EP4587682A1 - Pump stator tie layer - Google Patents
Pump stator tie layerInfo
- Publication number
- EP4587682A1 EP4587682A1 EP23877946.6A EP23877946A EP4587682A1 EP 4587682 A1 EP4587682 A1 EP 4587682A1 EP 23877946 A EP23877946 A EP 23877946A EP 4587682 A1 EP4587682 A1 EP 4587682A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stator
- elastomer
- layer
- fluid
- materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C2/00—Rotary-piston machines or pumps
- F04C2/08—Rotary-piston machines or pumps of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing
- F04C2/10—Rotary-piston machines or pumps of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing of internal-axis type with the outer member having more teeth or tooth-equivalents, e.g. rollers, than the inner member
- F04C2/107—Rotary-piston machines or pumps of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing of internal-axis type with the outer member having more teeth or tooth-equivalents, e.g. rollers, than the inner member with helical teeth
- F04C2/1071—Rotary-piston machines or pumps of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing of internal-axis type with the outer member having more teeth or tooth-equivalents, e.g. rollers, than the inner member with helical teeth the inner and outer member having a different number of threads and one of the two being made of elastic materials, e.g. Moineau type
- F04C2/1073—Rotary-piston machines or pumps of intermeshing-engagement type, i.e. with engagement of co-operating members similar to that of toothed gearing of internal-axis type with the outer member having more teeth or tooth-equivalents, e.g. rollers, than the inner member with helical teeth the inner and outer member having a different number of threads and one of the two being made of elastic materials, e.g. Moineau type where one member is stationary while the other member rotates and orbits
- F04C2/1075—Construction of the stationary member
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C13/00—Adaptations of machines or pumps for special use, e.g. for extremely high pressures
- F04C13/008—Pumps for submersible use, i.e. down-hole pumping
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B4/00—Drives for drilling, used in the borehole
- E21B4/02—Fluid rotary type drives
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/12—Methods or apparatus for controlling the flow of the obtained fluid to or in wells
- E21B43/121—Lifting well fluids
- E21B43/128—Adaptation of pump systems with down-hole electric drives
Definitions
- Electric submersible pumps are deployed downhole to provide artificial lift for lifting oil to a collection location.
- An ESP has a series of centrifugal pump stages contained within a protective housing and mated to a submersible electric motor.
- the ESP may be installed at the end of a production string and is powered and controlled via an armor protected cable.
- Electric submersible pumps may be used in a variety of moderate-to-high-production rate wells, however each ESP is designed for a specific well and for a relatively tight range of pumping rates.
- the ESP can begin to operate outside of the specified range. This results in substantial reductions in system efficiencies and can lead to major mechanical problems, excessive energy costs, and premature pumping system failure.
- a low flow solution such as a sucker rod pump or similar system which can accommodate the lower production volumes.
- such low flow systems have relatively limited applications and often cannot be deployed in unconventional deviated wells, e.g. horizontal wells.
- a fluid displacement pump can include a rotor; and a stator, where the stator includes two materials bonded by a tie layer.
- a method can include providing materials; bonding two of the materials using another one of the materials as a tie layer to form a stator material; forming a stator of a pump using the stator material.
- Figure 1 is a schematic illustration of an example of an electric submersible progressive cavity pumping system having a progressive cavity pump and being deployed downhole in a borehole, e.g. a wellbore, according to an embodiment of the disclosure;
- Figure 2 is a cross-sectional view of an example of a progressive cavity pump, according to an embodiment of the disclosure
- Figure 4 is an end view of an example of a composite stator, according to an embodiment of the disclosure.
- Figure 7 is an example of a plot
- Figure 8 is a photograph of an example of a failed stator
- FIG. 10 is a series of diagrams of examples of pump operations
- Figure 11 is a series of diagrams of examples of pump components;
- Figure 12 is a diagram of an example of pump components;
- Figure 13 is a diagram of an example of a chemical formula
- Figure 14 is a diagram of an example of a method and an example of a system.
- Figure 15 is a diagram of computing devices.
- the disclosure herein generally involves a system and methodology for facilitating efficient well production in relatively low volume applications, e.g. applications after well pressure and volume taper off for a given well.
