EP1961931A1 - Exhaust device for a diesel engine - Google Patents
Exhaust device for a diesel engine Download PDFInfo
- Publication number
- EP1961931A1 EP1961931A1 EP07250776A EP07250776A EP1961931A1 EP 1961931 A1 EP1961931 A1 EP 1961931A1 EP 07250776 A EP07250776 A EP 07250776A EP 07250776 A EP07250776 A EP 07250776A EP 1961931 A1 EP1961931 A1 EP 1961931A1
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- EP
- European Patent Office
- Prior art keywords
- gas
- exhaust
- flammable
- catalyst
- fuel
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/025—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
- F01N2240/14—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a fuel burner
Definitions
- the present invention relates to an exhaust device for a diesel engine and more particularly, concerns an exhaust device for a diesel engine adapted for compact construction.
- a supply passage of the flammable gas extends from the gas generator, and has an outlet in communication with with an exhaust-gas route upstream of a diesel-particulate-filter.
- the flammable gas from the flammable-gas outlet is made to burn in the exhaust gas, thereby generating combustion heat with which the fine particles of the exhaust gas remaining at the filter can be burnt.
- An exhaust device of this type has an advantage that even when, for example at a light load, the exhaust gas temperature is comparatively low, the combustion heat of the flammable gas raises the temperature of the exhaust gas flowing into the filter, thereby burning the fine particles of the exhaust gas, facilitating recovery of the filter.
- the general object of the invention is to provide an improved exhaust device of this general character.
- One object of the invention is to facilitate the provision of a compact exhaust device.
- Another, alternative or additional, object of the invention is to promote the efficient production and combustion of the flammable gas.
- an exhaust device for a diesel engine comprises a source 5 which supplies liquid fuel (denoted by the arrow 6) to a gas generator 3.
- the gas generator 3 converts the liquid fuel to flammable gas 7.
- the flammable-gas outlet 9 communicates with an exhaust-gas route 1 upstream of a diesel particulate-filter 2.
- the flammable gas 7 which flows out of the flammable-gas outlet 9 is burnt in the exhaust gas denoted by the arrow 10 to generate combustion heat which can burn the fine particles of the exhaust gas residue at the filter 2.
- a filter-containing case 11 which contains the filter 2 accommodates at least part of the gas generator 3.
- the filter-containing case 11 which contains the filter 2 accommodates at least part of the gas generator 3. Therefore, when compared with the case where the gas generator 3 is separated from the filter-containing case 11, the exhaust device can be made more compact.
- the fuel from a fuel reservoir 5a of the diesel engine is used as the liquid fuel 6.
- this air 44 may be the air from a supercharger 39.
- the fuel reservoir 5a and the diesel engine's supercharger 39 can serve as the fuel supply source and the air supply source of the gas generator 3, respectively, so that the exhaust device may be made at a low cost.
- a catalyst chamber 51 has an upper portion where a heat sink in the form of a thermally conductive plate 52 is disposed. There is formed a fuel-passing gap 53 along an upper surface of the plate 52. The gap 53 has a lateral opening to provide a fuel outlet 54 to the catalyst chamber 51.
- the catalytic combustion heat generated in the catalyst chamber 51 is conducted to the fuel-passage gap 53 through the plate 52.
- the liquid fuel 6 and the air 44 are pre-heated within the fuel-passing gap 53 ahead of the catalyst chamber 51. This promotes the vaporization of the liquid fuel 6 and the feeding of a homogeneous mixture of air and fuel to the catalyst chamber 51, thereby enhancing the efficiency of gas generation in the catalyst chamber 51.
- the thermally conductive plate may be heated at a low cost.
- the catalytic combustion heat generated in the catalyst chamber 51 is conducted through by way of the plate 52 to the fuel-passing gap 53. Consequently, while the catalytic combustion heat is being generated, it is unnecessary to heat the thermally conductive plate 52 by means of a glow plug 45 or the like.
- the liquid fuel 6 which flows out of the fuel outlet 54 impinges on a side 56a of a guide plate 56 and is guided by the guide plate 56 so as to approach an exothermic portion 45a of the glow plug 45.
- the glow plug 45 exothermic at the time of the commencement of gas generation before the catalytic combustion heat is generated in the catalyst chamber 51, without the catalytic combustion heat, the liquid fuel 6 is pre-heated ahead of the catalyst chamber 51. This accelerates the vaporization of the liquid fuel 6, introduces a homogeneous mixture of air and fuel into the catalyst chamber 51 and activates a catalyst 51a with heat from the glow plug 45, whereby to promote the prompt commencement of the gas generation.
- a flame-quenching material 57 occupies a space between the thermally conductive plate 52 and the guide plate 56.
- heat from the 45 is conducted through the flame-quenching material 57 to the heat conduction-plate 52 and the guide plate 56.
- the liquid fuel 6 and the air 44 are pre-heated while they are passing through the fuel-passing gap 53 and the flame-quenching material 57 ahead of the catalyst chamber 51 and the liquid fuel 6 which flows out of the fuel-passing gap 53 is pre-heated while it is guided by the guide plate 56.
- the gas may be highly efficiently generated in the catalyst chamber.
- the flame-quenching material 57 occupies the space between the plate 52 and the guide plate 56. While the catalyst is burning in the catalyst chamber 51, the catalytic combustion heat is conducted through the guide plate 56 and the flame-quenching material 57 to the plate 52.
- the liquid fuel 6 and the air 44 are pre-heated while they are passing through the fuel-passing gap 53 and the flame-quenching material 57 ahead of the catalyst chamber 51. This accelerates the vaporization of the liquid fuel 6 and the introduction of homogeneous mixture of air and fuel to the catalyst chamber 51, to improve the efficiency of gas generation in the catalyst chamber 51.
- the guide plate 56 has an under surface which is in contact with a catalyst 51a within the catalyst chamber 51. While the catalyst 51a is burning in the catalyst chamber 51, the catalytic combustion heat is efficiently conducted to the guide plate 56 as well as to the flame-quenching material 57 and the thermally conductive plate 52. Thus the liquid fuel 6 and the air 44 are efficiently pre-heated while they are passing through the flame-quenching material 57 and the fuel-passing gap 53 ahead of the catalyst chamber 51 to entail a high efficiency of the gas generation in the catalyst chamber 51.
- Gas may be generated within the catalyst chamber with an increased efficiency. Since a catalyst component is supported on the flame-quenching material 57, part of the liquid fuel 6 undergoes catalytic combustion while the liquid fuel 6 is passing through the flame-quenching material 57 before the catalyst chamber 51 to produce heat with which the liquid fuel 6 is pre-heated. This promotes the the vaporization of the liquid fuel 6 and the introduction of a homogeneous mixture of air and fuel into the catalyst chamber 51, whereby to improve the efficiency of gas generation in the catalyst chamber 51.
- the glow plug 45 when the glow plug 45 is made exothermic, the heat of this glow plug 45 is conducted through the thermally conductive plate 52 to the fuel-passing gap 53.
- the liquid fuel 6 and the air 44 are pre-heated while they are passing through the fuel-passing gap 53 ahead of the catalyst chamber 51. This promotes the vaporization of the liquid fuel 6 and the introduction of a homogeneous mixture of air and fuel into the catalyst chamber 51, to promote prompt commencement of gas generation.
- an oxidation catalyst 12 for accelerating the combustion of the flammable gas 7 is disposed between the flammable-gas outlet 9 and an inlet 2a of the filter 2.
- the exhaust gas 10 has a low temperature, it can still cause burning of the flammable gas 7.
- the oxidation catalyst 12 occupies a case 65 for accommodating the oxidation catalyst 12 and the flammable-gas outlet 9 opens into the oxidation catalyst 12.
- the case 65 has a side wall 66 provided with a plurality of exhaust gas inlets 67 and has an end part 68 provided with an exhaust gas outlet 69. Therefore, it is possible to reduce the inlet rate of the exhaust gas per unit area of each of the exhaust gas inlets 67 in accordance with the possible increase of the total opening area of the exhaust gas inlets 67.
- the exhaust gas inlets 67 are disposed in parallel with one another in the side 66 of the 65 from a front end 70 of the case 65 to a rear end 68 thereof.
- the caser 65 tapers outwardly, the side wall 66 of the case 65 which accommodates the oxidation-catalyst progressively increasing in diameter from the front end 70 to the rear end 68 of the case 65. Accordingly, the cross-sectional area of the oxidation catalyst 12 increases towards the end 68 in compliance with the increasing rate of the exhaust gas and thereby the resistance that the exhaust gas 10 encounters when it passes through the oxidation catalyst 12 is reduced.
- the oxidation catalyst 12 is preferably a catalyst which comprises a catalyst component supported on a metal substrate of a cubic mesh-structure.
- the quenching function of the substrate inhibits the flame-combustion within the oxidation catalyst 12, so as to reduce the damage that the oxidation catalyst experiences when it burns.
- the oxidation catalyst 12 and at least part of the gas generator 3 are arranged within the exhaust-gas inlet pipe 21 of the filter-containing case 11; this arrangement allows a more compact realization of the exhaust device.
