EP4533576A1 - Cell unit with securely fixed seal around manifold opening - Google Patents
Cell unit with securely fixed seal around manifold openingInfo
- Publication number
- EP4533576A1 EP4533576A1 EP22732469.6A EP22732469A EP4533576A1 EP 4533576 A1 EP4533576 A1 EP 4533576A1 EP 22732469 A EP22732469 A EP 22732469A EP 4533576 A1 EP4533576 A1 EP 4533576A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- support plate
- cell unit
- gasket
- plate
- cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
- C25B1/042—Hydrogen or oxygen by electrolysis of water by electrolysis of steam
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/60—Constructional parts of cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
- C25B9/75—Assemblies comprising two or more cells of the filter-press type having bipolar electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0276—Sealing means characterised by their form
- H01M8/0278—O-rings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2404—Processes or apparatus for grouping fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the invention relates to the field of electrochemical cell units and stacks thereof, and, in particular, relates to the field of fuel cells and electrolyser cells, and stacks thereof. More specifically, the invention relates to the field of solid oxide cells (SOCs), including metal-supported solid oxide cells of either the oxidizer type (SOFC) or electrolyser type (SOEC), and stacks thereof.
- SOCs solid oxide cells
- SOFC oxidizer type
- SOEC electrolyser type
- Solid oxide cells are a particular class of electrochemical cells, with the electrolyte layer being formed from a solid oxide, such as e.g. Yttria-stabilized zirconia (YSZ), Gadolinia-doped Ceria or Cerium Gadolinium Oxide (CGO).
- SOCs can be run as solid oxide fuel cell (SOFC) or as solid oxide electrolyser cell (SOEC).
- SOFCs use an electrochemical conversion process that oxidises fuel to produce electricity. For this, a fuel, or reformed fuel, contacts an fuel electrode and an oxidant, such as air or an oxygen rich fluid, contacts the oxidant electrode. The solid oxide electrolyte then conducts negative oxygen ions from the oxidant electrode to the fuel electrode.
- the fuel electrode constitutes the anode and the air or oxidant electrode constitutes the cathode.
- SOECs are SOCs run in reverse mode compared to SOFCs and are commonly used for the electrolysis of water, in particular for generating hydrogen and oxygen gas.
- the fuel electrode constitutes the cathode and the air or oxidant electrode constitutes the anode.
- a cell unit preferably an electrochemical cell unit.
- the cell unit comprises an areally extending support plate for supporting electrochemical layers, an areally extending interconnector (or separator) plate, and at least one gasket.
- Said support plate and said interconnector plate are overlying one another, and are extending perpendicular to a stacking direction. That is to say, the support plate and the interconnector plate are stacked upon one another along a stacking direction, with the support plate and the interconnector plate being areally extending perpendicular to said stacking direction.
- the support plate and the interconnector plate are arranged in parallel to each other and, optionally, contact each other in areal fashion.
- At least one through-hole is provided in the cell unit, said through-hole extending through the support plate and the interconnector plate to form a fluid port of the cell unit for supplying fluid, in particular fuel, to the cell unit.
- at least one through-hole is provided in each of the support plate and the interconnector plate of the cell unit, said through-hole of the support plate and the said through-hole of interconnector plate being arranged coaxially to each other.
- said through-hole (fluid port) of the cell unit is provided with a gasket. This, however, does not exclude that the cell unit may comprise additional through-holes that fulfill different purpose and are not provided with a gasket.
- the gasket preferably is configured to seal the through-hole of the cell unit (fluid port) against a neighboring cell in a cell stack.
- the gasket is located on a side of the support plate that is facing away from the interconnector plate.
- the gasket is supported by the support plate. More preferably, the gasket is in direct contact with a surface of the support plate, said surface facing away from the interconnector plate, and preferably extending perpendicular to the stacking direction.
- the gasket comprises an opening, said opening being delimited by an inner surface of said gasket and being in alignment with said through-hole (fluid port) of the cell unit such that the gasket is arranged around said through-hole (i.e. around the fluid port).
- the cell unit further comprises a positioning fixture for said gasket.