- use of an electric submersible progressive cavity pump is enabled in harsh, high temperature downhole environments.
- an ESP system may initially be used to pump fluid, e.g. oil, from the well while the volume of flow is moderate to high.
- the ESP system is then removed and replaced by the electric submersible progressive cavity pump.
- Substitution of the electric submersible progressive cavity pump provides a seamless way for continuing efficient production.
- the electric submersible progressive cavity pump is constructed for long-term use even in the high temperature, harsh downhole environment.
- the composite stator can include an outer housing and a thermoset resin layer located within the outer housing and secured to the outer housing.
- the thermoset resin layer is constructed with an internal surface having an internal thread design, e.g. a helical thread design.
- an elastomeric layer is located within (e.g., radially within and/or on or adjacent an inner surface of) the thermoset resin layer and has a shape which follows the internal thread. In this manner, the elastomeric layer is able to provide an interior surface generally matching the shape of the internal thread of the thermoset resin layer.
- the arrangement of the layers and the materials selected for the layers provide a composite stator structure which has great longevity in harsh, high temperature downhole environments while providing an appropriate surface for creating pumping cavities along which fluid is pumped when an internal rotor is rotated relative to the composite pump stator.
- the inner elastomer layer may be initially formed as an extruded tube which is then inserted into an interior of the intermediate thermoset layer. The extruded tube conforms to the thread pattern and provides an enhanced surface interface with the rotor.
- the electric submersible progressive cavity pump system combines a progressive cavity pump with a motor and a gearbox which are all submersible and may be fully submersed downhole. This allows the electric submersible progressive cavity pump system to be constructed as a drop-in replacement for an ESP and to utilize the same surface equipment. As a result, continued production can be maintained on a cost effective basis. Additionally, use of a progressive cavity pump enables use of the overall electric submersible progressive cavity pump system in a wide variety of wells including unconventional deviated wells, e.g. horizontal wells.
- an example of an electric submersible progressive cavity pump system 20 is illustrated as deployed in a borehole 22, e.g. a wellbore.
- the wellbore 22 is drilled into a subterranean formation 24 and, in some applications, may be lined with casing 26. Perforations are formed through the casing 26 and out into the surrounding formation 24 to enable the inflow of oil 28 and/or other fluids which may then be pumped to a collection location via the electric submersible progressive cavity pump system 20.
- the electric submersible progressive cavity pump system 20 may comprise a submersible motor 30, e.g. an induction motor or a PMM (permanent magnet motor), a submersible gearbox 32 driven by the motor 30, and a progressive cavity pump 34 driven via the gearbox 32.
- the progressive cavity pump 34 may comprise a rotor 36 rotatably positioned within a surrounding composite stator 38.
- the motor 30 and gearbox 32 may be used to drive/rotate the rotor 36 within the composite stator 38 to pump fluid, e.g. oil 28.
- the oil 28 entering wellbore 22 may be drawn in through a pump intake 40 and pumped via progressive cavity pump 34 up through a tubing 42, e.g. a production tubing. From tubing 42, the pumped fluid may be directed through a wellhead 44 to an appropriate surface collection location.
- Electric power may be provided downhole to the submersible motor 30 via a power cable 46.
- the power cable 46 is routed along the tubing 42 and connected with a power source 48, e.g. a variable speed drive or switchboard, via a cable junction box 50.
- a power source 48 e.g. a variable speed drive or switchboard
- appropriate electrical power may be provided to the downhole motor 30 via various types of power supply systems.
- the power cable 46 is connected to the motor 30 by a sealed motor electrical connector 52.
- the electric submersible progressive cavity pump system 20 may comprise a variety of other components and/or may be coupled with a variety of other components and systems.
- various shaft seals, motor protectors, and other components may be connected with, or integrated into, the motor 30 and/or gearbox 32.
- a lower component 54 is coupled with motor 30 on a downhole side of the motor 30.
- the lower component 54 may be an oil compensator or a base gauge.
- many other types of components and systems may be connected with or used in combination with the electric submersible progressive cavity pump system 20.
- an embodiment of the composite stator 38 of progressive cavity pump 34 comprises an outer housing 56, e.g. a metal outer housing, and a first layer 58 located within (e.g., radially within) the outer housing 56.