- the exhaust-gas inlet pipe 21 is inserted into an exhaust gas-inlet chamber 19 along a radial direction of the filter-containing case 11, and the oxidation catalyst 12 and at least part of the gas generator 3 are arranged in the afore-mentioned order within the exhaust-gas inlet pipe 21 from an upstream side.
- This arrangement can allow a decrease in the front-to-rear dimension of the filter-containing case 11.
- the exhaust-gas inlet pipe 21 is inserted into the exhaust gas inlet chamber 19 along the radial direction of the filter-containing case 11, and the oxidation catalyst 12 and at least part of the gas generator 3 are arranged within the exhaust-gas inlet pipe 21.
- the oxidation catalyst 12 is protected doubly by a wall of the filter-containing case 11 and a wall of the exhaust gas inlet pipe 21 as well as the at least part of the gas generator 3, thereby reducing the incidence of damage to the oxidation catalyst 12 and the gas generator 3.
- the exhaust-gas inlet pipe 21 is inserted into the exhaust-gas inlet chamber 19 along the radial direction of the filter-containing case 11 and the oxidation catalyst 12 is disposed within the exhaust gas inlet pipe 21.
- the oxidation catalyst 12 is surrounded doubly by the wall of the exhaust-gas inlet pipe 21 and the wall of the filter-containing case 11 so that the heat of the oxidation catalyst 12 hardly escapes. For this reason, even the exhaust gas at a low temperature is sufficient to reach the activation temperature of the oxidation catalyst 12.
- the exhaust-gas inlet pipe 21 is inserted into the exhaust-gas inlet chamber 19 along the radial direction of the filter-containing case 11, and the oxidation catalyst 12 and at least part of the gas generator 3 are arranged in the mentioned order within the exhaust-gas inlet pipe 21 from the upstream side. Further, a flammable-gas supply passage 8 conducted out of the gas generator 3 is inserted into the oxidation catalyst 12. Therefore, the flammable-gas supply passage 8 is protected by the wall of the filter-containing case 11, the wall of the exhaust-gas inlet pipe 21 and the oxidation catalyst 12.
- the gas generator 3 vaporizes the liquid fuel 6 to covert this liquid fuel 6 into the flammable gas 7.
- a reaction such as partial oxidation
- the gas generator 3 partially oxidizes the liquid fuel 6 to convert the liquid fuel 6 into the flammable gas 7 containing carbon monoxide and hydrogen. Accordingly, the flammable gas 7 ignites at a relatively low temperature and therefore can be burnt even if the exhaust gas 10 has a low temperature.
- an oxidation-passage 14 is formed within the exhaust-gas passage 13 upstream of the oxidation catalyst 12 to make the exhaust-gas passage 13 into a double-cylinder structure.
- the upstream oxidation-passage 14 accommodates an upstream oxidation catalyst 15, on an upstream side of which the flammable-gas outlet 9 of the gas generator 3 opens into the upstream oxidation-passage 14.
- the flammable gas at a high temperature is mixed with part of the exhaust gas 10 flowing into the upstream oxidation-passage 14, among the whole of the exhaust gas, shown by the arrows 10, 10 which passes through the exhaust-gas passage 13, and the mixture enters the upstream oxidation-catalyst 15. Therefore, even if the exhaust gas 10 has a low temperature, the mixture of the flammable gas 7 and the exhaust gas 10 flows into the upstream oxidation-catalyst 15 at a relatively high temperature sufficient to reach the activation temperature of the upstream oxidation-catalyst 15. Thus the the flammable gas 7 is partly burnt by the upstream oxidation-catalyst 15.
- the combustion heat increases the temperature of the whole exhaust gas which flows into the oxidation catalyst 12 disposed downstream and enables the activation temperature of this oxidation catalyst 12 to be attained. Consequently, this oxidation catalyst 12 burns the residual flammable gas 7 to increase further the temperature of the whole exhaust gas.
- This exhaust gas 10 can then burn the fine particles of the exhaust gas at the filter 2.
- Figs. 1 to 3 show an exhaust device for a diesel engine, in accordance with a first embodiment of the present invention.
- Figs. 4 to 6 show an exhaust device for a diesel engine, in accordance with a second embodiment of the present invention.
- Fig. 7 shows an exhaust device for a diesel engine, in accordance with a third embodiment of the present invention.
- liquid fuel 6 is supplied from a source 5 of the liquid fuel 6 to a gas generator 3, which converts the liquid fuel 6 into flammable gas 7.
- a supply passage 8 of the flammable gas 7 is conducted out of the gas generator 3.
- the supply passage 8 has a flammable-gas outlet 9 which communicates with an exhaust-gas route 1 upstream of a diesel-particulate-filter 2.
- the flammable gas 7 which flows out of the flammable-gas outlet 9 is burnt in exhaust gas 10 to generate combustion heat which in turn can burn fine particles of the exhaust gas 10 remaining at the filter 2.
- This exhaust device is connected to an exhaust-gas outlet 36 of an exhaust manifold for a diesel engine.
- the diesel-particulate-filter 2 is generally called as DPE and may have has a ceramic honeycomb structure.
- An oxidation catalyst is supported on the diesel-particulate-filter 2.
- a NOx-occlusion catalyst may be supported on the filter 2.
- a case 11 for containing the filter 2 accommodates part of the gas generator 3.
- the liquid fuel 6 is fuel from a fuel reservoir 5a of the diesel engine.
- the liquid fuel 6 is mixed with air 44 from a supercharger 39.
- a gap 53 through which the fuel passes, has an inlet side communicating with the fuel reservoir 5a of the diesel engine through a liquid-fuel supply passage 46 and with the supercharger 39 through an air-supply passage 38.
- the liquid-fuel supply passage 46 is provided with a liquid-fuel valve 40 and the air-supply passage 38 is provided with an air valve 41.
- Each of the valves 40 and 41 is associated with a back-pressure sensor 43 through a controller 42. If the filter 2 is clogged with fine particles of the exhaust gas, the back pressure increases. Then, based on the detection of this increase by the back-pressure sensor 43, the controller 42 opens the liquid-fuel valve 40 and the air valve 41 so as to supply the liquid fuel 6 and the air 44 to the gas generator 3.
- the liquid fuel 6 is vaporized to convert the liquid fuel 6 into flammable gas 7. This flammable gas 7 is fed into the exhaust-gas route 1.
- a catalyst 51a within a catalyst chamber 51 is an oxidation catalyst, which partially oxidizes the liquid fuel 6 to generate oxidation heat that vaporizes the remaining liquid fuel 6.
- the catalyst 51a may be a catalyst which comprises a catalytic component, such as platinum, supported on a metal substrate of a cubic mesh-structure.
- metal foam may be used for the substrate of the catalyst 51a.
- the metal foam is a metallic porous substance having the same cubic mesh-structure as a foamed resin, an example of which of which is a sponge, and is obtained by any suitable known method.
- the substrate of the catalyst 51a alumina pellets or the like metal pellets may be used.
- the mixing ratio of the liquid fuel 6 to the air 44 namely air-fuel ratio (O/C) is set in range generally centred on 0.6, for example from 0.4 to 0.8.
- the gas generator 3 vaporizes the liquid fuel 6 to convert it into the flammable gas 7
- the gas generator 3 may partly oxidize the liquid fuel 6 to convert it into a flammable gas 7 containing carbon monoxide and hydrogen.
- a partial-oxidation catalyst in the chamber 51 is utilized instead of the previously mentioned oxidation catalyst.
- Such a partial-oxidation catalyst may comprise a catalytic component, such as palladium or rhodium, supported on a metal substrate of a cubic mesh-structure.
- aluminas pellets or the like metal pellets may be employed.
- the mixing ratio of the liquid fuel 6 to the air 44 namely air-fuel ratio (O/C) may be set in a range about 1.3, for example from 1.0 to 1.6.
- the gas generator 3 is provided with a catalyst chamber 51.
- this catalyst chamber 51 has an upper portion at which a thermally conductive plate 52 is disposed.
- a fuel-passing gap 53 Formed along an upper surface of this thermally conductive plate 52 is a fuel-passing gap 53, to which the liquid fuel 6 and the air 44 are supplied.
- This fuel-passing gap 53 has a side opening to provide a fuel outlet 54 to the catalyst chamber 51 so as to conduct the catalytic combustion heat generated within the catalyst chamber 51 through the thermally conductive plate 52 to the fuel-passing gap 53.
- the glow plug 45 has an exothermic portion 45a projected downwards from a mid portion of the thermally conductive plate 52.
- the metal guide plate 56 is arranged below the thermally conductive plate 52 and is downwardly inclined from a peripheral portion 56a below the fuel outlet 54 to underneath the exothermic portion 45a of the glow plug 45, so that the liquid fuel 6 which flows from of the fuel outlet 54 impinges on the portion 56a of the guide plate 56 and approaches the exothermic portion 45a of the glow plug 45 through the guidance of the guide plate 56.
- a metal flame-quenching material 57 of a cubic mesh-structure occupies a space between the thermally conductive plate 52 and the guide plate 56.
- the glow plug 45 When the glow plug 45 generates heat, the heat generated by the glow plug 45 is conducted through the flame-quenching material 57 to the thermally conductive plate 52 and the guide plate 56. During the combustion of the catalyst 51a within the catalyst chamber 51, the catalytic combustion heat is conducted through the guide plate 56 and the flame-quenching material 57 to the thermally conductive plate 52.
