EP4630664A1

EP4630664A1 - Combustion system having a fuel cell and a carbon capture system

Info

Publication number: EP4630664A1
Application number: EP23918823.8A
Authority: EP
Inventors: Dhinesh THANGANADAR; Murali Krishna KALAGA; Joel Meador HALL; Thomas Raymond FARRELL
Original assignee: Ge Vernova Technology GmbH
Current assignee: Ge Vernova Technology GmbH
Priority date: 2023-01-25
Filing date: 2023-01-25
Publication date: 2025-10-15
Also published as: CN120418525A; WO2024158389A1; JP2026502582A; KR20250137586A

Abstract

A combustion system is provided. The combustion system includes a topping cycle generating a flow of exhaust gas and a bottoming cycle. The combustion system further includes a heat recovery steam generator (HRSG) that receives the exhaust gases from the topping cycle. The HRSG generates a flow of steam for use in the bottoming cycle. A fuel cell includes an anode side, a cathode side, and an electrolyte. The cathode side receives the flow of exhaust gas from HRSG via a cathode inlet line. The cathode side removes a first portion of pollutants from the exhaust gas. A carbon capture system is fluidly coupled to cathode side via a cathode outlet line. The carbon capture system removes a second portion of pollutants from the exhaust gas.

Description

COMBUSTION SYSTEM HAVING A FUEL CELL AND A CARBON CAPTURE SYSTEM

FIELD

[0001] The present disclosure relates generally to a combustion system having a fuel cell and one or more additional carbon capture systems. Particularly, the present disclosure relates to a combustion system having a fuel cell and a carbon capture system.

BACKGROUND

[0002] A gas turbine power plant such as a combined cycle power plant (CCPP) or combined cycle system (CCS) generally includes a gas turbine having a compressor section, a combustion section, a turbine section, a heat recovery steam generator (HRSG) that is disposed downstream from the turbine and at least one steam turbine in fluid communication with the HRSG. During operation, air enters the compressor via an inlet system and is progressively compressed as it is routed towards a compressor discharge or diffuser casing that at least partially surrounds the combustor(s) of the combustion section. At least a portion of the compressed air is mixed with a fuel and burned within a combustion chamber defined within the combustor(s), thereby generating high temperature and high pressure combustion gases.

[0003] The combustion gases are routed along a hot gas path from the combustor through the turbine where they progressively expand as they flow across alternating stages of stationary vanes and rotatable turbine blades which are coupled to a rotor shaft. Energy is transferred from the combustion gases to the turbine blades, causing the rotor shaft to rotate. The rotational energy of the rotor shaft may be converted to electrical energy via a generator. The combustion gases exit the turbine as exhaust gas, and the exhaust gas enters the HRSG. Thermal energy from the exhaust gas is transferred to water flowing through one or more heat exchangers of the HRSG, thereby producing superheated or supercritical steam. The superheated steam is then routed into the steam turbine which may be used to generate additional electricity, thus enhancing overall power plant efficiency. [0004] Turbomachine combustion systems usually bum hydrocarbon fuels and produce air polluting emissions such as oxides of nitrogen (NOx), carbon monoxide (CO), and carbon dioxide (CO2). In an effort to reduce emissions, carbon capture systems are utilized to capture the CO2, and other air polluting gases before exhausting the turbomachine gases to the atmosphere. However, known carbon capture systems are only partially effective and require a large amount of energy. [0005] Accordingly, an improved combined cycle power plant having a carbon capture system, that removes pollutants from the emissions without requiring a large amount of electrical power, is desired and would be appreciated in the art.

BRIEF DESCRIPTION

[0006] Aspects and advantages of the combined cycle systems and methods in accordance with the present disclosure will be set forth in part in the following description, or may be obvious from the description, or may be learned through practice of the technology.

[0007] In accordance with one embodiment, a combustion system is provided. The combustion system includes a topping cycle generating a flow of exhaust gas and a bottoming cycle. The combustion system further includes a fuel cell having an anode side, a cathode side, and an electrolyte. The cathode side receives the flow of exhaust gas from the topping cycle via a cathode inlet line. The cathode side removing a first portion of pollutants from the exhaust gas. The combustion system further includes a heat recovery steam generator (HRSG) that receives the exhaust gases from the cathode side via a cathode outlet line. The HRSG generates a flow of steam for use in the bottoming cycle. A carbon capture system is fluidly coupled to the HRSG via an HRSG outlet line. The carbon capture system removes a second portion of pollutants from the exhaust gas.

[0008] In accordance with another embodiment, a method of removing pollutants in a combustion system is provided. The method includes operating a topping cycle of the combustion system, whereby a first power output and exhaust gases are generated. The method further includes conveying the exhaust gases through a cathode side of a fuel cell, whereby a first portion of the pollutants are removed from the exhaust gases. The method further includes providing the exhaust gases from an outlet of the cathode side to a carbon capture system. A second portion of the pollutants are removed from the exhaust gases by the carbon capture system.

[0009] In accordance with another embodiment, A combustion system is provided. The combustion system includes a topping cycle generating a flow of exhaust gas and a bottoming cycle. The combustion system further includes a heat recovery steam generator (HRSG) that receives the exhaust gases from the topping cycle. The HRSG generates a flow of steam for use in the bottoming cycle. A fuel cell includes an anode side, a cathode side, and an electrolyte. The cathode side receives the flow of exhaust gas from HRSG via a cathode inlet line. The cathode side removes a first portion of pollutants from the exhaust gas. A carbon capture system is fluidly coupled to cathode side via a cathode outlet line. The carbon capture system removes a second portion of pollutants from the exhaust gas.

[0010] In accordance with another embodiment, a combustion system is provided. The combustion system includes a gas turbine having a compressor section, a combustion section, and a turbine section. The turbine section generates exhaust gases. A fuel cell includes an anode side, a cathode side, and an electrolyte. The cathode side receives the exhaust gases from the turbine section via an exhaust gas outlet line. The cathode side removes a first portion of pollutants from the exhaust gas. A carbon capture system is fluidly coupled to the fuel cell for removing a second portion of pollutants from the exhaust gas. An exhaust gas recirculation line extends from the exhaust gas outlet line to the compressor section.

[0011] These and other features, aspects and advantages of the present combustion systems and methods will become better understood with reference to the following description and appended claims. The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments of the technology and, together with the description, serve to explain the principles of the technology.

BRIEF DESCRIPTION OF THE DRAWINGS

[0012] A full and enabling disclosure of the present combustion systems and methods, including the best mode of making and using the present systems and methods, directed to one of ordinary skill in the art, is set forth in the specification, which makes reference to the appended figures, in which:

[0013] FIG. 1 is a schematic illustration of a combustion system in accordance with embodiments of the present disclosure;

[0014] FIG. 2 is a schematic illustration of a combustion system in accordance with embodiments of the present disclosure; and

[0015] FIG. 3 is a flow diagram of a method of removing pollutants in a combustion system in accordance with embodiments of the present disclosure.

DETAILED DESCRIPTION

[0016] Reference now will be made in detail to embodiments of the present combustion systems and methods, one or more examples of which are illustrated in the drawings. Each example is provided by way of explanation, rather than limitation of, the technology. In fact, it will be apparent to those skilled in the art that modifications and variations can be made in the present technology without departing from the scope or spirit of the claimed technology. For instance, features illustrated or described as part of one embodiment can be used with another embodiment to yield a still further embodiment. Thus, it is intended that the present disclosure covers such modifications and variations as come within the scope of the appended claims and their equivalents.

[0017] The word “exemplary” is used herein to mean “serving as an example, instance, or illustration.” Any implementation described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other implementations. Additionally, unless specifically identified otherwise, all embodiments described herein should be considered exemplary.