- the first layer 58 may be formed from a thermoset resin and may be secured to the outer housing 56 along an interior surface of the outer housing 56.
- the first layer 58 is molded or otherwise constructed to have an interior surface 60 formed as an internal thread 62.
- the internal thread 62 may be formed as a helical thread (see also Figures 3 and 4).
- the illustrated composite stator 38 further comprises a second layer 64 located within (e.g., radially within and/or on or adjacent an inner surface of) first layer 58.
- the second layer 64 can be secured to the first layer 58 along the internal thread 62.
- the second layer 64 may be formed from an elastomer in a shape which follows the internal thread 62 such that a second layer interior surface 66 generally matches the shape of the first layer interior surface 60.
- the interior surface 66 of second layer 64 also presents an internal thread construction, e.g. a helical internal thread, which provides an operational interface with rotor 36.
- the various layers of composite stator 38 may be constructed from various types of materials, as described in greater detail below.
- the layer materials as well as the materials/mechanisms for securing the multiple layers together are selected to enable operation at high temperatures and in aggressive fluid environments for long durations.
- the composite stator 38 enables long-term operation of the electric submersible progressive cavity pump system 20 in downhole environments.
- the outer housing/layer 56 may be constructed from metal or other suitable material able to withstand downhole conditions.
- the outer housing 56 may be constructed from various carbon steels or stainless steels.
- the outer housing 56 also may be constructed from materials such as ni-resist, nickel alloys, or other suitable materials.
- this layer may be constructed from a thermoset resin which may be formulated in various thermoset composites.
- the first layer 58 may be a structural thermoset resin having a glass transition temperature greater than a desired final application temperature. Additionally, the structural thermoset resin should be capable of bonding completely with a bonding layer as discussed in greater detail below.
- thermoset resin may be combined into various additives.
- fillers may be incorporated into the thermoset resin to improve heat dissipation and to reduce the coefficient of thermal expansion (CTE).
- suitable fillers include mineral particles, metal powder, ceramic or organic particles, silica, alumina fillers, aluminum metal particles, or other suitable metal particles.
- adhesion promoting additives may be combined into the thermoset resin layer 58 to enhance bonding to adjacent layers.
- rubberized additives may be added to the thermoset resin layer 58 to increase toughness/fracture resistance. This could involve blending a certain amount of elastomer into the thermoset material.
- Various other additives may be combined to, for example, promote compatibility with the adjacent elastomer layer 64.
- second layer 64 By forming the second layer 64 as an extruded tube 72, much higher viscosities can be tolerated. As a result, elastomer materials having much higher strength may be selected so as to provide a substantially greater resistance to damage.
- suitable elastomer materials for construction of second layer 64/extruded tube 72 include nitrile rubber (NBR), hydrogenated nitrile rubber (HNBR), and FKM fluoroelastomer, e.g. VITONTM available from The Chemours Company or FluorelTM available from Dyneon LLC. For very high heat applications, e.g.
- the second layer 64/extruded tube 72 may be constructed from materials such as tetrafluoroethylene propylene (e.g. FEPM) or VITONTM ExtremeTM fluoroelastomer products available from The Chemours Company.
- materials such as tetrafluoroethylene propylene (e.g. FEPM) or VITONTM ExtremeTM fluoroelastomer products available from The Chemours Company.
- the bonding layer 76 may similarly use a variety of materials.
- the bonding layer 76 comprises an elastomer compound which may use the same base polymer as the elastomer of second layer 64 or other suitable variants.
- the bonding layer 76 may use a similar material but with 30% ACN.
- the bonding layer 76 also can be formulated with a different type of elastomer that is at least partially compatible, e.g. forming bonding layer 76 with ethylene propylene diene monomer (EPDM) while the primary elastomer of second layer 64 is formed with hydrogenated nitrile rubber (HNBR).
- EPDM ethylene propylene diene monomer
- HNBR hydrogenated nitrile rubber
- the bonding layer 76 is formulated with an elastomer material capable of coextrusion and co-crosslinking with the elastomer of elastomer layer 64. Accordingly, both the bonding layer 76 and the elastomer layer 64 may be capable of using the same type of cross-linking system, although the bulk of each elastomer may use different curing systems. To facilitate longevity downhole in certain applications, the formulation of bonding layer 76 may be optimized for bonding instead of, for example, dynamic loading and high tensile strength.
