
  • the mixture was slowly heated from room temperature to 210 ⁇ C and held isothermally at 210 ⁇ C for about 8-10 hours.
  • the one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 1% residual maleic anhydride.
  • Example A5 Grafting of maleic anhydride onto canola oil.
  • 100 g of canola oil and 22.2 g (2 mole eq. based on canola oil) of maleic anhydride was charged.
  • the mixture was sparged with nitrogen for 15 min at RT only.
  • the mixture was slowly heated from room temperature to 210 ⁇ C and held isothermally at 210 ⁇ C for about 8-10 hours.
  • the one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 1% residual maleic anhydride.
  • Example A6 Grafting of maleic anhydride onto sunflower oil.
  • 100 g of sunflower oil and 22.4 g (2 mole eq. based on sunflower oil) of maleic anhydride was charged.
  • the mixture was sparged with nitrogen for 15 min at RT only.
  • the mixture was slowly heated from room temperature to 210 ⁇ C and held isothermally at 210 ⁇ C for about 8-10 hours.
  • the one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 1% residual maleic anhydride.
  • Example A7 Grafting of maleic anhydride onto castor oil.
  • 100 g of yellow color castor oil and 21 g (2 mole eq. based on castor oil) of maleic anhydride was charged.
  • the mixture was sparged with nitrogen for 15 min at RT only.
  • the mixture was slowly heated from room temperature to 210 ⁇ C and held isothermally at 210 ⁇ C for about 8-10 hours.
  • the one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 1% residual maleic anhydride.
  • Example B Grafting of hydrophobic alcohol (octyl dodecanol) onto maleic anhydride onto natural oil
  • Example B1 [0255] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A1 and 30.5 g (1 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B2 [0257] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A2 and 55.64 g (2 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B3 [0259] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A2 and 61.20 g (2.2 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B4 [0261] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 25.44 g (1 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B5 [0263] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 31.81 g (1.25 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B6 [0265] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 38.17 g (1.5 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B7 [0267] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A 3 and 50.89 g (2 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B8 [0269] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 63.61 g (2.5 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B9 [0271] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A4 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B10 [0273] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A5 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B11 [0275] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A6 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ⁇ C and held for 6 hours.
  • Example B12 [0277] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A7 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ⁇ C and held for 6 hours.
  • the one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC ⁇ 5% for residual octyl dodecanol and LC ⁇ 1% residual maleic anhydride.
  • Example C Grafting of hydrophobic and hydrophilic moiety (glycerin) onto hydrophobic maleic anhydride onto natural oil with octyl dodecanol
  • Example C1 [0280] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 6 and 5.7 g (1 mole eq.) of glycerin were mixed and heated to 90 ⁇ C and held for 4-6 hours.
  • Example C 2 [0282] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 4 and 6.28 g (1 mole eq.) of glycerin were mixed and heated to 90 ⁇ C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example C 3 [0284] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 4 and 9.42 g (1.5 mole eq.) of glycerin were mixed and heated to 90 ⁇ C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example C 4 [0286] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 9 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ⁇ C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example C 5 [0288] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 10 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ⁇ C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example C 6 [0290] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 11 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ⁇ C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example C 7 [0292] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 12 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ⁇ C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example C 8 [0294] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 152 g of amber color viscous product from reaction B 4 and 4.74 g (1 mole eq.) of ethanol were mixed and heated to 90 ⁇ C and held for 8 hours. The one pot reaction without catalyst and solvent yields >96% amber color product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example C 9 [0296] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 152 g of amber color viscous product from reaction B 4 and 9.47 g (2 mole eq.) of ethanol were mixed and heated to 90 ⁇ C and held for 8 hours. The one pot reaction without catalyst and solvent yields >96% amber color product which was characterized by NMR and LC ⁇ 0.05% residual maleic anhydride.
  • Example D Grafting of hydrophilic alcohol (beta cyclodextrin, glycerin) onto maleic anhydride onto natural oil
  • Example D 1 [0299] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 68.43 g of amber color viscous product from reaction B 6 and 23.73 g (0.50 mole eq.) of beta cyclodextrin were mixed and heated to 90 ⁇ C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC ⁇ 0.05% residual maleic anhydride.
  • Example D 2 [0301] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 68.43 g of amber color viscous product from reaction B 6 and 23.73 g (0.50 mole eq.) of beta cyclodextrin and 3.85 g (1 mole eq.) of glycerin were mixed and heated to 90 ⁇ C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC ⁇ 0.05% residual maleic anhydride.
  • Example D 3 [0303] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 68.43 g of amber color viscous product from reaction B 6 and 23.73 g (0.50 mole eq.) of beta cyclodextrin and 1.93 g (0.50 mole eq.) of glycerin were mixed and heated to 90 ⁇ C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC ⁇ 0.05% residual maleic acid.
  • Example E Maleination reaction with water
  • Example E 1 [0306] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction A 3 and 6.10 g (3 mole eq.) of water were mixed and heated to 90 ⁇ C and held for 20 hours. The one pot reaction without catalyst and solvent yields >90% yellow color product which was characterized by NMR, IR and LC ⁇ 0.05% residual maleic acid.
  • Example F Grafting of hydrophilic glycerin onto maleic anhydride onto soybean oil
  • Example F 1 [0309] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 176 g of amber color viscous product from maleination reaction A 3 and 6.87 g (0.5 mole eq.) of glycerin were mixed and heated to 90 ⁇ C and held for 2 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC ⁇ 0.05% residual maleic anhydride.
  • Example F 2 [0311] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 176 g of amber color viscous product from maleination reaction A 3 and 13.74 g (1 mole eq.) of glycerin were mixed and heated to 90 ⁇ C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC ⁇ 0.05% residual maleic anhydride.
  • Example G [0312] Example G: [0313] Example G1: Maleated soybean oil with 2-octyldodecanol and glycerin at 1%, 3% and 5% with zinc oxide and titanium dioxide with zinc oxide (10%w/w)- Table 1: Table 1: Maleated soybean oil with 2-octyldodecanol and glycerin with zinc oxide (10%w/w) [0314] Example G2: Maleated soybean oil reacted with 2-octyldodecanol and glycerin at 1%, 3% and 5% with zinc oxide and titanium dioxide (10%w/w)- Table 2 : Table 2: with Titanium Dioxide (10%w/w) 129 6119 129 6121 129 6123 [0258] Example G3: Sodium salt of maleated soybean oil with 2-octyldodecanol and glycerin at 1%, 3% and 5% with zinc oxide (10%w/w)- Table 3: Table 3: Sodium salt of
  • Kaolin was used as particulate component. Table 7: using Kaolin.
  • EXAMPLE 2 using Silica [0322] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Silica was used as particulate component. Table 8 - using Silica [0323]
  • EXAMPLE 3 using Zinc Oxide [0324] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Zinc oxide was used as particulate component. Table 9 - using Zinc Oxide [0325]
  • Example 4 using Titanium Dioxide [0326] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed.
  • Titanium dioxide was used as particulate component. The prepared samples were compared with that of the competitor. Table 10 - using Titanium dioxide [0327]
  • Example 5 using Titanium Dioxide [0328] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component and castor oil as liquid component of the dispersant composition.
  • Table 11 - using Titanium dioxide [0329]
  • Example 6 using Titanium dioxide & Esters [0330] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component.
  • Isodecyl Neopentanoate and tridecyl Neopentanoate were used as liquid components in the dispersant composition.
  • Table 12 using Titanium dioxide & Esters [0331]
  • Example 7 using Titanium dioxide & Esters [0332] Two dispersant compositions with soybean bean oil ester in different weight percentages were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component. Tridecyl Neopentanoate were used as liquid component in the dispersant composition.
  • Table 13 - using Titanium dioxide & Esters.
  • Example 8 using Titanium dioxide & Esters [0334] Three dispersant compositions without and with soybean bean oil ester (in different weight percentages) were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component. Tridecyl Neopentanoate and Octyldodecyl Stearoyl Stearate were used as liquid component in either of the dispersant compositions. Table 14 - using Titanium dioxide & Esters [0335] EXAMPLE 9: using Titanium dioxide & Esters [0336] Four dispersant compositions without and with soybean bean oil ester (in different weight percentages) were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component.
  • EXAMPLE 11 SPF Fluid Shake [0341] Four SPF fluid shake dispersions for skin care were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below: Table 17 - SPF Fluid Shake [0342]
  • EXAMPLE 12 Eye shadow [0343] Four different cosmetic care samples of eyeshadow were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 18 - Eyeshadow [0344]
  • EXAMPLE 13 Lip Gloss [0345] Four different cosmetic care samples of Lip gloss were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below.
  • EXAMPLE 14 Blush [0347] Four different cosmetic care samples of Blush were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 20 - Blush [0348] EXAMPLE 15: Pressed Powder [0349] Four different cosmetic care samples of Pressed powder samples were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 21 - Pressed Powder [0350] EXAMPLE 16: Carbon Black Mascara [0351] Four different cosmetic care samples of Carbon black mascara were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below.
  • EXAMPLE 17 Volume Curling Mascara [0353] Four different cosmetic care samples of volume curling mascara were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 23 - Volume Curling Mascara [0354] EXAMPLE 18: Clay Mask [0355] Four different cosmetic care samples of clay mask were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 24 - Clay Mask [0356] EXAMPLE 19: Long Wear Intense Lipstick [0357] Four different cosmetic care samples of Long Wear Intense Lipstick were prepared without and with soybean oil ester in different weight percentages.

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Abstract

The present invention provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (A) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof. (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base. (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a base.

Description

DISPERSANT COMPOSITIONS COMPRISING HYDROPHOBIC AND HYDROPHILIC MODIFIED MALEATED NATURAL OILS, AND APPLICATIONS THEREOF FIELD OF THE INVENTION [0001] The present application relates to dispersant compositions comprising modified maleated natural oils. Further, the present application provides use of these compositions as wetting agents and dispersing agents in personal care, coatings, agriculture, and pharmaceuticals. BACKGROUND OF THE INVENTION [0002] Modified natural oils can be non-dispersible in water or alcohols. As a result, these oils can be incorporated into a wide variety of compositions. Such compositions include, but are not limited to, personal care (e.g., hair care, sun care, skin care, oral care), adhesives, coatings, paints, electronics, household, industrial and institutional (HI&I) compositions, inks, membranes, metal working fluids, oilfield chemicals, plastics and plasticizers, textiles, industrial products, biocides, pharmaceuticals/nutritional, and agrochemical compositions. [0003] Natural oils, such as soybean and linseed oils, are one of the most promising raw materials for the synthesis of renewable compounds, including polymers, plastics, and plasticizers. These natural materials are inexpensive, highly abundant, come from reliable and sustainable sources, and have high potential for modification. Natural oils are generally blends of different triglycerides, the esterification product of fatty acids and glycerol, and contain varying degrees of unsaturation (i.e., double bonds). Oils can be characterized by a hydroxyl value and the fatty acid compositions. Both natural fatty acids and natural oils must be chemically modified to make them sufficiently reactive to allow structural alterations and polymerizations to occur because the olefin functional groups are relatively unreactive. Unsaturated double bonds in these compounds have been converted to epoxide functional groups and succinic anhydride functional groups, allowing the addition of many hydroxyl containing species to be introduced into the natural oils. [0004] Maleated natural oils are natural oils that have been chemically functionalized by the chemical addition of epoxide (oxirane) and succinic anhydride functional groups. Examples include epoxidized and maleated soybean oil and linseed oil, unsaturated natural oils lend themselves to this chemical functionalization. [0005] Dispersing agents are commonly used to wet out the dry filler during mixing, reduce the viscosity and make the formulation more workable. Numerous dispersing agents are available in the market. One such example are pigments which are traditionally milled and sold as powders or as dispersion in solvent. [0006] PCT Application WO2019/113068A1 (assigned to) and WO2005/071050A1 (assigned to) describes a technology related to metalworking fluids comprising maleated soybean oil derivatives. [0007] PCT Application WO2021252426A1 assigned to Sun Chemical Corporation discloses a solid pigment dispersion comprising one or more pigments approved for cosmetic use and a combination of one or more oils and/or waxes that are plant-based wherein the dispersion is in the form of a dry powder. [0008] US granted patent US10836910B2 assigned to Sherwin Williams Co. discloses concentrate for use in the manufacture of fluid colorants or finished coating compositions, wherein at least 95 wt.% of the concentrate is a mixture of (i) solid pigment particles with (ii) a non-volatilizing, reactive liquid diluent having a viscosity less than 1,000 cps, and comprising at least 60 wt.% of one or more molecular species having at least three reactive unsaturated sites and having a molar equivalent weight per reactive unsaturated site that is less than 500 grams (g), wherein when the reactive liquid diluent does not by itself stably disperse the pigment particles then the concentrate also contains (iii) one or more pigment wetting or dispersing agents. [0009] There is a need in the art for a dispersion composition for use in personal care and coatings which are prepared from materials that are renewable, natural, and biodegradable having different and controllable chemical, physical, and/or mechanical properties such that the limitations found in natural and maleated natural oils are minimized or eliminated. SUMMARY OF THE INVENTION [0010] In one important aspect, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof. [0011] In one important aspect, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; [0012] In one important aspect, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base. [0013] In one important aspect, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a base. [0014] In another important aspect, the present application provides a dispersant composition for coatings, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0015] In another important aspect, the present application provides a dispersant composition for personal care, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0016] In another important aspect, the present application provides a dispersant composition for color cosmetics, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0017] In yet another important aspect, the present application provides a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (B) 2 to 70 wt.% of at least one solid particulate component. [0018] In yet another important aspect, the present application provides a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety. [0019] In yet another important aspect, the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component. [0020] In yet another important aspect, the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component. [0021] In yet another important aspect, the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component. [0022] In yet another important aspect, the present application provides a dispersant composition for personal care, the composition comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (c) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (B) from about 1.0 to about 90.0 wt.% of one or more personal care active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient. [0023] In yet another important aspect, the present application provides a dispersant composition for personal care application comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide and mixtures thereof; and (c) 2-octyldodecyl alcohol, glycerol, or combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the 2-octyldodecyl alcohol or glycerol; (B) from about 1.0 to about 90.0 wt.% of one or more agricultural active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient. [0024] In yet another important aspect, the present application provides a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base. [0025] In yet another important aspect, the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component. [0026] In yet another important aspect, the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component. [0027] In yet another important aspect, the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component. [0028] In yet another important aspect, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base. [0029] In yet another important aspect, the present application provides a dispersant composition for coatings, the composition comprising: (a) least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base; and (b) a particulate compound. [0030] In yet another important aspect, the present application provides a dispersant composition for personal care, the composition comprising: (a) least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base; and (b) a particulate compound. [0031] In yet another important aspect, the present application provides a dispersant composition for color cosmetics, the composition comprising: (a) least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base; and (b) a particulate compound. [0032] In yet another important aspect, the present application provides a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (B) 2 to 70 wt.% of at least one particulate component.
