EP2854960A1 - Recyclable golf ball - Google Patents
Recyclable golf ballInfo
- Publication number
- EP2854960A1 EP2854960A1 EP13797882.1A EP13797882A EP2854960A1 EP 2854960 A1 EP2854960 A1 EP 2854960A1 EP 13797882 A EP13797882 A EP 13797882A EP 2854960 A1 EP2854960 A1 EP 2854960A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- golf ball
- materials
- melting point
- ball according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 claims abstract description 152
- 238000002844 melting Methods 0.000 claims abstract description 72
- 230000008018 melting Effects 0.000 claims abstract description 72
- 239000000654 additive Substances 0.000 claims abstract description 35
- 230000000996 additive effect Effects 0.000 claims abstract description 34
- 239000010410 layer Substances 0.000 claims description 263
- 239000012792 core layer Substances 0.000 claims description 54
- 239000000853 adhesive Substances 0.000 claims description 13
- 230000001070 adhesive effect Effects 0.000 claims description 13
- 229920001169 thermoplastic Polymers 0.000 claims description 8
- 229920001187 thermosetting polymer Polymers 0.000 claims description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000005060 rubber Substances 0.000 claims description 4
- 229910000859 α-Fe Inorganic materials 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 3
- 229920006332 epoxy adhesive Polymers 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 239000006247 magnetic powder Substances 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 238000004064 recycling Methods 0.000 abstract description 9
- 239000002699 waste material Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 52
- 239000007788 liquid Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 230000005484 gravity Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 229920000909 polytetrahydrofuran Polymers 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229920002614 Polyether block amide Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 229920003305 DuPont™ Surlyn® 8528 Polymers 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 229920006309 Invista Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229920003182 Surlyn® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000828 alnico Inorganic materials 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920006345 thermoplastic polyamide Polymers 0.000 description 1
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0023—Covers
- A63B37/0024—Materials other than ionomers or polyurethane
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0038—Intermediate layers, e.g. inner cover, outer core, mantle
- A63B37/0039—Intermediate layers, e.g. inner cover, outer core, mantle characterised by the material
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0038—Intermediate layers, e.g. inner cover, outer core, mantle
- A63B37/004—Physical properties
- A63B37/0045—Thickness
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/005—Cores
- A63B37/0051—Materials other than polybutadienes; Constructional details
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B45/00—Apparatus or methods for manufacturing balls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/0042—Producing plain balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B2209/00—Characteristics of used materials
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B2209/00—Characteristics of used materials
- A63B2209/08—Characteristics of used materials magnetic
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
- A63B37/0076—Multi-piece balls, i.e. having two or more intermediate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
- B29B17/0404—Disintegrating plastics, e.g. by milling to powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0217—Mechanical separating techniques; devices therefor
- B29B2017/0237—Mechanical separating techniques; devices therefor using density difference
- B29B2017/0244—Mechanical separating techniques; devices therefor using density difference in liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0255—Specific separating techniques using different melting or softening temperatures of the materials to be separated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/54—Balls
- B29L2031/546—Golf balls
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/52—Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Definitions
- the present invention relates generally to a golf ball made of recyclable materials.
- the game of golf is an increasingly popular sport at both amateur and professional levels.
- a wide range of technologies related to the manufacture and design of golf balls are known in the art. Such technologies have resulted in golf balls with a variety of play characteristics. For example, some golf balls have a better flight performance than other golf balls. Some golf balls have a good feel when hit with a golf club. While materials have advanced to increase the performance of golf balls, the materials are not always easy to recycle. Thus, to help manage costs and reduce damage to the environment, it would be advantageous to make a golf ball made of recyclable materials.
- the present disclosure relates to a recyclable golf ball.
- the structure of the disclosed golf ball and/or the materials used to make the golf ball may enhance the ability to recycle the golf ball.
- the disclosed golf ball may decrease waste and the costs associated with acquiring and/or processing new materials.
- the disclosure provides a golf ball that may have a first layer having a first melting point and a second layer enclosing the first layer.
- the second layer may have a second melting point that is at least 50 degrees Celsius different from the first melting point.
- the golf ball may include a third layer disposed between the first layer and the second layer.
- the third layer may have a third melting point that is at least 10 degrees Celsius different from the first melting point and the second melting point.
- the golf ball may include a fourth layer disposed between the second layer and the third layer.
