EP3038838B1 - Feuille de données pour un document sécurisé et/ou de valeur - Google Patents

Feuille de données pour un document sécurisé et/ou de valeur Download PDF

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Publication number
EP3038838B1
EP3038838B1 EP14745064.7A EP14745064A EP3038838B1 EP 3038838 B1 EP3038838 B1 EP 3038838B1 EP 14745064 A EP14745064 A EP 14745064A EP 3038838 B1 EP3038838 B1 EP 3038838B1
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EP
European Patent Office
Prior art keywords
layers
material layer
paper material
data sheet
poly
Prior art date
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EP14745064.7A
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German (de)
English (en)
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EP3038838A2 (fr
Inventor
Edward Springmann
Detlef Märtens
Martin Siebert
Thomas Felske
Roland Gutmann
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Bundesdruckerei GmbH
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Bundesdruckerei GmbH
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D1/00—Books or other bound products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D1/00—Books or other bound products
    • B42D1/002—Back of leaves or signatures prepared for binding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D1/00—Books or other bound products
    • B42D1/003—Books or other bound products characterised by shape or material of the sheets
    • B42D1/008—Sheet materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D13/00—Loose leaves modified for binding; Inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
    • B42D25/24—Passports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/333—Watermarks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/351—Translucent or partly translucent parts, e.g. windows
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/30—Identification or security features, e.g. for preventing forgery
    • B42D25/355—Security threads
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B42D25/455—Associating two or more layers using heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B42D25/46—Associating two or more layers using pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B42D25/465—Associating two or more layers using chemicals or adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/40—Manufacture
    • B42D25/45—Associating two or more layers
    • B42D25/465—Associating two or more layers using chemicals or adhesives
    • B42D25/47—Associating two or more layers using chemicals or adhesives using adhesives

Definitions

  • the invention relates to a data sheet for incorporation into a book-shaped security and / or value document, wherein the data sheet is formed of at least two stacked layers of an organic polymer material and wherein at least in a portion between the layers and outside of the layers, forming a tab, a flexible is arranged.
  • the invention further relates to a method for producing such a data sheet and to a security and / or value document comprising such a data sheet.
  • Such data sheets typically carry information, at least partially individualized and / or personalized.
  • Individualized means related to a document, e.g. a serial number.
  • Personalized means referring to the document holder, e.g. Name or picture.
  • security features can be integrated in such a data sheet. For all standard safety features come into question, which are typically used in plastic laminates as a data sheet.
  • a disadvantage of the known security and / or value documents is an insufficient flexibility of the tab of the data sheet, which has a "unlocking" the book result. Furthermore, in the case of TPU tabs, for example, there is a potential delamination possibility of the passcard between TPU inner layer and PC outer layers, which can only be reduced by additional expenditure, for example coatings or material modification.
  • tissue bag concepts for the production of security and / or value documents a passcard or data sheet foreign tissue material, for. B. polyester used. To achieve an intimate connection of tab material and polymer layers of the data sheet, elaborate breakthroughs must be introduced, as for example in the reference WO 2006079224 are described.
  • This book-type document comprises a data sheet which is formed from a multilayer laminate, wherein a microchip is inserted between the laminate layers. On these laminated components, which are referred to as inlay, an arc is applied. This bow is double-sided and therefore does not form a flap. Rather, the tab is formed by the outer laminate layers.
  • the invention is therefore based on the technical problem of specifying a data sheet, which on the one hand has a flap with high flexibility and so safely avoids "unlocking" the document, and on the other hand a secure connection of all components of the data sheet, including the tab, with each other easier To ensure manufacturability.
  • the invention teaches a data sheet according to claim 1.
  • a highly flexible tab is guaranteed, which serves as a hinge flap in the finished document and which is also particularly securely connected to the layers of the data sheet. It will be a very good serve and low blocking tendency reached.
  • An inventive data sheet is also relatively easy to produce. Such a data sheet can finally be sewn into a security and / or value document simply and with little effort.
  • the organic polymer of the layers can basically be any polymer material used in the field of security and / or value documents. Examples of these are: transparent, opaque or opaque polymer materials.
