EP3635371A1 - Dispositif infrarouge - Google Patents
Dispositif infrarougeInfo
- Publication number
- EP3635371A1 EP3635371A1 EP18758927.0A EP18758927A EP3635371A1 EP 3635371 A1 EP3635371 A1 EP 3635371A1 EP 18758927 A EP18758927 A EP 18758927A EP 3635371 A1 EP3635371 A1 EP 3635371A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- resistive element
- infrared device
- infrared
- sub
- cavity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/28—Envelopes; Vessels
- H01K1/32—Envelopes; Vessels provided with coatings on the walls; Vessels or coatings thereon characterised by the material thereof
- H01K1/325—Reflecting coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B7/00—Microstructural systems ; Auxiliary parts of microstructural devices or systems
- B81B7/0032—Packages or encapsulation
- B81B7/0067—Packages or encapsulation for controlling the passage of optical signals through the package
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
- G01J3/10—Arrangements of light sources specially adapted for spectrometry or colorimetry
- G01J3/108—Arrangements of light sources specially adapted for spectrometry or colorimetry for measurement in the infrared range
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/02—Incandescent bodies
- H01K1/04—Incandescent bodies characterised by the material thereof
- H01K1/08—Metallic bodies
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/02—Incandescent bodies
- H01K1/04—Incandescent bodies characterised by the material thereof
- H01K1/10—Bodies of metal or carbon combined with other substance
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/02—Incandescent bodies
- H01K1/14—Incandescent bodies characterised by the shape
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/28—Envelopes; Vessels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/36—Seals between parts of vessel, e.g. between stem and envelope
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/50—Selection of substances for gas fillings; Specified pressure thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K3/00—Apparatus or processes adapted to the manufacture, installing, removal, or maintenance of incandescent lamps or parts thereof
- H01K3/02—Manufacture of incandescent bodies
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K3/00—Apparatus or processes adapted to the manufacture, installing, removal, or maintenance of incandescent lamps or parts thereof
- H01K3/12—Joining of mount or stem to vessel; Joining parts of the vessel, e.g. by butt sealing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K3/00—Apparatus or processes adapted to the manufacture, installing, removal, or maintenance of incandescent lamps or parts thereof
- H01K3/26—Closing of vessels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K7/00—Lamps for purposes other than general lighting
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/0033—Heating devices using lamps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2201/00—Specific applications of microelectromechanical systems
- B81B2201/04—Optical MEMS
- B81B2201/047—Optical MEMS not provided for in B81B2201/042 - B81B2201/045
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2203/00—Forming microstructural systems
- B81C2203/01—Packaging MEMS
- B81C2203/0118—Bonding a wafer on the substrate, i.e. where the cap consists of another wafer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C2203/00—Forming microstructural systems
- B81C2203/03—Bonding two components
- B81C2203/033—Thermal bonding
- B81C2203/035—Soldering
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3577—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing liquids, e.g. polluted water
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/061—Sources
- G01N2201/06186—Resistance heated; wire sources; lamelle sources
Definitions
- the present invention relates to an infrared device with an infrared source.
- the present invention relates to an infrared device for the detection of gas.
- Non-dispersive infrared sources (“NDI R” or “Non-Dispersive I nfraRed” in the Anglo-Saxon terminology) are known in the state of the art, and are commonly used in gas detectors.
- FIG. 1 illustrates an infrared micro-source known from the state of the art and described by Barritault et al. [1].
- the infrared microsource comprises a metal filament formed on a membrane suspended by two suspension arms.
- the metallic filament when traversed by an electric current, heats and emits infrared radiation according to the law of the black body.
- the intensity of the infrared radiation increases with the temperature at which the metal filament is heated.
- This operating temperature of the infrared source remains limited, however, and can not exceed the degradation temperature of the constituent elements of the infrared source, de facto restricting the intensity of the infrared radiation likely to be emitted by said source.
- the efficiency of the infrared source is also limited by conduction losses in the air that can occur when the latter is in operation.
- it has been proposed to keep the infrared source under vacuum, or at least in a reduced pressure atmosphere, for example at a pressure of less than 10 -2 mbar, in order to reduce losses by thermal conduction .
