EP3034178A1 - Dispensing head for a product dispensing system - Google Patents

Dispensing head for a product dispensing system Download PDF

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Publication number
EP3034178A1
EP3034178A1 EP15200284.6A EP15200284A EP3034178A1 EP 3034178 A1 EP3034178 A1 EP 3034178A1 EP 15200284 A EP15200284 A EP 15200284A EP 3034178 A1 EP3034178 A1 EP 3034178A1
Authority
EP
European Patent Office
Prior art keywords
product
dispensing head
dispensing
nozzle
head according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP15200284.6A
Other languages
German (de)
French (fr)
Other versions
EP3034178B1 (en
Inventor
Richard Bloc
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Silgan Dispensing Systems Le Treport SAS
Original Assignee
Albea Le Treport SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albea Le Treport SAS filed Critical Albea Le Treport SAS
Publication of EP3034178A1 publication Critical patent/EP3034178A1/en
Application granted granted Critical
Publication of EP3034178B1 publication Critical patent/EP3034178B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C3/00Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
    • B67C3/02Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
    • B67C3/06Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus using counterpressure, i.e. filling while the container is under pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/06Gas or vapour producing the flow, e.g. from a compressible bulb or air pump
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005Components or details
    • B05B11/0062Outlet valves actuated by the pressure of the fluid to be sprayed
    • B05B11/007Outlet valves actuated by the pressure of the fluid to be sprayed being opened by deformation of a sealing element made of resiliently deformable material, e.g. flaps, skirts, duck-bill valves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/0005Components or details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1042Components or details
    • B05B11/1043Sealing or attachment arrangements between pump and container
    • B05B11/1046Sealing or attachment arrangements between pump and container the pump chamber being arranged substantially coaxially to the neck of the container
    • B05B11/1047Sealing or attachment arrangements between pump and container the pump chamber being arranged substantially coaxially to the neck of the container the pump being preassembled as an independent unit before being mounted on the container
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D2200/00Details not otherwise provided for in A45D
    • A45D2200/05Details of containers
    • A45D2200/054Means for supplying liquid to the outlet of the container
    • A45D2200/057Spray nozzles; Generating atomised liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/75Aerosol containers not provided for in groups B65D83/16 - B65D83/74
    • B65D83/753Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by details or accessories associated with outlets
    • B65D83/7535Outlet valves opened by the product to be delivered