DETAILED DESCRIPTION OF THE INVENTION [0033] What is herein described is a dispersant composition comprising modified maleated natural oils and application of these dispersant compositions in personal care, coatings, agriculture, and pharmaceuticals. [0034] Unless otherwise defined herein, technical terms used in connection with the disclosed and/or claimed inventive concept(s) shall have the meanings that are commonly understood by those of ordinary skill in the art. Further, unless otherwise required by context, singular terms shall include pluralities and plural terms shall include the singular. [0035] The singular forms "a," "an," and "the" include plural forms unless the context clearly dictates otherwise specified or clearly implied to the contrary by the context in which the reference is made. The term “Comprising” and “Comprises of” includes the more restrictive claims such as “Consisting essentially of” and “Consisting of”. [0036] For purposes of the following detailed description, other than in any operating examples, or where otherwise indicated, numbers that express, for example, quantities of ingredients used in the specification and claims are to be understood as being modified in all instances by the term "about". The numerical parameters set forth in the specification and attached claims are approximations that may vary depending upon the desired properties to be obtained in carrying out the invention. [0037] All percentages, parts, proportions, and ratios as used herein, are by weight of the total composition, unless otherwise specified. All such weights as they pertain to listed ingredients are based on the active level and, therefore; do not include solvents or by-products that may be included in commercially available materials, unless otherwise specified. [0038] All publications, articles, papers, patents, patent publications, and other references cited herein are hereby incorporated herein in their entirety for all purposes to the extent consistent with the disclosure herein. [0039] The use of the term “at least one” will be understood to include one as well as any quantity more than one, including but not limited to, 1, 2, 3, 4, 5, 10, 15, 20, 30, 40, 50, 100, etc. The term “at least one” may extend up to 100 or 1000 or more depending on the term to which it is attached. In addition, the quantities of 100/1000 are not to be considered limiting as lower or higher limits may also produce satisfactory results. [0040] The term “alkyl” refers to a functionalized or unfunctionalized, monovalent, straight-chain, branched-chain, or cyclic C1-C60 hydrocarbyl group optionally having one or more heteroatoms. In one non-limiting embodiment, an alkyl is a C1-C45 hydrocarbyl group. In another non-limiting embodiment, an alkyl is a C1-C30 hydrocarbyl group. Non-limiting examples of alkyl include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl, isopentyl, n-hexyl, n- heptyl, n-octyl, 2-ethylhexyl, tert-octyl, iso-norbornyl, n-dodecyl, tert-dodecyl, n-tetradecyl, n- hexadecyl, n-octadecyl, n-eicosyl, cyclobutyl, cyclopentyl, cyclohexyl, and the like. The definition of “alkyl” also includes groups obtained by combinations of straight-chain, branched- chain and/or cyclic structures. [0041] The term “aryl” refers to a functionalized or unfunctionalized, monovalent, aromatic hydrocarbyl group optionally having one or more heteroatoms. The definition of aryl includes carbocyclic and heterocyclic aromatic groups. Non-limiting examples of aryl groups include phenyl, naphthyl, indenyl, indanyl, azulenyl, fluorenyl, anthracenyl, furyl, thienyl, pyridyl, pyrrolyl, oxazolyl, thiazolyl, imidazolyl, pyrazolyl, 2-pyrazolinyl, pyrazolidinyl, isoxazolyl, isothiazolyl, 1,2,3-oxadiazolyl, 1,2,3-triazolyl, 1,3,4-thiadiazolyl, pyridazinyl, pyrimidinyl, pyrazinyl, 1,3,5-triazinyl, 1,3,5-trithianyl, indolizinyl, indolyl, isoindolyl, 3H-indolyl, indolinyl, benzo[b]furanyl, 2,3-dihydrobenzofuranyl, benzo[b]thiophenyl, 1H-indazolyl, benzimidazolyl, benzthiazolyl, purinyl, 4H-quinolizinyl, isoquinolinyl, cinnolinyl, phthalazinyl, quinazolinyl, quinoxalinyl, 1,8-naphthridinyl, pteridinyl, carbazolyl, acridinyl, phenazinyl, phenothiazinyl, phenoxyazinyl, pyrazolo[1,5-c]triazinyl, and the like. [0042] The term “aralkyl” refers to an alkyl group comprising one or more aryl substituent(s) wherein "aryl" and "alkyl" are as defined above. Non-limiting examples of aralkyl groups include benzyl, 2-phenyl-ethyl, 3-phenyl-propyl, 4-phenyl-butyl, 5-phenyl-pentyl, 4-phenylcyclohexyl, 4- benzylcyclohexyl, 4-phenylcyclohexylmethyl, 4-benzylcyclohexylmethyl, and the like. [0043] The term “alkylene” refers to a functionalized or unfunctionalized, divalent, straight-chain, branched-chain, or cyclic C1-C40 hydrocarbyl group optionally having one or more heteroatoms. In one non-limiting embodiment, an alkylene is a C1-C30 group. In another non-limiting embodiment, an alkylene is a C1-C20 group. Non-limiting examples of alkylene groups include: [0044] The term “arylene” refers to a functionalized or unfunctionalized, divalent, aromatic hydrocarbyl group optionally having one or more heteroatoms. The definition of arylene includes carbocyclic and heterocyclic groups. Non-limiting examples of arylene groups include phenylene, naphthylene, pyridinylene, and the like. [0045] The term "branched and unbranched alkyl groups" refers to alkyl groups, which may be straight chained or branched. Branched groups include isopropyl, tert-butyl, and the like. [0046] As used herein, the words “comprising” (and any form of comprising, such as “comprise” and “comprises”), “having” (and any form of having, such as “have” and “has”), “including” (and any form of including, such as “includes” and “include”) or “containing” (and any form of containing, such as “contains” and “contain”) are inclusive or open-ended and do not exclude additional, unrecited elements or method steps. [0047] The term “dispersing agent” as used herein refers to a “substance added to a suspension to improve the separation of particles and to prevent settling or clumping. [0048] The term “each independently selected from the group consisting of” means when a group appears more than once in a structure, that group may be selected independently each time it appears. [0049] The term “heteroatom” refers to oxygen, nitrogen, sulfur, silicon, phosphorous, or halogen. The heteroatom(s) may be present as a part of one or more heteroatom-containing functional groups. Non-limiting examples of heteroatom-containing functional groups include ether, hydroxy, epoxy, carbonyl, carboxamide, carboxylic ester, carboxylic acid, imine, imide, amine, sulfonic, sulfonamide, phosphonic, and silane groups. The heteroatom(s) may also be present as a part of a ring such as in heteroaryl and heteroarylene groups. [0050] The term “hydrocarbyl” includes straight-chain and branched-chain alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl groups, and combinations thereof with optional heteroatom(s). A hydrocarbyl group may be mono-, di- or polyvalent and have carbon chains contain at least 2 carbon atoms and preferably 2 to 100 carbon atoms. [0051] The term "hydrophilic" means that the compound has an affinity for water, whereas "hydrophobic" means not having an affinity for water. [0052] In one non-limiting embodiment, the hydrophobic moiety and the hydrophilic moiety is a hydrocarbyl alcohol, a hydrocarbyl amine, a silicon-based compound, or a combination thereof. [0053] Hydrocarbyl alcohols are classified as primary, secondary and tertiary alcohols, based on the number of carbon atoms connected to the carbon atom that bears the hydroxyl group. Each classification of alcohol may have a general formula. For example, the general formula for primary alcohols is the general formula for secondary alcohols is and the general formula for tertiary alcohols is wherein R, R′ and R″ stand for hydrogen, different alkyl, alkylene, aryl, aralkyl, arylene, heteroatom groups. [0054] The terms are relative terms, where a hydrophilic moiety it has a higher affinity for water than a hydrophobic moiety, but the hydrophilic moiety may or may not be completely water soluble. Likewise, hydrophobic moieties have less of an affinity for water than hydrophilic moieties, but the hydrophobic moieties may not necessarily be water-repellant. While hydrophilic moieties have an affinity for water and other polar solvents, hydrophobic moieties tend to have an affinity for oils, fats, and other non-polar solvents. [0055] The term “functional ingredient” refers to any ingredient that provides pharmacological activity or other direct effect in the diagnosis, cure, mitigation, treatment, or prevention of disease, or affects the structure or any function of the body of man or animals. The functional ingredient may be present either in a personal care product, a coating product, or an agriculture product. When the functional ingredient is present in a personal care product that contains at least one active personal care ingredient, the personal care ingredient includes, but is not limited to, analgesics, anesthetics, antibiotic agents, antifungal agents, antiseptic agents, antidandruff agents, antibacterial agents, vitamins, hormones, antidiarrhea agents, corticosteroids, anti-inflammatory agents, vasodilators, kerolytic agents, dry-eye compositions, wound-healing agents, anti-infection agents, as well as solvents, diluents, adjuvants and other ingredients such as water, mineral oils, preservatives, surfactants, propellants, fragrances, essential oils, and viscosifying agents. [0056] The term “functionalized” with reference to any moiety refers to the presence of one or more functional groups in the moiety. Various functional groups may be introduced in a moiety by way of one or more functionalization reactions known to a person having ordinary skill in the art. Non-limiting examples of functionalization reactions include: alkylation, epoxidation, sulfonation, hydrolysis, amidation, esterification, hydroxylation, dihydroxylation, amination, ammonolysis, acylation, nitration, oxidation, dehydration, elimination, hydration, dehydrogenation, hydrogenation, acetalization, halogenation, dehydrohalogenation, Michael addition, aldol condensation, Cannizzaro reaction, Mannich reaction, Clasien condensation, Suzuki coupling, and the like. In one non-limiting embodiment, the term “functionalized” with reference to any moiety refers to the presence of one more functional group selected from the groups consisting of alkyl, alkenyl, hydroxyl, carboxyl, halogen, alkoxy, amino, imino, and combinations thereof, in the moiety. [0057] The term “maleated natural oil”, as used herein, refers to natural oil contains at least one or more maleated functionalities. Accordingly, the term "maleation" or "maleated" as used hereafter should be understood to mean "functionalization" insofar as the use of functionalizing reagents other than maleic anhydride are contemplated for use in the process of the invention. [0058] The term “moiety” or “moieties” refer to a part or a functional group(s) of a molecule. [0059] The term “natural oil” refers to compounds comprising triglycerides and may contain varying levels of fatty acids, monoglycerides, diglycerides and triglycerides refer to oil derived from plants or animal sources. Natural oils also include fatty acid glyceryl esters, which are synthesized by reacting glycerol with 1, 2, or 3 molar equivalents of a fatty acid or a mixture of fatty acids. These compounds can be mono, di or triglycerides of a single fatty acid or a mixture of fatty acids. [0060] The term “polymer” refers to a compound comprising repeating structural units (monomers) connected by covalent chemical bonds. Polymers may be further derivatized, crosslinked, grafted or end-capped. Non-limiting examples of polymers include copolymers, terpolymers, tetrapolymers, quaternary polymers, and homologues. The term “copolymer” refers to a polymer consisting essentially of two or more different types of monomers polymerized to obtain said copolymer. [0061] The term “reaction product” refers to a substance or substances produced from a chemical reaction of one or more reactant substances. [0062] The term “soybean oil ester” as used herein refers to a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol. [0063] The term "sequestering agent" or “chelating agent” as used herein relates to a compound which is capable of bonding or complexing a metal ion between two or more atoms of the compound, thereby neutralizing, or controlling harmful effects of such metal ions. Wherein holding or bonding of a metal ion is through combination of one or more different types of bonds including coordination and/or ionic bonds. Further, the information on sequestering and chelating agents that are considered for the present application is duly disclosed in T. E. Furia, CRC Handbook of Food Additives, 2nd Edition, pp. 271-294 (1972), and M. S. Peterson and A. M. Johnson (Eds.), Encyclopedia of Food Science, pp. 694-699 (1978) are incorporated herein by reference in its entirety. [0064] The structures set out below may refer to the first, second, or third structure, or combinations thereof. The succinic anhydride group may be present in the top, middle, or lower chain. [0065] The term “unreacted maleated functionality” refers to refers to present of an unreacted maleic anhydride compound or functionality in the reaction product of this invention, wherein, the maleated functionality are completely unreacted and intact. [0066] In one important embodiment, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof. [0067] In one important embodiment, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; [0068] In one important embodiment, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base. [0069] In one important embodiment, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a base. [0070] The maleated natural oil is a natural oil with maleated functionality. Further, the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated almond oils, maleated coconut oils, maleated corn oils, maleated canola oils, maleated cottonseed oils, maleated flaxseed oils, maleated grapeseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated walnut oils, and mixtures thereof. The maleated natural oil is a maleated soybean oil. [0071] In an embodiment, the hydrophobic moiety is a moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C6 to about C36 atoms, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl amines, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C6 to about C36 atoms, silicon-based compounds, and combinations thereof. [0072] Accordingly, the hydrophobic alcohol is selected from the group consisting of heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tertradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2-propyl-1- pentanol, 4-methyl-1-pentanol, and mixtures thereof, and hydrophobic amine is selected from the group consisting of benzylamine, cyclohexylamine, hexylamine, methylhexylamine, phenethylamine, octylamine, oleylamine, decylamine, dodecylamine, octadecylamine, undecyl amine, pentadecyl amine, 2-methyl butyl amine, dimethyl amine, and mixtures thereof. [0073] In an embodiment, the hydrophilic moiety is a moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C1 to about C5 atoms, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl amines, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C1 to about C5 atoms, unsubstituted or substituted polyols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C2 to about C36 atoms, silanes, and combinations thereof. [0074] Accordingly, the hydrophilic alcohol is selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxy polyethylene glycol, polypropylene glycol, hexylene glycol, sorbitol, neopentylglycol, eythritol, mannitol, xylitol, threitol, pentaerythritol, beta-cyclodextrin, L-Ribose, 2-deoxy-D-galactose, and mixtures thereof, and the hydrophilic amine is selected from the group consisting of 2-methylpentane-1,5-diamine, diethanol amine, diisopropanol amine, serinol hydrochloride, 2-amino-2-ethyl-1,3-propanediol, N- methyl-D-glucosamine, D-galactosamine hydrochloride, D-glucosamine hydrochloride, D- mannosamine hydrochloride, and mixtures thereof. [0075] Accordingly, the silane is functionalized with an alcohol or an amine, and combinations thereof. More preferably, the hydrophobic alcohol is selected from the group consisting of heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tertradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2- propyl-1-pentanol, 4-methyl-1-pentanol, and mixtures thereof. More preferably, the hydrophilic alcohol is selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxypolyethylene glycol, polypropylene glycol, hexylene glycol, sorbitol, neopentylglycol, eythritol, mannitol, xylitol, threitol, pentaerythritol, beta-cyclodextrin, L-Ribose, 2-deoxy-D-galactose, and mixtures thereof. [0076] Accordingly, the silicon-based compound is a hydrophobic compound selected from the group consisting of aminopropyl methylsiloxane–dimethylsiloxane, N-ethylamino isobutyl terminated polydimethylsiloxane, poly(1,1-dimethylsilazane) telomer, aminopropyl terminated polydimethylsiloxane, monoamino propyl terminated polydimethylsiloxane, (tetramethyl piperidinyloxy)propylmethylsiloxane]-dimethylsiloxane copolymer, polydimethylsiloxane, carbinol (hydroxyl) terminated polydimethylsiloxane, monocarbinol terminated polydimethylsiloxane, monocarbinol terminated functional polydimethylsiloxane, [Bis(hydroxyethyl)amine] terminated polydimethylsiloxane, silanol terminated polydimethylsiloxane, silanol terminated polydiphenylsiloxane, dodecylmethylsiloxane- hydroxypolyalkyleneoxypropyl methylsiloxane, and mixtures thereof. Preferably, the silane is a hydrophilic compound selected from the group consisting of 3-aminopropylsilanetriol, N-(2- aminoethyl)-3-aminopropylsilanetriol, and mixtures thereof. [0077] The reactions according to the application may be readily synthesized by procedures known by those skilled in the art, non-limiting examples of which include free radical solution polymerization, dispersion polymerization, emulsion polymerization, ionic chain polymerization, living polymerization, bulk polymerization, suspension polymerization or precipitation polymerization. Particularly, the polymerization is carried out by any one of the methods disclosed in “Principles of Polymerization” 4th edition, 2004, Wiley by George Odian and is referred and disclosed herein in its entirety and described in “Decomposition Rate of Organic Free Radical Polymerization” by K.W. Dixon (section II in Polymer Handbook, volume 1, 4th edition, Wiley- Interscience, 1999), which is herein incorporated in its entirety by reference. [0078] The maleinization reaction in natural oil can occur under heating in three different ways. The first one is known as “Ene” reaction (reaction between an allylic hydrogen and an enophile- pericyclic reaction), obtaining a triglyceride structure with anhydride moieties (succinic anhydride). The second one is a radical addition, which consumes a double bond in the fatty acid, incorporating the succinic anhydride into the natural oil structure. The final reaction is also a radical addition that incorporates the maleic anhydride into the natural oil structure without consuming C=C bonds (fatty acid chain and maleic anhydride); this reaction occurs due to deprotonation of a hydrogen between two alkenes groups. Subsequently, the maleinized natural oil can be reacted with hydrophobic moiety and the hydrophilic moiety of a hydrocarbyl alcohol, a hydrocarbyl amine, a silicon-based compound forming a reticulated structure (see examples). This kind of reaction has been applied at the reaction occurred by heating 6-10 hours at 210oC. [0079] Thus, the reaction of the non-limiting example above, for illustration purposes only, may be performed at elevated temperatures, such as a temperature between about 150° C. and about 300° C., alternatively between about 170° C. and about 230° C., or alternatively between about 200° C and about 220° C. The reaction time may be between about 0.5 hours and about 10 hours. In one embodiment the reaction time is between about 1 hour and about 5 hours, and in another embodiment, between about 2 hours and 4 hours. and in another embodiment, between about 6 hours and 10hours. [0080] During maleation, the mole ratio of natural oil to maleic anhydride in some embodiments is equal to 1, in other embodiments from 1 to 2, in other embodiments from 1 to 2.8 and in still other embodiments from 1 to 3.2 moles of maleic anhydride for each mole of natural oil. [0081] The mole ratio of reaction of maleated natural oil and a hydrophobic moiety, a hydrophilic moiety, or a combination thereof mixtures is equal to 1:1 to form a reaction product comprising at least one unreacted maleated functionality. [0082] In some embodiments, the suitable range of a reaction product of a maleated natural oil and one or more functionalized or unfunctionalized moieties selected from a hydrophobic moiety, a hydrophilic moiety or a combination can be varied from about 0.01 wt.% to about 0.1 wt.%, from about 0.1 wt.% to about 1 wt.%, or from about 1 wt.% to about 5wt.%, or from about 5 wt.% to about 10 wt.% based on the total weight of the aqueous personal care composition. [0083] In another embodiment, the dispersing agent / wetting agent for the current composition can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.