- the fourth layer may have a fourth melting point that is at least 10 degrees Celsius different from the first melting point, the second melting point, and the third melting point.
- the first layer may be a core layer and the second layer may be a cover layer.
- the golf ball may include a third layer that is a core layer made of a thermoset.
- the golf ball may include a first intermediate layer disposed between the first layer and the second layer.
- the first intermediate layer may have a thickness ranging from about 1 ⁇ m to about 1 mm.
- the first intermediate layer may have a third melting point that is 10 degrees Celsius different from the first melting point and the second melting point.
- the disclosure provides a golf ball that may have a first layer and a second layer surrounding the first layer.
- the golf ball may have a first intermediate layer disposed between the first layer and the second layer.
- the first intermediate layer may have a thickness ranging from about 1 ⁇ m to about 1 mm and the first intermediate layer may be made of at least one of epoxy adhesives, acrylic adhesives, urethane adhesives, ethylene vinyl acetate adhesives, and rubber adhesives.
- the first intermediate layer may have a thickness ranging from about 1 ⁇ m to about 0.6 mm.
- the golf ball may have a third layer surrounding the second layer and a second intermediate layer disposed between the second layer and the third layer.
- the disclosure provides a golf ball that may have a first layer and a second layer enclosing the first layer.
- One of the first layer and the second layer may include magnetic additive.
- a third layer may be disposed between the first layer and the second layer.
- the third layer may include magnetic additive.
- One of the first layer and the second layer may include at least about 2 vol % to about 20 vol % less magnetic additive than the third layer.
- One of the first layer and the second layer may include of at least about 5 vol % to about 15 vol % of magnetic additive and the third layer may include about 7 vol % to about 35 vol % of magnetic additive.
- the type of magnetic additive added to one of the first layer and the second layer may be a ferrite magnetic powder.
- the first layer may be a thermoset containing magnetic additive.
- the first layer may be a thermoplastic containing magnetic additive.
- the second layer may be a thermoplastic containing magnetic additive.
- FIG. 1 is a golf ball according to an exemplary embodiment
- FIG. 2 is a golf ball according to an exemplary embodiment
- FIG. 3 is a golf ball according to an exemplary embodiment
- FIG. 4 is an outer view of the golf ball shown in FIG. 3.
- the present disclosure relates to a recyclable golf ball.
- the terms“used golf ball” and“new golf ball” are used to distinguish between a golf ball that is to be recycled and a golf ball that is made from recycled materials. Accordingly,“used golf ball” means a golf ball that is to be recycled.
- the term“used golf ball” can include golf balls that have literally been used in a golf game and golf balls that have not literally been used.
- “New golf ball” refers to a golf ball made from materials recycled from the“used golf ball.”
- FIG. 1 shows an exemplary embodiment of a golf ball 100.
- Golf ball 100 may include an inner core layer 110, an outer core layer 120, a mantle (inner cover) layer 130, and an outer cover layer 140. While the exemplary embodiment of golf ball 100 has been described and illustrated as having four layers, other embodiments may include any number of layers. For example, in some embodiments, golf ball 100 may be a one-piece, two-piece, three-piece, or five-piece ball. In some embodiments, golf ball 100 may include more than five layers. The number of layers may be selected based on a variety of factors. For example, the number of layers may be selected based on the type of materials used to make the golf ball and/or the size of the golf ball.
- the type of materials used to make the layers of the golf ball may be selected based on a variety of factors.
- the type of materials used to make the layers of the golf ball may be selected based on the properties of the material and/or the processes used to form the layers.
- one or more layers may be made from different materials. In some embodiments, one or more layers may be made from the same materials.
- the materials used to make the layers of the golf ball may be selected to aid in recycling the golf ball.
- the materials may be selected to aid in separating and identifying the materials before reusing the materials. This way the materials may be stored separately before using and/or the proper proportions of the materials may be measured out for reusing.
- the used golf ball may be pulverized into particles so that the materials may be reused to make new golf balls.
- Pulverizing the used golf ball may result in particles of material A and material B to become intermixed. If only material A, and not material B, is to be used in a layer of a new golf ball, it may be helpful to be able to separate material A from material B. Similarly, if material A and material B are to be used in a certain proportion in a layer of a new golf ball, it may be helpful to be able to distinguish between material A and material B. Separating and identifying materials may be helpful in recycling golf balls made of any number of materials and during any type of recycling process. For example, separating and identifying materials may be helpful in recycling golf balls made of four different types of materials.