  • the organic polymer material of the layers may, for example, be selected from the group consisting of PC (polycarbonate, especially bisphenol A polycarbonate), PET (polyethylene glycol terephthalate), PMMA (polymethyl methacrylate), TPU (thermoplastic polyurethane elastomers), PE (polyethylene), PP (polypropylene) , PI (polyimide or poly-trans-isoprene), PVC (polyvinyl chloride), polystyrene, polyacrylates and methacrylates, vinyl esters, ABS and copolymers of such polymers. Particularly preferred is the use of PC for the layers.
  • Suitable plastics for the plastic films are all transparent thermoplastics: polyacrylates, polymethacrylates (PMMA, Plexiglas® from Röhm), cycloolefin copolymers (COC; Topas® from Ticona, Zenoex® from Nippon Zeon, Apel® from Japan Synthetic Rubber), polysulfones (Ultrason® Fa. BASF, Udel® Fa.
  • polyesters such as PET or PEN
  • polycarbonate such as PET or PEN
  • polycarbonate such as PET or PEN
  • polycarbonate such as PC / CoPET
  • PCCD Polycyclohexylmethanolcyclohexandicarboxylat
  • PCCD Polycyclohexylmethanolcyclohexandicarboxylat
  • PBT Xylex®
  • thermoplastic material (s) in the layers are, independently of one another, polycarbonates or copolycarbonates based on diphenols, poly- or copolyacrylates, poly- or co-polymethacrylates, poly- or copolymers with styrene, thermoplastic polyurethanes , Polyolefins, poly- or copolycondensates of terephthalic acid or naphthalenedicarboxylic acid or mixtures thereof, preferably polycarbonates or copolycarbonates based on diphenols, poly- or copolyacrylates, poly- or copolymers of copolycondensates of terephthalic acid or naphthalenedicarboxylic acid or mixtures thereof.
  • the organic binder may be in the core of any binder, which forms a firm and permanent bond with the organic polymer of the layers, in particular during lamination.
  • a polycarbonate derivative in particular based on bisphenol A, preferably based on a geminally disubstituted dihydroxydiphenyl-cycloalkane, is preferred.
  • the binder which is preferably in the form of a polycarbonate derivative, can contain functional carbonate structural units of the formula (I) wherein R 1 and R 2 independently of one another are hydrogen, halogen, preferably chlorine or bromine, C 1 -C 8 -alkyl, C 5 -C 6 -cycloalkyl, C 6 -C 10 -aryl, preferably phenyl, and C 7 -C 12 -Aralkyl, preferably phenyl-C 1 -C 4 -alkyl, in particular benzyl; m is an integer from 4 to 7, preferably 4 or 5; R 3 and R 4 are individually selectable for each X independently of one another hydrogen or C 1 -C 6 -alkyl; X is carbon and n is an integer greater than 20, with the proviso that on at least one atom X, R 3 and R 4 are simultaneously alkyl.
  • R 1 and R 2 independently of one another are hydrogen, halogen, preferably chlorine or bromine, C 1 -
  • X, R 3 and R 4 are simultaneously alkyl at 1 to 2 atoms, in particular only at one atom.
  • R 3 and R 4 may be in particular methyl.
  • the X atoms alpha to the diphenyl-substituted C atom (C1) may not be dialkyl-substituted.
  • the X atoms beta to C1 may be disubstituted with alkyl.
  • m 4 or 5.
  • the polycarbonate derivative can be prepared, for example, on the basis of monomers, such as 4,4 '- (3,3,5-trimethylcyclohexane-1,1-diyl) diphenol, 4,4' - (3,3-) dimethylcyclohexane-1,1-diyl) diphenol, or 4,4 '- (2,4,4-trimethylcyclopentane-1,1-diyl) diphenol.
  • monomers such as 4,4 '- (3,3,5-trimethylcyclohexane-1,1-diyl) diphenol, 4,4' - (3,3-) dimethylcyclohexane-1,1-diyl) diphenol, or 4,4 '- (2,4,4-trimethylcyclopentane-1,1-diyl) diphenol.
  • An inventive binder can, for example, according to the literature DE 38 32 396.6 are prepared from diphenols of the formula (Ia), the disclosure content of which is hereby incorporated in full in the disclosure of this description.
  • diphenols of the formula (Ia) may also be mixed with other diphenols, for example those of the formula (Ib) HO - Z - OH (Ib), be used for the preparation of high molecular weight, thermoplastic, aromatic polycarbonate derivatives.