- the glow plug 45 is associated with the controller 42 so as to generate heat for a predetermined period of time at the initial term of the gas generation.
- Metal foam is used for the flame-quenching material 57, but material made of stainless steel, and formed as 'wire-mesh', may be used.
- the guide plate 56 has an under-surface with which the catalyst 51a within the catalyst chamber 51 is brought into contact.
- a catalyst component is supported on the flame-quenching material 57.
- the glow plug 45 When the glow plug 45 generates heat, the heat generated by the glow plug 45 is conducted through the thermally conductive plate 52 to the fuel-passing gap 53.
- An oxidation-catalyst component is supported on the flame-quenching material 57.
- each of the guide plate 56 and the partition 58 is opened to provide a central aperture hole 56b and a central aperture 58b, respectively.
- Peripheral apertures 56c are regularly spaced around the central aperture 56b and a plurality apertures 58c are regularly spaced around the central aperture 58b.
- the apertures 56c and 58c of the guide plate 56 and the partition 58 are mutually staggered, when seen from above, so that the liquid fuel 6 flowed out of the fuel outlet 54 is prevented from flowing straight through both the apertures 56c and the apertures 58c in the mentioned order.
- Both the guide plate 56 and the partition 58 may be made of stainless steel.
- an oxidation catalyst 12 for accelerating the combustion of the flammable gas 7 is located between a flammable-gas outlet 9 and an inlet 2a of the filter 2.
- the oxidation catalyst 12 is composed as follows. As shown in Fig. 3 , in order that the flammable gas 7 heated by the exothermic reaction within the gas generator 3 can flow out of the flammable-gas outlet 9 to the oxidation catalyst 12, the oxidation catalyst 12 occupies the case 65 and the flammable-gas outlet 9 opens into the oxidation catalyst 12.
- the case 65 has a peripheral wall 66 provided with a plurality of exhaust-gas inlets 67 and has a rear 68 formed with an exhaust-gas outlet 69.
- Exhaust-gas inlets 67 are disposed in the peripheral wall 66 of the oxidation-catalyst accommodating case 65.
- the exhaust-gas inlets 67 are located side by side in the peripheral wall 66 from the front end 70 of the case 65 to the rear end 68 thereof.
- the peripheral wall 66 of the 65 has a diameter which progressively increases from the front 70 to the rear end 68.
- the case 65 resembles a cup in the form of a truncated cone.
- the case 11 is a cylindrical, with end walls 17 and 18. An axial direction of this case 11 is taken as a front-to-rear direction.
- a inlet side 2a of the filter 2 is regarded as the 'front' and an an outlet side 2b is regarded as the 'rear'.
- Within the case 11 is disposed an exhaust-gas inlet chamber 19 in front of the filter 2 and an exhaust-gas outlet chamber 20 is arranged at the rear of the filter 2.
- the exhaust-gas inlet chamber 19 communicates with an exhaust-gas inlet pipe 21 and the exhaust-gas outlet chamber 20 communicates with an exhaust gas outlet pipe 22.
- the exhaust-gas inlet pipe 21 is inserted into the exhaust-gas inlet chamber 19 along a radial direction of the filter-containing case 11.
- the oxidation catalyst 12 and part of the gas generator 3 are disposed from the upstream side of the exhaust gas into the exhaust-gas inlet pipe 21 in the mentioned order.
- the flammable-gas supply passage 8 from the gas generator 3 extends into the oxidation
- An exhaust muffler 28 is utilized as the filter-containing case 11.
- the exhaust-gas inlet chamber 19 is composed of a first expansion chamber 29 and the exhaust-gas outlet chamber 20 is constructed by a final expansion chamber 30.
- the exhaust-gas inlet pipe 21 is formed from an exhaust-gas lead-in pipe 31 of the first expansion chamber 29 and the exhaust-gas outlet pipe 22 is composed of an exhaust-gas lead-out pipe 32 of the final expansion chamber 30.
- the exhaust gas 10 which passes through the exhaust-gas route 1 flows into the oxidation catalyst 12 and is mixed with the high-temperature flammable gas 7 and the mixture passes through the oxidation catalyst 12.
- the flammable gas 7 is oxidized (burnt) by the oxygen contained in the mixed exhaust gas 10 to produce oxidation heat (combustion heat) which heats the mixed exhaust gas 10.
- the exhaust gas 10 flows out of the oxidation catalyst 12 as shown by arrows 60 and further flows out of the outlet holes 47 of the exhaust-gas lead-in pipe 31 into the first expansion chamber 29. Then, as shown by arrows 62, it enters the filter 2 from the inlets 2a and passes through the filter. The exhaust gas 10 that has passed through the filter 2 flows from the outlets 2b of the filter 2 into the final expansion chamber 30 as shown by arrows 63. Thereafter, the gas flows from the inlet holes 48 of the exhaust-gas lead-in pipe 32 into the exhaust-gas lead-in pipe 32 and flows out of the exhaust-gas lead-out pipe 32 as shown by an arrow 64.
- the second embodiment as shown in Figs. 4 to 6 is different from the first embodiment as follows.
- the oxidation catalyst 12 is arranged outside the exhaust-gas inlet pipe 31, although it exists within the filter-containing case 11.
- an upstream oxidation-passage 14 is formed within the exhaust-gas passage 13 upstream of the oxidation catalyst 12 and is formed into a double-cylinder structure.
- the upstream oxidation-passage 14 accommodates an upstream oxidation-catalyst 15, on an upstream side of which the flammable-gas outlet 9 is opened toward the upstream oxidation-passage 14.
- the exhaust-gas passage 13 is the exhaust -gas inlet pipe 21.
- the upstream oxidation-passage has a sectional area set as follows. As shown in Fig. 4(B) , the upstream oxidation-passage 14 of the exhaust-gas passage 13 of the double-cylinder structure has a sectional area set to a fraction (such as 1/4) of the sectional area of the whole exhaust-gas passage 13 including the upstream oxidation-passage 14. In order to ensure the oxidation-acceleration function of the upstream oxidation-catalyst 15, it is desirable to set the sectional area of the upstream oxidation- passage 14 of the exhaust-gas passage 13 of double-cylinder structure within a range of 1/4 to 1/2 of the total sectional area of the exhaust-gas passage 13 including the upstream oxidation passage 14.
- the flammable-gas outlet and the upstream oxidation-passage are opened in the following direction.
- the flammable-gas lead-out pipe 8 oriented in the direction where the upstream oxidation-passage 14 is formed, has its terminal end 8a closed and has a peripheral wall near the terminal end 8a opened to provide the plurality of flammable-gas outlets 9 oriented radially of the upstream oxidation-passage 14.
- the upstream oxidation-passage 14 has its terminal end 14a closed and has a peripheral wall near the terminal end 14a, opened to form a plurality of upstream oxidation-passage outlets 16 oriented radially of a passage 4 in front of the oxidation-catalyst inlet.
- the high-temperature flammable gas 7 is fed from the flammable-gas supply passage 8 to the upstream oxidation-passage 14 within the exhaust-gas passage 13.
- part 10 of the exhaust gas shown by the arrows 10
- the flammable gas 7 is oxidized (burnt) by the oxygen contained in the mixed exhaust gas 10 to produce oxidation heat (combustion heat) which heats the mixed exhaust gas 10.
- the heated exhaust gas 10 flows out of the upstream oxidation-passage outlet 16; as shown by the arrows 35, and is mixed with the remaining exhaust gas 10 and 10 which did not flow into the upstream oxidation-passage 14.
- the mixture flows out of the outlet holes 47 and passes through the oxidation catalyst 12.
- the flammable gas 7 oxidized (burnt) by the upstream oxidation-catalyst 15 and remaining is oxidized (burnt) by the oxygen in the mixed exhaust gas 10 to produce oxidation (combustion) heat with which the mixed exhaust gas 10 is heated.
- the upstream oxidation catalyst 15 comprises a catalytic component supported on a substrate 25 formed by overlaying and winding a corrugated metal sheet 23 and a flat metal sheet 24.
- Each of the metal sheets 23 and 24 may be a stainless steel sheet having a thickness of 0.5 mm. Platinum may be used as the catalyst component.
- a relatively wide inter-catalyst passage 34 is formed and therefore even the upstream oxidation-passage 14 of a smaller diameter assures a sufficient sectional area of the inter-catalyst passage within the upstream oxidation-catalyst 15.
- the upstream oxidation-catalyst 15 may comprises a catalytic component supported on a substrate 27 formed from a metal mesh 26.
- This metal mesh 26 may be made of stainless steel and is generally called as "wire-mesh". Platinum may be used as the catalytic component.
- the oxidation catalyst 12 may comprise a catalytic component supported on a substrate 25 formed by overlaying and winding a corrugated metal sheet 23 and a flat metal sheet 24.
- Each of the metal sheets 23 and 24 may be a stainless steel sheet having a thickness of 0.5 mm. Platinum may be used as the catalyst component.
- the catalyst may comprise a catalytic component supported on a substrate 27 formed from a metal mesh 26. This metal mesh 26 may be made of stainless steel and is generally called as "wire-mesh". Platinum may be used as the catalyst component.