Definitions

  • the invention relates to a dispensing head for a product dispensing system, a dispensing system comprising such a head attached to a product pressurized tube and a bottle intended to contain a product to be dispensed at the dispenser. means of such a distribution system.
  • the fluid product is of the lotion, gel or cream type, for example for use in cosmetics or for pharmaceutical treatments.
  • Dispensing systems comprising a pump provided with a tube for feeding the product under pressure on which a push-button type distribution head is fixed to actuate the displacement of said tube over a dispensing / suction stroke of the product.
  • the dispensing head may comprise a body having a mounting well of said head on the feed tube and a product distribution path.
  • the distribution path opens into a dispensing space formed in a nozzle having an outlet passage of the product.
  • Cosmetics are becoming more and more fragile. In particular, they hardly withstand the mechanical or thermal stress (causing for example a phase shift), the contact of the air (causing for example desiccation, oxidation), and are easily contaminated by bacteria, yeasts and molds.
  • the formulators try to reinforce the intrinsic conservative activity of their products by adding ingredients with a conservative activity like certain essential oils, essences of orange, vitamin C, ... which are not declared as curators. Also, they limit the free activity of the water they are trying to keep low (AW ⁇ 0.6) so that the bacteria do not grow or little.
  • AW ⁇ 0.6 free activity of the water they are trying to keep low
  • the flasks must prevent microbiological contamination of the product, not only during storage but especially between two uses, and especially by retro-contamination from the outlet passage to the interior of the tank through the space of distribution.
  • dispensing heads whose outlet passage is equipped with a deformable membrane by pressure of the product on it, between a state respectively of closing and opening of said outlet passage.
  • the sealing of the closure between two distributions can be achieved by plating the flexible membrane on a rigid geometry.
  • the membrane plated in the outlet passage is in direct contact with the outside air, inducing a risk of rapid drying of the weak quantity of product disposed at the sealing interface.
  • the membrane tends to stick in closed state, an actuation of the distribution inducing a pressurization of the product in the distribution space to a sufficient value to ensure the separation, leading then to a sudden exit of the product through the passage thus opened.
  • the invention aims to improve the prior art by proposing in particular a dispensing head of simple design in which the distribution of the product is ensured by avoiding its microbial contamination between two uses, in particular by retro-contamination from the exit passage to the inside the tank, and this by maintaining a gradual return of the product during the actuation of the distribution even after a relatively prolonged non-use.
  • the invention proposes a dispensing head for a dispensing system of a product, said head comprising a body having a mounting well of said head on a tube for feeding the product under pressure. and a housing in communication with said well via a distribution path, said housing being equipped with a nozzle defining a distribution space between said path and an outlet passage formed in said nozzle, the nozzle being equipped with an insert having a membrane forming in the distribution space a communication interface between an upstream part in which the distribution path opens and a downstream part which feeds the outlet passage, said membrane being reversibly deformable by pressure of the product coming from of the upstream part, between a state at rest in which the dimension of the communication interface is minimal and a constrained state in which the A dimension of said interface is increased to ensure distribution, said nozzle being preferably capable of ensuring a microbiocidal or at least microbiostatic action on the product contained at least in the downstream part of the distribution space.
  • the invention proposes a system for dispensing a product, said system comprising such a dispensing head and a tube for feeding the product under pressure on which the mounting well of said head is fixed.
  • the invention proposes a bottle comprising a reservoir in which a product is intended to be packaged, said reservoir being equipped with such a dispensing system which is mounted so as to put the supply tube in communication with said reservoir for allowing the product to be conveyed from said feed tube to the outlet passage.
  • a pushbutton type dispensing head for a system for dispensing a product under pressure, for example in the form of a hazelnut or a continuous stream.
  • the fluid product is a lotion, a gel or a cream, for a cosmetic use or for pharmaceutical treatments.
  • the dispensing head comprises a body 1 having an annular skirt 2 which surrounds a well 3 for mounting said head on a feed tube under pressure of the product. Furthermore, the dispensing head comprises an upper zone 4 allowing the user to exert a digital support on said head in order to be able to move it axially.
  • the dispensing head is intended to equip a dispensing system which comprises a sampling device 5 provided with a tube 6 for feeding under pressure a product to be dispensed, on which the mounting shaft 3 of said head is fixed with sealing way to allow, by axial displacement of said head, the displacement of said tube on a dispensing / suction stroke of the product.
  • the sampling device 5 of the dispensing system may comprise a manually operated pump or, in the case where the product is packaged under pressure, a manually operated valve.
  • the pump or the valve is actuated to supply the feed tube 6 with pressure product.
  • a manually operated pump conventionally comprises a body in which are arranged means necessary for pressurizing the product to be dispensed.
  • the pump is of the type without air intake in compensation of the volume of product dispensed, so as not to introduce contaminant in the packaged product.
  • the dispensing system further comprises means, for example a hoop 7, to allow its mounting on the tank of a bottle 8 in which a product to be dispensed is intended to be packaged, and means for feeding the sampling device 5 in conditioned product, for example a dip tube disposed in the reservoir or, as shown in FIG. figure 1 , a supply piston 9 mounted slidably in the body of said reservoir so as to collect the product in said sampling device.
  • means for example a hoop 7, to allow its mounting on the tank of a bottle 8 in which a product to be dispensed is intended to be packaged
  • means for feeding the sampling device 5 in conditioned product for example a dip tube disposed in the reservoir or, as shown in FIG. figure 1 , a supply piston 9 mounted slidably in the body of said reservoir so as to collect the product in said sampling device.
  • the body 1 also has an annular housing 10 which is in communication with the mounting shaft 3 via a distribution path 11.
  • the housing 10 has an axis perpendicular to that of the well. mounting 3 to allow a lateral distribution of the product relative to the body 1.
  • the housing may be collinear with the mounting well, in particular for a distribution head forming nasal dispensing nozzle.
  • the housing 10 is equipped with a nozzle 12 delimiting a distribution space 13 between the distribution path 11 and an outlet passage 14 formed in said nozzle.
  • the housing 10 is provided with an anvil 15 around which the nozzle 12 is mounted to define the dispensing space 13, said anvil having at least one duct 16 in which at least part of the path distribution 11 extends.
  • the duct 16 extends axially in the central part of the anvil 15, in order to allow a central supply of the distribution space 13.
  • the distribution of the product is carried out by pressing on the body 1 to actuate the movement of said tube in order to convey the packaged product from the feed tube 6 to the exit passage 14.
  • the dispensing head can also be used for other types of dispensing.
  • the tank of the bottle 8 may comprise a flexible body, the pressurization of the product in the feed tube then taking place by bringing the walls of said tank closer together, without the use of a pump.
  • the nozzle 12 has a cylindrical side wall 12a of revolution which is closed forward by a distal wall 12b in which the outlet passage 14 is formed.
  • the association of the nozzle 12 in the housing 10 is formed by fitting of the side wall 12a.
  • the anvil 15 has a chamfer 15a formed on its front end.
  • the bottom of the housing 10 has a groove 17 which surrounds the anvil 15 and in which a rear portion of the side wall 12a is arranged to be mounted in tight contact between said anvil and a side wall of the housing 10.
  • At least the side wall 12a of the nozzle 12 may be made of a material whose rigidity is greater than the stiffness of the material forming the body 1.
  • the significant stiffness of the side wall 12a makes it possible to avoid its deformation during its mounting in the housing 10.
  • the lower stiffness of the body 1 provides improved sealing between the mounting well 3 and the feed tube 6.
  • the nozzle 12 is also equipped with an insert 18 which has a membrane 19 forming in the distribution space 13 a communication interface 20 between an upstream portion 13a into which the distribution path 11 opens and a downstream portion 13b which feeds the exit passage 14.
  • the membrane 19 is deformable reversibly by pressure of the product coming from the upstream part 13a, and this between a state at rest, in which the dimension of the communication interface 20 is minimal, and a constrained state, in which the dimension of said interface is increased to provide product distribution.
  • the insert 18 is made of a flexible material, in particular based on a thermoplastic elastomer (TPE) and / or a low density polyethylene (LDPE), such materials having good properties in terms of deformation reversible.
  • TPE thermoplastic elastomer
  • LDPE low density polyethylene
  • the membrane 19 has at least one deformable web 21 defining a communication interface 20 with an inner surface 22 extending on the internal face of the side wall 12a, said web being arranged to flex by pressure of the product on it by inducing a reduction the outer dimension of said web.
  • the insert 18 further has a central pin 23 around which the web 21 of the membrane 19 extends radially.
  • the insert 18 is disposed in the dispensing space 13 so that the central duct 16 of the anvil 15, and therefore the distribution path 11, opens out axially opposite the central pin 23, which allows a homogeneous angular distribution of the product leaving said path in the upstream portion 13a of the distribution space 13.
  • the membrane 19 has at least two, and in particular three webs 21 which each extend on an angular sector being angularly separated by a bridge 24, whose rigidity is greater than that of said sails, in particular to not to bend by pressure of the product on him.
  • the bridges 24 extend radially from the periphery of the central peg 23 by being angularly equilateral, so that the webs 21 have identical angular dimensions.
  • the webs 21 subjected to the pressure of said product deform in a homogeneous manner to allow a substantially symmetrical increase in the size of the communication interface. 20.
  • each sail 21 has a bellows 25 arranged to control its deformation under the effect of the pressure of the product.
  • the bellows 25 are arranged so that the diaphragm 19 in the stressed state comes to bear axially on the inside of the distal wall 12b maintaining a communication interface 20 between said support and said wall.
  • the bridges 24 each extend from a front portion of the central pin 23 and each have a front stop 24a which bears axially on the inside of the distal wall 12b, in particular under the effect of the pressure exerted by the product on the sails 21.
  • the front stops 24a extend axially beyond the front end 23a of the central pin 23, so as to prevent said front end from occulting the outlet passage 14, in particular in the event of significant pressure of the product in the upstream portion 13a.
  • the product may remain immobilized in the dispensing space 13, bringing it into contact with the potentially contaminating outside air by bacteria and / or fungi.
  • the outlet passage 14 into the dispensing space 13
  • at least the dose of product to be distributed later can be contaminated.
  • the nozzle 12 is furthermore capable of ensuring a microbiocidal or at least a microbiostatic action on the product contained at least in the downstream part 13b of the distribution space 13.
  • the product contained in the downstream portion 13b is more exposed to the outside air than the product contained in the upstream portion 13a, and therefore has greater risk of contamination by said air outside.
  • At least the surfaces of the nozzle 12 which delimit the downstream portion 13b are arranged to ensure a microbiocidal or at least microbiostatic action on the product.
  • the entire inner face of the side wall 12a can be arranged to ensure a microbiocidal or at least microbiostatic action on the product, to also allow a decontamination of the product contained in the upstream portion 13a.
  • the outer surface of the distal wall 12b is also capable of ensuring a microbiocidal or at least microbiostatic function to prevent the contamination of soil disposed on it between two distributions, thus ensuring that the product subsequently distributed is not contaminated by said defilements.
  • the side wall 14a delimiting the outlet passage 14 may be capable of ensuring a microbiocidal or at least microbiostatic function, since the product contained in the downstream part 13b between two distributions is also in contact with the outside air.
  • the outlet passage 14 has an orifice 26 which is delimited by a side wall 14a provided with at least one inner projection 27, and in particular of five internal projections 27, which allows the product to be dispensed in the form of a tablecloth stiffened.
  • a stiffening of the sheet of product to be dispensed is combined by means of the lateral projections 27 with an action against the contamination of the product of said sheet by the bacteria , yeasts and molds.
  • the sail 21 has, in connection with the figure 5b an outer dimension at rest which is less than the inner dimension of the inner bearing surface 22, to prevent contact of said web on said inner bearing surface.
  • the web 21 may have an outside dimension at rest which is substantially equal to the internal dimension of the surface 22.
  • the rest dimension of the communication interface 20 is substantially zero, which makes it possible to limit as much as possible the passage in the upstream portion 13a of external contaminants and / or undistributed product and potentially contaminated.
  • the insert 18 may also be capable of ensuring a microbiocidal or at least microbiostatic action on the product contained at least at the level of the communication interface 20.
  • the insert 18 may consist entirely of a material having microbiocidal or at least microbiostatic properties, so as to participate with the nozzle 12 in the decontamination of the product remaining in the downstream part 13b after use of the bottle 8, and thus avoid contamination by said product remaining product passing through said downstream part during a subsequent use of said bottle.
  • the nozzle 12 may in particular be made from at least one material having microbiocidal or at least microbiostatic properties, so that said nozzle is active relative to the inhibition by being hostile to microbial growth in the product disposed in its vicinity.
  • the microbiocidal or at least microbiostatic properties of the material are obtained by contacting the product with a microbiocidal or at least microbiostatic agent, for example by using a metallic material such as a copper or zinc alloy or a material comprising less a charge of such metal particles or having undergone a surface treatment by fluorination, zinc plating or copper plating.
  • a metallic material such as a copper or zinc alloy or a material comprising less a charge of such metal particles or having undergone a surface treatment by fluorination, zinc plating or copper plating.
  • the nozzle 12 may comprise metallic copper or a copper-based metal alloy which, by virtue of its microbiostatic properties, prevents the proliferation or eliminates contaminants in contact with said nozzle, and without migration into the product of a any antimicrobial agent.
  • the use of the nozzle 12 then makes it possible to locate the use of copper at the dispensing space, without having to copper and / or charge in copper particles the body 1 of the dispensing head.
  • the nozzle 12 comprises an alloy based on copper, nickel and zinc, in particular the CuNi 12 Zn 24 alloy, which also has good properties in terms of machining and corrosion resistance.
  • the nozzle 12 may be made entirely of metal copper or one of its alloys, in particular by stamping a sheet, such a solution having the particular advantage of being simple and inexpensive to achieve.
  • the nozzle 12 may be made of synthetic material, for example of the polyolefin type and in particular based on polypropylene (PP), of which at least one surface intended to delimit the distribution space 13 is metallized with a copper deposit or of one of his alloys.
  • PP polypropylene
  • the nozzle 12 is made of a synthetic material which is loaded with metallic copper particles with a charge rate sufficient for copper particles to be disposed on the surface to be in contact with the product.
  • the microbiocidal or at least microbiostatic properties of the material may also be obtained by diffusion in the product of an antimicrobial agent, for example on an organic base such as Trichlosan (commercial name of the company Melcoplast) or on silver base, or mineral.
  • an antimicrobial agent for example on an organic base such as Trichlosan (commercial name of the company Melcoplast) or on silver base, or mineral.
  • the material may comprise at least one polyolefin, for example polyethylene (PE), in particular at low density (LDPE), polypropylene (PP) and / or polystyrene, which is loaded with at least one antimicrobial agent.
  • microbiocidal or at least microbiostatic properties of the material may also be obtained by irradiation of the product with radiation of suitable wavelength, in particular by means of a material which exhibits photoluminescence properties after exposure to external light.
  • the material may be based on at least one polyolefin, for example low density polyethylene (LDPE), said polyolefin being charged with at least one additive capable of emitting photoluminescent radiation which has a wavelength between 250 and 260 nanometers, including 254 nanometers, which corresponds to the order of magnitude of sterilizing ultraviolet radiation.
  • LDPE low density polyethylene

