EP3174967A1 - Hard surface cleaning composition - Google Patents

Hard surface cleaning composition

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Publication number
EP3174967A1
EP3174967A1 EP15734190.0A EP15734190A EP3174967A1 EP 3174967 A1 EP3174967 A1 EP 3174967A1 EP 15734190 A EP15734190 A EP 15734190A EP 3174967 A1 EP3174967 A1 EP 3174967A1
Authority
EP
European Patent Office
Prior art keywords
composition
cleaning
abrasive
water
absorbent material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP15734190.0A
Other languages
German (de)
French (fr)
Other versions
EP3174967B1 (en
Inventor
Punam Bandyopadhyay
Kingshuk Dutta
Suresh Murigeppa NADAKATTI
Paolo Mondani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP3174967A1 publication Critical patent/EP3174967A1/en
Application granted granted Critical
Publication of EP3174967B1 publication Critical patent/EP3174967B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1233—Carbonates, e.g. calcite or dolomite
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions

Definitions

  • the present invention is in the field of hard surface cleaning compositions; in particular cleaning compositions that can be used to clean hard surfaces without the use of water.
  • One way of saving water is to reuse the water and another way is to reduce the amount of water being used.
  • Washing processes including laundry, dishwashing and other household cleaning processes, require large amounts of water throughout the world. These are daily chores in which the use of water and a detergent cannot be avoided.
  • WO 2014/075845 discloses a granular composition with an improved cleaning efficiency comprising a polyacrylic acid based swellable polymer, cellulose fibre and water, which is suitable for use in a cleaning method which requires little or no added water.
  • the composition is majorly comprised of organic materials which is not economical.
  • WO0068349A1 discloses detergent bars containing 5 to 40 % surfactant, 10 to 85 % abrasive materials, comprising aluminium oxide which has Moh ' s hardness of 8 to 9.5 and absorbent which preferably is silica gel or precipitated or spray-dried silica.
  • the invention also provides a process for cleaning dishes and cooking utensils which involves the step of applying thereto a cleaning composition described above. Ail the exemplified compositions have about 12 wt% water,
  • US4615821 A discloses powdered abrasive cleanser composition having 0.1 to 6 wt% surfactant, 0.5 to 40 wt% benzyl alcohol, 20 to 95 wt% water-insoluble abrasive material and 1 to 50 wt% detergency builder.
  • the exemplified composition has 3.1 wt% water.
  • cleaning effect is attributed to the presence of benzyl alcohol.
  • a hard surface cleaning composition for cleaning hard surfaces without the use of water may be obtained by a combination of an inorganic absorbent material having a surface area of more than 50m 2 /g and an abrasive having a Mohs' hardness of more than 3 when present in a ratio of between 1 :2 and 1 :20.
  • the present invention provides a hard surface cleaning composition
  • a hard surface cleaning composition comprising 0.1 to 50% by weight of a surfactant, 2 to 35% by weight of an inorganic absorbent material having a surface area of more than 50m 2 /g and 33 to 96% by weight of an abrasive having a Mohs' index of more than 3, wherein the ratio of the inorganic absorbent material to the abrasive is between 1 :2 to 1 :20.
  • the invention provides a process for cleaning a hard surface without the use of water comprising the steps of applying onto the hard surface a composition according to the invention, scrubbing the hard surface, dusting off the composition using hands and optionally wiping the hard surface with a wet cloth.
  • the invention provides use of a composition according to the invention for cleaning hard surfaces without using water.
  • the invention in a first aspect, relates to a hard surface cleaning composition
  • a hard surface cleaning composition comprising a surfactant, an inorganic absorbent material and an abrasive.
  • composition according to the invention comprises one or more surfactants that are generally selected from anionic, non-ionic, cationic, zwitterionic or amphoteric surfactants.
  • Suitable classes of anionic surfactants are water-soluble salts of organic sulphuric acid mono-esters and sulphonic acids having in the molecular structure a branched or straight chain alkyl group containing 8 to 22 carbon atoms or an alkylaryl group containing 6 to 20 carbon atoms in the alkyl part.
  • anionic surfactants water soluble salts of:
  • PAS alcohol sulphates
  • fatty alcohols produced from tallow or coconut oil or the synthetic alcohols derived from petroleum especially those obtained by sulphating the fatty alcohols produced from tallow or coconut oil or the synthetic alcohols derived from petroleum
  • alkylbenzene-sulphonates such as those in which the alkyl group contains from 6 to 20 carbon atoms
  • alkylglyceryl ether sulphates especially of the ethers of fatty alcohols derived from tallow and coconut oil;
  • alkylphenol ethylenoxy-ether sulphates with from 1 to 8 ethyleneoxy units per molecule and in which the alkyl groups contain from 4 to 14 carbon atoms; - the reaction product of fatty acids esterified with isethionic acid and neutralised with alkali; and
  • carboxylic acids from 8-18 carbon chain length.
  • a suitable class of nonionic surfactants can be broadly described as compounds produced by the condensation of simple alkylene oxides, which are hydrophilic in nature, with an aliphatic or alkyl-aromatic hydrophobic compound having a reactive hydrogen atom.
  • the length of the hydrophilic or polyoxyalkylene chain which is attached to any particular hydrophobic group can be readily adjusted to yield a compound having the desired balance between hydrophilic and hydrophobic elements. This enables the choice of nonionic surfactants with the right HLB.
  • Particular examples include:
  • condensation products of aliphatic alcohols having from 8 to 22 carbon atoms in either straight or branched chain configuration with ethylene oxide such as a coconut alcohol/ethylene oxide condensates having from 2 to 15 moles of ethylene oxide per mole of coconut alcohol;
  • nonionic surfactants are:
  • alkyl polyglycosides which are condensation products of long chain aliphatic alcohols and saccharides
  • tertiary amine oxides of structure RRRNO where one R is an alkyl group of 8 to 20 carbon atoms and the other R's are each alkyl or hydroxyalkyl groups of 1 to 3 carbon atoms, e.g. dimethyldodecylamine oxide;
  • RRRPO - tertiary phosphine oxides of structure RRRPO, where one R is an alkyl group of
  • R's are each alkyl or hydroxyalkyl groups of 1 to 3 carbon atoms, for instance dimethyl-dodecylphosphine oxide;
  • fatty acid alkylolamides such as the ethanol amides
  • alkyl mercaptans A specific group of surfactants are the tertiary amines obtained by condensation of ethylene and/or propylene oxide with long chain aliphatic amines. The compounds behave like nonionic surfactants in alkaline medium and like cationic surfactants in acid medium.
