EP4584480A1 - Self-sufficient system for evaporation of lng - Google Patents
Self-sufficient system for evaporation of lngInfo
- Publication number
- EP4584480A1 EP4584480A1 EP23787012.6A EP23787012A EP4584480A1 EP 4584480 A1 EP4584480 A1 EP 4584480A1 EP 23787012 A EP23787012 A EP 23787012A EP 4584480 A1 EP4584480 A1 EP 4584480A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- expander
- heat exchanger
- natural gas
- pressure
- lng
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/04—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled condensation heat from one cycle heating the fluid in another cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/18—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids characterised by adaptation for specific use
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
- F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
- F01K25/10—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/16—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being hot liquid or hot vapour, e.g. waste liquid, waste vapour
- F22B1/167—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being hot liquid or hot vapour, e.g. waste liquid, waste vapour using an organic fluid
Definitions
- LNG liquefied natural gas
- the LNG which is stored in suitable vessels, is sent to a LNG pump in order to increase the LNG pressure and, after LNG pressurization, it is sent to at least one heat exchanger to heat it up and perform LNG evaporation; typically, it is used sea water or ambient air (that is, in general, around 15 - 25 °C) to rise up the temperature of LNG and performing LNG evaporation.
- the natural gas is sent into the pipeline.
- LNG liquefied natural gas
- Fig. 1 shows a general schematic drawing of a first embodiment of an innovative self-sufficient system for evaporation of liquefied natural gas (LNG),
- LNG liquefied natural gas
- Fig. 2 shows a general schematic drawing of a second embodiment of an innovative self-sufficient system for evaporation of liquefied natural gas (LNG) with electrical power generation
- Fig. 3 shows a general schematic drawing of a third embodiment of an innovative self-sufficient system for evaporation of liquefied natural gas (LNG) with electrical power generation.
- the subject-matter disclosed herein relates to a self-sufficient LNG evaporation system for evaporating liquefied natural gas (which is previously stored in liquid phase, i.e. in conditions below the boiling point) in order to send evaporated natural gas to distribution pipelines.
- self-sufficient means that the embodiments of the system described herein do not require any electrical supply to, for example, pump LNG before evaporation.
- the system comprises an evaporation station which receives LNG from the storage, raises the pressure of the LNG with a pump and then increases the temperature of the LNG through a main heat exchanger in order to supply evaporated NG to an expander which can extract mechanical work from NG expansion and finally expanded NG is provided to distribution pipelines.
- the pump and the expander of the evaporation station are mechanically coupled with a shaft so that the mechanical work extracted by the expander can drive the pump, avoiding then the need for an external electrical supply to the evaporation station, in particular to the pump.
- the main heat exchanger provides the heat needed to evaporate the LNG; in particular, the main heat exchanger is configured to transfer heat from a mixed refrigerant to the LNG, thereby cooling the mixed refrigerant and heating the LNG.
- BOG boil-off gas
- FIG. 1 shows a schematic drawing of a first embodiment of an innovative self-sufficient system for evaporation of liquefied natural gas (LNG) 1000, referred in the following as “innovative self-sufficient system for LNG evaporation” or simply “LNG evaporating system”.
- LNG liquefied natural gas
- a second and a third embodiment 2000 and 3000 of an LNG evaporating system will be described in the following with the aid of Figs. 2 and 3. It is to be noted that elements in Figs. 2 and 3 which have the same reference number of the elements in first embodiment 1000 shown in Fig. 1 may be identical or similar to the elements in Fig. 1 and perform the same or similar functions.
- the main heat exchanger 300 is a critical component of the system and it has technical limitations in the maximum design conditions, such as maximum operating pressure and maximum temperature difference between hot and cold streams in the main heat exchanger 300.
- the maximum temperature difference between the LNG and the mixed refrigerant is about 50°C; in particular, a proper mixed refrigerant has to be used to ensure this requirement.
