EP2089229B1 - Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof - Google Patents

Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof Download PDF

Info

Publication number
EP2089229B1
EP2089229B1 EP06827989A EP06827989A EP2089229B1 EP 2089229 B1 EP2089229 B1 EP 2089229B1 EP 06827989 A EP06827989 A EP 06827989A EP 06827989 A EP06827989 A EP 06827989A EP 2089229 B1 EP2089229 B1 EP 2089229B1
Authority
EP
European Patent Office
Prior art keywords
nozzle assembly
roof
actuator
inkjet
nozzle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP06827989A
Other languages
German (de)
French (fr)
Other versions
EP2089229A4 (en
EP2089229A1 (en
Inventor
Gregory John Mcavoy
Misty Bagnat
Vincent Patrick Lawlor
Emma Rose Kerr
Kia Silverbrook
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zamtec Ltd
Original Assignee
Silverbrook Research Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Silverbrook Research Pty Ltd filed Critical Silverbrook Research Pty Ltd
Priority to SI200631460T priority Critical patent/SI2089229T1/en
Priority to PL06827989T priority patent/PL2089229T3/en
Publication of EP2089229A1 publication Critical patent/EP2089229A1/en
Publication of EP2089229A4 publication Critical patent/EP2089229A4/en
Application granted granted Critical
Publication of EP2089229B1 publication Critical patent/EP2089229B1/en
Priority to CY20121101049T priority patent/CY1113795T1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/14427Structure of ink jet print heads with thermal bend detached actuators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/015Ink jet characterised by the jet generation process
    • B41J2/04Ink jet characterised by the jet generation process generating single droplets or particles on demand
    • B41J2/045Ink jet characterised by the jet generation process generating single droplets or particles on demand by pressure, e.g. electromechanical transducers
    • B41J2/05Ink jet characterised by the jet generation process generating single droplets or particles on demand by pressure, e.g. electromechanical transducers produced by the application of heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/135Nozzles
    • B41J2/14Structure thereof only for on-demand ink jet heads
    • B41J2/14427Structure of ink jet print heads with thermal bend detached actuators
    • B41J2002/14435Moving nozzle made of thermal bend detached actuator
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2202/00Embodiments of or processes related to ink-jet or thermal heads
    • B41J2202/01Embodiments of or processes related to ink-jet heads
    • B41J2202/15Moving nozzle or nozzle plate