  • Suitable amphoteric surfactants include derivatives of aliphatic secondary and tertiary amines containing an alkyl group of 8 to 18 carbon atoms and an aliphatic radical substituted by an anionic water-solubilizing group, such as sodium 3-dodecylamino- propionate, sodium 3-dodecylaminopropane sulphonate and sodium N-2- hydroxydodecyl-N-methyltaurate.
  • Suitable cationic surfactants are quaternary ammonium salts according to the present invention are quaternary ammonium salts characterised in that the ammonium salt has the general formula: R-i R2R3R 4 N + X " , wherein Ri is a C12-C18 alkyl group, each of R2, R3 and R 4 independently is a C1-C3 alkyl group and X is an inorganic anion. Ri is preferably a Ci 4 -Ci6 straight chain alkyl group, more preferably C16. R2-R 4 are preferably methyl groups.
  • the inorganic anion is preferably chosen from halide, sulphate, bisulphate or OH " .
  • a quaternary ammonium hydroxide is considered to be a quaternary ammonium salt. More preferably the anion is a halide ion or sulphate, most preferably a chloride, bromide or sulphate. Cetyl-trimethylammonium bromide is a specific example of a suitable compound and commercially abundantly available.
  • quaternary ammonium cationic surfactant is the class of benzalkonium halides, also known as alkyldimethylbenzylammonium halides.
  • the most common type being benzalkonium chloride, also known as alkyldimethylbenzylammonium chloride (or ADBAC).
  • a preferred class of bezalkonium chlorides is given in the formula below.
  • n 8, 10, 12, 14, 16, 18
  • Suitable zwitterionic surfactants include derivatives of aliphatic quaternary ammonium, sulphonium and phosphonium compounds having an aliphatic radical of from 8 to 18 carbon atoms and an aliphatic radical substituted by an anionic water-solubilising group, for instance 3-(N-N-dimethyl-N-hexadecylammonium) propane-1 -sulphonate betaine, 3-(dodecylmethyl sulphonium) propane-1 -sulphonate betaine and 3- (cetylmethylphosphonium) ethane sulphonate betaine.
  • anionic water-solubilising group for instance 3-(N-N-dimethyl-N-hexadecylammonium) propane-1 -sulphonate betaine, 3-(dodecylmethyl sulphonium) propane-1 -sulphonate betaine and 3- (cetylmethylphosphonium) ethane sulphonate betaine.
  • betaines include alkylamidopropyl betaines wherein the alkylamido group is derived from coconut oil fatty acids.
  • suitable surfactants are compounds commonly used as surface- active agents given in the well-known textbooks like "Surface Active Agents” Vol. 1 , by Schwartz & Perry, Interscience 1949, Vol. 2 by Schwartz, Perry & Berch, Interscience 1958, and/or the current edition of "McCutcheon's Emulsifiers and Detergents” published by Manufacturing Confectioners Company or in "Tenside-Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Verlag, 1981 .
  • the surfactant is present in the composition in a concentration of 0.1 to 50%, preferably not more than 45%, more preferably not more than 40%, still more preferably not more than 35%, even more preferably not more than 30% or even more than 25% but typically not less than 1 %, preferably not less than 2%, more preferably not less than 3%, still more preferably not more than 4% by weight of the total composition.
  • Preferred surfactants of the present invention are sodium linear alkylbenzene sulfonates, sodium dodecyl sulphate, sodium dodecanoate, sodium salt of alpha olefin sulphonate, methyl ester sulfonate, primary alkyl sulphates, sodium
  • dodecylbenzenesulfonate sodium stearate, amine oxides, non-ionic E07, E05, Cetyl trimethylammonium bromide and cetyl trimethylammonium chloride.
  • the most preferred ones are sodium linear alkylbenzene sulfonates, sodium salt of alpha olefin sulphonate, sodium dodecyl sulphate, amine oxides ad non-ionic E07.
  • Inorganic absorbent material sodium linear alkylbenzene sulfonates, sodium salt of alpha olefin sulphonate, sodium dodecyl sulphate, amine oxides ad non-ionic E07.
  • composition according to the invention comprises an inorganic absorbent material having a surface area of more than 50m 2 /g.
  • the inorganic absorbent material is selected from the group of materials with high BET (Brunauer, Emmett and Teller) surface area. It is preferred that the surface area of the inorganic absorbent material is between 50 and 1500 m 2 /g, more preferably between 80 and 1000 m 2 /g, still more preferably between 100 and 800 m 2 /g and even more preferably between 150 and 500 m 2 /g.
  • BET Brunauer, Emmett and Teller
  • suitable inorganic absorbent materials include precipitated silica, fumed silica, alumina, titanium dioxide, zinc oxide, clays such as montmorillonite, bentonite, kaolinite/china clay, layered double hydroxides, activated carbon, calcium carbonate, apatites and calcium oxides/hydroxides, having a surface area of more than 50m 2 /g.
  • the preferred inorganic absorbent materials of the invention are fumed silica, alumina, bentonite clay, titanium dioxide and activated charcoal, having a surface area of more than 50m 2 /g.
  • the inorganic absorbent material is present in the composition in a concentration of 2 to 35%, preferably not more than 30%, more preferably not more than 25%, still more preferably not more than 20% but typically not less than 4%, more preferably not less than 6%, still more preferably not less than 7% by weight of the total composition.
  • composition according to the invention comprises an abrasive having a Mohs' hardness of between 3 and 7.