- the positioning fixture is configured to hold the gasket aligned by a form-fit perpendicular to the stacking direction. More specifically, the positioning fixture is configured and arranged to contact the gasket on its inner surface and to hold the gasket aligned with said through-hole (fluid port) of the cell unit by a form-fit in the plane perpendicular to the stacking direction.
- the positioning fixture is arranged within the extent of the through-hole through the support plate.
- the positioning fixture is configured such that the gasket is force-fittingly (i.e. by a friction lock) held in place by the positioning fixture along the stacking direction, that is in a direction perpendicular to the areal extent of the support plate.
- the positioning fixture may by configured such that the positioning fixture is biased against the inner surface of the gasket in a direction perpendicular to the stacking direction.
- the gasket may be held in a loss-proof manner by the positioning fixture.
- the cell repeat units may be fuel cell units, electrolyser cell units or reversible cell units.
- the cell repeat units may be solid oxide fuel cell units or solid oxide electrolyser cell units.
- the positioning fixture protrudes over the surface of the support plate to an extent that is less than the thickness of the gasket along the stacking direction, thus allowing for gasket compression during a stacking process.
- the positioning fixture may provide a hard stop during assembly and stacking of a stack of cell units.
- the positioning fixture extends through the through-hole formed in the support plate along the entire thickness of the support plate, and protrudes into the opening of the gasket. That is to say, the positioning fixture preferably extends from the side of the support plate that is facing the interconnector plate through the through-hole in the support plate, and protrudes beyond the surface of the support plate that is facing away from the interconnector plate. This has the advantage, that the positioning fixture may additionally perform a locating function for the support plate.
- the at least one positioning fixture may be provided by the interconnector plate. More preferably, the positioning fixture is integrally formed with the interconnector plate. This allows for easy manufacturing of the cell unit as the number of individual parts can be reduced. In addition, such a positioning fixture may perform a locating function for providing a fixed position for the support plate relative to the interconnector plate.
- the positioning fixture is constituted by one or more raised members integrally formed with the interconnector plate, said raised members preferably extending in a direction locally orthogonal to the areal extent of the interconnector plate, and towards the support plate.
- the positioning fixture may be formed by at least one portion of the interconnector plate bent towards the support plate, preferably bent in a direction locally orthogonal to the areal extent of the interconnector plate. That is to say, the positioning fixture may be formed by bending one or more portions of the interconnector plate in a direction towards the support plate, i.e. along the stacking direction. For this, it may be advantageous if the interconnector plate ist formed from metal. Preferably, the at least one portion is a portion surrounding the through-hole in the interconnector plate.
- the positioning fixture may comprise two or more positioning projections, said two or more positioning projections extending towards the support plate, preferably in a direction locally orthogonal to the areal extent of the interconnector plate.
- the positioning projections preferably are circumferentially, more preferably evenly, distributed around the fluid port of the cell unit.
- the positioning fixture may comprise a plurality of raised members that are arranged to define a perimeter for accommodating a gasket outside of the raised members.
- the two or more positioning projections may be spacedapart from each other by circumferential gaps. Said gaps preferably are configured to allow for fluid flowing from the fluid port to a cell space formed between the support plate and the interconnector plate.
- the positioning fixture may be a ring shaped projection, said ring-shaped projection preferably extending towards the support plate, more preferably locally orthogonal to the areal extend of the interconnector plate.
- the ring-shaped projection preferably is configured to define an outer perimeter for accommodating the inner surface of the gasket. That is, in the cell unit, the inner surface of the gasket preferably abuts an outer surface of the ring-shaped projection.
- an outer diameter of the ring-shaped projection equals a diameter of the opening of the gasket.
- the ring shaped projection may be formed by bending a circular portion of the interconnector plate surrounding the through-hole in a direction locally orthogonal to the areal extent of the interconnector plate. Thus, the ring-shaped projection may delimit the through-hole in the insulation plate.
- the spacer may be held by the positioning fixture in alignment with said fluid port (through-hole of the cell unit) by a form-fit in the plane perpendicular to the stacking direction.
- the positioning fixture may extend through the opening in the spacer, when the cell unit is assembled.