[0018] The detailed description uses numerical and letter designations to refer to features in the drawings. Like or similar designations in the drawings and description have been used to refer to like or similar parts of the invention. As used herein, the terms “first”, “second”, and “third” may be used interchangeably to distinguish one component from another and are not intended to signify location or importance of the individual components. [0019] The term “fluid” may be a gas or a liquid. The term “fluid communication” means that a fluid is capable of making the connection between the areas specified. [0020] As used herein, the terms “upstream” (or “forward”) and “downstream” (or “aft”) refer to the relative direction with respect to fluid flow in a fluid pathway. For example, “upstream” refers to the direction from which the fluid flows, and “downstream” refers to the direction to which the fluid flows. However, the terms “upstream” and “downstream” as used herein may also refer to a flow of electricity. The term “radially” refers to the relative direction that is substantially perpendicular to an axial centerline of a particular component, the term “axially” refers to the relative direction that is substantially parallel and/or coaxially aligned to an axial centerline of a particular component and the term “circumferentially” refers to the relative direction that extends around the axial centerline of a particular component. [0021] Terms of approximation, such as “about,” “approximately,” “generally,” and “substantially,” are not to be limited to the precise value specified. In at least some instances, the approximating language may correspond to the precision of an instrument for measuring the value, or the precision of the methods or machines for constructing or manufacturing the components and/or systems. For example, the approximating language may refer to being within a 1, 2, 4, 5, 10, 15, or 20 percent margin in either individual values, range(s) of values and/or endpoints defining range(s) of values. When used in the context of an angle or direction, such terms include within ten degrees greater or less than the stated angle or direction. For example, “generally vertical” includes directions within ten degrees of vertical in any direction, e.g., clockwise or counter-clockwise.

[0022] The terms “coupled,” “fixed,” “attached to,” and the like refer to both direct coupling, fixing, or attaching, as well as indirect coupling, fixing, or attaching through one or more intermediate components or features, unless otherwise specified herein. As used herein, the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having” or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a process, method, article, or apparatus that comprises a list of features is not necessarily limited only to those features but may include other features not expressly listed or inherent to such process, method, article, or apparatus. Further, unless expressly stated to the contrary, “or” refers to an inclusive- or and not to an exclusive- or. For example, a condition A or B is satisfied by any one of the following: A is true (or present) and B is false (or not present), A is false (or not present) and B is true (or present), and both A and B are true (or present).

[0023] Here and throughout the specification and claims, range limitations are combined and interchanged, such ranges are identified and include all the sub-ranges contained therein unless context or language indicates otherwise. For example, all ranges disclosed herein are inclusive of the endpoints, and the endpoints are independently combinable with each other.

[0024] As used herein, the term “line” may refer to a fluid carrying conduit, such as a pipe, hose, tube, duct, or other fluid carrying conduit.

[0025] Referring now to the drawings, FIGS. 1 and 2 each illustrate a schematic diagram an embodiment of a combustion system or combined cycle system 100 that includes a topping cycle 102 and a bottoming cycle 104. In the topping cycle 102, fuel is burnt to produce electrical or mechanical power, and, as a result, exhaust gas 34 containing carbon dioxide is generated. In the bottoming cycle 104, the exhaust gas 34 from the topping cycle 102 may be then used to produce additional electrical or mechanical power. In various embodiments, the topping cycle 102 may be an internal combustion engine, an in industrial process in which fuel is burned, or others. In some embodiments, the bottoming cycle 104 may be a heat exchanger, a boiler, a supercritical CO2 cycle, a superheater, a evaporator, a pump, or others. In exemplary embodiments, as shown, the topping cycle 102 may be a gas turbine 10, and the bottoming cycle 104 may be a steam turbine system 22.

[0026] The combined cycle system 100 may include a gas turbine 10 for driving a first load 14. The first load 14 may, for instance, be an electrical generator for producing electrical power. The gas turbine 10 may include a turbine section 16, combustors or a combustion section 18, and a compressor section 20. The turbine section 16 and the compressor section 20 may be connected by one or more shafts 21. A combustor fuel supply 15 may supply a fuel to the combustors in the combustion section 18. The combustor fuel supply 15 may supply a natural gas to the combustion section 18, such as a hydrocarbon fuel, which may include methane, propane, or others. In exemplary embodiments, the combustor fuel supply 15 may supply methane (CH4) to the combustion section 18. Additionally, or alternatively, the combustor fuel supply 15 may supply liquid fuel to the combustors, such as diesel, crude oil, syngas, or others.

[0027] During operation of the gas turbine 10, a working fluid such as air 171 flows into the compressor section 20 where the air is progressively compressed, thus providing compressed air to the combustor(s) of combustion section 18. The compressed air is mixed with fuel and burned within each combustor to produce combustion gases. The combustion gases flow through the hot gas path from the combustion section 18 into the turbine section 16, where energy (kinetic and/or thermal) is transferred from the combustion gases to the rotor blades, causing the one or more shafts 21 to rotate. The mechanical rotational energy may then be used to power the compressor section 20 and/or to generate electricity.

[0028] Heated exhaust gas 34 exiting the turbine section 16 may then be exhausted from the gas turbine 10 and routed first to either a heat recovery steam generator (HRSG) 32 or through a fuel cell 106, where a first portion of pollutants (e.g., CO2) are removed from the exhaust gas 34. For example, in some embodiments, as shown in FIG. 2, the exhaust gas 34 may be first routed through the HRSG 32 before entering the fuel cell 106. In such embodiments, in which the exhaust gas 34 is routed via HRSG 32 first prior to entering the fuel cell 106, the exhaust gas will be cooled to between about 60 °C and about 150 °C upon exiting the HRSG 32. The inlet temperature of the exhaust gases 34 at the cathode side 116 needs to be between about 500°C and about 650°C. As such, a heat exchanger 180 may be disposed on the cathode inlet line 118 for preheating the exhaust gas 34 prior to entrance into the cathode side 116. The heat exchanger 180 may be disposed in thermal communication on the cathode inlet line 118 downstream of the HRSG 32 and upstream of the cathode side 116. The heat exchanger 180 may receive cathode output products (e.g., an entirety of the cathode output products) as the thermal fluid. For example, the heat exchanger 180 may be in fluid communication on the cathode outlet line 146. After passing through the heat exchanger 180, the cathode output products may be provided to the carbon capture system 108. The cathode output products may transfer heat to the exhaust gases in the cathode inlet line 118. Additionally, or alternatively, a burner 184 may be included on the cathode inlet line 118 for increasing the temperature of the exhaust gases prior to entrance into the cathode side 116. The burner 184 may bum fuel, which may be either natural gas (e.g., from the fuel supply 15) or anode output products.

[0029] In other embodiments, as shown in FIG. 1, exhaust gas 34 may be first routed through the fuel cell 106 before entering the HRSG 32. In the HRSG 32, a heat transfer takes place between the exhaust gas 34 and the various components of the HRSG 32 to generate steam, which is provided to the steam turbine system 22. The exhaust gases 34 may then be routed to a carbon capture system 108, such as an adsorption bed, where a second portion (e.g., a remainder) of the pollutants (e.g., CO2) is removed from the exhaust gas. Finally, the exhaust gas 34 may exit the carbon capture system 108 to the atmosphere via an exhaust stack 110.

[0030] Upon exiting the turbine section 16, the exhaust gas 34 may include mostly nitrogen (N2), carbon dioxide (CO2), oxygen (O2), and water (H2O). Additionally, the exhaust gas 34 may include traces of carbon monoxide (CO), nitrogen oxides (NOx), sulfur oxides (SOx), and/or argon (Ar). In exemplary implementations of the combined cycle system 100, a first portion of the carbon dioxide (CO2) may be removed from the exhaust gas 34 in the fuel cell 106, and a second portion of the carbon dioxide (CO2) may be removed from the exhaust gas 34 in the additional carbon capture system 108 (e.g., an adsorption bed). In many embodiments, the second portion of the CO2 that is removed in the carbon capture system 108 may be a remainder of the CO2 in the exhaust gas 34, such that all of the CO2 (e.g., 100%) may be removed from the exhaust gas 34 prior to being exhausted via the exhaust stack 110.