  • Mohs' hardness is a scale classifying the relative hardness of minerals on a scale of 1 to 10. The complete scale is given in textbooks like "Novel and Traditional Fillers for Plastics: Technology and Market Developments" by Geoffrey Pritchard, Rapra
  • Mohs' hardness of the abrasive according to the present invention is preferably between 3 and 7. This includes all the abrasives from calcite (Mohs' hardness of 3) and upwards on the scale.
  • the abrasive may be soluble or insoluble in water.
  • Water soluble abrasives when used may be present in such excess to any water present in the composition so that the solubility of the abrasive in the aqueous phase is exceeded and consequently the abrasive exists in the composition.
  • the volume average particle size of the abrasive is between 0.5 and 400 ⁇ , preferably between 10 and 200 ⁇ .
  • the span is between 2 and 5; and wherein the span is defined as the broadness or width in particle distribution between a 10% limit (D10) and a 90% limit (D90) divided by the mean particle diameter (D50), whereby 10% by volume of the particles have a diameter below the 10% limit and 10% by volume of the particles have a diameter above the 90% limit.
  • the preferred abrasives include feldspar, silica, dolomite, calcite, synthetic aluminium oxide, amalgam, anatase, apatite, cuttlebone, diopside, enamel, enstatite, fluorite, glass bead, glass, hematite, kyanite, magnetite, olivine, orthoclase, petalite, porcelain, feldspathic , pyrite, pumice, quartz (silica sand), spodumene, titanium dioxide, particulate zeolites, silicates, other carbonates, bicarbonates, borates and sulphates.
  • abrasives examples include feldspar, synthetic aluminium oxide, dolomite and calcite.
  • the abrasive is present in the composition in a concentration of 33 to 96%, preferably not more than 90%, more preferably not more 85% but typically not less than 35%, more preferably not less than 40%, still more preferably not less than 45%, even more preferably not less than 50% or even not less than 60% by weight of the total composition.
  • the inorganic absorbent material with the high surface area quickly starts acting on the oily and/or watery parts to accumulate the soil into its structure and the abrasives help to dislodge the soil from the substrate. Due to the high absorption capacity of the inorganic absorbent material, they form aggregates when pressure is applied which then gets lifted from the surface and carried away swiftly by the action of abrasives, thus resulting in cleaning.
  • a critical ratio of inorganic absorbent material to abrasive is required to achieve the desired cleaning action.
  • the inorganic absorbent material and the abrasive are present in a ratio of between 1 :2 and 1 :20, preferably between 1 :3 and 1 :12 or more preferably between 1 :4 and 1 :10.
  • the skilled person would not follow the ratio of 1 :2, although it falls within the claimed range, because then the abrasive content would fall significantly short of the minimum claimed value.
  • the content of the absorbent is 35 wt%, then the ratio of 1 :20 would lead to an impractical value of 700 wt% of the abrasive.
  • the skilled person would know that the maximum absorbent content is 96 wt% and would then accordingly select a suitable ratio from the claimed range.
  • Water is present in the hard surface cleaning composition of the present invention. Water is in a concentration of less than 2% by weight of the composition.
  • Optional Ingredients are present in the hard surface cleaning composition of the present invention. Water is in a concentration of less than 2% by weight of the composition.
  • compositions according to the invention may contain other ingredients which aid in their cleaning or sensory performance.
  • Compositions according to the invention can also contain, in addition to the ingredients already mentioned, various other optional ingredients such as builders, ash, perfume, colourants, electrolytes, structuring agents, fillers and antimicrobial agents.
  • the invention in a second aspect, relates to a process for cleaning a hard surface without the use of water comprising the steps of applying onto the hard surface a composition according to the invention, scrubbing the hard surface, dusting off the composition using hands; and optionally wiping the hard surface with a wet cloth.
  • the composition may be dusted off using the same scrubbing implement.
  • the invention relates to the use of a composition according to the invention for cleaning hard surfaces without using water.
  • Titanium dioxide MT-600B (ex Tayca Corporation)
  • Titanium dioxide MT-150W (ex Tayca Corporation)
  • each of the sample composition was prepared following the sequence of addition of ingredients as described herein.
  • half of the abrasive material was taken in a mortar and pestle to which surfactant was added. The concoction was ground and mixed for 5 minutes. Then, the required amount of absorbent was added and ground thoroughly for another 10 minutes. Finally, the remaining half of the abrasive was added, ground and mixed for another 5 minutes to get the final powder composition.
  • the LAS acid was pre- neutralized with a stoichiometric amount of base (eg, soda) and catalytic water and added into the mortar and pestle at the specified step.
  • base eg, soda
  • 0.5 g of sunflower oil was spread on a substrate (porcelain plate if not otherwise mentioned, with -8-10 cm radius). 1.25 g of cleaning powder sample was sprinkled on top of it. It was scrubbed with a plastic paper with 10X15 cm 2 dimension for 30 seconds. The soil along with powder was dusted off with the plastic implement itself. The substrate was thereafter set under a hair-dryer for 10 seconds to remove any additional loosely bound particles. A pre-weighed tissue paper was used then to remove the soil left on the substrate. The difference between the initial and final weight of the tissue paper was calculated which equals to the residual amount of soil on each plate. Cleaning of ⁇ 85% is considered to be good.
  • Example 1 Effect of ratio of the inorganic absorbent material and the abrasive on cleaning
  • Ex 1 to Ex 9 comprising the inorganic absorbent material and the abrasive in a ratio within the scope of the invention are compared to C1 to C4 comprising the inorganic absorbent material and the abrasive in a ratio outside the scope of the present invention.
  • the amount of initial oil in this example is 0.5 grams.
  • the table above shows that the desired cleaning of more than 85% is obtained when the inorganic absorbent material and the abrasive is present in a ratio according to the invention.
  • Example 2 Effect of the surface area of the inorganic absorbent material on cleaning
  • inorganic absorbent materials with various surface areas are compared.
  • Ex 10 to Ex 15 are compositions according to the invention comprising an inorganic absorbent material having a surface area of more than 50 m 2 /g and C5 and C6 are comparative compositions comprising an inorganic absorbent material having a surface area of less than 50 m 2 /g.