- the second embodiment is the same as the first embodiment except for the variants described above.
- the third embodiment shown in Fig. 7 is distinct from the first embodiment on the following point.
- Alumina pellets may be used for the substrate of the catalyst 51a within the catalyst chamber 51.
- the oxidation catalyst 12 is accommodated between the upstream oxidation catalyst 15 and the catalyst chamber 51 of the gas generator 3 within the exhaust-gas inlet pipe 21 of the filter-containing case 11.
- the flammable-gas lead-out passage 8 extends through the oxidation catalyst 12.
- the third embodiment is the same as the second embodiment except for the other constructions and functions.
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Abstract
Description
- The present invention relates to an exhaust device for a diesel engine and more particularly, concerns an exhaust device for a diesel engine adapted for compact construction.
- In a known exhaust device for the diesel engine, that supplies liquid fuel from a source of liquid fuel to a gas generator, which converts the liquid fuel to flammable gas, a supply passage of the flammable gas extends from the gas generator, and has an outlet in communication with with an exhaust-gas route upstream of a diesel-particulate-filter. The flammable gas from the flammable-gas outlet is made to burn in the exhaust gas, thereby generating combustion heat with which the fine particles of the exhaust gas remaining at the filter can be burnt.
An exhaust device of this type has an advantage that even when, for example at a light load, the exhaust gas temperature is comparatively low, the combustion heat of the flammable gas raises the temperature of the exhaust gas flowing into the filter, thereby burning the fine particles of the exhaust gas, facilitating recovery of the filter. - The general object of the invention is to provide an improved exhaust device of this general character.
One object of the invention is to facilitate the provision of a compact exhaust device. Another, alternative or additional, object of the invention is to promote the efficient production and combustion of the flammable gas. - The invention is defined in the claims.
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Fig. 1 is a vertical sectional side view of an exhaust device for a diesel engine, in accordance with a first embodiment of the present invention; -
Fig. 2 shows essential portions of the exhaust device shown inFig. 1 .Fig. 2(A) is a vertical sectional side view of a gas generator.Fig. 2(B) is a plan view of a guide plate andFig. 2(C) is a top view of a partition; -
Fig. 3 is a vertical sectional side view of an oxidation catalyst to be used for the exhaust device shown inFig. 1 and its parts positioned in the vicinity thereof; -
Fig. 4 shows an exhaust device for a diesel engine, in accordance with a second embodiment of the present invention.Fig. 4(A) is a vertical sectional side view of a front portion andFig. 4(B) is a sectional view taken along a line B-B inFig. 4(A) ; -
Fig. 5 shows an upstream oxidation-catalyst to be used for the exhaust device inFig. 4 .Fig. 5 (A) is a sectional view taken along a line V-V inFig. 4 (A) andFig. 5(B) corresponds toFig. 5(A) of a modification; -
Fig. 6 is an oxidation catalyst to be used for the exhaust device inFig. 4 .Fig. 6(A) is a sectional view taken along a line VI-VI ofFig. 4 (A) andFig. 6(B) corresponds toFig. 6(A) of the modification; and -
Fig. 7 is a vertical sectional view of an exhaust device for a diesel engine, in accordance with a third embodiment of the present invention. - As exemplified in
Fig. 1 , an exhaust device for a diesel engine comprises asource 5 which supplies liquid fuel (denoted by the arrow 6) to agas generator 3. Thegas generator 3 converts the liquid fuel toflammable gas 7. There is a flammable-gas supply passage 8 extending out of thegas generator 3 and having anoutlet 9 for the flammable gas denoted by thearrow 7. The flammable-gas outlet 9 communicates with an exhaust-gas route 1 upstream of a diesel particulate-filter 2. Theflammable gas 7 which flows out of the flammable-gas outlet 9 is burnt in the exhaust gas denoted by thearrow 10 to generate combustion heat which can burn the fine particles of the exhaust gas residue at thefilter 2. In this exhaust device for the diesel engine, a filter-containingcase 11 which contains thefilter 2 accommodates at least part of thegas generator 3. - It is feasible to make the exhaust device compact. As exemplified in
Fig. 1 , the filter-containingcase 11 which contains thefilter 2 accommodates at least part of thegas generator 3. Therefore, when compared with the case where thegas generator 3 is separated from the filter-containingcase 11, the exhaust device can be made more compact. - It is also feasible to manufacture the exhaust device at a low cost. As illustrated in
Fig. 1 , the fuel from afuel reservoir 5a of the diesel engine is used as theliquid fuel 6. When thisliquid fuel 6 is mixed with air (denoted by the arrow 44), thisair 44 may be the air from asupercharger 39. Accordingly, thefuel reservoir 5a and the diesel engine's supercharger 39 can serve as the fuel supply source and the air supply source of thegas generator 3, respectively, so that the exhaust device may be made at a low cost. - Gas may be very efficiently generated in a catalyst chamber. As exemplified in
Fig. 2(A) , acatalyst chamber 51 has an upper portion where a heat sink in the form of a thermallyconductive plate 52 is disposed. There is formed a fuel-passing gap 53 along an upper surface of theplate 52. Thegap 53 has a lateral opening to provide afuel outlet 54 to thecatalyst chamber 51. The catalytic combustion heat generated in thecatalyst chamber 51 is conducted to the fuel-passage gap 53 through theplate 52. Thus theliquid fuel 6 and theair 44 are pre-heated within the fuel-passing gap 53 ahead of thecatalyst chamber 51. This promotes the vaporization of theliquid fuel 6 and the feeding of a homogeneous mixture of air and fuel to thecatalyst chamber 51, thereby enhancing the efficiency of gas generation in thecatalyst chamber 51. - The thermally conductive plate may be heated at a low cost. As exemplified in
Fig. 2(A) , the catalytic combustion heat generated in thecatalyst chamber 51 is conducted through by way of theplate 52 to the fuel-passing gap 53. Consequently, while the catalytic combustion heat is being generated, it is unnecessary to heat the thermallyconductive plate 52 by means of aglow plug 45 or the like. - It is possible to effect the commencement of gas generation promptly in several ways. As illustrated in
Fig. 2(A) , theliquid fuel 6 which flows out of thefuel outlet 54 impinges on aside 56a of aguide plate 56 and is guided by theguide plate 56 so as to approach anexothermic portion 45a of theglow plug 45. By making theglow plug 45 exothermic at the time of the commencement of gas generation before the catalytic combustion heat is generated in thecatalyst chamber 51, without the catalytic combustion heat, theliquid fuel 6 is pre-heated ahead of thecatalyst chamber 51. This accelerates the vaporization of theliquid fuel 6, introduces a homogeneous mixture of air and fuel into thecatalyst chamber 51 and activates acatalyst 51a with heat from theglow plug 45, whereby to promote the prompt commencement of the gas generation. - Furthermore, as exemplified in
Fig. 2(A) , a flame-quenchingmaterial 57 occupies a space between the thermallyconductive plate 52 and theguide plate 56. When theglow plug 45 is made exothermic, heat from the 45 is conducted through the flame-quenchingmaterial 57 to the heat conduction-plate 52 and theguide plate 56. Thus by making theglow plug 45 exothermic at the time of commencement of gas generation before the catalytic combustion heat is generated in thecatalyst chamber 51, without the catalytic combustion heat, theliquid fuel 6 and theair 44 are pre-heated while they are passing through the fuel-passing gap 53 and the flame-quenchingmaterial 57 ahead of thecatalyst chamber 51 and theliquid fuel 6 which flows out of the fuel-passing gap 53 is pre-heated while it is guided by theguide plate 56. This promotes the acceleration of the vaporization of theliquid fuel 6 and the introduction of homogeneous mixture of air and fuel to thecatalyst chamber 51. - The gas may be highly efficiently generated in the catalyst chamber. As previously explained with reference to
Fig. 2(A) , the flame-quenchingmaterial 57 occupies the space between theplate 52 and theguide plate 56. While the catalyst is burning in thecatalyst chamber 51, the catalytic combustion heat is conducted through theguide plate 56 and the flame-quenchingmaterial 57 to theplate 52. Theliquid fuel 6 and theair 44 are pre-heated while they are passing through the fuel-passing gap 53 and the flame-quenchingmaterial 57 ahead of thecatalyst chamber 51. This accelerates the vaporization of theliquid fuel 6 and the introduction of homogeneous mixture of air and fuel to thecatalyst chamber 51, to improve the efficiency of gas generation in thecatalyst chamber 51. - It is possible to inhibit damage to the gas generator by flame-combustion. Owing to the quenching function of the flame-
quenching material 57, it inhibits the occurrence of the flame-combustion between the thermallyconductive plate 52 and theguide plate 56 and can prevent damage to the gas generator caused by the flame-combustion. - As exemplified in
