EP4544924A1 - Smoking product filter comprising lyocell tow, and smoking product comprising same - Google Patents

Smoking product filter comprising lyocell tow, and smoking product comprising same Download PDF

Info

Publication number
EP4544924A1
EP4544924A1 EP24750579.5A EP24750579A EP4544924A1 EP 4544924 A1 EP4544924 A1 EP 4544924A1 EP 24750579 A EP24750579 A EP 24750579A EP 4544924 A1 EP4544924 A1 EP 4544924A1
Authority
EP
European Patent Office
Prior art keywords
filter
smoking article
lyocell
tec
triethyl citrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP24750579.5A
Other languages
German (de)
French (fr)
Other versions
EP4544924A4 (en
Inventor
Kyeng Bae Ma
Ki Jin AHN
Sung Hoon Ha
Min Hee Hwang
Jin Chul Yang
Jun Hui Lee
Jong Cheol Jeong
Sang Woo Jin
Eun Young Park
Jeong Hun Lee
Seung Dong SEO
Yeong Nam Hwang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kolon Industries Inc
KT&G Corp
Original Assignee
Kolon Industries Inc
KT&G Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020240002364A external-priority patent/KR20240122324A/en
Application filed by Kolon Industries Inc, KT&G Corp filed Critical Kolon Industries Inc
Publication of EP4544924A1 publication Critical patent/EP4544924A1/en
Publication of EP4544924A4 publication Critical patent/EP4544924A4/en
Pending legal-status Critical Current

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/048Tobacco smoke filters characterised by their shape or structure containing additives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/04Cigars; Cigarettes with mouthpieces or filter-tips
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/067Use of materials for tobacco smoke filters characterised by functional properties
    • A24D3/068Biodegradable or disintegrable
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/08Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A24D3/10Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES OF CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter tips or filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces of cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/14Use of materials for tobacco smoke filters of organic materials as additive