  • the amount of initial oil in this example is 0.5 grams.
  • Example 3 Effect of Mohs' hardness of the abrasive on cleaning
  • compositions comprising abrasives having a Mohs' hardness according to the invention are compared to C7, a composition comprising an abrasive having a Mohs' hardness outside the scope of the invention.
  • the amount of initial oil in this example is 0.5 grams.
  • Ex 18 to Ex 20 are compositions comprising the surfactant in a concentration according to the invention and C8 and C9 are compositions comprising the surfactant in a concentration outside the scope of the invention.
  • the amount of initial oil in this example is 0.5 grams.
  • the amount of initial oil in this example is 0.5 grams.
  • composition comprises a surfactant selected from anionic, cationic, non-ionic, zwitterionic, sodium salts of carboxylic acids.
  • Example 6 Cleaning performance of the composition according to the invention on different substrates
  • This example illustrates the cleaning performance of the composition according to the invention on different substrates (Ex 28 to Ex 31 ).
  • the amount of initial oil in this example is 0.5 grams.
  • Example 7 Effect of high concentration of the abrasive (when taken alone) on cleaning This example illustrates that cleaning performance of the composition according to the invention (Ex 17A) cannot be achieved even if a high concentration of the abrasive is used alone (C10).
  • the amount of initial oil in this example is 0.5 grams.
  • Three dish-wash compositions were prepared with varying level of water content in them. For precise control over water level, all the ingredients were dried previously in a hot air oven at 85 °C for 6 hours. After that the ingredients were mixed following the sequence of addition mentioned earlier. In this step it was ensured that the moisture content remained ⁇ 0.5% in the prepared compositions.

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Abstract

Disclosed is a hard surface cleaning composition comprising: a) 0.1 to 50% by weight of a surfactant; b) 2 to 35% by weight of an inorganic absorbent material having a surface area of more than 50m2/g; and c) 33 to 96% by weight of an abrasive having a Mohs' hardness of between 3 and 7; wherein the ratio of the inorganic absorbent material to the abrasive is between 1:2 to 1:20 and wherein water is in a concentration of less than 2% by weight of the composition.

Description

HARD SURFACE CLEANING COMPOSITION Field of the invention
The present invention is in the field of hard surface cleaning compositions; in particular cleaning compositions that can be used to clean hard surfaces without the use of water.
Background of the invention
Water is becoming a more and more scarcely available commodity, especially in developing countries, where it is not unusual that people have to walk many kilometres to arrive at a water source. As a result of which, there is an increasing need to save water.
One way of saving water is to reuse the water and another way is to reduce the amount of water being used.
Washing processes, including laundry, dishwashing and other household cleaning processes, require large amounts of water throughout the world. These are daily chores in which the use of water and a detergent cannot be avoided.
The amount of water required for cleaning is entirely dependent on the detergent or the cleaning agent used. Therefore, the use of water can be reduced or controlled based on the detergent or the cleaning agent. WO 2014/075845 discloses a granular composition with an improved cleaning efficiency comprising a polyacrylic acid based swellable polymer, cellulose fibre and water, which is suitable for use in a cleaning method which requires little or no added water. The composition is majorly comprised of organic materials which is not economical.
WO0068349A1 (Unilever) discloses detergent bars containing 5 to 40 % surfactant, 10 to 85 % abrasive materials, comprising aluminium oxide which has Moh's hardness of 8 to 9.5 and absorbent which preferably is silica gel or precipitated or spray-dried silica. The invention also provides a process for cleaning dishes and cooking utensils which involves the step of applying thereto a cleaning composition described above. Ail the exemplified compositions have about 12 wt% water,
US4615821 A [P&G, 1986] discloses powdered abrasive cleanser composition having 0.1 to 6 wt% surfactant, 0.5 to 40 wt% benzyl alcohol, 20 to 95 wt% water-insoluble abrasive material and 1 to 50 wt% detergency builder. The exemplified composition has 3.1 wt% water. In addition, cleaning effect is attributed to the presence of benzyl alcohol.
It is therefore an object of the present invention to provide water saving in household process, especially dish wash processes.
It is another object of the present invention to provide a hard surface cleaning composition that requires less or no water for cleaning. It is yet another object of the present invention to provide a hard surface cleaning composition that removes fatty soils without the use of water.
Surprisingly, it has been found that a hard surface cleaning composition for cleaning hard surfaces without the use of water may be obtained by a combination of an inorganic absorbent material having a surface area of more than 50m2/g and an abrasive having a Mohs' hardness of more than 3 when present in a ratio of between 1 :2 and 1 :20.
Summary of the invention
Accordingly, in a first aspect, the present invention provides a hard surface cleaning composition comprising 0.1 to 50% by weight of a surfactant, 2 to 35% by weight of an inorganic absorbent material having a surface area of more than 50m2/g and 33 to 96% by weight of an abrasive having a Mohs' index of more than 3, wherein the ratio of the inorganic absorbent material to the abrasive is between 1 :2 to 1 :20. In a second aspect, the invention provides a process for cleaning a hard surface without the use of water comprising the steps of applying onto the hard surface a composition according to the invention, scrubbing the hard surface, dusting off the composition using hands and optionally wiping the hard surface with a wet cloth. In a third aspect, the invention provides use of a composition according to the invention for cleaning hard surfaces without using water.
In the context of the present invention, the reference to "hard surface" or "substrate" typically means utensils or kitchenware, kitchen tops, kitchen floors, sinks and platforms, floors and bathrooms. These and other aspects, features and advantages will become apparent to those of ordinary skill in the art from a reading of the following detailed description and the appended claims. For the avoidance of doubt, any feature of one aspect of the present invention may be utilised in any other aspect of the invention. The word "comprising" is intended to mean "including" but not necessarily "consisting of" or "composed of." In other words, the listed steps or options need not be exhaustive. It is noted that the examples given in the description below are intended to clarify the invention and are not intended to limit the invention to those examples per se. Similarly, all percentages are weight/weight percentages unless otherwise indicated. Except in the operating and comparative examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts of material or conditions of reaction, physical properties of materials and/or use are to be understood as modified by the word "about". Numerical ranges expressed in the format "from x to y" are understood to include x and y. When for a specific feature multiple preferred ranges are described in the format "from x to y", it is understood that all ranges combining the different endpoints are also contemplated.