Definitions

  • This invention relates to thermal bend actuators. It has been developed primarily to provide improved inkjet nozzles which eject ink via thermal bend actuation.
  • Thermal bend actuation generally means bend movement generated by thermal expansion of one material, having a current passing therethough, relative to another material. The resulting bend movement may be used to eject ink from a nozzle opening, optionally via movement of a paddle or vane, which creates a pressure wave in a nozzle chamber.
  • the Applicant's US Patent No. 6,416,167 describes an inkjet nozzle having a paddle positioned in a nozzle chamber and a thermal bend actuator positioned externally of the nozzle chamber.
  • the actuator takes the form of a lower active beam of conductive material (e.g . titanium nitride) fused to an upper passive beam of non-conductive material (e.g . silicon dioxide).
  • the actuator is connected to the paddle via an arm received through a slot in the wall of the nozzle chamber.
  • the actuator bends upwards and, consequently, the paddle moves towards a nozzle opening defined in a roof of the nozzle chamber, thereby ejecting a droplet of ink.
  • An advantage of this design is its simplicity of construction.
  • a drawback of this design is that both faces of the paddle work against the relatively viscous ink inside the nozzle chamber.
  • the Applicant's US Patent No. 6,260,953 (assigned to the present Applicant) describes an inkjet nozzle in which the actuator forms a moving roof portion of the nozzle chamber.
  • the actuator is takes the form of a serpentine core of conductive material encased by a polymeric material.
  • Upon actuation the actuator bends towards a floor of the nozzle chamber, increasing the pressure within the chamber and forcing a droplet of ink from a nozzle opening defined in the roof of the chamber.
  • the nozzle opening is defined in a non-moving portion of the roof.
  • An advantage of this design is that only one face of the moving roof portion has to work against the relatively viscous ink inside the nozzle chamber.
  • a drawback of this design is that construction of the actuator from a serpentine conductive element encased by polymeric material is difficult to achieve in a MEMS process.
  • the Applicant's US Patent No. 6,623,101 describes an inkjet nozzle comprising a nozzle chamber with a moveable roof portion having a nozzle opening defined therein.
  • the moveable roof portion is connected via an arm to a thermal bend actuator positioned externally of the nozzle chamber.
  • the actuator takes the form of an upper active beam spaced apart from a lower passive beam. By spacing the active and passive beans apart, thermal bend efficiency is maximized since the passive beam cannot act as heat sink for the active beam.
  • the moveable roof portion, having the nozzle opening defined therein is caused to rotate towards a floor of the nozzle chamber, thereby ejecting through the nozzle opening.
  • drop flight direction may be controlled by suitable modification of the shape of the nozzle rim.
  • An advantage of this design is that only one face of the moving roof portion has to work against the relatively viscous ink inside the nozzle chamber.
  • a further advantage is the minimal thermal losses achieved by spacing apart the active and passive beam members.
  • a drawback of this design is the loss of structural rigidity in spacing apart the active and passive beam members.
  • the present invention provides an inkjet nozzle assembly as detailed in claim 1.
  • the invention also relates to an inkjet printhead or an inkjet printhead integrated circuit as detailed in claim 15.
  • Advantageous embodiments are described in the dependent claims.
  • a MEMS thermal bend actuator (or thermoelastic actuator) comprises a pair of elements in the form of an active element and a passive element, which constrains linear expansion of the active element.
  • the active element is required to undergo greater thermoelastic expansion relative to the passive element, thereby providing a bending motion.
  • the elements may be fused or bonded together for maximum structural integrity or spaced apart for minimizing thermal losses to the passive element.
  • titanium nitride as being a suitable candidate for an active thermoelastic element in a thermal bend actuator (see, for example, US 6,416,167 ).
  • Other suitable materials described in, for example, Applicant's US Patent No. 6,428,133 are TiB 2 , MoSi, and TiAlN.
  • aluminium In terms of its high thermal expansion and low density, aluminium is strong candidate for use as an active thermoelastic element.
  • aluminum suffers from a relatively low Young's modulus, which detracts from its overall thermoelastic efficiency. Accordingly, aluminium had previously been disregarded as a suitable material for use an active thermoelastic element.
  • aluminium alloys are excellent materials for use as thermoelastic active elements, since they combine the advantageous properties of high thermal expansion, low density and high Young's modulus.
  • aluminium is alloyed with at least one metal having a Young's modulus of >100 GPa.
  • aluminium is alloyed with at least one metal selected from the group comprising: vanadium, manganese, chromium, cobalt and nickel.
  • the alloy comprises at least 60%, optionally at least 70%, optionally at least 80% or optionally at least 90% aluminium.
  • Figure 1 shows a bimorph thermal bend actuator 200 in the form of a cantilever beam 201 fixed to a post 202.
  • the cantilever beam 201 comprises a lower active beam 210 bonded to an upper passive beam 220 of silicon dioxide.
  • the thermoelastic efficiencies of the actuator 200 were compared for active beams comprised of: (i) 100% Al; (ii) 95% Al/5% V; and (iii) 90% Al/10% V.
  • Thermoelastic efficiencies were compared by stimulating the active beam 210 with a short electrical pulse and measuring the energy required to establish a peak oscillatory velocity of 3 m/s, as determined by a laser interferometer. The results are shown in the Table below: Active Beam Material Energy Required to Reach Peak Oscillatory Velocity 100% Al 466 nJ 95% Al/5% V 224 nJ 90% Al/10% V 219 nJ
  • the 95% Al/5% V alloy required 2.08 times less energy than the comparable 100% Al device.
  • the 90% Al/10% V alloy required 2.12 times less energy than the comparable 100% Al device. It was therefore concluded that aluminium alloys are excellent candidates for use as active thermoelastic elements in a range of MEMS applications, including thermal bend actuators for inkjet nozzles.
  • thermal bend actuator having an active element comprised of aluminium alloy.
  • FIGS. 2(A) and 3 there are shown schematic illustrations of a nozzle assembly 100 according to a first embodiment.
  • the nozzle assembly 100 is formed by MEMS processes on a passivation layer 2 of a silicon substrate 3, as described in US 6,416,167 .
  • the nozzle assembly 100 comprises a nozzle chamber 1 having a roof 4 and sidewall 5.
  • the nozzle chamber 1 is filled with ink 6 by means of an ink inlet channel 7 etched through the substrate 3.
  • the nozzle chamber 1 further includes a nozzle opening 8 for ejection of ink from the nozzle chamber.
  • An ink meniscus 20 is pinned across a rim 21 of the nozzle opening 8, as shown in Figure 2(A) .
  • the nozzle assembly 100 further comprises a paddle 9, positioned inside the nozzle chamber 1, which is interconnected via an arm 11 to an actuator 10 positioned externally of the nozzle chamber. As shown more clearly in Figure 2 , the arm extends through a slot 12 in nozzle chamber 1. Surface tension of ink within the slot 12 is sufficient to provide a fluidic seal for ink contained in the nozzle chamber 1.
  • the actuator 10 comprises a plurality of elongate actuator units 13, which are spaced apart transversely. Each actuator unit extends between a fixed post 14, which is mounted on the passivation layer 2, and the arm 11. Hence, the post 14 provides a pivot for the bending motion of the actuator 10.
  • Each actuator unit 13 comprises a first active beam 15 and a second passive beam 16 fused to an upper face of the active beam.
  • the active beam 15 is conductive and connected to drive circuitry in a CMOS layer of the substrate 3.
  • the passive beam 16 is typically non-conductive.
  • a droplet of ink 17 is ejected from the nozzle opening 8 and at the same time ink 6 reflows into the nozzle chamber 1 via the ink inlet 7.
  • the forward momentum of the ink outside the nozzle rim 21 and the corresponding backflow results in a general necking and breaking off of the droplet 17 which proceeds towards a print medium, as shown in Figure 2(C) .
  • the collapsed meniscus 20 causes ink 6 to be sucked into the nozzle chamber 1 via the ink inlet 7.
  • the nozzle chamber 1 is refilled such that the position in Figure 2(A) is again reached and the nozzle assembly 100 is ready for the ejection of another droplet of ink.
  • actuator units 13 are tapered with respect to their transverse axes, having a narrower end connected to the post 14 and a wider end connected to the arm 11. This tapering ensures that maximum resistive heating takes place near the post 14, thereby maximizing the thermoelastic bending motion.
  • the passive beam 16 is comprised of silicon dioxide or TEOS deposited by CVD. As shown in the Figures 2 to 4 , the arm 11 is formed from the same material.
  • the active beam 15 is comprised of an aluminum alloy, preferably an aluminum-vanadium alloy as described above.
  • Nozzle Assembly Comprising Spaced Apart Thermal Bend Actuator
  • the nozzle assembly 300 is constructed (by way of MEMS technology) on a substrate 301 defining an ink supply aperture 302 opening through a hexagonal inlet 303 (which could be of any other suitable configuration) into a chamber 304.
  • the chamber is defined by a floor portion 305, roof portion 306 and peripheral sidewalls 307 and 308 which overlap in a telescopic manner.
  • the sidewalls 307, depending downwardly from roof portion 306, are sized to be able to move upwardly and downwardly within sidewalls 308 which depend upwardly from floor portion 305.
  • the ejection nozzle is formed by rim 309 located in the roof portion 306 so as to define an opening for the ejection of ink from the nozzle chamber as will be described further below.
  • the roof portion 306 and downwardly depending sidewalls 307 are supported by a bend actuator 310 typically made up of layers forming a Joule heated cantilever which is constrained by a non-heated cantilever, so that heating of the Joule heated cantilever causes a differential expansion between the Joule heated cantilever and the non-heated cantilever causing the bend actuator 310 to bend.
  • a bend actuator 310 typically made up of layers forming a Joule heated cantilever which is constrained by a non-heated cantilever, so that heating of the Joule heated cantilever causes a differential expansion between the Joule heated cantilever and the non-heated cantilever causing the bend actuator 310 to bend.
  • the proximal end 311 of the bend actuator is fastened to the substrate 301, and prevented from moving backwards by an anchor member 312 which will be described further below, and the distal end 313 is secured to, and supports, the roof portion 306 and sidewalls 307 of the ink jet nozzle.
  • ink is supplied into the nozzle chamber through passage 302 and opening 303 in any suitable manner.
  • an electric current is supplied to the bend actuator 310 causing the actuator to bend to the position shown in Figure 6 and move the roof portion 306 downwardly toward the floor portion 305.
  • This relative movement decreases the volume of the nozzle chamber, causing ink to bulge upwardly through the nozzle rim 309 as shown at 314 ( Fig. 6 ) where it is formed to a droplet by the surface tension in the ink.
  • the actuator reverts to the straight configuration as shown in Figure 7 moving the roof portion 306 of the nozzle chamber upwardly to the original location.
  • the momentum of the partially formed ink droplet 314 causes the droplet to continue to move upwardly forming an ink drop 315 as shown in Fig. 7 which is projected on to the adjacent paper surface or other article to be printed.
  • the opening 303 in floor portion 305 is relatively large compared with the cross-section of the nozzle chamber and the ink droplet is caused to be ejected through the nozzle rim 309 upon downward movement of the roof portion 306 by viscous drag in the sidewalls of the aperture 302, and in the supply conduits leading from the ink reservoir (not shown) to the opening 302.
  • a fluidic seal is formed between sidewalls 307 and 308 as will now be further described with specific reference to Figures 7 and 8 .
  • the ink is retained in the nozzle chamber during relative movement of the roof portion 306 and floor portion 305 by the geometric features of the sidewalls 307 and 308 which ensure that ink is retained within the nozzle chamber by surface tension.