%; or from about 55 wt.% to about 60 wt.%; or from about 60 wt.% to about 65 wt.%; or from about 65 wt.% to about 70 wt.%; or from about 70 wt.% to about 75 wt.%; or from about 75 wt.% to about 80 wt.%; or from about 80 wt.% to about 85 wt.%; or from about 85 wt.% to about 90 wt.% based on the total weight of the dispersant composition. [0084] Preferably, the dispersing agent is present in an amount of from 0.1 to 90 wt.% of the total dispersant composition. [0085] In another embodiment, the dispersant composition further comprises at least one particulate component. The particulate component is a solid selected from the group consisting of pigments for personal care, architectural and industrial coatings; extenders and fillers for paints and plastics materials; optical brightening agents for paper; textile auxiliaries for solvent dyebaths and inks; particulate ceramic materials; magnetic particles for use in magnetic recording media; organic solid biocides for agrochemicals and pharmaceuticals; solid particulates for food and preservatives; and solid polymeric surfactants for home care. Specific particulate components include graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof. For agricultural use, the particulate component can be an organic solid biocide selected from the group consisting of fungicides, insecticides, bactericides, and herbicides. [0086] In some embodiments, the suitable range of solid particulate component for the current composition can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.%; or from about 55 wt.% to about 60 wt.%; or from about 60 wt.% to about 65 wt.%; or from about 65 wt.% to about 70 wt.%; or from about 70 wt.% to about 75 wt.%; or from about 75 wt.% to about 80 wt.%; or from about 80 wt.% to about 85 wt.%; or from about 85 wt.% to about 90 wt.% based on the total weight of the dispersion composition. [0087] Accordingly, the particulate component is present in an amount of from 0.1 to 70 wt.% of the total dispersant composition. [0088] The particulate component is selected from the group consisting of pigments for personal care, architectural and industrial coatings; extenders and fillers for paints and plastics materials; optical brightening agents for paper; textile auxiliaries for solvent dyebaths and inks; particulate ceramic materials; magnetic particles for use in magnetic recording media; organic solid biocides for agrochemicals and pharmaceuticals; solid particulates for food and preservatives; and solid polymeric surfactants for home care. [0089] The particulate component is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof. [0090] In another embodiment, the present dispersant composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols. [0091] Non-limiting examples of esters include isotridecyl isononanoate, polyethylene glycol diheptanoate, isostearyl neopentanoate, tridecyl neopentanoate, cetyl octanoate, cetyl palmitate, cetyl ricinoleate, cetyl stearate, cetyl myristate, isopropyl myristate, coco-dicaprylate/caprate, decyl isostearate, isodecyl oleate, isodecyl neopentanoate, isohexyl neopentanoate, octyl palmitate, dioctyl malate, tridecyl octanoate, myristyl myristate, octododecanol, and fatty alcohols such as oleyl alcohol, isocetyl alcohol. [0092] Non-limiting examples of oils include glyceryl esters of fatty acids, or triglycerides, such as castor oil, lanolin oil, triisocetyl citrate, C10-18 triglycerides, caprylic/capric/triglycerides, coconut oil, mineral oil, almond oil, apricot kernel oil, avocado oil, babassu oil, evening primrose oil, camelina sativa seed oil, grape seed oil, macadamia ternifolia seed oil, com oil, meadowfoam seed oil, mink oil, olive oil, palm kernel oil, safflower oil, sesame oil, soybean oil, sunflower oil, wheat germ oil and camellia reticulata seed oil. Also suitable as the oils are glyceryl esters (excluding fats and oils which are glyceryl esters of fatty acids) which are primarily fatty acid mono-, di-, and triglycerides which are modified by reaction with other alcohols, for example, acetylated castor oil, glyceryl stearate, glyceryl dioleate, glyceryl distearate, glyceryl trioctanoate, glyceryl distearate, glyceryl linoleate, glyceryl myristate, glyceryl isostearate, PEG castor oils, PEG glyceryl oleates, PEG glyceryl stearates and PEG glyceryl tallowates. Also suitable as the organic oil are non-volatile hydrocarbons such as isoparaffins, hydrogenated polyisobutene, mineral oil and squalene. Also suitable as the oil are various lanolin derivatives such as acetylated lanolin, acetylated lanolin alcohol, and various fluorinated oils, such as fluoro Guerbet esters or perfluropolyethers. Other suitable oils include sorbitan derivatives such as PEG sorbitan beeswax, PEG sorbitan isostearate, PEG sorbitan lanolate, PEG sorbitan laurate, PEG sorbitan oleate, PEG sorbitan palmitate, PEG sorbitan stearate, polysorbates, sorbitan trioleates, sorbitan sesquioleates, sorbitan stearates, and sorbitan tristearates. [0093] Non-limiting examples of alcohols include isostearyl alcohol, oleyl alcohol, octyl dodecanol, octyl alcohol, decyl alcohol, arachyl alcohol, hexyl decanol, chimyl alcohol, β-glucan, cholesterol, sitosterol, dihydrocholesterol, stearyl alcohol, cetanol, cetostearyl alcohol, phytosterol, hexyl decanol, behenyl alcohol, lauryl alcohol, lanolin alcohol, and myristyl alcohol, polyhydric alcohols such as erythritol, glycerol, xylitol, diglycerol, dipropylene glycol, sorbitol, trehalose, 1,3-butylene glycol, propylene glycol, 1,2-pentanediol, polyethylene glycol, polyoxyethylene glycerol, polypropylene, polyoxypropylene glyceryl ether, polyoxypropylene diglyceryl ether, polyoxypropylene butyl ether, polyoxyethylene-polyoxypropylene butyl ether, polyoxyethylene methyl glucoside, polyglycerol, maltitol, and mannitol, mucopolysaccharides such as sodium hyaluronate, sodium acetyl hyaluronate, and sodium chondroitin sulfate. [0094] Preferably, the liquid component is selected from the group consisting of soya methyl ester, rapeseed oil methyl ester, methyl tallowate, methyl oleate, butyl stearate, butyl oleate, 2-ethylhexyl oleate, ethylhexyl palmitate, ethylhexyl stearate, ethylhexyl cocoate, isotridecyl stearate, isodecyl neopentanoate, tridecyl neopentanoate, octyl dodecyl stearoyl stearate, castor oil, polyhydroxy stearic acid, and C12-15 alkyl benzoate. [0095] In some embodiments, the suitable range of liquid component for the current dispersant composition can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.%; or from about 55 wt.% to about 60 wt.%; or from about 60 wt.% to about 65 wt.%; or from about 65 wt.% to about 70 wt.%; or from about 70 wt.% to about 75 wt.%; or from about 75 wt.% to about 80 wt.%; or from about 80 wt.% to about 85 wt.%; or from about 85 wt.% to about 90 wt.% based on the total weight of the dispersion composition. [0096] Accordingly, the liquid component is present in an amount of from about 2% to about 90 wt.% of the total weight of the dispersant agent. [0097] Accordingly, the dispersant composition find its application in agricultural compositions, biocidal compositions, cleaning compositions, coating compositions, cosmetic compositions, construction compositions, disinfecting compositions, energy compositions, food compositions, hair care compositions, homecare compositions, industrial and institutional compositions, laundry compositions, nutraceutical composition, oral care compositions, pharmaceuticals compositions, preservative compositions, skin care compositions, textile compositions. [0098] Accordingly, the dispersant composition is a personal care composition, an industrial coating composition, a food coating composition, a pharmaceutical coating composition, and an agricultural coating composition. [0099] Accordingly, the dispersant composition is a used for lacquer coating, primer coating, ink jet printing, top coating, varnish coating, architectural coating, wood coating, printing inks or metallic or non-metallic coating. [0100] Accordingly, the dispersant composition is a the composition is coated on a substrate selected from the group consisting of porous and non-porous substrates, papers, non-woven materials, textiles, leather, wood, concrete, masonry, metals, non-metals, house wrap, building materials, fiberglass, polymeric articles, face masks, medical drapes and gowns, carpets, upholstery, tents, awnings, air bags, fabrics, ceramics, yarns, and blends, woven, knitted, natural, synthetic, and regenerated substrates. [0101] In another important embodiment, the dispersing agent is selected from the group of structures represented by the structures set out below: [0102] The dispersant composition further comprises at least one functional ingredient selected from personal care agents, coating agents, food coating agents, pharmaceutical tablet coatings agents, and agricultural coatings agents. Preferably, the dispersant composition is a personal care composition, a coating composition, a food coating composition, a pharmaceutical coating composition, and an agricultural coating composition. [0103] In some embodiments, the suitable range of functional ingredient for the present application can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.%; or from about 55 wt.% to about 60 wt.%; or from about 60 wt.% to about 65 wt.%; or from about 65 wt.% to about 70 wt.%; or from about 70 wt.% to about 75 wt.%; or from about 75 wt.% to about 80 wt.%; or from about 80 wt.% to about 85 wt.%; or from about 85 wt.% to about 90 wt.% based on the total weight of the dispersant composition. [0104] The dispersant composition for personal care may be a formulation selected from the group consisting of sprays, lotions, mousses, fluids, serums, solutions, suspensions, perms, emulsions, gels, mists, vesicles, dispersions, pastes, creams, solid sticks, shampoos, balms, wipes, milks, foams, jellies, liquids, a foundation, a long wear intense lipstick, a clay mask, a volume curling mascara, a carbon black mascara, a pressed powder, a blush, a lip gloss, an eye shadow, a SPF fluid shake. [0105] In another embodiment, the present application provides a dispersant composition for coatings, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0106] Accordingly, the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols. Further, the dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol. [0107] Accordingly, the solid particulate is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof. [0108] Accordingly, the dispersant composition for coatings may be used in architectural coatings, metal coatings, marine coatings, paints, decorative paints, interior paints, exterior paints, non- woven coatings, ceramic coatings, anti-corrosion coatings, flame retardant coatings, glass coatings, protective coatings, powder coatings, wood coatings, industrial coatings, anti-fouling coatings, anti-microbial coatings, thermal insulation coatings, water-based coatings, and solvent based coatings. [0109] The dispersant composition for agriculture can be used in fertilizers, pesticides selected from the group of rodenticides, miticides, algicides, molluscicides, acaricides, avicides, insecticides, herbicides, ovicides, fungicides, germicides, antibiotics, antibacterial, antivirals, antifungals, antiprotozoals, anti-parasites and antimicrobials compounds. [0110] In another embodiment, the present application provides a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (B) 2 to 70 wt.% of at least one particulate component. [0111] In another aspect, the present invention provides a composition comprising a reaction product of (a) a maleated natural oil; (b) a functionalized or unfunctionalized hydrophobic moiety; and (c) a glycerol moiety. [0112] In a non-limiting embodiment, the reaction product comprises an unreacted maleated functionality or a maleated functionality functionalized with a hydrophobic moiety, a hydrophilic moiety, or combinations thereof. [0113] The preferences listed for the invention set out above for a “dispersant composition comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention. [0114] Preferably, the hydrophobic moiety is a moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C6 to about C36 atoms, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl amines, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C6 to about C36 atoms, silicon-based compounds, and combinations thereof. Preferably, the hydrophobic moiety is an alcohol selected from the group consisting of heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tertradecanol, 2- hexadecanol, 3,7-dimethyl-1-octanol, 2-propyl-1-pentanol, 4-methyl-1-pentanol, and mixtures thereof. Preferably, the hydrophobic moiety is an amine selected from the group consisting of benzylamine, cyclohexylamine, hexylamine, methylhexylamine, phenethylamine, octylamine, oleylamine, decylamine, dodecylamine, octadecylamine, undecyl amine, pentadecyl amine, 2-methyl butyl amine, dimethyl amine, and mixtures thereof. [0115] Preferably, the silicon-based compound is a hydrophobic compound selected from the group consisting of aminopropyl methylsiloxane–dimethylsiloxane, N-ethylamino isobutyl terminated polydimethyl siloxane, poly(1,1-dimethylsilazane) telomer, aminopropyl terminated polydimethyl siloxane, monoamino propyl terminated polydimethyl siloxane, (tetramethyl piperidinyloxy) propylmethyl siloxane]-dimethyl siloxane copolymer, polydimethylsiloxane, carbinol (hydroxyl) terminated polydimethylsiloxane, monocarbinol terminated polydimethylsiloxane, monocarbinol terminated functional polydimethylsiloxane, [Bis(hydroxyethyl)amine] terminated polydimethylsiloxane, silanol terminated polydimethylsiloxane, silanol terminated polydiphenyl siloxane, dodecyl methylsiloxane-hydroxypolyalkyleneoxy propyl methylsiloxane, and mixtures thereof. [0116] Preferably, the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated coconut oils, maleated corn oils, maleated cottonseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated almond oils, maleated canola oils, maleated flaxseed oils, maleated grapeseed oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated walnut oils, and mixtures thereof. More preferably, the maleated natural oil is a maleated soybean oil. [0117] Preferably, the dispersant composition is selected from the group consisting of skin care compositions, oral care compositions, hair care compositions, energy compositions, construction compositions, biocidal compositions, preservative compositions, nutraceutical compositions, food compositions, agricultural compositions, coating compositions, cosmetic compositions, homecare compositions, industrial and institutional compositions, textile compositions, laundry compositions, cleaning compositions, and disinfecting compositions. [0118] A preferred dispersant composition comprises compounds selected from the group of structures represented by the structures set out below: [0119] In another important embodiment, the present application provides a dispersant composition comprising: (A) a reaction product of: (a) a maleated natural oil, and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; with the proviso that the hydrophilic moiety is not a glycerol moiety, and (B) (a) a functional ingredient. [0120] The preferences listed for the invention set out above for a “dispersant composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention. [0121] The dispersant compositions may be selected from the group consisting of skin care compositions, oral care compositions, hair care compositions, energy compositions, construction compositions, biocidal compositions, preservative compositions, nutraceutical compositions, food compositions, agricultural compositions, coating compositions, cosmetic compositions, homecare compositions, industrial and institutional compositions, textile compositions, laundry compositions, cleaning compositions, and disinfecting compositions. [0122] In yet another aspect, the invention provides a dispersant composition comprising: (A) a reaction product of (a) a maleated natural oil; (b) a functionalized or unfunctionalized hydrophobic moiety; and (c) a glycerol moiety; and (B) a functional ingredient. [0123] The preferences listed for the invention set out above for a “dispersant composition comprising: (A) a reaction product of (a) a maleated natural oil; (b) a functionalized or unfunctionalized hydrophobic moiety; and (c) a glycerol moiety; and (B) a functional ingredient” also apply to this aspect of the invention. [0124] The dispersant compositions may be selected from the group consisting of skin care compositions, oral care compositions, hair care compositions, energy compositions, construction compositions, biocidal compositions, preservative compositions, nutraceutical compositions, food compositions, agricultural compositions, coating compositions, cosmetic care compositions, homecare compositions, industrial and institutional compositions, textile compositions, laundry compositions, cleaning compositions, and disinfecting compositions. [0125] A preferred dispersant composition comprises dispersing agents selected from the group of structures represented by the structures set out below: [0126] In yet another aspect, the invention provides a personal care composition comprising: (A) a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; with the proviso that the hydrophilic moiety is not a glycerol moiety; and (B) (a) a personal care functional ingredient. [0127] The preferences listed for the invention set out above for a “composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; with the proviso that the hydrophilic moiety is not a glycerol moiety” also apply to this aspect of the invention. [0128] The composition may be present in an amount of from about 0.01% to about 10% and (B) is present in an amount of from about 90% to about 99.99%. [0129] The personal care functional ingredient may be selected from the group consisting of color agents, hair care agents, skin care agents, and sun care agents. [0130] In yet another aspect, the invention provides a personal care composition comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a functionalized or unfunctionalized hydrophobic moiety; and (c) a glycerol moiety; and (B) a personal care functional ingredient. [0131] The preferences listed for the invention set out above for a “composition comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a functionalized or unfunctionalized hydrophobic moiety; (c) a glycerol moiety; and (B) a functional ingredient” also apply to this aspect of the invention. [0132] The composition may be present in an amount of (A) in an amount of from about 0.01% to about 10% and (B) is present in an amount of from about 90% to about 99.99%. [0133] The personal care functional ingredient may be selected from the group consisting of color agents, hair care agents, skin care agents, and sun care agents. [0134] The personal care composition may be a formulation selected from the group consisting of sprays, lotions, mousses, fluids, serums, solutions, suspensions, perms, emulsions, gels, mists, vesicles, dispersions, pastes, creams, solid sticks, shampoos, balms, wipes, milks, foams, jellies, and liquids. [0135] In another embodiment, the present application provides a dispersant composition for personal care, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0136] In yet another aspect, the application provides a skin care composition comprising a dispersant composition comprising: (A) a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; with the proviso that the hydrophilic moiety is not a glycerol moiety; and (B) a skin care functional ingredient. [0137] The preferences listed for the application set out above for a “dispersant composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention. [0138] The composition may be present in an amount of (A) in an amount of from about 0.01% to about 10% and (B) is present in an amount of from about 90% to about 99.99%. [0139] The skin care functional ingredient may be selected from the group consisting of color agents, hair care agents, skin care agents, and sun care agents. [0140] In yet another aspect, the invention provides a skin care composition comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a functionalized or unfunctionalized hydrophobic moiety; and (c) a glycerol moiety; and (B) a skin care functional ingredient. [0141] The preferences listed for the invention set out above for a “composition comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a functionalized or unfunctionalized hydrophobic moiety; (c) a glycerol moiety; and (B) a functional ingredient” also apply to this aspect of the invention. [0142] The composition may be present in an amount of (A) in an amount of from about 0.01% to about 10% and (B) is present in an amount of from about 90% to about 99.99%. [0143] Preferably, the skin care functional ingredient is selected from the group consisting of color agents, hair care agents, skin care agents, and sun care agents. [0144] In another embodiment, the present application provides a dispersant composition for color cosmetics, wherein the composition comprises (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0145] Preferably, the skin care functional ingredient is a formulation selected from the group consisting of sprays, lotions, mousses, fluids, serums, solutions, suspensions, perms, emulsions, gels, mists, vesicles, dispersions, pastes, creams, solid