  • Suitable other diphenols of the formula (Ib) are those in which Z is an aromatic radical having 6 to 30 C atoms, which may contain one or more aromatic nuclei, may be substituted, and aliphatic radicals or cycloaliphatic radicals other than those of the formula (II) Ia) or heteroatoms may contain as bridge members.
  • diphenols of the formula (Ib) are: hydroquinone, resorcinol, dihydroxydiphenyls, bis (hydroxyphenyl) alkanes, bis (hydroxyphenyl) cycloalkanes, bis (hydroxyphenyl) sulfides, bis (hydroxyphenyl) ether, bis (hydroxyphenyl) ether, bis (hydroxyphenyl) ether, (hydroxyphenyl) ketones, bis (hydroxyphenyl) sulfones, bis (hydroxyphenyl) sulfoxides, alpha, alpha 'bis (hydroxyphenyl) diisopropylbenzenes and their ring-alkylated and ring-halogenated compounds.
  • Preferred other diphenols are, for example: 4,4'-dihydroxydiphenyl, 2,2-bis (4-hydroxyphenyl) propane, 2,4-bis (4-hydroxyphenyl) -2-methylbutane, 1,1-bis ( 4-hydroxyphenyl) cyclohexane, alpha, alpha -bis (4-hydroxyphenyl) -p-diisopropylbenzene, 2,2-bis (3-methyl-4-hydroxyphenyl) -propane, 2,2-bis (3-methyl) chloro-4-hydroxyphenyl) -propane, bis (3,5-dimethyl-4-hydroxyphenyl) -methane, 2,2-bis (3,5-dimethyl-4-hydroxyphenyl) -propane, bis (3, 5-dimethyl-4-hydroxyphenyl) sulfone, 2,4-bis (3,5-dimethyl-4-hydroxyphenyl) -2-methylbutane, 1,1-bis (3,5-dimethyl-4-hydroxyphenyl) -
  • diphenols of the formula (Ib) are, for example: 2,2-bis (4-hydroxyphenyl) propane, 2,2-bis (3,5-dimethyl-4-hydroxyphenyl) propane, 2,2-bis - (3,5-dichloro-4-hydroxyphenyl) -propane, 2,2-bis (3,5-dibromo-4-hydroxyphenyl) -propane and 1,1-bis (4-hydroxyphenyl) -cyclohexane.
  • 2,2-bis (4-hydroxyphenyl) propane is preferred.
  • the other diphenols can be used both individually and in a mixture.
  • the molar ratio of diphenols of the formula (Ia) to the optionally used other diphenols of the formula (Ib) should be between 100 mol% (Ia) to 0 mol% (Ib) and 2 mol% (Ia) to 98 mol -% (Ib), preferably between 100 mol% (Ia) to 0 mol% (Ib) and 10 mol% (Ia) to 90 mol% (Ib) and especially between 100 mol% (Ia) to 0 mol% (Ib) and 30 mol% (Ia) to 70 mol% (Ib) and more particularly between 100 mol% (Ia) to 0 mol% (Ib) and 50 mol% (Ia) to 50 mol% (Ib).
  • the high molecular weight polycarbonates of the diphenols of the formula (Ia), optionally in combination with other diphenols, can be prepared by the known polycarbonate production processes.
  • the various diphenols can be linked together both statistically and in blocks.
  • the polycarbonate derivatives used according to the invention can be branched in a manner known per se. If the branching is desired, it is possible in known manner by condensing small amounts, preferably amounts between 0.05 and 2.0 mol% (based on diphenols used), of trifunctional or more than trifunctional compounds, in particular those having three or more Some branching agents having three or more than three phenolic hydroxyl groups are: phloroglucinol, 4,6-dimethyl-2,4,6-tri- (4-hydroxyphenyl) -heptene-2, 4,6 Dimethyl 2,4,6-tri (4-hydroxyphenyl) heptane, 1,3,5-tri (4-hydroxyphenyl) benzene, 1,1,1-tri- (4-hydroxyphenyl) -ethane , Tri- (4-hydroxyphenyl) -phenylmethane, 2,2-bis [4,4-bis (4-hydroxyphenyl) -cyclohexyl] -propane, 2,4-bis (4-hydroxyphenyl
  • trifunctional compounds are 2,4-dihydroxybenzoic acid, trimesic acid, cyanuric chloride and 3,3-bis (3-methyl-4-hydroxyphenyl) -2-oxo-2,3-dihydroindole.
