EP3284844A1 - System and method for low thermal shock-fast cooling of thermal barrier coating - Google Patents

System and method for low thermal shock-fast cooling of thermal barrier coating Download PDF

Info

Publication number
EP3284844A1
EP3284844A1 EP17154312.7A EP17154312A EP3284844A1 EP 3284844 A1 EP3284844 A1 EP 3284844A1 EP 17154312 A EP17154312 A EP 17154312A EP 3284844 A1 EP3284844 A1 EP 3284844A1
Authority
EP
European Patent Office
Prior art keywords
chamber
arcuate wall
workpiece
cool down
infrared lamp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP17154312.7A
Other languages
German (de)
French (fr)
Other versions
EP3284844B1 (en
Inventor
Shayan Ahmadian
Hoyt Y Chang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RTX Corp
Original Assignee
United Technologies Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by United Technologies Corp filed Critical United Technologies Corp
Publication of EP3284844A1 publication Critical patent/EP3284844A1/en
Application granted granted Critical
Publication of EP3284844B1 publication Critical patent/EP3284844B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment
    • C23C14/5806Thermal treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • C23C14/28Vacuum evaporation by wave energy or particle radiation
    • C23C14/30Vacuum evaporation by wave energy or particle radiation by electron bombardment

Definitions

  • the present disclosure relates to a system for thermal barrier coatings (TBCs), and more particularly, to thermal control therein.
  • TBCs thermal barrier coatings
  • Thermal barrier coatings are multilayer materials that are typically applied to hot sections of an engine to reduce the surface temperature experienced by workpieces.
  • TBCs often include (1) a substrate, which may be an engine workpiece-typically a gamma-gamma prime superalloy (2) an aluminum rich bond coat (3) thermally grown oxide (TGO) that reduce further oxidation of bond coat by blocking oxygen (4) a low thermal conductivity ceramic top coat.
  • a substrate which may be an engine workpiece-typically a gamma-gamma prime superalloy
  • TGO thermally grown oxide
  • EB-PVD electron beam-physical vapor deposition
  • a columnar top coat microstructure develops on the surface of the workpieces in near vacuum at elevated temperatures.
  • EB-PVD is a form of physical vapor deposition in which an ingot of material is bombarded with an electron beam given off by a charged tungsten filament under high vacuum. The electron beam causes atoms from the ingot to transform into the gaseous phase. These atoms then condense into solid form, coating the workpiece in the vacuum chamber, and within a line of sight, with a thin layer of the material.
  • a coating system can include a reflective cool down chamber with at least one arcuate wall and an infrared lamp directed at the arcuate wall.
  • a further embodiment of the present disclosure may include wherein the at least one arcuate wall includes an interior surface with a high index of reflection.
  • a further embodiment of the present disclosure may include wherein the at least one arcuate wall includes an interior surface with a mirror finish.
  • a further embodiment of the present disclosure may include, wherein the infrared lamp is located on a movable door that permits intake of a workpiece holder.
  • a further embodiment of the present disclosure may include, wherein the infrared lamp is located on a movable door that permits egress of a workpiece holder.
  • a further embodiment of the present disclosure may include a diffusion lens mounted to the infrared lamp.
  • a further embodiment of the present disclosure may include a diffusion chamber adjacent to the reflective cool down chamber.
  • a further embodiment of the present disclosure may include, wherein the diffusion chamber is an electron beam physical vapor deposition (EB PVD).
  • EB PVD electron beam physical vapor deposition
  • a method of coating a workpiece according to one disclosed non-limiting embodiment of the present disclosure can include moving a workpiece holder from a deposition chamber to a reflective cool down chamber with at least one arcuate wall; and directing infrared energy from an infrared lamp at the arcuate wall to reduce a temperature gradient of a workpiece.
  • a further embodiment of the present disclosure may include directing the infrared energy for 3-10 seconds.
  • a further embodiment of the present disclosure may include diffusing the infrared energy.
  • a further embodiment of the present disclosure may include locating the infrared lamp on a door of the reflective cool down chamber.