[0031] The combined cycle system 100 may also include the steam turbine system 22 for driving a second load 24. The second load 24 may also be an electrical generator for generating electrical power. However, both the first and second loads 14, 24 may be other types of loads capable of being driven by the gas turbine 10 and steam turbine system 22. In addition, although the gas turbine 10 and steam turbine system 22 may drive separate loads 14 and 24, as shown in the illustrated embodiment, the gas turbine 10 and steam turbine system 22 may also be utilized in tandem to drive a single load via a single shaft.

[0032] In the illustrated embodiment, the steam turbine system 22 may include a low pressure (LP) steam turbine 26, an intermediate pressure (IP) steam turbine 28, and a high pressure (HP) steam turbine 30. The low pressure (LP) steam turbine 26, the intermediate pressure (IP) steam turbine 28, the high pressure (HP) steam turbine 30, and the load 24 may each be disposed on one or more shafts 23 (such as a common shaft in some embodiments).

[0033] In exemplary embodiments, the fuel cell 106 may include an anode side 112, a cathode side 116, and an electrolyte 114 (which may conduct electrically charged ions). The fuel cell 106 may directly convert chemical energy stored in hydrocarbon fuel into electrical energy by means of an electrochemical reaction. In exemplary embodiments, the fuel cell 106 may be a molten carbonate fuel cell (MCFC), such as an internal reforming MCFC and/or an external reforming MCFC. In such embodiments, the electrolyte 114 may be a molten carbonate salt mixture suspended in a porous, chemically inert, ceramic matrix of beta-alumina solid electrolyte (BASE). The MCFC may operate by passing a reactant fuel gas (e.g., natural gas) through the anode side 112, while oxidizing gas (e.g., the exhaust gas which contains carbon dioxide along with oxygen) is passed through the cathode side 116, which causes an electrochemical reaction across the electrolyte 114 that consumes (or chemically converts) carbon dioxide and produces electricity.

Particularly, in the cathode side 116, oxygen and carbon dioxide formulate carbonate ions (CO3² ).

[0034] As briefly mentioned above, the fuel cell 106 converts the anode fuel stream and exhaust gas into electrical energy while removing CO2 from the exhaust gas (e.g., the CO2 is removed via an electrochemical reaction within the fuel cell 106). For example, a fuel cell power output 120 may be directed to a power converter 121 in order to change the DC current into AC current that can be effectively utilized by one or more subsystems. In particular, for the embodiment depicted, the power output 120 is provided from the power converter to one or more electric devices 122 via an electric bus 124. The electric bus 124 may be an electric bus dedicated to the combined cycle system 100, the gas turbine 10, the steam turbine system 22, an electric bus of the fuel cell 106, an electric bus of the carbon capture system 108, or others. The electric bus 124 is in electric communication with one or more additional electrical devices 122, which may be a power source, a power sink, or both. For example, the additional electrical devices 122 may be a power storage device (such as one or more batteries), an electric machine (an electric generator, an electric motor, or both). Alternatively, or additionally, the power output 120 may aid in driving the first load 14 and/or the second load 24. The combined cycle system 100 may generate a total power output (e.g., the summation of the first load 14, the second load 24, and the power output 120 of the fuel cell 106). In many embodiments, the power output 120 of the fuel cell 106 may be between about 10% and about 30% of the total power output of the combined cycle system 100. In other embodiments, the power output 120 of the fuel cell 106 may be between about 15% and about 25% of the total power output of the combined cycle system 100.

[0035] In many embodiments, the cathode side 116 may be fluidly coupled (e.g., directly fluidly coupled) to the gas turbine 10 via a cathode inlet line 118. The cathode inlet line 118 may be the same conduit as an exhaust outlet line 117 extending from an outlet of the turbine section 16, or the cathode inlet line 118 may extend from the exhaust outlet line 117. Particularly, the cathode side 116 may be fluidly coupled to an outlet of the turbine section 16 such that the cathode side 116 receives a flow of exhaust gas 34 from the turbine section 16. For example, the cathode inlet line 118 may extend (e.g., directly) between an outlet of the turbine section 16 and an inlet of the cathode side 116 of the fuel cell 106 to convey exhaust gas 34 from the turbine section 16 to the cathode side 116. In exemplary embodiments, all of the exhaust gas 34 from the outlet of the turbine section 16 may be routed through the cathode side 116 of the fuel cell 106 to remove a first portion of pollutants (e.g., CO2) from the exhaust gas 34 (i.e., no branch lines may extend from the cathode inlet line 118). In optional embodiments, as shown in FIG. 1, a fan or blower 157 may be included on the cathode inlet line 118. The fan 157 may advantageously overcome the flow resistance in the cathode side 116, HRSG 32, direct contact cooler 155, and carbon capture system 108. In other words, the fan 157 may promote the flow of exhaust gases through the cathode side 116, HRSG 32, direct contact cooler 155, and carbon capture system 108.

[0036] In various embodiments, the anode side 112 may receive a flow of fuel and/or steam via an anode inlet line 126. The fuel and steam may be conveyed through the anode side 112. The anode inlet line 126 may fluidly couple the anode side 112 to an anode fuel supply 128. In some embodiments, the anode fuel supply 128 may be the same as the combustor fuel supply 15, such that the same fuel is supplied to both the combustion section and the anode side of the fuel cell 106. In other embodiments, the anode fuel supply 128 and the combustor fuel supply 15 may be different. In many implementations, the anode fuel supply 128 may supply a natural gas (e.g., a hydrocarbon fuel) to the anode side 112 via the anode inlet line 126. The natural gas may include methane, propane, or others. In exemplary embodiments, the anode fuel supply 128 may supply methane (CH4) to the anode side 112. A fuel preheater 130, such as a heat exchanger, may be disposed in thermal communication on the anode inlet line 126. The fuel preheater 130 may heat the fuel prior to entrance into the anode side 112 of the fuel cell 106, which advantageously increases the efficiency of the fuel cell 106.

[0037] In exemplary embodiments, the combined cycle system 100 may include an anode steam supply line 188. The anode steam supply line 188 may extend between the heat exchanger 136 and the anode inlet line 126. Steam may be produced by the heat from the anode output products within the heat exchanger 136 and provided to the anode inlet line 126. The anode steam supply line 188 may provide a flow of steam to the anode inlet line 126 for use in the anode side 112 of the fuel cell 106. In various embodiments (not shown), the anode steam supply line 126 may be fluidly coupled to the HRSG 32, such that the HRSG 32 supplies steam to both the steam turbine system 22 and the anode side 112 of the fuel cell 106.

[0038] In many embodiments, the combined cycle system 100 may include an anode outlet line 132 that is fluidly coupled to an outlet of the anode side 112, such that the anode outlet line 132 receives the output products from the anode side 112 after the electrochemical reaction within the fuel cell 106. In certain embodiments, the anode output products may include CO2, CO, H2, water, and unutilized CH4 (e.g., methane that was not utilized within the fuel cell 106 during the electrochemical reaction). The anode output products may be supplied to a separation system 134, which may remove the water and liquified CO2 from the anode output products.