  • Suitable compounds are, for example, phenol, tert-butylphenols or other alkyl-substituted phenols.
  • phenols of the formula (Ic) are suitable wherein R is a branched C 8 - and / or C 9 -alkyl radical.
  • the chain terminators are generally used in amounts of 0.5 to 10, preferably 1.5 to 8 mol%, based on diphenols used.
  • the polycarbonate derivatives may preferably be prepared according to the interfacial behavior (cf. H. Schnell "Chemistry and Physics of Polycarbonates ", Polymer Reviews, Vol. IX, p. 33ff., Interscience Publ. 1964 ) are prepared in a conventional manner.
  • the diphenols of the formula (Ia) are dissolved in an aqueous alkaline phase.
  • mixtures of diphenols of the formula (Ia) and the other diphenols, for example those of the formula (Ib), are used.
  • chain terminators e.g. of the formula (Ic) are added.
  • organic phase is reacted with phosgene by the method of interfacial condensation.
  • the reaction temperature is between 0 ° C and 40 ° C.
  • the optionally used branching agents can either be initially charged with the diphenols in the aqueous alkaline phase or added in the organic solvent before phosgenation.
  • diphenols of the formula (Ia) and, if appropriate, other diphenols (Ib) their mono- and / or bis-chlorocarbonic acid esters may also be used, these being added dissolved in organic solvents.
  • the amount of chain terminators and of branching agents then depends on the molar amount of diphenolate radicals corresponding to formula (Ia) and optionally formula (Ib); When using chloroformates the amount of phosgene can be reduced accordingly in a known manner.
  • Suitable organic solvents for the chain terminators and optionally for the branching agents and the chloroformates are, for example, methylene chloride, chlorobenzene, in particular mixtures of methylene chloride and chlorobenzene.
  • the chain terminators and branching agents used can be dissolved in the same solvent.
  • methylene chloride, chlorobenzene and mixtures of methylene chloride and chlorobenzene serve as the organic phase for the interfacial polycondensation.
  • the aqueous alkaline phase used is, for example, NaOH solution.
  • the preparation of the polycarbonate derivatives by the interfacial process can be catalyzed in a conventional manner by catalysts such as tertiary amines, in particular tertiary aliphatic amines such as tributylamine or triethylamine; the catalysts can be used in amounts of 0.05 to 10 mol%, based on moles of diphenols used.
  • the catalysts can be added before the beginning of the phosgenation or during or after the phosgenation.
  • the polycarbonate derivatives can be prepared by the known method in the homogeneous phase, the so-called "pyridine process” and by the known melt transesterification process using, for example, diphenyl carbonate instead of phosgene.
  • the polycarbonate derivatives may be linear or branched, they are homopolycarbonates or copolycarbonates based on the diphenols of the formula (Ia).
  • the polycarbonate properties can be varied in a favorable manner.
  • the diphenols of the formula (Ia) are present in amounts of from 100 mol% to 2 mol%, preferably in amounts of from 100 mol% to 10 mol% and in particular in amounts of from 100 mol% to 30 mol% % and more particularly from 100 mol% to 50 mol%, based on the total amount of 100 mol% of diphenol units, contained in polycarbonate derivatives.
  • a particularly advantageous embodiment of the invention is characterized in that the polycarbonate derivative contains a copolymer, in particular consisting of monomer units M1 based on bisphenol A and monomer units M2 based on the geminally disubstituted dihydroxydiphenylcycloalkane, preferably of the 4,4 '- (3,3,5 -trimethylcyclohexane-1,1-diyl) diphenol, wherein the molar ratio M2 / M1 is preferably greater than 0.5, in particular greater than 0.8, for example greater than 1.0.
  • liquid preparation comprising: A) 1 to 40% by weight of a polycarbonate derivative used according to the invention, and B) 50 to 99% by weight of an organic solvent or solvent mixture.
  • the organic solvents used are preferably halogen-free solvents.
  • Particularly suitable are aliphatic, cycloaliphatic, aromatic hydrocarbons, such as mesitylene, 1,2,4-trimethylbenzene, cumene and solvent naphtha, toluene, xylene; Esters such as methyl acetate, ethyl acetate, butyl acetate, methoxypropyl acetate, ethyl 3-ethoxypropionate, butyl glycol acetate.