- a pressure of less than 10 -2 mbar for example at a pressure of less than 10 -2 mbar
- the radiation emitted by the infrared source remains highly dispersed, so that only a useful fraction of said radiation is actually used for the detection of gases.
- An object of the present invention is therefore to provide an infrared device, comprising an infrared source, and having a better efficiency than known devices of the state of the art.
- Another object of the present invention is to provide an infrared device that can be implemented for the detection of gas without using an optical detector.
- Another object of the present invention is to provide an arrangement of an infrared source in the infrared device for designing a gas detector whose sensitivity is improved over gas detectors known from the state of the art.
- Another object of the present invention is to provide an infrared device coupled to a waveguide.
- an object of the present invention is to provide an infrared device, the majority of the emitted infrared radiation is coupled to the waveguide.
- an infrared device for generating infrared radiation comprising:
- a main element comprising an outer surface and an inner surface, the inner surface defining a cavity
- At least one resistive element intended to emit infrared radiation when it is traversed by a current, said at least one resistive element being kept in suspension, by at least two suspension arms, in the cavity, said suspension arms being arranged to establish an electrical contact between the resistive element and two connection terminals disposed outside the cavity,
- the outer surface and / or the inner surface are at least partly coated with a reflective coating, said reflective coating having a reflectivity of at least 90%, preferably at least 95%, even more preferably at least 99%, in the range of infrared wavelengths that can be emitted by the at least one resistive element, the reflective coating is also arranged so that the infrared radiation emitted by the resistive element and reflected by said coating is at least partly absorbed by the resistive element.
- the at least one resistive element is in an environment maintained at a pressure of less than 10 ⁇ 2 mbar, preferably between 10 ⁇ 3 mbar and 10 ⁇ 2 mbar.
- the main element comprises two sub-elements, respectively, first sub-element and second sub-element, arranged so as to form the cavity, and each defining a first sub-volume and a second sub-element. sub-volume of said cavity, the two sub-elements being interconnected by a hermetic connection.
- the two suspension arms are maintained at the level of the hermetic connection, and extend in the direction of the resistive element.
- a waveguide is coupled, at a first end of said waveguide, to the cavity at a through aperture formed on the reflective coating, and so that infrared radiation diffusing at the through aperture out of the cavity is at least partly guided by said waveguide, said reflective coating being arranged so that only the infrared radiation likely to be emitted by the resistive element and through the diffuse through opening out of the cavity.
- the first end of the waveguide is flush with the inner surface and in correspondence with the through opening.
- the first end of the waveguide is at a predetermined distance from the inner surface, the predetermined distance advantageously being less than a wavelength of the infrared radiation that can be emitted by the element. resistive, and intended to be guided by said waveguide.
- the first sub-element is made of a material that is transparent to infrared radiation.
- the reflective coating comprises a first coating portion covering the inner surface (210b) at the first sub-element.
- the waveguide extends from the first end in a direction substantially perpendicular to the normal direction defined by the inner surface section in correspondence with the through opening.
- the reflective coating comprises a second coating portion covering one or the other of the inner and outer surfaces at the second sub-element.
- the waveguide is included in the main element.
- said infrared device further comprises a membrane that is transparent to infrared radiation that can be emitted by the resistive element, said membrane hermetically separating the volume of the cavity into two so-called volume sections, respectively, first volume section and second volume section, the main element comprises at least one, advantageously two, openings opening at the level of the first volume section and intended to ensure the flow of a gas or a liquid in said first volume section, the resistive element is disposed in the second volume section.
- the infrared device further comprises means for detecting the temperature change of the resistive element.
- the main element comprises the two connection terminals.
- the resistive element comprises a metal filament, advantageously the metal filament is interposed between two dielectric layers, in addition, advantageously, the stack comprising the metal filament interposed between the two dielectric layers is arranged on a mechanical support.
- the first sub-element and the second sub-element comprise a semiconductor material, the semiconductor material advantageously being silicon.