- the density and/or specific gravity of the materials used to make golf ball 100 may be used to separate the materials during recycling.
- Specific gravity is the ratio of the density of a substance compared to the density of fresh water at 4°C (39°F). At this temperature the density of water is at its greatest value and equals 1 g/cm 3 . Since specific gravity is a ratio, specific gravity is dimensionless. An object will float in water if its density is less than the density of water and sink if its density is greater than the density of water. Thus, an object with specific gravity less than 1 will float in water and an object with a specific gravity greater than 1 will sink in water. The same principle may be applied to other types of liquids.
- the ratio of the density of an object to the density of a liquid is less than 1 , the object will float in that particular liquid.
- the density of an object may cause the object to become suspended at a certain level within the liquid.
- the ratio of the density of the object to the density of the liquid may dictate the level to which the object is suspended in that particular liquid.
- golf ball 100 made from materials having different densities.
- golf ball 100 may be pulverized into particles. Then, the particles may be added to a liquid having a certain known density.
- the liquid and/or the materials may be selected based on their densities. In other words, the materials and/or liquid may be selected based on the levels the particles will float to within the liquid. This way, the particles can be separated based on the level to which the particles float in the liquid.
- the temperature of the liquid may be changed to alter the density of the liquid, thereby altering the level to which the particles float.
- the type of liquid may be changed to alter the density of the liquid. For example, in some embodiments, salt may be added to water to change the density of the water.
- inner core layer 110, outer core layer 120, mantle layer 130, and outer cover layer 140 may be each made from a single type of material or a composition including multiple materials.
- inner core layer 110 may be made from HPF 2000, produced by E. I. DuPont de Nemours and Company. HPF 2000 has a density of 0.96 g/cm 3 .
- Outer core layer 120 may be made from TAIPOLTM BR0150, which is the trade name of a rubber produced by Taiwan Synthetic Rubber Corp. The density of outer core layer 120 may be from about 1.05 g/cm 3 to about 1.35 g/cm 3 .
- Mantle layer 130 may be made from Neothane 6303D, which is the trade name of a thermoplastic polyurethane produced by Dongsung Highchem Co. LTD.
- Cover layer 140 may be made from PTMEG.
- PTMEG polytetramethylene ether glycol, commercially available from Invista under the trade name of Terathane® 2000.
- the density of mantle layer 130 or outer cover layer 140 may range from about 1.1 g/cm 3 to about 1.35 g/cm 3 .
- Pulverizing golf ball 100 of this embodiment into particles and putting the particles in water having a temperature of 4°C (39°F) may result in the materials of each layer floating to a different level in the water. The particles may be removed from the water level by level to keep like particles together.
- particles of HPF 2000 may have the lowest density and may, therefore, float to the top of the water. These particles may be removed first to reveal the next level of particles, which may include the particles having the second lowest density. Then, the particles having the second lowest density may be removed to reveal the next level of particles. In this manner, the particles may be separated into levels and removed level by to level to keep like particles together.
- the melting point of the materials used to make golf ball 100 may be used to separate the materials during recycling. This way, the materials of golf ball 100 may be melted one at a time.
- golf ball 100 may be made from materials having different melting points such that, as the temperature of golf ball 100 is raised, more materials may begin to melt. In this manner, the layers may be melted one by one and molten material may be separated from solid material.
- the materials may be selected based on the melting temperatures of the materials. The melting temperatures may be used to control which material melts.
- the materials used to make the golf ball may include any suitable material generally known to be used in golf balls. In some embodiments, the materials may include
- thermoplastics may include high melt thermoplastics, such as polyetheramides and/or polyetheresters.
- the materials may include PEBAX (a polyetheramide produced by Elf-Atochem), HYTREL (a polyetherester produced by DuPont), ESTANE (a thermoplastic urethane either ether or ester urethane produced by Lubrizol, Inc.), or any other material disclosed in Comeau et al., U.S. patent publication number
- the materials may include resins, such as SURLYN, produced by E. I. DuPont de Nemours and Company.
- the materials may include a highly neutralized acid polymer, such as HPF 1000 or AD 1035, both produced by E. I. DuPont de Nemours and Company.
- the different materials used to make the golf ball may each have a melting temperature that is at least 10 degrees Celsius different from the melting temperatures of the other materials.