  • the ink (shown as a dark shaded area) is restrained within the small aperture between the downwardly depending sidewall 307 and inward faces 316 of the upwardly extending sidewall by the proximity of the two sidewalls which ensures that the ink "self seals" across free opening 317 by surface tension, due to the close proximity of the sidewalls.
  • the upwardly depending sidewall 308 is provided in the form of an upwardly facing channel having not only the inner surface 316 but a spaced apart parallel outer surface 18 forming a U-shaped channel 319 between the two surfaces. Any ink drops escaping from the surface tension between the surfaces 307 and 316, overflows into the U-shaped channel where it is retained rather than "wicking" across the surface of the nozzle strata. In this manner, a dual wall fluidic seal is formed which is effective in retaining the ink within the moving nozzle mechanism.
  • the actuator 310 is comprised of a first, active beam 358 arranged above and spaced apart from a second, passive beam 360. By spacing apart the two beams, thermal transfer from the active beam 358 to the passive beam 360 is minimized. Accordingly, this spaced apart arrangement has the advantage of maximizing thermoelastic efficiency.
  • the active beam 358 may be comprised of an aluminium alloy, as described above, such as aluminium-vanadium alloy.
  • FIG. 5 The embodiments exemplified by Figures 5 to 8 showed a nozzle assembly 300 comprising a nozzle chamber 304 having a roof portion 306 which moves relative to a floor portion 305 of the chamber.
  • the moveable roof portion 306 is actuated to move towards the floor portion 305 by means of a bi-layered thermal bend actuator 310 positioned externally of the nozzle chamber 305.
  • a moving roof lowers the drop ejection energy, since only one face of the moving structure has to do work against the viscous ink.
  • a shorter pulse width can be used to provide the same amount of energy. With shorter pulse widths, improved drop ejection characteristics can be achieved.
  • actuator power is to increase the size of the actuator.
  • nozzle design shown in Figures 5 to 8 it is apparent that an increase in actuator size would adversely affect nozzle spacing, which is undesirable in the manufacture of high-resolution pagewidth printheads.
  • the nozzle assembly 400 comprises a nozzle chamber 401 formed on a passivated CMOS layer 402 of a silicon substrate 403.
  • the nozzle chamber is defined by a roof 404 and sidewalls 405 extending from the roof to the passivated CMOS layer 402.
  • Ink is supplied to the nozzle chamber 401 by means of an ink inlet 406 in fluid communication with an ink supply channel 407 receiving ink from backside of the silicon substrate.
  • Ink is ejected from the nozzle chamber 401 by means of a nozzle opening 408 defined in the roof 404.
  • the nozzle opening 408 is offset from the ink inlet 406.
  • the roof 404 has a moving portion 409, which defines a substantial part of the total area of the roof.
  • the moving portion 409 defines at least 20%, at least 30%, at least 40% or at least 50% of the total area of the roof 404.
  • the nozzle opening 408 and nozzle rim 415 are defined in the moving portion 409, such that the nozzle opening and nozzle rim move with the moving portion.
  • the nozzle assembly 400 is characterized in that the moving portion 409 is defined by a thermal bend actuator 410 having a planar upper active beam 411 and a planar lower passive beam 412.
  • the actuator 410 typically defines at least 20%, at least 30%, at least 40% or at least 50% of the total area of the roof 404.
  • the upper active beam 411 typically defines at least 20%, at least 30%, at least 40% or at least 50% of the total area of the roof 404.
  • the upper active beam 411 is spaced apart from the lower passive beam 412 for maximizing thermal insulation of the two beams. More specifically, a layer of Ti is used as a bridging layer 413 between the upper active beam 411 comprised of TiN and the lower passive beam 412 comprised of SiO 2 .
  • the bridging layer 413 allows a gap 414 to be defined in the actuator 410 between the active and passive beams. This gap 414 improves the overall efficiency of the actuator 410 by minimizing thermal transfer from the active beam 411 to the passive beam 412.
  • the active beam 411 may, alternatively, be fused or bonded directly to the passive beam 412 for improved structural rigidity.
  • Such design modifications would be well within the ambit of the skilled person and are encompassed within the scope of the present invention.
  • the active beam 411 is connected to a pair of contacts 416 (positive and ground) via the Ti bridging layer.
  • the contacts 416 connect with drive circuitry in the CMOS layers.
  • a current flows through the active beam 411 between the two contacts 416.
  • the active beam 411 is rapidly heated by the current and expand relative to the passive beam 412, thereby causing the actuator 410 (which defines the moving portion 409 of the roof 404) to bend downwards towards the substrate 403.
  • This movement of the actuator 410 causes ejection of ink from the nozzle opening 408 by a rapid increase of pressure inside the nozzle chamber 401.
  • the moving portion 409 of the roof 404 is allowed to return to its quiescent position, which sucks ink from the inlet 406 into the nozzle chamber 401, in readiness for the next ejection.
  • ink droplet ejection is analogous to that described above in connection with nozzle assembly 300.
  • thermal bend actuator 410 defining the moving portion 409 of the roof 404, a much greater amount of power is made available for droplet ejection, because the active beam 411 has a large area compared with the overall size of the nozzle assembly 400.
  • nozzle assembly 400 may be replicated into an array of nozzle assemblies to define a printhead or printhead integrated circuit.
  • a printhead integrated circuit comprises a silicon substrate, an array of nozzle assemblies (typically arranged in rows) fouled on the substrate, and drive circuitry for the nozzle assemblies.
  • a plurality of printhead integrated circuits may be abutted or linked to form a pagewidth inkjet printhead, as described in, for example, Applicant's earlier US Application Nos. 10/854,491 filed on May 27, 2004 and 11/014,732 filed on December 20, 2004 .
  • the nozzle assembly 500 shown in Figures 13 to 15 is similar to the nozzle assembly 400 insofar as a thermal bend actuator 510, having an upper active beam 511 and a lower passive beam 512, defines a moving portion of a roof 504 of the nozzle chamber 501.
  • the nozzle assembly 500 achieves the same advantages, in terms of increased power, as the nozzle assembly 400.
  • the nozzle opening 508 and rim 515 are not defined by the moving portion of the roof 504. Rather, the nozzle opening 508 and rim 515 are defined in a fixed portion of the roof 504 such that the actuator 510 moves independently of the nozzle opening and rim during droplet ejection.
  • An advantage of this arrangement is that it provides more facile control of drop flight direction.
  • the aluminium alloys may be used as the active beam in either of the thermal bend actuators 410 and 510 described above in connection with the embodiments shown in Figures 9 to 15 .
  • the nozzle assemblies 400 and 500 may be constructed using suitable MEMS technologies in an analogous manner to inkjet nozzle manufacturing processes exemplified in the Applicant's earlier US Patent Nos. 6,416,167 and 6,755,509 .
  • the upper active beams 411 and 511 of the actuators 410 and 510 are each comprised of a tortuous beam element having either a bent (in the case of beam 411) or serpentine (in the case of beam 511) configuration.
  • the tortuous beam element is elongate and has a relatively small cross-sectional area suitable for resistive heating.
  • the tortuous configuration enables respective ends of the beam element to be connected to respective contacts positioned at one end of the actuator, simplifying the overall design and construction of the nozzle assembly.
  • an elongate beam element 520 has a serpentine configuration defining the elongate active cantilever beam 511 of the actuator 510.
  • the serpentine beam element 520 has a planar, tortuous path connecting a first electrical contact 516 with a second electrical contact 516.
  • the electrical contacts 516 (positive and ground) are positioned at one end of the actuator 510 and provide electrical connection between drive circuitry in the CMOS layers 502 and the active beam 511.
  • the serpentine beam element 520 is fabricated by standard lithographic etching techniques and defined by a plurality of contiguous beam members.
  • beam members may be defined as solid portions of beam material, which extend substantially linearly in, for example, a longitudinal or transverse direction.
  • the beam members of beam element 520 are comprised of longer beam members 521, which extend along a longitudinal axis of the elongate cantilever beam 511, and shorter beam members 522, which extend across a transverse axis of the elongate cantilever beam 511.
  • An advantage of this configuration for the serpentine beam element 520 is that it provides maximum stiffness in a bend direction of the cantilever beam 511. Stiffness in the bend direction is advantageous because it facilitates bending of the actuator 510 back to its quiescent position after each actuation.
  • bent active beam configuration for the nozzle assembly 400 shown in Figure 11 achieves the same or similar advantages to those described above in connection with nozzle assembly 500.
  • the longer beam members, extending longitudinally, are indicated as 421, whilst the interconnecting shorter beam member, extending transversely, is indicated as 422.
  • the active beam is either bonded to the passive beam for structural robustness (see Figures 1 and 2 ), or the active beam is spaced apart from the passive beam for maximum thermal efficiency (see Figure 8 ).
  • the thermal efficiency provided by an air gap between the beams is, of course, desirable. However, this improvement in thermal efficiency is usually at the expense of structural robustness and a propensity for buckling of the thermal bend actuator.
  • porous silicon dioxide insulator having a dielectric constant of about 2.0 or less.
  • the material is formed by deposition of silicon carbide and oxidation of the carbon component to form porous silicon dioxide.
  • the porosity of the resultant porous silicon dioxide can be increased.
  • Porous silicon dioxide are known to be useful as a passivation layer in integrated circuits for reducing parasitic resistance.
  • porous materials of this type are useful for improving the efficiency of thermal bend actuators.
  • a porous material may be used either as an insulating layer between an active beam and a passive beam, or it may be used as the passive beam itself.
  • Figure 16 shows a thermal bend actuator 600 comprising an upper active beam 601, a lower passive beam 602 and an insulating layer 603 sandwiched between the upper and lower beams.
  • the insulating beam is comprised of porous silicon dioxide, while the active and passive beams 601 and 602 may be comprised of any suitable materials, such as TiN and SiO 2 , respectively.
  • the porosity of the insulating layer 603 provides excellent thermal insulation between the active and passive beams 601 and 602.
  • the insulating layer 603 also provides the actuator 600 with structural robustness. Hence, the actuator 600 combines the advantages of both types of thermal bend actuator described above in connection with Figures 1 , 2 and 8 .
  • the porous material may simply form the passive layer of a bi-layered thermal bend actuator.
  • the thermal bend actuator 650 comprises an upper active beam 651 comprised of TiN, and a lower passive beam 652 comprised of porous silicon dioxide.
  • thermal bend actuators of the types shown in Figures 16 and 17 may be incorporated into any suitable inkjet nozzle or other MEMS device.
  • the improvements in thermal efficiency and structural rigidity make such actuators attractive in any MEMS application requiring a mechanical actuator or transducer.
  • thermal bend actuators of the types shown in Figures 16 and 17 are particularly suitable for use in the inkjet nozzle assemblies 400 and 500 described above.
  • the skilled person would readily appreciate that appropriate modifications of the thermal bend actuators 410 and 10 would realize the above-mentioned improvements in thermal efficiency and structural robustness.
  • active beam members 601 and 651 in the thermal bend actuators 600 and 650 described above may be comprised of an aluminum alloy, as described herein, for further improvements in thermal bend efficiency.