Detailed description of the invention
In a first aspect, the invention relates to a hard surface cleaning composition comprising a surfactant, an inorganic absorbent material and an abrasive.
Surfactants
The composition according to the invention comprises one or more surfactants that are generally selected from anionic, non-ionic, cationic, zwitterionic or amphoteric surfactants.
Suitable classes of anionic surfactants are water-soluble salts of organic sulphuric acid mono-esters and sulphonic acids having in the molecular structure a branched or straight chain alkyl group containing 8 to 22 carbon atoms or an alkylaryl group containing 6 to 20 carbon atoms in the alkyl part.
Examples of such anionic surfactants are water soluble salts of:
- long chain (i.e. 8 to 22 carbon atoms) alcohol sulphates (hereinafter referred to as PAS), especially those obtained by sulphating the fatty alcohols produced from tallow or coconut oil or the synthetic alcohols derived from petroleum; alkylbenzene-sulphonates, such as those in which the alkyl group contains from 6 to 20 carbon atoms; and
- secondary alkanesulphonates.
Also suitable are the salts of:
alkylglyceryl ether sulphates, especially of the ethers of fatty alcohols derived from tallow and coconut oil;
- fatty acid monoglyceride sulphates;
sulphates of ethoxylated aliphatic alcohols containing 1 to 12 ethyleneoxy groups;
alkylphenol ethylenoxy-ether sulphates with from 1 to 8 ethyleneoxy units per molecule and in which the alkyl groups contain from 4 to 14 carbon atoms; - the reaction product of fatty acids esterified with isethionic acid and neutralised with alkali; and
carboxylic acids from 8-18 carbon chain length.
A suitable class of nonionic surfactants can be broadly described as compounds produced by the condensation of simple alkylene oxides, which are hydrophilic in nature, with an aliphatic or alkyl-aromatic hydrophobic compound having a reactive hydrogen atom. The length of the hydrophilic or polyoxyalkylene chain which is attached to any particular hydrophobic group can be readily adjusted to yield a compound having the desired balance between hydrophilic and hydrophobic elements. This enables the choice of nonionic surfactants with the right HLB. Particular examples include:
the condensation products of aliphatic alcohols having from 8 to 22 carbon atoms in either straight or branched chain configuration with ethylene oxide, such as a coconut alcohol/ethylene oxide condensates having from 2 to 15 moles of ethylene oxide per mole of coconut alcohol;
condensates of alkylphenols having C6 to C15 alkyl groups with 5 to 25 moles of ethylene oxide per mole of alkylphenol;
- condensates of the reaction product of ethylene-diamine and propylene oxide with ethylene oxide, the condensates containing from 40 to 80% of ethyleneoxy groups by weight and having a molecular weight of from 5,000 to 1 1 ,000.
Other classes of nonionic surfactants are:
- alkyl polyglycosides, which are condensation products of long chain aliphatic alcohols and saccharides;
tertiary amine oxides of structure RRRNO, where one R is an alkyl group of 8 to 20 carbon atoms and the other R's are each alkyl or hydroxyalkyl groups of 1 to 3 carbon atoms, e.g. dimethyldodecylamine oxide;
- tertiary phosphine oxides of structure RRRPO, where one R is an alkyl group of
8 to 20 carbon atoms and the other R's are each alkyl or hydroxyalkyl groups of 1 to 3 carbon atoms, for instance dimethyl-dodecylphosphine oxide;
dialkyl sulphoxides of structure RRSO where one R is an alkyl group of from 10 to 18 carbon atoms and the other is methyl or ethyl, for instance methyl- tetradecyl sulphoxide;
fatty acid alkylolamides, such as the ethanol amides;
- alkylene oxide condensates of fatty acid alkylolamides;
alkyl mercaptans. A specific group of surfactants are the tertiary amines obtained by condensation of ethylene and/or propylene oxide with long chain aliphatic amines. The compounds behave like nonionic surfactants in alkaline medium and like cationic surfactants in acid medium. Suitable amphoteric surfactants include derivatives of aliphatic secondary and tertiary amines containing an alkyl group of 8 to 18 carbon atoms and an aliphatic radical substituted by an anionic water-solubilizing group, such as sodium 3-dodecylamino- propionate, sodium 3-dodecylaminopropane sulphonate and sodium N-2- hydroxydodecyl-N-methyltaurate.
Suitable cationic surfactants are quaternary ammonium salts according to the present invention are quaternary ammonium salts characterised in that the ammonium salt has the general formula: R-i R2R3R4N+ X", wherein Ri is a C12-C18 alkyl group, each of R2, R3 and R4 independently is a C1-C3 alkyl group and X is an inorganic anion. Ri is preferably a Ci4-Ci6 straight chain alkyl group, more preferably C16. R2-R4 are preferably methyl groups. The inorganic anion is preferably chosen from halide, sulphate, bisulphate or OH". Thus, for the purposes of this invention, a quaternary ammonium hydroxide is considered to be a quaternary ammonium salt. More preferably the anion is a halide ion or sulphate, most preferably a chloride, bromide or sulphate. Cetyl-trimethylammonium bromide is a specific example of a suitable compound and commercially abundantly available.