- the hermetic connection between the first sub-element and the second sub-element is a metal-metal bonding, or a eutectic weld, advantageously the eutectic weld is made with silicon and gold, or Au and In, or Cu and Sn, or Au and Sn, or Au and Ge, or Al and Ge.
- the resistive element is provided with a filter adapted to select a spectral range of the infrared radiation likely to be emitted by said resistive element.
- the main element is made, at least in part, of a material transparent to infrared radiation.
- the invention also relates to the use of the infrared device for the detection and identification of gas and / or liquid.
- FIG. 1 is a schematic representation of a resistive element known from the state of the art
- FIG. 2a is a schematic representation according to a sectional plane of the infrared device according to a first variant of a first embodiment of the invention
- FIG. 2b is a schematic representation according to a sectional plane of the infrared device according to a second variant of the first embodiment of the invention
- FIG. 3 is a diagrammatic representation according to a sectional plane of the infrared device according to a second embodiment of the invention
- FIG. 4 is a perspective representation of a resistive element that can be implemented in the present invention.
- FIG. 5 is a graphical representation of the attenuation of the infrared radiation (vertical axis) as a function of the imaginary absorption index of the gas k, the dotted line curve represents the attenuation in an infrared device devoid of a reflective coating. , while the solid curve considers the presence of a reflective coating,
- FIGS. 6a-6f are schematic representations of the steps of a method of manufacturing the infrared device according to the first variant of the first embodiment of the invention.
- the invention described in detail below implements an infrared device comprising a resistive element suspended in a cavity formed in a main element, and capable of emitting infrared radiation when it is traversed by an electric current.
- the main element is covered, at least in part, on its outer surface and / or its inner surface by a reflective coating.
- the implementation of the reflective coating makes it possible to confine, at least in part, infrared radiation emitted by the resistive element in the cavity.
- FIGS. 2a, 2b, 3 and 4 show examples of implementations of an infrared device 100 according to the invention.
- the infrared device 100 comprises a main element 200.
- the main member 200 includes an outer surface 210a (or outer wall) and an inner surface 210b (or inner wall).
- the inner surface 210b delimits the volume of a cavity 220.
- Inner surface means a surface that is not exposed to the external environment. In other words, the cavity delimited by the inner surface is at least partly closed.
- Outer surface means a surface which, since it is free of any coating, is exposed to the external environment (that is, the environment outside the cavity).
- main element 200 forms an enclosure, at least partially closed.
- the space between the outer surface 210a and the inner surface 210b defines the thickness of the main member 200.
- the main element 200 may be made of a material transparent to infrared radiation.
- infrared radiation transparency is meant an element permitting an infrared transmissivity of at least 50%.
- the main element 200 may comprise at least one of the following materials: silicon, germanium, germanium silicon alloy, AIGaS, GaS, InP.
- the infrared device 100 also comprises a resistive element
- resistive element is meant an element which, when traversed by an electric current, heats and emits infrared radiation.
- the resistive element 300 is an electrically resistive element.
- Infrared radiation means light radiation in a range of wavelengths between 3 ⁇ and 12 ⁇ .
- the resistive element 300 is held in suspension in the cavity 220 by two suspension arms 310a and 310b.
- the resistive element 300 may comprise at least one structured part of a stack of layers 301 (FIG. 4).
- the stack of layers may comprise a metal filament 302, for example interposed between two dielectric layers 303, 304 made of a dielectric material.
- the metal filament 302 may in particular comprise platinum.
- the dielectric layers 302, 304 may comprise titanium nitride.
- the resistive element 300 may also comprise a mechanical support 305 on which the stack of layers 301 rests.
- the mechanical support 305 is for example made of silicon, or of silicon nitride.
- the resistive element 300 may be in the form of a circular patch. The invention should not, however, be limited to this form.
- the two suspension arms 310a and 310b extend from the resistive element 300, and are anchored to the main element 200.
- the structure of the suspension arms 310a and 310b is similar to that of the resistive element 300.
- the resistive element 300 is in an environment maintained at a pressure of less than 10 ⁇ 2 mbar, preferably between 10 ⁇ 3 mbar and 10 ⁇ 2 mbar.