- a motor section may be manufactured in part of corrosion-resistant stainless steel where a thin layer of chrome plating may be present to reduce friction and abrasion.
- tungsten carbide may be utilized to coat a rotor, for example, to reduce abrasion wear and corrosion damage.
- a stator it can be formed of a steel tube, which may be a housing (see, e.g., the housing 642) with an elastomeric material that lines the bore of the steel tube to define a stator.
- An elastomeric material may be referred to as a liner or, when assembled with the tube or housing, may be referred to as a stator.
- an elastomeric material may be molded into the bore of a tube.
- An elastomeric material can be formulated to resist abrasion and hydrocarbon induced deterioration.
- Various types of elastomeric materials may be utilized in a power section and some may be proprietary. Properties of an elastomeric material can be tailored for particular types of operations, which may consider factors such as temperature, speed, rotor type, type of drilling fluid, etc.
- Rotors and stators can be characterized by helical profiles, for example, by spirals and/or lobes.
- a rotor can have one less fewer spiral or lobe than a stator (see, e.g., the cross-sectional views in Figure 6).
- Torque increases with the number of lobes, which corresponds to a slower speed. Torque also depends on the number of stages where a stage is a complete spiral of a stator helix. Power is defined as speed times torque; however, a greater number of lobes in a motor does not necessarily mean that the motor produces more power. Motors with more lobes tend to be less efficient because the seal area between the rotor and the stator increases with the number of lobes.
- nitrile rubber which tends to be rated to approximately 138 C (280 F)
- highly saturated nitrile which may be formulated to resist chemical attack and be rated to approximately 177 C (350 F).
- Drilling fluid temperature which may be referred to as mud temperature or mud fluid temperature
- interference greater interference can result in a stator experiencing higher shearing stresses, which can cause fatigue damage. Fatigue can lead to premature chunking failure of a stator liner.
- chlorides or other such halides may cause damage to a power section.
- such halides may damage a rotor through corrosion where a rough edged rotor can cut into a stator liner (e.g., cutting the top off an elastomeric liner).
- Such cuts can reduce effectiveness of a rotor/stator seal and may cause a motor to stall (e.g., chunking the stator) at a low differential pressure.
- a coated rotor can be beneficial for oil-based mud (OBM) with supersaturated water phases and for salt muds.
- differential pressure it is defined as the difference between the on- bottom and off-bottom drilling pressure, which is generated by the rotor/stator section (power section) of a motor.
- power section the rotor/stator section
- a motor that is run with differential pressures greater than recommended can be more prone to premature chunking. Such chunking may follow a spiral path or be uniform through the stator liner.
- a life of a power section can depend on factors that can lead to chunking (e.g., damage to a stator), which may depend on characteristics of a rotor (e.g., surface characteristics, etc.).
- Figure 8 shows an example of a photograph 800 that illustrates fatigue failure as to an elastomeric material of a stator of a motor. Arrows indicate where separation from a tube or housing has occurred and where chunking has occurred.
- Figure 9 shows examples of PCP components, including synthetic and/or natural materials, which can include polymeric materials, metals, composite materials, etc.
- an ESP is versatile and adaptable for use in various applications (e.g., artificial lift, injection, etc.).
- an ESP can include a series of centrifugal pump stages contained within a protective housing mated to a submersible electric motor. It is installed at the end of the production tubing; an armor- protected cable connects the pump to electric power and surface controls.
- a complementary option to the ESP is an electrical submersible progressive cavity pump (ESPCP).
- ESPCP electrical submersible progressive cavity pump
- An ESPCP may be a fully submersible pumping system. While various types of PCP may utilize a motor and gearbox to remain at the surface and the rotor to be driven from the surface by attaching to a long shaft, the ESPCP has a motor and gearbox attached to the pump fully submersed in the well and driven by an electrical power cord. As such, an ESPCP can be a drop-in replacement for the ESP and may utilize the same surface equipment. This reduces the work over cost as well as providing an effective alternative for unconventional deviated and horizontal wells.
- stator components may be sources of issues.