Abstract

L'invention concerne une tête de distribution pour un système de distribution d'un produit, ladite tête comprenant un corps (1) présentant un puits de montage (3) de ladite tête sur un tube (6) d'amenée sous pression du produit et un logement (10) en communication avec ledit puits par l'intermédiaire d'un chemin de distribution (11), ledit logement étant équipé d'une buse (12) délimitant un espace de distribution (13) entre ledit chemin et un passage de sortie (14) formé dans ladite buse, la buse (12) étant équipée d'un insert (18) qui présente une membrane (19) formant dans l'espace (13) une interface de communication (20) entre une partie amont (13a) dans laquelle débouche le chemin (11) et une partie aval (13b) qui alimente le passage de sortie (14), ladite membrane étant déformable réversiblement par pression du produit provenant de la partie amont (13a), entre un état au repos dans lequel la dimension de l'interface (20) est minimale et un état contraint dans lequel la dimension de ladite interface est augmentée pour assurer la distribution, ladite buse étant préférentiellement apte à assurer une action microbiocide ou au moins microbiostatique sur le produit contenu au moins dans la partie aval (13b).The invention relates to a dispensing head for a dispensing system of a product, said head comprising a body (1) having a mounting well (3) of said head on a tube (6) for feeding the product under pressure. and a housing (10) in communication with said well via a distribution path (11), said housing being provided with a nozzle (12) defining a dispensing space (13) between said path and a passage outlet (14) formed in said nozzle, the nozzle (12) being equipped with an insert (18) which has a membrane (19) forming in the space (13) a communication interface (20) between an upstream part (13a) in which opens the path (11) and a downstream portion (13b) which feeds the outlet passage (14), said membrane being reversibly deformable by pressure of the product from the upstream portion (13a), between a state at rest in which the dimension of the interface (20) is minimal and a constrained state in which the dimension of said interface is increased to ensure distribution, said nozzle being preferably capable of ensuring a microbiocidal or at least microbiostatic action on the product contained at least in the downstream part (13b).

Description

L'invention concerne une tête de distribution pour un système de distribution d'un produit, un système de distribution comprenant une telle tête fixée sur un tube d'amenée sous pression du produit ainsi qu'un flacon destiné à contenir un produit à distribuer au moyen d'un tel système de distribution.The invention relates to a dispensing head for a product dispensing system, a dispensing system comprising such a head attached to a product pressurized tube and a bottle intended to contain a product to be dispensed at the dispenser. means of such a distribution system.

Dans une application particulière, le produit fluide est de type lotion, gel ou crème, par exemple pour une utilisation en cosmétique ou pour des traitements pharmaceutiques.In a particular application, the fluid product is of the lotion, gel or cream type, for example for use in cosmetics or for pharmaceutical treatments.

On connaît des systèmes de distribution comprenant une pompe pourvue d'un tube d'amenée sous pression du produit sur lequel une tête de distribution de type bouton poussoir est fixée pour actionner le déplacement dudit tube sur une course de distribution / aspiration du produit.Dispensing systems are known comprising a pump provided with a tube for feeding the product under pressure on which a push-button type distribution head is fixed to actuate the displacement of said tube over a dispensing / suction stroke of the product.

En particulier, la tête de distribution peut comprendre un corps présentant un puits de montage de ladite tête sur le tube d'amenée et un chemin de distribution du produit. Selon une réalisation, le chemin de distribution débouche dans un espace de distribution formé dans une buse présentant un passage de sortie du produit. Ainsi, par appui sur le corps de la tête de distribution, on actionne la pompe pour distribuer le produit au travers du passage de sortie sous la forme d'une noisette ou d'un flot continu.In particular, the dispensing head may comprise a body having a mounting well of said head on the feed tube and a product distribution path. In one embodiment, the distribution path opens into a dispensing space formed in a nozzle having an outlet passage of the product. Thus, by pressing on the body of the dispensing head, the pump is actuated to distribute the product through the outlet passage in the form of a hazelnut or a continuous stream.

A travers le monde, diverses directives visent à règlementer, maîtriser et limiter la présence de substances potentiellement dangereuses pour la santé humaine dans les produits notamment cosmétiques. L'une d'elles est la directive européenne REACh (Registration Evaluation and Authorisation of Chemicals). Aussi, une tendance environnementale pousse les cosméticiens à limiter, voire supprimer de leurs formules les conservateurs qui sont souvent cause d'allergies ou d'intolérances.Around the world, various directives aim to regulate, control and limit the presence of substances potentially dangerous for human health in products, especially cosmetics. One of them is the European REACh directive (Registration Evaluation and Authorization of Chemicals). Also, an environmental trend pushes cosmeticians to limit or eliminate from their formulas preservatives that are often cause allergies or intolerances.

Les produits cosmétiques deviennent donc de plus en plus fragiles. En particulier, ils supportent difficilement le stress mécanique ou thermique (causant par exemple un déphasage), le contact de l'air (causant par exemple un dessèchement, une oxydation), et sont facilement contaminables par les bactéries, levures et moisissures.Cosmetics are becoming more and more fragile. In particular, they hardly withstand the mechanical or thermal stress (causing for example a phase shift), the contact of the air (causing for example desiccation, oxidation), and are easily contaminated by bacteria, yeasts and molds.

Pour lutter contre ces contaminations, les formulateurs tentent de renforcer l'activité conservatrice intrinsèque de leurs produits en ajoutant des ingrédients ayant une activité conservatrice comme certaines huiles essentielles, des essences d'orange, de la vitamine C,... qui ne sont pas déclarés en tant que conservateurs. Aussi, ils limitent l'activité libre de l'eau qu'ils tentent de maintenir basse (AW<0,6) afin que les bactéries ne se développent pas ou peu. La norme NF 29621 décrit de tels moyens. Mais les formulateurs butent rapidement sur les limites d'une telle stratégie.To fight against these contaminations, the formulators try to reinforce the intrinsic conservative activity of their products by adding ingredients with a conservative activity like certain essential oils, essences of orange, vitamin C, ... which are not declared as curators. Also, they limit the free activity of the water they are trying to keep low (AW <0.6) so that the bacteria do not grow or little. The NF 29621 standard describes such means. But the formulators quickly stumble on the limits of such a strategy.

D'un autre côté, tant au niveau du réservoir dans lequel le produit est conditionné qu'au niveau de la tête de distribution, des flacons protecteurs apparaissent sur le marché. En particulier, les flacons doivent empêcher la contamination microbiologique du produit, non seulement lors du stockage mais surtout entre deux utilisations, et notamment par rétro-contamination depuis le passage de sortie vers l'intérieur du réservoir par l'intermédiaire de l'espace de distribution.On the other hand, both at the reservoir in which the product is conditioned and at the dispensing head, protective flasks appear on the market. In particular, the flasks must prevent microbiological contamination of the product, not only during storage but especially between two uses, and especially by retro-contamination from the outlet passage to the interior of the tank through the space of distribution.

Pour ce faire, on a proposé des têtes de distribution dont le passage de sortie est équipé d'une membrane déformable par pression du produit sur elle, entre un état respectivement de fermeture et d'ouverture dudit passage de sortie. En particulier, l'étanchéité de la fermeture entre deux distributions peut être réalisée par plaquage de la membrane souple sur une géométrie rigide.To do this, it has been proposed dispensing heads whose outlet passage is equipped with a deformable membrane by pressure of the product on it, between a state respectively of closing and opening of said outlet passage. In particular, the sealing of the closure between two distributions can be achieved by plating the flexible membrane on a rigid geometry.

Toutefois cette stratégie trouve sa limite dans l'impossibilité d'obtenir une interface de plaquage suffisamment intime pour empêcher les contaminants de très faibles tailles de pénétrer dans l'espace de distribution au travers de ladite interface.However, this strategy finds its limit in the impossibility of obtaining a plating interface sufficiently intimate to prevent contaminants of very small sizes from entering the dispensing space through said interface.

En outre, la membrane plaquée dans le passage de sortie est en contact direct avec l'air extérieur, induisant un risque de dessèchement rapide de la faible quantité de produit disposée au niveau de l'interface d'étanchéité. Ainsi, entre deux utilisations, a fortiori relativement espacées dans le temps, la membrane a tendance à venir se coller en état fermé, un actionnement de la distribution induisant une mise en pression du produit dans l'espace de distribution jusqu'à une valeur suffisante pour assurer le décollement, conduisant alors à une sortie brutale du produit au travers du passage ainsi ouvert.In addition, the membrane plated in the outlet passage is in direct contact with the outside air, inducing a risk of rapid drying of the weak quantity of product disposed at the sealing interface. Thus, between two uses, a fortiori relatively spaced in time, the membrane tends to stick in closed state, an actuation of the distribution inducing a pressurization of the product in the distribution space to a sufficient value to ensure the separation, leading then to a sudden exit of the product through the passage thus opened.

L'invention vise à perfectionner l'art antérieur en proposant notamment une tête de distribution de conception simple dans laquelle la distribution du produit est assurée en évitant sa contamination microbienne entre deux utilisations, notamment par rétro-contamination depuis le passage de sortie vers l'intérieur du réservoir, et ce en maintenant une restitution progressive du produit lors de l'actionnement de la distribution même après une non utilisation relativement prolongée.The invention aims to improve the prior art by proposing in particular a dispensing head of simple design in which the distribution of the product is ensured by avoiding its microbial contamination between two uses, in particular by retro-contamination from the exit passage to the inside the tank, and this by maintaining a gradual return of the product during the actuation of the distribution even after a relatively prolonged non-use.