  • a further embodiment of the present disclosure may include, wherein the diffusion chamber is an electron beam physical vapor deposition (EB PVD).
  • EB PVD electron beam physical vapor deposition
  • a further embodiment of the present disclosure may include operating the infrared energy for a time in response to a thermal mass of the workpiece.
  • Figure 1 schematically illustrates an example system 20 for depositing coating on workpieces 22 in the interior 24 of a deposition chamber 26.
  • the system 20 passes the workpiece 22 downstream along a workpiece flowpath sequentially through a first load lock chamber 28 forming an in-feed chamber, a preheat chamber 30, the deposition chamber 26, a cool down chamber 34, and a second load lock chamber 36.
  • Each of a multiple of workpieces 22 may be conveyed through the system on a workpiece holder 40 which, depending upon implementation, may support a single workpiece or multiple workpieces.
  • the workpiece holder 40 may be manipulated by a sting mechanism 42.
  • a loading station 50 and an unloading station 52 are provided. These may include robots (e.g., six-axis industrial robots) to transfer fixture workpieces from and to conveyors, pallets, and the like.
  • the sting mechanism 42 is withdrawn back through the preheat chamber 30 into the first load lock chamber 28, such that the workpieces may be removed from the deposition chamber 26.
  • the exemplary deposition chamber 26 is configured for electron beam physical vapor deposition (EB-PVD).
  • EB electron beam physical vapor deposition
  • at least one electron beam (EB) gun 60 is positioned to direct its beam to one or more deposition material ingots 70, 72.
  • the ingots may be ceramics of different composition for forming distinct layers in a thermal barrier coating, erosion coating, abradable coating, or abrasive coating.
  • Zirconia-based ingot examples include, but are not limited to, an yttria-stabilized zirconia (YSZ) such as 7YSZ, a gadolinia-stabilized zirconia, or an YSZ of different yttria content or dopant.
  • YSZ yttria-stabilized zirconia
  • 7YSZ a gadolinia-stabilized zirconia
  • YSZ yttria-stabilized zirconia
  • the reflective cool down chamber 34 provides a reflective chamber that includes an arcuate wall 100 and one or more infrared lamps 102 that have diffusing lenses 104 such that the reflective cool down chamber 34 forms an ovid-like shape.
  • the infrared lamps 102 may, for example, be located on a movable door 108 that permits entry and/or egress of the workpiece holder 40. The exact size and shape may be optimized such that the workpieces are cooled down slowly and uniformly.
  • An interior surface 106 of the arcuate wall 100 provides a high index of reflection, e.g., mirror polish aluminum, stainless steel, etc.
  • the cooling workpiece dissipates heat primarily through radiation and the reflective arcuate wall 100 of the reflective cool down chamber 34 reflects radiation back to the workpieces, thereby reducing the cooling rate.
  • the infrared lamps 102 may be located on movable doors 108 that permit intake and egress of the workpiece holder 40.
  • the infrared lamps 102 increase heat to make up for heat loss to the interior surface 106 of the arcuate wall 100 and also reduce the cooling rate.
  • the orientation of the infrared lamps 102 is configured to uniformly distribute heat to the workpieces. Thus, temperature gradients in the workpiece are significantly reduced.
  • the diffusing lenses 104 facilitate diffusion of the radiation in a suitably wide cone to permit uniform heating.
  • the reflective cool down chamber 34 and infrared lamps 102 may be used in conjunction with various existing coaters.
  • the infrared lamps 102 can be turned on and off quickly, unlike a heating oven that requires a relatively long time to heat up and cool down.
  • the reflective cool down chamber 34 is adjacent to the deposition chamber 26 such that after the coating process is complete (step 206), the door 108 opens (step 202) such that the workpieces, which are supported by workpiece holder 40, are moved from the deposition chamber 26 to the reflective cool down chamber 34 (step 204).
  • the movable doors 108 are then closed and the infrared lamps 102 are activated (step 206).
  • the infrared lamps 102 may be activated for about 3-10 seconds such that the infrared energy is provided in response to a thermal mass of the workpiece.
  • the workpieces are then cooled within the reflective cool down chamber 34 at a suitable rate, to prevent spallation.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