Fig. 2(A) , theguide plate 56 has an under surface which is in contact with acatalyst 51a within thecatalyst chamber 51. While thecatalyst 51a is burning in thecatalyst chamber 51, the catalytic combustion heat is efficiently conducted to theguide plate 56 as well as to the flame-quenchingmaterial 57 and the thermallyconductive plate 52. Thus theliquid fuel 6 and theair 44 are efficiently pre-heated while they are passing through the flame-quenchingmaterial 57 and the fuel-passing gap 53 ahead of thecatalyst chamber 51 to entail a high efficiency of the gas generation in thecatalyst chamber 51. - Gas may be generated within the catalyst chamber with an increased efficiency. Since a catalyst component is supported on the flame-quenching
material 57, part of theliquid fuel 6 undergoes catalytic combustion while theliquid fuel 6 is passing through the flame-quenchingmaterial 57 before thecatalyst chamber 51 to produce heat with which theliquid fuel 6 is pre-heated. This promotes the the vaporization of theliquid fuel 6 and the introduction of a homogeneous mixture of air and fuel into thecatalyst chamber 51, whereby to improve the efficiency of gas generation in thecatalyst chamber 51. - As exemplified in
Fig. 2(A) , when theglow plug 45 is made exothermic, the heat of thisglow plug 45 is conducted through the thermallyconductive plate 52 to the fuel-passinggap 53. By making theglow plug 45 exothermic at the time of commencement of gas generation before the catalytic combustion occurs in thecatalyst chamber 51, without the catalytic combustion heat, theliquid fuel 6 and theair 44 are pre-heated while they are passing through the fuel-passinggap 53 ahead of thecatalyst chamber 51. This promotes the vaporization of theliquid fuel 6 and the introduction of a homogeneous mixture of air and fuel into thecatalyst chamber 51, to promote prompt commencement of gas generation. - As exemplified in
Fig. 1 , anoxidation catalyst 12 for accelerating the combustion of theflammable gas 7 is disposed between the flammable-gas outlet 9 and aninlet 2a of thefilter 2. Thus even if theexhaust gas 10 has a low temperature, it can still cause burning of theflammable gas 7. - As exemplified in
Fig. 3 , in order that theflammable gas 7 heated by the exothermic reaction within thegas generator 3 may flow from the flammable-gas outlet 9 to theoxidation catalyst 12, theoxidation catalyst 12 occupies acase 65 for accommodating theoxidation catalyst 12 and the flammable-gas outlet 9 opens into theoxidation catalyst 12. Thecase 65 has aside wall 66 provided with a plurality ofexhaust gas inlets 67 and has anend part 68 provided with anexhaust gas outlet 69. Therefore, it is possible to reduce the inlet rate of the exhaust gas per unit area of each of theexhaust gas inlets 67 in accordance with the possible increase of the total opening area of theexhaust gas inlets 67. Owing to this arrangement, even when the exhaust gas has a low temperature, the mixture of theflammable gas 7 and theexhaust gas 10 passes through theoxidation catalyst 12 while it is retains sufficient heat to attain the activation temperature of theoxidation catalyst 12, so that theflammable gas 7 burns and the consequent increase in the temperature of theexhaust gas 10 causes the burning of the fine particles of the exhaust gas at thefilter 12. - It is possible to alleviate the resistance the exhaust gas undergoes when it passes through the oxidation catalyst. As shown in
Fig. 3 , theexhaust gas inlets 67 are disposed in parallel with one another in theside 66 of the 65 from afront end 70 of thecase 65 to arear end 68 thereof. Also, thecaser 65 tapers outwardly, theside wall 66 of thecase 65 which accommodates the oxidation-catalyst progressively increasing in diameter from thefront end 70 to therear end 68 of thecase 65. Accordingly, the cross-sectional area of theoxidation catalyst 12 increases towards theend 68 in compliance with the increasing rate of the exhaust gas and thereby the resistance that theexhaust gas 10 encounters when it passes through theoxidation catalyst 12 is reduced. - The
oxidation catalyst 12 is preferably a catalyst which comprises a catalyst component supported on a metal substrate of a cubic mesh-structure. The quenching function of the substrate inhibits the flame-combustion within theoxidation catalyst 12, so as to reduce the damage that the oxidation catalyst experiences when it burns. - As exemplified in
Fig. 1 , theoxidation catalyst 12 and at least part of thegas generator 3 are arranged within the exhaust-gas inlet pipe 21 of the filter-containingcase 11; this arrangement allows a more compact realization of the exhaust device. - As exemplified in
Fig. 1 , when an axial direction of the filter-containingcase 11 is taken as a front to rear direction, the exhaust-gas inlet pipe 21 is inserted into an exhaust gas-inlet chamber 19 along a radial direction of the filter-containingcase 11, and theoxidation catalyst 12 and at least part of thegas generator 3 are arranged in the afore-mentioned order within the exhaust-gas inlet pipe 21 from an upstream side. This arrangement can allow a decrease in the front-to-rear dimension of the filter-containingcase 11. - As exemplified in
Fig. 1 , the exhaust-gas inlet pipe 21 is inserted into the exhaustgas inlet chamber 19 along the radial direction of the filter-containingcase 11, and theoxidation catalyst 12 and at least part of thegas generator 3 are arranged within the exhaust-gas inlet pipe 21. Theoxidation catalyst 12 is protected doubly by a wall of the filter-containingcase 11 and a wall of the exhaustgas inlet pipe 21 as well as the at least part of thegas generator 3, thereby reducing the incidence of damage to theoxidation catalyst 12 and thegas generator 3. - As exemplified in
Fig. 1 , the exhaust-gas inlet pipe 21 is inserted into the exhaust-gas inlet chamber 19 along the radial direction of the filter-containingcase 11 and theoxidation catalyst 12 is disposed within the exhaustgas inlet pipe 21. Thus theoxidation catalyst 12 is surrounded doubly by the wall of the exhaust-gas inlet pipe 21 and the wall of the filter-containingcase 11 so that the heat of theoxidation catalyst 12 hardly escapes. For this reason, even the exhaust gas at a low temperature is sufficient to reach the activation temperature of theoxidation catalyst 12. - As exemplified in
Fig. 1(A) , the exhaust-gas inlet pipe 21 is inserted into the exhaust-gas inlet chamber 19 along the radial direction of the filter-containingcase 11, and theoxidation catalyst 12 and at least part of thegas generator 3 are arranged in the mentioned order within the exhaust-gas inlet pipe 21 from the upstream side. Further, a flammable-gas supply passage 8 conducted out of thegas generator 3 is inserted into theoxidation catalyst 12. Therefore, the flammable-gas supply passage 8 is protected by the wall of the filter-containingcase 11, the wall of the exhaust-gas inlet pipe 21 and theoxidation catalyst 12. - As illustrated in
Fig. 1 , since anexhaust muffler 28 is employed as the filter-containingcase 11, there is no need to provide the filter-containingcase 11 and theexhaust muffler 28 separately and thereby the exhaust device can be made more compact. - The
gas generator 3 vaporizes theliquid fuel 6 to covert thisliquid fuel 6 into theflammable gas 7. Thus, as compared with a reaction such as partial oxidation, there is less fluctuation of the component ratio of theflammable gas 7 and thereby the combustion heat of theflammable gas 7 can be stabilised. - The
gas generator 3 partially oxidizes theliquid fuel 6 to convert theliquid fuel 6 into theflammable gas 7 containing carbon monoxide and hydrogen. Accordingly, theflammable gas 7 ignites at a relatively low temperature and therefore can be burnt even if theexhaust gas 10 has a low temperature. - As illustrated in
Figs. 4 and7 , in order that theflammable gas 7, heated by the exothermic reaction within thegas generator 3, can flow from the flammable-gas outlet 9 to the upstream of theoxidation catalyst 12, an oxidation-passage 14 is formed within the exhaust-gas passage 13 upstream of theoxidation catalyst 12 to make the exhaust-gas passage 13 into a double-cylinder structure. The upstream oxidation-passage 14 accommodates anupstream oxidation catalyst 15, on an upstream side of which the flammable-gas outlet 9 of thegas generator 3 opens into the upstream oxidation-passage 14. Owing to this arrangement, the flammable gas at a high temperature is mixed with part of theexhaust gas 10 flowing into the upstream oxidation-passage 14, among the whole of the exhaust gas, shown by the 10, 10 which passes through the exhaust-arrows gas passage 13, and the mixture enters the upstream oxidation-catalyst 15. Therefore, even if theexhaust gas 10 has a low temperature, the mixture of theflammable gas 7 and theexhaust gas 10 flows into the upstream oxidation-catalyst 15 at a relatively high temperature sufficient to reach the activation temperature of the upstream oxidation-catalyst 15. Thus the theflammable gas 7 is partly burnt by the upstream oxidation-catalyst 15. The combustion heat increases the temperature of the whole exhaust gas which flows into theoxidation catalyst 12 disposed downstream and enables the activation temperature of thisoxidation catalyst 12 to be attained. Consequently, thisoxidation catalyst 12 burns the residualflammable gas 7 to increase further the temperature of the whole exhaust gas. Thisexhaust gas 10 can then burn the fine particles of the exhaust gas at thefilter 2. -