A cet effet, selon un premier aspect, l'invention propose une tête de distribution pour un système de distribution d'un produit, ladite tête comprenant un corps présentant un puits de montage de ladite tête sur un tube d'amenée sous pression du produit et un logement en communication avec ledit puits par l'intermédiaire d'un chemin de distribution, ledit logement étant équipé d'une buse délimitant un espace de distribution entre ledit chemin et un passage de sortie formé dans ladite buse, la buse étant équipée d'un insert qui présente une membrane formant dans l'espace de distribution une interface de communication entre une partie amont dans laquelle débouche le chemin de distribution et une partie aval qui alimente le passage de sortie, ladite membrane étant déformable réversiblement par pression du produit provenant de la partie amont, entre un état au repos dans lequel la dimension de l'interface de communication est minimale et un état contraint dans lequel la dimension de ladite interface est augmentée pour assurer la distribution, ladite buse étant préférentiellement apte à assurer une action microbiocide ou au moins microbiostatique sur le produit contenu au moins dans la partie aval de l'espace de distribution.For this purpose, according to a first aspect, the invention proposes a dispensing head for a dispensing system of a product, said head comprising a body having a mounting well of said head on a tube for feeding the product under pressure. and a housing in communication with said well via a distribution path, said housing being equipped with a nozzle defining a distribution space between said path and an outlet passage formed in said nozzle, the nozzle being equipped with an insert having a membrane forming in the distribution space a communication interface between an upstream part in which the distribution path opens and a downstream part which feeds the outlet passage, said membrane being reversibly deformable by pressure of the product coming from of the upstream part, between a state at rest in which the dimension of the communication interface is minimal and a constrained state in which the A dimension of said interface is increased to ensure distribution, said nozzle being preferably capable of ensuring a microbiocidal or at least microbiostatic action on the product contained at least in the downstream part of the distribution space.

Selon un deuxième aspect, l'invention propose un système de distribution d'un produit, ledit système comprenant une telle tête de distribution et un tube d'amenée sous pression du produit sur lequel le puits de montage de ladite tête est fixé.According to a second aspect, the invention proposes a system for dispensing a product, said system comprising such a dispensing head and a tube for feeding the product under pressure on which the mounting well of said head is fixed.

Selon un troisième aspect, l'invention propose un flacon comprenant un réservoir dans lequel un produit est destiné à être conditionné, ledit réservoir étant équipé d'un tel système de distribution qui est monté de sorte à mettre le tube d'amenée en communication avec ledit réservoir pour permettre l'acheminement du produit depuis ledit tube d'amenée vers le passage de sortie.According to a third aspect, the invention proposes a bottle comprising a reservoir in which a product is intended to be packaged, said reservoir being equipped with such a dispensing system which is mounted so as to put the supply tube in communication with said reservoir for allowing the product to be conveyed from said feed tube to the outlet passage.

D'autres objets et avantages de l'invention apparaîtront dans la description qui suit, faite en référence aux figures annexées, dans lesquelles :

  • la figure 1 est une vue en coupe longitudinale d'un flacon de distribution selon un mode de réalisation de l'invention ;
  • les figures 2 sont des vues de la tête de distribution du flacon de la figure 1, respectivement en perspective éclatée (figure 2a) et en coupe longitudinale (figure 2b) ;
  • la figure 3 est une vue en perspective montrant l'intérieur de la buse équipant la tête de distribution des figures 2 ;
  • les figures 4 sont des vues en perspective de l'insert équipant la tête de distribution des figures 2, respectivement orienté par l'arrière (figure 4a) et orienté par l'avant (figure 4b) ;
  • les figures 5 et 6 sont des représentations de la disposition de l'insert des figures 4 dans la buse de la figure 3, montrant l'insert en état au repos (figures 5) et en état contraint (figures 6), respectivement en vue arrière (figures 5a, 6a) et en coupe longitudinale (figures 5b, 6b).
Other objects and advantages of the invention will appear in the description which follows, made with reference to the appended figures, in which:
  • the figure 1 is a longitudinal sectional view of a dispensing bottle according to one embodiment of the invention;
  • the figures 2 are views of the dispensing head of the bottle of the figure 1 , respectively in exploded perspective ( figure 2a ) and in longitudinal section ( figure 2b );
  • the figure 3 is a perspective view showing the inside of the nozzle equipping the distribution head of the figures 2 ;
  • the figures 4 are perspective views of the insert equipping the distribution head of the figures 2 , respectively oriented by the rear ( figure 4a ) and oriented from the front ( figure 4b );
  • the Figures 5 and 6 are representations of the layout of the insert of the figures 4 in the nozzle of the figure 3 , showing the insert in a state of rest ( figures 5 ) and in a constrained state ( figures 6 ), respectively in rear view ( Figures 5a, 6a ) and in longitudinal section ( Figures 5b, 6b ).

En relation avec les figures, on décrit une tête de distribution de type bouton poussoir pour un système de distribution d'un produit sous pression, par exemple sous la forme d'une noisette ou d'un flot continu. Dans un exemple d'application, le produit fluide est une lotion, un gel ou une crème, pour un usage cosmétique ou pour des traitements pharmaceutiques.In connection with the figures, there is described a pushbutton type dispensing head for a system for dispensing a product under pressure, for example in the form of a hazelnut or a continuous stream. In an example for application, the fluid product is a lotion, a gel or a cream, for a cosmetic use or for pharmaceutical treatments.

La tête de distribution comprend un corps 1 présentant une jupe annulaire 2 qui entoure un puits 3 de montage de ladite tête sur un tube d'amenée sous pression du produit. Par ailleurs, la tête de distribution comprend une zone supérieure 4 permettant à l'utilisateur d'exercer un appui digital sur ladite tête afin de pouvoir la déplacer axialement.The dispensing head comprises a body 1 having an annular skirt 2 which surrounds a well 3 for mounting said head on a feed tube under pressure of the product. Furthermore, the dispensing head comprises an upper zone 4 allowing the user to exert a digital support on said head in order to be able to move it axially.

La tête de distribution est destinée à équiper un système de distribution qui comprend un dispositif de prélèvement 5 pourvu d'un tube 6 d'amenée sous pression d'un produit à distribuer, sur lequel le puits de montage 3 de ladite tête est fixé de façon étanche pour permettre, par déplacement axial de ladite tête, le déplacement dudit tube sur une course de distribution / aspiration du produit.The dispensing head is intended to equip a dispensing system which comprises a sampling device 5 provided with a tube 6 for feeding under pressure a product to be dispensed, on which the mounting shaft 3 of said head is fixed with sealing way to allow, by axial displacement of said head, the displacement of said tube on a dispensing / suction stroke of the product.

Le dispositif de prélèvement 5 du système de distribution peut comprendre une pompe à actionnement manuel ou, dans le cas où le produit est conditionné sous pression, une valve à actionnement manuel. Ainsi, lors d'un déplacement manuel de la tête de distribution, la pompe ou la valve est actionnée pour alimenter le tube d'amenée 6 en produit sous pression.The sampling device 5 of the dispensing system may comprise a manually operated pump or, in the case where the product is packaged under pressure, a manually operated valve. Thus, during a manual movement of the dispensing head, the pump or the valve is actuated to supply the feed tube 6 with pressure product.

En particulier, une pompe à actionnement manuel comprend classiquement un corps dans lequel sont disposés des moyens nécessaires pour la mise sous pression du produit à distribuer. Selon une réalisation particulière, la pompe est de type sans reprise d'air en compensation du volume de produit distribué, de sorte à ne pas introduire de contaminant dans le produit conditionné.In particular, a manually operated pump conventionally comprises a body in which are arranged means necessary for pressurizing the product to be dispensed. According to a particular embodiment, the pump is of the type without air intake in compensation of the volume of product dispensed, so as not to introduce contaminant in the packaged product.

De façon connue, le système de distribution comprend par ailleurs des moyens, par exemple une frette 7, pour permettre son montage sur le réservoir d'un flacon 8 dans lequel un produit à distribuer est destiné à être conditionné, ainsi que des moyens pour alimenter le dispositif de prélèvement 5 en produit conditionné, par exemple un tube plongeur disposé dans le réservoir ou, comme représenté sur la figure 1, un piston 9 d'amenée monté coulissant dans le corps dudit réservoir de sorte à rassembler le produit dans ledit dispositif de prélèvement.In known manner, the dispensing system further comprises means, for example a hoop 7, to allow its mounting on the tank of a bottle 8 in which a product to be dispensed is intended to be packaged, and means for feeding the sampling device 5 in conditioned product, for example a dip tube disposed in the reservoir or, as shown in FIG. figure 1 , a supply piston 9 mounted slidably in the body of said reservoir so as to collect the product in said sampling device.