- a stator may be an injectable elastomer that the rotor moves against. Over time, the elastomer may degrade and/or swell from exposure to the downhole environment.
- stator deterioration is managed by swapping rotors at the surface.
- the stator must survive the harsh conditions for generally a longer time than PCP stators can manage in order to make a system a more viable alternative for the low flow unconventional applications.
- the reactive chemistries frequently utilized in solvent based adhesives include isocyanates, phenol/formaldehyde systems, cyanoacrylates, acrylated molecules, chlorinated polymers, and other reactive, typically polar materials that may generate strong adhesive bonds but are subject to hydrolytic degradation and thermal breakdown over time in the downhole environment.
- the adhesive material very quickly and obviously becomes the limiting factor.
- an compatabilizing elastomer based tie layer By utilizing an compatabilizing elastomer based tie layer, a more robust bonding of the elastomer and thermoset can be generated through covalent bonding of each material; chemically crosslinking the elastomer to a thermoset.
- geometry of a standard PCP stator can makes it inherently a source of elastomer inconsistencies.
- the shape profile can describe an eccentric displacement that results in uneven sections of elastomeric material.
- a thick uneven elastomer wall can exhibit several drawbacks that can result in it being a primary source for failure down hole.
- Figure 10 shows an example of a PCP 1000 with various types and ranges of motions that can impact various components, particularly when exposed to downhole conditions.
- elastomer where, because the wall is uneven, when exposed to downhole fluid and gas, the stator elastomer can swell unevenly, resulting in stator fit mismatch that can result in reduced pumping efficiency and damage to the elastomer.
- heat dissipation elastomeric materials tend to be inherently good thermal insulators. As a result, heat generated from the dynamic oscillation of the elastomer wall can buildup in the thick elastomer portions and eventually lead to thermal degradation of the elastomer.
- one or more compatabilizing layers may be utilized to allow for more complete and permanent bonding of these dissimilar materials (e.g., dynamic elastomer to structural thermoset).
- a compatabilizing layer can facilitate bonding of an elastomer to a rigid support structure which in the case of the composite PCP can be a thermoset material.
- a tie layer can be a compatabilizing tie layer that is designed with several potential advantages, which can include one or more of permanent bonding, improved aging and bond facilitation.
- Figure 12 shows an example of a PCP with a tie layer adjacent to a thermoset resin and a rubber lining where the PCP includes a metallic tube for a housing (e.g., exterior shell).
- a tie layer system may employ a common base chemistry and a common cure system as stator and thermoset regions to achieve desired bonding. Desirable properties for mechanical stability, chemical resistance, swell, embrittlement, softening, etc., can be imparted through use of a tie layer system where they may no longer be weak points in the bonding of the layers.
- a tie layer may be an additional layer that is a layer to facilitate bonding.
- a primary rubber lining of an elastomer stator may be formulated using one or more elastomer materials with inherently low reactivity and high degree of saturation in the polymer backbone.
- elastomers based on these systems tend to be inherently difficult to bond.
- a tie layer may be an elastomer with properties that may be selected or otherwise tailored to be similar to a stator elastomer and, for example, with greater unsaturation in a polymer backbone.
- a method can include co-vulcanizing with a primary elastomer liner.
- thermosetting chemistries for high temperature bonding applications, these may be based on cyanoacrylate, acrylate, polyester, epoxy, benzoxazine, polyimide, bismaleimide, and/or cyanate ester chemistry. While robust in many uphole applications, these thermosets may be limited in chemical compatibility and high-temperature capability. For example, with high-temperature exposure with small amounts of water, these polymers may be susceptible to hydrolytic attack, which results in a depolymerization reaction of the material and subsequent loss of adhesion. [0086] However, a range of resin chemistries for encapsulation are available. Such resin chemistries can offer low viscosity processing, high glass transition temperatures, excellent electrical/mechanical/thermal properties, and hydrolysis resistant chemistries. These materials can be formulated for the material to be used at temperatures up to 300 C (572 F).
- a polymer may be a thermosetting polymer.
- a polymer may be a non-thermosetting polymer.
- a polymeric material may include a mixture of one or more thermosetting polymers and one or more non-thermosetting polymers.