sticks, shampoos, balms, wipes, milks, foams, jellies, and liquids. [0146] In yet another embodiment, the present application provides compositions comprising a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) two functionalized or unfunctionalized hydrophilic moieties. [0147] In yet another embodiment, the present application provides compositions comprising: (A) a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) two functionalized or unfunctionalized hydrophilic moieties; and (B) a functional ingredient. [0148] In one non-limiting embodiment, the hydrophobic moiety hydrocarbyl alcohol contains C2 to C36 carbon atoms and is linear, branched, saturated, unsaturated, aliphatic, aromatic, monofunctional or multifunctional. [0149] In one non-limiting embodiment, the hydrocarbyl alcohol is selected from the group consisting of monohydric alcohols, dihydric alcohols, polyhydric alcohols, and combinations thereof. [0150] In one non-limiting embodiment, the hydrocarbyl amine is selected from the group consisting of primary amines, secondary amines, and combinations thereof. [0151] Hydrocarbyl amines are classified as primary, secondary and tertiary alcohols, based on the number of carbon atoms connected to the carbon atom that bears the hydroxyl group. Each classification of alcohol may have a general formula. For example, the general formula for primary amine is and the general formula for secondary amine is wherein R, R′ stand for hydrogen, different alkyl, alkylene, aryl, aralkyl, arylene, heteroatom groups. [0152] In one non-limiting embodiment, the hydrophobic moiety hydrocarbyl amine contains C2 to C36 carbon atoms and is linear, branched, saturated, unsaturated, aliphatic, aromatic, monofunctional or multifunctional. [0153] In one non-limiting embodiment, the silicon-base compound is a wherein R stands for different alkyl, alkylene, aryl, aralkyl, arylene, hetero groups functionalized with at least one or more alcohol, an amine, or a combination thereof and n has the value of 1 to 10. [0154] In one non-limiting embodiment, the silicon-base compound is a siloxane, or a silane functionalized with an alcohol, an amine, or a combination thereof. [0155] In one non-limiting embodiment, the silicon-based compound is a linear, branched, saturated, unsaturated, aliphatic, aromatic, monofunctional or multifunctional compound. [0156] In one non-limiting embodiment, the hydrocarbyl alcohol is selected from the group consisting of monohydric alcohols, dihydric alcohols, polyhydric alcohols, and combinations thereof. [0157] In one non-limiting embodiment, the hydrocarbyl alcohol is a hydrophobic alcohol selected from the group consisting of propanol, butanol, pentanol, heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tertradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2-propyl-1-pentanol, 4-methyl-1- pentanol and mixtures thereof. [0158] In one non-limiting embodiment, the hydrocarbyl alcohol is a hydrophilic alcohol selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxypolyethylene glycol, polypropylene glycol, hexylene glycol, glycerol, sorbitol, octanol, methyl ethyl pentanol, trimethyl pentanol, ethyl hexanol, methyl heptanol, nonanol, methyl octanol, ethyl heptanol, methyl ethyl hexanol, cyclohexanol, dimethyl heptanol, decanol, methyl nonanol, ethyl octanol, trimethyl heptanol, undecanol, methyl decanol, ethyl nonanol, dodecanol, tetradecanol, hexadecanol, octadecanol, benzyl alcohol, phenoxyethanol, neopentylglycol, trimethylol propane, methyldiethanol amine, erythritol, mannitol, xylitol, pentaerythritol, threitol, pentaerythritol, beta-cyclodextrin, L-Ribose, 2-deoxy-D-galactose and mixtures thereof. [0159] In one non-limiting embodiment, the hydrocarbyl amine is hydrophobic amine selected from the group consisting of benzylamine, cyclohexylamine, hexylamine, methylhexylamine, phenethylamine, octylamine, oleylamine, decylamine, dodecylamine, octadecylamine, undecyl amine, pentadecyl amine, 2-methyl butyl amine, dimethyl amine, and mixtures thereof. [0160] In one non-limiting embodiment, the hydrocarbyl amine is hydrophilic amine selected from the group consisting of 2-methylpentane-1,5-diamine, diethanol amine, diisopropanolamine, serinol hydrochloride, 2-amino-2-ethyl-1, 3-propanediol, N-methyl-D-glucosamine, D- galactosamine hydrochloride, D-glucosamine hydrochloride, D-mannosamine hydrochloride and mixtures thereof. [0161] In one non-limiting embodiment, the silicon-based compound is a hydrophobic compound selected from the group consisting of aminopropyl methylsiloxane–dimethylsiloxane, N- ethylaminoisobutyl terminated polydimethylsiloxane, poly(1,1-dimethylsilazane) telomer, aminopropyl terminated polydimethylsiloxane, monoaminopropyl terminated polydimethylsiloxane, (tetramethylpiperidinyloxy)propylmethylsiloxane]-dimethylsiloxane copolymer, polydimethylsiloxane, carbinol (hydroxyl) terminated polydimethylsiloxane, monocarbinol terminated polydimethylsiloxane, monocarbinol terminated functional polydimethylsiloxane, [Bis(hydroxyethyl)amine] terminated polydimethylsiloxane, silanol terminated polydimethylsiloxane, silanol terminated polydiphenylsiloxane, dodecylmethylsiloxane-hydroxypolyalkyleneoxypropyl methylsiloxane and mixtures thereof. [0162] In one non-limiting embodiment, the silicon-based compound is hydrophilic compound selected from the group consisting of 3-aminopropylsilanetriol, N-(2-aminoethyl)-3- aminopropylsilanetriol and mixtures thereof. [0163] In one non-limiting embodiment, the maleated natural oil is selected from the group consisting of a maleated avocado oil, a maleated coconut oil, a maleated corn oil, a maleated cottonseed oil, a maleated jojoba oil, a maleated linseed oil, a maleated nut oil, a maleated olive oil, a maleated palm oil, a maleated raisin oil, a maleated rapeseed oil, a maleated safflower oil, a maleated sesame oil, a maleated soybean oil, a maleated squash oil, a maleated sunflower oil, a maleated almond oil, a maleated canola oil, a maleated flaxseed oil, a maleated grapeseed oil, a maleated palm oil, a maleated palm kernel oil, a maleated peanut oil, and a maleated walnut oil thereof. [0164] In another important embodiment, the present application provides a dispersant composition for coatings comprising (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0165] The preferences listed for the invention set out above for a “dispersant composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention. [0166] In one non-limiting embodiment, the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols. [0167] In another non-limiting embodiment, the dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol. [0168] The dispersant composition for coatings can be used in architectural coatings, metal coatings, marine coatings, paints, decorative paints, interior paints, exterior paints, non-woven coatings, ceramic coatings, anti-corrosion coatings, flame retardant coatings, glass coatings, protective coatings, powder coatings, wood coatings, industrial coatings, anti-fouling coatings, thermal insulation coatings, water-based coatings, and solvent based coatings. [0169] In another important embodiment, the present application provides a dispersant composition for personal care comprising (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0170] The preferences listed for the invention set out above for a “dispersant composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention. [0171] Preferably, the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols. The dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol. [0172] The dispersant composition for personal care can an emulsion selected from oil-in-water emulsion and water-in-oil emulsion. [0173] According to another embodiment of the present application, it is contemplated to employ at least one personal care functional ingredient selected from the group consisting of surfactants, water-insoluble ingredients, oxidizing agents, conditioning agents, humectants, pH adjusting buffers, waxes, mineral oils, emulsifiers, fatty substances, gelling agents, thickeners, emollients, hydrophilic or lipophilic active agent, antioxidants, sequestering agents, preserving agents, acidifying or basifying agents, fragrances, fillers, dyestuffs, plant extracts, moisturizers, proteins, peptides, neutralizing agents, solvents, anti-dandruff ingredients, reducing agents and combinations thereof. [0174] In some embodiments, the suitable range of personal care ingredient for the present application can be varied from about 0.1 wt.% to about 1 wt.%; or from about 1 wt.% to about 2.5 wt.%; or from about 2.5 wt.% to about 5 wt.%; or from about 5 wt.% to about 10 wt.%; or 10 wt.% to about 15 wt.%; or from about 15 wt.% to about 20 wt.%; or from about 20 wt.% to about 25 wt.%; or from about 25 wt.% to about 30 wt.%; or from about 30 wt.% to about 35 wt.%; or from about 35 wt.% to about 40 wt.%; or from about 40 wt.% to about 45 wt.%; or from about 45 wt.% to about 50 wt.%; or from about 50 wt.% to about 55 wt.%; or from about 55 wt.% to about 60 wt.%; or from about 60 wt.% to about 65 wt.%; or from about 65 wt.% to about 70 wt.%; or from about 70 wt.% to about 75 wt.%; or from about 75 wt.% to about 80 wt.%; or from about 80 wt.% to about 85 wt.%; or from about 85 wt.% to about 90 wt.% based on the total weight of the dispersant composition. [0175] Preferably personal care composition is a cosmetic care composition specifically applied to skin, nail and hair. [0176] In one embodiment of the present application, at least one primary surfactant, co-surfactant or a system of surfactants comprising at least one primary surfactant and at least one co-surfactant are employed to prepare sun care or skin care compositions, and wherein said primary surfactants, co-surfactants or a system surfactant can be selected from the group consisting of anionic surfactants, cationic surfactants, non-ionic surfactants, zwitterionic surfactants and amphoteric surfactants. The range of surfactants can be from 0.1 wt.% to 20 wt.% based on the total weight of the composition. Other ranges of surfactants are from 0.1 wt.% to 5 wt.%, from 5 wt.% to 10 wt.%, from 10 wt.% to 15 wt.%, or from 15 wt.% to 20 wt.% of total weight of the composition. The contemplated surfactants for use herein are as follows: [0177] (A) Anionic Surfactants: Anionic surfactants are particularly useful in accordance with certain embodiments of the present application. Surfactants of the anionic type that may be useful include: (1) Sulfonates and Sulfates: Suitable anionic surfactants include sulfonates and sulfates such as alkyl sulfates, alkylether sulfates, alkyl sulfonates, alkylether sulfonates, alkylbenzene sufonates, alkylbenzene ether sulfates, alkylsulfoacetates, secondary alkane sulfonates, secondary alkylsulfates, alkyl sulfosuccinates and the like. Further, examples of anionic surfactants include water-soluble salts of higher fatty acid monoglyceride monosulfates, such as the sodium salt of the monosulfated monoglyceride of hydrogenated coconut oil fatty acids, higher alkyl sulfates such as sodium lauryl sulfate, alkyl aryl sulfonates such as sodium dodecyl benzene sulfonate, higher alkyl sulfoacetates, higher fatty acid esters of 1,2-dihydroxy propane sulfonate, and the substantially saturated higher aliphatic acyl amides of lower aliphatic amino carboxylic acid compounds, such as those having 12 to 16 carbons in the fatty acid, alkyl or acyl radicals, and the like. (2) Phosphates and Phosponates: Suitable anionic surfactants also include phosphates such as alkyl phosphates, alkylether phosphates, aralkylphosphates, and aralkylether phosphates. Examples include a mixture of mono-, di- and tri-(alkyltetraglycolether)-o-phosphoric acid esters generally referred to as trilaureth-4-phosphate commercially available under the trade designation HOSTAPHAT 340KL from Clariant Corp., as well as PPG-5 ceteth 10 phosphate available under the trade designation CRODAPHOS SG from Croda Inc., Parsipanny, NJ. (3) Amine Oxides: Suitable anionic surfactants also include amine oxides. Examples of amine oxide surfactants include lauryldimethylamine oxide, laurylamidopropyldimethylamine oxide, and/or cetyl amine oxide. (B) Amphoteric Surfactants: Surfactants of the amphoteric type include surfactants having tertiary amine groups which may be protonated as well as quaternary amine containing zwitterionic surfactants. Those that may be useful include: (1) Ammonium Carboxylate Amphoterics: Examples of such amphoteric surfactants include but are not limited to certain betaines such as cocobetaine and cocamidopropyl betaine; monoacetates such as sodium lauroamphoacetate; diacetates such as disodium lauroamphoacetate; amino- and alkylamino-propionates such as lauraminopropionic acid. (2) Ammonium Sulfonate Amphoterics: These classes of amphoteric surfactants are often referred to as "sultaines" or "sulfobetaines" for example, cocamidopropylhydroxysultaine. (C) Nonionic Surfactants: Surfactants of the nonionic type that may be particularly useful include: (1) Polyethylene oxide extended sorbitan monoalkylates (i.e., Polysorbates); (2) Polyalkoxylated alkanols; (3) Polyalkoxylated alkylphenols include polyethoxylated octyl or nonyl phenols having HLB values of at least about 14, which are commercially available under the trade designations ICONOL and TRITON; (4) Polaxamers. Surfactants based on block copolymers of ethylene oxide (EO) and propylene oxide (PO) may also be effective. Both EO-PO-EO blocks, and PO-EO-PO blocks are expected to work well as long as the HLB is at least about 14, and preferably at least about 16. Such surfactants are commercially available under the trade designations PLURONIC and TETRONIC from BASF; (5) Polyalkoxylated esters - Polyalkoxylated glycols such as ethylene glycol, propylene glycol, glycerol, and the like may be partially or completely esterified, i.e., one or more alcohols may be esterified, with a (C8 to C22) alkyl carboxylic acid. Such polyethoxylated esters having an HLB of at least about 14, and preferably at least about 16, may be suitable for use in compositions of the present invention; (6) Alkyl Polyglucosides – This includes glucopon 425, which has a (C8 to C16) alkyl chain length. (D) Cationic Surfactants: Surfactants of the cationic type that may be useful include but are not limited to, primary amines, secondary amines, tertiary amines, quaternary amines, alkanolamines, mono-alkyl alkanolamines, di-alkyl alkanolamines, tri-alkyl alkanolamines, alkyl mono alkanolamines, alkyl di-alkanolamines, alkylamines, mono-alkyl amines, di-alkyl amines, tri- alkylamines, alkoxylated amines, alkyl and aryl amine alkoxylates, methoxylated alkylamines, ethoxylated alkylamines, alkoxylated alkanolamines, alkyl alkanolamines, alkoxylated ethylene diamine derivatives, alkyl/aryl/arylalkyl amine oxides. Preferred cationic surfactants of the present invention include, but are not limited to, (a) alkyl alkanolamines; and (b) alkyl tertiary amines. Additional information on useful cationic surfactants for the purpose of present invention is set forth in McCutcheon's Detergents and Emulsifiers, North American Ed., 1982 and Kirk-Othmer, Encyclopedia of Chemical Technology, 3rd Ed., Vol.22, pp.346-387, the contents of which are incorporated herein by reference. [0178] Suitable emollients for use herein include, for example, optionally hydroxy-substituted C8 -C50 unsaturated fatty acids and esters thereof, C1 - C24 esters of C8 -C30 saturated fatty acids such as isopropyl myristate, cetyl palmitate and octyldodecylmyristate (Wickenol 142), beeswax, saturated and unsaturated fatty alcohols such as behenyl alcohol and cetyl alcohol, hydrocarbons such as mineral oils, petrolatum, squalane, fatty sorbitan esters, lanolin and lanolin derivatives, such as lanolin alcohol ethoxylated, hydroxylated and acetylated lanolins, cholesterol and derivatives thereof, animal and vegetable triglycerides such as almond oil, peanut oil, wheat germ oil, linseed oil, jojoba oil, oil of apricot pits, walnuts, palm nuts, pistachio nuts, sesame seeds, rapeseed, cade oil, corn oil, peach pit oil, poppyseed oil, pine oil, castor oil, soybean oil, avocado oil, safflower oil, coconut oil, hazelnut oil, olive oil, grapeseed oil, and sunflower seed oil and C1 -C24 esters of dimer and trimer acids such as diisopropyl dimerate, diisostearyl malate, diisostearyl dimerate and triisostearyltrimerate. [0179] Suitable emollients for use herein include isocetyl alcohol, octyl palmitate, isostearyl neopentanoate and isocetyl stearyl stearate, natural or synthetic oils selected from mineral, vegetable, and animal oils, fats and waxes, fatty acid esters, fatty alcohols, alkylene glycol and polyalkylene glycol ethers and esters, fatty acids, and mixtures thereof. [0180] Preferred emollients are selected from hydrocarbons such as isohexadecane, mineral oils, petrolatum, squalene, lanolin alcohol, and stearyl alcohol. These emollients may be used independently or in mixtures and may be present in the composition of the present invention in an amount from about 1% to about 30% by weight, and preferably are present in an amount from about 5% to about 15% by weight of the total composition. [0181] Suitable emulsifiers include the following classes of ethers and esters: ethers of polyglycols and of fatty alcohols, esters of polyglycols and of fatty acids, ethers of polyglycols and of fatty alcohols which are glycosylated, esters of polyglycols and of fatty acids which are glycosylated, ethers of C12-30 alcohols and of glycerol or of polyglycerol, esters of C12-30 fatty acids and of glycerol or of polyglycerol, ethers of oxyalkylene-modified C12-30 alcohols and of glycerol or polyglycerol, ethers of C12-30fatty alcohols comprising and of sucrose or of glucose, esters of sucrose and of C12-30 fatty acids, esters of pentaerythritol and of C12-30 fatty acids, esters of sorbitol and/or of sorbitan and of C12-30 fatty acids, ethers of sorbitol and/or of sorbitan and of alkoxylated sorbitan, ethers of polyglycols and of cholesterol, esters of C12-30 fatty acids and of alkoxylated ethers of sorbitol and/or sorbitan, and combinations thereof. Linear or branched type silicone emulsifiers may also be used. Particularly useful polyether modified silicones include KF- 6011, KF-6012, KF-6013, KF-6015, KF-6015, KF-6017, KF-6043, KF-6028, and KF-6038 from Shin-Etsu. Also particularly useful are the polyglycerolated linear or branched siloxane emulsifiers including KF-6100, KF-6104, and KF-6105 from Shin-Etsu. Emulsifiers also include glyceryl stearate and laureth 23, PEG 20 stearate, and mink-amidopropyl dimethyl 2- hydroxyethylammonium chloride and emulsifying silicone elastomers. Suitable emulsifying silicone elastomers may include at least one polyalkyl ether or polyglycerolated unit. [0182] Moisturizers employed in the present application would include glycols, glycerols, propylene glycol, diethylene glycol monoethyl ether, sorbitol, sodium salt of pyroglutamic acid, glycerol, glycerol derivatives, glycerin, trehalose, sorbitol, maltitol, dipropylene glycol, 1,3- butylene glycol, sodium hyaluronate, and the like. [0183] Examples of humectants which can be incorporated into a product of the present application are glycerine, propylene glycol, polypropylene glycol, polyethylene glycol, lactic acid, sodium lactate, pyrrolidone carboxylic acid, urea, phospholipids, collagen, elastin, ceramides, lecithin sorbitol, PEG-4, and mixtures thereof. Additional suitable moisturizers are polymeric moisturizers that belong to water soluble and/or water swellable in nature. Polysaccharides such as hyaluronic acid, chitosan can also be employed along with moisturizers of the present application as binder to enhance their property. The range of moisturizer is from about 0.1 wt. % to about 10 wt. %. [0184] The compositions of the invention can also contain a hydrophilic gelling agent at a level from about 0.01% to about 10%, preferably from about 0.02% to about 2%, and especially from about 0.02% to about 0.5%. The gelling agent preferably has a viscosity (1% aqueous solution, 20° C., Brookfield RVT) of at least about 4000 mPa.s, more preferably at least about 10,000 mPa.s and especially at least 50,000 mPa.s. [0185] Suitable hydrophilic gelling agents can generally be described as water-soluble or colloidally water-soluble polymers and include cellulose ethers (e.g. Hydroxyethyl cellulose, methyl cellulose, hydroxypropyl methyl cellulose), polyvinylalcohol, polyquaternium-10, guar gum, hydroxypropyl guar gum and xanthan gum. [0186] Among suitable hydrophilic gelling agents are acrylic acid/ethyl acrylate copolymers and the carboxyvinyl polymers sold by the B.F. Goodrich Company under the trademark of Carbopol® resins. These resins consist essentially of a colloidally water-soluble polyalkenyl polyether crosslinked polymer of acrylic acid crosslinked with from 0.75% to 2.00% of a crosslinking agent such as polyallyl sucrose or polyally pentaerythritol. Examples include Carbopol 934, Carbopol 940, Carbopol 950, Carbopol 980, Carbopol 951 and Carbopol 981. Carbopol 934 is a water- soluble polymer of acrylic acid crosslinked with about 1% of a polyallyl ether of sucrose having an average of about 5.8 allyl groups for each sucrose molecule. Also suitable for use herein are hydrophobically modified crosslinked polymers of acrylic acid having amphipathic properties available under the Trade Name Carbopol 1382, Carbopol 1342 and