A coating system including a reflective cool down chamber (34) with at least one arcuate wall (100); and an infrared lamp (102) directed at the arcuate wall.

Description

    BACKGROUND
  • The present disclosure relates to a system for thermal barrier coatings (TBCs), and more particularly, to thermal control therein.
  • Thermal barrier coatings (TBCs) are multilayer materials that are typically applied to hot sections of an engine to reduce the surface temperature experienced by workpieces. TBCs often include (1) a substrate, which may be an engine workpiece-typically a gamma-gamma prime superalloy (2) an aluminum rich bond coat (3) thermally grown oxide (TGO) that reduce further oxidation of bond coat by blocking oxygen (4) a low thermal conductivity ceramic top coat.
  • One of the fabrication methods for top coat is electron beam-physical vapor deposition (EB-PVD) in which a columnar top coat microstructure develops on the surface of the workpieces in near vacuum at elevated temperatures. EB-PVD is a form of physical vapor deposition in which an ingot of material is bombarded with an electron beam given off by a charged tungsten filament under high vacuum. The electron beam causes atoms from the ingot to transform into the gaseous phase. These atoms then condense into solid form, coating the workpiece in the vacuum chamber, and within a line of sight, with a thin layer of the material.
  • To reduce the thermal shock between the ceramic top coat and the metallic bond coat post top coating, workpieces are slowly cooled down to room temperature in a preheated oven. The aforementioned method of cool down may be time consuming and not cost effective.
  • SUMMARY
  • A coating system according to one disclosed non-limiting embodiment of the present disclosure can include a reflective cool down chamber with at least one arcuate wall and an infrared lamp directed at the arcuate wall.
  • A further embodiment of the present disclosure may include wherein the at least one arcuate wall includes an interior surface with a high index of reflection.
  • A further embodiment of the present disclosure may include wherein the at least one arcuate wall includes an interior surface with a mirror finish.
  • A further embodiment of the present disclosure may include, wherein the infrared lamp is located on a movable door that permits intake of a workpiece holder.
  • A further embodiment of the present disclosure may include, wherein the infrared lamp is located on a movable door that permits egress of a workpiece holder.
  • A further embodiment of the present disclosure may include a diffusion lens mounted to the infrared lamp.
  • A further embodiment of the present disclosure may include a diffusion chamber adjacent to the reflective cool down chamber.
  • A further embodiment of the present disclosure may include, wherein the diffusion chamber is an electron beam physical vapor deposition (EB PVD).
  • A method of coating a workpiece according to one disclosed non-limiting embodiment of the present disclosure can include moving a workpiece holder from a deposition chamber to a reflective cool down chamber with at least one arcuate wall; and directing infrared energy from an infrared lamp at the arcuate wall to reduce a temperature gradient of a workpiece.
  • A further embodiment of the present disclosure may include directing the infrared energy for 3-10 seconds.
  • A further embodiment of the present disclosure may include diffusing the infrared energy.
  • A further embodiment of the present disclosure may include locating the infrared lamp on a door of the reflective cool down chamber.
  • A further embodiment of the present disclosure may include, wherein the diffusion chamber is an electron beam physical vapor deposition (EB PVD).
  • A further embodiment of the present disclosure may include operating the infrared energy for a time in response to a thermal mass of the workpiece.
  • The foregoing features and elements may be combined in various combinations without exclusivity, unless expressly indicated otherwise. These features and elements as well as the operation thereof will become more apparent in light of the following description and the accompanying drawings. It should be understood, however, the following description and drawings are intended to be exemplary in nature and non-limiting.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • Various features will become apparent to those skilled in the art from the following detailed description of the disclosed non-limiting embodiment. The drawings that accompany the detailed description can be briefly described as follows:
    • Figure 1 is a partial schematic view of a deposition system; and
    • Figure 2 is a schematic view a reflective cool down chamber.
    • Figure 3 is a schematic view of the reflective cool down chamber operation.
    DETAILED DESCRIPTION
  • Figure 1 schematically illustrates an example system 20 for depositing coating on workpieces 22 in the interior 24 of a deposition chamber 26. The system 20 passes the workpiece 22 downstream along a workpiece flowpath sequentially through a first load lock chamber 28 forming an in-feed chamber, a preheat chamber 30, the deposition chamber 26, a cool down chamber 34, and a second load lock chamber 36.
  • Each of a multiple of workpieces 22 may be conveyed through the system on a workpiece holder 40 which, depending upon implementation, may support a single workpiece or multiple workpieces. In the deposition chamber 26, the workpiece holder 40 may be manipulated by a sting mechanism 42. In one embodiment, a loading station 50 and an unloading station 52 are provided. These may include robots (e.g., six-axis industrial robots) to transfer fixture workpieces from and to conveyors, pallets, and the like.
