EP2507195A4 - Increasing octane number of light naphtha using a germanium-zeolite catalyst - Google Patents

Increasing octane number of light naphtha using a germanium-zeolite catalyst

Info

Publication number
EP2507195A4
EP2507195A4 EP10835119.8A EP10835119A EP2507195A4 EP 2507195 A4 EP2507195 A4 EP 2507195A4 EP 10835119 A EP10835119 A EP 10835119A EP 2507195 A4 EP2507195 A4 EP 2507195A4
Authority
EP
European Patent Office
Prior art keywords
germanium
octane number
zeolite catalyst
light naphtha
increasing octane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP10835119.8A
Other languages
German (de)
French (fr)
Other versions
EP2507195A1 (en
Inventor
Scott Stevenson
Paul E Ellis
Mike Mier
Dustin Farmer
Alla Khanmamedove
Scott Mitchell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US12/592,883 priority Critical patent/US20110132804A1/en
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Priority to PCT/US2010/058723 priority patent/WO2011068964A1/en
Publication of EP2507195A1 publication Critical patent/EP2507195A1/en
Publication of EP2507195A4 publication Critical patent/EP2507195A4/en
Application status is Withdrawn legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/06Catalytic reforming characterised by the catalyst used
    • C10G35/065Catalytic reforming characterised by the catalyst used containing crystalline zeolitic molecular sieves, other than aluminosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/047Germanosilicates; Aluminogermanosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/06Catalytic reforming characterised by the catalyst used
    • C10G35/085Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/20After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • C10G2300/1044Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1081Alkanes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1096Aromatics or polyaromatics
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/305Octane number, e.g. motor octane number [MON], research octane number [RON]
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018Spatial velocity, e.g. LHSV, WHSV
EP10835119.8A 2009-12-04 2010-12-02 Increasing octane number of light naphtha using a germanium-zeolite catalyst Withdrawn EP2507195A4 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/592,883 US20110132804A1 (en) 2009-12-04 2009-12-04 Increasing octane number of light naphtha using a germanium-zeolite catalyst
PCT/US2010/058723 WO2011068964A1 (en) 2009-12-04 2010-12-02 Increasing octane number of light naphtha using a germanium-zeolite catalyst

Publications (2)

Publication Number Publication Date
EP2507195A1 EP2507195A1 (en) 2012-10-10
EP2507195A4 true EP2507195A4 (en) 2014-11-26

Family

ID=44080965

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10835119.8A Withdrawn EP2507195A4 (en) 2009-12-04 2010-12-02 Increasing octane number of light naphtha using a germanium-zeolite catalyst

Country Status (8)

Country Link
US (1) US20110132804A1 (en)
EP (1) EP2507195A4 (en)
JP (1) JP2013512317A (en)
KR (1) KR20120088829A (en)
CN (1) CN102639472A (en)
IN (1) IN2012DN03131A (en)
SG (1) SG181153A1 (en)
WO (1) WO2011068964A1 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9242233B2 (en) * 2012-05-02 2016-01-26 Saudi Basic Industries Corporation Catalyst for light naphtha aromatization
US8772192B2 (en) 2012-06-29 2014-07-08 Saudi Basic Industries Corporation Germanium silicalite catalyst and method of preparation and use
US9180441B2 (en) 2012-09-20 2015-11-10 Saudi Basic Industries Corporation Method of forming zeolite shaped body with silica binder
KR101451902B1 (en) * 2012-11-26 2014-10-22 한국과학기술원 Zeolite with MRE structure and their analogue materials possessing mesopore, and synthesis method thereof
US9782758B2 (en) * 2013-04-23 2017-10-10 Saudi Basic Industries Corporation Method of preparing hydrocarbon aromatization catalyst, the catalyst, and the use of the catalyst
CN105636693B (en) * 2013-11-22 2019-12-13 沙特基础工业公司 catalyst with improved activity/selectivity for light naphtha aromatization
US9446389B2 (en) * 2013-12-13 2016-09-20 Saudi Basic Industries Corporation Hydrocarbon aromatization catalyst composition and method of formation
EP3318619A1 (en) * 2016-11-03 2018-05-09 Wolfdieter Klein Consulting GmbH Oel- und Gastechnologie Method for the production of fuels from gas condensates
CN106582793A (en) * 2016-12-07 2017-04-26 张吉照 Naphtha isomerization and desulfuration double-effect catalyst and preparation method thereof
WO2019040487A1 (en) * 2017-08-23 2019-02-28 Phillips 66 Company Processes for selective naphtha reforming
WO2019118825A1 (en) * 2017-12-15 2019-06-20 Invista North America S.A.R.L. Processes for preparing hydrocarbon compositions
US20190224653A1 (en) * 2018-01-23 2019-07-25 Saudi Arabian Oil Company Modified usy-zeolite catalyst for reforming hydrocarbons