Another type of quaternary ammonium cationic surfactant is the class of benzalkonium halides, also known as alkyldimethylbenzylammonium halides. The most common type being benzalkonium chloride, also known as alkyldimethylbenzylammonium chloride (or ADBAC). A preferred class of bezalkonium chlorides is given in the formula below.
n = 8, 10, 12, 14, 16, 18
Suitable zwitterionic surfactants include derivatives of aliphatic quaternary ammonium, sulphonium and phosphonium compounds having an aliphatic radical of from 8 to 18 carbon atoms and an aliphatic radical substituted by an anionic water-solubilising group, for instance 3-(N-N-dimethyl-N-hexadecylammonium) propane-1 -sulphonate betaine, 3-(dodecylmethyl sulphonium) propane-1 -sulphonate betaine and 3- (cetylmethylphosphonium) ethane sulphonate betaine. Other betaines include alkylamidopropyl betaines wherein the alkylamido group is derived from coconut oil fatty acids. Further examples of suitable surfactants are compounds commonly used as surface- active agents given in the well-known textbooks like "Surface Active Agents" Vol. 1 , by Schwartz & Perry, Interscience 1949, Vol. 2 by Schwartz, Perry & Berch, Interscience 1958, and/or the current edition of "McCutcheon's Emulsifiers and Detergents" published by Manufacturing Confectioners Company or in "Tenside-Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Verlag, 1981 .
The surfactant is present in the composition in a concentration of 0.1 to 50%, preferably not more than 45%, more preferably not more than 40%, still more preferably not more than 35%, even more preferably not more than 30% or even more than 25% but typically not less than 1 %, preferably not less than 2%, more preferably not less than 3%, still more preferably not more than 4% by weight of the total composition.
Preferred surfactants of the present invention are sodium linear alkylbenzene sulfonates, sodium dodecyl sulphate, sodium dodecanoate, sodium salt of alpha olefin sulphonate, methyl ester sulfonate, primary alkyl sulphates, sodium
dodecylbenzenesulfonate, sodium stearate, amine oxides, non-ionic E07, E05, Cetyl trimethylammonium bromide and cetyl trimethylammonium chloride.
The most preferred ones are sodium linear alkylbenzene sulfonates, sodium salt of alpha olefin sulphonate, sodium dodecyl sulphate, amine oxides ad non-ionic E07. Inorganic absorbent material
The composition according to the invention comprises an inorganic absorbent material having a surface area of more than 50m2/g.
The inorganic absorbent material is selected from the group of materials with high BET (Brunauer, Emmett and Teller) surface area. It is preferred that the surface area of the inorganic absorbent material is between 50 and 1500 m2/g, more preferably between 80 and 1000 m2/g, still more preferably between 100 and 800 m2/g and even more preferably between 150 and 500 m2/g. Examples of suitable inorganic absorbent materials include precipitated silica, fumed silica, alumina, titanium dioxide, zinc oxide, clays such as montmorillonite, bentonite, kaolinite/china clay, layered double hydroxides, activated carbon, calcium carbonate, apatites and calcium oxides/hydroxides, having a surface area of more than 50m2/g.
The preferred inorganic absorbent materials of the invention are fumed silica, alumina, bentonite clay, titanium dioxide and activated charcoal, having a surface area of more than 50m2/g.
The inorganic absorbent material is present in the composition in a concentration of 2 to 35%, preferably not more than 30%, more preferably not more than 25%, still more preferably not more than 20% but typically not less than 4%, more preferably not less than 6%, still more preferably not less than 7% by weight of the total composition.
Abrasive
The composition according to the invention comprises an abrasive having a Mohs' hardness of between 3 and 7. Mohs' hardness is a scale classifying the relative hardness of minerals on a scale of 1 to 10. The complete scale is given in textbooks like "Novel and Traditional Fillers for Plastics: Technology and Market Developments" by Geoffrey Pritchard, Rapra
Technology Ltd., ISBN: 1-85957-183-2, Page-28 and "Minerals of the World" by Walter Schumann, Sterling Publishing Company, Inc., 2008 - Nature, Sterling ISBN: 978-1- 4027-5339-8.
Mohs' hardness of the abrasive according to the present invention is preferably between 3 and 7. This includes all the abrasives from calcite (Mohs' hardness of 3) and upwards on the scale.
The abrasive may be soluble or insoluble in water. Water soluble abrasives when used may be present in such excess to any water present in the composition so that the solubility of the abrasive in the aqueous phase is exceeded and consequently the abrasive exists in the composition.
The volume average particle size of the abrasive is between 0.5 and 400 μηη, preferably between 10 and 200 μηη. Preferably the span is between 2 and 5; and wherein the span is defined as the broadness or width in particle distribution between a 10% limit (D10) and a 90% limit (D90) divided by the mean particle diameter (D50), whereby 10% by volume of the particles have a diameter below the 10% limit and 10% by volume of the particles have a diameter above the 90% limit.
The preferred abrasives include feldspar, silica, dolomite, calcite, synthetic aluminium oxide, amalgam, anatase, apatite, cuttlebone, diopside, enamel, enstatite, fluorite, glass bead, glass, hematite, kyanite, magnetite, olivine, orthoclase, petalite, porcelain, feldspathic , pyrite, pumice, quartz (silica sand), spodumene, titanium dioxide, particulate zeolites, silicates, other carbonates, bicarbonates, borates and sulphates.
Examples of the most preferred abrasives include feldspar, synthetic aluminium oxide, dolomite and calcite. The abrasive is present in the composition in a concentration of 33 to 96%, preferably not more than 90%, more preferably not more 85% but typically not less than 35%, more preferably not less than 40%, still more preferably not less than 45%, even more preferably not less than 50% or even not less than 60% by weight of the total composition.
Ratio of Inorganic absorbent material to Abrasive
Without wishing to be bound by a particular theory, it is thought that when the composition according to the invention is applied on a soiled surface, the inorganic absorbent material with the high surface area quickly starts acting on the oily and/or watery parts to accumulate the soil into its structure and the abrasives help to dislodge the soil from the substrate. Due to the high absorption capacity of the inorganic absorbent material, they form aggregates when pressure is applied which then gets lifted from the surface and carried away swiftly by the action of abrasives, thus resulting in cleaning. However, a critical ratio of inorganic absorbent material to abrasive is required to achieve the desired cleaning action.
The inorganic absorbent material and the abrasive are present in a ratio of between 1 :2 and 1 :20, preferably between 1 :3 and 1 :12 or more preferably between 1 :4 and 1 :10.