- a polymeric material may be or include an ethylene propylene diene monomer (M-class) rubber (EPDM), which is a type of synthetic rubber that is an elastomer.
- EPDM ethylene propylene diene monomer
- a polymeric material may be or include a nitrile butadiene rubber (NBR), which is a family of unsaturated copolymers of 2-propenenitrile and various butadiene monomers (1 ,2-butadiene and 1 ,3-butadiene).
- NBR nitrile butadiene rubber
- a polymeric material may be or include polyether ether ketone (PEEK), which is an organic thermoplastic polymer in the polyaryletherketone (PAEK) family.
- PEEK polyether ether ketone
- Epoxy resins also known as polyepoxides are a class of reactive prepolymers and polymers which contain epoxide groups.
- Polybutadiene is a synthetic rubber that is a polymer that can be formed from the polymerization process of the monomer 1 ,3-butadiene.
- Oxazines are heterocyclic compounds that include one oxygen atom and one nitrogen atom. Isomers exist depending on the relative position of the heteroatoms and relative position of the double bonds. Derivatives may also referred to as oxazines; examples include ifosfamide and morpholine (tetrahydro-1 , 4-oxazine).
- Silicones are polymers that include repeating units of siloxane. Silicones can be relatively heat-resistant and/or rubber-like, for example, consider examples such as silicone oil, silicone grease, silicone rubber, silicone resin, and silicone caulk.
- a polymer may be formed at least in part via ROMP.
- a prepolymer component amenable to forming a polymer via ROMP consider a carbon backbone with functional groups that include at least one oxygen that provides an amount of hydrophilicity may be present along with a hydrocarbon chain (e.g., carbon backbone) that provides an amount of hydrophobicity where at least one functional group may be present on the hydrophobic hydrocarbon chain where such a functional group may participate in ROMP (e.g., via relief of ring stress).
- the prepolymer component may be an ester such as a diester, a triester, etc. (e.g., an n-ester).
- a triester that includes at least one hydrocarbon chain with a functional group that includes a ring that is amenable to ROMP via relief of ring stress.
- DILULIN material (Cargill Inc., Minneapolis, MN) may be utilized, which is a mixture of norbornyl-functionalized linseed oil and cyclopentadiene (CPD) oligomers (e.g., one fraction consisting of modified linseed oil at about 70 percent by weight and another of cyclopentadiene (CPD) oligomers at about 30 percent by weight).
- CPD cyclopentadiene
- the norbornene groups are ROMP-reactive.
- DCPD dicyclopentadiene
- ENB ethylidenenorbornene
- a copolymer which may be a terpolymer, etc.
- DCPD is a white crystalline solid.
- Norbornene is a bridged cyclic hydrocarbon that can be provided as a white solid.
- Norbornene includes a cyclohexene ring with a methylene bridge between C-3 and C-6; it carries a double bond which induces ring strain.
- ENB is a bicyclic monomer and intermediate that includes two double bonds, each with a different reactivity. ENB can be produced from vinyl norbornene, which can be made from butadiene and dicyclopentadiene DCPD.
- cationic polymerization can be accomplished using one or more cationic catalysts, such as, for example, one or more of BF3 O(C2H5)2 (boron trifluoride ethyl etherate), B(C6Fs)3 (tris (pentafluorophenyl) borane), MAO (methylalumoxane), VCh (tetrachlorovanadium), and AIBrs (tribromoalumane).
- BF3 O(C2H5)2 boron trifluoride ethyl etherate
- B(C6Fs)3 tris (pentafluorophenyl) borane
- MAO methylalumoxane
- VCh tetrachlorovanadium
- AIBrs tribromoalumane
- the low reactivity of the DILULIN material due to the low number of bicyclic moiety compared to DCPD and ENB can decrease curing kinetics, which can, for example, provide time for one or more filling and/or impregnation process (e.g., before gelation, a transition from liquid to solid).
- the relatively low viscosity of DCPD and/or ENB may be controlled by adding different concentrations of the DILULIN material.
- a terpolymer or other copolymer formed via use of a functionalized n-ester and ROMP may exhibit toughness and adhesion (e.g., via presence of the n-ester structure).