Abstract

An inkjet nozzle assembly is provided. The assembly comprises a nozzle chamber comprising a floor and a roof. The roof has a nozzle opening defined therein, and a moving portion moveable towards the floor. The assembly further comprises a thermal bend actuator, having a plurality of cantilever beams, for ejecting ink through the nozzle opening. A first active beam of the actuator defines at least 30% of a total area of the roof.

Description

    Field of the Invention
  • This invention relates to thermal bend actuators. It has been developed primarily to provide improved inkjet nozzles which eject ink via thermal bend actuation.
  • Background of the Invention
  • The present Applicant has described previously a plethora of MEMS inkjet nozzles using thermal bend actuation. Thermal bend actuation generally means bend movement generated by thermal expansion of one material, having a current passing therethough, relative to another material. The resulting bend movement may be used to eject ink from a nozzle opening, optionally via movement of a paddle or vane, which creates a pressure wave in a nozzle chamber.
  • The Applicant's US Patent No. 6,416,167 describes an inkjet nozzle having a paddle positioned in a nozzle chamber and a thermal bend actuator positioned externally of the nozzle chamber. The actuator takes the form of a lower active beam of conductive material (e.g. titanium nitride) fused to an upper passive beam of non-conductive material (e.g. silicon dioxide). The actuator is connected to the paddle via an arm received through a slot in the wall of the nozzle chamber. Upon passing a current through the lower active beam, the actuator bends upwards and, consequently, the paddle moves towards a nozzle opening defined in a roof of the nozzle chamber, thereby ejecting a droplet of ink. An advantage of this design is its simplicity of construction. A drawback of this design is that both faces of the paddle work against the relatively viscous ink inside the nozzle chamber.
  • The Applicant's US Patent No. 6,260,953 (assigned to the present Applicant) describes an inkjet nozzle in which the actuator forms a moving roof portion of the nozzle chamber. The actuator is takes the form of a serpentine core of conductive material encased by a polymeric material. Upon actuation the actuator bends towards a floor of the nozzle chamber, increasing the pressure within the chamber and forcing a droplet of ink from a nozzle opening defined in the roof of the chamber. The nozzle opening is defined in a non-moving portion of the roof. An advantage of this design is that only one face of the moving roof portion has to work against the relatively viscous ink inside the nozzle chamber. A drawback of this design is that construction of the actuator from a serpentine conductive element encased by polymeric material is difficult to achieve in a MEMS process.
  • The Applicant's US Patent No. 6,623,101 describes an inkjet nozzle comprising a nozzle chamber with a moveable roof portion having a nozzle opening defined therein. The moveable roof portion is connected via an arm to a thermal bend actuator positioned externally of the nozzle chamber. The actuator takes the form of an upper active beam spaced apart from a lower passive beam. By spacing the active and passive beans apart, thermal bend efficiency is maximized since the passive beam cannot act as heat sink for the active beam. Upon passing a current through the active upper beam, the moveable roof portion, having the nozzle opening defined therein, is caused to rotate towards a floor of the nozzle chamber, thereby ejecting through the nozzle opening. Since the nozzle opening moves with the roof portion, drop flight direction may be controlled by suitable modification of the shape of the nozzle rim. An advantage of this design is that only one face of the moving roof portion has to work against the relatively viscous ink inside the nozzle chamber. A further advantage is the minimal thermal losses achieved by spacing apart the active and passive beam members. A drawback of this design is the loss of structural rigidity in spacing apart the active and passive beam members.
  • The Applicant's US Published Application No. US 2005/243131 describes an inkjet nozzle assembly comprising a nozzle chamber having a moveable roof. The moveable roof is engaged with a plurality of thermal bend actuators, positioned externally of the nozzle chamber, which urge the moveable roof towards a floor of the nozzle chamber upon actuation.
  • There is a need to improve upon the design of thermal bend inkjet nozzles, so as to achieve more efficient drop ejection and improved mechanical robustness.
  • Summary of the Invention
  • Accordingly, the present invention provides an inkjet nozzle assembly as detailed in claim 1. The invention also relates to an inkjet printhead or an inkjet printhead integrated circuit as detailed in claim 15. Advantageous embodiments are described in the dependent claims.
  • Brief Description of the Drawings
    • Figure 1 is a schematic side view of a bi-layered thermal bend actuator comprising an active beam formed from aluminium-vanadium alloy;
    • Figures 2(A)-(C) are schematic side sectional views of an inkjet nozzle assembly comprising a fused thermal bend actuator at various stages of operation;
    • Figure 3 is a perspective view of the nozzle assembly shown in Figure 2(A);
    • Figure 4 is a perspective view of part of a printhead integrated circuit comprising an array of nozzle assemblies, as shown in Figures 2(A) and 3;
    • Figure 5 is a cutaway perspective view of an inkjet nozzle assembly comprising a spaced apart thermal bend actuator and moving roof structure;
    • Figure 6 is a cutaway perspective view of the inkjet nozzle assembly shown in Figure 5 in an actuated configuration;
    • Figure 7 is a cutaway perspective view of the inkjet nozzle assembly shown in Figure 5 immediately after de-actuation;
    • Figure 8 is a side sectional view of the nozzle assembly shown in Figure 6;
    • Figure 9 is a side sectional view of an inkjet nozzle assembly comprising a roof having a moving portion defined by a thermal bend actuator;
    • Figure 10 is a cutaway perspective view of the nozzle assembly shown in Figure 9;
    • Figure 11 is a perspective view of the nozzle assembly shown in Figure 10;
    • Figure 12 is a cutaway perspective view of an array of the nozzle assemblies shown in Figure 10;
    • Figure 13 is a side sectional view of an alternative inkjet nozzle assembly comprising a roof having a moving portion defined by a thermal bend actuator;
    • Figure 14 is a cutaway perspective view of the nozzle assembly shown in Figure 13:
    • Figure 15 is a perspective view of the nozzle assembly shown in Figure 13;
    • Figure 16 is a schematic side view of a tri-layered thermal bend actuator comprising a sandwiched insulating beam formed of porous material; and
    • Figure 17 is a schematic side view of a bi-layered thermal bend actuator comprising a passive beam formed of porous material.
    Detailed Description of the Invention Thermoelastic Active Element Comprised of Aluminium Alloy
  • Typically, a MEMS thermal bend actuator (or thermoelastic actuator) comprises a pair of elements in the form of an active element and a passive element, which constrains linear expansion of the active element. The active element is required to undergo greater thermoelastic expansion relative to the passive element, thereby providing a bending motion. The elements may be fused or bonded together for maximum structural integrity or spaced apart for minimizing thermal losses to the passive element.
  • Hitherto, we described titanium nitride as being a suitable candidate for an active thermoelastic element in a thermal bend actuator (see, for example, US 6,416,167 ). Other suitable materials described in, for example, Applicant's US Patent No. 6,428,133 are TiB2, MoSi, and TiAlN.
  • In terms of its high thermal expansion and low density, aluminium is strong candidate for use as an active thermoelastic element. However, aluminum suffers from a relatively low Young's modulus, which detracts from its overall thermoelastic efficiency. Accordingly, aluminium had previously been disregarded as a suitable material for use an active thermoelastic element.
  • However, it has now been found that aluminium alloys are excellent materials for use as thermoelastic active elements, since they combine the advantageous properties of high thermal expansion, low density and high Young's modulus.
  • Typically, aluminium is alloyed with at least one metal having a Young's modulus of >100 GPa. Typically, aluminium is alloyed with at least one metal selected from the group comprising: vanadium, manganese, chromium, cobalt and nickel. Surprisingly, it has been found that the excellent thermal expansion properties of aluminium are not compromised when alloyed with such metals.
  • Optionally, the alloy comprises at least 60%, optionally at least 70%, optionally at least 80% or optionally at least 90% aluminium.
  • Figure 1 shows a bimorph thermal bend actuator 200 in the form of a cantilever beam 201 fixed to a post 202. The cantilever beam 201 comprises a lower active beam 210 bonded to an upper passive beam 220 of silicon dioxide. The thermoelastic efficiencies of the actuator 200 were compared for active beams comprised of: (i) 100% Al; (ii) 95% Al/5% V; and (iii) 90% Al/10% V.
  • Thermoelastic efficiencies were compared by stimulating the active beam 210 with a short electrical pulse and measuring the energy required to establish a peak oscillatory velocity of 3 m/s, as determined by a laser interferometer. The results are shown in the Table below:
    Active Beam Material Energy Required to Reach Peak Oscillatory Velocity
    100% Al 466 nJ
    95% Al/5% V 224 nJ
    90% Al/10% V 219 nJ
  • Thus, the 95% Al/5% V alloy required 2.08 times less energy than the comparable 100% Al device. Further, the 90% Al/10% V alloy required 2.12 times less energy than the comparable 100% Al device. It was therefore concluded that aluminium alloys are excellent candidates for use as active thermoelastic elements in a range of MEMS applications, including thermal bend actuators for inkjet nozzles.
  • Inkjet Nozzles Comprising a Thermal Bend Actuator
  • There now follows a description of typical inkjet nozzles, which may incorporate a thermal bend actuator having an active element comprised of aluminium alloy.
  • Nozzle Assembly Comprising Fused Thermal Bend Actuator