- the evaporating station 100 comprises further a first expander 20 mechanically coupled to the first pump 10 so that the first expander 20 drives the first pump 10.
- the first expander 20 and the first pump 10 have a common shaft which couples them and allows the transmission of the mechanical work to drive the first pump 10. It is to be noted that the evaporating station 100 does not need any electrical driver as the first expander 20 may provide sufficient power to drive the first pump 10.
- the first expander 20 is fluidly coupled to the main heat exchanger 300 and receives NG from the main heat exchanger 300 to perform NG expansion.
- the first pump 10 and the second pump 30 have a minimum efficiency equal to or greater than 60% and the first expander 20 and the second expander 40 have isentropic efficiency preferably at least 90%.
- the efficiency of the machines is lower, in particular the efficiency of the first pump 10
- the first pump 10 may have to raise the LNG pressure in the main heat exchanger 300 to a higher level, risking exceeding the maximum design pressure possible with BAHX; it is to be noted that the risk may be overcome by using DBHE instead of BAHX, which is however associated with increased cost and/or size limitations of the system.
- the same may be valid for the first expander 20 and its efficiency.
- the efficiency of the machines is lower, there may be the need of external heat sources and higher heating temperatures of the evaporating mixed refrigerant, for example even beyond the ambient temperature.
- the closed-loop refrigeration cycle implemented by the heat pumping station 200 includes at least a step of heating the mixed refrigerant, in particular performed by the secondary heat exchanger 35, advantageously totally evaporating the mixed refrigerant; a step of expanding the mixed refrigerant, in particular performed by the second expander 40, advantageously extracting mechanical work from the mixed refrigerant expansion; a step of cooling the mixed refrigerant, in particular performed by the main heat exchanger 300, advantageously condensing the mixed refrigerant; a step of pumping the mixed refrigerant, in particular performed by the second pump 30, advantageously rising up the mixed refrigerant pressure; and a step of heating the mixed refrigerant, in particular performed by the main heat exchanger 300.
- the secondary heat exchanger 35 is arranged upstream the second expander 40, in particular the secondary heat exchanger 35 is directly coupled to the second expander 40 inlet.
- the second expander 40 is directly coupled to the main heat exchanger 300, so that the mixed refrigerant exiting from the second expander 40 is directly supplied to the main heat exchanger 300.
- the step of cooling the mixed refrigerant in order to condensate it and heating the mixed refrigerant at a higher pressure level may both be performed by the main heat exchanger 300, in particular by two different sections of the main heat exchanger 300 (see sections 301 and 302 respectively in Fig. 1).
- part of the heat that is removed from the mixed refrigerant (so that mixed refrigerant is condensed) in section 301 of the main heat exchanger is partially transferred to the LNG in order to evaporate it (see section 303 in Fig. 1) and partially transferred to the mixed refrigerant itself at a higher pressure level (see section 302 in Fig. 1).
- the mixed refrigerant exiting from section 302 may be only partly evaporated, as the available heat in the main heat exchanger 300 may not allow for complete evaporation.
- complete evaporation of the mixed refrigerant may be reached, for example by staggered the cold side outlet streams so that they don’t have the same temperature and/or by further heating the mixed refrigerant exiting from section 302 of the main heat exchanger 300, before being expanded by the second expander 40.
- the mixed refrigerant can be fully evaporated performing heat transfer from ambient air (which can have a temperature in the range 15-45 °C) to the mixed refrigerant, for example by exposing to the ambient air the coils in which the mixed refrigerant can flow.
- the mixed refrigerant can be used to cool a gas turbine air inlet, therefore performing heat transfer from gas turbine air inlet to the mixed refrigerant, in particular in a first secondary heat exchanger 35.
- the mixed refrigerant can be fully evaporated and possibly superheated by exploiting an external heat source 31 (see for example Figs. 1-3): the first secondary heat exchanger 35 may transfer heat from the external heat source 31 to the mixed refrigerant in order to supply mixed refrigerant in the form of gas downstream the first secondary heat exchanger 35.