Figs. 1 to 3 show an exhaust device for a diesel engine, in accordance with a first embodiment of the present invention.Figs. 4 to 6 show an exhaust device for a diesel engine, in accordance with a second embodiment of the present invention.Fig. 7 shows an exhaust device for a diesel engine, in accordance with a third embodiment of the present invention. - As shown in
Fig. 1 ,liquid fuel 6 is supplied from asource 5 of theliquid fuel 6 to agas generator 3, which converts theliquid fuel 6 intoflammable gas 7. Asupply passage 8 of theflammable gas 7 is conducted out of thegas generator 3. Thesupply passage 8 has a flammable-gas outlet 9 which communicates with an exhaust-gas route 1 upstream of a diesel-particulate-filter 2. Theflammable gas 7 which flows out of the flammable-gas outlet 9 is burnt inexhaust gas 10 to generate combustion heat which in turn can burn fine particles of theexhaust gas 10 remaining at thefilter 2. This exhaust device is connected to an exhaust-gas outlet 36 of an exhaust manifold for a diesel engine. The diesel-particulate-filter 2 is generally called as DPE and may have has a ceramic honeycomb structure. An oxidation catalyst is supported on the diesel-particulate-filter 2. Alternatively, a NOx-occlusion catalyst may be supported on thefilter 2. Acase 11 for containing thefilter 2 accommodates part of thegas generator 3. - As shown in
Fig. 1 , theliquid fuel 6 is fuel from afuel reservoir 5a of the diesel engine. Theliquid fuel 6 is mixed withair 44 from asupercharger 39. For this purpose, agap 53, through which the fuel passes, has an inlet side communicating with thefuel reservoir 5a of the diesel engine through a liquid-fuel supply passage 46 and with thesupercharger 39 through an air-supply passage 38. - As illustrated in
Fig. 1 , the liquid-fuel supply passage 46 is provided with a liquid-fuel valve 40 and the air-supply passage 38 is provided with anair valve 41. Each of the 40 and 41 is associated with a back-valves pressure sensor 43 through acontroller 42. If thefilter 2 is clogged with fine particles of the exhaust gas, the back pressure increases. Then, based on the detection of this increase by the back-pressure sensor 43, thecontroller 42 opens the liquid-fuel valve 40 and theair valve 41 so as to supply theliquid fuel 6 and theair 44 to thegas generator 3. In thegas generator 3, theliquid fuel 6 is vaporized to convert theliquid fuel 6 intoflammable gas 7. Thisflammable gas 7 is fed into the exhaust-gas route 1. Acatalyst 51a within acatalyst chamber 51 is an oxidation catalyst, which partially oxidizes theliquid fuel 6 to generate oxidation heat that vaporizes the remainingliquid fuel 6. Thecatalyst 51a may be a catalyst which comprises a catalytic component, such as platinum, supported on a metal substrate of a cubic mesh-structure. In particular metal foam may be used for the substrate of thecatalyst 51a. The metal foam is a metallic porous substance having the same cubic mesh-structure as a foamed resin, an example of which of which is a sponge, and is obtained by any suitable known method. For example, it may be obtained by using polyurethane foam of cubic mesh-framework as a base material; subjecting this base material to an electric-conduction treatment; then electroplating it; decomposing it by heat for removal; and leaving the metal cubic mesh-framework. As for the substrate of thecatalyst 51a, alumina pellets or the like metal pellets may be used. The mixing ratio of theliquid fuel 6 to theair 44, namely air-fuel ratio (O/C) is set in range generally centred on 0.6, for example from 0.4 to 0.8. - Although, in this embodiment, the
gas generator 3 vaporizes theliquid fuel 6 to convert it into theflammable gas 7, thegas generator 3 may partly oxidize theliquid fuel 6 to convert it into aflammable gas 7 containing carbon monoxide and hydrogen. In this case, a partial-oxidation catalyst in thechamber 51 is utilized instead of the previously mentioned oxidation catalyst. Such a partial-oxidation catalyst may comprise a catalytic component, such as palladium or rhodium, supported on a metal substrate of a cubic mesh-structure. Alternatively, aluminas pellets or the like metal pellets may be employed. The mixing ratio of theliquid fuel 6 to theair 44, namely air-fuel ratio (O/C) may be set in a range about 1.3, for example from 1.0 to 1.6. - As shown in
Fig. 2(A) , thegas generator 3 is provided with acatalyst chamber 51. In order to accommodate acatalyst 51a within thecatalyst chamber 51, thiscatalyst chamber 51 has an upper portion at which a thermallyconductive plate 52 is disposed. Formed along an upper surface of this thermallyconductive plate 52 is a fuel-passinggap 53, to which theliquid fuel 6 and theair 44 are supplied. This fuel-passinggap 53 has a side opening to provide afuel outlet 54 to thecatalyst chamber 51 so as to conduct the catalytic combustion heat generated within thecatalyst chamber 51 through the thermallyconductive plate 52 to the fuel-passinggap 53. - As shown in
Fig. 2(A) , theglow plug 45 has anexothermic portion 45a projected downwards from a mid portion of the thermallyconductive plate 52. Themetal guide plate 56 is arranged below the thermallyconductive plate 52 and is downwardly inclined from aperipheral portion 56a below thefuel outlet 54 to underneath theexothermic portion 45a of theglow plug 45, so that theliquid fuel 6 which flows from of thefuel outlet 54 impinges on theportion 56a of theguide plate 56 and approaches theexothermic portion 45a of theglow plug 45 through the guidance of theguide plate 56. A metal flame-quenchingmaterial 57 of a cubic mesh-structure occupies a space between the thermallyconductive plate 52 and theguide plate 56. When theglow plug 45 generates heat, the heat generated by theglow plug 45 is conducted through the flame-quenchingmaterial 57 to the thermallyconductive plate 52 and theguide plate 56. During the combustion of thecatalyst 51a within thecatalyst chamber 51, the catalytic combustion heat is conducted through theguide plate 56 and the flame-quenchingmaterial 57 to the thermallyconductive plate 52. Theglow plug 45 is associated with thecontroller 42 so as to generate heat for a predetermined period of time at the initial term of the gas generation. Metal foam is used for the flame-quenchingmaterial 57, but material made of stainless steel, and formed as 'wire-mesh', may be used. - As shown in
Fig. 2(A) , theguide plate 56 has an under-surface with which thecatalyst 51a within thecatalyst chamber 51 is brought into contact. A catalyst component is supported on the flame-quenchingmaterial 57. When theglow plug 45 generates heat, the heat generated by theglow plug 45 is conducted through the thermallyconductive plate 52 to the fuel-passinggap 53. An oxidation-catalyst component is supported on the flame-quenchingmaterial 57. There is disposed below theguide plate 56 apartition 58, which divides the interior area of thecatalyst chamber 51. As shown inFigs. 2(B) and 2(C) , each of theguide plate 56 and thepartition 58 is opened to provide acentral aperture hole 56b and acentral aperture 58b, respectively.Peripheral apertures 56c are regularly spaced around thecentral aperture 56b and aplurality apertures 58c are regularly spaced around thecentral aperture 58b. The 56c and 58c of theapertures guide plate 56 and thepartition 58 are mutually staggered, when seen from above, so that theliquid fuel 6 flowed out of thefuel outlet 54 is prevented from flowing straight through both theapertures 56c and theapertures 58c in the mentioned order. Both theguide plate 56 and thepartition 58 may be made of stainless steel. - As shown in
Fig. 1 , anoxidation catalyst 12 for accelerating the combustion of theflammable gas 7 is located between a flammable-gas outlet 9 and aninlet 2a of thefilter 2. Theoxidation catalyst 12 is composed as follows.
As shown inFig. 3 , in order that theflammable gas 7 heated by the exothermic reaction within thegas generator 3 can flow out of the flammable-gas outlet 9 to theoxidation catalyst 12, theoxidation catalyst 12 occupies thecase 65 and the flammable-gas outlet 9 opens into theoxidation catalyst 12. Thecase 65 has aperipheral wall 66 provided with a plurality of exhaust-gas inlets 67 and has a rear 68 formed with an exhaust-gas outlet 69. There is a plurality of flammable-gas outlets 9, are arranged side by side along of theend part 8a of thesupply passage 8. Exhaust-gas inlets 67 are disposed in theperipheral wall 66 of the oxidation-catalystaccommodating case 65. - As shown in
Fig. 3 , when the exhaust-gas inlets 67 are located side by side in theperipheral wall 66 from thefront end 70 of thecase 65 to therear end 68 thereof. Theperipheral wall 66 of the 65 has a diameter which progressively increases from the front 70 to therear end 68. Thecase 65 resembles a cup in the form of a truncated cone. - As shown in
Fig. 1 , thecase 11 is a cylindrical, with 17 and 18. An axial direction of thisend walls case 11 is taken as a front-to-rear direction. Ainlet side 2a of thefilter 2 is regarded as the 'front' and an anoutlet side 2b is regarded as the 'rear'. Within thecase 11 is disposed an exhaust-gas inlet chamber 19 in front of thefilter 2 and an exhaust-gas outlet chamber 20 is arranged at the rear of thefilter 2. The exhaust-gas inlet chamber 19 communicates with an exhaust-gas inlet pipe 21 and the exhaust-gas outlet chamber 20 communicates with an exhaustgas outlet pipe 22.