  • Turning initially to Figures 2(A) and 3, there are shown schematic illustrations of a nozzle assembly 100 according to a first embodiment. The nozzle assembly 100 is formed by MEMS processes on a passivation layer 2 of a silicon substrate 3, as described in US 6,416,167 . The nozzle assembly 100 comprises a nozzle chamber 1 having a roof 4 and sidewall 5. The nozzle chamber 1 is filled with ink 6 by means of an ink inlet channel 7 etched through the substrate 3. The nozzle chamber 1 further includes a nozzle opening 8 for ejection of ink from the nozzle chamber. An ink meniscus 20 is pinned across a rim 21 of the nozzle opening 8, as shown in Figure 2(A).
  • The nozzle assembly 100 further comprises a paddle 9, positioned inside the nozzle chamber 1, which is interconnected via an arm 11 to an actuator 10 positioned externally of the nozzle chamber. As shown more clearly in Figure 2, the arm extends through a slot 12 in nozzle chamber 1. Surface tension of ink within the slot 12 is sufficient to provide a fluidic seal for ink contained in the nozzle chamber 1.
  • The actuator 10 comprises a plurality of elongate actuator units 13, which are spaced apart transversely. Each actuator unit extends between a fixed post 14, which is mounted on the passivation layer 2, and the arm 11. Hence, the post 14 provides a pivot for the bending motion of the actuator 10.
  • Each actuator unit 13 comprises a first active beam 15 and a second passive beam 16 fused to an upper face of the active beam. The active beam 15 is conductive and connected to drive circuitry in a CMOS layer of the substrate 3. The passive beam 16 is typically non-conductive.
  • Referring now to Figure 2(B), when current flows through the active beam 15, it is heated and undergoes thermal expansion relative to the passive beam 16. This causes upward bending movement of the actuator 10, which is magnified into a rotational movement of the paddle 9.
  • This consequential paddle movement causes a general increase in pressure around the ink meniscus 20 which expands, as illustrated in Figure 1(B), in a rapid manner. Subsequently the actuator is deactivated, which causes the paddle 9 to return to its quiescent position (Figure 2(C)).
  • During this pulsing cycle, a droplet of ink 17 is ejected from the nozzle opening 8 and at the same time ink 6 reflows into the nozzle chamber 1 via the ink inlet 7. The forward momentum of the ink outside the nozzle rim 21 and the corresponding backflow results in a general necking and breaking off of the droplet 17 which proceeds towards a print medium, as shown in Figure 2(C). The collapsed meniscus 20 causes ink 6 to be sucked into the nozzle chamber 1 via the ink inlet 7. The nozzle chamber 1 is refilled such that the position in Figure 2(A) is again reached and the nozzle assembly 100 is ready for the ejection of another droplet of ink.
  • Turning to Figure 3, it will be seen that the actuator units 13 are tapered with respect to their transverse axes, having a narrower end connected to the post 14 and a wider end connected to the arm 11. This tapering ensures that maximum resistive heating takes place near the post 14, thereby maximizing the thermoelastic bending motion.
  • Typically, the passive beam 16 is comprised of silicon dioxide or TEOS deposited by CVD. As shown in the Figures 2 to 4, the arm 11 is formed from the same material.
  • In the present invention, the active beam 15 is comprised of an aluminum alloy, preferably an aluminum-vanadium alloy as described above.
  • Nozzle Assembly Comprising Spaced Apart Thermal Bend Actuator
  • Turning now to Figures 5 to 8, there is shown a nozzle assembly 300, in accordance with a second embodiment. Referring to Figures 5 to 7 of the accompanying drawings, the nozzle assembly 300 is constructed (by way of MEMS technology) on a substrate 301 defining an ink supply aperture 302 opening through a hexagonal inlet 303 (which could be of any other suitable configuration) into a chamber 304. The chamber is defined by a floor portion 305, roof portion 306 and peripheral sidewalls 307 and 308 which overlap in a telescopic manner. The sidewalls 307, depending downwardly from roof portion 306, are sized to be able to move upwardly and downwardly within sidewalls 308 which depend upwardly from floor portion 305.
  • The ejection nozzle is formed by rim 309 located in the roof portion 306 so as to define an opening for the ejection of ink from the nozzle chamber as will be described further below.
  • The roof portion 306 and downwardly depending sidewalls 307 are supported by a bend actuator 310 typically made up of layers forming a Joule heated cantilever which is constrained by a non-heated cantilever, so that heating of the Joule heated cantilever causes a differential expansion between the Joule heated cantilever and the non-heated cantilever causing the bend actuator 310 to bend.
  • The proximal end 311 of the bend actuator is fastened to the substrate 301, and prevented from moving backwards by an anchor member 312 which will be described further below, and the distal end 313 is secured to, and supports, the roof portion 306 and sidewalls 307 of the ink jet nozzle.
  • In use, ink is supplied into the nozzle chamber through passage 302 and opening 303 in any suitable manner. When it is desired to eject a drop of ink from the nozzle chamber, an electric current is supplied to the bend actuator 310 causing the actuator to bend to the position shown in Figure 6 and move the roof portion 306 downwardly toward the floor portion 305. This relative movement decreases the volume of the nozzle chamber, causing ink to bulge upwardly through the nozzle rim 309 as shown at 314 (Fig. 6) where it is formed to a droplet by the surface tension in the ink.
  • As the electric current is withdrawn from the bend actuator 310, the actuator reverts to the straight configuration as shown in Figure 7 moving the roof portion 306 of the nozzle chamber upwardly to the original location. The momentum of the partially formed ink droplet 314 causes the droplet to continue to move upwardly forming an ink drop 315 as shown in Fig. 7 which is projected on to the adjacent paper surface or other article to be printed.
  • In one form of the invention, the opening 303 in floor portion 305 is relatively large compared with the cross-section of the nozzle chamber and the ink droplet is caused to be ejected through the nozzle rim 309 upon downward movement of the roof portion 306 by viscous drag in the sidewalls of the aperture 302, and in the supply conduits leading from the ink reservoir (not shown) to the opening 302.
  • In order to prevent ink leaking from the nozzle chamber during actuation ie. during bending of the bend actuator 310, a fluidic seal is formed between sidewalls 307 and 308 as will now be further described with specific reference to Figures 7 and 8.
  • The ink is retained in the nozzle chamber during relative movement of the roof portion 306 and floor portion 305 by the geometric features of the sidewalls 307 and 308 which ensure that ink is retained within the nozzle chamber by surface tension. To this end, there is provided a very fine gap between downwardly depending sidewall 307 and the mutually facing surface 316 of the upwardly depending sidewall 308. As can be clearly seen in Fig. 8 the ink (shown as a dark shaded area) is restrained within the small aperture between the downwardly depending sidewall 307 and inward faces 316 of the upwardly extending sidewall by the proximity of the two sidewalls which ensures that the ink "self seals" across free opening 317 by surface tension, due to the close proximity of the sidewalls.
  • In order to make provision for any ink which may escape the surface tension restraint due to impurities or other factors which may break the surface tension, the upwardly depending sidewall 308 is provided in the form of an upwardly facing channel having not only the inner surface 316 but a spaced apart parallel outer surface 18 forming a U-shaped channel 319 between the two surfaces. Any ink drops escaping from the surface tension between the surfaces 307 and 316, overflows into the U-shaped channel where it is retained rather than "wicking" across the surface of the nozzle strata. In this manner, a dual wall fluidic seal is formed which is effective in retaining the ink within the moving nozzle mechanism.
  • Referring to Figure 8, it will been seen that the actuator 310 is comprised of a first, active beam 358 arranged above and spaced apart from a second, passive beam 360. By spacing apart the two beams, thermal transfer from the active beam 358 to the passive beam 360 is minimized. Accordingly, this spaced apart arrangement has the advantage of maximizing thermoelastic efficiency. In the present invention, the active beam 358 may be comprised of an aluminium alloy, as described above, such as aluminium-vanadium alloy.
  • Thermal Bend Actuator Defining Moving Nozzle Roof
  • The embodiments exemplified by Figures 5 to 8 showed a nozzle assembly 300 comprising a nozzle chamber 304 having a roof portion 306 which moves relative to a floor portion 305 of the chamber. The moveable roof portion 306 is actuated to move towards the floor portion 305 by means of a bi-layered thermal bend actuator 310 positioned externally of the nozzle chamber 305.
  • A moving roof lowers the drop ejection energy, since only one face of the moving structure has to do work against the viscous ink. However, there is still a need to increase the amount of power available for drop ejection. By increasing the amount of power, a shorter pulse width can be used to provide the same amount of energy. With shorter pulse widths, improved drop ejection characteristics can be achieved.
  • One means for increasing actuator power is to increase the size of the actuator. However, in the nozzle design shown in Figures 5 to 8, it is apparent that an increase in actuator size would adversely affect nozzle spacing, which is undesirable in the manufacture of high-resolution pagewidth printheads.
  • A solution to this problem is provided by the nozzle assembly 400 shown in Figures 9 to 12. The nozzle assembly 400 comprises a nozzle chamber 401 formed on a passivated CMOS layer 402 of a silicon substrate 403. The nozzle chamber is defined by a roof 404 and sidewalls 405 extending from the roof to the passivated CMOS layer 402. Ink is supplied to the nozzle chamber 401 by means of an ink inlet 406 in fluid communication with an ink supply channel 407 receiving ink from backside of the silicon substrate. Ink is ejected from the nozzle chamber 401 by means of a nozzle opening 408 defined in the roof 404. The nozzle opening 408 is offset from the ink inlet 406.
  • As shown more clearly in Figure 10, the roof 404 has a moving portion 409, which defines a substantial part of the total area of the roof. Typically, the moving portion 409 defines at least 20%, at least 30%, at least 40% or at least 50% of the total area of the roof 404. In the embodiment shown in Figures 9 to 12, the nozzle opening 408 and nozzle rim 415 are defined in the moving portion 409, such that the nozzle opening and nozzle rim move with the moving portion.