- the external heat source 31 may be ambient air or sea water or process waste heat.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT102022000020478A IT202200020478A1 (en) | 2022-10-05 | 2022-10-05 | Self-sufficient LNG evaporation system |
| PCT/EP2023/025419 WO2024074223A1 (en) | 2022-10-05 | 2023-10-04 | Self-sufficient system for evaporation of lng |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4584480A1 true EP4584480A1 (en) | 2025-07-16 |
Family
ID=84369592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP23787012.6A Pending EP4584480A1 (en) | 2022-10-05 | 2023-10-04 | Self-sufficient system for evaporation of lng |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20260103999A1 (en) |
| EP (1) | EP4584480A1 (en) |
| AU (1) | AU2023355462A1 (en) |
| IT (1) | IT202200020478A1 (en) |
| MX (1) | MX2025003569A (en) |
| WO (1) | WO2024074223A1 (en) |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55148907A (en) * | 1979-05-08 | 1980-11-19 | Setsuo Yamamoto | Compound cycle plant |
| US4444015A (en) * | 1981-01-27 | 1984-04-24 | Chiyoda Chemical Engineering & Construction Co., Ltd. | Method for recovering power according to a cascaded Rankine cycle by gasifying liquefied natural gas and utilizing the cold potential |
| DE3261605D1 (en) * | 1981-05-26 | 1985-01-31 | Daikin Ind Ltd | Working fluids for use with rankine cycle |
| JPS59180012A (en) * | 1983-03-30 | 1984-10-12 | Toshiba Corp | Combined cycle turbine power plant utilizing liquefied natural gas and low-boiling point medium |
| DE3836061A1 (en) * | 1987-12-21 | 1989-06-29 | Linde Ag | Method for evaporating liquid natural gas |
| TW414851B (en) * | 1998-03-27 | 2000-12-11 | Exxon Production Research Co | Producing power from liquefied natural gas |
| EP2301886A1 (en) * | 2009-09-03 | 2011-03-30 | Ammonia Casale S.A. | Waste heat recovery in a chemical process and plant, particularly for the synthesis of ammonia |
| WO2013103447A2 (en) * | 2012-01-03 | 2013-07-11 | Exxonmobil Upstream Research Company | Power generation using non-aqueous solvent |
| US9118226B2 (en) * | 2012-10-12 | 2015-08-25 | Echogen Power Systems, Llc | Heat engine system with a supercritical working fluid and processes thereof |
| WO2015057472A1 (en) * | 2013-10-14 | 2015-04-23 | J R Thermal LLC | Heat transfer engine |
| US20180120009A1 (en) * | 2015-05-06 | 2018-05-03 | Trienco Ltd. | System and method for dynamic mechanical power management |
| US12540559B2 (en) * | 2023-02-09 | 2026-02-03 | Flibe Energy, Inc. | sCO2 power conversion system |
| JP2025148907A (en) * | 2024-03-26 | 2025-10-08 | キヤノン株式会社 | Application program, storage medium, control method and information processing device |
-
2022
- 2022-10-05 IT IT102022000020478A patent/IT202200020478A1/en unknown
-
2023
- 2023-10-04 EP EP23787012.6A patent/EP4584480A1/en active Pending
- 2023-10-04 US US19/117,271 patent/US20260103999A1/en active Pending
- 2023-10-04 AU AU2023355462A patent/AU2023355462A1/en active Pending
- 2023-10-04 WO PCT/EP2023/025419 patent/WO2024074223A1/en not_active Ceased
-
2025
- 2025-03-26 MX MX2025003569A patent/MX2025003569A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2024074223A1 (en) | 2024-04-11 |
| AU2023355462A1 (en) | 2025-04-24 |
| MX2025003569A (en) | 2025-05-02 |
| IT202200020478A1 (en) | 2024-04-05 |
| US20260103999A1 (en) | 2026-04-16 |
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Legal Events
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