- a first material of the golf ball may include HPF 2000, produced by E. I. Dupont de Nemours and Company.
- HPF 2000 has a melting temperature of about 73 degrees Celsius.
- a second material of the golf ball may include SURLYN 8528, produced by E. I. DuPont de Nemours and Company. SURLYN 8528 has a melting temperature of about 93 degrees Celsius. In such embodiments, when the temperature of the golf ball is raised to 75 degrees Celsius, the first material may melt and the second material may remain solid.
- golf ball 100 may be pulverized into particles before melting the materials.
- the materials may be selected based on the melting temperature of the materials.
- outer cover layer 140 may have the highest melting temperature.
- Mantle layer 130 may have the lowest melting temperature.
- Outer core layer 120 may have the second highest melting temperature.
- Inner core layer 110 may have the second lowest melting temperature.
- the melting points of the materials may be sufficiently disparate for the melting of the materials to occur at different temperatures.
- the particles of golf ball 100 may be heated to the certain temperatures to control which materials melt.
- the particles may be heated to a temperature that is the same or higher than the lowest melting point of the materials and lower than the second lowest melting point of the materials. This heating may cause the particles of the materials having the lowest melting point to melt without causing the particles of the other materials to melt.
- the melted material may be strained out from the solid particles.
- the temperature of the particles may be progressively raised to melt different types of materials. For example, after melting the particles having the lowest melting point, the particles may be heated to a temperature that is the same or higher than the second lowest melting point of the materials and lower than the second highest melting point of the materials. In some embodiments, less than all of the materials may be melted. For example, only one or two materials may be melted and strained from the solid particles. Then, the solid particles may be separated in another way and/or prepared for another type of processing. For example, the solid particles leftover after melting may be separated by their densities in the manner described above. Any of the techniques used to separate materials may be combined with each other.
- the materials of the particles not intended to be melted may include materials simply having melting points that are higher than the melting points of the materials intended to be melted.
- the materials of the particles not intended to be melted may be materials not conducive to melting, such as thermosets.
- the materials intended to be melted may include
- thermoplastics thermoplastics.
- the materials used to make the layers of golf ball 100 may be selected such that the melting points of the layers
- the melting temperatures of the layers may become progressively higher from outer cover layer 140 to inner core layer 110.
- golf ball 100 may be melted without being pulverized first.
- Outer cover layer 140 may have the lowest melting temperature.
- Mantle layer 130 may have the second lowest melting temperature.
- Outer core layer 120 may have the second highest melting temperature.
- Inner core layer 110 may have the highest melting temperature.
- This embodiment may be recycled by melting each layer from the outside in.
- the temperature of the golf ball 100 may be raised to a temperature that is the same or higher than the melting point of outer cover layer 140 and lower than the melting point of the other layers of golf ball 100.
- This temperature may cause outer cover layer 140 to melt without causing the other layers of golf ball 100 to melt.
- mantle layer 130, and outer core layer 120 may be melted and removed from underlying layers. With all of the layers surrounding inner core layer 110 being separately melted and collected, inner core layer 110 may be melted and collected.
- less than all of the layers may be melted.
- the melting point of the layers not intended to be melted may be sufficiently high to prevent such layers from melting during processing.
- inner core layer 110 may have a melting point that is higher than all of the other layers. After all of the other layers are melted and removed from inner core layer 110, inner core layer 110 may be left whole or may be prepared for another type of processing. For example, inner core layer 110 may be pulverized to prepare the material of inner core layer 110 to be mixed with particles of other materials.
- the layers not intended to be melted may be made of a thermoset or other type of material that may not be conducive to melting. Accordingly, the materials of these layers may be separated from each other by another manner.
- these layers may be ground away from the other layers.
- these layers may be pulverized and separated by their densities in the manner discussed above.
- outer cover layer 140 may be the only layer removed through melting.
- the materials of the other layers may have a higher melting point than that of outer cover layer 110 such that the other layers do not melt when outer cover layer 110 is melted.
- the melting points of the other layers may be the same or different from each other since the other layers may not be melted.
- the materials used to make the layers of golf ball 100 may be selected based on the magnetic susceptibility of the materials.
- the material used to make a first layer of golf ball 100 may be magnetically susceptible and the material used to make a second layer be magnetically non-susceptible.
- Magnetic additives may be mixed with materials to make the materials magnetically susceptible.