- a copolymer material formed at least in part from a functionalized n-ester and ROMP can be utilized where high Tg, high toughness thermoset resins with a very low curing temperature are presently used.
- a copolymer material may replace one or more of phenolic and epoxy materials (e.g., while providing improved properties and processability).
- a pre-ceramic polymer can be a polymer that can be heated to elevated temperature or pyrolyzed to form a ceramic material.
- a ceramic material For example, consider polycarbosilanes, with a carbon-silicon backbone, that produce silicon carbide on pyrolysis and polysiloxanes, with a silicon-oxygen backbone, that produce silicon oxycarbides on pyrolysis.
- a polymer composite material can include a polymer matrix that is an organic or inorganic polymer matrix (e.g., one or more of epoxy, bismaleimide, polybutadiene, benzoxazine, cyanate ester, silicone, Ring-Opening Metathesis Polymers (ROMP), preceramic polymers) or a mixture thereof.
- an organic or inorganic polymer matrix e.g., one or more of epoxy, bismaleimide, polybutadiene, benzoxazine, cyanate ester, silicone, Ring-Opening Metathesis Polymers (ROMP), preceramic polymers
- a polymer composite material can be cured by application of heat and can be used as either a solvent free system or dispersed in solvent to aid in viscosity reduction.
- a polymer composite can be obtained through use of a polymer matrix filled with particulate filler.
- particulate filler can include one or more of aluminum oxide, aluminum nitride, boron nitride, silicon nitride, and beryllium oxide.
- Figure 14 shows an example of a method 1400 that includes providing materials 1410; bonding two of the materials using another one of the materials as a tie layer to form a stator material 1420; forming a stator for a pump using the stator material 1430; and operating the pump 1440.
- a fluid displacement pump can include a rotor; and a stator, where the stator includes two materials bonded by a tie layer.
- the two materials can include a thermoset and an elastomer.
- a fluid displacement pump can include a motor operatively coupled to a rotor.
- a fluid displacement pump can include a fluid inlet and a fluid outlet.
- a rotor may be driven by fluid flowing from the fluid inlet to the fluid outlet.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202263415379P | 2022-10-12 | 2022-10-12 | |
| PCT/US2023/034876 WO2024081278A1 (en) | 2022-10-12 | 2023-10-11 | Pump stator tie layer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP4587682A1 true EP4587682A1 (en) | 2025-07-23 |
| EP4587682A4 EP4587682A4 (en) | 2025-08-06 |
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ID=90670040
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23877946.6A Pending EP4587682A4 (en) | 2022-10-12 | 2023-10-11 | PUMP STATOR BINDING LAYER |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP4587682A4 (en) |
| WO (1) | WO2024081278A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12560061B2 (en) * | 2024-05-09 | 2026-02-24 | Schlumberger Technology Corporation | Pump having hollow rotor disposed in stator |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022040522A1 (en) | 2020-08-21 | 2022-02-24 | Schlumberger Technology Corporation | System and methodology comprising composite stator for low flow electric submersible progressive cavity pump |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7950914B2 (en) * | 2007-06-05 | 2011-05-31 | Smith International, Inc. | Braze or solder reinforced Moineau stator |
| WO2014138068A1 (en) * | 2013-03-05 | 2014-09-12 | Schlumberger Canada Limited | Method and apparatus to manufacture a progressive cavity motor or pump |
| US20150122549A1 (en) * | 2013-11-05 | 2015-05-07 | Baker Hughes Incorporated | Hydraulic tools, drilling systems including hydraulic tools, and methods of using hydraulic tools |
| US10920493B2 (en) * | 2017-02-21 | 2021-02-16 | Baker Hughes, A Ge Company, Llc | Method of forming stators for downhole motors |
-
2023
- 2023-10-11 EP EP23877946.6A patent/EP4587682A4/en active Pending
- 2023-10-11 WO PCT/US2023/034876 patent/WO2024081278A1/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022040522A1 (en) | 2020-08-21 | 2022-02-24 | Schlumberger Technology Corporation | System and methodology comprising composite stator for low flow electric submersible progressive cavity pump |
Also Published As
| Publication number | Publication date |
|---|---|
| EP4587682A4 (en) | 2025-08-06 |
| WO2024081278A1 (en) | 2024-04-18 |
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