Definitions

  • the present invention relates to a smoking article filter in which triethyl citrate (TEC) is added as a phenol reducing material to lyocell tow and a smoking article including the smoking article filter.
  • TEC triethyl citrate
  • Typical cigarette filters include cellulose acetate tow formed by extracting cellulose from wood pulp and acetylating the extracted cellulose. Also, cigarette filters are assembled into cigarette products, distributed to consumers, provided for smoking, and then finally discarded after smoking is completed. Also, some cigarette filters are directly discarded as manufacturing residue from a cigarette filter manufacturing plant. This cigarette filter waste is collected as refuse and landfilled for disposal. In addition, in some cases, smoked cigarettes are left in the natural environment without being collected as refuse.
  • a phenol reducing material that can specifically reduce phenols generated during smoking is added to reduce phenols in mainstream smoke.
  • PEG polyethylene glycol
  • TEC triethyl citrate
  • TA triacetin
  • the phenol reducing material also serves as a plasticizer for cellulose acetate fibers and causes the cellulose acetate fibers, which are hydrophobic, to bond to each other, thus reducing biodegradability.
  • a phenol reducing material such as PEG or TEC
  • the lyocell fibers which are hydrophilic, are not plasticized. Accordingly, the addition of a phenol reducing material such as PEG or TEC to lyocell fibers has been found to reduce phenols in mainstream smoke while not degrading biodegradability.
  • One object of the present invention is to provide a smoking article filter in which triethyl citrate (TEC), whose content is designed to be optimal, is added to lyocell tow to constitute the smoking article filter, thereby more effectively removing components such as phenols present in cigarette smoke during smoking and having excellent biodegradability.
  • TEC triethyl citrate
  • Another object of the present invention is to provide a smoking article including a smoking article filter in which triethyl citrate (TEC), whose content is designed to be optimal, is added to lyocell tow to constitute the smoking article filter, thereby more effectively removing components such as phenols present in cigarette smoke during smoking and having excellent biodegradability.
  • TEC triethyl citrate
  • One embodiment for achieving the one object provides a smoking article filter including: lyocell tow including lyocell fibers; and a phenol reducing material dispersed in the lyocell tow, wherein the phenol reducing material includes triethyl citrate (TEC), and the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.
  • a smoking article filter including: lyocell tow including lyocell fibers; and a phenol reducing material dispersed in the lyocell tow, wherein the phenol reducing material includes triethyl citrate (TEC), and the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.
  • TEC triethyl citrate
  • the content of the triethyl citrate (TEC) may range from 0.18 mg to 1.2 mg per length (mm) of the lyocell tow.
  • the content of the triethyl citrate (TEC) may range from 0.5 mg to 0.95 mg per length (mm) of the lyocell tow.
  • the content of the triethyl citrate (TEC) may range from 0.6 mg to 0.85 mg per length (mm) of the lyocell tow.
  • the smoking article filter may have a hardness ranging from of 70% to 95%.
  • the lyocell fibers may have a shaped cross-section.
  • One embodiment for achieving the another object provides a smoking article including: a smoking material portion; a filter portion disposed downstream of the smoking material portion; and a wrapper configured to wrap around the smoking material portion or the filter portion, wherein the filter portion includes lyocell tow including lyocell fibers and a phenol reducing material dispersed in the lyocell tow, the phenol reducing material includes triethyl citrate (TEC), and the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.
  • TEC triethyl citrate
  • the content of the triethyl citrate (TEC) may range from 0.6 mg to 0.85 mg per length (mm) of the lyocell tow.
  • the lyocell fibers may have a shaped cross-section.
  • the filter portion may further include a capsule configured to generate a flavor.
  • a smoking article filter and a smoking article including the same it is possible to provide a lyocell filter to which lyocell tow, to which triethyl citrate (TEC) is added as a phenol reducing material, is applied, and in this way, components such as phenols present in cigarette smoke can be more effectively removed during smoking.
  • TEC triethyl citrate
  • TEC triethyl citrate
  • TEC triethyl citrate
  • FIG. 1 is a view illustrating a schematic configuration of a smoking article according to one embodiment of the present invention.
  • first, second, A, B, (a), and (b) may be used. Such terms are only used for distinguishing one component from another component, and the essence, order, sequence, or the like of the corresponding component is not limited by the terms.
  • a certain component is described as being “connected,” “coupled,” or “linked” to another component, it should be understood that, although the component may be directly connected or linked to the other component, still another component may also be “connected,” “coupled,” or “linked” between the two components.
  • smoking article may refer to any product that can be smoked or any product that can provide a smoking experience, regardless of whether the product is based on tobacco, tobacco derivatives, expanded tobacco, reconstituted tobacco, or tobacco substitutes.
  • smoking articles may include products that can be smoked, such as cigarettes, cigars, and cigarillos.
  • smoking material may refer to any type of material that may be used in a smoking article.
  • upstream or “upstream direction” may refer to a direction moving away from an oral region of a smoker
  • downstream or “downstream direction” may refer to a direction approaching the oral region of the smoker.
  • longitudinal direction may refer to a direction corresponding to a longitudinal axis of a smoking article.
  • FIG. 1 is a view illustrating a schematic configuration of a smoking article according to one embodiment of the present invention.
  • smoking article may refer to anything capable of generating an aerosol, such as tobacco (cigarettes) and cigars.
  • the smoking article may include an aerosol-generating material or an aerosol-forming substrate.
  • the smoking article may include a solid material based on tobacco raw materials, such as reconstituted tobacco leaves, shredded tobacco, and reconstituted tobacco.
  • a smoking material may include volatile compounds.
  • upstream or upstream direction refers to a direction moving away from an oral region of a user smoking a smoking article 100
  • downstream or “downstream direction” refers to a direction approaching the oral region of the user smoking the smoking article 100.
  • a smoking material portion 10 is disposed upstream or in an upstream direction of a smoking article filter portion 20 (a smoking article filter 20 or a filter portion 20).
  • the smoking article 100 is a combustion-type cigarette is described as an example.
  • the present invention is not limited thereto, and the smoking article 100 may also be a heating-type cigarette or the like that is used together with an aerosol generation device (not illustrated) such as an electronic cigarette device.
  • the present invention relates to the smoking article filter 20 (or the smoking article filter portion 20 or the filter portion 20) included in the smoking article 100, and the smoking article filter 20 according to one embodiment of the present invention includes lyocell tow including lyocell fibers and a phenol reducing material added to the lyocell tow, wherein the phenol reducing material includes triethyl citrate (TEC).