The skilled person would understand how the above ratio should be read and interpreted in light of weight ranges applicable to the inorganic absorbent material and the abrasive. However, for the avoidance of doubt, it is clarified that the ratio which is between 1 :2 and 1 :20 should be read harmoniously with the weight ranges so as to make technical sense out of the two claimed parameters.
For example, at an absorbent content of 2 weight%, the skilled person would not follow the ratio of 1 :2, although it falls within the claimed range, because then the abrasive content would fall significantly short of the minimum claimed value. Similarly, if the content of the absorbent is 35 wt%, then the ratio of 1 :20 would lead to an impractical value of 700 wt% of the abrasive. The skilled person would know that the maximum absorbent content is 96 wt% and would then accordingly select a suitable ratio from the claimed range.
Water
Water is present in the hard surface cleaning composition of the present invention. Water is in a concentration of less than 2% by weight of the composition. Optional Ingredients
The composition according to the invention may contain other ingredients which aid in their cleaning or sensory performance. Compositions according to the invention can also contain, in addition to the ingredients already mentioned, various other optional ingredients such as builders, ash, perfume, colourants, electrolytes, structuring agents, fillers and antimicrobial agents. Process
In a second aspect, the invention relates to a process for cleaning a hard surface without the use of water comprising the steps of applying onto the hard surface a composition according to the invention, scrubbing the hard surface, dusting off the composition using hands; and optionally wiping the hard surface with a wet cloth.
In a different embodiment, the composition may be dusted off using the same scrubbing implement. In a third aspect, the invention relates to the use of a composition according to the invention for cleaning hard surfaces without using water.
The invention will now be illustrated by means of the following non-limiting examples Examples
Materials
Surfactants
Anionic: Linear alkylbenzene sulfonic acid- LAS acid (ex Rhodia and Advanced
Surfactants)
Sodium dodecyl sulfate-SDS (ex Sigma Aldrich)
Sodium dodecanoate (ex Sigma Aldrich)
Sodium stearate (ex Sigma Aldrich)
Sodium dodecylbenzenesulfonate- SDBS (ex Sigma Aldrich)
Cationic: Cetyltrimethylammonium bromide-CTAB (ex Loba Cheme)
Zwitterionic Amine oxide Empigen OD (ex Huntsman)
Non-ionic: E07 (ex Galaxy Surfactants)
Inorganic absorbent materials
Sodium bentonite-Low SA (ex Sigma Aldrich)
Sodium bentonite- High SA (ex Sigma Aldrich)
Alumina, DISPERSAL P2 (ex Sasol)
Silica, Aerosil-200 (ex Evonik) Silica, MFIL-100 special (ex Madhu silica)
Titanium dioxide, MT-600B (ex Tayca Corporation)
Titanium dioxide, MT-150W (ex Tayca Corporation)
Activated Charcoal, DARCO (ex Sigma Aldrich)
Abrasives
Feldspar (ex Salice Exim, Chennai, India)
Dolomite (ex Exim, Chennai, India)
Calcite 30AV (ex OMYA)
Talc (ex Sigma Aldrich)
Preparation of the compositions:
Each of the sample composition was prepared following the sequence of addition of ingredients as described herein. In a typical experiment, half of the abrasive material was taken in a mortar and pestle to which surfactant was added. The concoction was ground and mixed for 5 minutes. Then, the required amount of absorbent was added and ground thoroughly for another 10 minutes. Finally, the remaining half of the abrasive was added, ground and mixed for another 5 minutes to get the final powder composition.
For the preparation of the anionic surfactant sodium LAS, the LAS acid was pre- neutralized with a stoichiometric amount of base (eg, soda) and catalytic water and added into the mortar and pestle at the specified step. Test for Cleaning
0.5 g of sunflower oil was spread on a substrate (porcelain plate if not otherwise mentioned, with -8-10 cm radius). 1.25 g of cleaning powder sample was sprinkled on top of it. It was scrubbed with a plastic paper with 10X15 cm2 dimension for 30 seconds. The soil along with powder was dusted off with the plastic implement itself. The substrate was thereafter set under a hair-dryer for 10 seconds to remove any additional loosely bound particles. A pre-weighed tissue paper was used then to remove the soil left on the substrate. The difference between the initial and final weight of the tissue paper was calculated which equals to the residual amount of soil on each plate. Cleaning of≥85% is considered to be good.
Example 1 : Effect of ratio of the inorganic absorbent material and the abrasive on cleaning
In this example, Ex 1 to Ex 9 comprising the inorganic absorbent material and the abrasive in a ratio within the scope of the invention are compared to C1 to C4 comprising the inorganic absorbent material and the abrasive in a ratio outside the scope of the present invention.
The amount of initial oil in this example is 0.5 grams.
Table 1
Note: * Inorganic absorbent material to Abrasive
The table above shows that the desired cleaning of more than 85% is obtained when the inorganic absorbent material and the abrasive is present in a ratio according to the invention.
Example 2: Effect of the surface area of the inorganic absorbent material on cleaning In this example, inorganic absorbent materials with various surface areas are compared. Ex 10 to Ex 15 are compositions according to the invention comprising an inorganic absorbent material having a surface area of more than 50 m2/g and C5 and C6 are comparative compositions comprising an inorganic absorbent material having a surface area of less than 50 m2/g.
The amount of initial oil in this example is 0.5 grams.
Table 1
Ex 14 3 Titanium 87 80- 0.051 1 0.0539 0.0525 89.5 Dioxide, MT- 1 10
150W
Ex15 3 Activated 87 600 0.0164 0.0158 0.0161 96.8
Charcoal,
Darco
The table above shows that the desired cleaning of more than 85% is obtained when the inorganic absorbent material has a surface area of more than 50m2/g. Example 3: Effect of Mohs' hardness of the abrasive on cleaning
This example demonstrates the effect of Mohs' hardness of the abrasive on cleaning. Ex 16, Ex 17 and Ex 17A, compositions comprising abrasives having a Mohs' hardness according to the invention are compared to C7, a composition comprising an abrasive having a Mohs' hardness outside the scope of the invention.