Pemulen TR-1 (CTFA Designation: Acrylates/10-30 Alkyl Acrylate Crosspolymer). A combination of the polyalkenyl polyether cross-linked acrylic acid polymer and the hydrophobically modified crosslinked acrylic acid polymer is also suitable for use herein. Other suitable gelling agents suitable for use herein are oleogels such as trihydroxystearin and aluminum magnesium hydroxy stearate. [0187] Non-limiting examples of suitable thickeners and/or viscosifiers include: Acetamide MEA; acrylamide/ethalkonium chloride acrylate copolymer; acrylamide/ethyltrimonium chloride acrylate/ethalkonium chloride acrylate copolymer; acrylamides copolymer; acrylamide/sodium acrylate copolymer; acrylamide/sodium acryloyldimethyltaurate copolymer; acrylates/acetoacetoxyethyl methacrylate copolymer; acrylates/beheneth-25 methacrylate copolymer; acrylates/C10-C30 alkyl acrylate crosspolymer; acrylates/ceteth-20 itaconate copolymer; acrylates/ceteth-20 methacrylate copolymer; acrylates/laureth-25 methacrylate copolymer; acrylates/palmeth-25 acrylate copolymer; acrylates/palmeth-25 itaconate copolymer; acrylates/steareth-50 acrylate copolymer; acrylates/steareth-20 itaconate copolymer; acrylates/steareth-20 methacrylate copolymer; acrylates/stearyl methacrylate copolymer; acrylates/vinyl isodecanoate crosspolymer; acrylic acid/acrylonitrogens copolymer; adipic acid/methyl DEA crosspolymer; agar; agarose; alcaligenes polysaccharides; algin; alginic acid; almondamide DEA; almondamidopropyl betaine; aluminum/magnesium hydroxide stearate; ammonium acrylates/acrylonitrogens copolymer; ammonium acrylates copolymer; ammonium acryloyldimethyltaurate/vinyl formamide copolymer; ammonium acryloyldimethyltaurate/VP copolymer; ammonium alginate; ammonium chloride; ammonium polyacryloyldimethyl taurate; ammonium sulfate; amylopectin; apricotamide DEA; apricotamidopropyl betaine; arachidyl alcohol; arachidyl glycol; arachis hypogaea (peanut) flour; ascorbyl methylsilanol pectinate; astragalus gummifer gum; attapulgite; avena sativa (oat) kernel flour; avocadamide DEA; avocadamidopropyl betaine; azelamide MEA; babassuamide DEA; babassuamide MEA; babassuamidopropyl betaine; behenamide DEA; behenamide MEA; behenamidopropyl betaine; behenyl betaine; bentonite; butoxy chitosan; caesalpinia spinosa gum; calcium alginate; calcium carboxymethyl cellulose; calcium carrageenan; calcium chloride; calcium potassium carbomer; calcium starch octenylsuccinate; C20-40 alkyl stearate; canolamidopropyl betaine; capramide DEA; capryl/capramidopropyl betaine; carbomer; carboxybutyl chitosan; carboxymethyl cellulose acetate butyrate; carboxymethyl chitin; carboxymethyl chitosan; carboxymethyl dextran; carboxymethyl hydroxyethylcellulose; carboxymethyl hydroxypropyl guar; carnitine; cellulose acetate propionate carboxylate; cellulose gum; ceratonia siliqua gum; cetearyl alcohol; cetyl alcohol; cetyl babassuate; cetyl betaine; cetyl glycol; cetyl hydroxyethylcellulose; chimyl alcohol; cholesterol/HDI/pullulan copolymer; cholesteryl hexyl dicarbamate pullulan; citrus aurantium dulcis (orange) peel extract; cocamide DEA; cocamide MEA; cocamide MIPA; cocamidoethyl betaine; cocamidopropyl betaine; cocamidopropyl hydroxysultaine; coco-betaine; coco- hydroxysultaine; coconut alcohol; coco/oleamidopropyl betaine; coco-Sultaine; cocoyl sarcosinamide DEA; cornamide/cocamide DEA; cornamide DEA; croscarmellose; cross-linked bacillus/glucose/sodium glutamate ferment; cyamopsis tetragonoloba (guar) gum; decyl alcohol; decyl betaine; dehydroxanthan gum; dextrin; dibenzylidene sorbitol; diethanolaminooleamide DEA; diglycol/CHDM/isophthalates/SIP copolymer; dihydroabietyl behenate; dihydrogenated tallow benzylmonium hectorite; dihydroxyaluminum aminoacetate; dimethicone/PEG-10 crosspolymer; dimethicone/PEG-15 crosspolymer; dimethicone propyl PG-betaine; dimethylacrylamide/acrylic acid/polystyrene ethyl methacrylate copolymer; dimethylacrylamide/sodium acryloyldimethyltaurate crosspolymer; disteareth-100 IPDI; DMAPA acrylates/acrylic acid/acrylonitrogens copolymer; erucamidopropyl hydroxysultaine; ethylene/sodium acrylate copolymer; gelatin; gellan gum; glyceryl alginate; glycine soja (soybean) flour; guar hydroxypropyltrimonium chloride; hectorite; hyaluronic acid; hydrated silica; hydrogenated potato starch; hydrogenated tallow; hydrogenated tallowamide DEA; hydrogenated tallow betaine; hydroxybutyl methylcellulose; hydroxyethyl acrylate/sodium acryloyldimethyl taurate copolymer; hydroxyethylcellulose; hydroxyethyl chitosan; hydroxyethyl ethylcellulose; hydroxyethyl stearamide-MIPA; hydroxylauryl/hydroxymyristyl betaine; hydroxypropylcellulose; hydroxypropyl chitosan; hydroxypropyl ethylenediamine carbomer; hydroxypropyl guar; hydroxypropyl methylcellulose; hydroxypropyl methylcellulose stearoxy ether; hydroxypropyl starch; hydroxypropyl starch phosphate; hydroxypropyl xanthan gum; hydroxystearamide MEA; isobutylene/sodium maleate copolymer; isostearamide DEA; isostearamide MEA; isostearamide mIPA; isostearamidopropyl betaine; lactamide MEA; lanolinamide DEA; lauramide DEA; lauramide MEA; lauramide MIPA; lauramide/myristamide DEA; lauramidopropyl betaine; lauramidopropyl hydroxysultaine; laurimino bispropanediol; lauryl alcohol; lauryl betaine; lauryl hydroxysultaine; lauryl/myristyl glycol hydroxypropyl ether; lauryl sultaine; lecithinamide DEA; linoleamide DEA; linoleamide MEA; linoleamide MIPA; lithium magnesium silicate; lithium magnesium sodium silicate; macrocystis pyrifera (kelp); magnesium alginate; magnesium/aluminum/hydroxide/carbonate; magnesium aluminum silicate; magnesium silicate; magnesium trisilicate; methoxy PEG-22/dodecyl glycol copolymer; methylcellulose; methyl ethylcellulose; methyl hydroxyethylcellulose; microcrystalline cellulose; milkamidopropyl betaine; minkamide DEA; minkamidopropyl betaine; MIPA-myristate; montmorillonite; Moroccan lava clay; myristamide DEA; myristamide MEA; myristamide MIPA; myristamidopropyl betaine; myristamidopropyl hydroxysultaine; myristyl alcohol; myristyl betaine; natto gum; nonoxynyl hydroxyethylcellulose; oatamide MEA; oatamidopropyl betaine; octacosanyl glycol isostearate; octadecene/MA copolymer; oleamide DEA; oleamide MEA; oleamide MIPA; oleamidopropyl betaine; oleamidopropyl hydroxysultaine; oleyl betaine; olivamide DEA; olivamidopropyl betaine; oliveamide MEA; palmamide DEA; palmamide MEA; palmamide MIPA; palmamidopropyl betaine; palmitamide DEA; palmitamide MEA; palmitamidopropyl betaine; palm kernel alcohol; palm kernelamide DEA; palm kernelamide MEA; palm kernelamide MIPA; palm kernelamidopropyl betaine; peanutamide MEA; peanutamide MIPA; pectin; PEG-800; PEG-crosspolymer; PEG-150/decyl alcohol/SMDI copolymer; PEG-175 diisostearate; PEG-190 distearate; PEG-15 glyceryl tristearate; PEG-140 glyceryl tristearate; PEG-240/HDI copolymer bis-decyltetradeceth-20 ether; PEG-100/IPDI copolymer; PEG-180/laureth-50/TMMG copolymer; PEG-10/lauryl dimethicone crosspolymer; PEG-15/lauryl dimethicone crosspolymer; PEG-2M; PEG-5M; PEG-7M; PEG-9M; PEG-14M; PEG-20M; PEG-23M; PEG-25M; PEG-45M; PEG-65M; PEG-90M; PEG-115M; PEG-160M; PEG-180M; PEG-120 methyl glucose trioleate; PEG-180/octoxynol-40/TMMG copolymer; PEG- 150 pentaerythrityl tetrastearate; PEG-4 rapeseedamide; PEG-150/stearyl alcohol/SMDI copolymer; phaseolus angularis seed powder; polianthes tuberosa extract; polyacrylate-3; polyacrylic acid; polycyclopentadiene; polyether-1; polyethylene/isopropyl maleate/MA copolyol; polyglyceryl-3 disiloxane dimethicone; polyglyceryl-3 polydimethylsiloxyethyl dimethicone; polymethacrylic acid; polyquaternium-52; polyvinyl alcohol; potassium alginate; potassium aluminum polyacrylate; potassium carbomer; potassium carrageenan; potassium chloride; potassium palmate; potassium polyacrylate; potassium sulfate; potato starch modified; PPG-2 cocamide; PPG-1 hydroxyethyl caprylamide; PPG-2 hydroxyethyl cocamide; PPG-2 hydroxyethyl coco/isostearamide; PPG-3 hydroxyethyl soyamide; PPG-14 laureth-60 hexyl dicarbamate; PPG-14 laureth-60 isophoryl dicarbamate; PPG-14 palmeth-60 hexyl dicarbamate; propylene glycol alginate; PVP/decene copolymer; PVP montmorillonite; pyrus cydonia seed; pyrus malus (apple) fiber; rhizobian gum; ricebranamide DEA; ricinoleamide DEA; ricinoleamide MEA; ricinoleamide MIPA; ricinoleamidopropyl betaine; ricinoleic acid/adipic acid/AEEA copolymer; rosa multiflora flower wax; sclerotium gum; sesamide DEA; sesamidopropyl betaine; sodium acrylate/acryloyldimethyl taurate copolymer; sodium acrylates/acrolein copolymer; sodium acrylates/acrylonitrogens copolymer; sodium acrylates copolymer; sodium acrylates crosspolymer; sodium acrylate/sodium acrylamidomethylpropane sulfonate copolymer; sodium acrylates/vinyl isodecanoate crosspolymer; sodium acrylate/vinyl alcohol copolymer; sodium carbomer; sodium carboxymethyl chitin; sodium carboxymethyl dextran; sodium carboxymethyl beta-glucan; sodium carboxymethyl starch; sodium carrageenan; sodium cellulose sulfate; sodium chloride; sodium cyclodextrin sulfate; sodium hydroxypropyl starch phosphate; sodium isooctylene/MA copolymer; sodium magnesium fluorosilicate; sodium oleate; sodium palmitate; sodium palm kernelate; sodium polyacrylate; sodium polyacrylate starch; sodium polyacryloyldimethyl taurate; sodium polygamma-glutamate; sodium polymethacrylate; sodium polystyrene sulfonate; sodium silicoaluminate; sodium starch octenylsuccinate; sodium stearate; sodium stearoxy PG-hydroxyethylcellulose sulfonate; sodium styrene/acrylates copolymer; sodium sulfate; sodium tallowate; sodium tauride acrylates/acrylic acid/acrylonitrogens copolymer; sodium tocopheryl phosphate; solanum tuberosum (potato) starch; soyamide DEA; soyamidopropyl betaine; starch/acrylates/acrylamide copolymer; starch hydroxypropyltrimonium chloride; stearamide AMP; stearamide DEA; stearamide DEA-distearate; stearamide DIBA- stearate; stearamide MEA; stearamide MEA-stearate; stearamide MIPA; stearamidopropyl betaine; steareth-60 cetyl ether; steareth-100/PEG-136/HDI copolymer; stearyl alcohol; stearyl betaine; sterculia urens gum; synthetic fluorphlogopite; tallamide DEA; tallow alcohol; tallowamide DEA; tallowamide MEA; tallowamidopropyl betaine; tallowamidopropyl hydroxysultaine; tallowamine oxide; tallow betaine; tallow dihydroxyethyl betaine; tamarindus indica seed gum; tapioca starch; TEA-alginate; TEA-carbomer; TEA-hydrochloride; trideceth-2 carboxamide MEA; tridecyl alcohol; triethylene glycol dibenzoate; trimethyl pentanol hydroxyethyl ether; triticum vulgare (wheat) germ powder; triticum vulgare (wheat) kernel flour; triticum vulgare (wheat) starch; tromethamine acrylates/acrylonitrogens copolymer; tromethamine magnesium aluminum silicate; undecyl alcohol; undecylenamide DEA; undecylenamide MEA; undecylenamidopropyl betaine; welan gum; wheat germamide DEA; wheat germamidopropyl betaine; xanthan gum; yeast beta-glucan; yeast polysaccharides; zea mays (corn) starch; and blends thereof. [0188] Preferred thickeners for use herein include crosslinked maleic anhydride-alkyl methyl vinyl ethers, and copolymers, sold as Stabileze® QM (International Specialty Products (ISP)). Also useful are Carbomer®, natural gums, highly crosslinked polymethacrylate copolymer such as Microsponges® 5647, which take the form of generally spherical particles of crosslinked hydrophobic polymer having a pore size of from about 0.01 to about 0.05 μm and a surface area of 200-300 m2 /g. [0189] Neutralizing agents suitable for use in neutralizing acidic group containing hydrophilic gelling agents herein include sodium hydroxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanolamine and triethanolamine, and aminomethyl propanol. [0190] The skin care and sun care composition of present application can be preserved by adding minor quantity of preservatives to the compositions. Such preservatives can be selected from, but are not limited to triazoles, imidazoles, naphthalene derivatives, benzimidazoles, morpholine derivatives, dithiocarbamates, benzisothiazoles, benzamides, boron compounds, formaldehyde donors, isothiazolones, thiocyanates, quaternary ammonium compounds, iodine derivates, phenol derivatives, microbicides, pyridines, dialkyl thiocarbamates, nitriles, parabens, alkyl parabens and salts thereof. Wherein the range of preservative employed is in the range of from about 0.01 wt. % to about 10 wt. %. The preservative concentration in the composition, based on the total weight of that composition, is in the range of between about 0.05% and about 1.0% by weight, preferably between about 0.1% and about 0.4% by weight. Suitable preservatives for use herein include sodium benzoate and propyl paraben, and mixtures thereof. [0191] The preferred fatty substance-based additive/excipient for the present application include fatty alcohols, natural and synthetic waxes, ceramides, mineral oils, vegetable oils, animal oils, synthetic oils. The other preferred fatty substances are isododecane, hydrogenated polyisobutene, squalane, isononyl isononanoate, cyclotetra- and – penta dimethicones, phenyl trimethicone, ethylene homopolymers, ethoxylated fats and oils, fluoroalkanes, seracite, shea butter, arachidyl propionate alone or in combination. For the definition of waxes, mention may be made, for example, of P. D. Dorgan, Drug and Cosmetic Industry, December 1983, pp.30-33. [0192] The suitable solvent of the present application can consist of water, a cosmetically /dermatologically acceptable solvent, or a blend of water and a cosmetically / dermatologically acceptable solvent, such as a lower alcohol composed of C1 to C4, such as ethanol, isopropanol, t-butanol, n-butanol, alkylene glycols such as propylene glycol, and glycol ethers. However, the compositions of the invention can be anhydrous. The most preferred solvents of the present application would include water, ethanol and/or iso-propanol. It is contemplated to employ other suitable solvents for preparing products of the present application which would include but are not limited to, linear and branched C1-C6 alcohols, such as ethanol, propanol, isopropanol, butanol, hexanol, and mixtures thereof; aromatic alcohols, such as benzyl alcohol, cycloaliphatic alcohols, such as cyclohexanol, and the like; saturated C12-C30 fatty alcohol, such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, and the like. Non-limiting examples of polyols include polyhydroxy alcohols, such as glycerin, propylene glycol, butylene glycol, hexylene glycol, C2-C4 alkoxylated alcohols and C2-C4 alkoxylated polyols, such as ethoxylated, propoxylated, and butoxylated ethers of alcohols, diols, and polyols having about 2 to about 30 carbon atoms and 1 to about 40 alkoxy units, polypropylene glycol, polybutylene glycol, and the like. Non-limiting examples of non-aqueous auxiliary solvents include silicones, and silicone derivatives, such as cyclomethicone, and the like, aliphatic solvents such as cyclohexane and heptane, ketones such as acetone and methyl ethyl ketone, and mixtures thereof; ethers such as diethyl ether, dimethoxymethane, and mixtures thereof, natural and synthetic oils and waxes, such as vegetable oils, plant oils, animal oils, essential oils, mineral oils, C7-C40 isoparaffins, alkyl carboxylic esters, such as ethyl acetate, amyl acetate, ethyl lactate, and the like, jojoba oil, shark liver oil, and the like. [0193] The alkaline pH adjusting agents such as alkali metal hydroxides, for example, sodium hydroxide, and potassium hydroxide; ammonium hydroxide; organic bases, such as triethanolamine, diisopropylamine, dodecylamine, diisopropanolamine, aminomethyl propanol, cocamine, oleamine, morpholine, triamylamine, triethylamine, tromethamine (2-amino-2- hydroxymethyl)-1,3-propanediol), and tetrakis(hydroxypropyl)ethylenediamine; and alkali metal salts of inorganic acids, such as sodium borate (borax), sodium phosphate, sodium pyrophosphate, and the like, and mixtures thereof. Acidic pH adjusting agents can be organic acids, including amino acids, and inorganic mineral acids. Non-limiting examples of acidic pH adjusting agents include acetic acid, citric acid, fumaric acid, glutamic acid, glycolic acid, hydrochloric acid, lactic acid, nitric acid, phosphoric acid, sodium bisulfate, sulfuric acid, tartaric acid, and the like, and mixtures thereof. The desired pH of the personal care composition is in the range of from about 2 to about 13, and in some embodiment, it is preferably between about 4 to about 8. The utility levels of the pH modifying agent can be present in an effective amount required to achieve the desired pH level. [0194] The coloring agents, colorants or dyes used herein include natural foods colors and dyes suitable for food, drug and cosmetic applications. These colorants are also known as FD & C, and D&C dyes and lakes and are preferably water-soluble in nature. A full recitation of all FD&C and D&C dyes and their corresponding chemical structures may be found in the Kirk-Othmer Encyclopedia of Chemical Technology, Volume 5, pages 857-884, which text is accordingly incorporated herein by reference. These coloring agents may be incorporated in amount up to about 3%, more particularly up to about 2%, and in some cases less than about 1% by weight of the personal care compositions. [0195] A perfume or fragrance obtained from natural or synthetic source can be employed in the present skin/sun care composition. The fragrance can be used along with a suitable solvent, diluents or carrier. Fragrances may be added in any conventionally known method, for example, admixing to a composition or blending with other ingredients used to form a composition, in amounts which are found to be useful to increase or impart the desired scent characteristics to the disinfectant or cleaning compositions. Fragrances for the present application can be one or more selected from the following non-limiting group of compounds such as essential oils, absolutes, resinoids, resins, concretes, hydrocarbons, alcohols, aldehydes, ketones, ethers, acids, esters, acetals, ketals, nitriles, including saturated and unsaturated compounds and aliphatic, carbocyclic, and heterocyclic compounds. [0196] Suitable sunscreens which can be formulated into the compositions of the instant invention are those selected from among: methoxydibenzoyl methane; octyl salicylate; pentyl dimethyl PABA; octyl dimethyl PABA; benzophenone-1; benzophenone-6; 2-(2H-benzotriazole-2-yl)-4,6- di-tert- pentylphenol; ethyl-2-cyano-3,3-diphenylacrylate; homomethyl salicylate (homosalate); bis-ethylhexyloxyphenol methoxyphenyl triazine; methyl-(l,2,2,6,6-pentamethyl-4- piperidyl)- sebacate; 2-(2H-benzotriazole-2-yl)-4-methylphenol; diethylhexyl butamido triazone; amyl dimethyl PABA; 4,6-bis(octylthiomethyl)-o-cresol; red petroleum; ethylhexyl triazone; octocrylene; isoamyl-p-methoxycinnamate; drometrizole; titanium dioxide; 2,4-di-tert-butyl-6-(5- chloro-2H-benzotriazole-2-yl)-phenol; 2-hydroxy-4- octyloxybenzophenone; benzophenone-2; diisopropyl methylcinnamate; PEG-25 PABA; 2-(l,l-dimethylethyl)-6-[[3-(l,l-demethylethyl)-2- hydroxy-5-methylphenyl]methyl-4- methylphenyl acrylate; drometrizole trisiloxane; menthyl anthranilate; butyl methoxydibenzoyl methane; 2-ethoxyethyl p-methoxycinnamate; benzylidene camphor sulfonic acid; dimethoxyphenyl-[l-(3,4)]-4,4-dimethyl 1,3-pentanedione; zinc oxide; N,N'-hexane-l,6-diylbis[3-(3,5-di-tert-butyl-4-hydroxyphenylpropionamide)]; pentaerythritol tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]; 2,6-di-tert- butyl-4-[4,6-bis(octylthio)- l,3,5-triazin-2-ylamino]phenol; 2-(2H-benzotriazole-2-yl)- 4,6-bis(l-methyl-l-phenylethyl) phenol; trolamine salicylate; diethylanolamine p- methoxycinnamate; polysilicone-15; 4- methylbenzylidene camphor; bisoctrizole; N- phenyl-benzenamine; reaction products with 2,4,4- trimethylpentene; sulisobenzone; (2- ethylhexyl)-2-cyano-3,3-diphenylacrylate; digalloyl trioleate; polyacrylamido methylbenzylidene camphor; glyceryl ethylhexanoate dimethoxycinnamate; l,3-bis-[(2'- cyano-3',3'-diphenylacryloyl)oxy]-2,2-bis-[(2'-cyano-bis- (2,2,6,6-tetramethyl-4- piperidyl) - sebacate ; benzophenone- 5 ; 1 , 3 , 5 -tris (3 ,5 -di-tert-butyl- 4-hydroxybenzyl) -1,3,5- triazine-2,4,6(lH,3H,5H)-trione; hexamethylendiamine; benzophenone- 8; ethyl-4- bis(hydroxypropyl)aminobenzoate; 6-tert-butyl-2-(5-chloro-2H-benzotriazole-2-yl)-4- methylphenol; p-aminobenzoic acid; 3,3',3",5,5',5"-hexa-tert-butyl-a-a'-a"-(mesitylene- 2,4,6- triyl)tri-p-cresol; lawsone with dihydroxyacetone; benzophenone-9; benzophenone - 4; ethylhexyl dimethoxy benzylidene dioxoimidazoline propionate; N,N'-bisformyl-N,N'- bis-(2,2,6,6- tetramethyl-4-piperidinyl)-; 3-benzylidene camphor; terephthalylidene dicamphor sulfonic acid; camphor benzalkonium methosulfate; bisdisulizole disodium; etocrylene; ferulic acid; 2-(2H- benzotriazole-2-yl)-4-(l,l,3,3-tetramethylbutyl)-phenol; 4,6-bis(dodecylthiomethyl)-o-cresol; β-2- glucopyranoxy propyl hydroxy benzophenone; phenylbenzimidazole sulfonic acid; benzophenone-3; diethylamine hydroxybenzoyl hexylbenzoate; 3',3'-diphenylacryloyl) oxy]methyl}-propane; ethylhexyl p- methoxycinnamate, and blends thereof. [0197] Suitable sunscreens which can be formulated into the compositions of the instant invention are those selected from among: aminobenzoic acid, amyldimethyl PABA, cinoxate, diethanolamine p-methoxycinnamate, digalloyl trioleate, dioxybenzone, 2-ethoxyethyl p- methoxycinnamate, ethyl 4-bis(hydroxypropyl)aminobenzoate, 2-ethylhexyl-2-cyano-3,3- diphenylacrylate, ethylhexyl p-methoxycinnamate, 2-ethylhexyl salicylate, glyceryl aminobenzoate, homomenthyl salicylate, homosalate, 3-imidazol-4-ylacrylic acid and ethyl ester, methyl anthranilate, octyldimethyl PABA, 2-phenylbenzimidazole-5-sulfonic acid and salts, red petrolatum, sulisobenzone, titanium dioxide, triethanolamine salicylate, N,N,N-trimethyl-4-(2- oxoborn-3-ylidene methyl)anillinium methyl sulfate, and mixtures thereof. [0198] The composition may also contain additional materials such as, for example, fillers such as nylon, electrolytes such as sodium chloride, proteins, antioxidants, and chelating agents as appropriate. [0199] Synthetic essential oils may include, for example, esters, such as acetylated castor oil, cetyl octanoate, cetyl palmitate, cetyl ricinoleate, cetyl stearate, cetyl myristate, coco- dicaprylate/caprate, decyl isostearate, dioctyl malate, glyceryl stearate, glyceryl dioleate, glyceryl distearate, glyceryl trioctanoate, glyceryl distearate, glyceryl linoleate, glyceryl myristate, glyceryl isostearate, hydrogenated castor oil, PEG castor oils, PEG glyceryl oleates, PEG glyceryl stearates, PEG glyceryl tallowates, PEG-4 diheptanoate, myristyl myristate, octadecanoyl isotridecyl isononanoate, octyl palmitate, isostearyl neopentanoate, tridecyl neopentanoate, isodecyl oleate, isodecyl neopentanoate, isohexyl neopentanoate, tridecyl octanoate, tridecyl octanoate; fatty alcohols such as oleyl alcohol, isocetyl alcohol; and silicone. [0200] In another important embodiment, the present application provides a dispersant composition for color cosmetics comprising (i) at least one dispersing agent comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (ii) at least one solid particulate component. [0201] The preferences listed for the invention set out above for a “dispersant composition comprising a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof” also apply to this aspect of the invention. [0202] In one non-limiting embodiment, the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols. [0203] In another non-limiting embodiment, the dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol. [0204] In one non-limiting embodiment, the composition further comprises at least one-color cosmetic ingredient. The present dispersant composition can be used in color cosmetic application selected from the group consisting of a facial foam/cream, cleansing, massage cream, pack, lotion, milky lotion, cream, serum, makeup base, and sunscreen, and finishing cosmetics including foundation, white powder, eye shadow, eyeliner, mascara, eyebrow, concealer, lipstick, lip gloss, and lip balm. [0205] In yet another important non-limiting embodiment, the present application provides a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; and (B) 2 to 70 wt.% of at least one solid particulate component. [0206] In another embodiment, the present application provides a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety. [0207] Accordingly, the reaction product is selected from the group of structures represented by the following structures:
, and combinations thereof. [0208] Accordingly, the base is selected from the group consisting of inorganic bases, organic bases, and mixtures thereof. The inorganic base is selected from the group consisting of oxides of alkali metals and alkaline earth metals, hydroxides of alkali metals and alkaline earth metals, carbonates of alkali metals and alkaline earth metals, bicarbonates of alkali metals and alkaline earth metals, oxides of transition metals, hydroxides of transition metals, carbonates of transition metals, bicarbonates of transition metals, and combinations thereof. Further, the inorganic base is selected from the group consisting of oxides, hydroxides, carbonates and bicarbonates of sodium, calcium, and combinations thereof. [0209] Accordingly, the alkali metal is selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, francium, and mixtures thereof. the alkaline earth metal is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, and mixtures thereof. the transition metal is selected from the group consisting of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, rutherfordium, dubnium, seaborgium, bohrium, hassium, meitnerium, darmstadtium, roentgenium, and mixtures thereof. [0210] Accordingly, the organic base is selected from the group consisting of ammonia, primary amines, secondary amines, pyridine, imidazole, benzimidazole, histidine, guanidine, and mixtures thereof. [0211] In another embodiment, the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component. [0212] In another embodiment, the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component. [0213] In another embodiment, the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (ii) at least one solid particulate component. [0214] In another embodiment, the present application provides a dispersant composition for personal care, the composition comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (c) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (B) from about 1.0 to about 90.0 wt.% of one or more personal care active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient. [0215] In another embodiment, the present application provides a dispersant composition for personal care application comprising: (A) from about 0.01 to about 20.0 wt.% of a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide and mixtures thereof; and (c) 2-octyldodecyl alcohol, glycerol, or combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the 2-octyldodecyl alcohol or glycerol; (B) from about 1.0 to about 90.0 wt.% of one or more agricultural active ingredient; and (C) from about 1.0 to about 99.0 wt.% of one or more additional ingredient. [0216] In another embodiment, the present application provides a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base. [0217] In another embodiment, the reaction product is represented by the following structure: wherein R is one or more hydrophilic or hydrophobic moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, aryl and alkaryl moieties containing from about 1 to about 36 carbon atoms; and wherein each Q is independently selected from the group consisting of H, Li, Na, K, Rb, Cs, Fr, ½ Mg, ½ Ca, ½ Co, ½ Cu, ½ Zn, ammonium, alkylammonium, dialkylammonium, trialkylammonium and tetraalkylammonium. [0218] Accordingly, the reaction product is a polymer represented by the following structure: wherein n is greater than 1; wherein R is one or more hydrophilic or hydrophobic moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, aryl and alkaryl moieties containing from about 1 to about 36 carbon atoms; and wherein each Q is independently selected from the group consisting of H, Li, Na, K, Rb, Cs, Fr, ½ Mg, ½ Ca, ½ Co, ½ Cu, ½ Zn, ammonium, alkylammonium, dialkylammonium, trialkylammonium and tetraalkylammonium. [0219] Accordingly, the reaction product is selected from the group of structures represented by the following structures:
[0220] Accordingly, the reaction product is a polymer selected from the group of structures represented by the following structures: wherein 1 < n < 30. [0221] In another embodiment, the present application provides a dispersant composition for coatings, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component. [0222] In another embodiment, the present application provides a dispersant composition for personal care, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component. [0223] In another embodiment, the present application provides a dispersant composition for color cosmetics, the composition comprising: (i) a dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base; and (ii) at least one solid particulate component. [0224] In another embodiment, the present application provides a dispersant composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base. [0225] Accordingly, the reaction product comprises a maleated functionality fully or partially reacted with the base. The base is selected from the group consisting of inorganic bases, organic bases, and mixtures thereof. [0226] Accordingly, the inorganic base is selected from the group consisting of oxides of alkali metals and alkaline earth metals, hydroxides of alkali metals and alkaline earth metals, carbonates of alkali metals and alkaline earth metals, bicarbonates of alkali metals and alkaline earth metals, oxides of transition metals, and combinations thereof. Further, the organic base is selected from the group consisting of ammonia, primary amines, secondary amines, pyridine, imidazole, benzimidazole, histidine, guanidine, and mixtures thereof. The alkali metal is selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, francium, and mixtures thereof. The alkaline earth metal is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, and mixtures thereof. The transition metal is selected from the group consisting of oxides, hydroxides, carbonates or bicarbonates of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, rutherfordium, dubnium, seaborgium, bohrium, hassium, meitnerium, darmstadtium, roentgenium, and mixtures thereof. The inorganic base is selected from the group consisting of oxides, hydroxides, carbonates and bicarbonates of sodium, calcium, and combinations thereof. [0227] Accordingly, the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated coconut oils, maleated corn oils, maleated cottonseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated almond oils, maleated canola oils, maleated flaxseed oils, maleated grapeseed oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated walnut oils, and mixture thereof. [0228] Accordingly, the maleated natural oil is a maleated soybean oil and the base is sodium hydroxide. The reaction product is selected from the group of structures comprising a maleated functionality fully or partially reacted with the base. consisting of the following structures: , ,
, and mixtures thereof. [0229] In another non-limiting embodiment, the present application provides a dispersant composition for coatings, the composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base. [0230] In another non-limiting embodiment, the present application provides a dispersant composition for personal care, the composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base. [0231] In another non-limiting embodiment, the present application provides a dispersant composition for color cosmetics, the composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base. [0232] In another non-limiting embodiment, the present application provides a dispersant composition comprising: (A) 10 to 90 wt.% of at least one dispersing agent comprising: (i) 0.1 to 10 wt.% of a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a base; and (B) 2 to 70 wt.% of at least one particulate component. [0233] In another non-limiting embodiment, the present application provides a method for preparing a dispersant composition for personal care, the method comprising: (a) adding dispersing agent into a glass jar; (b) sprinkling solid particulate component slowly onto the contents of step (a), (c) mixing the contents of step (b) until homogenous; and (d) obtaining the dispersant composition; wherein, said dispersant composition is characterized by an enhanced resistance to cracking, flaking, or breaking of the particulate component. [0234] The reactions and compositions according to the application may be analyzed by known techniques. Especially preferred are the techniques of 13C nuclear magnetic resonance (NMR) spectroscopy, gas chromatography (GC), Infra-red (IR), Liquid Chromatography (LC) and gel permeation chromatography (GPC) to decipher identity, residual monomer concentrations, molecular weight, and molecular weight distribution. [0235] The currently disclosed dispersant composition brings about unique features to the end user formulations in that the primary dispersing agent (i) reduces the viscosity of the mixture during solid particulate blending, (ii) enhances the dispersion of powder particulates, (iii) increases the solid loading since it drastically reduces the viscosity of the blend allowing one to add more solid particulates like pigments, (iv) are highly stable with good affinity for skin, (v) highly compatible to be used in emulsions, anhydrous and non-volatile systems, (vi) show improved wear and pleasing aesthetics such as better skin feel, high solid content, enhanced color strength, and (vii) are easy to incorporate with mixing and homogenizing offering stability and color consistency. [0236] Further, certain aspects of the present application are illustrated in detail by way of the following examples. The examples are given herein for illustration of the application and are not intended to be limiting thereof. [0237] EXPERIMENTATION [0238] Example A: Grafting of maleic anhydride onto natural oils. [0239] Example A1: Grafting of 1 mole of maleic anhydride onto soybean oil. [0240] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen sparge adapter, and a mechanical stirrer, 600 g of yellow color Soybean oil and 67 g (1 mole eq. based on SBO) of maleic anhydride were charged. The mixture was sparged with nitrogen for 15 min at RT only. The mixture was slowly heated from room temperature to 210 ˚C and was held isothermally at 210 ˚ C for about 6-8 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 1% residual maleic anhydride. O soybea o (S O) [0241] Example A2: Grafting of 2 moles of maleic anhydride onto soybean oil. [0242] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen sparge adapter, and a mechanical stirrer, 600 g of yellow color Soybean oil and 137.7 g (2 mole eq. based on SBO) of maleic anhydride were charged. The mixture was sparged with nitrogen for 15 min at RT only. The mixture was slowly heated from room temperature to 210 ˚C and was held isothermally at 210 ˚ C for about 6-8 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 1% residual maleic anhydride. [0243] Example A3: Grafting of 3 moles of maleic anhydride onto soybean oil. [0244] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen sparge adapter, and a mechanical stirrer, 600 g of yellow color soybean oil and 204 g (3 mole eq. based on SBO) of maleic anhydride were charged. The mixture was sparged with nitrogen for 15 min at RT only. The mixture was slowly heated from room temperature to 210 ˚C and was held isothermally at 210 ˚ C for about 6-8 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 1% residual maleic anhydride. [0245] Example A4: Grafting of maleic anhydride onto palm oil. [0246] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen sparge adapter, and a mechanical stirrer, 100 g of palm oil and 23 g (2 mole eq. based on palm oil) of maleic anhydride was charged. The mixture was sparged with nitrogen for 15 min at RT only. The mixture was slowly heated from room temperature to 210 ˚C and held isothermally at 210 ˚C for about 8-10 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 1% residual maleic anhydride. [0247] Example A5: Grafting of maleic anhydride onto canola oil. [0248] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen sparge adapter, and a mechanical stirrer, 100 g of canola oil and 22.2 g (2 mole eq. based on canola oil) of maleic anhydride was charged. The mixture was sparged with nitrogen for 15 min at RT only. The mixture was slowly heated from room temperature to 210 ˚C and held isothermally at 210 ˚C for about 8-10 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 1% residual maleic anhydride. [0249] Example A6: Grafting of maleic anhydride onto sunflower oil. [0250] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen sparge adapter, and a mechanical stirrer, 100 g of sunflower oil and 22.4 g (2 mole eq. based on sunflower oil) of maleic anhydride was charged. The mixture was sparged with nitrogen for 15 min at RT only. The mixture was slowly heated from room temperature to 210 ˚C and held isothermally at 210 ˚C for about 8-10 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 1% residual maleic anhydride. [0251] Example A7: Grafting of maleic anhydride onto castor oil. [0252] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen sparge adapter, and a mechanical stirrer, 100 g of yellow color castor oil and 21 g (2 mole eq. based on castor oil) of maleic anhydride was charged. The mixture was sparged with nitrogen for 15 min at RT only. The mixture was slowly heated from room temperature to 210 ˚C and held isothermally at 210 ˚C for about 8-10 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 1% residual maleic anhydride. [0253] Example B: Grafting of hydrophobic alcohol (octyl dodecanol) onto maleic anhydride onto natural oil [0254] Example B1: [0255] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A1 and 30.5 g (1 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0256] Example B2: [0257] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A2 and 55.64 g (2 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0258] Example B3: [0259] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A2 and 61.20 g (2.2 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR, GC < 5% for residual octyl dodecanol and LC< 1% residual maleic anhydride. [0260] Example B4: [0261] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 25.44 g (1 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0262] Example B5: [0263] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 31.81 g (1.25 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0264] Example B6: [0265] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 38.17 g (1.5 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0266] Example B7: [0267] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A 3 and 50.89 g (2 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0268] Example B8: [0269] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A3 and 63.61 g (2.5 mole eq.) of 2-octyl-1-dodecanol were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0270] Example B9: [0271] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A4 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0272] Example B10: [0273] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A5 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0274] Example B11: [0275] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A6 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0276] Example B12: [0277] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction Example A7 and 35 g (1 mole eq.) of 2-octyl-1-dodecanol was mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product, which was characterized by NMR, IR, GC < 5% for residual octyl dodecanol and LC < 1% residual maleic anhydride. [0278] Example C: Grafting of hydrophobic and hydrophilic moiety (glycerin) onto hydrophobic maleic anhydride onto natural oil with octyl dodecanol [0279] Example C1: [0280] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 6 and 5.7 g (1 mole eq.) of glycerin were mixed and heated to 90 ˚C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0281] Example C 2: [0282] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 4 and 6.28 g (1 mole eq.) of glycerin were mixed and heated to 90 ˚C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0283] Example C 3: [0284] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 4 and 9.42 g (1.5 mole eq.) of glycerin were mixed and heated to 90 ˚C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0285] Example C 4: [0286] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 9 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ˚C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0287] Example C 5: [0288] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 10 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ˚C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0289] Example C 6: [0290] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 11 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ˚C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0291] Example C 7: [0292] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from reaction B 12 and 11 g (1 mole eq.) of glycerin was mixed and heated to 90 ˚C and held for 4-6 hours. The one pot reaction without catalyst and solvent yields >96% amber color viscous product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0293] Example C 8: [0294] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 152 g of amber color viscous product from reaction B 4 and 4.74 g (1 mole eq.) of ethanol were mixed and heated to 90 ˚ C and held for 8 hours. The one pot reaction without catalyst and solvent yields >96% amber color product which was characterized by NMR and LC < 0.05% residual maleic anhydride. O [0295] Example C 9: [0296] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 152 g of amber color viscous product from reaction B 4 and 9.47 g (2 mole eq.) of ethanol were mixed and heated to 90 ˚ C and held for 8 hours. The one pot reaction without catalyst and solvent yields >96% amber color product which was characterized by NMR and LC < 0.05% residual maleic anhydride. [0297] Example D: Grafting of hydrophilic alcohol (beta cyclodextrin, glycerin) onto maleic anhydride onto natural oil [0298] Example D 1: [0299] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 68.43 g of amber color viscous product from reaction B 6 and 23.73 g (0.50 mole eq.) of beta cyclodextrin were mixed and heated to 90 ˚C and held for 6 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC < 0.05% residual maleic anhydride.