[0039] The separation system 134 may include, in a serial flow order (e.g., from upstream to downstream), a heat exchanger 136, a water flash separator 138, a compressor 140, a chiller 142, and a liquid carbon dioxide separator 144. The heat exchanger 136 may be thermally and fluidly coupled to the anode outlet line 132. For example, the anode outlet line 132 may extend between an outlet of the anode side 112 and the heat exchanger 136. The heat exchanger 136 may remove heat from the anode output products prior to entrance into the water flash separator 138, which produces steam in the steam inlet line 188 for use at the inlet of the anode side in order to maintain a desired steam to carbon molar ratio (which may be between about 1.5 and about 5, or particularly between about 2 and about 3). A water flash inlet line 137 may extend between, and fluidly couple, the heat exchanger 136 and the water flash separator 138. The water flash separator 138 may remove any water from the anode output products. For example, the water in the anode output products may be cooled to a liquification temperature by the heat exchanger 136 and subsequently removed by the water flash separator 138. In some embodiments, the anode output products may pass through a water gas shift reactor to convert the carbon monoxide to hydrogen. In such embodiments, the water gas shift reactor may be disposed between the heat exchanger 136 and the water flash separator 138.

[0040] In many embodiments, a compressor inlet line 139 may extend between, and fluidly couple, the water flash separator 138 and the compressor 140. The compressor 140 may pressurize the anode output products and provide the pressurized anode output products to a chiller 142 via a chiller inlet line 141. The chiller 142 may liquify the CO2 in the pressurized anode output products by reducing the temperature of the pressurized anode output products. Subsequently, the liquid CO2 may be removed via the liquid carbon dioxide separator 144. The removed liquid carbon dioxide may be sent to carbon sequestration or utilization. For example, the chiller 142 may be fluidly coupled to the liquid carbon dioxide separator 144 via a connection line 143.

[0041] An anode recirculation line 145 may extend from an outlet of the separation system 134 to the anode inlet line 126 (upstream of the fuel preheater 130). For example, the anode recirculation line 145 may extend from the liquid carbon dioxide separator 144 to the anode inlet line 126 downstream of the fuel preheater 130 to reintroduce the anode output products (which have had the water and liquid carbon dioxide removed) into the anode side 112. For example, the anode recirculation line 145 may advantageously reintroduce any unutilized methane and excess hydrogen back into the anode side 112 for electrochemical conversion. [0042] In some embodiments, as shown in FIG. 1, the HRSG 32 may be disposed downstream of the cathode side 116. In such embodiments, the HRSG 32 may be fluidly coupled (e.g., directly fluidly coupled in some embodiments) to an outlet of the cathode side 116 of the fuel cell 106. The HRSG 32 may generate a flow of steam for use in the bottoming cycle 104. For example, a cathode outlet line 146 may extend between, and fluidly couple, an outlet of the cathode side 116 and the HRSG 32. The HRSG 32 may generate steam with the heat from the exhaust gases exiting the cathode side 116, and the steam may be supplied to the steam turbine system 22. [0043] In other embodiments, as shown in FIG. 2, the HRSG 32 may be disposed upstream of the cathode side 116. In such embodiments, the HRSG 32 may be fluidly coupled (e.g., directly fluidly coupled in some embodiments) to an outlet of the turbine section 16. The HRSG 32 may generate a flow of steam for use in the bottoming cycle 104. The HRSG 32 may generate steam with the heat from the exhaust gases exiting turbine section 16, and the steam may be supplied to the steam turbine system 22.

[0044] A steam supply line 148 may extend from the HRSG 32 to the steam turbine system 22. Particularly, the steam supply line 148 may extend from the HRSG 32 to the HP steam turbine 30. The outlet of the HP steam turbine 30 may be fluidly coupled to an inlet of the IP steam turbine 28, and an outlet of the IP steam turbine 28 may be fluidly coupled to an inlet of the LP steam turbine 26. Alternatively, in other embodiments (not shown), the outlet steam of the HP steam turbine 30 may re-enter a reheater in the HRSG and be superheated and subsequently returned to an inlet of the IP steam turbine 28. An outlet of the LP steam turbine may be fluidly coupled to a condenser 150 via a turbine outlet line 152. The condenser may convert the steam from the outlet of the LP steam turbine 26 to water, which may be provided back to the HRSG 32 via a condensate return line 151.

[0045] In certain embodiments, the combined cycle system 100 may further include a cathode recirculation line 168 that extends from, and fluidly couples, the cathode outlet line 146 to the cathode inlet line 118. For example, the cathode recirculation line 168 may fluidly extend between an inlet disposed on the cathode outlet line 146 (e.g., between an outlet of the cathode side 116 and an inlet of the HRSG 32) and an outlet disposed on the cathode inlet line 118. The cathode recirculation line may reintroduce any unreacted CO2 back into the cathode side 116 for further reacting/removal from the exhaust gas.

[0046] In many embodiments, as shown in FIG. 1, a carbon capture system 108, such as a sorbent based carbon capture system, may be fluidly coupled to the fuel cell 106, such that the carbon capture system 108 receives cathode output products from the cathode side 116 of the fuel cell 106. Particularly, the carbon capture system may be fluidly coupled to an outlet of the HRSG 32 via an HRSG outlet line 154. The HRSG outlet line 154 may convey the exhaust gases from the outlet of the HRSG 32 to the carbon capture system 108. In exemplary embodiments, the carbon capture system 108 may be an adsorption bed 156 that removes a second portion of pollutants (e.g., CO2) from the exhaust gas. Particularly, the adsorption bed 156 may remove the remainder of the CO2 from the exhaust gas, such that all of the CO2 is removed from the exhaust gas prior to exiting the exhaust stack 110. Additionally, in some embodiments, as shown in FIG. 1, a direct contact cooler 155 may be included in the HRSG outlet line 154 for further cooling the exhaust gas exiting the HRSG 32 prior to entrance into the carbon capture system 108. For example, the direct contact cooler 155 may be disposed on the HRSG outlet line 154 upstream of the carbon capture system 108. The direct contact cooler 155 may be spray water (or other suitable coolant) into the exhaust gases, thereby cooling the temperature of the exhaust gases prior to entrance into the carbon capture system 108.

[0047] In other embodiments, as shown in FIG. 2, the carbon capture system 108 may be fluidly coupled (e.g., directly fluidly coupled) to an outlet of the cathode side 116 via a cathode outlet line 146. In such embodiments, the cathode outlet line 146 may extend between, and fluidly couple, the cathode side 116 and the carbon capture system 108. The cathode outlet line 146 may convey the exhaust gases from the outlet of the cathode side 146 to the carbon capture system 108.

[0048] While exemplary embodiments of the carbon capture system 108 include an adsorption bed 156, the carbon capture system 108 may apply various techniques including but not limited to pressure swing adsorptions, temperature swing adsorption, rapid thermal swing adsorption, vacuum temperature swing adsorption, chemical absorption, cryogenic separation, and membrane separation to separate the remaining carbon dioxide from the exhaust gas. [0049] In various embodiments, the carbon capture system 108 may employ pressure swing adsorption (PSA). PSA may be used for separation of carbon dioxide from a mixture of gases. In PSA techniques, at a high partial pressure, solid molecular sieves can adsorb carbon dioxide. As a result, at elevated pressures, carbon dioxide is removed from the mixture of gases when this mixture is passed through an adsorption bed. Regeneration of the bed is accomplished by depressurization and purging. Typically for critical operations, a plurality of adsorption vessels are used for continuous separation of carbon dioxide, in which one adsorption bed is used while the others are regenerated.

[0050] In exemplary embodiments, the carbon capture system 108 may employ temperature swing adsorption (TSA). In TSA, the sorbent adsorbs the CO2 from the cathode output products at cold temperatures (preferably between cryogenic low temperature up to <60 °C). Subsequently, the saturated sorbent bed undergoes desorption by increasing the temperature (typically >100 °C). The desorption may happen under vacuum condition or with the presence of sweep gas to lower the partial pressure of CO2. The heat required for desorption may be supplied by steam from the low pressure steam turbine. Finally, the sorbent bed will be cooled back to the initial temperature so that the bed is ready for the next adsorption cycle.