  • TEC triethyl citrate
  • the "phenol” may refer to a group of chemical compounds composed of hydroxyl groups (-OH) directly bound to aromatic hydrocarbon functional groups, and a phenolic group includes phenol, catechol, m+P cresol, and o-cresol.
  • the "phenol reducing material” may correspond to a material that can specifically reduce a phenolic material in smoke generated during smoking, for example, at least one of phenol, catechol, m+P cresol, and o-cresol.
  • the lyocell fibers are eco-friendly fibers made of cellulose extracted from wood pulp.
  • the lyocell tow refers to a bundle formed by cross-connecting adjacent lyocell fibers.
  • the lyocell fibers may have a shaped cross-section.
  • the shaped cross-section is defined as a cross-section having a shape including a plurality of protrusions instead of having a circular shape.
  • a cross-section having a shape in which a plurality of protrusions extend from the center may be referred to as "shaped cross-section.”
  • the lyocell fibers may have a Y-shaped cross-section with three protrusions branching from the center, a cross-shaped cross-section with four protrusions, a star-shaped cross-section with five protrusions, or an O-shaped cross-section, but the present invention is not limited thereto.
  • the phenol reducing material may be uniformly dispersed in lyocell tow and may be distributed throughout the entire region of the lyocell tow constituting the smoking article filter.
  • the phenol reducing material including triethyl citrate (TEC) may be applied on the surfaces of the lyocell fibers constituting the lyocell tow.
  • the phenol reducing material including triethyl citrate (TEC) may be dispersed in lyocell tow in any manner.
  • the phenol reducing material including triethyl citrate (TEC) may be applied on lyocell tow and dispersed in the lyocell tow in a spray type manner, for example, a transfer jet nozzle system (TINS) manner.
  • a spray type manner for example, a transfer jet nozzle system (TINS) manner.
  • TIS transfer jet nozzle system
  • the present invention is not limited thereto, and the phenol reducing material including triethyl citrate (TEC) may also be dispersed in lyocell tow using a brush type manner. Accordingly, a smoking article filter including lyocell tow in which the phenol reducing material including triethyl citrate (TEC) is dispersed may be manufactured without adding or modifying manufacturing equipment.
  • triethyl citrate may not act as a plasticizer between the lyocell fibers. Accordingly, even when triethyl citrate (TEC) is added as a phenol reducing material to lyocell tow, a plurality of lyocell fibers included in the smoking article filter may not be substantially connected to each other, and the biodegradability of the smoking article filter may not be reduced. That is, an additive for binding the lyocell fibers together may not be included in the smoking article filter according to the present invention.
  • TEC triethyl citrate
  • the smoking article filter to which lyocell tow is applied according to the present invention includes a phenol reducing material including triethyl citrate (TEC) that is dispersed in the lyocell tow and thus may have a greater effect of reducing phenols generated during smoking, compared to a smoking article filter to which triethyl citrate (TEC) is not added.
  • TEC triethyl citrate
  • the content of triethyl citrate (TEC) dispersed in the lyocell tow may range from 3 mg/rod to 50 mg/rod, 4 mg/rod to 40 mg/rod, 5 mg/rod to 30 mg/rod, 8 mg/rod to 29 mg/rod, 10 mg/rod to 28 mg/rod, 12 mg/rod to 27 mg/rod, or 15 mg/rod to 25 mg/rod, preferably, 18 mg/rod to 22 mg/rod.
  • the above ranges of the content of triethyl citrate (TEC) may be suitable for a lyocell filter having a diameter of 7.71 mm, a circumference of 24.20 mm, and a length of 27 mm.
  • TEC triethyl citrate
  • phenol reducing performance may be excellent while physical properties of the smoking article filter are maintained.
  • the content of triethyl citrate (TEC) dispersed in the lyocell tow may range from 0.11 mg to 1.85 mg, 0.18 mg to 1.2 mg, or 0.5 mg to 0.95 mg, preferably, 0.6 mg to 0.85 mg, per length (mm) of the lyocell tow.
  • TEC triethyl citrate
  • phenol reducing performance may be excellent while physical properties of the smoking article filter are maintained.
  • triethyl citrate (TEC) dispersed in the lyocell tow may be added at 0.1 wt% to 15 wt% of the weight of the lyocell tow.
  • the mono denier of the lyocell fibers constituting the lyocell tow may satisfy a range of 2 to 6, 2.3 to 5, 2.5 to 4.5, 2.7 to 4, 3 to 3.5, or 3.1 to 3.4.
  • the total denier of the lyocell fibers constituting the lyocell tow may satisfy a range of 15,000 to 50,000, 25,000 to 48,000, 30,000 to 45,000, or 35,000 to 40,000.
  • the smoking article filter including the lyocell tow in which the phenol reducing material including triethyl citrate (TEC) is dispersed may have a resistance to draw ranging from 50 mmWG/27 mm to 150 mmWG/27 mm, 60 mmWG/27 mm to 140 mmWG/27 mm, 70 mmWG/27 mm to 130 mmWG/27 mm, or 80 mmWG/27 mm to 120 mmWG/27 mm or a resistance to draw of 100 mmWG/27 mm.
  • the present invention is not limited thereto, but lyocell tow included in the smoking article filter having a resistance to draw in the above numerical range may have a weight of 700 mg/108 mm.
  • the smoking article filter including the lyocell tow in which the phenol reducing material including triethyl citrate (TEC) is dispersed may have a hardness ranging from 60% to 98%, 65% to 97%, or 70% to 95%.
  • the hardness of the smoking article filter is a numerical value of the degree to which a diameter of the smoking article filter is maintained when the smoking article filter is pressed with a force of a certain level in a direction perpendicular to the longitudinal direction of the smoking article filter and may be a percentage value of a ratio of a diameter of the smoking article filter after the force is applied to a diameter of the smoking article filter before the force is applied.
  • the smoking article filter including lyocell tow and triethyl citrate (TEC) dispersed in a predetermined content range in the lyocell tow can reduce a delivered amount of a phenolic material in smoke passing through the filter, compared to a smoking article filter including lyocell tow in which triethyl citrate (TEC) is not dispersed.
  • TEC triethyl citrate
  • the delivered amount of the phenolic material in smoke passing through the smoking article filter may be reduced 20% to 55%, 25% to 52%, or 45% to 50% compared to the delivered amount of the phenolic material in smoke passing through the smoking article filter to which the lyocell tow in which triethyl citrate (TEC) is not dispersed is applied.
  • TEC triethyl citrate
  • the smoking article filter may further include a capsule configured to generate a flavor.
  • the smoking article filter may further include a crushable capsule disposed in the lyocell tow and having a structure in which a liquid including a flavoring is wrapped with a film.
  • One or more crushable capsules may be included in the lyocell tow in which triethyl citrate (TEC) is dispersed.
  • TEC triethyl citrate
  • the smoking article filter may further include a wrapper (or a filter portion wrapper) configured to wrap around the lyocell tow in which triethyl citrate (TEC) is dispersed.
  • the filter portion wrapper may have a basis weight of 90 mg -2 or less, but the present invention is not limited thereto.
  • TEC triethyl citrate
  • a smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) added onto the lyocell tow was added at 10 mg/rod instead of 5 mg/rod.
  • TEC triethyl citrate
  • a smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) added onto the lyocell tow was added at 20 mg/rod instead of 5 mg/rod.
  • TEC triethyl citrate