  • After deposition is complete, the sting mechanism 42 is withdrawn back through the preheat chamber 30 into the first load lock chamber 28, such that the workpieces may be removed from the deposition chamber 26.
  • The exemplary deposition chamber 26 is configured for electron beam physical vapor deposition (EB-PVD). In this example, at least one electron beam (EB) gun 60 is positioned to direct its beam to one or more deposition material ingots 70, 72. In this example, there are two ingots 70, 72 of different materials. The ingots may be ceramics of different composition for forming distinct layers in a thermal barrier coating, erosion coating, abradable coating, or abrasive coating. For example, Zirconia-based ingot examples include, but are not limited to, an yttria-stabilized zirconia (YSZ) such as 7YSZ, a gadolinia-stabilized zirconia, or an YSZ of different yttria content or dopant.
  • With reference to Figure 2, in one exemplary implementation, the reflective cool down chamber 34 provides a reflective chamber that includes an arcuate wall 100 and one or more infrared lamps 102 that have diffusing lenses 104 such that the reflective cool down chamber 34 forms an ovid-like shape. The infrared lamps 102 may, for example, be located on a movable door 108 that permits entry and/or egress of the workpiece holder 40. The exact size and shape may be optimized such that the workpieces are cooled down slowly and uniformly. An interior surface 106 of the arcuate wall 100 provides a high index of reflection, e.g., mirror polish aluminum, stainless steel, etc. The cooling workpiece dissipates heat primarily through radiation and the reflective arcuate wall 100 of the reflective cool down chamber 34 reflects radiation back to the workpieces, thereby reducing the cooling rate.
  • The infrared lamps 102 may be located on movable doors 108 that permit intake and egress of the workpiece holder 40. The infrared lamps 102 increase heat to make up for heat loss to the interior surface 106 of the arcuate wall 100 and also reduce the cooling rate. The orientation of the infrared lamps 102 is configured to uniformly distribute heat to the workpieces. Thus, temperature gradients in the workpiece are significantly reduced.
  • The diffusing lenses 104 facilitate diffusion of the radiation in a suitably wide cone to permit uniform heating. The reflective cool down chamber 34 and infrared lamps 102 may be used in conjunction with various existing coaters. The infrared lamps 102 can be turned on and off quickly, unlike a heating oven that requires a relatively long time to heat up and cool down.
  • With reference to Figure 3, the reflective cool down chamber 34 is adjacent to the deposition chamber 26 such that after the coating process is complete (step 206), the door 108 opens (step 202) such that the workpieces, which are supported by workpiece holder 40, are moved from the deposition chamber 26 to the reflective cool down chamber 34 (step 204). The movable doors 108 are then closed and the infrared lamps 102 are activated (step 206). In one example, the infrared lamps 102 may be activated for about 3-10 seconds such that the infrared energy is provided in response to a thermal mass of the workpiece. The workpieces are then cooled within the reflective cool down chamber 34 at a suitable rate, to prevent spallation.
  • The use of the terms "a," "an," "the," and similar references in the context of description (especially in the context of the following claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or specifically contradicted by context. The modifier "about" used in connection with a quantity is inclusive of the stated value and has the meaning dictated by the context (e.g., it includes the degree of error associated with measurement of the particular quantity). All ranges disclosed herein are inclusive of the endpoints, and the endpoints are independently combinable with each other.
  • Although the different non-limiting embodiments have specific illustrated components, the embodiments of this invention are not limited to those particular combinations. It is possible to use some of the components or features from any of the non-limiting embodiments in combination with features or components from any of the other non-limiting embodiments.
  • It should be appreciated that like reference numerals identify corresponding or similar elements throughout the several drawings. It should also be appreciated that although a workpiece component arrangement is disclosed in the illustrated embodiment, other arrangements will benefit herefrom.
  • Although particular step sequences are shown, described, and claimed, it should be understood that steps may be performed in any order, separated or combined unless otherwise indicated and will still benefit from the present disclosure.
  • The foregoing description is exemplary rather than defined by the limitations within. Various non-limiting embodiments are disclosed herein, however, one of ordinary skill in the art would recognize that various modifications and variations in light of the above teachings will fall within the scope of the appended claims. It is therefore to be understood that within the scope of the appended claims, the disclosure may be practiced other than as specifically described. For that reason the appended claims should be studied to determine true scope and content.