  • mesitylene, 1,2,4-trimethylbenzene, cumene and solvent naphtha toluene, xylene, methyl acetate, ethyl acetate, methoxypropyl acetate, butylglycol acetate.
  • Ethyl 3-ethoxypropionate Especially preferred are mesitylene (1,3,5-trimethylbenzene), 1,2,4-trimethylbenzene, cumene (2-phenylpropane), solvent naphtha, ethyl 3-ethoxypropionate, methoxypropyl acetate and butylglycol acetate.
  • a suitable solvent mixture comprises, for example, L1) 0 to 10% by weight, preferably 1 to 5% by weight, in particular 2 to 3% by weight, mesitylene, L2) 10 to 50% by weight, preferably 20 to 50% by weight %, in particular 20 to 40% by weight, 1-methoxy-2-propanol acetate, L3) 0 to 20% by weight, preferably 1 to 20% by weight, in particular 7 to 15% by weight, 1 , 2,4-trimethylbenzene, L4) 10 to 50 wt.%, Preferably 20 to 50 wt.%, In particular 20 to 40 wt.%, Ethyl 3-ethoxypropionate, L5) 0 to 10 wt.
  • the solvent mixture also contains L7) with 10 to 50 wt .-%, preferably 20 to 50 wt .-%, in particular 20 to 40 wt .-%, butyl glycol acetate, wherein the sum of the components used L1 to L7 always 100 wt. -% results.
  • Suitable organic solvents in the preparation of a binder solution suitable for coating a layer or textile are all those customary in the context of, for example, printing technology, in particular inkjet printing technology, customary solvents and solvent mixtures.
  • the use of aqueous dispersions which contain less than 10% by weight of organic solvents is also possible.
  • the binder with its components according to the invention is present as dispersed film-forming particles.
  • the preparation can be in the form of a solution, dispersion, emulsion or paste.
  • the setting of a suitable viscosity can easily be selected and carried out by the person skilled in the art in accordance with the coating technology to be used. Coloring agents and / or dispersing additives, for example commercially available from Evonik or Byk, may be added.
  • the paper material layer (5) is substantially homogeneous and absorbent in the direction perpendicular to the main surfaces, the paper material layer (5) being saturated with the organic binder (6).
  • surface-coated, non-calendered, absorbent paper materials are suitable for this purpose.
  • “Absorbent” refers to such a paper material whose water absorption according to Cobb (Cobb 60s, DIN EN 20535) is above 1 g / m 2 , in particular above 10 or 20 or 50 g / m 2 .
  • the Cobb value of a paper material can be varied and specifically adjusted in particular by varying the degree of sizing of the paper material.
  • the paper material layer (5) has a multilayered construction and has at least one slightly absorbent middle layer (5a) and an absorbent outer layer (5b, 5c) on each side of the middle layer (5a) and connected thereto, wherein the paper material layer (5) in the region between the layers (2, 3) and / or outside the layers (2, 3) is impregnated substantially exclusively in the outer layers (5b, 5c) with the organic binder (6).
  • a "less absorbent" paper material has a Cobb value (Cobb 60s, DIN EN 20535) of not more than 90%, in particular not more than 50%, preferably not more than 10%, especially less than 1%, of the Cobb value of the absorbent paper material.
  • the binder and / or the paper material layer additionally one or more Substances or materials from the group consisting of color pigments, effect pigments, optically variable pigments, and luminescent pigments.
  • one or more security features from the group consisting of watermarks, mottling fibers, planchettes, security threads and window threads can additionally or instead be set up.
  • paper grades for the paper material layer and their different layers are in particular cotton paper and cellulose paper in question.
  • At least one electronic circuit with an antenna connected thereto is arranged on the paper material layer or between the paper material layer and a layer embedded in the binder.
  • the invention also encompasses a method for producing a data sheet according to the invention, wherein two layers of an organic polymer material and a paper material layer are provided, wherein at least partial regions of one side of one layer or both layers and / or partial regions of one side or both sides of the paper material layer Coating of a liquid uncured binder preparation applied, in particular imprinted, wherein the layers and the paper material layer stacked to each other and arranged with mutually facing coated sides with the proviso that a part of the paper material layer as a tab outside the two layers protruding, in which case the layers and the paper material layer are laminated together, and wherein the binder is cured or crosslinked.