Le corps 1 présente également un logement annulaire 10 qui est en communication avec le puits de montage 3 par l'intermédiaire d'un chemin de distribution 11. Dans le mode de réalisation représenté, le logement 10 est d'axe perpendiculaire à celui du puits de montage 3 pour permettre une distribution latérale du produit relativement au corps 1. En variante non représentée, le logement peut être colinéaire au puits de montage, notamment pour une tête de distribution formant embout nasal de distribution.The body 1 also has an annular housing 10 which is in communication with the mounting shaft 3 via a distribution path 11. In the embodiment shown, the housing 10 has an axis perpendicular to that of the well. mounting 3 to allow a lateral distribution of the product relative to the body 1. In a variant not shown, the housing may be collinear with the mounting well, in particular for a distribution head forming nasal dispensing nozzle.

Le logement 10 est équipé d'une buse 12 délimitant un espace de distribution 13 entre le chemin de distribution 11 et un passage de sortie 14 formé dans ladite buse. Dans le mode de réalisation représenté, le logement 10 est pourvu d'une enclume 15 autour de laquelle la buse 12 est montée pour délimiter l'espace de distribution 13, ladite enclume présentant au moins un conduit 16 dans lequel au moins une partie du chemin de distribution 11 s'étend. En particulier, le conduit 16 s'étend axialement dans la partie centrale de l'enclume 15, afin de permettre une alimentation centrale de l'espace de distribution 13.The housing 10 is equipped with a nozzle 12 delimiting a distribution space 13 between the distribution path 11 and an outlet passage 14 formed in said nozzle. In the embodiment shown, the housing 10 is provided with an anvil 15 around which the nozzle 12 is mounted to define the dispensing space 13, said anvil having at least one duct 16 in which at least part of the path distribution 11 extends. In particular, the duct 16 extends axially in the central part of the anvil 15, in order to allow a central supply of the distribution space 13.

Ainsi, en fixant le puits de montage 3 sur le tube d'amenée 6, la distribution du produit est réalisée par appui sur le corps 1 pour actionner le déplacement dudit tube afin d'acheminer le produit conditionné depuis le tube d'amenée 6 vers le passage de sortie 14.Thus, by fixing the mounting well 3 on the feed tube 6, the distribution of the product is carried out by pressing on the body 1 to actuate the movement of said tube in order to convey the packaged product from the feed tube 6 to the exit passage 14.

La tête de distribution peut également être utilisée pour d'autres types de distribution. En particulier, le réservoir du flacon 8 peut comprendre un corps souple, la mise en pression du produit dans le tube d'amenée s'effectuant alors par rapprochement des parois dudit réservoir, sans mise en oeuvre d'une pompe.The dispensing head can also be used for other types of dispensing. In particular, the tank of the bottle 8 may comprise a flexible body, the pressurization of the product in the feed tube then taking place by bringing the walls of said tank closer together, without the use of a pump.

Dans les modes de réalisation représentés, la buse 12 présente une paroi latérale 12a cylindrique de révolution qui est fermée vers l'avant par une paroi distale 12b dans laquelle le passage de sortie 14 est formé.In the embodiments shown, the nozzle 12 has a cylindrical side wall 12a of revolution which is closed forward by a distal wall 12b in which the outlet passage 14 is formed.

L'association de la buse 12 dans le logement 10 est réalisée par emmanchement de la paroi latérale 12a. Pour ce faire, l'enclume 15 présente un chanfrein 15a formé sur son extrémité avant. En outre, le fond du logement 10 présente une gorge 17 qui entoure l'enclume 15 et dans laquelle une partie arrière de la paroi latérale 12a est disposée afin d'être montée en contact serrant entre ladite enclume et une paroi latérale du logement 10.The association of the nozzle 12 in the housing 10 is formed by fitting of the side wall 12a. To do this, the anvil 15 has a chamfer 15a formed on its front end. In addition, the bottom of the housing 10 has a groove 17 which surrounds the anvil 15 and in which a rear portion of the side wall 12a is arranged to be mounted in tight contact between said anvil and a side wall of the housing 10.

De façon avantageuse, au moins la paroi latérale 12a de la buse 12 peut être réalisée en un matériau dont la rigidité est supérieure à la rigidité du matériau formant le corps 1. Ainsi, la raideur importante de la paroi latérale 12a permet d'éviter sa déformation lors de son montage dans le logement 10. En outre, la raideur moins importante du corps 1 permet une étanchéité améliorée entre le puits de montage 3 et le tube d'amenée 6.Advantageously, at least the side wall 12a of the nozzle 12 may be made of a material whose rigidity is greater than the stiffness of the material forming the body 1. Thus, the significant stiffness of the side wall 12a makes it possible to avoid its deformation during its mounting in the housing 10. In addition, the lower stiffness of the body 1 provides improved sealing between the mounting well 3 and the feed tube 6.

La buse 12 est en outre équipée d'un insert 18 qui présente une membrane 19 formant dans l'espace de distribution 13 une interface 20 de communication entre une partie amont 13a dans laquelle débouche le chemin de distribution 11 et une partie aval 13b qui alimente le passage de sortie 14.The nozzle 12 is also equipped with an insert 18 which has a membrane 19 forming in the distribution space 13 a communication interface 20 between an upstream portion 13a into which the distribution path 11 opens and a downstream portion 13b which feeds the exit passage 14.

En particulier, la membrane 19 est déformable réversiblement par pression du produit provenant de la partie amont 13a, et ce entre un état au repos, dans lequel la dimension de l'interface de communication 20 est minimale, et un état contraint, dans lequel la dimension de ladite interface est augmentée pour assurer la distribution de produit.In particular, the membrane 19 is deformable reversibly by pressure of the product coming from the upstream part 13a, and this between a state at rest, in which the dimension of the communication interface 20 is minimal, and a constrained state, in which the dimension of said interface is increased to provide product distribution.

Pour ce faire, l'insert 18 est réalisé en un matériau souple, notamment à base d'un élastomère thermoplastique (TPE) et/ou d'un polyéthylène basse densité (PEBD), de tels matériaux présentant de bonnes propriétés en termes de déformation réversible.To do this, the insert 18 is made of a flexible material, in particular based on a thermoplastic elastomer (TPE) and / or a low density polyethylene (LDPE), such materials having good properties in terms of deformation reversible.

La membrane 19 présente au moins un voile déformable 21 délimitant une interface de communication 20 avec une portée intérieure 22 s'étendant sur la face interne de la paroi latérale 12a, ledit voile étant agencé pour fléchir par pression du produit sur lui en induisant une réduction de la dimension extérieure dudit voile.The membrane 19 has at least one deformable web 21 defining a communication interface 20 with an inner surface 22 extending on the internal face of the side wall 12a, said web being arranged to flex by pressure of the product on it by inducing a reduction the outer dimension of said web.

L'insert 18 présente en outre un pion central 23 autour duquel le voile 21 de la membrane 19 s'étend radialement. En particulier, l'insert 18 est disposé dans l'espace de distribution 13 de manière à ce que le conduit central 16 de l'enclume 15, et donc le chemin de distribution 11, débouche axialement en regard du pion central 23, ce qui permet une répartition angulaire homogène du produit sortant dudit chemin dans la partie amont 13a de l'espace de distribution 13.The insert 18 further has a central pin 23 around which the web 21 of the membrane 19 extends radially. In particular, the insert 18 is disposed in the dispensing space 13 so that the central duct 16 of the anvil 15, and therefore the distribution path 11, opens out axially opposite the central pin 23, which allows a homogeneous angular distribution of the product leaving said path in the upstream portion 13a of the distribution space 13.

Selon un mode de réalisation, la membrane 19 présente au moins deux, et notamment trois voiles 21 qui s'étendent chacun sur un secteur angulaire en étant séparés angulairement par un pont 24, dont la rigidité est supérieure à celle desdits voiles, notamment pour ne pas fléchir par pression du produit sur lui.According to one embodiment, the membrane 19 has at least two, and in particular three webs 21 which each extend on an angular sector being angularly separated by a bridge 24, whose rigidity is greater than that of said sails, in particular to not to bend by pressure of the product on him.

En relation avec les figures, les ponts 24 s'étendent radialement depuis la périphérie du pion central 23 en étant angulairement équirépartis, de manière à ce que les voiles 21 présentent des dimensions angulaires identiques. Ainsi, grâce à leur agencement identique et à la répartition angulaire homogène du produit dans la partie amont 13a, les voiles 21 soumis à la pression dudit produit se déforment de façon homogène pour permettre une augmentation sensiblement symétrique de la dimension de l'interface de communication 20.In relation to the figures, the bridges 24 extend radially from the periphery of the central peg 23 by being angularly equilateral, so that the webs 21 have identical angular dimensions. Thus, thanks to their identical arrangement and the homogeneous angular distribution of the product in the upstream part 13a, the webs 21 subjected to the pressure of said product deform in a homogeneous manner to allow a substantially symmetrical increase in the size of the communication interface. 20.