The amount of initial oil in this example is 0.5 grams.
Table 3
The results in the above table indicate that the desired cleaning of more than 85% is obtained when the abrasive has a Mohs' hardness according to the invention. Example 4: Effect of concentration of the surfactant on cleaning
In this example, different concentrations of the surfactant are compared. Ex 18 to Ex 20 are compositions comprising the surfactant in a concentration according to the invention and C8 and C9 are compositions comprising the surfactant in a concentration outside the scope of the invention.
The amount of initial oil in this example is 0.5 grams.
Table 4
Note: * Inorganic absorbent material to Abrasive The table above shows that the desired cleaning of more than 85% is obtained when the surfactant is present in the composition in a concentration according to the invention.
Example 5: Effect of different surfactants on cleaning
This example demonstrates the cleaning performance of the compositions according to invention comprising different surfactants (Ex 21 to Ex 27).
The amount of initial oil in this example is 0.5 grams. Table 5
The table above shows that the desired cleaning of more than 85% is obtained when the composition comprises a surfactant selected from anionic, cationic, non-ionic, zwitterionic, sodium salts of carboxylic acids.
Example 6: Cleaning performance of the composition according to the invention on different substrates
This example illustrates the cleaning performance of the composition according to the invention on different substrates (Ex 28 to Ex 31 ).
The amount of initial oil in this example is 0.5 grams. Table 6
It is apparent from the above table that a cleaning of more than 85% is obtained with the composition according to the inventions on any kind of substrate.
Example 7: Effect of high concentration of the abrasive (when taken alone) on cleaning This example illustrates that cleaning performance of the composition according to the invention (Ex 17A) cannot be achieved even if a high concentration of the abrasive is used alone (C10).
The amount of initial oil in this example is 0.5 grams.
Table 7
Set Surfacta Absorb Abrasive Moh Left Over (g) Averag Cleaning nt ent (Calcite) s' e (g) %
(NaLAS) (Aerosil wt% Hard
wt% -200) ness
wt%
C10 3 - 97 3 0.1896 0.2009 0.1953 61.0
Ex 3 10 87 3 0.0151 0.0163 0.0157 96.9 17A The above table shows that even if an abrasive like calcite is used at high
concentrations alone, a cleaning of more than 85% is still not obtained.
Example 8: The effect of water
Three dish-wash compositions were prepared with varying level of water content in them. For precise control over water level, all the ingredients were dried previously in a hot air oven at 85 °C for 6 hours. After that the ingredients were mixed following the sequence of addition mentioned earlier. In this step it was ensured that the moisture content remained <0.5% in the prepared compositions.
After this step, calculated amount of water was added externally to each formulation to match up the final required moisture level. Details of the compositions are mentioned below in table 8. The cleaning procedure is as described earlier under the heading of test for cleaning. The cleaning data is also included in table 8.
Table 8
From the data in table 8 it can be concluded that the content of water has an effect on efficacy of the formulation. For a given surface area of the chosen absorbent (80-100 m2/g) it was observed that an increase in the water level from 1 .8 wt% to 3 wt% resulted in reduction in the cleaning performance by about 12 units i.e., 12% (drop from 86% to about 74%) and beyond the threshold value defined elsewhere in the description. This effect is further confirmed by the drop in cleaning efficacy in the case of the composition C12.

Claims

Claims
1. A hard surface cleaning composition comprising
a) 0.1 to 50% by weight of a surfactant;
b) 2 to 35% by weight of an inorganic absorbent material having a surface area of more than 50m2/g; and
c) 33 to 96% by weight of an abrasive having a Mohs' hardness of between 3 and 7;
wherein the ratio of the inorganic absorbent material to the abrasive is between 1 :2 to 1 :20 and wherein water is in a concentration of less than 2% by weight of the composition.
2. A composition according to claim 1 , wherein the inorganic absorbent material has a surface area of between 50 and 1500 m2/g.
3. A composition according to claim 1 or 2, wherein the inorganic absorbent material is selected from precipitated silica, fumed silica, alumina, titanium dioxide, zinc oxide, clays such as montmorillonite, bentonite, kaolinite/china clay, layered double hydroxides, activated carbon, calcium carbonate, apatites and calcium oxides/hydroxides.
4. A composition according to any of the preceding claims, wherein the abrasive is selected from feldspar, silica, dolomite, calcite, synthetic aluminium oxide, amalgam, anatase, apatite, cuttlebone, diopside, enamel, enstatite, fluorite, glass bead, glass, hematite, kyanite, magnetite, olivine, orthoclase, petalite, porcelain, feldspathic , pyrite, pumice, quartz (silica sand), spodumene, titanium dioxide, particulate zeolites, silicates, other carbonates, bicarbonates, borates and sulphates.
5. A composition according to any of the preceding claims wherein the composition is in granular or powder form. A process for cleaning a hard surface without the use of water comprising the steps of:
a) applying onto the hard surface a composition according to anyone of claims 1 to 5;
b) scrubbing the hard surface;
c) dusting off the composition using hands; and
d) optionally wiping the hard surface with a wet cloth.
Use of a composition according to claim 1 for cleaning hard surfaces without using water.
EP15734190.0A 2014-08-01 2015-07-07 Hard surface cleaning composition Not-in-force EP3174967B1 (en)

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Publication number Priority date Publication date Assignee Title
US2296690A (en) * 1940-03-02 1942-09-22 J B Ford Company Abrasive scouring powder
US4615821A (en) * 1984-09-25 1986-10-07 The Procter & Gamble Company Benzyl alcohol for improved powdered cleansers
GB9821781D0 (en) * 1998-10-06 1998-12-02 Unilever Plc Improved detergent bar composition
IN192087B (en) * 1999-05-11 2004-02-21 Lever Hindustan Ltd
EA027538B1 (en) * 2012-11-16 2017-08-31 Юнилевер Н.В. Surface cleaning composition

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