The exhaust-gas inlet pipe 21 is inserted into the exhaust-gas inlet chamber 19 along a radial direction of the filter-containingcase 11. Theoxidation catalyst 12 and part of thegas generator 3 are disposed from the upstream side of the exhaust gas into the exhaust-gas inlet pipe 21 in the mentioned order. The flammable-gas supply passage 8 from thegas generator 3 extends into theoxidation catalyst 12. - An
exhaust muffler 28 is utilized as the filter-containingcase 11. The exhaust-gas inlet chamber 19 is composed of afirst expansion chamber 29 and the exhaust-gas outlet chamber 20 is constructed by afinal expansion chamber 30. The exhaust-gas inlet pipe 21 is formed from an exhaust-gas lead-inpipe 31 of thefirst expansion chamber 29 and the exhaust-gas outlet pipe 22 is composed of an exhaust-gas lead-outpipe 32 of thefinal expansion chamber 30. - As shown in
Fig. 2(A) , when thegas generator 3 is supplied with theliquid fuel 6 and with theair 44, theliquid fuel 6 mixes with theair 44 within the fuel-passinggap 53. Theliquid fuel 6 is converted into fine particles, which flow from the fuel-passinggap 53 through the flame-quenchingmaterial 57 into thecatalyst chamber 51. Part of thisliquid fuel 6 is oxidized (i.e. it undergoes catalytic combustion) within thecatalyst chamber 51 to generate oxidation (combustion) heat by means of which the remainingliquid fuel 6 is vaporized to become high-temperatureflammable gas 7. This high-temperatureflammable gas 7, as shown inFig. 2(A) , is fed from the flammable-gas supply passage 8 into theoxidation catalyst 12. On the other hand, theexhaust gas 10 which passes through the exhaust-gas route 1 flows into theoxidation catalyst 12 and is mixed with the high-temperatureflammable gas 7 and the mixture passes through theoxidation catalyst 12. Theflammable gas 7 is oxidized (burnt) by the oxygen contained in themixed exhaust gas 10 to produce oxidation heat (combustion heat) which heats themixed exhaust gas 10. - As shown in
Fig. 1 , theexhaust gas 10 flows out of theoxidation catalyst 12 as shown byarrows 60 and further flows out of the outlet holes 47 of the exhaust-gas lead-inpipe 31 into thefirst expansion chamber 29. Then, as shown byarrows 62, it enters thefilter 2 from theinlets 2a and passes through the filter. Theexhaust gas 10 that has passed through thefilter 2 flows from theoutlets 2b of thefilter 2 into thefinal expansion chamber 30 as shown byarrows 63. Thereafter, the gas flows from the inlet holes 48 of the exhaust-gas lead-inpipe 32 into the exhaust-gas lead-inpipe 32 and flows out of the exhaust-gas lead-outpipe 32 as shown by anarrow 64. - The second embodiment as shown in
Figs. 4 to 6 is different from the first embodiment as follows.
As shown inFig. 4(A) , theoxidation catalyst 12 is arranged outside the exhaust-gas inlet pipe 31, although it exists within the filter-containingcase 11. In order that theflammable gas 7 heated by the exothermic reaction within thegas generator 3 from the flammable-gas outlet 9 may flow to the upstream side of theoxidation catalyst 12, an upstream oxidation-passage 14 is formed within the exhaust-gas passage 13 upstream of theoxidation catalyst 12 and is formed into a double-cylinder structure. The upstream oxidation-passage 14 accommodates an upstream oxidation-catalyst 15, on an upstream side of which the flammable-gas outlet 9 is opened toward the upstream oxidation-passage 14. The exhaust-gas passage 13 is the exhaust -gas inlet pipe 21. - The upstream oxidation-passage has a sectional area set as follows.
As shown inFig. 4(B) , the upstream oxidation-passage 14 of the exhaust-gas passage 13 of the double-cylinder structure has a sectional area set to a fraction (such as 1/4) of the sectional area of the whole exhaust-gas passage 13 including the upstream oxidation-passage 14. In order to ensure the oxidation-acceleration function of the upstream oxidation-catalyst 15, it is desirable to set the sectional area of the upstream oxidation-passage 14 of the exhaust-gas passage 13 of double-cylinder structure within a range of 1/4 to 1/2 of the total sectional area of the exhaust-gas passage 13 including theupstream oxidation passage 14. - The flammable-gas outlet and the upstream oxidation-passage are opened in the following direction.
As shown inFig. 4(A) , the flammable-gas lead-outpipe 8, oriented in the direction where the upstream oxidation-passage 14 is formed, has itsterminal end 8a closed and has a peripheral wall near theterminal end 8a opened to provide the plurality of flammable-gas outlets 9 oriented radially of the upstream oxidation-passage 14. Further, the upstream oxidation-passage 14 has itsterminal end 14a closed and has a peripheral wall near theterminal end 14a, opened to form a plurality of upstream oxidation-passage outlets 16 oriented radially of a passage 4 in front of the oxidation-catalyst inlet. - As shown in
Fig. 4(A) , the high-temperatureflammable gas 7 is fed from the flammable-gas supply passage 8 to the upstream oxidation-passage 14 within the exhaust-gas passage 13. On the other hand,part 10 of the exhaust gas (shown by the arrows 10) which passes through the exhaust-gas passage 13 flows into the upstream oxidation-passage 14 and is mixed with the high-temperatureflammable gas 7 and the mixture passes through the upstream oxidation-catalyst 15. Theflammable gas 7 is oxidized (burnt) by the oxygen contained in themixed exhaust gas 10 to produce oxidation heat (combustion heat) which heats themixed exhaust gas 10. Theheated exhaust gas 10 flows out of the upstream oxidation-passage outlet 16; as shown by thearrows 35, and is mixed with the remaining 10 and 10 which did not flow into the upstream oxidation-exhaust gas passage 14. The mixture flows out of the outlet holes 47 and passes through theoxidation catalyst 12. Theflammable gas 7 oxidized (burnt) by the upstream oxidation-catalyst 15 and remaining is oxidized (burnt) by the oxygen in themixed exhaust gas 10 to produce oxidation (combustion) heat with which themixed exhaust gas 10 is heated. - As shown in
Fig. 5(A) , theupstream oxidation catalyst 15 comprises a catalytic component supported on asubstrate 25 formed by overlaying and winding acorrugated metal sheet 23 and aflat metal sheet 24. Each of the 23 and 24 may be a stainless steel sheet having a thickness of 0.5 mm. Platinum may be used as the catalyst component. In the case where the upstream oxidation-metal sheets catalyst 15 has such a structure, a relatively wideinter-catalyst passage 34 is formed and therefore even the upstream oxidation-passage 14 of a smaller diameter assures a sufficient sectional area of the inter-catalyst passage within the upstream oxidation-catalyst 15. Additionally, since the substrate itself 25 is resilient, it can be retained within the upstream oxidation-passage 14 without using any cushioning material.
As shown inFig. 5(B) , the upstream oxidation-catalyst 15 may comprises a catalytic component supported on asubstrate 27 formed from ametal mesh 26. Thismetal mesh 26 may be made of stainless steel and is generally called as "wire-mesh". Platinum may be used as the catalytic component. - As shown in
Fig.6 (A) , theoxidation catalyst 12 may comprise a catalytic component supported on asubstrate 25 formed by overlaying and winding acorrugated metal sheet 23 and aflat metal sheet 24. Each of the 23 and 24 may be a stainless steel sheet having a thickness of 0.5 mm. Platinum may be used as the catalyst component. In the case where themetal sheets oxidation catalyst 12 has such a structure, a relatively wideinter-catalyst passage 34 is formed and therefore a sufficient sectional area of the inter-catalyst passage within theoxidation catalyst 12 is assured. Additionally, since thesubstrate 25 itself is resilient, it can be retained within the filter-containingcase 11 without using any cushioning material.
As shown inFig. 6(B) , the catalyst may comprise a catalytic component supported on asubstrate 27 formed from ametal mesh 26. Thismetal mesh 26 may be made of stainless steel and is generally called as "wire-mesh". Platinum may be used as the catalyst component. - The second embodiment is the same as the first embodiment except for the variants described above.
- The third embodiment shown in
Fig. 7 is distinct from the first embodiment on the following point.
Alumina pellets may be used for the substrate of thecatalyst 51a within thecatalyst chamber 51. Theoxidation catalyst 12 is accommodated between theupstream oxidation catalyst 15 and thecatalyst chamber 51 of thegas generator 3 within the exhaust-gas inlet pipe 21 of the filter-containingcase 11. The flammable-gas lead-outpassage 8 extends through theoxidation catalyst 12. The third embodiment is the same as the second embodiment except for the other constructions and functions.
Claims (17)
- An exhaust device for a diesel engine, that supplies liquid fuel (6) from a source (5) of the liquid fuel (6) to a gas generator (3) which converts the liquid fuel (6) to flammable gas (7) and from which a flammable-gas supply passage (8) is conducted, the flammable-gas supply passage (8) having a flammable-gas outlet (9) in communication with an exhaust-gas route (1) upstream of a diesel-particulate-filter (2), flammable gas (7) which flows from the flammable-gas outlet (9) being burnt in exhaust gas (10) to generate combustion heat which can burn fine particles of the exhaust gas (10) remaining at the filter (2), a case (11) for containing the filter (2) accommodating at least part of the gas generator (3).
- An exhaust device according to claim 1, and arranged to mix air from a supercharger (39) with fuel from a fuel reservoir (5a) of the diesel engine.