- the resistive element 300 is also electrically connected to connection terminals 330a and 330b from which an electric current can be imposed on said resistive element 300.
- connection terminals 330a and 330b are disposed outside the cavity 220. It is thus understood, without it being necessary to specify, that the connection Electrical connection between the resistive element 300 and the two connection terminals 330a and 330b is via the suspension arms 310a and 310b.
- the infrared device within the meaning of the present invention further comprises a reflective coating 240.
- the reflective coating 240 may cover, at least in part, the outer surface 210a and / or the inner surface 210b.
- the reflective coating 240 also has a reflectivity coefficient of at least 90%, preferably at least 95%, even more preferably at least 99%, in the range of infrared wavelengths that can be emitted by the resistive element 300.
- the reflective coating 240 may comprise a metal species, for example gold, and / or silver, and / or aluminum.
- the reflective coating 240 may, for example, exclusively cover the outer surface 210a or the inner surface 210b
- the main element 200 may comprise two sub-elements, respectively, first sub-element 250a and second sub-element 250b.
- the two sub-elements 250a and 250b are arranged to form the cavity.
- Each sub-element 250a and 250b forms a hollow element and comprises a rim.
- the two sub-elements 250a and 250b when assembled, are advantageously connected by a hermetic connection.
- the hermetic bond may advantageously be a eutectic weld.
- eutectic welding can be performed with silicon and gold, or Au and In, or Cu and Sn, or Au and Sn, or Au and Ge, or Al and Ge.
- the hermetic bond may be a metal-to-metal bond.
- the two suspension stockings 310a and 310b can be maintained at the hermetic connection, and extend towards the resistive element 300.
- the two suspension arms 310a and 310b can pass through the main element from the inside to the outside of the cavity.
- the reflective coating 240 may cover, at the first sub-element, the outer surface 210a or the inner surface 210b.
- the reflective coating 240 may cover, at the second sub-member 250b, the outer surface 210a or the inner surface 210b.
- the infrared device may comprise a waveguide 400.
- waveguide is meant a channel adapted to guide light radiation in the direction of extension of said channel.
- the reflective coating 240 comprises a through opening 241, and is arranged so that only the infrared radiation, capable of being emitted by the resistive element 300, and passing through the through opening 241 diffuses out of cavity 220.
- the waveguide 400 within the meaning of the present invention, is then coupled at its first end 410 to the cavity 220 at the through opening 241, so that infrared radiation diffusing out of the cavity is guided, at least in part, by the waveguide.
- the waveguide is disposed outside the cavity.
- the waveguide may comprise a core made of a SiGe alloy.
- the first end 410 of the waveguide 400 is flush with the inner surface and in correspondence with the through opening.
- the waveguide 400 may open into the cavity 220 at the first sub-element 250a.
- the reflective coating 240 may cover the inner surface 210b at the level of first sub-element 250a, and covering either the inner surface 210b or the outer surface 210a at the second sub-element 250b.
- the first end 410 of the waveguide 400 is at a predetermined distance from the inside surface 210b.
- the waveguide 400 does not open into the cavity at the inner surface 210b. It is also clear that when there is an optical coupling between the cavity and the waveguide at its first end, the latter is necessarily close to the through opening.
- the predetermined distance is advantageously less than a wavelength of the infrared radiation likely to be emitted by the resistive element 300, and intended to be guided by said waveguide 400.
- the waveguide 400 may extend, from the first end, in a direction substantially perpendicular to the normal direction defined by the inner surface section 210b in correspondence with the through aperture.
- inner surface section 210b in correspondence with the through opening is meant a surface section of the inner surface circumscribed by the contour of the through opening.
- normal to a surface section means a direction perpendicular to said surface, where appropriate, perpendicular to a mean plane defined by said surface section.
- the reflective coating 240 includes a first coating portion 240a that overlies, at the first sub-member 250a, the inner surface 210a.
- the through opening 241 is further disposed at the first coating portion 240a.
- the reflective coating 240 comprises a second coating portion 240b covering either of the inner and outer surfaces at the second sub-member (particularly in Figure 2b, the second coating portion is disposed on the inner surface at the second sub-element).