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4645586A (en) * 1983-06-03 1987-02-24 Chevron Research Company Reforming process
US5114565A (en) * 1990-01-26 1992-05-19 Chevron Research And Technology Company Reforming naphtha with boron-containing large-pore zeolites
US20080255398A1 (en) * 2007-04-12 2008-10-16 Saudi Basic Industries Corporation Aromatization of alkanes using a germanium-zeolite catalyst

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL238183A (en) * 1962-08-03
US6740228B1 (en) * 1989-10-30 2004-05-25 Exxonmobil Chemical Patents Inc. Process for reforming petroleum hydrocarbon stocks
US5510016A (en) * 1991-08-15 1996-04-23 Mobil Oil Corporation Gasoline upgrading process
US6177374B1 (en) * 1997-01-17 2001-01-23 Council Of Scientific & Industrial Research Catalyst comprising oxides of silicon, zinc and aluminium used for the preparation of LPG and high octane aromatics and a process for preparing the same
US6245219B1 (en) * 1997-04-18 2001-06-12 Exxonmobil Chemical Patents Inc. Naphtha aromatization process
US6083379A (en) * 1998-07-14 2000-07-04 Phillips Petroleum Company Process for desulfurizing and aromatizing hydrocarbons
US6884531B2 (en) * 2001-05-21 2005-04-26 Saudi Arabian Oil Company Liquid hydrocarbon based fuels for fuel cell on-board reformers
US6784333B2 (en) * 2002-08-06 2004-08-31 Saudi Basic Industries Corporation Catalyst for aromatization of alkanes, process of making and using thereof
US7414007B2 (en) * 2002-09-13 2008-08-19 Uop Llc Isomerization catalyst and process
US7029572B2 (en) * 2003-02-25 2006-04-18 Chevron U.S.A. Inc Process for producing high RON gasoline using ATS zeolite
US7037422B2 (en) * 2003-02-25 2006-05-02 Chevron U.S.A. Inc Process for producing high RON gasoline using CFI Zeolite
US7307422B2 (en) * 2003-11-12 2007-12-11 Koninklijke Philips Electronics N.V. MRI system with RF receiver coils fixed to the housing
US7223898B2 (en) * 2005-03-11 2007-05-29 Uop Llc Isomerization process
US8993468B2 (en) * 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
US9221723B2 (en) * 2007-05-24 2015-12-29 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4645586A (en) * 1983-06-03 1987-02-24 Chevron Research Company Reforming process
US5114565A (en) * 1990-01-26 1992-05-19 Chevron Research And Technology Company Reforming naphtha with boron-containing large-pore zeolites
US20080255398A1 (en) * 2007-04-12 2008-10-16 Saudi Basic Industries Corporation Aromatization of alkanes using a germanium-zeolite catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2011068964A1 *

Also Published As

Publication number Publication date
CN102639472A (en) 2012-08-15
SG181153A1 (en) 2012-07-30
IN2012DN03131A (en) 2015-09-18
WO2011068964A1 (en) 2011-06-09
EP2507195A1 (en) 2012-10-10
JP2013512317A (en) 2013-04-11
KR20120088829A (en) 2012-08-08
US20110132804A1 (en) 2011-06-09

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RIC1 Classification (correction)

Ipc: C10G 35/06 20060101ALI20141021BHEP

Ipc: B01J 29/04 20060101ALI20141021BHEP

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