[0051] In certain embodiments, the carbon capture system 108 may separate carbon dioxide from the exhaust gas by chemical absorption using oxides, such as, calcium oxide (CaO) and magnesium oxide (MgO) or a combination thereof. In one embodiment, at elevated pressure and temperature, CO2 is absorbed by CaO forming calcium carbonate (CaCOs). thereby removing CO2 from the gas mixture. The sorbent CaO is regenerated by calcinations of CaCO3, which can again reform CaCOs to CaO.

[0052] In some embodiments, membrane separation technology may also be used by the carbon capture system 108 for separation of carbon dioxide from the exhaust gas. The membranes used for high temperature carbon dioxide separation include zeolite and ceramic membranes, which are selective to CO2. Membrane separators work more efficiently at higher pressures, and use of a membrane separator to separate the carbon dioxide from the exhaust gas may be achieved by further compression (e.g., with one or more compressors upstream of the carbon capture system 108).

[0053] In other embodiments, another technique that may be used by the carbon capture system 108 for separation of CO2 from the exhaust gas may include, but is not limited to, chemical absorption of CO2 using amines. The exhaust gas may be cooled to a suitable temperature to use chemical absorption of carbon dioxide using amines. This technique is based on alkanol amines solvents that have the ability to absorb carbon dioxide at relatively low temperatures, and are easily regenerated by raising the temperature of the rich solvents. A carbon dioxide rich stream is obtained after regeneration of the rich solvent. The solvents used in this technique may include pure or a mixture of triethanolamine, monoethanolamine, diethanolamine, diisopropanolamine, diglycolamine, and piperazine.

[0054] In some other embodiments, the carbon capture system may comprise at least one absorption vessel, where a chemical absorption technique is used. In yet another embodiment the carbon dioxide separator comprises at least one membrane separator.

[0055] ]In exemplary embodiments, the carbon capture system may include at least one adsorption bed 156, in which a TSA technique may be used to separate the carbon dioxide from the exit stream exhaust gas. Particularly, in exemplary embodiments, the carbon capture system 108 may include a plurality of adsorption beds 156 (e.g., between about 10 and about 500 adsorption beds, or such as between about 10 and about 400 adsorption beds, or such as between about 30 and about 250 adsorption beds, or such as between about 10 and about 100 adsorption beds). In operation, some adsorption beds 156 will undergo adsorption and some adsorption beds 156 may undergo desorption, while the remaining adsorption beds undergo cooling for a temperature swing adsorption process. Under part load, only some of the adsorption beds will be required to be operational owing to reduced CO2 flow rate in the exhaust gas (or cathode output products), which makes other adsorption beds 156 stand-by. Ambient air can be supplied to these stand-by adsorption beds 156 to adsorb additional CO2 from the atmosphere, thereby achieving negative system emissions. Alternatively, or additionally, some additional adsorption beds can be added which can act as a direct air capture system accepting steam from the steam turbine for desorption. In this way, negative carbon emission may be achieved during normal full load condition.

[0056] In other embodiments, the adsorption beds 156 may be direct contact adsorption beds. Direct contact adsorption beds include one large rotating bed that includes many segments which undergo different processes. In such embodiments, the carbon capture system 108 may include between about 1 and about 100 direct contact adsorption beds.

[0057] For example, the combined cycle system 100 may further include an air inlet line 160 fluidly coupled to the atmosphere (or the ambient environment) and to the carbon capture system 108. Particularly, the air inlet line 160 may be in fluid communication with each of the adsorption beds 156, such that additional air may be supplied to stand-by adsorption beds 156 for additional carbon capture. . In many embodiments, a pump 162 (such as a fan or blower) and a valve 164 may be disposed in fluid communication on the air inlet line 160. The valve 164 may be actuatable between an open position (which allows for air to flow through therethrough) and a closed position (which restricts or otherwise prevents the passage of air). The valve 164 may be downstream of the pump 162. The pump 162 may create a pressure differential that pulls air from the atmosphere when the pump is operating. The air from the atmosphere may be passed through the carbon capture system 108 (e.g., the adsorption bed 156) to remove any pollutants (e.g., CO2) present in the air. This advantageously allows the combined cycle system 100 to have negative carbon dioxide emissions because all of the carbon dioxide (e.g., 100%) in the exhaust gas from the turbine section 16 may be captured by the fuel cell 106 and the carbon capture system 108, and additional atmospheric air may be introduced to the carbon capture system 108 by the air inlet line 160 for carbon dioxide removal of the additional atmospheric air.

[0058] Using the various techniques described herein, a carbon dioxide rich stream 158 is generated from the carbon capture system 108. The carbon dioxide rich stream 158 may be sequestered or exported for any other industrial use.

[0059] In many embodiments, the combined cycle system 100 may further include an exhaust line 166 extending between the carbon capture system 108 and the exhaust stack 110. Particularly, the exhaust line 166 may extend between an outlet of the adsorption bed 156 and the exhaust stack 110. The exhaust stack 110 may exhaust the exhaust gases (which have had the pollutants removed) to the atmosphere.

[0060] As described above, the fuel cell 106 and the carbon capture system 108 may collectively remove all of the pollutants (e.g., carbon dioxide) from the exhaust gas exiting the topping cycle 102 prior to exhaustion of the exhaust gas into the atmosphere via the exhaust stack 110. For example, between about 85% and about 100% of the pollutants from the exhaust gases exiting the topping cycle 102 are captured collectively by the fuel cell 106 and the carbon capture system 108 (e.g., the adsorption bed 156). The fuel cell 106 may remove a majority of the carbon dioxide from the exhaust gas, and the carbon capture system 108 may remove the remainder of the carbon dioxide from the exhaust gas. Particularly, between about 50% and about 90% of the carbon dioxide from the exhaust gas may be removed in the fuel cell 106 when exhaust gas recirculation is implemented, or such as between about 75% and about 85% without exhaust gas recirculation. While more carbon dioxide may be removed in the fuel cell 106, this is not possible without overly stressing the fuel cell 106, reducing the life of the fuel cell 106, and reducing the electric efficiency (i.e., the ratio between the electricity produced from the fuel cell to the fuel energy supplied at the anode) of the fuel cell 106. As such, operating the fuel cell 106 in a manner that removes between about 75% and about 85% of the carbon dioxide from the exhaust gas advantageously preserves the life of the fuel cell 106 and allows for efficient operation. The remainder of the carbon dioxide in the exhaust gas exiting the turbine section 16, e.g., between about 10% and about 30% of the carbon dioxide in the exhaust gas (or such as between about 15% and about 25% of the carbon dioxide in the exhaust gas) may be removed by the carbon capture system 108 (e.g., the adsorption beds 156 in exemplary embodiments).