Claims (13)

  1. A coating system, comprising:
    a reflective cool down chamber (34) with at least one arcuate wall (100); and an infrared lamp (102) directed at the arcuate wall.
  2. The system as claimed in claim 1, wherein the at least one arcuate wall (100) includes an interior surface (106) with a high index of reflection.
  3. The system as claimed in claim 1 or 2, wherein the at least one arcuate wall (100) includes an interior surface (106) with a mirror finish.
  4. The system as claimed in claim 1, 2 or 3, wherein the infrared lamp (102) is located on a movable door (108) that permits intake of a workpiece holder (40).
  5. The system as claimed in any preceding claim, wherein the infrared lamp (102) is located on a movable door (108) that permits egress of a workpiece holder (40).
  6. The system as claimed in any preceding claim, further comprising a diffusion lens (104) mounted to the infrared lamp (102).
  7. The system as claimed in any preceding claim, further comprising a diffusion chamber adjacent to the reflective cool down chamber (34).
  8. A method of coating a workpiece, comprising:
    moving a workpiece holder (40) from a deposition chamber (26) to a reflective cool down chamber (34) with at least one arcuate wall (100); and
    directing infrared energy from an infrared lamp (102) at the arcuate wall to reduce a temperature gradient of a workpiece.
  9. The method as claimed in claim 8, further comprising directing the infrared energy for 3-10 seconds.
  10. The method as claimed in claim 8 or 9, further comprising diffusing the infrared energy.
  11. The method as claimed in claim 8, 9 or 10, further comprising locating the infrared lamp (102) on a door (108) of the reflective cool down chamber (34).
  12. The method as claimed in any of claims 8 to 11, wherein the deposition chamber (26) is an electron beam physical vapor deposition (EB-PVD).
  13. The method as claimed in any of claims 8 to 12, further comprising operating the infrared energy for a time in response to a thermal mass of the workpiece.
EP17154312.7A 2016-02-03 2017-02-02 System and method for low thermal shock-fast cooling of thermal barrier coating Active EP3284844B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US15/014,232 US20170218505A1 (en) 2016-02-03 2016-02-03 System and Method for Low Thermal Shock-Fast Cooling of Thermal Barrier Coating