- An exhaust device according to claim 1 or 2, wherein the gas generator (3) is provided with a catalyst chamber (51), a thermally conductive plate (52) is arranged at an upper portion of the catalyst chamber (51) and a fuel-passing gap (53) is formed along a surface of the thermally conductive plate (52), the fuel-passing gap (53) and having a an opening to provide a fuel outlet (54) to the catalyst chamber (51), whereby catalytic combustion heat generated within the catalyst chamber (15) is conducted through the thermally conductive plate (52) to the fuel-passing gap (53).
- An exhaust device according to claim 3, wherein the thermally conductive plate (52) has a mid portion from which an exothermic portion (45a) of a glow plug (45) projects downwards, and a guide (56) is arranged below the thermally conductive plate (52), the guide (56) being downwardly inclined from a periphery (56a) underneath the fuel outlet (54) to below the exothermic portion (45a) of the glow plug (45), thereby to guide the fuel towards the exothermic portion (45a) of the glow plug (45).
- An exhaust device according to claim 4, wherein a flame-quenching material (57) occupies a space between the thermally conductive plate (52) and the guide (56), whereby when the glow plug (45) generates heat, heat generated by the glow plug (45) is conducted through the flame-quenching material (57) to the thermally conductive plate (52) and the guide plate (56), and whereby during the catalytic combustion within the catalyst chamber (51), catalytic combustion heat is conducted through the guide (56) and the flame-quenching material (57) to the thermally conductive plate (52).
- An exhaust device according to claim 5, wherein the guide (56) has a surface with which a catalyst (51a) within the catalyst chamber (51) is brought into contact.
- An exhaust device according to claim 5 or claim 6, wherein a catalytic component is supported on the flame-quenching material (57).
- An exhaust device according to any one of claims 4 to 7, wherein when the glow plug (45) generates heat, heat generated by the glow plug (45) is conducted through the thermally conductive plate (52) to the fuel-passing gap (53) .
- An exhaust device according to any one of claims 1 to 8, wherein an oxidation catalyst (12) for accelerating the combustion of the flammable gas (7) is disposed between the flammable-gas outlet (9) and an inlet (2a) of the filter (2).
- An exhaust device according to claim 9, wherein in order that the flammable gas (7) heated by the exothermic reaction within the gas generator (3) from the flammable-gas outlet (9) can flow to the oxidation catalyst (12), the oxidation catalyst (12) occupies a case (65) and the flammable-gas outlet (9) opens into the oxidation catalyst (12), the case (65) having a peripheral wall (66) provided with a plurality of exhaust-gas inlets (67) and having an end portion (68) provided with an exhaust-gas outlet (69).
- An exhaust device according to claim 10, wherein the exhaust-gas inlets (67)are disposed along the peripheral wall (66) from a front end (70) of the case (65) toward a rear end (68) thereof, and the cross-sectional area of the case (65)progressively increases from the front end (70) to the rear end (68).
- An exhaust device according to any one of claims 9 to 11, wherein the oxidation catalyst (12) comprises a catalytic component supported on a metal mesh.
- An exhaust device according to any one of claims 9 to 12, wherein the filter-containing case (11) is cylindrical, an exhaust-gas inlet chamber (19) being provided at a front end of the filter (2) and an exhaust-gas outlet chamber (20) being provided at a rear end of the filter (2) within the filter-containing case (11), an exhaust-gas inlet pipe (21) communicating with the exhaust-gas inlet chamber (19) and an exhaust-gas outlet pipe (22) communicating with the exhaust-gas outlet chamber (20), and the exhaust-gas inlet pipe (21) extends into the exhaust-gas inlet chamber (19) along a radial direction of the filter-containing case (11), within the exhaust-gas inlet pipe (21) the oxidation catalyst (12) and at least part of the gas generator (3) are arranged in the mentioned order from upstream side of the exhaust-gas inlet pipe, the flammable-gas supply passage (8) from the gas generator (3) being inserted into the oxidation catalyst (12).
- An exhaust device according to claim 13, wherein an exhaust muffler (28) is disposed as the filter-containing case (11) and the exhaust-gas inlet chamber (19) is formed from a first expansion chamber (29), the exhaust-gas outlet chamber (20) being composed of a final expansion chamber (30), the exhaust-gas inlet pipe (21) being formed from an exhaust-gas lead-in pipe (31), and the exhaust-gas outlet pipe (22) being composed of an exhaust-gas lead-out pipe (32).
- An exhaust according to any one of claims 1 to 14, wherein the gas generator (3) is disposed to vaporize the liquid fuel (6) to convert it into the flammable gas (7).
- An exhaust device according to any one of claims 1 to 14, wherein the gas generator (3) is disposed to partly oxidizes the liquid fuel (6) to convert it into flammable gas (7) containing carbon monoxide and hydrogen.
- An exhaust device according to claim 9, wherein in order that flammable gas (7) heated by the exothermic reaction within the gas generator (3) from the flammable-gas outlet (9) can flow to the upstream side of the oxidation catalyst (12), an upstream oxidation-passage (14) is formed upstream of the oxidation catalyst (12) within an exhaust-gas passage (13), which is formed into a double-cylinder structure, and an upstream oxidation-catalyst (15) is accommodated within the upstream oxidation-passage (14), the flammable-gas outlet (9) opening into the upstream oxidation-passage (14) on an upstream side of the upstream oxidation-catalyst (15).
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP20070250776 EP1961931B1 (en) | 2007-02-23 | 2007-02-23 | Exhaust device for a diesel engine |
| DE200760004186 DE602007004186D1 (en) | 2007-02-23 | 2007-02-23 | Exhaust device for a diesel engine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP20070250776 EP1961931B1 (en) | 2007-02-23 | 2007-02-23 | Exhaust device for a diesel engine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1961931A1 true EP1961931A1 (en) | 2008-08-27 |
| EP1961931B1 EP1961931B1 (en) | 2010-01-06 |
Family
ID=38196551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20070250776 Ceased EP1961931B1 (en) | 2007-02-23 | 2007-02-23 | Exhaust device for a diesel engine |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP1961931B1 (en) |
| DE (1) | DE602007004186D1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102510975A (en) * | 2009-09-30 | 2012-06-20 | 株式会社Ihi | Ignition device |
| CN103670607A (en) * | 2012-09-11 | 2014-03-26 | 株式会社久保田 | Exhaust treatment device of diesel engine |
| EP2554810A4 (en) * | 2010-03-31 | 2016-03-02 | Kubota Kk | EXHAUST GAS TREATMENT DEVICE FOR DIESEL ENGINE |
| CN109248556A (en) * | 2018-11-16 | 2019-01-22 | 李东东 | Industrial waste gas treatment device |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE20023560U1 (en) * | 2000-03-24 | 2005-01-27 | Huss Umwelttechnik Gmbh | Fuel fired burner has the input air passed through a pre-heating space to increase the burn efficiency |
| US20050150219A1 (en) * | 2004-01-13 | 2005-07-14 | Crawley Wilbur H. | Method and apparatus for controlling the temperature of a fuel-fired burner of an emission abatement assembly |
| WO2007011113A1 (en) | 2005-07-22 | 2007-01-25 | Korea Institute Of Machinery And Materials | Inner flame burner for regeneration of diesel particulate filter |
-
2007
- 2007-02-23 EP EP20070250776 patent/EP1961931B1/en not_active Ceased
- 2007-02-23 DE DE200760004186 patent/DE602007004186D1/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE20023560U1 (en) * | 2000-03-24 | 2005-01-27 | Huss Umwelttechnik Gmbh | Fuel fired burner has the input air passed through a pre-heating space to increase the burn efficiency |
| US20050150219A1 (en) * | 2004-01-13 | 2005-07-14 | Crawley Wilbur H. | Method and apparatus for controlling the temperature of a fuel-fired burner of an emission abatement assembly |
| WO2007011113A1 (en) | 2005-07-22 | 2007-01-25 | Korea Institute Of Machinery And Materials | Inner flame burner for regeneration of diesel particulate filter |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102510975A (en) * | 2009-09-30 | 2012-06-20 | 株式会社Ihi | Ignition device |
| EP2484973A4 (en) * | 2009-09-30 | 2013-03-13 | Ihi Corp | IGNITION DEVICE |
| CN102510975B (en) * | 2009-09-30 | 2015-04-22 | 株式会社Ihi | Ignition device |
| US9395083B2 (en) | 2009-09-30 | 2016-07-19 | Ihi Corporation | Ignition device |
| EP2554810A4 (en) * | 2010-03-31 | 2016-03-02 | Kubota Kk | EXHAUST GAS TREATMENT DEVICE FOR DIESEL ENGINE |
| CN103670607A (en) * | 2012-09-11 | 2014-03-26 | 株式会社久保田 | Exhaust treatment device of diesel engine |
| CN103670607B (en) * | 2012-09-11 | 2017-09-22 | 株式会社久保田 | Exhaust treatment device of diesel engine |
| CN109248556A (en) * | 2018-11-16 | 2019-01-22 | 李东东 | Industrial waste gas treatment device |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1961931B1 (en) | 2010-01-06 |
| DE602007004186D1 (en) | 2010-02-25 |
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