- the waveguide 400 is included in the main element so that the material constituting the main element 200 forms a sheath around the waveguide 400.
- the heart of the waveguide may comprise an alloy of silicon germanium.
- the infrared radiation emitted by the resistive element 300 is largely coupled to the waveguide 400.
- the infrared radiation emitted by the resistive element 300 undergoes multiple reflections, which are either reabsorbed by said resistive element 300, or coupled to the waveguide 400.
- the radiation reabsorbed by the resistive element 300 heats said resistive element, and can therefore be reemitted as infrared radiation.
- the implementation of the reflective coating and a waveguide according to the present invention makes it possible to create a guided NDIR source.
- the reflective coating makes it possible to exacerbate the light power in a particular direction (i.e. the direction defined by the waveguide).
- the waveguide 400 may be both a single-mode waveguide and a multimode waveguide.
- the sizing of the waveguide is left to the appreciation of the person skilled in the art and of his general knowledge.
- the infrared device makes it possible to consider the co-integration of said device on a silicon chip with other devices, for example a gas chamber, a detector.
- the infrared device makes it possible to consider a gas sensor also devoid of optical filter.
- the inventors have been able to perform optical simulations according to the first variant of the first embodiment. These optical simulations were conducted considering two sizing cavities different from the infrared device.
- the resistive element considered emits infrared radiation at a length of 4.2 ⁇
- the inner surface of the main element is covered with a layer of gold.
- the waveguide is opening on the inner surface, and is of a height of 3 ⁇ (monomode waveguide).
- the two cavity sizing are, respectively, 100 ⁇ x 100 ⁇ (first dimensioning), and 200 ⁇ x 200 ⁇ (second dimensioning).
- the coupling ratio of infrared radiation is 85% and 60%, respectively, for the first cavity sizing and the second cavity sizing.
- the infrared device comprises a transparent membrane 500 to infrared radiation that can be emitted by the resistive element 300.
- the transparent membrane 500 hermetically separates the volume of the cavity into two so-called volume sections, respectively, first volume section 260a and second volume section 260b.
- the transparent membrane 500 is for example made of silicon, but may include any other material transparent to infrared radiation.
- the main element 200 comprises two openings 270a and
- the resistive element 300 is disposed in the second volume section. Particularly advantageously, the atmosphere in the second volume section is maintained at a pressure of less than 10 -2 mbar, preferably between 10 3 mbar and 10 -2 mbar.
- the infrared device 100 may also include temperature change detecting means of the resistive element 300.
- this device makes it possible to detect and identify a liquid or a gas.
- the infrared radiation emitted by the resistive element 300 undergoes multiple reflections, which are either reabsorbed by said resistive element 300, or absorbed by the gas or liquid (hereinafter "gas") circulating in the first volume section 260a. .
- the absorption by the gas then limits the heating of the resistive element 300 by reabsorption of the reflected or "multi-reflected" infrared radiation.
- the implementation of the reflective coating within the meaning of the present invention makes it possible to consider multiple reflections of the infrared radiation, and thus increase the probability of absorption of said infrared radiation by the gas.
- the temperature variations thus observed at the level of the resistive element 300 are then exacerbated, so that the infrared device according to the second embodiment can constitute a gas detector of improved sensitivity compared to the same detector devoid of reflective coating. .
- the temperature variations of the resistive element 300 can be detected by measuring the circulating current (for example with a ammeter) in said resistive element as a function of the electrical voltage imposed on it.
- the gas can therefore be detected by a sudden cooling of the resistive element 300.
- the inventors have determined by numerical simulation the reflective coating effect on the sensitivity of a gas detector according to the second embodiment.
- Figure 5 is a graphical representation resulting from the simulation.
- the dashed line represents the attenuation of the infrared radiation as a function of the imaginary absorption index k of the gas in the absence of a reflective coating, while the solid line curve considers the presence of a reflective coating. It is noted that the attenuation of the infrared radiation is much greater in the presence of reflective coating. In other words, a gas detector based on this second embodiment sees its sensitivity exacerbated by the implementation of the reflective coating.