[0300] Example D 2: [0301] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 68.43 g of amber color viscous product from reaction B 6 and 23.73 g (0.50 mole eq.) of beta cyclodextrin and 3.85 g (1 mole eq.) of glycerin were mixed and heated to 90 ˚ C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC < 0.05% residual maleic anhydride. [0302] Example D 3: [0303] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 68.43 g of amber color viscous product from reaction B 6 and 23.73 g (0.50 mole eq.) of beta cyclodextrin and 1.93 g (0.50 mole eq.) of glycerin were mixed and heated to 90 ˚C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC < 0.05% residual maleic acid. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC < 0.05% residual maleic anhydride. [0304] Example E: Maleination reaction with water [0305] Example E 1: [0306] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 100 g of amber color viscous product from maleination reaction A 3 and 6.10 g (3 mole eq.) of water were mixed and heated to 90 ˚C and held for 20 hours. The one pot reaction without catalyst and solvent yields >90% yellow color product which was characterized by NMR, IR and LC < 0.05% residual maleic acid. [0307] Example F: Grafting of hydrophilic glycerin onto maleic anhydride onto soybean oil [0308] Example F 1 [0309] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 176 g of amber color viscous product from maleination reaction A 3 and 6.87 g (0.5 mole eq.) of glycerin were mixed and heated to 90 ˚C and held for 2 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC < 0.05% residual maleic anhydride. [0310] Example F 2: [0311] In a 1- Liter, 4 neck kettle equipped with a thermocouple, a condenser, a nitrogen purge adapter, and a mechanical stirrer, 176 g of amber color viscous product from maleination reaction A 3 and 13.74 g (1 mole eq.) of glycerin were mixed and heated to 90 ˚C and held for 4 hours. The one pot reaction without catalyst and solvent yields >96% yellow color product which was characterized by IR and LC < 0.05% residual maleic anhydride. [0312] Example G: [0313] Example G1: Maleated soybean oil with 2-octyldodecanol and glycerin at 1%, 3% and 5% with zinc oxide and titanium dioxide with zinc oxide (10%w/w)- Table 1: Table 1: Maleated soybean oil with 2-octyldodecanol and glycerin with zinc oxide (10%w/w) [0314] Example G2: Maleated soybean oil reacted with 2-octyldodecanol and glycerin at 1%, 3% and 5% with zinc oxide and titanium dioxide (10%w/w)- Table 2 : Table 2: with Titanium Dioxide (10%w/w) 129 6119 129 6121 129 6123 [0258] Example G3: Sodium salt of maleated soybean oil with 2-octyldodecanol and glycerin at 1%, 3% and 5% with zinc oxide (10%w/w)- Table 3: Table 3: Sodium salt of maleated soybean oil with 2-octyldodecanol and glycerin with Zinc oxide (10%w/w) 129 61 1 129 61 2 129 61 3 [0315] Example G4: Sodium salt of maleated soybean oil with hydrophobic 2-octyldodecanol and hydrophilic glycerin at 1%, 3% and 5% with titanium dioxide (10%w/w) - Table 4 : Table 4: Sodium salt of maleated soybean oil with 2-octyldodecanol and glycerin with Titanium dioxide (10%w/w) [0316] Example G5: Sodium salt of maleated soybean oil at 1% and 3% with zinc oxide - (10%w/w ) – Table 5: Table 5: Sodium salt of maleated soybean oil with Zinc oxide (10% w/w) [0317] Example G 6: Sodium salt of maleated soybean oil at 1% and 3% with titanium oxide (10%w/w ) – Table 6: Table 6: Sodium salt of maleated soybean oil with Titanium dioxide (10%w/w) [0318] DISPERSANT COMPOSITIONS [0319] EXAMPLE 1: using Kaolin [0320] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Kaolin was used as particulate component. Table 7: using Kaolin. [0321] EXAMPLE 2: using Silica [0322] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Silica was used as particulate component. Table 8 - using Silica [0323] EXAMPLE 3: using Zinc Oxide [0324] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Zinc oxide was used as particulate component. Table 9 - using Zinc Oxide [0325] Example 4: using Titanium Dioxide [0326] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component. The prepared samples were compared with that of the competitor. Table 10 - using Titanium dioxide [0327] Example 5: using Titanium Dioxide [0328] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component and castor oil as liquid component of the dispersant composition. Table 11 - using Titanium dioxide [0329] Example 6: using Titanium dioxide & Esters [0330] Two dispersant compositions with and without soybean bean oil ester were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component. Isodecyl Neopentanoate and tridecyl Neopentanoate were used as liquid components in the dispersant composition. Table 12 - using Titanium dioxide & Esters [0331] Example 7: using Titanium dioxide & Esters [0332] Two dispersant compositions with soybean bean oil ester in different weight percentages were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component. Tridecyl Neopentanoate were used as liquid component in the dispersant composition. Table 13 - using Titanium dioxide & Esters. [0333] Example 8: using Titanium dioxide & Esters [0334] Three dispersant compositions without and with soybean bean oil ester (in different weight percentages) were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component. Tridecyl Neopentanoate and Octyldodecyl Stearoyl Stearate were used as liquid component in either of the dispersant compositions. Table 14 - using Titanium dioxide & Esters [0335] EXAMPLE 9: using Titanium dioxide & Esters [0336] Four dispersant compositions without and with soybean bean oil ester (in different weight percentages) were prepared and their respective viscosities were analyzed. Titanium dioxide was used as particulate component. Mineral Oil and Octyldodecyl Stearoyl Stearate were used as liquid components in either of the dispersant compositions. Table 15 - using Titanium dioxide & Esters [0337] EXAMPLE 10: using Titanium dioxide - ITT & Esters [0338] Three dispersant compositions without and with soybean bean oil ester (in different weight percentages) were prepared and their respective viscosities were analyzed. Either titanium dioxide or titanium dioxide - triisostearate were used as particulate components. Mineral oil was used as liquid component in either of the dispersant compositions. Table 16 - using Titanium dioxide-ITT & Esters [0339] FORMULATION EXAMPLES [0340] EXAMPLE 11: SPF Fluid Shake [0341] Four SPF fluid shake dispersions for skin care were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below: Table 17 - SPF Fluid Shake [0342] EXAMPLE 12: Eye shadow [0343] Four different cosmetic care samples of eyeshadow were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 18 - Eyeshadow [0344] EXAMPLE 13: Lip Gloss [0345] Four different cosmetic care samples of Lip gloss were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 19 - Lip Gloss [0346] EXAMPLE 14: Blush [0347] Four different cosmetic care samples of Blush were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 20 - Blush [0348] EXAMPLE 15: Pressed Powder [0349] Four different cosmetic care samples of Pressed powder samples were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 21 - Pressed Powder [0350] EXAMPLE 16: Carbon Black Mascara [0351] Four different cosmetic care samples of Carbon black mascara were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 22 - Carbon Black Mascara ih S b il ih S b il [0352] EXAMPLE 17: Volume Curling Mascara [0353] Four different cosmetic care samples of volume curling mascara were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 23 - Volume Curling Mascara [0354] EXAMPLE 18: Clay Mask [0355] Four different cosmetic care samples of clay mask were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 24 - Clay Mask [0356] EXAMPLE 19: Long Wear Intense Lipstick [0357] Four different cosmetic care samples of Long Wear Intense Lipstick were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 25 - Long Wear Intense Lipstick [0358] EXAMPLE 20: W/O Liquid Foundation [0359] Four cosmetic care samples of W/O Liquid Foundation were prepared without and with soybean oil ester in different weight percentages. The ingredients are tabulated below. Table 26 - W/O Liquid Foundation [0360] While the invention has been described in connection with the preferred embodiments, it is not intended to limit the scope of the invention to the form set forth but, on the contrary, it is intended to cover such alternatives, modifications, and equivalents as may be included within the spirit and scope of the invention as defined by the appended claims.

Claims

We claim: 1. A dispersant composition comprising at least one dispersing agent comprising a reaction product of (a) a maleated natural oil comprising a natural oil with maleated functionality; and (b) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof.
2. The dispersant composition according to claim 1, wherein the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated almond oils, maleated coconut oils, maleated corn oils, maleated canola oils, maleated cottonseed oils, maleated flaxseed oils, maleated grapeseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated walnut oils, and mixtures thereof.
3. The dispersant composition according to claim 1, wherein the maleated natural oil is a maleated soybean oil.
4. The dispersant composition according to claim 1, wherein the (a) hydrophobic moiety is a moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C6 to about C36 atoms, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl amines, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C6 to about C36 atoms, silicon-based compounds, and combinations thereof; and (b) hydrophilic moiety is a moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C1 to about C5 atoms, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl amines, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C1 to about C5 atoms, unsubstituted or substituted polyols, wherein any of the beforehand mentioned groups may be with or without heteroatoms, containing from about C2 to about C36 atoms, silanes, and combinations thereof.
5. The dispersant composition according to claim 4 (a), wherein the (i) hydrophobic alcohol is selected from the group consisting of heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1- dodecyl alcohol, 2-tertradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2-propyl-1-pentanol, 4- methyl-1-pentanol, and mixtures thereof; and (ii) hydrophobic amine is selected from the group consisting of benzylamine, cyclohexylamine, hexylamine, methylhexylamine, phenethylamine, octylamine, oleylamine, decylamine, dodecylamine, octadecylamine, undecyl amine, pentadecyl amine, 2-methyl butyl amine, dimethyl amine, and mixtures thereof.
6. The dispersant composition according to claim 4 (b), wherein the (i) hydrophilic alcohol is selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxy polyethylene glycol, polypropylene glycol, hexylene glycol, sorbitol, neopentylglycol, eythritol, mannitol, xylitol, threitol, pentaerythritol, beta-cyclodextrin, L-Ribose, 2-deoxy-D-galactose, and mixtures thereof; and (ii) hydrophilic amine is selected from the group consisting of 2-methylpentane-1,5- diamine, diethanol amine, diisopropanol amine, serinol hydrochloride, 2-amino-2-ethyl-1,3- propanediol, N-methyl-D-glucosamine, D-galactosamine hydrochloride, D-glucosamine hydrochloride, D-mannosamine hydrochloride, and mixtures thereof.
7. The composition according to claim 1, wherein the dispersing agent is present in an amount of from 0.1 to 90 wt.% of the total dispersant composition.
8. The dispersant composition according to claim 1, wherein the composition further comprises at least one particulate component.
9. The dispersant composition according to claim 8, wherein the particulate component is selected from the group consisting of pigments for personal care, architectural and industrial coatings; extenders and fillers for paints and plastics materials; optical brightening agents for paper; textile auxiliaries for solvent dyebaths and inks; particulate ceramic materials; magnetic particles for use in magnetic recording media; organic solid biocides for agrochemicals and pharmaceuticals; solid particulates for food and preservatives; and solid polymeric surfactants for home care.
10. The dispersant composition according to claim 9, wherein the particulate component is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
11. The composition according to claim 8, wherein the particulate component is present in an amount of from 0.1 to 70 wt.% of the total dispersant composition.
12. The dispersant composition according to claim 8, wherein the particulate component further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
13. The dispersant composition according to claim 13, wherein the liquid component is selected from the group consisting of isodecyl neopentanoate, tridecyl neopentanoate, octyl dodecyl stearoyl stearate, castor oil, polyhydroxy stearic acid, and C12-15 alkyl benzoate.
14. The composition according to claim 12, wherein the liquid component is present in an amount of from about 2 wt.% to about 90 wt.% of the total weight of the dispersant agent.
15. The dispersant composition according to claim 1, wherein the dispersing agent is selected from the group of structures represented by the structures set out below:
16. The dispersant composition according to claim 1, wherein the dispersant composition is a personal care composition, a coating composition, a food coating composition, and a pharmaceutical coating composition,
17. The dispersant composition according to claim 1, wherein the dispersant composition further comprises at least one functional ingredient selected from personal care agents, coating agents, food coating agents, pharmaceutical tablet coatings agents, and dispersant coatings agents.
18. A dispersant composition for coatings, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 1; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
19. The dispersant composition for coatings according to claim 18, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
20. The dispersant composition for coatings according to claim 18, wherein the solid particulate is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
21. The dispersant composition according to claim 18, wherein the dispersant composition is used in preparation of coating compositions selected from the group of architectural coatings, metal coatings, marine coatings, paints, decorative paints, interior paints, exterior paints, non-woven coatings, ceramic coatings, anti-corrosion coatings, flame retardant coatings, protective coatings, powder coatings, wood coatings, industrial coatings, anti-fouling coatings, anti-microbial coatings, thermal insulation coatings, water based coatings, and solvent based coatings.
22. The coating composition according to claim 18, wherein the dispersant composition is used for lacquer coating, primer coating, ink jet printing, top coating, varnish coating, architectural coating, wood coating, printing inks or metallic or non-metallic coating.
23. The coating composition according to claim 18, wherein the dispersant composition is coated on a substrate selected from the group consisting of porous and non-porous substrates, papers, non-woven materials, textiles, leather, wood, concrete, masonry, metals, non- metals, house wrap, building materials, fiberglass, polymeric articles, face masks, medical drapes and gowns, carpets, upholstery, tents, awnings, air bags, fabrics, ceramics, yarns, and blends, woven, knitted, natural, synthetic, and regenerated substrates.
24. The dispersant composition for coatings according to claim 18, wherein the dispersing agent is a reaction product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol.
25. A dispersant composition for personal care, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 1; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
26. The dispersant composition for personal care according to claim 25, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
27. The dispersant composition for personal care according to claim 25, wherein the personal care composition is a skin care composition, hair care composition, and nail care composition.
28. The dispersant composition for personal care according to claim 25, wherein the personal care composition is a cosmetic composition selected from the group consisting of an eyeliner composition, a foundation composition, a long wear intense lipstick composition, a clay mask composition, a volume curling mascara composition, a carbon black mascara composition, a pressed powder composition, a blush composition, a lip gloss composition, an eye shadow composition, and a SPF composition.
29. The dispersant composition according to claim 25, wherein the dispersant composition is used in preparation of personal care compositions selected from the group comprising a foundation, a long wear intense lipstick, a clay mask, a volume curling mascara, a carbon black mascara, a pressed powder, a blush, a lip gloss, an eye shadow, a SPF fluid shake.
30. The dispersant composition for personal care according to claim 25, wherein the composition is an emulsion selected from oil-in-water emulsion and water-in-oil emulsion.
31. The dispersant composition for personal care according to claim 25, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
32. The dispersant composition for personal care according to claim 25, wherein the dispersing agent is a product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol.
33. A dispersant composition for color cosmetics, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 1; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
34. The dispersant composition for color cosmetics according to claim 33, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
35. The dispersant composition for color cosmetics according to claim 33, wherein the color cosmetic is selected from the group comprising cleansing foam cream, massage cream, pack, skin lotion, milky lotion, sunscreen, foundation, white powder, eye shadow, blush, eyeliner, mascara, eyebrow, concealer, lipstick, and lip gloss.
36. The dispersant composition for color cosmetics according to claim 33, wherein the dispersing agent is a product of (i) maleated soybean oil, (ii) octyldodecyl alcohol, and (iii) glycerol.
37. A dispersant composition comprising a reaction product of: (A) a maleated natural oil comprising a natural oil with maleated functionality; (B) a base; and (C) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof; wherein the maleated functionality has been partially reacted with the base, and wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety.
38. The dispersant composition according to claim 37, wherein the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated coconut oils, maleated corn oils, maleated cottonseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated almond oils, maleated canola oils, maleated flaxseed oils, maleated grapeseed oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated walnut oils, and mixtures thereof.
39. The dispersant composition according to claim 37, wherein the maleated natural oil is a maleated soybean oil.
40. The dispersant composition according to claim 37, wherein the base is selected from the group consisting of inorganic bases, organic bases, and mixtures thereof.
41. The dispersant composition according to claim 37, wherein the inorganic base is selected from the group consisting of oxides of alkali metals and alkaline earth metals, hydroxides of alkali metals and alkaline earth metals, carbonates of alkali metals and alkaline earth metals, bicarbonates of alkali metals and alkaline earth metals, oxides of transition metals, hydroxides of transition metals, carbonates of transition metals, bicarbonates of transition metals, and combinations thereof.
42. The dispersant composition according to claim 37, wherein the inorganic base is selected from the group consisting of oxides, hydroxides, carbonates and bicarbonates of sodium, calcium, and combinations thereof.
43. The dispersant composition according to claim 41, wherein the alkali metal is selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, francium, and mixtures thereof.
44. The dispersant composition according to claim 41, wherein the alkaline earth metal is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, and mixtures thereof.
45. The dispersant composition according to claim 41, wherein the transition metal is selected from the group consisting of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, rutherfordium, dubnium, seaborgium, bohrium, hassium, meitnerium, darmstadtium, roentgenium, and mixtures thereof.
46. The dispersant composition according to claim 40, wherein the organic base is selected from the group consisting of ammonia, primary amines, secondary amines, pyridine, imidazole, benzimidazole, histidine, guanidine, and mixtures thereof.
47. The dispersant composition according to claim 37, wherein the hydrophobic moiety is a moiety selected from those of the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols and amines, wherein the alcohols and amines contain from about 6 to about 36 carbon atoms and may contain heteroatoms; silicon-based compounds; and combinations thereof.
48. The dispersant composition according to claim 37, wherein the hydrophilic moiety is a moiety selected from those of the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, and aryl alcohols and amines, wherein the alcohols and amines contain from about 1 to about 5 carbon atoms and may contain heteroatoms; unsubstituted or substituted polyols, wherein the unsubstituted or substituted polyols contain from about 2 to about 36 carbon atoms and may contain heteroatoms; silanes; and combinations thereof.
49. The dispersant composition according to claim 48, wherein the silane is functionalized with an alcohol, an amine, or combinations thereof.
50. The dispersant composition according to claim 47, wherein the hydrophobic moiety is that of an alcohol selected from the group consisting of heptanol, nonanol, decanol, dodecanol, phenol, ethylbenzyl alcohol, 2-ethyl-1-hexanol, 1-octanol, 2-octanol, 2-octyl-1-dodecyl alcohol, 2-tetradecanol, 2-hexadecanol, 3,7-dimethyl-1-octanol, 2-propyl-1-pentanol, 4-methyl-1- pentanol, and mixtures thereof.
51. The dispersant composition according to claim 47, wherein the hydrophilic moiety is that of an alcohol selected from the group consisting of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, dibutylene glycol, polyethylene glycol, methoxypolyethylene glycol, polypropylene glycol, hexylene glycol, sorbitol, neopentylglycol, eythritol, mannitol, xylitol, threitol, pentaerythritol, beta-cyclodextrin, ribose, 2-deoxy-D-galactose, and mixtures thereof.
52. The dispersant composition according to claim 47, wherein the hydrophobic moiety is that of an amine selected from the group consisting of benzylamine, cyclohexylamine, hexylamine, methylhexylamine, phenethylamine, octylamine, oleylamine, decylamine, dodecylamine, octadecylamine, undecylamine, pentadecylamine, 2-methylbutylamine, dimethylamine, and mixtures thereof.