  • the tab can be provided with binder or have no binder.
  • the paper material layer can be arranged only in a partial area between the layers, or in the entire area between the layers.
  • the direction of travel (orientation of the paper fiber direction) of the paper material layer is oriented parallel to the longitudinal extent of the tab. As a result, a good impact or folding behavior of the finished security and / or value document with sewn-in data sheet is achieved.
  • Suitable printing techniques for the application of the binder or a preparation containing the binder are all customary techniques in the field of security and / or value documents, such as screen printing, flexographic printing, offset printing, letterpress, gravure printing, letterpress printing, thermal sublimation printing, or inkjet printing.
  • the painting, -Rakeln, - rolling, stamping, casting such as film casting, painting, dipping, roller or grid application method, spin, calendering, etc. possible.
  • the invention relates to a security and / or value document containing a data sheet according to the invention, wherein the data sheet by means of the tab in a book spine involved, in particular sewn or glued.
  • the polycarbonate derivative showed a relative solution viscosity of 1.255.
  • the polycarbonate derivative showed a relative solution viscosity of 1.263.
  • Example 2 As in Example 1, a mixture of 149.0 g (0.65 mol) of bisphenol A and 107.9 g (0.35 mol) of 1,1-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane converted to polycarbonate.
  • the polycarbonate derivative showed a relative solution viscosity of 1.263.
  • Example 2.1 Preparation of a first liquid preparation used according to the invention
  • liquid composition which can be applied by printing
  • the following solution is prepared: 17.5 parts by weight of the polycarbonate from Example 1.3, 82.5 parts by weight of the following solvent mixture, consisting of: mesitylene 2.4 1-methoxy-2-propanol 34.95 1,2,4-trimethylbenzene 10.75 Ethyl 3-ethoxypropionate 33.35 cumene 0.105 Solvent naphtha 18.45
  • an appropriate amount of the solution APEC PUD 6581-9 (Bayer MaterialScience) can also be used.
  • Example 2.2 Preparation of a second liquid preparation used according to the invention
  • the preparation is prepared analogously to Example 2.1, except that 8% by weight of CD740 from Honeywell are used as the luminescent substance.
  • Example 2.3 Preparation of a third liquid preparation used according to the invention
  • the preparation is prepared analogously to Example 2.1, except that 8% by weight of CD702 from Honeywell are used as the luminescent substance.
  • Example 2.4 Preparation of a fourth liquid preparation used according to the invention
  • the preparation is analogous to Example 2.1, but the luminescent substance is omitted.
  • a data sheet 1 according to the invention or its components before lamination is shown.
  • two layers 2, 3 of an organic polymer material, preferably of transparent polycarbonate, are initially recognizable.
  • the layers 2, 3 may in turn be formed from a plurality of stacked films.
  • printing layers and / or security features not shown on or in a layer 2, 3 or both layers 2, 3 can be set up.
  • this paper material layer 5 is formed from a absorbent paper material.
  • Cellulose is suitable for this purpose, for example.
  • a binder 6 can be seen, which has been applied to the paper material layer 5 and impregnates it.
  • the binder 6 may be applied by means of a printing technology to the paper material layer 5, by one-sided or two-sided printing or by any other customary coating technology.
  • the paper material layer 5 is formed from a central position 5a, on both sides of which an outer layer 5b, 5c is attached.
  • the connection between central layer 5a and outer layers 5b and 5c may be done by Gautschen, for example.
  • Tear-resistant cotton paper for example, is suitable as the middle layer 5a, while cellulose paper can be used for the outer layers 5b and 5c.
  • the middle layer ensures stability and tear resistance.
  • the outer layers 5b and 5c ensure the absorption (absorption) of the binder 6.
  • the finished data sheet 1 is produced by laminating the illustrated components in the illustrated arrangement or stacking thereof.
  • the binder 6 may be dried before laminating, but this is not absolutely necessary.
  • the lamination takes place by means of a laminating device 7, which can be formed from two-layer laminating sheets 8 and 9. These are heated in a customary manner in a heating / cooling press combination under pressure and cooled.