- the gas detector is also devoid of optical detector.
- the infrared radiation emitted by the resistive element 300 can be filtered.
- the resistive element may be provided with a filter 320 (FIG. 4) adapted to select a spectral range at which the gas of interest is sensitive.
- the filter 320 may be a metal-insulator-metal resonator (MIMs) placed directly on the resistive element 300.
- MIMs metal-insulator-metal resonator
- the implementation of a filter 320 also makes it possible to improve the sensitivity of the detector relative to the specific gas (in other words to improve its detection threshold).
- the limitation of the emission spectrum of the resistive element limits the amount of radiation reabsorbed by said resistive element.
- the specific gas absorbs at least part of the infrared radiation emitted by the resistive element, a larger temperature drop of said resistive element.
- a first step of the manufacturing method consists in providing a first substrate SI, for example a silicon substrate, which comprises two so-called faces, respectively, front face FAV and rear face FAR (FIG. 6a).
- a first substrate SI for example a silicon substrate, which comprises two so-called faces, respectively, front face FAV and rear face FAR (FIG. 6a).
- a trench T intended to receive the GO waveguide, is then formed (by dry etching or liquid) on the front face FAV of the substrate S.
- the trench T is then filled with a material intended to form the core of the guide.
- GO wave for example SiGe.
- An encapsulation layer CE is formed on the front face FAV of the substrate S so as to encapsulate the waveguide.
- the encapsulation layer CE may be a silicon layer formed by an epitaxial step (FIG. 6b).
- the formation of the encapsulation layer CE is then followed by a step of forming a first cavity CA1 (FIG. 6c).
- the step of forming the cavity comprises an etching step (for example a liquid etching) performed so that the waveguide GO opens, in a first end PE, in said cavity.
- the cavity forming step includes steps of masking, and / or alignment of lithographic photo masks which are part of the knowledge general of the person skilled in the art and which are therefore not explained in this presentation.
- the walls of the cavity are then covered with a reflective coating provided with a through opening OT at the first end PE of the waveguide GO.
- the reflective coating can be a layer of gold.
- the formation of the gold layer on the walls of the first cavity CA1 may be preceded by the deposition of diffusion barriers comprising, for example, a stack of a titanium layer and a silicon oxide layer.
- the manufacturing method also comprises a step of forming a resistive element ER on a second substrate S2 (FIG. 6d).
- the resistive element ER is suspended by two suspension arms BS1 and BS2 over a second cavity CA2.
- a metallization bead CM comprising chromium, nickel and gold may be formed around the cavity.
- This metallization bead CM is for example intended to ensure a hermetic assembly, by metal-metal bonding or by eutectic bonding, for example, between the first cavity CA1 and the second cavity CA2 (FIG. 6e).
- a step of thinning the second substrate S2, following the assembly of the two cavities CA1 and CA2, can be performed.
- a trench TA defining the second sub-element described above, is then performed.
- This trench TA can be formed by "RIE” ("Reactive Ion Etching"), and is followed by a step of forming the reflective coating on the outer surface of the second sub-element 250b.
- a method of manufacturing the infrared device according to the second embodiment can essentially be transposed to the manufacturing steps previously presented.