Comme représenté notamment sur les figures 4, chaque voile 21 présente un soufflet 25 agencé pour contrôler sa déformation sous l'effet de la pression du produit. En particulier, en relation avec les figures 6, les soufflets 25 sont agencés pour que la membrane 19 en état contraint vienne en appui axial sur l'intérieur de la paroi distale 12b en maintenant une interface de communication 20 entre ledit appui et ladite paroi.As represented in particular on figures 4 each sail 21 has a bellows 25 arranged to control its deformation under the effect of the pressure of the product. In particular, in relation to figures 6 , the bellows 25 are arranged so that the diaphragm 19 in the stressed state comes to bear axially on the inside of the distal wall 12b maintaining a communication interface 20 between said support and said wall.

En outre, les ponts 24 s'étendent chacun depuis une portion avant du pion central 23 et présentent chacun une butée avant 24a qui est en appui axial sur l'intérieur de la paroi distale 12b, notamment sous l'effet de la pression exercée par le produit sur les voiles 21. En particulier, les butées avant 24a s'étendent axialement au-delà de l'extrémité avant 23a du pion central 23, de sorte à éviter que ladite extrémité avant ne vienne occulter le passage de sortie 14, notamment en cas de pression importante du produit en partie amont 13a.In addition, the bridges 24 each extend from a front portion of the central pin 23 and each have a front stop 24a which bears axially on the inside of the distal wall 12b, in particular under the effect of the pressure exerted by the product on the sails 21. In particular, the front stops 24a extend axially beyond the front end 23a of the central pin 23, so as to prevent said front end from occulting the outlet passage 14, in particular in the event of significant pressure of the product in the upstream portion 13a.

Entre deux distributions, du produit peut rester immobilisé dans l'espace de distribution 13, le mettant en contact avec l'air extérieur potentiellement contaminant par des bactéries et/ou des champignons. Ainsi, par rétrodiffusion depuis le passage de sortie 14 dans l'espace de distribution 13, au moins la dose de produit à distribuer ultérieurement peut être contaminée.Between two distributions, the product may remain immobilized in the dispensing space 13, bringing it into contact with the potentially contaminating outside air by bacteria and / or fungi. Thus, by backscattering from the outlet passage 14 into the dispensing space 13, at least the dose of product to be distributed later can be contaminated.

Pour limiter cette contamination, la buse 12 est en outre apte à assurer une action microbiocide ou au moins microbiostatique sur le produit contenu au moins dans la partie aval 13b de l'espace de distribution 13. En effet, du fait de la présence de l'insert 18 et de la proximité du passage de sortie 14, le produit contenu dans la partie aval 13b est plus exposé à l'air extérieur que le produit contenu dans la partie amont 13a, et présente donc plus de risque de contamination par ledit air extérieur.To limit this contamination, the nozzle 12 is furthermore capable of ensuring a microbiocidal or at least a microbiostatic action on the product contained at least in the downstream part 13b of the distribution space 13. In fact, because of the presence of the insert 18 and the proximity of the outlet passage 14, the product contained in the downstream portion 13b is more exposed to the outside air than the product contained in the upstream portion 13a, and therefore has greater risk of contamination by said air outside.

Pour ce faire, au moins les surfaces de la buse 12 qui délimitent la partie aval 13b, c'est-à-dire la surface intérieure de la paroi distale 12b et la portée intérieure 22 délimitant l'interface de communication 20, sont agencées pour assurer une action microbiocide ou au moins microbiostatique sur le produit. En variante, toute la face interne de la paroi latérale 12a peut être agencée pour pouvoir assurer une action microbiocide ou au moins microbiostatique sur le produit, afin de permettre également une décontamination du produit contenu dans la partie amont 13a.To do this, at least the surfaces of the nozzle 12 which delimit the downstream portion 13b, that is to say the inner surface of the distal wall 12b and the inner surface 22 delimiting the communication interface 20, are arranged to ensure a microbiocidal or at least microbiostatic action on the product. Alternatively, the entire inner face of the side wall 12a can be arranged to ensure a microbiocidal or at least microbiostatic action on the product, to also allow a decontamination of the product contained in the upstream portion 13a.

De façon avantageuse, la surface extérieure de la paroi distale 12b est également apte à assurer une fonction microbiocide ou au moins microbiostatique pour empêcher la contamination des souillures disposées sur elle entre deux distributions, assurant ainsi que le produit distribué ultérieurement ne soit pas contaminé par lesdites souillures.Advantageously, the outer surface of the distal wall 12b is also capable of ensuring a microbiocidal or at least microbiostatic function to prevent the contamination of soil disposed on it between two distributions, thus ensuring that the product subsequently distributed is not contaminated by said defilements.

De même, la paroi latérale 14a délimitant le passage de sortie 14 peut être apte à assurer une fonction microbiocide ou au moins microbiostatique, puisque le produit contenu dans la partie aval 13b entre deux distributions est également en contact avec l'air extérieur.Similarly, the side wall 14a delimiting the outlet passage 14 may be capable of ensuring a microbiocidal or at least microbiostatic function, since the product contained in the downstream part 13b between two distributions is also in contact with the outside air.

En relation avec la figure 3, le passage de sortie 14 présente un orifice 26 qui est délimité par une paroi latérale 14a pourvue d'au moins une saillie intérieure 27, et notamment de cinq saillies intérieures 27, ce qui permet de distribuer le produit sous la forme d'une nappe rigidifiée. Ainsi, lorsque la paroi latérale 14a est apte à assurer une fonction microbiocide ou au moins microbiostatique, on combine une rigidification de la nappe de produit à distribuer au moyen des saillies latérales 27 avec une action contre la contamination du produit de ladite nappe par les bactéries, levures et moisissures.In relation to the figure 3 , the outlet passage 14 has an orifice 26 which is delimited by a side wall 14a provided with at least one inner projection 27, and in particular of five internal projections 27, which allows the product to be dispensed in the form of a tablecloth stiffened. Thus, when the side wall 14a is capable of ensuring a microbiocidal or at least microbiostatic function, a stiffening of the sheet of product to be dispensed is combined by means of the lateral projections 27 with an action against the contamination of the product of said sheet by the bacteria , yeasts and molds.

En particulier, on assure la décontamination du produit qui, entre deux distributions, est localisé au voisinage du passage de sortie 14 et on empêche la pénétration des bactéries, levures et moisissures dans le flacon 8 par l'intermédiaire du chemin de distribution 11.In particular, it ensures the decontamination of the product which, between two distributions, is located in the vicinity of the outlet passage 14 and it prevents the penetration of bacteria, yeasts and molds in the bottle 8 via the distribution path 11.

Par ailleurs, du fait de la dimension minimale de l'interface de communication 20 entre deux distributions, on limite le passage dans la partie amont 13a des contaminants de très faible taille provenant de l'extérieur, et a fortiori du produit restant dans la partie aval 13b qui en est potentiellement infesté. Ainsi, le risque de rétro-contamination depuis le passage de sortie 14 vers l'intérieur du réservoir est limité.Furthermore, because of the minimum dimension of the communication interface 20 between two distributions, it limits the passage in the upstream portion 13a of very small contaminants from the outside, and a fortiori the product remaining in the part downstream 13b which is potentially infested. Thus, the risk of retro-contamination from the outlet passage 14 to the interior of the tank is limited.

En outre, dans la mesure où la membrane 19 régulant le passage de produit à distribuer est disposée dans la buse 12, c'est-à-dire dans un espace relativement fermé, le contact de ladite membrane avec l'air extérieur est limité, ce qui permet de réduire le risque de dessèchement de la faible quantité de produit disposé au niveau de l'interface 20 formée par ladite membrane. Ainsi, on limite le risque d'adhérence de la membrane 19 à la portée intérieure 22 en état de repos, et donc le risque de surpression et de sortie brutale du produit à distribuer ultérieurement.In addition, insofar as the membrane 19 regulating the passage of product to be dispensed is disposed in the nozzle 12, that is to say in a relatively closed space, the contact of said membrane with the outside air is limited, which makes it possible to reduce the risk of drying out the small quantity of product disposed at the interface 20 formed by said membrane. Thus, it limits the risk of adhesion of the membrane 19 to the inner bearing 22 in the rest state, and therefore the risk of overpressure and sudden output of the product to be distributed later.

Pour limiter davantage le risque d'adhésion de la membrane 19 à la portée intérieure 22, le voile 21 présente, en relation avec la figure 5b, une dimension extérieure au repos qui est inférieure à la dimension intérieure de la portée intérieure 22, afin d'empêcher une mise en contact dudit voile sur ladite portée intérieure.To further limit the risk of adhesion of the diaphragm 19 to the inner bearing 22, the sail 21 has, in connection with the figure 5b an outer dimension at rest which is less than the inner dimension of the inner bearing surface 22, to prevent contact of said web on said inner bearing surface.

En variante, le voile 21 peut présenter une dimension extérieure au repos qui est sensiblement égale à la dimension intérieure de la portée 22. Ainsi, la dimension au repos de l'interface de communication 20 est sensiblement nulle, ce qui permet de limiter au maximum le passage dans la partie amont 13a de contaminants extérieurs et/ou de produit non distribué et potentiellement contaminé.As a variant, the web 21 may have an outside dimension at rest which is substantially equal to the internal dimension of the surface 22. Thus, the rest dimension of the communication interface 20 is substantially zero, which makes it possible to limit as much as possible the passage in the upstream portion 13a of external contaminants and / or undistributed product and potentially contaminated.