  • The nozzle assembly 400 is characterized in that the moving portion 409 is defined by a thermal bend actuator 410 having a planar upper active beam 411 and a planar lower passive beam 412. Hence, the actuator 410 typically defines at least 20%, at least 30%, at least 40% or at least 50% of the total area of the roof 404. Correspondingly, the upper active beam 411 typically defines at least 20%, at least 30%, at least 40% or at least 50% of the total area of the roof 404.
  • As shown in Figures 9 and 10, at least part of the upper active beam 411 is spaced apart from the lower passive beam 412 for maximizing thermal insulation of the two beams. More specifically, a layer of Ti is used as a bridging layer 413 between the upper active beam 411 comprised of TiN and the lower passive beam 412 comprised of SiO2. The bridging layer 413 allows a gap 414 to be defined in the actuator 410 between the active and passive beams. This gap 414 improves the overall efficiency of the actuator 410 by minimizing thermal transfer from the active beam 411 to the passive beam 412.
  • However, it will of course be appreciated that the active beam 411 may, alternatively, be fused or bonded directly to the passive beam 412 for improved structural rigidity. Such design modifications would be well within the ambit of the skilled person and are encompassed within the scope of the present invention.
  • The active beam 411 is connected to a pair of contacts 416 (positive and ground) via the Ti bridging layer. The contacts 416 connect with drive circuitry in the CMOS layers.
  • When it is required to eject a droplet of ink from the nozzle chamber 401, a current flows through the active beam 411 between the two contacts 416. The active beam 411 is rapidly heated by the current and expand relative to the passive beam 412, thereby causing the actuator 410 (which defines the moving portion 409 of the roof 404) to bend downwards towards the substrate 403. This movement of the actuator 410 causes ejection of ink from the nozzle opening 408 by a rapid increase of pressure inside the nozzle chamber 401. When current stops flowing, the moving portion 409 of the roof 404 is allowed to return to its quiescent position, which sucks ink from the inlet 406 into the nozzle chamber 401, in readiness for the next ejection.
  • Accordingly, the principle of ink droplet ejection is analogous to that described above in connection with nozzle assembly 300. However, with the thermal bend actuator 410 defining the moving portion 409 of the roof 404, a much greater amount of power is made available for droplet ejection, because the active beam 411 has a large area compared with the overall size of the nozzle assembly 400.
  • Turning to Figure 12, it will be readily appreciated that the nozzle assembly 400 (as well as all other nozzle assemblies described herein) may be replicated into an array of nozzle assemblies to define a printhead or printhead integrated circuit. A printhead integrated circuit comprises a silicon substrate, an array of nozzle assemblies (typically arranged in rows) fouled on the substrate, and drive circuitry for the nozzle assemblies. A plurality of printhead integrated circuits may be abutted or linked to form a pagewidth inkjet printhead, as described in, for example, Applicant's earlier US Application Nos. 10/854,491 filed on May 27, 2004 and 11/014,732 filed on December 20, 2004 .
  • The nozzle assembly 500 shown in Figures 13 to 15 is similar to the nozzle assembly 400 insofar as a thermal bend actuator 510, having an upper active beam 511 and a lower passive beam 512, defines a moving portion of a roof 504 of the nozzle chamber 501. Hence, the nozzle assembly 500 achieves the same advantages, in terms of increased power, as the nozzle assembly 400.
  • However, in contrast with the nozzle assembly 400, the nozzle opening 508 and rim 515 are not defined by the moving portion of the roof 504. Rather, the nozzle opening 508 and rim 515 are defined in a fixed portion of the roof 504 such that the actuator 510 moves independently of the nozzle opening and rim during droplet ejection. An advantage of this arrangement is that it provides more facile control of drop flight direction.
  • It will of course be appreciated that the aluminium alloys, with their inherent advantage of improved thermal bend efficiency, may be used as the active beam in either of the thermal bend actuators 410 and 510 described above in connection with the embodiments shown in Figures 9 to 15.
  • The nozzle assemblies 400 and 500 may be constructed using suitable MEMS technologies in an analogous manner to inkjet nozzle manufacturing processes exemplified in the Applicant's earlier US Patent Nos. 6,416,167 and 6,755,509 .
  • Active Beam Having Optimal Stiffness in a Bend Direction
  • Referring now to Figures 11 and 15, it will be seen that the upper active beams 411 and 511 of the actuators 410 and 510 are each comprised of a tortuous beam element having either a bent (in the case of beam 411) or serpentine (in the case of beam 511) configuration. The tortuous beam element is elongate and has a relatively small cross-sectional area suitable for resistive heating. In addition, the tortuous configuration enables respective ends of the beam element to be connected to respective contacts positioned at one end of the actuator, simplifying the overall design and construction of the nozzle assembly.
  • Referring specifically to Figures 14 and 15, an elongate beam element 520 has a serpentine configuration defining the elongate active cantilever beam 511 of the actuator 510. The serpentine beam element 520 has a planar, tortuous path connecting a first electrical contact 516 with a second electrical contact 516. The electrical contacts 516 (positive and ground) are positioned at one end of the actuator 510 and provide electrical connection between drive circuitry in the CMOS layers 502 and the active beam 511.
  • The serpentine beam element 520 is fabricated by standard lithographic etching techniques and defined by a plurality of contiguous beam members. In general, beam members may be defined as solid portions of beam material, which extend substantially linearly in, for example, a longitudinal or transverse direction. The beam members of beam element 520 are comprised of longer beam members 521, which extend along a longitudinal axis of the elongate cantilever beam 511, and shorter beam members 522, which extend across a transverse axis of the elongate cantilever beam 511. An advantage of this configuration for the serpentine beam element 520 is that it provides maximum stiffness in a bend direction of the cantilever beam 511. Stiffness in the bend direction is advantageous because it facilitates bending of the actuator 510 back to its quiescent position after each actuation.
  • It will be appreciated that the bent active beam configuration for the nozzle assembly 400 shown in Figure 11 achieves the same or similar advantages to those described above in connection with nozzle assembly 500. In Figure 11, the longer beam members, extending longitudinally, are indicated as 421, whilst the interconnecting shorter beam member, extending transversely, is indicated as 422.
  • Use of Porous Material For Improving Thermal Efficiency
  • In all the embodiments described above, as well as all other embodiments of thermal bend actuators described by the present Applicant, the active beam is either bonded to the passive beam for structural robustness (see Figures 1 and 2), or the active beam is spaced apart from the passive beam for maximum thermal efficiency (see Figure 8). The thermal efficiency provided by an air gap between the beams is, of course, desirable. However, this improvement in thermal efficiency is usually at the expense of structural robustness and a propensity for buckling of the thermal bend actuator.
  • US Patent No. 6,163,066 , describes a porous silicon dioxide insulator, having a dielectric constant of about 2.0 or less. The material is formed by deposition of silicon carbide and oxidation of the carbon component to form porous silicon dioxide. By increasing the ratio of carbon to silicon, the porosity of the resultant porous silicon dioxide can be increased. Porous silicon dioxide are known to be useful as a passivation layer in integrated circuits for reducing parasitic resistance.
  • However, the present Applicant has found that porous materials of this type are useful for improving the efficiency of thermal bend actuators. A porous material may be used either as an insulating layer between an active beam and a passive beam, or it may be used as the passive beam itself.
  • Figure 16 shows a thermal bend actuator 600 comprising an upper active beam 601, a lower passive beam 602 and an insulating layer 603 sandwiched between the upper and lower beams. The insulating beam is comprised of porous silicon dioxide, while the active and passive beams 601 and 602 may be comprised of any suitable materials, such as TiN and SiO2, respectively.
  • The porosity of the insulating layer 603 provides excellent thermal insulation between the active and passive beams 601 and 602. The insulating layer 603 also provides the actuator 600 with structural robustness. Hence, the actuator 600 combines the advantages of both types of thermal bend actuator described above in connection with Figures 1, 2 and 8.
  • Alternatively, and as shown in Figure 17, the porous material may simply form the passive layer of a bi-layered thermal bend actuator. Accordingly, the thermal bend actuator 650 comprises an upper active beam 651 comprised of TiN, and a lower passive beam 652 comprised of porous silicon dioxide.
  • It will, of course, be appreciated that thermal bend actuators of the types shown in Figures 16 and 17 may be incorporated into any suitable inkjet nozzle or other MEMS device. The improvements in thermal efficiency and structural rigidity make such actuators attractive in any MEMS application requiring a mechanical actuator or transducer.
  • The thermal bend actuators of the types shown in Figures 16 and 17 are particularly suitable for use in the inkjet nozzle assemblies 400 and 500 described above. The skilled person would readily appreciate that appropriate modifications of the thermal bend actuators 410 and 10 would realize the above-mentioned improvements in thermal efficiency and structural robustness.
  • It will be further appreciated that the active beam members 601 and 651 in the thermal bend actuators 600 and 650 described above may be comprised of an aluminum alloy, as described herein, for further improvements in thermal bend efficiency.
  • It will, of course, be appreciated that the present invention has been described by way of example only and that modifications of detail may be made within the scope of the invention, which is defined in the accompanying claims.