53. The dispersant composition according to claim 47, wherein the hydrophilic moiety is (i) at least one amine selected from the group consisting of 2-methylpentane-1,5-diamine, diethanolamine, diisopropanolamine, serinol, 2-amino-2-ethyl-1,3-propanediol, N-methyl-D- glucosamine, D-galactosamine, D-glucosamine, D-mannosamine, and their hydrochloride salts; and (ii) at least one amine selected from the group consisting of 2-methylpentane-1,5-diamine, diethanolamine, diisopropanolamine, serinol, 2-amino-2-ethyl-1,3-propanediol, N-methyl-D- glucosamine, D-galactosamine, D-glucosamine, D-mannosamine, and their ammonium salts.
54. The dispersant composition according to claim 47, wherein the silicon based compound is a hydrophobic compound selected from the group consisting of aminopropylmethylsiloxane–dimethylsiloxane, N-ethylaminoisobutyl terminated polydimethyl siloxane, poly(1,1-dimethylsilazane) telomer, aminopropyl terminated polydimethylsiloxane, monoaminopropyl terminated polydimethyl siloxane, (tetramethylpiperidinyloxy) propylmethyl siloxane]-dimethylsiloxane copolymer, polydimethylsiloxane, carbinol (hydroxyl) terminated polydimethylsiloxane, monocarbinol terminated polydimethylsiloxane, monocarbinol terminated functional polydimethylsiloxane, [Bis(hydroxyethyl)amine] terminated polydimethylsiloxane, silanol terminated polydimethylsiloxane, silanol terminated polydiphenylsiloxane, dodecylmethyl siloxane-hydroxypolyalkyleneoxypropyl methylsiloxane, and mixtures thereof.
55. The dispersant composition according to claim 48, wherein the silane is a hydrophilic compound selected from the group consisting of 3-aminopropylsilanetriol, N-(2- aminoethyl)-3-aminopropylsilanetriol, and mixtures thereof.
56. The dispersant composition according to claim 37, wherein the reaction product is selected from the group of structures represented by the following structures:
, and combinations thereof.
57. The dispersant composition according to claim 37, wherein the dispersant composition is a personal care composition, a coating composition, a food coating composition, and a pharmaceutical coating composition,
58. The dispersant composition according to claim 37, wherein the dispersant composition further comprises at least one functional ingredient selected from personal care agents, coating agents, food coating agents, pharmaceutical tablet coatings agents, and dispersant coatings agents.
59. A dispersant composition for coatings, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 37; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
60. The dispersant composition for coatings according to claim 59, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
61. The dispersant composition for coatings according to claim 59, wherein the solid particulate is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
62. The dispersant composition according to claim 59, wherein the dispersant composition is used in preparation of coating compositions selected from the group of architectural coatings, metal coatings, marine coatings, paints, decorative paints, interior paints, exterior paints, non-woven coatings, ceramic coatings, anti-corrosion coatings, flame retardant coatings, protective coatings, powder coatings, wood coatings, industrial coatings, anti-fouling coatings, anti-microbial coatings, thermal insulation coatings, water based coatings, and solvent based coatings.
63. The coating composition according to claim 59, wherein the dispersant composition is used for lacquer coating, primer coating, ink jet printing, top coating, varnish coating, architectural coating, wood coating, printing inks or metallic or non-metallic coating.
64. The coating composition according to claim 59, wherein the dispersant composition is coated on a substrate selected from the group consisting of porous and non-porous substrates, papers, non-woven materials, textiles, leather, wood, concrete, masonry, metals, non- metals, house wrap, building materials, fiberglass, polymeric articles, face masks, medical drapes and gowns, carpets, upholstery, tents, awnings, air bags, fabrics, ceramics, yarns, and blends, woven, knitted, natural, synthetic, and regenerated substrates.
65. The dispersant composition for coatings according to claim 59, wherein the dispersing agent is a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide and mixtures thereof; and (c) 2-octyldodecyl alcohol, glycerol, or combinations thereof; wherein the maleated functionality has been partially reacted with the base, wherein the maleated functionality has been partially reacted with the 2- octyldodecyl alcohol or glycerol;
66. A dispersant composition for personal care, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of 37; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
67. The dispersant composition for personal care according to claim 66, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
68. The dispersant composition for personal care according to claim 66, wherein the personal care composition is a skin care composition, hair care composition, and nail care composition.
69. The dispersant composition for personal care according to claim 66, wherein the personal care composition is a cosmetic composition selected from the group consisting of an eyeliner composition, a foundation composition, a long wear intense lipstick composition, a clay mask composition, a volume curling mascara composition, a carbon black mascara composition, a pressed powder composition, a blush composition, a lip gloss composition, an eye shadow composition, and a SPF composition.
70. The dispersant composition according to claim 66, wherein the dispersant composition is used in preparation of personal care compositions selected from the group comprising a foundation, a long wear intense lipstick, a clay mask, a volume curling mascara, a carbon black mascara, a pressed powder, a blush, a lip gloss, an eye shadow, a SPF fluid shake.
71. The dispersant composition for personal care according to claim 66, wherein the composition is an emulsion selected from oil-in-water emulsion and water-in-oil emulsion.
72. The dispersant composition for personal care according to claim 66, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
73. The dispersant composition for personal care according to claim 66, wherein the dispersing agent is a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide and mixtures thereof; and (c) 2-octyldodecyl alcohol, glycerol, or combinations thereof; wherein the maleated functionality has been partially reacted with the base, wherein the maleated functionality has been partially reacted with the 2- octyldodecyl alcohol or glycerol;
74. A dispersant composition for color cosmetics, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 37; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
75. The dispersant composition for color cosmetics according to claim 74, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
76. The dispersant composition for color cosmetics according to claim 74, wherein the color cosmetic is selected from the group comprising cleansing foam cream, massage cream, pack, skin lotion, milky lotion, sunscreen, foundation, white powder, eye shadow, blush, eyeliner, mascara, eyebrow, concealer, lipstick, and lip gloss.
77. The dispersant composition for personal care according to claim 74, wherein the dispersing agent is a reaction product of (a) a maleated natural oil, comprising a natural oil with maleated functionality; (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide and mixtures thereof; and (c) 2-octyldodecyl alcohol, glycerol, or combinations thereof; wherein the maleated functionality has been partially reacted with the base, wherein the maleated functionality has been partially reacted with the 2- octyldodecyl alcohol or glycerol;
78. A dispersant composition comprising a reaction product of: (A) a maleated natural oil, comprising a natural oil with maleated functionality; and (B) a functionalized or unfunctionalized moiety selected from the group consisting of hydrophobic moieties, hydrophilic moieties, and combinations thereof, wherein the maleated functionality has been partially reacted with the functionalized or unfunctionalized moiety; and (C) a base.
79. The dispersant composition according to claim 78, wherein the reaction product is represented by the following structure: wherein R is one or more hydrophilic or hydrophobic moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, aryl and alkaryl moieties containing from about 1 to about 36 carbon atoms; and wherein each Q is independently selected from the group consisting of H, Li, Na, K, Rb, Cs, Fr, ½ Mg, ½ Ca, ½ Co, ½ Cu, ½ Zn, ammonium, alkylammonium, dialkylammonium, trialkylammonium and tetraalkylammonium.
80. The dispersant composition according to claim 78, wherein the reaction product is a polymer represented by the following structure: wherein n is greater than 1; wherein R is one or more hydrophilic or hydrophobic moiety selected from the group consisting of unsubstituted or substituted alkyl, cycloalkyl, alkenyl, aryl and alkaryl moieties containing from about 1 to about 36 carbon atoms; and wherein each Q is independently selected from the group consisting of H, Li, Na, K, Rb, Cs, Fr, ½ Mg, ½ Ca, ½ Co, ½ Cu, ½ Zn, ammonium, alkylammonium, dialkylammonium, trialkylammonium and tetraalkylammonium.
81. The dispersant composition according to claim 79, wherein the reaction product is selected from the group of structures represented by the following structures:
82. The dispersant composition according to claim 80, wherein the reaction product is a polymer selected from the group of structures represented by the following structures: wherein 1 < n < 30.
83. The dispersant composition according to claim 80, wherein the reaction product is a polymer having a weight-average molecular weight from about 3,000 Daltons to about 20,000 Daltons and a weight-average degree of polymerization, n, of about 3 to about 20.
84. The dispersant composition according to claim 80, wherein the reaction product is a polymer having a viscosity measured at 25 oC with a Brookfield viscometer ranging from about 100 to 10,000 cps.
85. The dispersant composition according to claim 78, wherein the dispersant composition is a personal care composition, a coating composition, a food coating composition, and a pharmaceutical coating composition,
86. The dispersant composition according to claim 78, wherein the dispersant composition further comprises at least one functional ingredient selected from personal care agents, coating agents, food coating agents, pharmaceutical tablet coatings agents, and dispersant coatings agents.
87. A dispersant composition for coatings, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 78; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
88. The dispersant composition for coatings according to claim 87, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
89. The dispersant composition for coatings according to claim 87, wherein the solid particulate is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
90. The dispersant composition according to claim 87, wherein the dispersant composition is used in preparation of coating compositions selected from the group of architectural coatings, metal coatings, marine coatings, paints, decorative paints, interior paints, exterior paints, non-woven coatings, ceramic coatings, anti-corrosion coatings, flame retardant coatings, protective coatings, powder coatings, wood coatings, industrial coatings, anti-fouling coatings, anti-microbial coatings, thermal insulation coatings, water based coatings, and solvent based coatings.
91. The coating composition according to claim 87, wherein the dispersant composition is used for lacquer coating, primer coating, ink jet printing, top coating, varnish coating, architectural coating, wood coating, printing inks or metallic or non-metallic coating.
92. The coating composition according to claim 87, wherein the dispersant composition is coated on a substrate selected from the group consisting of porous and non-porous substrates, papers, non-woven materials, textiles, leather, wood, concrete, masonry, metals, non- metals, house wrap, building materials, fiberglass, polymeric articles, face masks, medical drapes and gowns, carpets, upholstery, tents, awnings, air bags, fabrics, ceramics, yarns, and blends, woven, knitted, natural, synthetic, and regenerated substrates.
93. A dispersant composition for personal care, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 78; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
94. The dispersant composition for personal care according to claim 93, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
95. The dispersant composition for personal care according to claim 93, wherein the personal care composition is a skin care composition, hair care composition, and nail care composition.
96. The dispersant composition for personal care according to claim 93, wherein the personal care composition is a cosmetic composition selected from the group consisting of an eyeliner composition, a foundation composition, a long wear intense lipstick composition, a clay mask composition, a volume curling mascara composition, a carbon black mascara composition, a pressed powder composition, a blush composition, a lip gloss composition, an eye shadow composition, and a SPF composition.
97. The dispersant composition according to claim 93, wherein the dispersant composition is used in preparation of personal care compositions selected from the group comprising a foundation, a long wear intense lipstick, a clay mask, a volume curling mascara, a carbon black mascara, a pressed powder, a blush, a lip gloss, an eye shadow, a SPF fluid shake.
98. The dispersant composition for personal care according to claim 93, wherein the composition is an emulsion selected from oil-in-water emulsion and water-in-oil emulsion.
99. The dispersant composition for personal care according to claim 93, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
100. A dispersant composition for color cosmetics, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 78; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
101. The dispersant composition for color cosmetics according to claim 100, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
102. The dispersant composition for color cosmetics according to claim 100, wherein the color cosmetic is selected from the group comprising cleansing foam cream, massage cream, pack, skin lotion, milky lotion, sunscreen, foundation, white powder, eye shadow, blush, eyeliner, mascara, eyebrow, concealer, lipstick, and lip gloss.
103. A dispersant composition comprising at least one dispersing agent comprising a reaction product of: (a) a maleated natural oil, comprising a natural oil with maleated functionality; and (b) a base.
104. The dispersant composition according to claim 103, wherein the reaction product comprises a maleated functionality fully or partially reacted with the base.
105. The dispersant composition according to claim 103, wherein the base is selected from the group consisting of inorganic bases, organic bases, and mixtures thereof.
106. The dispersant composition according to claim 105, wherein the inorganic base is selected from the group consisting of oxides of alkali metals and alkaline earth metals, hydroxides of alkali metals and alkaline earth metals, carbonates of alkali metals and alkaline earth metals, bicarbonates of alkali metals and alkaline earth metals, oxides of transition metals, and combinations thereof.
107. The dispersant composition according to claim 105, wherein the organic base is selected from the group consisting of ammonia, primary amines, secondary amines, pyridine, imidazole, benzimidazole, histidine, guanidine, and mixtures thereof.
108. The dispersant composition according to claim 106, wherein the alkali metal is selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, francium, and mixtures thereof.
109. The dispersant composition according to claim 106, wherein the alkaline earth metal is selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, radium, and mixtures thereof.
110. The dispersant composition according to claim 106, wherein the transition metal is selected from the group consisting of oxides, hydroxides, carbonates or bicarbonates of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, rutherfordium, dubnium, seaborgium, bohrium, hassium, meitnerium, darmstadtium, roentgenium, and mixtures thereof.
111. The dispersant composition according to claim 106, wherein the inorganic base is selected from the group consisting of oxides, hydroxides, carbonates and bicarbonates of sodium, calcium, and combinations thereof.
112. The dispersant composition according to claim 102, wherein the maleated natural oil is selected from the group consisting of maleated avocado oils, maleated coconut oils, maleated corn oils, maleated cottonseed oils, maleated jojoba oils, maleated linseed oils, maleated nut oils, maleated olive oils, maleated palm oils, maleated raisin oils, maleated rapeseed oils, maleated safflower oils, maleated sesame oils, maleated soybean oils, maleated squash oils, maleated sunflower oils, maleated almond oils, maleated canola oils, maleated flaxseed oils, maleated grapeseed oils, maleated palm oils, maleated palm kernel oils, maleated peanut oils, maleated walnut oils, and mixture thereof.
113 The dispersant composition according to claim 103, wherein the maleated natural oil is a maleated soybean oil and the base is sodium hydroxide.
114. The dispersant composition according to claim 103, wherein the reaction product is selected from the group of structures, comprising a maleated functionality fully or partially reacted with the base, consisting of the following structures: , and mixtures thereof.
115. The dispersant composition according to claim 103, wherein the dispersant composition is a personal care composition, a coating composition, a food coating composition, and a pharmaceutical coating composition,
116. The dispersant composition according to claim 103, wherein the dispersant composition further comprises at least one functional ingredient selected from personal care agents, coating agents, food coating agents, pharmaceutical tablet coatings agents, and dispersant coatings agents.
117. A dispersant composition for coatings, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 103; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
118. The dispersant composition for coatings according to claim 117, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
119. The dispersant composition for coatings according to claim 117, wherein the solid particulate is selected from the group consisting of graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
120. The dispersant composition according to claim 117, wherein the dispersant composition is used in preparation of coating compositions selected from the group of architectural coatings, metal coatings, marine coatings, paints, decorative paints, interior paints, exterior paints, non-woven coatings, ceramic coatings, anti-corrosion coatings, flame retardant coatings, protective coatings, powder coatings, wood coatings, industrial coatings, anti-fouling coatings, anti-microbial coatings, thermal insulation coatings, water based coatings, and solvent based coatings.
121. The coating composition according to claim 117, wherein the dispersant composition is used for lacquer coating, primer coating, ink jet printing, top coating, varnish coating, architectural coating, wood coating, printing inks or metallic or non-metallic coating.
122. The coating composition according to claim 117, wherein the dispersant composition is coated on a substrate selected from the group consisting of porous and non-porous substrates, papers, non-woven materials, textiles, leather, wood, concrete, masonry, metals, non- metals, house wrap, building materials, fiberglass, polymeric articles, face masks, medical drapes and gowns, carpets, upholstery, tents, awnings, air bags, fabrics, ceramics, yarns, and blends, woven, knitted, natural, synthetic, and regenerated substrates.
123. The dispersant composition for coatings according to claim 117, wherein the dispersing agent is a reaction product of a maleated soybean natural oil, comprising a soybean oil with maleated functionality; and (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide; and mixtures thereof.
124. A dispersant composition for personal care, the composition comprising: (i) from about 0.1 to about 10 wt.% a dispersant composition of claim 103; and (ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
125. The dispersant composition for personal care according to claim 124, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
126. The dispersant composition for personal care according to claim 124, wherein the personal care composition is a skin care composition, hair care composition, and nail care composition.
127. The dispersant composition for personal care according to claim 124, wherein the personal care composition is a cosmetic composition selected from the group consisting of an eyeliner composition, a foundation composition, a long wear intense lipstick composition, a clay mask composition, a volume curling mascara composition, a carbon black mascara composition, a pressed powder composition, a blush composition, a lip gloss composition, an eye shadow composition, and a SPF composition.
128. The dispersant composition according to claim 124, wherein the dispersant composition is used in preparation of personal care compositions selected from the group comprising a foundation, a long wear intense lipstick, a clay mask, a volume curling mascara, a carbon black mascara, a pressed powder, a blush, a lip gloss, an eye shadow, a SPF fluid shake.
129. The dispersant composition for personal care according to claim 124, wherein the composition is an emulsion selected from oil-in-water emulsion and water-in-oil emulsion.
130. The dispersant composition for personal care according to claim 124, wherein the composition further optionally comprises at least one liquid component selected from oils, esters, alcohols, and glycols.
131. The dispersant composition for coatings according to claim 124, wherein the dispersing agent is a reaction product of a maleated soybean natural oil, comprising a soybean oil with maleated functionality; and (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide; and mixtures thereof.
132. A dispersant composition for color cosmetics, the composition comprising:
(i) from about 0.1 to about 10 wt.% a dispersant composition of claim 103; and
(ii) from about 0.1 to about 70 wt.% at least one solid particulate component.
133. The dispersant composition for color cosmetics according to claim 132, wherein the solid particulate is graphite, barium sulfate, metal oxide, carbon black, calcium silicate, calcium carbonate, clay, hydrated aluminum oxide, indigo, kaolin, silica, talc, zinc dioxide, titanium dioxide - isopropyl titanium triisostearate, zinc phthalocyanine, and mixtures thereof.
134. The dispersant composition for color cosmetics according to claim 132, wherein the color cosmetic is selected from the group comprising cleansing foam cream, massage cream, pack, skin lotion, milky lotion, sunscreen, foundation, white powder, eye shadow, blush, eyeliner, mascara, eyebrow, concealer, lipstick, and lip gloss.
135. The dispersant composition for coatings according to claim 132, wherein the dispersing agent is a reaction product of a maleated soybean natural oil, comprising a soybean oil with maleated functionality; and (b) a base selected from the group consisting of sodium hydroxide, potassium hydroxide, calcium hydroxide; and mixtures thereof.
EP24775726.3A 2023-03-22 2024-03-21 Dispersant compositions comprising hydrophobic and hydrophilic modified maleated natural oils, and applications thereof Pending EP4683973A2 (en)

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