Par ailleurs, l'insert 18 peut également être apte à assurer une action microbiocide ou au moins microbiostatique sur le produit contenu au moins au niveau de l'interface de communication 20. En particulier, l'insert 18 peut être entièrement constitué d'un matériau présentant des propriétés microbiocides ou au moins microbiostatiques, de sorte à participer avec la buse 12 à la décontamination du produit restant dans la partie aval 13b après une utilisation du flacon 8, et ainsi éviter la contamination par ledit produit restant du produit passant dans ladite partie aval lors d'une utilisation ultérieure dudit flacon.Furthermore, the insert 18 may also be capable of ensuring a microbiocidal or at least microbiostatic action on the product contained at least at the level of the communication interface 20. In particular, the insert 18 may consist entirely of a material having microbiocidal or at least microbiostatic properties, so as to participate with the nozzle 12 in the decontamination of the product remaining in the downstream part 13b after use of the bottle 8, and thus avoid contamination by said product remaining product passing through said downstream part during a subsequent use of said bottle.

Pour pouvoir assurer une action microbiocide ou au moins microbiostatique, la buse 12 peut notamment être réalisée à base d'au moins un matériau présentant des propriétés microbiocides ou au moins microbiostatiques, afin que ladite buse soit active relativement à l'inhibition en étant hostile au développement microbien dans le produit disposé dans son voisinage.In order to be able to ensure a microbiocidal or at least microbiostatic action, the nozzle 12 may in particular be made from at least one material having microbiocidal or at least microbiostatic properties, so that said nozzle is active relative to the inhibition by being hostile to microbial growth in the product disposed in its vicinity.

Selon une réalisation, les propriétés microbiocides ou au moins microbiostatiques du matériau sont obtenues par contact du produit avec un agent microbiocide ou au moins microbiostatique, par exemple en utilisant un matériau métallique tel qu'un alliage de cuivre ou de zinc ou un matériau comprenant au moins une charge de telles particules métalliques ou ayant subi un traitement de surface par fluoration, zingage ou cuivrage.According to one embodiment, the microbiocidal or at least microbiostatic properties of the material are obtained by contacting the product with a microbiocidal or at least microbiostatic agent, for example by using a metallic material such as a copper or zinc alloy or a material comprising less a charge of such metal particles or having undergone a surface treatment by fluorination, zinc plating or copper plating.

En particulier, la buse 12 peut comprendre du cuivre métallique ou un alliage à base de cuivre métallique qui, de par ses propriétés microbiostatiques, empêche la prolifération voire élimine les contaminants en contact avec ladite buse, et ce sans migration dans le produit d'un quelconque agent antimicrobien. L'utilisation de la buse 12 permet alors de localiser l'utilisation du cuivre au niveau de l'espace de distribution, sans avoir à cuivrer et/ou charger en particules de cuivre le corps 1 de la tête de distribution.In particular, the nozzle 12 may comprise metallic copper or a copper-based metal alloy which, by virtue of its microbiostatic properties, prevents the proliferation or eliminates contaminants in contact with said nozzle, and without migration into the product of a any antimicrobial agent. The use of the nozzle 12 then makes it possible to locate the use of copper at the dispensing space, without having to copper and / or charge in copper particles the body 1 of the dispensing head.

De façon particulièrement avantageuse, la buse 12 comprend un alliage à base de cuivre, de nickel et de zinc, notamment l'alliage CuNi12Zn24, qui présente en outre de bonnes propriétés en termes d'usinage et de résistance à la corrosion.Particularly advantageously, the nozzle 12 comprises an alloy based on copper, nickel and zinc, in particular the CuNi 12 Zn 24 alloy, which also has good properties in terms of machining and corrosion resistance.

En particulier, la buse 12 peut être réalisée entièrement en cuivre métallique ou en un de ses alliages, notamment par mise en forme par emboutissage d'une feuille, une telle solution présentant notamment l'avantage d'être simple et peu coûteuse à réaliser.In particular, the nozzle 12 may be made entirely of metal copper or one of its alloys, in particular by stamping a sheet, such a solution having the particular advantage of being simple and inexpensive to achieve.

En variante, la buse 12 peut être réalisée en matériau synthétique, par exemple de type polyoléfine et notamment à base de polypropylène (PP), dont au moins une surface destinée à délimiter l'espace de distribution 13 est métallisée avec un dépôt de cuivre ou d'un de ses alliages.As a variant, the nozzle 12 may be made of synthetic material, for example of the polyolefin type and in particular based on polypropylene (PP), of which at least one surface intended to delimit the distribution space 13 is metallized with a copper deposit or of one of his alloys.

Selon une autre réalisation, la buse 12 est réalisée en un matériau synthétique qui est chargé en particules de cuivre métallique avec un taux de charge suffisant pour que des particules de cuivre soient disposées sur la surface pour être en contact avec le produit.In another embodiment, the nozzle 12 is made of a synthetic material which is loaded with metallic copper particles with a charge rate sufficient for copper particles to be disposed on the surface to be in contact with the product.

Les propriétés microbiocides ou au moins microbiostatiques du matériau peuvent également être obtenues par diffusion dans le produit d'un agent antimicrobien, par exemple sur base organique tel que le Trichlosan (dénomination commerciale de la société Melcoplast) ou sur base argent, ou encore minérale. En particulier, le matériau peut comprendre au moins une polyoléfine, par exemple du polyéthylène (PE), notamment à basse densité (PEBD), du polypropylène (PP) et/ou du polystyrène, qui est chargée avec au moins un agent antimicrobien.The microbiocidal or at least microbiostatic properties of the material may also be obtained by diffusion in the product of an antimicrobial agent, for example on an organic base such as Trichlosan (commercial name of the company Melcoplast) or on silver base, or mineral. In particular, the material may comprise at least one polyolefin, for example polyethylene (PE), in particular at low density (LDPE), polypropylene (PP) and / or polystyrene, which is loaded with at least one antimicrobial agent.

Les propriétés microbiocides ou au moins microbiostatiques du matériau peuvent également être obtenues par irradiation du produit avec un rayonnement de longueur d'onde adaptée, notamment au moyen d'un matériau qui présente des propriétés de photoluminescence après exposition à la lumière extérieure.The microbiocidal or at least microbiostatic properties of the material may also be obtained by irradiation of the product with radiation of suitable wavelength, in particular by means of a material which exhibits photoluminescence properties after exposure to external light.

En particulier, le matériau peut être à base d'au moins une polyoléfine, par exemple du polyéthylène basse densité (PEBD), ladite polyoléfine étant chargée avec au moins un additif apte à émettre un rayonnement photoluminescent qui présente une longueur d'onde comprise entre 250 et 260 nanomètres, et notamment de 254 nanomètres, ce qui correspond à l'ordre de grandeur des rayonnements ultraviolets stérilisants.In particular, the material may be based on at least one polyolefin, for example low density polyethylene (LDPE), said polyolefin being charged with at least one additive capable of emitting photoluminescent radiation which has a wavelength between 250 and 260 nanometers, including 254 nanometers, which corresponds to the order of magnitude of sterilizing ultraviolet radiation.

Claims (19)