Claims (15)

  1. An inkjet nozzle assembly (400) comprising:
    a nozzle chamber (401) for containing ink, said nozzle chamber comprising a floor (402) and a roof (404), said roof having a nozzle opening (408) defined therein said roof having a moving portion (409) moveable towards the floor; and
    a thermal bend actuator (410), having a plurality of cantilever beams, for ejecting ink through the nozzle opening,
    wherein said thermal bend actuator (410) comprises:
    a first active beam (411) for connection to drive circuitry; and
    a second passive beam (412) mechanically cooperating with the first beam, such that when a current is passed through the first beam, the first beam expands relative to the second beam, resulting in bending of the actuator,
    characterized in that:
    the moving portion (409) of the roof (404) comprises the thermal bend actuator
  2. The inkjet nozzle assembly of claim 1, wherein the first active beam (411) defines at least 30% of a total area of the roof (404).
  3. The inkjet nozzle assembly of claim 1, wherein the first active beam (411) defines at least part of an exterior surface of said roof (404).
  4. The inkjet nozzle assembly of claim 1, wherein the nozzle opening (408) is defined in the moving portion (409), such that the nozzle opening is moveable relative to the floor (402).
  5. The inkjet nozzle assembly of claim 1, wherein the actuator (510) is moveable relative to the nozzle opening (508).
  6. The inkjet nozzle assembly of claim 1, wherein the first beam (511) is defined by a tortuous beam element (520), said tortuous beam element having a plurality of contiguous beam members.
  7. The inkjet nozzle assembly of claim 6, wherein the plurality of contiguous beam members comprises a plurality of longer beam members (521) extending along a longitudinal axis of the first beam, and at least one shorter beam member (522) extending across a transverse axis of the first beam and interconnecting longer beam members.
  8. The inkjet nozzle assembly of claim 1, wherein one of said plurality of beams is comprised of a porous material
  9. The inkjet nozzle assembly of claim 8, wherein said porous material is porous silicon dioxide having a dielectric constant of 2 or less.
  10. The inkjet nozzle assembly of claim 1, wherein the thermal bend actuator (410) further comprises a third insulation beam sandwiched between the first beam (411) and the second beam (412).
  11. The inkjet nozzle assembly of claim 10, wherein the third insulation beam is comprised of a porous material.
  12. The inkjet nozzle assembly of claim 1, wherein the first beam (411) is fused or bonded to the second beam (412).
  13. The inkjet nozzle assembly of claim 1. wherein at least part of the first beam (411) is spaced apart from the second beam (412).
  14. The inkjet nozzle assembly of claim 1, wherein the first beam (=411) is comprised of a material selected from the group comprising: titanium nitride, titanium aluminum nitride and an aluminium alloy.
  15. An inkjet printhead or an inkjet printhead integrated circuit comprising an array of nozzle assemblies according to any one of the preceding claims.
EP06827989A 2006-12-04 2006-12-04 Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof Active EP2089229B1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SI200631460T SI2089229T1 (en) 2006-12-04 2006-12-04 Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof
PL06827989T PL2089229T3 (en) 2006-12-04 2006-12-04 Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof
CY20121101049T CY1113795T1 (en) 2006-12-04 2012-11-01 INK PROJECTION INJECTION INCREASING A THERMAL BENEFIT INTEGRATED WITH AN INTERFACE BASE SPECIFIED BY A SUBSTANTIAL PART OF THIS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/AU2006/001831 WO2008067581A1 (en) 2006-12-04 2006-12-04 Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof

Publications (3)

Publication Number Publication Date
EP2089229A1 EP2089229A1 (en) 2009-08-19
EP2089229A4 EP2089229A4 (en) 2011-03-16
EP2089229B1 true EP2089229B1 (en) 2012-08-15

Family

ID=39491550

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06827989A Active EP2089229B1 (en) 2006-12-04 2006-12-04 Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof

Country Status (11)

Country Link
EP (1) EP2089229B1 (en)
JP (1) JP4933629B2 (en)
KR (1) KR101030152B1 (en)
CY (1) CY1113795T1 (en)
DK (1) DK2089229T3 (en)
ES (1) ES2393305T3 (en)
PL (1) PL2089229T3 (en)
PT (1) PT2089229E (en)
SI (1) SI2089229T1 (en)
TW (1) TWI468301B (en)
WO (1) WO2008067581A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102164748B (en) * 2008-09-29 2013-07-17 扎姆泰科有限公司 Efficient inkjet nozzle assembly
KR101399304B1 (en) 2009-10-08 2014-05-28 엘지디스플레이 주식회사 Liquid crystal display device and method of driving the same
KR102549376B1 (en) 2021-02-26 2023-06-30 한국과학기술원 Printing Ink Dispensing Apparatus with Heatable Cantilever Structured Fluid Channel and Manufacturing Method of the Same