  • Deviating from the presentation of Figures 1 and 2 can be provided in the region of the tab 4 no binder.
  • the tab 4 is given a comparatively higher flexibility.
  • a document 10 which contains a data sheet 1 according to the invention.
  • the further inner layers 12 may be formed from a paper material or from a synthetic organic polymer material. Likewise, commercially available composite materials for the further inner layers 12 can be used. It can be seen that the data sheet 1 with its flap 4 in the region of a seam 13 is sewn into the cover 11 together with the further inner layers 12.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Business, Economics & Management (AREA)
  • Educational Administration (AREA)
  • Educational Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Laminated Bodies (AREA)

Claims (12)

  1. Feuille de données (1) destinée à être intégrée dans un document de sécurité et/ou de valeur en forme de livret,
    dans laquelle ladite feuille de données (1) est formée d'au moins deux couches (2, 3) superposées, constituées d'un matériau polymère organique,
    dans laquelle une couche de matériau papier (5) est disposée au moins dans une partie située entre les couches (2, 3) ainsi qu'à l'extérieur desdites couches (2, 3) de manière à former une patte (4),
    dans laquelle la couche de matériau papier (5) est imprégnée au moins dans la partie située entre les couches (2, 3) au moins partiellement par un liant organique (6) et est assemblée auxdites deux couches (2, 3) par conjugaison de matières au moyen du liant (6).
  2. Feuille de données (1) selon la revendication 1, dans laquelle le matériau polymère organique est choisi parmi le groupe comprenant le PC (polycarbonate, en particulier bisphénol A polycarbonate), le PET (polytéréphtalate d'éthylèneglycol), le PMMA (polyméthacrylate de méthyle), le TPU (élastomères de polyuréthane thermoplastiques), le PE (polyéthylène), le PP (polypropylène), le PI (polyimide ou poly-transisoprène), le PVC (chlorure de polyvinyle), le polystyrène, les polyacrylates et méthacrylates, l'ester de vinyle, l'ABS et les copolymères de cesdits polymères, les copolymères de cyclooléfine, des polysulfones, le polyester, le PET, le PEN, les mélanges de polycarbonate/polyester, par ex. le PC/CoPET, le polycarbonate/polycyclohexylméthanol-cyclohexanedicarboxylate, en particulier des polycarbonates ou des copolycarbonates à base de diphénols, des poly- ou copolyacrylates, des poly-ou copolyméthacrylates, des poly- ou copolymères comportant du styrène, des polyuréthanes thermoplastiques, des polyoléfines, des poly- ou copolycondensats de l'acide téréphtalique ou de l'acide naphtalènedicarboxylique ou des mélanges de ceux-ci, de manière privilégiée des polycarbonates ou copolycarbonates à base de diphénols, des poly- ou copolyacrylates, des poly-ou copolyméthacrylates, des poly- ou copolycondensats de l'acide téréphtalique ou de l'acide naphtalènedicarboxylique ou des mélanges de ceux-ci.
  3. Feuille de données (1) selon la revendication 1 ou 2, dans laquelle le liant organique (6) est un dérivé de polycarbonate, en particulier à base de bisphénol A, de préférence à base d'un dihydroxy-diphényle-cycloalcane disubstitué de manière géminée.
  4. Feuille de données selon l'une quelconque des revendications 1 à 3, dans laquelle la couche de matériau papier (5) est formée essentiellement de manière homogène et absorbante en direction perpendiculaire aux faces principales, et dans laquelle la couche de matériau papier (5) est imprégnée par le liant organique (6).
  5. Feuille de données (1) selon l'une quelconque des revendications 1 à 3, dans laquelle la couche de matériau papier (5) est réalisée en plusieurs couches et présente au moins une couche centrale (5a) peu absorbante et, de chaque côté de ladite couche centrale (5a), respectivement une couche extérieure (5b, 5c) absorbante, reliée à cette dernière, la couche de matériau papier (5) étant imprégnée par le liant organique (6) dans la zone située entre les couches (2, 3) et/ou en dehors des couches (2, 3), essentiellement de manière exclusive dans les couches extérieures (5b, 5c).