  • a smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) added onto the lyocell tow was added at 30 mg/rod instead of 5 mg/rod.
  • TEC triethyl citrate
  • a smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) was not added as a phenol reducing material onto the lyocell tow.
  • TEC triethyl citrate
  • Smoking articles were manufactured using the smoking article filters of Comparative Example 1 and Examples 1 to 4, smoke components emitted during smoking using the cigarette smoking machine HAUNI LX20 manual (linear type) as a smoking device under HC conditions (puff volume: 55 ml / puff frequency: 30 s / puff duration: 2 s / vent blocking) as smoking conditions were collected using a Cambridge filter pad (CFP), and in order to extract substances from the smoke components collected on the CFP, 30 mL of 1% acetic acid was added and then stirred, the substances were filtered using a 0.45 ⁇ m PVDF syringe filter, phenols in the smoke passing through each smoking article filter were measured and analyzed using an Alliance HPLC-FLD analysis device of Waters Corporation, and results thereof are shown in Table 1 below.
  • CFP Cambridge filter pad
  • a phenol reducing effect varies according to the content of triethyl citrate (TEC) dispersed in the lyocell tow.
  • TEC triethyl citrate
  • the amount of delivered phenol decreased 45% to 50% and significantly decreased compared to Comparative Example 1 and Examples 1 and 2.
  • FIG. 1 is a view illustrating a schematic configuration of a smoking article according to one embodiment of the present invention.
  • the smoking article 100 includes the smoking material portion 10 and the filter portion 20, and the above-described smoking article filter may be applied to the filter portion 20 of the smoking article 100.
  • the smoking material portion 10 is located upstream of the filter portion 20.
  • the smoking material portion 10 may be filled with a smoking material such as raw tobacco leaves, reconstituted tobacco leaves, or a mixture of tobacco leaves and reconstituted tobacco leaves.
  • a processed smoking material may be filled in the smoking material portion 10 in the form of a sheet or shredded tobacco.
  • the smoking material portion 10 may have the form of a longitudinally extending rod whose length, circumference, and diameter are not particularly limited, but the length, circumference, and diameter may be adjusted to sizes generally used in the art in consideration of the amount of smoking material filled therein, user preferences, or the like.
  • the smoking material portion 10 may include at least one aerosol-generating material among glycerin, propylene glycol, ethylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and oleyl alcohol.
  • the smoking material portion 10 may contain other additives such as a flavoring agent, a wetting agent, and/or an acetate compound.
  • the aerosol-generating material and the additive may be contained in the smoking material.
  • the filter portion 20 is disposed downstream of the smoking material portion 10 and serves as a filter through which an aerosol material generated in the smoking material portion 10 passes right before being inhaled by the user.
  • the filter portion 20 may be manufactured using various materials or manufactured in various forms.
  • the filter portion 20 basically includes the above-described smoking article filter including lyocell tow including a plurality of lyocell fibers and triethyl citrate (TEC) dispersed in the lyocell tow.
  • the smoking article filter including the lyocell tow and triethyl citrate (TEC) may replace all or part of the filter portion 20 of existing smoking articles, and when the smoking article filter replaces part of the filter portion 20, a filter material that is used conventionally may be used together.
  • a cellulose acetate filter, a paper filter, a hollow tube filter, or the like may be used as the conventional filter material.
  • the filter portion 20 is illustrated as a mono filter formed of a single filter in FIG. 1 , but the present invention is not limited thereto.
  • the filter portion 20 may be provided as a dual filter, a triple filter, or the like, which includes two or more filters, in order to increase filter efficiency.
  • the filter (hereinafter, "lyocell filter”) of the present invention that includes lyocell tow including lyocell fibers and triethyl citrate (TEC) dispersed in the lyocell tow may be applied as any one filter of the plurality of filters, and a cellulose acetate filter and/or a paper filter may be applied as the other or another filter of the plurality of filters.
  • a length of the lyocell filter of the present invention may be 25% to 50% of the overall length of the filter portion 20.
  • the smoking article 100 may further include a hollow tube structure which is a tubular structure including a hollow therein.
  • the hollow tube structure may be disposed downstream of the filter portion 20 including the lyocell filter.
  • perforations may be formed in the hollow tube structure, but the present invention is not limited thereto. Perforations may not be formed in the hollow tube structure. In some embodiments, when perforations are formed in the hollow tube structure, the perforations may be formed at a position located 10 mm to 15 mm from the downstream end of the smoking article 100 in the upstream direction.
  • the exterior of the smoking material portion 10 and the filter portion 20 may be wrapped with a wrapper 30a or 30b.
  • the smoking material portion 10 may be wrapped with a smoking material portion wrapper 30a.
  • Some of the cigarette smoke generated in a typical combustion process of the smoking material portion 10 is released into the atmosphere through the smoking material portion wrapper 30a before passing through the filter portion 20, and sidestream smoke gives an unpleasant feeling to people exposed thereto.
  • sidestream smoke such as filling conventional cigarette paper with a filler such as magnesium oxide, titanium oxide, cerium oxide, aluminum oxide, calcium carbonate, and zirconium carbonate.
  • a filler such as magnesium oxide, titanium oxide, cerium oxide, aluminum oxide, calcium carbonate, and zirconium carbonate.
  • tobacco smoke taste degradation, combustion interruption, ash integrity degradation, or the like may occur, and it is difficult to address the above-mentioned problem through suitable combinations of materials contained in the filler.
  • a filler in which magnesium oxide (MgO and/or Mg(OH) 2 ) and calcium carbonate (CaCO 3 ) are mixed may be applied to the smoking material portion wrapper 30a in order to prevent tobacco smoke taste degradation, ash integrity degradation, and combustion interruption while reducing sidestream smoke.
  • the filter portion 20 may be wrapped with a filter portion wrapper 30b.
  • the filter portion wrapper 30b may be manufactured using grease-resistant wrapping paper, and an aluminum foil may be further included at an inner surface of the filter portion wrapper 30b.
  • the filter portion wrapper 30b may have a basis weight of 90 mg -2 or less, but the present invention is not limited thereto.
  • the smoking material portion 10 wrapped with the smoking material portion wrapper 30a and the filter portion 20 wrapped with the filter portion wrapper 30b may be wrapped together with tipping paper 40.
  • the tipping paper 40 may be wrapped around at least a portion (for example, a partial downstream region) of the smoking material portion wrapper 30a and an outer periphery of the filter portion wrapper 30b.
  • the tipping paper 40 may be made of nonporous wrapping paper that has not been treated to be grease-resistant, but the present invention is not limited thereto.
  • the tipping paper 40 may include an incombustible material to prevent a phenomenon in which the filter portion 20 burns, but the present invention is not limited thereto.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