Tête de distribution pour un système de distribution d'un produit, ladite tête comprenant un corps (1) présentant un puits de montage (3) de ladite tête sur un tube (6) d'amenée sous pression du produit et un logement (10) en communication avec ledit puits par l'intermédiaire d'un chemin de distribution (11), ledit logement étant équipé d'une buse (12) délimitant un espace de distribution (13) entre ledit chemin et un passage de sortie (14) formé dans ladite buse, ladite tête étant caractérisée en ce que la buse (12) est équipée d'un insert (18) qui présente une membrane (19) formant dans l'espace de distribution (13) une interface de communication (20) entre une partie amont (13a) dans laquelle débouche le chemin de distribution (11) et une partie aval (13b) qui alimente le passage de sortie (14), ladite membrane étant déformable réversiblement par pression du produit provenant de la partie amont (13a), entre un état au repos dans lequel la dimension de l'interface de communication (20) est minimale et un état contraint dans lequel la dimension de ladite interface est augmentée pour assurer la distribution.Dispensing head for a dispensing system of a product, said head comprising a body (1) having a mounting well (3) of said head on a tube (6) for feeding the product under pressure and a housing (10). ) in communication with said well via a distribution path (11), said housing being provided with a nozzle (12) defining a dispensing space (13) between said path and an outlet passage (14) formed in said nozzle, said head being characterized in that the nozzle (12) is equipped with an insert (18) which has a diaphragm (19) forming in the distribution space (13) a communication interface (20) between an upstream part (13a) in which the distribution path (11) opens and a downstream part (13b) which feeds the outlet passage (14), said membrane being reversibly deformable by pressure of the product coming from the upstream part (13a) ), between a state at rest in which the dimension of the inter communication face (20) is minimal and a constrained state in which the dimension of said interface is increased to provide distribution. Tête de distribution selon la revendication 1, caractérisée en ce que la membrane (19) présente au moins un voile (21) déformable qui délimite une interface de communication (20) avec une portée intérieure (22) de la buse (12), ledit voile étant agencé pour fléchir par pression du produit sur lui en induisant une réduction de la dimension extérieure dudit voile.Dispensing head according to claim 1, characterized in that the membrane (19) has at least one deformable web (21) which delimits a communication interface (20) with an inner bearing (22) of the nozzle (12), said veil being arranged to flex by pressure of the product on it by inducing a reduction of the outer dimension of said veil. Tête de distribution selon la revendication 2, caractérisée en ce que le voile (21) présente une dimension extérieure au repos qui est inférieure à la dimension intérieure de la portée (22) afin d'empêcher une mise en contact dudit voile sur ladite portée.Dispensing head according to claim 2, characterized in that the web (21) has an outer dimension at rest which is smaller than the inner dimension of the bearing surface (22) to prevent contact of said web on said surface. Tête de distribution selon l'une des revendications 2 ou 3, caractérisée en ce que la membrane (19) présente au moins deux voiles (21) qui s'étendent chacun sur un secteur angulaire, lesdits voiles étant séparés angulairement par un pont (24) dont la rigidité est supérieure à celle desdits voiles pour ne pas fléchir par pression du produit sur lui.Dispensing head according to one of claims 2 or 3, characterized in that the membrane (19) has at least two webs (21) which each extend over an angular sector, said webs being angularly separated by a bridge (24) whose rigidity is greater than that of said sails so as not to flex by pressure of the product on it. Tête de distribution selon l'une quelconque des revendications 2 à 4, caractérisée en ce qu'un voile (21) présente un soufflet (25) de contrôle de la déformation dudit voile par pression du produit sur lui.Dispensing head according to any one of claims 2 to 4, characterized in that a web (21) has a bellows (25) for controlling the deformation of said web by pressure of the product on it. Tête de distribution selon l'une quelconque des revendications 1 à 5, caractérisée en ce que l'insert (18) présente un pion central (23) autour duquel la membrane (19) s'étend radialement.Dispensing head according to any one of claims 1 to 5, characterized in that the insert (18) has a central pin (23) around which the membrane (19) extends radially. Tête de distribution selon la revendication 6, caractérisée en ce que le chemin de distribution (11) débouche axialement en regard du pion (23).Dispensing head according to claim 6, characterized in that the distribution path (11) opens axially opposite the pin (23). Tête de distribution selon l'une quelconque des revendications 1 à 7, caractérisée en ce que le logement (10) est pourvu d'une enclume (15) autour de laquelle la buse (12) est montée pour délimiter l'espace de distribution (13), ladite enclume présentant au moins un conduit (16) dans lequel au moins une partie du chemin de distribution (11) s'étend.Dispensing head according to any one of claims 1 to 7, characterized in that the housing (10) is provided with an anvil (15) around which the nozzle (12) is mounted to define the distribution space ( 13), said anvil having at least one conduit (16) in which at least a portion of the distribution path (11) extends. Tête de distribution selon la revendication 8, caractérisée en ce que le conduit (16) s'étend axialement dans la partie centrale de l'enclume (15).Dispensing head according to claim 8, characterized in that the duct (16) extends axially in the central part of the anvil (15). Tête de distribution selon l'une quelconque des revendications 1 à 9, caractérisée en ce que la buse (12) présente une paroi distale (12b) dans laquelle le passage de sortie (14) est formé, et une paroi latérale (12a) présentant une portée intérieure (22) délimitant l'interface de communication (20).Dispensing head according to one of claims 1 to 9, characterized in that the nozzle (12) has a distal wall (12b) in which the outlet passage (14) is formed, and a side wall (12a) having an inner bearing (22) defining the communication interface (20). Tête de distribution selon la revendication 10, caractérisée en ce que l'insert (18) présente au moins une butée avant (24a) qui est en appui axial sur l'intérieur de la paroi distale (12b).Dispensing head according to claim 10, characterized in that the insert (18) has at least one forward stop (24a) which bears axially on the inside of the distal wall (12b). Tête de distribution selon l'une des revendications 10 ou 11, caractérisée en ce que la membrane (19) en état contraint est agencée pour venir en appui axial sur l'intérieur de la paroi distale (12b) en maintenant une interface de communication (20) entre ledit appui et ladite paroi.Dispensing head according to one of Claims 10 or 11, characterized in that the membrane (19) in the stressed state is arranged to bear axially on the inside of the distal wall (12b) while maintaining a communication interface ( 20) between said support and said wall. Tête de distribution selon l'une quelconque des revendications 1 à 12, caractérisée en ce que la buse (12) est réalisée à base d'au moins un matériau présentant des propriétés microbiocides ou au moins microbiostatiques par diffusion d'un agent antimicrobien, par contact avec un agent microbiocide ou au moins microbiostatique et/ou par irradiation avec un rayonnement de longueur d'onde adaptée.Dispensing head according to any one of claims 1 to 12, characterized in that the nozzle (12) is made of at least one material having microbiocidal or at least microbiostatic properties by diffusion of an antimicrobial agent, by contact with a microbiocidal or at least microbiostatic agent and / or irradiation with radiation of suitable wavelength. Tête de distribution selon la revendication 13, caractérisée en ce que la buse (12) comprend du cuivre métallique ou un alliage à base de cuivre métallique.Dispensing head according to Claim 13, characterized in that the nozzle (12) comprises metallic copper or a metal-copper-based alloy. Tête de distribution selon l'une quelconque des revendications 1 à 14, caractérisée en ce que l'insert (18) est apte à assurer une action microbiocide ou au moins microbiostatique sur le produit contenu au moins au niveau de l'interface de communication (20).Dispensing head according to any one of Claims 1 to 14, characterized in that the insert (18) is capable of ensuring a microbiocidal or at least microbiostatic action on the product contained at least at the level of the communication interface ( 20). Tête de distribution selon l'une quelconque des revendications 1 à 15, caractérisée en ce que le passage de sortie (14) présente un orifice (26) qui est délimité par une paroi latérale (14a) pourvue d'au moins une saillie intérieure (27).Dispensing head according to any one of claims 1 to 15, characterized in that the outlet passage (14) has an orifice (26) which is delimited by a side wall (14a) provided with at least one inner projection ( 27). Système de distribution d'un produit, ledit système comprenant une tête de distribution selon l'une quelconque des revendications 1 à 16 et un tube (6) d'amenée sous pression du produit sur lequel le puits de montage (3) de ladite tête est fixé.System for dispensing a product, said system comprising a dispensing head according to any one of claims 1 to 16 and a tube (6) for feeding the product under pressure on which the mounting well (3) of said head is fixed. Système de distribution selon la revendication 17, caractérisé en ce qu'il comprend une pompe (5) actionnée par la tête de distribution, ladite pompe comprenant le tube (6) d'amenée sous pression du produit.Dispensing system according to claim 17, characterized in that it comprises a pump (5) actuated by the dispensing head, said pump comprising the tube (6) for feeding the product under pressure. Flacon (8) comprenant un réservoir dans lequel un produit est destiné à être conditionné, ledit réservoir étant équipé d'un système de distribution selon l'une des revendications 17 ou 18 qui est monté de sorte à mettre le tube d'amenée (6) en communication avec ledit réservoir pour permettre l'acheminement du produit depuis ledit tube d'amenée vers le passage de sortie (14).Vial (8) comprising a reservoir in which a product is intended to be packaged, said reservoir being equipped with a dispensing system according to one of claims 17 or 18 which is mounted so as to put the feed tube (6 ) in communication with said reservoir to allow the product to be conveyed from said feed tube to the outlet passage (14).
EP15200284.6A 2014-12-18 2015-12-15 Dispensing head for a product dispensing system Active EP3034178B1 (en)

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US11254488B2 (en) * 2017-12-21 2022-02-22 Shl Medical Ag Spray nozzle chip and a medicament delivery device comprising the same
FR3081113B1 (en) * 2018-05-18 2020-05-29 Albea Le Treport PISTON FOR TANK OF A DISPENSER OF A FLUID PRODUCT WITHOUT AIR INTAKE
US20220072241A1 (en) * 2019-01-25 2022-03-10 Shl Medical Ag Spray nozzle chip and a medicament delivery device comprising the same

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EP1327477A1 (en) * 2002-01-10 2003-07-16 AERO PUMP GMBH Zerstäuberpumpen A force and suction pump actuator for spraying of a product from a container
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US9724712B2 (en) 2017-08-08
CN105709961B (en) 2019-11-12
US20160175863A1 (en) 2016-06-23
CN105709961A (en) 2016-06-29
EP3034178B1 (en) 2019-03-27
FR3030313B1 (en) 2017-01-13
FR3030313A1 (en) 2016-06-24
BR102015031866B1 (en) 2021-01-05
BR102015031866A2 (en) 2018-03-20

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