- the positioning fixture is configured to contact an inner surface of the spacer, said inner surface delimiting said opening in the spacer, such that the spacer is held aligned with the fluid port assigned to it (through-hole of the cell unit) by a form-fit in the plane perpendicular to the stacking direction. This further eases manufacturing of the cell unit.
- the spacer is configured and arranged such that the circumferential location of the channels or openings in the spacer overlaps with gaps between positioning projections of the positioning projection (e.g. gaps between a plurality of circumferentially distributed positioning projections or gaps between segments of a ring-shaped projection, see above), or openings defined in a ring-shaped projection.
- the spacer may comprise channels or openings, said channels or openings being arranged at circumferential locations around the fluid port, said locations corresponding to the locations of gaps between positioning projections of the positioning fixture, or to the locations of openings of a ringshaped projection of the positioning fixture.
- the spacer may comprise channels or openings, said channels or openings being arranged such that the channels or openings in the spacer are located between adjacent positioning projections (if multiple are present) or (in case of a ring-shaped projection) at positions locally corresponding to the positions of the radial openings of a ring shaped projection. This allows for fluid flowing from the fluid port to the cell space.
- the step of providing the at least one spacer may comprise the step of providing one spacer (e.g. in the form of a spacer ring) for each through-hole in the support plate, each spacer comprising one positioning fixture.
- the step of providing the at least one spacer may comprise the step of providing a, preferably single, spacer plate, said spacer plate comprising one or more through-holes and one or more positioning fixtures located at positions corresponding to the through-holes in the support plate and the interconnector plate.
- the method may further comprise a step of connecting adjacent cell units by joining the interconnector plate of one cell unit to the support plate of the adjacent cell unit, preferably using a welding process, more preferably a laser welding process.
- Fig. 1 shows an exploded perspective view of an interconnector plate and a support plate of an exemplary embodiment of a cell unit
- Fig. 2 shows perspective view of a fluid port of a cell unit
- Fig. 3a shows a perspective sectional view of the fluid port according to Fig. 2 ; and Fig. 3b shows a detail of Fig 3a; Fig. 4 shows a perspective sectional view of an interconnector plate and a spacer.
- the cell unit 10 may comprise electrochemical layers (not shown) to form a fuel cell or electrolyser cell.
- Said electrochemical layers preferably are provided on a side 24 of the support plate 12 that is facing away from the interconnector plate 14, preferably as thin coatings on a surface 38 of the support plate 12.
- the support plate 12 may have a porous region 26 (only rectangular perimeter indicated in Fig. 1 ) surrounded by a non-porous region 28 with the electrochemical layers being deposited upon the porous region 26.
- fuel may pass through the pores from the cell space 20 to the electrochemical layers.
- the support plate 12 may be provided with multiple small holes to enable fluid in the cell space 20 to be in contact with the side of the electrochemical layers that is closest to the support plate 12.
- the support plate 12 and the interconnector plate 14 each comprise four through-holes 30, 32 extending along the stacking direction 16.
- the support plate 12 and the interconnector plate 14 may comprise more or less through-holes 30, 32.
- the through-holes 30 in the support plate 12 and the through-holes 32 in the interconnector plate 14 preferably are arranged coaxially to each other such that - when the support plate 12 and the interconnector plate 14 are connected - each pair of through- holes 30, 32 forms a through-hole 34 extending through the cell unit 10 along the stacking direction 16.
- the through-holes 34 (through-holes 30, 32) are in fluid communication with the cell space 20, allowing for fluid exiting and entering the cell space 20.
- the through-holes 34 form fluid ports 36 of the cell unit 10.
- FIG. 2 there is shown a detail of a cell unit 10 in the area of a fluid port 36 from a perspective view to the side 24 of the support plate 12 that is facing away from the interconnector plate 14. That is, the cell unit 10 shown in Fig. 2 is oriented upside down relative to the cell unit 10 shown in Fig. 1.
- the fluid port 36 (through-hole 34) is provided with a gasket 18, configured to seal the fluid port 36 against a neighbouring cell unit 10, when the cell unit 10 is integrated into a cell stack (not shown) comprising a plurality of cell units 10 stacked upon one another along the stacking direction 16.