[0061] As discussed above, in some embodiments, as shown in FIG. 1, the HRSG 32 may be disposed downstream of the cathode side 116, such that the exhaust gases 34 travel through the cathode side 116 prior to entering the HRSG 32. In such embodiments, the cathode outlet line 146 provide the exhaust gases (or cathode output products) to the HRSG 32, and the HRSG outlet line 154 may provide the exhaust gases to the carbon capture system 108. Alternatively, as shown in FIG. 2, the HRSG 32 may be disposed upstream of the cathode side 116. In such embodiments, the HRSG 32 may receive exhaust gases from the exhaust gas outlet line 117. Subsequently, the exhaust gases may be provided to the cathode side 116 via the cathode inlet line 118. Additionally, as shown in FIG. 2, when the HRSG 32 is disposed upstream of the fuel cell 106, the cathode output products may be provided directly to the carbon capture system 108 (e.g., via the cathode outlet line 146). [0062] In many embodiments, as shown in FIGS. 1 and 2, the combined cycle system 100 may include an exhaust gas recirculation line 170 that fluidly couples the turbine section 16 to the compressor section 20, such that exhaust gas from an outlet of the turbine section 16 are provided to an inlet of the compressor section 20. The exhaust gas recirculation line 170 may extend from the exhaust gas outlet line 117 to the compressor section 20. In such embodiments, the compressor 20 may receive ambient air 171 as well as recirculated exhaust gas. When exhaust gas recirculation is introduced, this increases the CO2 mol% in the gas turbine exhaust gases from about 4.3% to about ~8%, which allows for the fuel cell 106 to operate at higher efficiency. For example, with exhaust gas recirculation, the fuel cell 106 may remove up to 90% of the CO2 from the exhaust gases. The exhaust gas recirculation line 170 selectively divert a portion of the exhaust gas from the exhaust gas outlet line 117 back to the inlet of the compressor section 20. For example, a valve 172 may be disposed on the exhaust gas recirculation line 170. The valve 172 may be selectively actuated between an open position (which allows for exhaust gas recirculation) and a closed position (which restricts or prevents exhaust gas recirculation). Additionally, in exemplary embodiments, an exhaust gas cooler 174 may be disposed on the exhaust gas recirculation line 170. The exhaust gas cooler 174 may be a heat exchanger that cools the exhaust gas within the exhaust gas recirculation line 170 in order to meet inlet temperature requirements for the gas turbine 10.

[0063] Referring now to FIG. 3, a flow diagram of one embodiment of a method 200 for removing pollutants in a combined cycle system is illustrated in accordance with aspects of the present subject matter. In general, the method 200 will be described herein with reference to the combined cycle system 100 described above with reference to FIGS. 1 and 2. However, it will be appreciated by those of ordinary skill in the art that the disclosed method 200 may generally be utilized with any suitable combined cycle system and/or may be utilized in connection with a system having any other suitable system configuration. In addition, although FIG. 3 depicts steps performed in a particular order for purposes of illustration and discussion, the methods discussed herein are not limited to any particular order or arrangement unless otherwise specified in the claims. One skilled in the art, using the disclosures provided herein, will appreciate that various steps of the methods disclosed herein can be omitted, rearranged, combined, and/or adapted in various ways without deviating from the scope of the present disclosure.

[0064] As shown, the method 200 may include at (202) operating a topping cycle 102 of the combined cycle system 100, whereby a first power output and exhaust gases are generated. For example, operating a topping cycle 102 may include operating a gas turbine 10 at part or full load. As a result, a first power output and exhaust gases are generated. The first power output may be generated by the first load 14. The first load 14 may, for instance, be an electrical generator coupled to the gas turbine 10 via one or more shafts, which rotate to produce the first power output. The gas turbine 10 may bum natural gas fuel in the combustion section 18, which may be routed through the turbine section 16 and exhausted as exhaust gases, which may contain pollutants such as carbon dioxide.

[0065] In exemplary implementations, as shown, the method 200 may further include at (204) conveying the exhaust gases through a cathode side 116 of a fuel cell 106, whereby a first portion of the pollutants are removed from the exhaust gases. For example, an electrochemical reaction may take place within the fuel cell 106 that both removes the carbon dioxide from the exhaust gas and produces electricity, which may be provided to one or more electrical devices 122 via an electric bus 124. In exemplary embodiments, the fuel cell 106 may be a molten carbonate fuel cell (MCFC), such as an internal reforming MCFC and/or an external reforming MCFC. The MCFC may operate by passing a reactant fuel gas mixed with steam (e.g., natural gas mixed with steam) through the anode side 112, while oxidizing gas (e.g., the exhaust gas which contains carbon dioxide and oxygen) is passed through the cathode side 116, which causes an electrochemical reaction across the electrolyte 114 that removes (or chemically converts) carbon dioxide and produces electricity and hydrogen. [0066] In many implementations, as shown, the method 200 may further include at (206) providing the exhaust gases from an outlet of the cathode side (i.e. , the cathode output products) to a carbon capture system 108. A second portion of the pollutants (e.g., carbon dioxide) is removed from the exhaust gases once passed through the carbon capture system 108. For example, the carbon capture system 108 may be an adsorption bed 156 that removes the remainder of the carbon dioxide from the exhaust gas downstream of the fuel cell 106.

[0067] For example, the pollutants may be carbon dioxide, and the first portion of the pollutants removed from the exhaust gases by the cathode side may be a majority (e.g., greater than 50%) of the carbon dioxide in the exhaust gases when exiting the gas turbine 10. As such, the second portion of the pollutants removed from the exhaust gases by the carbon capture system 108 may be a remainder of the carbon dioxide in the exhaust gases. Particularly, up to about 85% of the carbon dioxide in the exhaust gases from the turbine section 16 may be removed (i.e., electrochemically converted) in the cathode side 116 of the fuel cell 106, and the remainder (e.g., about 15%) of the carbon dioxide may be removed by the carbon capture system 108 prior to exhaustion from the exhaust stack 110. For example, between about 85% and about 100% of the pollutants from the exhaust gases exiting the topping cycle 102 are captured collectively by the fuel cell 106 and the carbon capture system 108 (e.g., the adsorption bed 156). The fuel cell 106 may remove a majority of the carbon dioxide from the exhaust gas, and the carbon capture system 108 may remove the remainder of the carbon dioxide from the exhaust gas. Particularly, between about 70% and about 90% of the carbon dioxide from the exhaust gas may be removed in the fuel cell 106, or such as between about 75% and about 85%. While more carbon dioxide may be removed in the fuel cell 106, this is not possible without overly stressing the fuel cell 106, reducing the life of the fuel cell 106, and reducing the efficiency of the fuel cell 106. As such, operating the fuel cell 106 in a manner that removes between about 50% and about 85% (or such as between about 50% and about 90% when exhaust gas recirculation is implemented) of the carbon dioxide from the exhaust gas advantageously preserves the life of the fuel cell 106 and allows for efficient operation. The remainder of the carbon dioxide in the exhaust gas exiting the turbine section 16, e.g., between about 15% and about 50% of the exhaust gas (or such as between about 15% and about 25%) may be removed by the carbon capture system 108 (e.g., the adsorption bed 156 in exemplary embodiments).

[0068] In many implementations, operating the combined cycle system 100 may generate a total power output (e.g., the summation of the power generated by the first load 14, the power generated by the second load 24, and the power output 120 of the fuel cell 106). In exemplary implementations, operating the fuel cell 106 and the carbon capture system 108 may require a power supply that is between about 0.5% and about 5% of the total power output (or such as between about 3% and about 5%). As discussed above, the fuel cell 106 may be capable of more aggressive operation, in which greater than 85-90% of the carbon dioxide is captured in the fuel cell 106; however, this increases the contribution from the loss mechanisms significantly, such as cathode polarization (which is the prevailing resistance due to low concentration of carbon dioxide), ohmic resistance, anode polarization, and activation loses. This reduces the overall plant efficiency, or electrical efficiency of the fuel cell 106.