Publications (2)

Publication Number Publication Date
EP3284844A1 true EP3284844A1 (en) 2018-02-21
EP3284844B1 EP3284844B1 (en) 2020-04-01

Family

ID=58192050

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17154312.7A Active EP3284844B1 (en) 2016-02-03 2017-02-02 System and method for low thermal shock-fast cooling of thermal barrier coating

Country Status (2)

Country Link
US (2) US20170218505A1 (en)
EP (1) EP3284844B1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19908387A1 (en) * 1998-03-02 1999-09-09 Behr Labortechnik Heating samples in an analytical oven with focussed radiation
US20010015746A1 (en) * 2000-02-17 2001-08-23 Hisasi Yosimura Ink drier and ink jet type image forming apparatus mounting the same
EP1791989A1 (en) * 2004-08-26 2007-06-06 Honeywell International Inc. Chromium and active elements modified platinum aluminide coatings
CN202238582U (en) * 2011-11-23 2012-05-30 深圳市雷巴环保材料有限公司 Infrared drier

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE439129B (en) * 1983-10-05 1985-06-03 Lennart Wictorin SET AND DEVICE FOR ASTADMATIC POINT HEATING OF A BODY, PARTICULAR TO CARRY OUT THE STAR OF GOLD MOLDING
JPH06102826B2 (en) 1985-11-08 1994-12-14 松下電器産業株式会社 Thin film manufacturing equipment
US5099586A (en) * 1989-09-08 1992-03-31 W. R. Grace & Co.-Conn. Reflector assembly for heating a substrate
DE19537092C1 (en) * 1995-10-05 1996-07-11 Ardenne Anlagentech Gmbh Multi-chamber electron beam vapour deposition unit
US5897921A (en) 1997-01-24 1999-04-27 General Electric Company Directionally solidified thermal barrier coating
US6946034B1 (en) 1999-08-04 2005-09-20 General Electric Company Electron beam physical vapor deposition apparatus
UA71572C2 (en) 1999-08-04 2004-12-15 Дженерал Електрік Компані An electron beam physical vapor deposition apparatus for application of coating on articles
US6770333B2 (en) 2002-04-30 2004-08-03 General Electric Company Method of controlling temperature during coating deposition by EBPVD
US7196460B2 (en) * 2004-07-01 2007-03-27 Osram Sylvania Inc. Incandescent reflector heat lamp with uniform irradiance
CA2582312C (en) * 2006-05-05 2014-05-13 Sulzer Metco Ag A method for the manufacture of a coating
US8350180B2 (en) 2010-03-12 2013-01-08 United Technologies Corporation High pressure pre-oxidation for deposition of thermal barrier coating with hood
US8328945B2 (en) 2010-03-12 2012-12-11 United Technologies Corporation Coating apparatus and method with indirect thermal stabilization
US9187815B2 (en) 2010-03-12 2015-11-17 United Technologies Corporation Thermal stabilization of coating material vapor stream

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19908387A1 (en) * 1998-03-02 1999-09-09 Behr Labortechnik Heating samples in an analytical oven with focussed radiation
US20010015746A1 (en) * 2000-02-17 2001-08-23 Hisasi Yosimura Ink drier and ink jet type image forming apparatus mounting the same
EP1791989A1 (en) * 2004-08-26 2007-06-06 Honeywell International Inc. Chromium and active elements modified platinum aluminide coatings
CN202238582U (en) * 2011-11-23 2012-05-30 深圳市雷巴环保材料有限公司 Infrared drier

Also Published As

Publication number Publication date
US20170218505A1 (en) 2017-08-03
EP3284844B1 (en) 2020-04-01
US20200318231A1 (en) 2020-10-08
US10995402B2 (en) 2021-05-04