- the cell unit 10 futher comprises a positioning fixture 46 configured to hold the gasket 18 aligned with the fluid port 36 (through-hole 34) assigned to it.
- the positioning fixture 46 comprises a plurality of positioning projections 48 formed integrally with the interconnector plate 14 (see Fig. 2 and 3a). More specifically, a plurality of portions 50 (in the example four portions 50) of the interconnector plate 14, said portions 50 surrounding the through-hole 32 in the interconnector plate 14, are bent towards the support plate 12 to form the positioning projections 48 of the positioning fixture 46. Preferably, said portions 50 are bent such that they extend locally orthogonal to the areal extent of the interconnector plate 14 (see e.g. Fig. 3b). As shown in Fig. 2, the positioning projections 48 (bent portions 50) are, preferably evenly, distributed around the circumference of the fluid port 36, with circumferential gaps 52 being provided between adjacent positioning projections 48.
- arc-shaped portions may be formed in the material of the interconnector plate 14 surrounding the through-hole 32 (e.g. by embossing or cutting the interconnector plate), whereby alternately one portion is bent (forming the positioning projections 48) and one portion is not bent (see arc-shaped portions 54 in Fig. 2 and 3a).
- the positioning fixture 46 may comprise a ringshaped (circular) projection, e.g. formed by bending material surrounding the through-hole 32 in the interconnector plate 14 towards the support plate 12.
- the cell unit 10 further comprises an optional spacer 22, exemplarily in the form of a spacer ring 56.
- each fluid port 36 is provided with a respective spacer 22.
- the spacer 22 (spacer ring 56) is supported by the interconnector plate 14.
- the spacer 22 is in direct contact with a surface 58 of the interconnector plate 14, said surface 58 facing the support plate 12.
- the spacer 22 is provided around the through-hole 32 in the interconnector plate 14 and comprises an opening 60 in alignment with the through-hole 32.
- the opening 60 of the spacer 22 is located coaxially to the through- hole 32.
- the spacer 22 preferably is held in place by the positioning fixture 46 in an analogous fashion as the gasket 18. More specifically, the positioning projections 48 preferably are in contact with a inner surface 62 of the spacer 22 such that the spacer is held in fixed position by a form-fit perpendicular to the stacking direction 16.
- the spacer 22 may be a spacer sheet or spacer plate comprising through-holes complementary to the through-holes 32.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
Abstract
Description
Claims
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2022/064817 WO2023232236A1 (en) | 2022-05-31 | 2022-05-31 | Cell unit with securely fixed seal around manifold opening |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4533576A1 true EP4533576A1 (en) | 2025-04-09 |
Family
ID=82156360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP22732469.6A Withdrawn EP4533576A1 (en) | 2022-05-31 | 2022-05-31 | Cell unit with securely fixed seal around manifold opening |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP4533576A1 (en) |
| CN (1) | CN119301782A (en) |
| TW (1) | TW202349775A (en) |
| WO (1) | WO2023232236A1 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10044703B4 (en) * | 2000-09-09 | 2013-10-17 | Elringklinger Ag | Fuel cell unit, fuel cell block assembly and method for producing a fuel cell block assembly |
| US20130236803A1 (en) * | 2010-12-02 | 2013-09-12 | Toyota Jidosha Kabushiki Kaisha | Fuel cell module |
| CA3123154C (en) | 2018-12-20 | 2023-01-10 | Ceres Intellectual Property Company Limited | Fuel cell unit having flanged perimeter features and fuel cell stack |
| GB201917650D0 (en) * | 2019-12-03 | 2020-01-15 | Ceres Ip Co Ltd | Cell unit and cell stack |
-
2022
- 2022-05-31 WO PCT/EP2022/064817 patent/WO2023232236A1/en not_active Ceased
- 2022-05-31 CN CN202280096577.XA patent/CN119301782A/en not_active Withdrawn
- 2022-05-31 EP EP22732469.6A patent/EP4533576A1/en not_active Withdrawn
-
2023
- 2023-05-30 TW TW112120119A patent/TW202349775A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN119301782A (en) | 2025-01-10 |
| WO2023232236A1 (en) | 2023-12-07 |
| TW202349775A (en) | 2023-12-16 |
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