  6. Feuille de données (1) selon l'une quelconque des revendications 1 à 5, dans laquelle le liant (6) et/ou la couche de matériau papier (5) contient en outre une ou plusieurs substances ou matériaux choisis parmi le groupe comprenant des pigments colorés, des pigments à effet, des pigments optiquement variables et des substances luminescentes ou pigments luminescents et/ou une ou plusieurs caractéristiques de sécurité choisies parmi le groupe comprenant des filigranes, des fibres chinées, des planchettes, des fils de sécurité et des fils à fenêtre.
  7. Feuille de données (1) selon l'une quelconque des revendications 1 à 5, dans laquelle est disposé, dans ou sur la couche de matériau papier (5), au moins un circuit électronique (7) pourvu d'une antenne (8) raccordée à ce dernier.
  8. Feuille de données (1) selon l'une quelconque des revendications 1 à 6, dans laquelle la couche de matériau papier (5) présente au moins un filigrane entre les couches (2, 3) et/ou à l'extérieur des couches (2, 3).
  9. Procédé destiné à la fabrication d'une feuille de données (1) selon l'une quelconque des revendications 1 à 8, lors duquel sont fournies deux couches (2, 3) à partir d'un matériau polymère organique et une couche de matériau papier (5),
    lors duquel sur au moins des parties d'une face d'une seule couche (2, 3) ou des deux couches (2, 3) et/ou sur des parties d'une seule face ou des deux faces de la couche de matériau papier (5) est appliqué, en particulier imprimé, un revêtement constitué d'un liant (6) liquide non durci,
    lors duquel les couches (2, 3) et la couche de matériau papier (5) sont superposées les unes aux autres et sont disposées de manière à présenter les unes aux autres leurs faces revêtues, et ce de telle sorte qu'une partie de la couche de matériau papier (5) fasse saillie, en tant que patte (4), vers l'extérieur par rapport aux deux couches (2, 3) ,
    lors duquel les couches (2, 3) et la couche de matériau papier (5) sont ensuite laminées de manière à les rendre solidaires, et
    lors duquel le liant (6) est durci ou réticulé.
  10. Procédé selon la revendication 9, lors duquel la patte (4) est pourvue de liant (6) ou ne présente pas de liant (6).
  11. Procédé selon l'une des revendications 9 ou 10, lors duquel le textile (5) est disposé uniquement dans une partie située entre les couches (2, 3).
  12. Document de sécurité et/ou de valeur renfermant une page de données (1) selon l'une quelconque des revendications 1 à 8, dans lequel la page de données (1) est intégrée, en particulier cousue ou collée, dans un dos de livret au moyen de la patte (4) .
EP14745064.7A 2013-08-29 2014-06-05 Feuille de données pour un document sécurisé et/ou de valeur Active EP3038838B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013014309.8A DE102013014309A1 (de) 2013-08-29 2013-08-29 Datenblatt für ein Sicherheits- und/oder Wertdokument
PCT/DE2014/000277 WO2015027971A2 (fr) 2013-08-29 2014-06-05 Feuille de données pour un document sécurisé et/ou de valeur

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EP3038838A2 EP3038838A2 (fr) 2016-07-06
EP3038838B1 true EP3038838B1 (fr) 2018-12-05

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EP (1) EP3038838B1 (fr)
CN (1) CN105473342B (fr)
DE (1) DE102013014309A1 (fr)
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WO (1) WO2015027971A2 (fr)

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FI3473451T4 (fi) * 2017-10-17 2024-07-22 Hid Global Ireland Teoranta Välilehti kirjamaiseen sähköiseen tunnistusasiakirjaan
WO2020116209A1 (fr) * 2018-12-03 2020-06-11 三菱ケミカル株式会社 Film multicouche pour impression laser, corps multicouche pour passeports électroniques, corps multicouche pour cartes plastiques, film pour cartes plastiques, carte plastique, feuille de données pour passeports électroniques et passeport électronique

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RU2016106000A3 (fr) 2018-02-28
WO2015027971A3 (fr) 2015-04-30
US10414192B2 (en) 2019-09-17
RU2016106000A (ru) 2017-10-04
EP3038838A2 (fr) 2016-07-06
CN105473342B (zh) 2018-11-20
CN105473342A (zh) 2016-04-06
DE102013014309A1 (de) 2015-03-05
US20160207343A1 (en) 2016-07-21
RU2660514C2 (ru) 2018-07-06
WO2015027971A2 (fr) 2015-03-05

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