Similar Documents

Publication Publication Date Title
Feuerstein et al. Technical and economical aspects of current thermal barrier coating systems for gas turbine engines by thermal spray and EBPVD: a review
Sohn et al. Microstructural development in physical vapour-deposited partially stabilized zirconia thermal barrier coatings
EP1013795A1 (en) Method for applying improved durability thermal barrier coatings
US20120231211A1 (en) Method for the manufacture of a thermal barrier coating structure
EP2506980B1 (en) Coating methods and apparatus
US6620465B2 (en) Physical properties of thermal barrier coatings using electron beam-physical vapor deposition
US6923868B2 (en) Installation for electron-ray coatication of coatings
US8404047B2 (en) Electron beam vapor deposition apparatus and method
Lin et al. Development of thermal barrier coatings using reactive pulsed dc magnetron sputtering for thermal protection of titanium alloys
JP2003522294A (en) Electron beam physical vapor deposition coating apparatus and method
KR20000011701A (en) Article having a durable ceramic coating and apparatus and method for making the article
US20140193760A1 (en) Coated article, process of coating an article, and method of using a coated article
EP2236642A1 (en) Controlled oxidation of bond coat
US8350180B2 (en) High pressure pre-oxidation for deposition of thermal barrier coating with hood
US10995402B2 (en) System and method for low thermal shock-fast cooling of thermal barrier coating
US6342278B1 (en) Method for forming a thermal barrier coating by electron beam physical vapor deposition
EP3159430B1 (en) Method of forming a multi-layered coating with columnar microstructure and branched columnar microstructure
US11542593B2 (en) Nanoparticle formation mitigation in a deposition process
US20030118873A1 (en) Stabilized zirconia thermal barrier coating with hafnia
US20190040525A1 (en) Physical vapor deposition using rotational speed selected with respect to deposition rate
EP3159429A1 (en) Multi-layered coating with columnar microstructure and branched columnar microstructure
EP3106538B1 (en) Uniform thickness thermal barrier coating for non line of sight and line of sight areas
JP2003506574A (en) Electron beam physical vapor deposition coating apparatus and crucible for the apparatus

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20181116

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20190423

GRAJ Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted

Free format text: ORIGINAL CODE: EPIDOSDIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTC Intention to grant announced (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20191017

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1251421

Country of ref document: AT

Kind code of ref document: T

Effective date: 20200415

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602017013795

Country of ref document: DE

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200701

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20200401

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200701

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200817

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200702

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200801

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1251421

Country of ref document: AT

Kind code of ref document: T

Effective date: 20200401

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602017013795

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

26N No opposition filed

Effective date: 20210112

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20210228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210228

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210202

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210202

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210228

REG Reference to a national code

Ref country code: DE

Ref legal event code: R081

Ref document number: 602017013795

Country of ref document: DE

Owner name: RAYTHEON TECHNOLOGIES CORPORATION (N.D.GES.D.S, US

Free format text: FORMER OWNER: UNITED TECHNOLOGIES CORPORATION, FARMINGTON, CONN., US

Ref country code: DE

Ref legal event code: R081

Ref document number: 602017013795

Country of ref document: DE

Owner name: RTX CORPORATION (N.D.GES.D. STAATES DELAWARE),, US

Free format text: FORMER OWNER: UNITED TECHNOLOGIES CORPORATION, FARMINGTON, CONN., US

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230520

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20170202

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

REG Reference to a national code

Ref country code: DE

Ref legal event code: R081

Ref document number: 602017013795

Country of ref document: DE

Owner name: RTX CORPORATION (N.D.GES.D. STAATES DELAWARE),, US

Free format text: FORMER OWNER: RAYTHEON TECHNOLOGIES CORPORATION (N.D.GES.D.STAATES DELAWARE), ARLINGTON, VA, US

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200401

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20260122

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20260121

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20260121

Year of fee payment: 10