Provided are a smoking article filter and a smoking article. The smoking article filter includes lyocell tow including lyocell fibers and a phenol reducing material dispersed in the lyocell tow, wherein the phenol reducing material includes triethyl citrate (TEC), and the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.

Description

    [Technical Field]
  • The present invention relates to a smoking article filter in which triethyl citrate (TEC) is added as a phenol reducing material to lyocell tow and a smoking article including the smoking article filter.
  • [Background Art]
  • Typical cigarette filters include cellulose acetate tow formed by extracting cellulose from wood pulp and acetylating the extracted cellulose. Also, cigarette filters are assembled into cigarette products, distributed to consumers, provided for smoking, and then finally discarded after smoking is completed. Also, some cigarette filters are directly discarded as manufacturing residue from a cigarette filter manufacturing plant. This cigarette filter waste is collected as refuse and landfilled for disposal. In addition, in some cases, smoked cigarettes are left in the natural environment without being collected as refuse.
  • Accordingly, in recent years, research for replacing cellulose acetate tow with an eco-friendly material to protect the natural environment and reduce costs has been carried out. For example, the development of tow (that is, lyocell tow) using lyocell fibers in which the cellulose itself is fiberized unlike cellulose acetate is in progress.
  • In manufacturing a smoking article filter, a phenol reducing material that can specifically reduce phenols generated during smoking is added to reduce phenols in mainstream smoke. Conventionally, it is known that polyethylene glycol (PEG), triethyl citrate (TEC), triacetin (TA), and the like are added as a phenol reducing material to cellulose acetate tow. In a case where a phenol reducing material composed of PEG and TEC is added to cellulose acetate which is hydrophobic, there is a problem in that the phenol reducing material also serves as a plasticizer for cellulose acetate fibers and causes the cellulose acetate fibers, which are hydrophobic, to bond to each other, thus reducing biodegradability.
  • Meanwhile, in a case where a phenol reducing material such as PEG or TEC is added to lyocell fibers, the lyocell fibers, which are hydrophilic, are not plasticized. Accordingly, the addition of a phenol reducing material such as PEG or TEC to lyocell fibers has been found to reduce phenols in mainstream smoke while not degrading biodegradability.
  • Meanwhile, in the case where a phenol reducing material is added to lyocell fibers to reduce phenols in mainstream smoke, there is a need for optimal design of a phenol reducing material that maintains the physical properties of a smoking article filter and has the best phenol reducing performance.
  • [Disclosure] [Technical Problem]
  • One object of the present invention is to provide a smoking article filter in which triethyl citrate (TEC), whose content is designed to be optimal, is added to lyocell tow to constitute the smoking article filter, thereby more effectively removing components such as phenols present in cigarette smoke during smoking and having excellent biodegradability.
  • Another object of the present invention is to provide a smoking article including a smoking article filter in which triethyl citrate (TEC), whose content is designed to be optimal, is added to lyocell tow to constitute the smoking article filter, thereby more effectively removing components such as phenols present in cigarette smoke during smoking and having excellent biodegradability.
  • [Technical Solution]
  • One embodiment for achieving the one object provides a smoking article filter including: lyocell tow including lyocell fibers; and a phenol reducing material dispersed in the lyocell tow, wherein the phenol reducing material includes triethyl citrate (TEC), and the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.
  • In some embodiments, the content of the triethyl citrate (TEC) may range from 0.18 mg to 1.2 mg per length (mm) of the lyocell tow.
  • In some embodiments, the content of the triethyl citrate (TEC) may range from 0.5 mg to 0.95 mg per length (mm) of the lyocell tow.
  • In some embodiments, the content of the triethyl citrate (TEC) may range from 0.6 mg to 0.85 mg per length (mm) of the lyocell tow.
  • In some embodiments, the smoking article filter may have a hardness ranging from of 70% to 95%.
  • In some embodiments, the lyocell fibers may have a shaped cross-section.
  • One embodiment for achieving the another object provides a smoking article including: a smoking material portion; a filter portion disposed downstream of the smoking material portion; and a wrapper configured to wrap around the smoking material portion or the filter portion, wherein the filter portion includes lyocell tow including lyocell fibers and a phenol reducing material dispersed in the lyocell tow, the phenol reducing material includes triethyl citrate (TEC), and the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.
  • In some embodiments, the content of the triethyl citrate (TEC) may range from 0.6 mg to 0.85 mg per length (mm) of the lyocell tow.
  • In some embodiments, the lyocell fibers may have a shaped cross-section.
  • In some embodiments, the filter portion may further include a capsule configured to generate a flavor.
  • [Advantageous Effects]
  • According to a smoking article filter and a smoking article including the same according to one embodiment, it is possible to provide a lyocell filter to which lyocell tow, to which triethyl citrate (TEC) is added as a phenol reducing material, is applied, and in this way, components such as phenols present in cigarette smoke can be more effectively removed during smoking.
  • Also, since triethyl citrate (TEC) does not act as a plasticizer for lyocell tow, which is hydrophilic, despite being added to the lyocell tow, it is possible to provide a smoking article filter having excellent biodegradability while having phenol reducing performance and a smoking article including the smoking article filter.
  • In addition, by designing the optimal content of triethyl citrate (TEC) added to lyocell tow, components such as phenols present in cigarette smoke can be more effectively removed during smoking.
  • The advantageous effects according to the technical spirit of the present disclosure are not limited to those mentioned above, and other unmentioned advantageous effects can be clearly understood by those of ordinary skill in the art from the description below.
  • [Description of Drawings]
  • FIG. 1 is a view illustrating a schematic configuration of a smoking article according to one embodiment of the present invention.
  • [Modes of the Invention]
  • Hereinafter, exemplary embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. Advantages and features of the present disclosure and methods of achieving the same should become clear with embodiments described in detail below with reference to the accompanying drawings. However, the technical spirit of the present disclosure is not limited to the following embodiments and may be implemented in various different forms. The following embodiments are only provided to make the technical spirit of the present disclosure complete and completely inform those of ordinary skill in the art to which the present disclosure pertains of the scope of the present disclosure. The technical spirit of the present disclosure is defined only by the scope of the claims.
  • In assigning reference numerals to components of each drawing, it should be noted that the same reference numerals are assigned to the same components wherever possible even when the components are illustrated in different drawings. Also, in describing the present disclosure, when it is determined that the detailed description of a known related configuration or function may obscure the gist of the present disclosure, the detailed description thereof will be omitted.
  • Unless otherwise defined, all terms including technical or scientific terms used herein have the same meaning as commonly understood by those of ordinary skill in the art to which the present disclosure pertains. Terms defined in commonly used dictionaries should not be interpreted in an idealized or overly formal sense unless expressly so defined herein. Terms used herein are for describing the embodiments and are not intended to limit the present disclosure. In the specification, a singular expression includes a plural expression unless the context clearly indicates otherwise.
  • Also, in describing components of the present disclosure, terms such as first, second, A, B, (a), and (b) may be used. Such terms are only used for distinguishing one component from another component, and the essence, order, sequence, or the like of the corresponding component is not limited by the terms. In a case in which a certain component is described as being "connected," "coupled," or "linked" to another component, it should be understood that, although the component may be directly connected or linked to the other component, still another component may also be "connected," "coupled," or "linked" between the two components.
  • The terms "comprises" and/or "comprising" used herein do not preclude the presence or addition of one or more components, steps, operations, and/or devices other than those mentioned.
  • First, some terms used herein will be clarified.
  • In the present specification, "smoking article" may refer to any product that can be smoked or any product that can provide a smoking experience, regardless of whether the product is based on tobacco, tobacco derivatives, expanded tobacco, reconstituted tobacco, or tobacco substitutes. For example, smoking articles may include products that can be smoked, such as cigarettes, cigars, and cigarillos.
  • In the present specification, "smoking material" may refer to any type of material that may be used in a smoking article.
  • In the present specification, "upstream" or "upstream direction" may refer to a direction moving away from an oral region of a smoker, and "downstream" or "downstream direction" may refer to a direction approaching the oral region of the smoker.
  • In the present specification, "longitudinal direction" may refer to a direction corresponding to a longitudinal axis of a smoking article.
  • Hereinafter, various embodiments of the present disclosure will be described in detail with reference to the accompanying drawings.
  • FIG. 1 is a view illustrating a schematic configuration of a smoking article according to one embodiment of the present invention.