- the layers of golf ball 100 may be made of thermoplastics and/or thermosets containing a magnetic additive.
- the magnetic additive may include any suitable magnetic additive.
- the magnetic additive may include a ferrite magnetic powder, such as barium ferrite powder, strontium ferrite powder, and/or AlNiCo powder.
- the magnetic additive may include iron oxides, such as hematite and magnetite.
- a material of the golf ball may include from about 5 vol % to about 80 vol % magnetic additive.
- golf ball 100 may be pulverized into particles and separated by applying a magnetic field to the particles.
- Materials with different amounts of magnetic additive may have different levels of attraction toward magnetic fields. For example, materials including 5 vol % magnetic additive may be less attracted to a magnetic field than materials including 10 vol % magnetic additive.
- a weak magnetic field may be used to separate material particles having the highest amount of magnetic additive from the other material particles.
- each layer may have a different amount of magnetic additive.
- outer cover layer 140 may include about 5 vol % to about 15 vol % magnetic additive.
- Mantle layer 130 may include about 20 vol % to about 35 vol % magnetic additive.
- Outer core layer 120 may include about 40 vol % to about 55 vol % magnetic additive.
- Inner core layer 110 may include 0% magnetic additive.
- FIG. 2 shows an exemplary embodiment of a golf ball 200.
- Golf ball 200 may include an inner core layer 210, an outer core layer 220, a mantle layer 238, and an outer cover layer 240. While the exemplary embodiment of golf ball 200 has been described and illustrated as having three layers, other embodiments may include any number of layers. For example, in some embodiments, golf ball 200 may be a one-piece, two-piece, four-piece, or five- piece ball. In some embodiments, golf ball 200 may include more than five layers. The number of layers may be selected based on a variety of factors. For example, the number of layers may be selected based on the type of materials used to make the golf ball and/or the size of the golf ball.
- Golf ball 200 may include an intermediate layer 216 between inner core layer 210 and outer core layer 220.
- golf ball 200 may include an intermediate layer 236 between outer core layer 220 and mantle layer 238.
- intermediate layer 216 and intermediate layer 236 may be made of the same types of materials.
- intermediate layer 216 and intermediate layer 236 may be made of different types of materials.
- intermediate layer 216 and/or intermediate layer 236 may act as primers and/or adhesives.
- intermediate layer 216 and/or intermediate layer 236 may include epoxy adhesives, acrylic adhesives, urethane adhesives, ethylene vinyl acetate adhesives, and/or rubber adhesives.
- Intermediate layer 216 and/or intermediate layer 236 may be made of materials that aid in separation between inner core layer 210, outer core layer 220, and mantle layer 238.
- intermediate layer 216 and/or intermediate layer 236 may be made of materials having lower melting points than the other layers. Such materials may be softened and/or melted to help separate inner core layer 210, outer core layer 220, and cover layer 240 from each other.
- golf ball 200 may be pulverized into particles. Then, to aid in separating the different materials, the particles may be heated to a temperature that is the melting point of intermediate layer 216 and/or intermediate layer 236. The materials of intermediate layer 216 and intermediate layer 236 soften and/or melt, releasing particles of mantle layer 238 from particles of outer core layer 220 and releasing particles of outer core layer 220 from particles of inner core layer 210. The melted material may be strained from the solid particles.
- inner core layer 210 may have a diameter ranging from about 19 mm to about 32 mm. In some embodiments, inner core layer 210 may have a diameter ranging from about 20 mm to about 30 mm. In some embodiments, inner core layer 210 may have a diameter ranging from about 21 mm to about 28 mm. In some embodiments, outer core layer 220 may have a thickness ranging from about 5 mm to about 11 mm. For example, outer core layer 220 may have a thickness of about 7 mm. In some
- outer core layer 220 may have a thickness ranging from about 8 mm to about 15 mm.
- outer core layer 220 may have a thickness of about 11 mm.
- outer cover layer 240 and/or mantle layer 238 of golf ball 200 may have a thickness ranging from about 0.5 mm to about 2 mm.
- outer cover layer 240 and/or mantle layer 238 may have a thickness of about 1 mm.
- outer cover layer 240 and/or mantle layer 238 may have a thickness ranging from about 1 mm to about 1.5 mm.
- outer cover layer 240 and/or mantle layer 238 may have a thickness of about 1.2 mm.