Operating the fuel cell 106 at a carbon dioxide consumption of up to about 85% while capturing the remaining carbon dioxide with an additional carbon capture system 108 (e.g., an adsorption bed 156 in exemplary embodiments) advantageously only requires a power supply that is between about 3% and about 5% of the total power output of the combined cycle system 100, which is lower than other designs) for achieving 100% carbon capture rate because the specific energy required to capture the CO2 (MJ/kg of CO2 captured) monotonically increases as the carbon capture rate increases. Additionally, fuel cell 106 (such as an MCFC) integration produces about 20-25 % additional power therefore, the plant net power output is increased whereas all other carbon capture technologies consume energy, thereby lowering the net power output from the plant. The fuel cell 106 (e.g., an MCFC) may produces excess power of about 20% to 25% (assuming a carbon capture rate of about 85%; when the carbon capture rate is reduced to about 50%, the lower range of the excess power may be about 10%); however, it also consumes fuel to do so. Increasing the CO2 capture rate from fuel cell 106 increases the losses within fuel cell 106 therefore reducing the fuel to electric efficiency of the fuel cell 106, thereby making the power production from fuel cell 106 relatively lesser efficient compared to producing power from combined cycle power plant. Moreover, the separation system 134 consumes parasitic load, and these contributes to the reduction of the overall plant efficiency by greater than about 2% (which may increase as the carbon capture rate in the fuel cell 106 is increased). In implementations where the carbon capture rate in the fuel cell 106 is reduced to about 50%, the reduction in overall plant efficiency may be about 1%.

[0069] The maximum CO2 capture limit of the fuel cell 106 (such as an MCFC) will vary as the function of the CO2 concentration in the exhaust gas. The gas turbine 10 exhaust gas 34 which contains typically about 5% mole of CO2. When exhaust gas recirculation is implemented, the %mol increases to about 8% mole of CO2, which in turn increases the maximum CO2 capture by the fuel cell 106 from about 85% to about 90%. Other processes, such as industrial processes, may have high CO2 concentration exhaust gases (for example, cement plant exhaust will have about 30%mole of CO2). In such implementations, when the fuel cell is supplied with exhaust gas from an industrial process having high %mol of CO2 (such as a cement plant or a coal plant) the fuel cell may achieve higher capture rates (such as greater than 90% carbon capture rate).

[0070] In optional implementations, as indicated by the dashed box, the method 200 may include at (208) conveying the exhaust gases from an outlet of the cathode side 116 through a heat recovery steam generator 32 (HRSG) prior to providing the exhaust gases to the carbon capture system 108. In such embodiments, the method may include at (210) generating steam with the HRSG 32 and at (212) providing the steam to a bottoming cycle 104. The bottoming cycle 104 may generate a second power output. For example, the bottoming cycle 104 may be a steam turbine system 22 that drives a second load 24 for producing electrical power. The second load 24 may also be an electrical generator for generating electrical power.

[0071] In some embodiments, the method 200 may include at (214) providing air from the atmosphere in addition to the exhaust gases to the carbon capture system 108 (e.g., when the topping cycle 102 is operated at a partial load for a normal sized adsorption bed, or when the topping cycle 102 is operated at full load for an oversized adsorption bed). For example, the air from the atmosphere may be introduced to the carbon capture system 108 via the air inlet line 160 when the gas turbine 10 is operating at partial load for systems having a carbon capture system 108 that is sized based on the carbon dioxide output of the topping cycle 102. Alternatively, the air from the atmosphere may be introduced to the carbon capture system 108 via the air inlet line 160 when the gas turbine 10 is operating at full load for systems having a carbon capture system 108 that is oversized (e.g., sized larger than the gas turbine carbon dioxide output requirement). As a result of providing air in addition to exhaust gas from the gas turbine, carbon dioxide is removed from the air and the exhaust gas such that the combustion system generates negative carbon capture emissions. The gas turbine 10 may be operational at full load (e.g., maximum capacity or 100%) and partial load (e.g., less than maximum capacity or less than 100%). During full load, the gas turbine 10 may generate a large amount of exhaust gases, which may utilize the full carbon dioxide capturing capacity of the fuel cell 106 and the carbon capture system 108. However, in partial load conditions, the gas turbine 10 may generate less exhaust gases, thereby giving the carbon capture system 108 additional capacity for capturing carbon dioxide. This additional capacity may be utilized for capturing carbon dioxide form the atmosphere, which advantageously allows for the fuel cell 106 and the carbon capture system 108 to capture greater than 100% of the carbon dioxide produced in the topping cycle 102 (e.g., gas turbine 10). For example, all of the carbon dioxide produced in the topping cycle 102 may be captured collectively by the fuel cell 106 and the carbon capture system 108, and additional carbon dioxide may be captured from the atmosphere by introducing air from the atmosphere to the carbon capture system 108 in addition to the exhaust gases.

[0072] This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to practice the invention, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they include structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal language of the claims.

[0073] Further aspects of the invention are provided by the subject matter of the following clauses: [0074] A combustion system comprising: a topping cycle generating a flow of exhaust gas; a bottoming cycle; a fuel cell including an anode side, a cathode side, and an electrolyte, the cathode side receiving the flow of exhaust gas from the topping cycle via a cathode inlet line, the cathode side removing a first portion of pollutants from the exhaust gas; a heat recovery steam generator (HRSG) that receives the exhaust gases from the cathode side via a cathode outlet line, the HRSG generating a flow of steam for use in the bottoming cycle; and a carbon capture system fluidly coupled to the HRSG via an HRSG outlet line, the carbon capture system removing a second portion of pollutants from the exhaust gas.

[0075] The combustion system as in any of the preceding clauses, wherein the carbon capture system comprises an adsorption bed.

[0076] The combustion system as in any of the preceding clauses, further comprising an air inlet line fluidly coupled to the atmosphere and to the carbon capture system.

[0077] The combustion system as in any of the preceding clauses, wherein the topping cycle is a gas turbine coupled to a first load, the gas turbine including a compressor section, a combustion section, and a turbine section, the turbine section generating the exhaust gases.

[0078] The combustion system as in any of the preceding clauses, further comprising an exhaust gas recirculation line fluidly coupling the turbine section to the compressor section.

[0079] The combustion system as in any of the preceding clauses, wherein fuel cell is a molten carbonate fuel cell (MCFC).

[0080] The combustion system as in any of the preceding clauses, further comprising a cathode recirculation line extending from the cathode outlet line to the cathode inlet line.

[0081] The carbon capture system as in any of the preceding clauses, further comprising an exhaust line fluidly extending between the carbon capture system and an exhaust stack.

[0082] The combustion system as in any of the preceding clauses, wherein the anode side receives a flow of fuel and/or steam via an anode inlet line. [0083] The combustion system as in any of the preceding clauses, further comprising an anode outlet line fluidly coupled to a separation system for removing water and liquid carbon dioxide from anode output products.

[0084] The combustion system as in any of the preceding clauses, wherein between about 85% and about 100% of the pollutants from the exhaust gases exiting the topping cycle are captured collectively by the fuel cell and the carbon capture system.

[0085] A method of removing pollutants in a combustion system, the method comprising: operating a topping cycle of the combustion system, whereby a first power output and exhaust gases are generated; conveying the exhaust gases through a cathode side of a fuel cell, whereby a first portion of the pollutants are removed from the exhaust gases; and providing the exhaust gases from an outlet of the cathode side to a carbon capture system, wherein a second portion of the pollutants are removed from the exhaust gases by the carbon capture system.

[0086] The method as in any of the preceding clauses, wherein the pollutants comprises carbon dioxide, wherein the first portion of the pollutants removed from the exhaust gases by the cathode side comprises a majority of the carbon dioxide in the exhaust gases, and wherein the second portion of the pollutants removed from the exhaust gases by the carbon capture system is a remainder of the carbon dioxide in the exhaust gases.

[0087] The method as in any of the preceding clauses, wherein the pollutants comprises carbon dioxide, and wherein between about 50% and about 90% of the carbon dioxide from the exhaust gases is removed in the cathode side of the fuel cell, and wherein a remainder of the carbon dioxide from the exhaust gases is removed in the carbon capture system.

[0088] The method as in any of the preceding clauses, wherein the combustion system generates a total power output, and wherein operating the fuel cell and the carbon capture system requires a power supply of between about 0.5% and about 5% of the total power output.