  • Throughout the specification, "smoking article" may refer to anything capable of generating an aerosol, such as tobacco (cigarettes) and cigars. The smoking article may include an aerosol-generating material or an aerosol-forming substrate. Also, the smoking article may include a solid material based on tobacco raw materials, such as reconstituted tobacco leaves, shredded tobacco, and reconstituted tobacco. A smoking material may include volatile compounds.
  • Also, throughout the specification, "upstream" or "upstream direction" refers to a direction moving away from an oral region of a user smoking a smoking article 100, and "downstream" or "downstream direction" refers to a direction approaching the oral region of the user smoking the smoking article 100. For example, in the smoking article 100 illustrated in FIG. 1, a smoking material portion 10 is disposed upstream or in an upstream direction of a smoking article filter portion 20 (a smoking article filter 20 or a filter portion 20).
  • Further, in the specification, a case where the smoking article 100 is a combustion-type cigarette is described as an example. However, the present invention is not limited thereto, and the smoking article 100 may also be a heating-type cigarette or the like that is used together with an aerosol generation device (not illustrated) such as an electronic cigarette device.
  • The present invention relates to the smoking article filter 20 (or the smoking article filter portion 20 or the filter portion 20) included in the smoking article 100, and the smoking article filter 20 according to one embodiment of the present invention includes lyocell tow including lyocell fibers and a phenol reducing material added to the lyocell tow, wherein the phenol reducing material includes triethyl citrate (TEC).
  • The "phenol" may refer to a group of chemical compounds composed of hydroxyl groups (-OH) directly bound to aromatic hydrocarbon functional groups, and a phenolic group includes phenol, catechol, m+P cresol, and o-cresol. The "phenol reducing material" may correspond to a material that can specifically reduce a phenolic material in smoke generated during smoking, for example, at least one of phenol, catechol, m+P cresol, and o-cresol.
  • The lyocell fibers are eco-friendly fibers made of cellulose extracted from wood pulp. The lyocell tow refers to a bundle formed by cross-connecting adjacent lyocell fibers.
  • In some embodiments, the lyocell fibers may have a shaped cross-section. The shaped cross-section is defined as a cross-section having a shape including a plurality of protrusions instead of having a circular shape. For example, a cross-section having a shape in which a plurality of protrusions extend from the center may be referred to as "shaped cross-section."
  • In some embodiments, the lyocell fibers may have a Y-shaped cross-section with three protrusions branching from the center, a cross-shaped cross-section with four protrusions, a star-shaped cross-section with five protrusions, or an O-shaped cross-section, but the present invention is not limited thereto.
  • In some embodiments, the phenol reducing material may be uniformly dispersed in lyocell tow and may be distributed throughout the entire region of the lyocell tow constituting the smoking article filter. The phenol reducing material including triethyl citrate (TEC) may be applied on the surfaces of the lyocell fibers constituting the lyocell tow.
  • The phenol reducing material including triethyl citrate (TEC) may be dispersed in lyocell tow in any manner. In some embodiments, the phenol reducing material including triethyl citrate (TEC) may be applied on lyocell tow and dispersed in the lyocell tow in a spray type manner, for example, a transfer jet nozzle system (TINS) manner. However, the present invention is not limited thereto, and the phenol reducing material including triethyl citrate (TEC) may also be dispersed in lyocell tow using a brush type manner. Accordingly, a smoking article filter including lyocell tow in which the phenol reducing material including triethyl citrate (TEC) is dispersed may be manufactured without adding or modifying manufacturing equipment.
  • In the smoking article filter according to the present invention, despite the phenol reducing material including triethyl citrate (TEC) being applied on the surfaces of the lyocell fibers, triethyl citrate (TEC) may not act as a plasticizer between the lyocell fibers. Accordingly, even when triethyl citrate (TEC) is added as a phenol reducing material to lyocell tow, a plurality of lyocell fibers included in the smoking article filter may not be substantially connected to each other, and the biodegradability of the smoking article filter may not be reduced. That is, an additive for binding the lyocell fibers together may not be included in the smoking article filter according to the present invention.
  • The smoking article filter to which lyocell tow is applied according to the present invention includes a phenol reducing material including triethyl citrate (TEC) that is dispersed in the lyocell tow and thus may have a greater effect of reducing phenols generated during smoking, compared to a smoking article filter to which triethyl citrate (TEC) is not added.
  • In some embodiments, the content of triethyl citrate (TEC) dispersed in the lyocell tow may range from 3 mg/rod to 50 mg/rod, 4 mg/rod to 40 mg/rod, 5 mg/rod to 30 mg/rod, 8 mg/rod to 29 mg/rod, 10 mg/rod to 28 mg/rod, 12 mg/rod to 27 mg/rod, or 15 mg/rod to 25 mg/rod, preferably, 18 mg/rod to 22 mg/rod. The above ranges of the content of triethyl citrate (TEC) may be suitable for a lyocell filter having a diameter of 7.71 mm, a circumference of 24.20 mm, and a length of 27 mm. In a case where triethyl citrate (TEC) is dispersed and included in the above range in the lyocell tow, phenol reducing performance may be excellent while physical properties of the smoking article filter are maintained.
  • In some embodiments, the content of triethyl citrate (TEC) dispersed in the lyocell tow may range from 0.11 mg to 1.85 mg, 0.18 mg to 1.2 mg, or 0.5 mg to 0.95 mg, preferably, 0.6 mg to 0.85 mg, per length (mm) of the lyocell tow. In a case where triethyl citrate (TEC) is dispersed and included in the above range in the lyocell tow, phenol reducing performance may be excellent while physical properties of the smoking article filter are maintained.
  • In some embodiments, triethyl citrate (TEC) dispersed in the lyocell tow may be added at 0.1 wt% to 15 wt% of the weight of the lyocell tow.
  • In some embodiments, the mono denier of the lyocell fibers constituting the lyocell tow may satisfy a range of 2 to 6, 2.3 to 5, 2.5 to 4.5, 2.7 to 4, 3 to 3.5, or 3.1 to 3.4.
  • In some embodiments, the total denier of the lyocell fibers constituting the lyocell tow may satisfy a range of 15,000 to 50,000, 25,000 to 48,000, 30,000 to 45,000, or 35,000 to 40,000.
  • In some embodiments, the smoking article filter including the lyocell tow in which the phenol reducing material including triethyl citrate (TEC) is dispersed may have a resistance to draw ranging from 50 mmWG/27 mm to 150 mmWG/27 mm, 60 mmWG/27 mm to 140 mmWG/27 mm, 70 mmWG/27 mm to 130 mmWG/27 mm, or 80 mmWG/27 mm to 120 mmWG/27 mm or a resistance to draw of 100 mmWG/27 mm. The present invention is not limited thereto, but lyocell tow included in the smoking article filter having a resistance to draw in the above numerical range may have a weight of 700 mg/108 mm.
  • In some embodiments, the smoking article filter including the lyocell tow in which the phenol reducing material including triethyl citrate (TEC) is dispersed may have a hardness ranging from 60% to 98%, 65% to 97%, or 70% to 95%. The hardness of the smoking article filter is a numerical value of the degree to which a diameter of the smoking article filter is maintained when the smoking article filter is pressed with a force of a certain level in a direction perpendicular to the longitudinal direction of the smoking article filter and may be a percentage value of a ratio of a diameter of the smoking article filter after the force is applied to a diameter of the smoking article filter before the force is applied. Specifically, the hardness of the smoking article filter is measured using Mathematical Formula 1 below. Hardness of smoking article filter % = a / D × 100
    Figure imgb0001
  • (D represents a diameter of the smoking article filter, and a represents a diameter of the smoking article filter after the smoking article filter is pressed for a predetermined amount of time using a weight.)
  • The smoking article filter including lyocell tow and triethyl citrate (TEC) dispersed in a predetermined content range in the lyocell tow according to one embodiment of the present invention can reduce a delivered amount of a phenolic material in smoke passing through the filter, compared to a smoking article filter including lyocell tow in which triethyl citrate (TEC) is not dispersed. The delivered amount of the phenolic material in smoke passing through the smoking article filter according to one embodiment of the present invention may be reduced 20% to 55%, 25% to 52%, or 45% to 50% compared to the delivered amount of the phenolic material in smoke passing through the smoking article filter to which the lyocell tow in which triethyl citrate (TEC) is not dispersed is applied.
  • In some embodiments, the smoking article filter may further include a capsule configured to generate a flavor. Specifically, the smoking article filter may further include a crushable capsule disposed in the lyocell tow and having a structure in which a liquid including a flavoring is wrapped with a film. One or more crushable capsules may be included in the lyocell tow in which triethyl citrate (TEC) is dispersed.
  • In some embodiments, the smoking article filter may further include a wrapper (or a filter portion wrapper) configured to wrap around the lyocell tow in which triethyl citrate (TEC) is dispersed. The filter portion wrapper may have a basis weight of 90 mg-2 or less, but the present invention is not limited thereto.
  • Hereinafter, the configurations of the present invention and the advantageous effects according thereto will be described in more detail using examples and comparative examples. However, the examples are merely for describing the present invention in more detail, and the scope of the present invention is not limited to these examples.
  • Example 1
  • Using HAUNI's KDF-2 equipment, triethyl citrate (TEC) was added at 5 mg/rod onto lyocell tow, and then the lyocell tow having triethyl citrate (TEC) dispersed therein was wrapped with wrapping paper to manufacture a smoking article filter having a length of 27 mm, a diameter of 7.71 mm, and a resistance to draw of 400 mmWG/108 mm.
  • Example 2
  • A smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) added onto the lyocell tow was added at 10 mg/rod instead of 5 mg/rod.
  • Example 3