- intermediate layer 216 and/or
- intermediate layer 236 may be substantially thinner than the other layers of golf ball 200.
- intermediate layer 216 and/or intermediate layer 236 may be less than or equal to 1 mm.
- intermediate layer 216 and/or intermediate layer 236 may range from about 1 ⁇ m to about 0.70 mm. In some embodiments, intermediate layer 216 and/or intermediate layer 236 may range from about 0.01 mm to about 0.4 mm.
- golf ball 200 may have an intermediate layer between each layer.
- golf ball 200 may include an intermediate layer between mantle layer 238 and outer cover layer 240.
- golf ball 200 may have an intermediate layer between less than all of the layers.
- golf ball 200 may include intermediate layer 216 and not intermediate layer 236.
- golf ball may include intermediate layer 236 and not intermediate layer 216.
- the number of intermediate layers may be selected based on a variety of factors. For example, the number of intermediate layers may be selected based on the process used to recycle golf ball 200.
- intermediate layer 236 may be made of materials that are dissolvable in certain solvents. Accordingly, in such embodiments, golf ball 200 may be pulverized into particles. Then, to aid in separating the different materials, the particles may be placed in a solvent. The materials of intermediate layer 216 and intermediate layer 236 may be dissolved, releasing particles of mantle layer 238 from particles of outer core layer 220 and releasing particles of outer core layer 220 from particles of inner core layer 210. For example, in some embodiments,
- dissolvable materials may include thermoplastic polyurethane elastomers, thermoplastic polyamide elastomers, thermoplastic polyester elastomers, and ethylene propylene diene monomer (EPDM) rubbers.
- solvents used to dissolve the dissolvable materials may include tetrahydrofuran, methyl isobutyl ketone, dimethylformamide, dimethyl sulfoxide, methylpyrrolidone, toluene, acetone, chloroform, and ethyl acetate.
- FIGS. 3 and 4 show an exemplary embodiment of a golf ball 300.
- FIG. 3 shows a cross-sectional view of golf ball 300 and FIG. 4 shows the outside of golf ball 300.
- golf ball 300 may include a core layer 310 and a cover layer 340.
- golf ball 300 may include multiple core layers and/or multiple cover layers.
- golf ball 300 may include an inner core layer, an outer core layer, an inner cover layer, and an outer cover layer.
- an outer cover layer with dimples may be formed around golf ball 300.
- golf ball 300 may be made through a sandwich molding process.
- concentric nozzles may be used to simultaneously inject multiple layers of a golf ball.
- concentric nozzles may include an outer nozzle 342 surrounding an inner nozzle 344. In embodiments including more layers, more concentric nozzles may be used.
- FIG. 3 shows golf ball 300 after golf ball 300 has been formed. The concentric nozzles are shown to illustrate how the materials flow from the concentric nozzles to form a pattern including a plume 348 within golf ball 300. A first material may be dispensed from outer nozzle 342 and a second material may be dispensed from inner nozzle 344.
- a first material may include a core material and the second material may include a cover material.
- the first material and the second material may include thermosets.
- the simultaneous injection of the first material and the second material may create plume 348 of the second material.
- the first material may flow around plume 348 and into the center of the mold.
- the second material may continue to flow from outer nozzle 342 and plume 348 to the walls of the mold to form outer cover layer 340.
- Plume 348 may solidify as a distinct region of the second material that is surrounded by the first material.
- plume 348 may have a fan-shaped cross-section. As shown in FIG.
- core layer 310 may be exposed through cover layer 340 at region 346.
- Region 346 may include a thinned region of cover layer 340 that is radially spaced from plume 348. Region 346 may be sufficiently thin for cover layer 340 to be visible from the outside of golf ball 300.
- a border between cover layer 340 and core layer 310 may be substantially more uneven, or ragged, in a first portion of golf ball 300 near plume 348. The border may become smoother and more even in a second portion of golf ball 300 that is located opposite plume 348.
- Golf ball 100, golf ball 200, and golf ball 300 may be made by any suitable process.
- injection molding and/or compression molding may be used to make any of the golf ball layers.
- the process of making the golf ball may be selected based on a variety of factors.
- the process of making the golf ball may be selected based on the type of materials used and/or the number of layers included.