[0089] The method as in any of the preceding clauses, further comprising conveying the exhaust gases from an outlet of the cathode side through a heat recovery steam generator (HRSG) prior to providing the exhaust gases to the carbon capture system.

[0090] The method as in any of the preceding clauses, further comprising: generating steam with the HRSG; and providing the steam to a bottoming cycle of the combustion system, the bottoming cycle generating a second power output.

[0091] The method as in any of the preceding clauses, further comprising providing air from the atmosphere in addition to the exhaust gases to the carbon capture system, whereby carbon dioxide is removed from the air such that the combustion system generates negative carbon capture emissions.

[0092] The method as in any of the preceding clauses, further comprising conveying fuel and/or steam through an anode side of the fuel cell.

[0093] A combustion system comprising: a topping cycle generating a flow of exhaust gas; a bottoming cycle; a heat recovery steam generator (HRSG) that receives the exhaust gases from the topping cycle, the HRSG generating a flow of steam for use in the bottoming cycle; and a fuel cell including an anode side, a cathode side, and an electrolyte, the cathode side receiving the flow of exhaust gas from HRSG via a cathode inlet line, the cathode side removing a first portion of pollutants from the exhaust gas; a carbon capture system fluidly coupled to cathode side via a cathode outlet line, the carbon capture system removing a second portion of pollutants from the exhaust gas.

[0094] The combustion system as in any of the preceding clauses, wherein the carbon capture system comprises an adsorption bed.

[0095] The combustion system as in any of the preceding clauses, further comprising an air inlet line fluidly coupled to the atmosphere and to the carbon capture system.

[0096] The combustion system as in any of the preceding clauses, wherein the topping cycle is a gas turbine coupled to a first load, the gas turbine including a compressor section, a combustion section, and a turbine section, the turbine section generating the exhaust gases.

[0097] The combustion system as in any of the preceding clauses, wherein fuel cell is a molten carbonate fuel cell (MCFC). [0098] The combustion system as in any of the preceding clauses, further comprising a cathode recirculation line extending from the cathode outlet line to the cathode inlet line.

[0099] The carbon capture system as in any of the preceding clauses, further comprising an exhaust line fluidly extending between the carbon capture system and an exhaust stack.

[00100] The combustion system as in any of the preceding clauses, wherein the anode side receives a flow of fuel and/or steam via an anode inlet line.

[00101] The combustion system as in any of the preceding clauses, further comprising an anode outlet line fluidly coupled to a separation system for removing water and liquid carbon dioxide from anode output products.

[00102] The combustion system as in any of the preceding clauses, wherein between about 85% and about 100% of the pollutants from the exhaust gases exiting the topping cycle are captured collectively by the fuel cell and the carbon capture system.

[00103] A combustion system comprising: a gas turbine including a compressor section, a combustion section, and a turbine section, the turbine section generating exhaust gases; a fuel cell including an anode side, a cathode side, and an electrolyte, the cathode side receiving the exhaust gases from the turbine section via an exhaust gas outlet line, the cathode side removing a first portion of pollutants from the exhaust gas; a carbon capture system fluidly coupled to the fuel cell for removing a second portion of pollutants from the exhaust gas; and an exhaust gas recirculation line extending from the exhaust gas outlet line to the compressor section.

[00104] The combustion system as in any of the preceding clauses, wherein the carbon capture system comprises an adsorption bed.

[00105] The combustion system as in any of the preceding clauses, further comprising an air inlet line fluidly coupled to the atmosphere and to the carbon capture system.

[00106] The combustion system as in any of the preceding clauses, wherein fuel cell is a molten carbonate fuel cell (MCFC). [00107] The combustion system as in any of the preceding clauses, further comprising a cathode recirculation line extending from the cathode outlet line to the cathode inlet line.

[00108] The carbon capture system as in any of the preceding clauses, further comprising an exhaust line fluidly extending between the carbon capture system and an exhaust stack.

[00109] The combustion system as in any of the preceding clauses, wherein the anode side receives a flow of fuel and/or steam via an anode inlet line.

[00110] The combustion system as in any of the preceding clauses, further comprising an anode outlet line fluidly coupled to a separation system for removing water and liquid carbon dioxide from anode output products.

[00111] The combustion system as in any of the preceding clauses, wherein between about 85% and about 100% of the pollutants from the exhaust gases exiting the topping cycle are captured collectively by the fuel cell and the carbon capture system.

Claims

WHAT IS CLAIMED IS:

1. A combustion system comprising: a topping cycle generating a flow of exhaust gas; a bottoming cycle; a heat recovery steam generator (HRSG) that receives the exhaust gases from the topping cycle, the HRSG generating a flow of steam for use in the bottoming cycle; and a fuel cell including an anode side, a cathode side, and an electrolyte, the cathode side receiving the flow of exhaust gas from HRSG via a cathode inlet line, the cathode side removing a first portion of pollutants from the exhaust gas; a carbon capture system fluidly coupled to cathode side via a cathode outlet line, the carbon capture system removing a second portion of pollutants from the exhaust gas.

2. The combustion system as in claim 1, wherein the carbon capture system comprises an adsorption bed.

3. The combustion system as in claim 1, further comprising an air inlet line fluidly coupled to the atmosphere and to the carbon capture system.

4. The combustion system as in claim 1, wherein the topping cycle is a gas turbine coupled to a first load, the gas turbine including a compressor section, a combustion section, and a turbine section, the turbine section generating the exhaust gases.

5. The combustion system as in claim 1, wherein fuel cell is a molten carbonate fuel cell (MCFC).

6. The combustion system as in claim 1, further comprising a cathode recirculation line extending from the cathode outlet line to the cathode inlet line.

7. The carbon capture system as in claim 1, further comprising an exhaust line fluidly extending between the carbon capture system and an exhaust stack.

8. The combustion system as in claim 1, wherein the anode side receives a flow of fuel and/or steam via an anode inlet line.

9. The combustion system as in claim 1, further comprising an anode outlet line fluidly coupled to a separation system for removing water and liquid carbon dioxide from anode output products.

10. The combustion system as in claim 1, wherein between about 85% and about 100% of the pollutants from the exhaust gases exiting the topping cycle are captured collectively by the fuel cell and the carbon capture system.

11. A combustion system comprising: a gas turbine including a compressor section, a combustion section, and a turbine section, the turbine section generating exhaust gases; a fuel cell including an anode side, a cathode side, and an electrolyte, the cathode side receiving the exhaust gases from the turbine section via an exhaust gas outlet line, the cathode side removing a first portion of pollutants from the exhaust gas; a carbon capture system fluidly coupled to the fuel cell for removing a second portion of pollutants from the exhaust gas; and an exhaust gas recirculation line extending from the exhaust gas outlet line to the compressor section.

12. The combustion system as in claim 11, wherein the carbon capture system comprises an adsorption bed.

13. The combustion system as in claim 11, further comprising an air inlet line fluidly coupled to the atmosphere and to the carbon capture system.

14. The combustion system as in claim 11, wherein fuel cell is a molten carbonate fuel cell (MCFC).

15. The combustion system as in claim 11, further comprising a cathode recirculation line extending from the cathode outlet line to the cathode inlet line.

16. The carbon capture system as in claim 11, further comprising an exhaust line fluidly extending between the carbon capture system and an exhaust stack.

17. The combustion system as in claim 11, wherein the anode side receives a flow of fuel and/or steam via an anode inlet line.

18. The combustion system as in claim 11, further comprising an anode outlet line fluidly coupled to a separation system for removing water and liquid carbon dioxide from anode output products.

19. The combustion system as in claim 11, wherein between about 85% and about 100% of the pollutants from the exhaust gases exiting the topping cycle are captured collectively by the fuel cell and the carbon capture system.