  • A smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) added onto the lyocell tow was added at 20 mg/rod instead of 5 mg/rod.
  • Example 4
  • A smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) added onto the lyocell tow was added at 30 mg/rod instead of 5 mg/rod.
  • Comparative Example 1
  • A smoking article filter was manufactured in the same manner as in Example 1 except that triethyl citrate (TEC) was not added as a phenol reducing material onto the lyocell tow.
  • Experimental Example 1: Evaluation of phenol reducing performance according to content of triethyl citrate (TEC)
  • Smoking articles were manufactured using the smoking article filters of Comparative Example 1 and Examples 1 to 4, smoke components emitted during smoking using the cigarette smoking machine HAUNI LX20 manual (linear type) as a smoking device under HC conditions (puff volume: 55 ml / puff frequency: 30 s / puff duration: 2 s / vent blocking) as smoking conditions were collected using a Cambridge filter pad (CFP), and in order to extract substances from the smoke components collected on the CFP, 30 mL of 1% acetic acid was added and then stirred, the substances were filtered using a 0.45 µm PVDF syringe filter, phenols in the smoke passing through each smoking article filter were measured and analyzed using an Alliance HPLC-FLD analysis device of Waters Corporation, and results thereof are shown in Table 1 below. [Table 1]
    Components in smoke
    Phenol (µg) m+P Cresol, o-Cresol (µg)
    Comparative Example 1 43.9 35.2
    Example 1 (5 mg/rod) 30.9 25.2
    Example 2 (10 mg/rod) 26.9 22.6
    Example 3 (20 mg/rod) 22.1 18.4
    Example 4 (30 mg/rod) 22.8 19.3
  • As shown in Table 1 above, the amount of delivered phenol decreased in the smoking article filters of Examples 1 to 4 manufactured using the lyocell tow in which triethyl citrate (TEC) was dispersed, compared to the smoking article filter of Comparative Example 1 in which triethyl citrate (TEC) was not dispersed in the lyocell tow. Specifically, it can be seen that Examples 1 to 4 have an effect of reducing the amount of delivered phenol 20% to 55% or 25% to 52% compared to Comparative Example 1.
  • Also, it can be seen that a phenol reducing effect varies according to the content of triethyl citrate (TEC) dispersed in the lyocell tow. Specifically, it can be seen that, in the case of Example 3 in which lyocell tow having triethyl citrate (TEC) dispersed at 20 mg/rod therein was included and Example 4 in which lyocell tow having triethyl citrate (TEC) dispersed at 30 mg/rod therein was included, the amount of delivered phenol decreased 45% to 50% and significantly decreased compared to Comparative Example 1 and Examples 1 and 2. Meanwhile, although not shown in Table 1 above, it was confirmed that, when triethyl citrate (TEC) is added at 40 mg/rod or more, there is a problem in that triethyl citrate (TEC) spreads to the wrapping paper wrapped around the lyocell tow, causing the wrapping paper to become wet, or an ink bleeding phenomenon occurs, causing a decrease in quality of the smoking article filter.
  • The above-described smoking article filter according to the present invention may be applied to a smoking article. FIG. 1 is a view illustrating a schematic configuration of a smoking article according to one embodiment of the present invention. The smoking article 100 includes the smoking material portion 10 and the filter portion 20, and the above-described smoking article filter may be applied to the filter portion 20 of the smoking article 100. In the smoking article 100, the smoking material portion 10 is located upstream of the filter portion 20.
  • The smoking material portion 10 may be filled with a smoking material such as raw tobacco leaves, reconstituted tobacco leaves, or a mixture of tobacco leaves and reconstituted tobacco leaves. A processed smoking material may be filled in the smoking material portion 10 in the form of a sheet or shredded tobacco. The smoking material portion 10 may have the form of a longitudinally extending rod whose length, circumference, and diameter are not particularly limited, but the length, circumference, and diameter may be adjusted to sizes generally used in the art in consideration of the amount of smoking material filled therein, user preferences, or the like. The smoking material portion 10 may include at least one aerosol-generating material among glycerin, propylene glycol, ethylene glycol, dipropylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, and oleyl alcohol. The smoking material portion 10 may contain other additives such as a flavoring agent, a wetting agent, and/or an acetate compound. The aerosol-generating material and the additive may be contained in the smoking material.
  • The filter portion 20 is disposed downstream of the smoking material portion 10 and serves as a filter through which an aerosol material generated in the smoking material portion 10 passes right before being inhaled by the user. The filter portion 20 may be manufactured using various materials or manufactured in various forms. The filter portion 20 according to one embodiment of the present invention basically includes the above-described smoking article filter including lyocell tow including a plurality of lyocell fibers and triethyl citrate (TEC) dispersed in the lyocell tow. The smoking article filter including the lyocell tow and triethyl citrate (TEC) may replace all or part of the filter portion 20 of existing smoking articles, and when the smoking article filter replaces part of the filter portion 20, a filter material that is used conventionally may be used together. For example, a cellulose acetate filter, a paper filter, a hollow tube filter, or the like may be used as the conventional filter material.
  • The filter portion 20 is illustrated as a mono filter formed of a single filter in FIG. 1, but the present invention is not limited thereto. For example, the filter portion 20 may be provided as a dual filter, a triple filter, or the like, which includes two or more filters, in order to increase filter efficiency.
  • In some embodiments, when the filter portion 20 is provided as a dual filter, a triple filter, or the like, the filter (hereinafter, "lyocell filter") of the present invention that includes lyocell tow including lyocell fibers and triethyl citrate (TEC) dispersed in the lyocell tow may be applied as any one filter of the plurality of filters, and a cellulose acetate filter and/or a paper filter may be applied as the other or another filter of the plurality of filters. In this case, a length of the lyocell filter of the present invention may be 25% to 50% of the overall length of the filter portion 20.
  • Also, although not illustrated, the smoking article 100 may further include a hollow tube structure which is a tubular structure including a hollow therein. The hollow tube structure may be disposed downstream of the filter portion 20 including the lyocell filter.
  • In some embodiments, perforations may be formed in the hollow tube structure, but the present invention is not limited thereto. Perforations may not be formed in the hollow tube structure. In some embodiments, when perforations are formed in the hollow tube structure, the perforations may be formed at a position located 10 mm to 15 mm from the downstream end of the smoking article 100 in the upstream direction.
  • The exterior of the smoking material portion 10 and the filter portion 20 may be wrapped with a wrapper 30a or 30b.
  • The smoking material portion 10 may be wrapped with a smoking material portion wrapper 30a. Some of the cigarette smoke generated in a typical combustion process of the smoking material portion 10 is released into the atmosphere through the smoking material portion wrapper 30a before passing through the filter portion 20, and sidestream smoke gives an unpleasant feeling to people exposed thereto. There have been various attempts to reduce sidestream smoke such as filling conventional cigarette paper with a filler such as magnesium oxide, titanium oxide, cerium oxide, aluminum oxide, calcium carbonate, and zirconium carbonate. However, when sidestream smoke is reduced by simply applying such a filler, tobacco smoke taste degradation, combustion interruption, ash integrity degradation, or the like may occur, and it is difficult to address the above-mentioned problem through suitable combinations of materials contained in the filler. In some embodiments, a filler in which magnesium oxide (MgO and/or Mg(OH)2) and calcium carbonate (CaCO3) are mixed may be applied to the smoking material portion wrapper 30a in order to prevent tobacco smoke taste degradation, ash integrity degradation, and combustion interruption while reducing sidestream smoke.
  • The filter portion 20 may be wrapped with a filter portion wrapper 30b. The filter portion wrapper 30b may be manufactured using grease-resistant wrapping paper, and an aluminum foil may be further included at an inner surface of the filter portion wrapper 30b. As described above, the filter portion wrapper 30b may have a basis weight of 90 mg-2 or less, but the present invention is not limited thereto.
  • The smoking material portion 10 wrapped with the smoking material portion wrapper 30a and the filter portion 20 wrapped with the filter portion wrapper 30b may be wrapped together with tipping paper 40. As illustrated in FIG. 1, the tipping paper 40 may be wrapped around at least a portion (for example, a partial downstream region) of the smoking material portion wrapper 30a and an outer periphery of the filter portion wrapper 30b. In other words, at least a portion of the smoking material portion 10 and the filter portion 20 may be further wrapped with the tipping paper 40 and physically combined. According to one embodiment of the present invention, the tipping paper 40 may be made of nonporous wrapping paper that has not been treated to be grease-resistant, but the present invention is not limited thereto. Also, the tipping paper 40 may include an incombustible material to prevent a phenomenon in which the filter portion 20 burns, but the present invention is not limited thereto.
  • Although embodiments of the present disclosure have been described above with reference to the accompanying drawings, those of ordinary skill in the art to which the present disclosure pertains should understand that the present disclosure may be embodied in other specific forms without changing the technical spirit or essential features thereof. Therefore, the embodiments described above should be understood as being illustrative, instead of limiting, in all aspects. The scope of protection of the present disclosure should be interpreted by the claims below, and all technical ideas within the scope equivalent to the claims should be interpreted as falling within the scope of rights of the technical spirit defined by the present disclosure.