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- Engineering & Computer Science (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Physics & Mathematics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
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Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1757149A FR3069707B1 (fr) | 2017-07-27 | 2017-07-27 | Dispositif infrarouge |
| PCT/FR2018/051903 WO2019020937A1 (fr) | 2017-07-27 | 2018-07-25 | Dispositif infrarouge |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3635371A1 true EP3635371A1 (fr) | 2020-04-15 |
Family
ID=60515495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP18758927.0A Withdrawn EP3635371A1 (fr) | 2017-07-27 | 2018-07-25 | Dispositif infrarouge |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US10937643B2 (fr) |
| EP (1) | EP3635371A1 (fr) |
| FR (1) | FR3069707B1 (fr) |
| WO (1) | WO2019020937A1 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11187655B2 (en) | 2018-05-16 | 2021-11-30 | Sensera, Inc. | Compact gas sensors |
| DE102019132829B4 (de) * | 2019-12-03 | 2022-12-08 | CiS Forschungsinstitut für Mikrosensorik GmbH | Strahlungsquelle zur Erzeugung elektromagnetischer Strahlung sowie Verfahren zu ihrer Herstellung |
| FR3112402B1 (fr) | 2020-07-07 | 2022-10-28 | Commissariat Energie Atomique | Dispositif de démultiplexage en longueur d’onde notamment pour un démultiplexage hors plan. |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58158914A (ja) * | 1982-03-16 | 1983-09-21 | Semiconductor Res Found | 半導体製造装置 |
| NO170366C (no) * | 1989-05-26 | 1997-02-10 | Kanstad Teknologi As | Pulserende infraröd strålingskilde |
| GB2248141A (en) * | 1990-09-18 | 1992-03-25 | Servomex | Infra-red source |
| DE4332244C2 (de) * | 1993-09-23 | 1999-01-28 | Heraeus Noblelight Gmbh | Strahlungsanordnung mit einer thermischen Strahlenquelle und deren Verwendung |
| US6367972B1 (en) * | 1998-09-29 | 2002-04-09 | Ishizuka Electronics Corporation | Non-contact temperature sensor with temperature compensating heat sensitive elements on plastic film |
| JP4055697B2 (ja) * | 2003-11-05 | 2008-03-05 | 株式会社デンソー | 赤外線光源 |
| NO321281B1 (no) | 2004-09-15 | 2006-04-18 | Sintef | Infrarod kilde |
| US20100097048A1 (en) * | 2007-01-04 | 2010-04-22 | Werner Douglas H | Passive detection of analytes |
| EP2848087B1 (fr) * | 2012-05-08 | 2017-11-15 | AMS Sensors UK Limited | Emetteur ir et détecteur de gaz non dispersif infrarouge |
| DE202015002315U1 (de) * | 2015-03-27 | 2015-05-06 | Infineon Technologies Ag | Gassensor |
| FR3052562B1 (fr) | 2016-06-10 | 2019-06-14 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Dispositif optique |
| FR3054664B1 (fr) | 2016-07-27 | 2018-09-07 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Dispositif optique a micro-resonateur en anneau segmente pour un capteur biologique ou chimique |
| FR3054882B1 (fr) | 2016-08-04 | 2020-10-09 | Commissariat Energie Atomique | Cavite d'absorption avec guides d'onde d'entree et sortie pour un capteur biologique ou chimique |
| FR3055977B1 (fr) | 2016-09-15 | 2018-09-28 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Dispositif de couplage optique |
| FR3056306B1 (fr) | 2016-09-20 | 2019-11-22 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Guide optique presentant un virage a pseudo-gradient d'indice |
| FR3068778B1 (fr) | 2017-07-04 | 2019-08-30 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Capteur de deplacement avec micro-resonateur en anneau segmente. |
| FR3069070A1 (fr) | 2017-07-17 | 2019-01-18 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Dispositif de focalisation optique a pseudo-gradient d'indice |
| FR3072458B1 (fr) | 2017-10-12 | 2022-04-01 | Commissariat Energie Atomique | Source de rayonnement infrarouge |
| FR3077652B1 (fr) | 2018-02-05 | 2022-05-27 | Commissariat Energie Atomique | Puce photonique a structure de collimation integree |
-
2017
- 2017-07-27 FR FR1757149A patent/FR3069707B1/fr not_active Expired - Fee Related
-
2018
- 2018-07-25 US US16/633,804 patent/US10937643B2/en not_active Expired - Fee Related
- 2018-07-25 EP EP18758927.0A patent/EP3635371A1/fr not_active Withdrawn
- 2018-07-25 WO PCT/FR2018/051903 patent/WO2019020937A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20200234942A1 (en) | 2020-07-23 |
| WO2019020937A1 (fr) | 2019-01-31 |
| FR3069707A1 (fr) | 2019-02-01 |
| US10937643B2 (en) | 2021-03-02 |
| FR3069707B1 (fr) | 2019-08-30 |
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