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1473204A (en) 1922-10-09 1923-11-06 Blades Robert Meat hanger and apparatus for applying the same
JP3321488B2 (en) * 1994-03-31 2002-09-03 シャープ株式会社 Ink jet recording device
US6255156B1 (en) 1997-02-07 2001-07-03 Micron Technology, Inc. Method for forming porous silicon dioxide insulators and related structures
US6416167B1 (en) 1997-07-15 2002-07-09 Silverbrook Research Pty Ltd Thermally actuated ink jet printing mechanism having a series of thermal actuator units
US6682174B2 (en) * 1998-03-25 2004-01-27 Silverbrook Research Pty Ltd Ink jet nozzle arrangement configuration
ATE358019T1 (en) * 1997-07-15 2007-04-15 Silverbrook Res Pty Ltd INK JET NOZZLE ASSEMBLY WITH PADDLES AS PART OF THE WALL
US6260953B1 (en) 1997-07-15 2001-07-17 Silverbrook Research Pty Ltd Surface bend actuator vented ink supply ink jet printing mechanism
US6447099B2 (en) * 1997-07-15 2002-09-10 Silverbrook Research Pty Ltd Ink jet mechanism with thermoelastic bend actuator having conductive and resistive beams
US6540332B2 (en) * 1997-07-15 2003-04-01 Silverbrook Research Pty Ltd Motion transmitting structure for a nozzle arrangement of a printhead chip for an inkjet printhead
US6623108B2 (en) * 1998-10-16 2003-09-23 Silverbrook Research Pty Ltd Ink jet printhead having thermal bend actuator heating element electrically isolated from nozzle chamber ink
WO2000048938A1 (en) * 1999-02-15 2000-08-24 Silverbrook Research Pty Ltd Thermal bend actuator and paddle structure for ink jet nozzle
AUPP993199A0 (en) * 1999-04-22 1999-05-20 Silverbrook Research Pty Ltd A micromechanical device and method (ij46p2a)
AUPP993099A0 (en) * 1999-04-22 1999-05-20 Silverbrook Research Pty Ltd A micromechancial device and method(ij46p2b)
AUPQ130999A0 (en) * 1999-06-30 1999-07-22 Silverbrook Research Pty Ltd A method and apparatus (IJ47V11)
US6428133B1 (en) 2000-05-23 2002-08-06 Silverbrook Research Pty Ltd. Ink jet printhead having a moving nozzle with an externally arranged actuator
US6412908B2 (en) * 2000-05-23 2002-07-02 Silverbrook Research Pty Ltd Inkjet collimator
AU2000247327C1 (en) * 2000-05-24 2004-10-07 Memjet Technology Limited Ink jet printhead nozzle array
WO2002002328A1 (en) * 2000-06-30 2002-01-10 Silverbrook Research Pty Ltd Buckle resistant thermal bend actuators
US6623101B1 (en) 2000-10-20 2003-09-23 Silverbrook Research Pty Ltd Moving nozzle ink jet
AUPR224000A0 (en) * 2000-12-21 2001-01-25 Silverbrook Research Pty. Ltd. An apparatus (mj28)
US6631979B2 (en) * 2002-01-17 2003-10-14 Eastman Kodak Company Thermal actuator with optimized heater length
US6536874B1 (en) * 2002-04-12 2003-03-25 Silverbrook Research Pty Ltd Symmetrically actuated ink ejection components for an ink jet printhead chip
US6721020B1 (en) * 2002-11-13 2004-04-13 Eastman Kodak Company Thermal actuator with spatial thermal pattern
US6755509B2 (en) * 2002-11-23 2004-06-29 Silverbrook Research Pty Ltd Thermal ink jet printhead with suspended beam heater
US7025443B2 (en) * 2003-06-27 2006-04-11 Eastman Kodak Company Liquid drop emitter with split thermo-mechanical actuator
KR100580654B1 (en) * 2004-10-29 2006-05-16 삼성전자주식회사 Nozzle plate, inkjet printhead having the same and manufacturing method of nozzle plate

Also Published As

Publication number Publication date
DK2089229T3 (en) 2012-12-17
WO2008067581A1 (en) 2008-06-12
EP2089229A4 (en) 2011-03-16
EP2089229A1 (en) 2009-08-19
TWI468301B (en) 2015-01-11
JP4933629B2 (en) 2012-05-16
ES2393305T3 (en) 2012-12-20
KR101030152B1 (en) 2011-04-18
PT2089229E (en) 2012-11-20
JP2010511527A (en) 2010-04-15
CY1113795T1 (en) 2016-07-27
SI2089229T1 (en) 2012-12-31
TW200824914A (en) 2008-06-16
PL2089229T3 (en) 2013-06-28
KR20090095562A (en) 2009-09-09

Similar Documents

Publication Publication Date Title
US7926915B2 (en) Inkjet nozzle assembly with thermal bend actuator defining moving portion of nozzle chamber roof
US7654641B2 (en) Inkjet nozzle assembly having moving roof portion defined by a thermal bend actuator having a plurality of cantilever beams
US7901051B2 (en) Inkjet nozzle assembly having thermoelastic actuator beam disposed on nozzle chamber roof
US7794055B2 (en) Thermal bend actuator comprising aluminium alloy
US7901052B2 (en) Thermal bend actuator comprising bilayered passive beam
US7971971B2 (en) Inkjet nozzle assembly having bilayered passive beam
US8491098B2 (en) Thermal bend actuator with conduction pad at bend region
US7984973B2 (en) Thermal bend actuator comprising aluminium alloy
EP2089229B1 (en) Inkjet nozzle assembly having thermal bend actuator with an active beam defining substantial part of nozzle chamber roof
US11691421B2 (en) Thermal bend actuator having improved lifetime
TWI436898B (en) Inkjet printer

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20090616

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20110211

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Ref country code: CH

Ref legal event code: EP

Ref country code: AT

Ref legal event code: REF

Ref document number: 570597

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120815

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: ZAMTEC LIMITED

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602006031500

Country of ref document: DE

Effective date: 20121018

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20121107

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: KEMIA SA, CH

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2393305

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20121220

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120815

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121215

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120815

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: MC

Payment date: 20121220

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121116

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120815

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120815

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120815

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: HU

Ref legal event code: AG4A

Ref document number: E015563

Country of ref document: HU

Ref country code: PL

Ref legal event code: T3

26N No opposition filed

Effective date: 20130516

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121115

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602006031500

Country of ref document: DE

Effective date: 20130516

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LV

Payment date: 20131120

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CY

Payment date: 20131121

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131231

REG Reference to a national code

Ref country code: HU

Ref legal event code: HC9C

Owner name: MEMJET TECHNOLOGY LIMITED, IE

Free format text: FORMER OWNER(S): ZAMTEC LIMITED, IE

REG Reference to a national code

Ref country code: ES

Ref legal event code: PC2A

Owner name: MEMJET TECHNOLOGY LIMITED

Effective date: 20141008

REG Reference to a national code

Ref country code: SI

Ref legal event code: SP73

Owner name: MEMJET TECHNOLOGY LIMITED; IE

Effective date: 20140908

REG Reference to a national code

Ref country code: CH

Ref legal event code: PFA

Owner name: MEMJET TECHNOLOGY LIMITED, IE

Free format text: FORMER OWNER: ZAMTEC LIMITED, IE

REG Reference to a national code

Ref country code: DE

Ref legal event code: R081

Ref document number: 602006031500

Country of ref document: DE

Owner name: MEMJET TECHNOLOGY LIMITED, IE

Free format text: FORMER OWNER: SILVERBROOK RESEARCH PTY. LIMITED, BALMAIN, NSW, AU

Effective date: 20141016

REG Reference to a national code

Ref country code: AT

Ref legal event code: HC

Ref document number: 570597

Country of ref document: AT

Kind code of ref document: T

Owner name: MEMJET TECHNOLOGY LIMITED, IE

Effective date: 20141015

REG Reference to a national code

Ref country code: FR

Ref legal event code: CD

Owner name: MEMJET TECHNOLOGY LIMITED, IE

Effective date: 20141118

Ref country code: FR

Ref legal event code: CA

Effective date: 20141118

REG Reference to a national code

Ref country code: NL

Ref legal event code: TD

Effective date: 20150128

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20141229

Year of fee payment: 9

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141204

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141204

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151231

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151204

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20161227

Year of fee payment: 11

Ref country code: HU

Payment date: 20161125

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20161122

Year of fee payment: 11

Ref country code: AT

Payment date: 20161121

Year of fee payment: 11

Ref country code: SI

Payment date: 20161122

Year of fee payment: 11

Ref country code: SE

Payment date: 20161129

Year of fee payment: 11

Ref country code: PL

Payment date: 20161118

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20161122

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 20161227

Year of fee payment: 11

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151204

PGRI Patent reinstated in contracting state [announced from national office to epo]

Ref country code: IT

Effective date: 20170710

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CZ

Payment date: 20171128

Year of fee payment: 12

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

Effective date: 20171231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180604

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 570597

Country of ref document: AT

Kind code of ref document: T

Effective date: 20171204

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171205

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171205

REG Reference to a national code

Ref country code: SI

Ref legal event code: KO00

Effective date: 20180709

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171204

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171205

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171204

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171204

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20190103

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181204

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191231

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20191231

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20211221

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20211226

Year of fee payment: 16

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171204

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20230102

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20221228

Year of fee payment: 17

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230414

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20230101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230101

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20231227

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IE

Payment date: 20231227

Year of fee payment: 18

Ref country code: FR

Payment date: 20231227

Year of fee payment: 18