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/485,654 US20130324324A1 (en) | 2012-05-31 | 2012-05-31 | Recyclable golf ball |
| PCT/US2013/043494 WO2013181475A1 (en) | 2012-05-31 | 2013-05-31 | Recyclable golf ball |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2854960A1 true EP2854960A1 (en) | 2015-04-08 |
| EP2854960A4 EP2854960A4 (en) | 2016-01-20 |
Family
ID=49670941
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13797882.1A Withdrawn EP2854960A4 (en) | 2012-05-31 | 2013-05-31 | Recyclable golf ball |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20130324324A1 (en) |
| EP (1) | EP2854960A4 (en) |
| JP (1) | JP2015521082A (en) |
| WO (1) | WO2013181475A1 (en) |
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|---|---|---|---|---|
| DE102014204361A1 (en) * | 2014-03-10 | 2015-09-10 | Brose Fahrzeugteile Gmbh & Co. Kg, Hallstadt | Method for producing a driver for a window regulator device |
| US9504878B2 (en) | 2015-03-25 | 2016-11-29 | Acushnet Company | Recyclable golf ball and method of making |
| DE102015223885B4 (en) * | 2015-12-01 | 2024-03-21 | Adidas Ag | ball |
| US10675526B2 (en) * | 2017-05-01 | 2020-06-09 | Intel Corporation | Sports apparatus and methods including tracking additives |
| US11819739B2 (en) | 2021-07-12 | 2023-11-21 | Acushnet Company | Golf ball and method of making same |
| SE2230201A1 (en) * | 2022-06-21 | 2023-12-22 | Bamdad Payvar | New plastic types that are easy to recycle and to sort |
| US12324964B2 (en) * | 2022-11-15 | 2025-06-10 | Acushnet Company | Golf ball core compositions with metamaterial |
| US12318665B2 (en) * | 2022-11-15 | 2025-06-03 | Acushnet Company | Golf ball compositions with metamaterial |
| US20250135617A1 (en) * | 2023-11-01 | 2025-05-01 | Ben Ciechanover | Differential density system for mechanical devices |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6270429B1 (en) * | 1996-09-16 | 2001-08-07 | Spalding Sports Worldwide, Inc. | Crosslinked foam as filler in an inner layer or core of a multi-component golf ball |
| US5783293A (en) * | 1996-11-07 | 1998-07-21 | Acushnet Company | Golf ball with a multi-layered cover |
| JP3861942B2 (en) * | 1997-04-18 | 2006-12-27 | ブリヂストンスポーツ株式会社 | Thread wound golf ball |
| JP3221391B2 (en) * | 1998-03-16 | 2001-10-22 | ブリヂストンスポーツ株式会社 | Multilayer solid golf ball |
| JPH11299931A (en) * | 1998-04-20 | 1999-11-02 | Bridgestone Sports Co Ltd | Golf ball |
| US6319451B1 (en) * | 1998-12-17 | 2001-11-20 | Acushnet Company | Method of molding a layer around a body |
| US20010005699A1 (en) * | 1999-02-03 | 2001-06-28 | Morgan William E. | Multi-layer golf ball |
| AU2002216753A1 (en) * | 2000-07-05 | 2002-01-14 | Richard R. Soelch | Oriented thermoplastic elastomer thread wound golf ball |
| WO2008024744A2 (en) * | 2006-08-21 | 2008-02-28 | Jay Vandelden | Adaptive golf ball |
| US8337331B2 (en) * | 2008-01-10 | 2012-12-25 | Acushnet Company | Very-low melt flow thermoplastic composition for golf ball core layers |
| US20130072323A1 (en) * | 2011-09-21 | 2013-03-21 | Nike, Inc. | Method Of Golf Ball Compression Molding |
| US9050739B2 (en) * | 2012-05-31 | 2015-06-09 | Nike, Inc. | Method of recycling a golf ball |
-
2012
- 2012-05-31 US US13/485,654 patent/US20130324324A1/en not_active Abandoned
-
2013
- 2013-05-31 WO PCT/US2013/043494 patent/WO2013181475A1/en not_active Ceased
- 2013-05-31 EP EP13797882.1A patent/EP2854960A4/en not_active Withdrawn
- 2013-05-31 JP JP2015515213A patent/JP2015521082A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP2854960A4 (en) | 2016-01-20 |
| WO2013181475A1 (en) | 2013-12-05 |
| JP2015521082A (en) | 2015-07-27 |
| US20130324324A1 (en) | 2013-12-05 |
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