Claims (10)

  1. A smoking article filter comprising:
    lyocell tow including lyocell fibers; and
    a phenol reducing material dispersed in the lyocell tow,
    wherein the phenol reducing material includes triethyl citrate (TEC), and
    the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.
  2. The smoking article filter of claim 1, wherein the content of the triethyl citrate (TEC) ranges from 0.18 mg to 1.2 mg per length (mm) of the lyocell tow.
  3. The smoking article filter of claim 2, wherein the content of the triethyl citrate (TEC) ranges from 0.5 mg to 0.95 mg per length (mm) of the lyocell tow.
  4. The smoking article filter of claim 3, wherein the content of the triethyl citrate (TEC) ranges from 0.6 mg to 0.85 mg per length (mm) of the lyocell tow.
  5. The smoking article filter of claim 1, wherein the smoking article filter has a hardness ranging from of 70% to 95%.
  6. The smoking article filter of claim 1, wherein the lyocell fibers have a shaped cross-section.
  7. A smoking article comprising:
    a smoking material portion;
    a filter portion disposed downstream of the smoking material portion; and
    a wrapper configured to wrap around the smoking material portion or the filter portion,
    wherein the filter portion includes lyocell tow including lyocell fibers and a phenol reducing material dispersed in the lyocell tow,
    the phenol reducing material includes triethyl citrate (TEC), and
    the content of the triethyl citrate (TEC) ranges from 0.11 mg to 1.85 mg per length (mm) of the lyocell tow.
  8. The smoking article of claim 7, wherein the content of the triethyl citrate (TEC) ranges from 0.6 mg to 0.85 mg per length (mm) of the lyocell tow.
  9. The smoking article of claim 7, wherein the lyocell fibers have a shaped cross-section.
  10. The smoking article of claim 7, wherein the filter portion further includes a capsule configured to generate a flavor.
EP24750579.5A 2023-02-03 2024-02-01 SMOKE PRODUCT FILTER WITH LYOCELL-TOW AND SMOKE PRODUCT SO THAT Pending EP4544924A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR20230014851 2023-02-03
KR1020240002364A KR20240122324A (en) 2023-02-03 2024-01-05 Filter for smoking article having lyocell tow, smoking article having thereof
PCT/KR2024/001515 WO2024162782A1 (en) 2023-02-03 2024-02-01 Smoking product filter comprising lyocell tow, and smoking product comprising same

Publications (2)

Publication Number Publication Date
EP4544924A1 true EP4544924A1 (en) 2025-04-30
EP4544924A4 EP4544924A4 (en) 2026-04-29

Family

ID=92147013

Family Applications (1)

Application Number Title Priority Date Filing Date
EP24750579.5A Pending EP4544924A4 (en) 2023-02-03 2024-02-01 SMOKE PRODUCT FILTER WITH LYOCELL-TOW AND SMOKE PRODUCT SO THAT

Country Status (4)

Country Link
EP (1) EP4544924A4 (en)
JP (1) JP2025537932A (en)
CN (1) CN120456834A (en)
WO (1) WO2024162782A1 (en)

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2641972C (en) * 1996-08-23 2012-11-13 Weyerhaeuser Company Lyocell fibers and process for their preparation
KR101350991B1 (en) * 2008-06-27 2014-01-15 코오롱인더스트리 주식회사 Lyocell multi-filament, its prparation process and tire cord comprising the same
GB201116425D0 (en) * 2011-09-23 2011-11-02 British American Tobacco Co Filter materials and uses thereof
CN104411189A (en) * 2012-07-13 2015-03-11 菲利普莫里斯生产公司 Degradable filter for smoking articles
ES2714124T3 (en) * 2013-12-20 2019-05-27 Philip Morris Products Sa Filter for a smoking article that includes a degradable filter component
KR102211219B1 (en) * 2014-06-30 2021-02-03 코오롱인더스트리 주식회사 Lyocell Material with Noncircle Cross Section for Cigarette Filter And Manufacturing Method of the same
KR101765291B1 (en) * 2015-02-27 2017-08-04 주식회사 케이티앤지 Cigarette filter having lyocell tow and manufacturing method thereof
MX2018015046A (en) * 2016-06-14 2019-04-11 Philip Morris Products Sa Coated plug wrap to enhance filter hardness.
KR102029981B1 (en) * 2017-10-31 2019-10-08 주식회사 케이티앤지 Cigarette filter, manufacturing method thereof and cigarette containing the same
CN114765995B (en) * 2019-12-13 2024-02-23 德尔福特集团有限公司 Hydroentangled filter materials for smoking articles
DE102020119388B4 (en) * 2020-07-22 2023-08-17 Delfortgroup Ag PLEATED FILTER MATERIAL FOR SMOKING ARTICLES
US20250098736A1 (en) * 2022-01-19 2025-03-27 Kt & G Corporation Novel cigarette filter containing moisturizer
KR102946086B1 (en) * 2022-04-21 2026-03-30 주식회사 케이티앤지 Filters with functional enhancing binders and smoking articles comprising thereof

Also Published As

Publication number Publication date
WO2024162782A1 (en) 2024-08-08
EP4544924A4 (en) 2026-04-29
CN120456834A (en) 2025-08-08
JP2025537932A (en) 2025-11-20

Similar Documents

Publication Publication Date Title
EP4544927A1 (en) Filter for smoking article containing lyocell tow, manufacturing method, and smoking article comprising same
EP4544930A1 (en) Smoking product filter comprising lyocell tow, and smoking product comprising same
EP4544932A1 (en) Filter for smoking article comprising chemically unmodified lyocell fiber, and smoking article comprising same
EP4544924A1 (en) Smoking product filter comprising lyocell tow, and smoking product comprising same
EP4544925A1 (en) Filter for smoking article, comprising lyocell tow, and smoking article comprising same
EP4181698A1 (en) Paper cavity filter
EP4699458A1 (en) Bio-disintegrable and eco-friendly filter for smoking article
EP4544929A1 (en) Filter for smoking article comprising lyocell tow, and smoking article comprising same
EP4544928A1 (en) Filter for smoking article comprising lyocell tow, and smoking article comprising same
KR20250020301A (en) Disintegrable eco-friendly filter for smoking article, smoking article having thereof
WO2024110525A1 (en) Sustainable filter
KR20240122324A (en) Filter for smoking article having lyocell tow, smoking article having thereof
KR102466512B1 (en) Smoking article filter and auxiliary filter for the same
EP4599705A1 (en) Filter for smoking article and smoking article having thereof
EP4544931A1 (en) Smoking product filter comprising lyocell tow that is not chemically modified, and smoking product comprising same
RU2859843C2 (en) Filter for smoking article containing chemically unmodified lyocell fibres, and smoking article containing such filter
KR102450720B1 (en) Filter for smoking articles with improved biodegradability and smoking articles including the same
EP4670528A1 (en) SMOKE ITEM FILTER AND SMOKE ITEMS WITH IT
KR20240122340A (en) Filter for smoking article having chemically unmodified lyocell fiber, smoking article having thereof
KR20250101928A (en) Filter for smoking article and smoking article having thereof
KR20260001084A (en) Filter for smoking article, smoking article having thereof

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20250122

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC ME MK MT NL NO PL PT RO RS SE SI SK SM TR

A4 Supplementary search report drawn up and despatched

Effective date: 20260330

RIC1 Information provided on ipc code assigned before grant

Ipc: A24D 3/04 20060101AFI20260324BHEP

Ipc: A24D 3/06 20060101ALI20260324BHEP

Ipc: A24D 3/10 20060101ALI20260324BHEP

Ipc: A24D 3/02 20060101ALI20260324BHEP

Ipc: A24D 1/04 20060101ALI20260324BHEP

Ipc: A24D 1/02 20060101ALI20260324BHEP

Ipc: A24D 3/14 20060101ALI20260324BHEP