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EP1889896A3 - Lubricating oil composition containing detergent additives - Google Patents

Lubricating oil composition containing detergent additives Download PDF

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Publication number
EP1889896A3
EP1889896A3 EP07111837A EP07111837A EP1889896A3 EP 1889896 A3 EP1889896 A3 EP 1889896A3 EP 07111837 A EP07111837 A EP 07111837A EP 07111837 A EP07111837 A EP 07111837A EP 1889896 A3 EP1889896 A3 EP 1889896A3
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Prior art keywords
independently
group
alkyl
moiety
cr
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EP07111837A
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German (de)
French (fr)
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EP1889896A2 (en
Inventor
James Christian c/o Infineum UK Ltd. Dodd
Jeremy Roger c/o Infineum UK Ltd. Spencer
Tushar c/o Infineum USA L.P. Bera
Jacob c/o Infineum USA L.P. Emert
Frederick Wein c/o Infineum USA L.P. Girshick
Michael Dennis c/o Infineum USA L.P. Hoey
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Infineum International Ltd
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Infineum International Ltd
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Priority to US11/500,730 priority Critical patent/US7781385B2/en
Priority to US11/772,896 priority patent/US7923420B2/en
Application filed by Infineum International Ltd filed Critical Infineum International Ltd
Publication of EP1889896A2 publication Critical patent/EP1889896A2/en
Publication of EP1889896A3 publication Critical patent/EP1889896A3/en
Application status is Pending legal-status Critical

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M165/00Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • C10M2203/1085Residual fractions, e.g. bright stocks used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028Overbased salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046Hydroxy ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
    • C10M2207/262Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/288Partial esters containing free carboxyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/042Alcohols; Ethers; Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/086Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089Overbased salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2230/00Specified physical or chemical properties of lubricating compositions
    • C10N2230/04Detergent properties, e.g. for cleaning, inhibition or removing varnish; Dispersion properties, e.g. for dispersing solids, carbon residues, sludge
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2240/00Specified uses or applications of lubricating compositions
    • C10N2240/10Internal-combustion engines
    • C10N2240/102Diesel engines

Abstract

A lubricating oil composition having a total base number of more than 15 mg KOH/g, as determined by ASTM D2896, and including at least 40 mass % of an oil of lubricating viscosity; at least one detergent; and at least one compound of the formula (I) and/or formula (II):
Figure imga0001
Figure imga0002
In formula (I), each Ar independently represents an aromatic moiety having 0 to 3 substituents selected from the group consisting of alkyl, alkoxy, alkoxyalkyl, aryloxy, aryloxyalkyl, hydroxy, hydroxyalkyl, halo and combinations thereof; each L is independently a linking moiety comprising a carbon-carbon single bond or a linking group; each Y is independently -OR1" or a moiety of the formula H(O(CR1 2)n)yX-, wherein X is selected from the group consisting of (CR1' 2)z, O and S; R1 and R1' are each independently selected from H, C1 to C6 alkyl and aryl; R1" is selected from C1 to C100 alkyl and aryl; z is 1 to 10; n is 0 to 10 when X is (CR1' 2)z, and 2 to 10 when X is O or S; and y is 1 to 30; each a is independently 0 to 3, with the proviso that at least one Ar moiety bears at least one group Y; and m is 1 to 100. In formula (II), each Ar' independently represents an aromatic moiety having 0 to 3 substituents selected from the group consisting of alkyl, alkoxy, alkoxyalkyl, hydroxy, hydroxyalkyl, acyloxy, acyloxyalkyl, aryloxy, aryloxy alkyl, halo and combinations thereof; each L' is independently a linking moiety comprising a carbon-carbon single bond or a linking group; each Y' is independently a moiety of the formula Z(O(CR2 2)n')y'X'-, wherein X' is selected from the group consisting of (CR2' 2)z', O and S; R2 and R2' are each independently selected from H, C1 to C6 alkyl and aryl; z' is 1 to 10; n' is 0 to 10 when X' is (CR2' 2)z', and 2 to 10 when X' is O or S; y' is 1 to 30; Z is H, an acyl group, an alkyl group or an aryl group; each a' is independently 0 to 3, with the proviso that at least one Ar' moiety bears at least one group Y' in which Z is not H; and m' is 1 to 100.
EP07111837A 2006-08-08 2007-07-05 Lubricating oil composition containing detergent additives Pending EP1889896A3 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US11/500,730 US7781385B2 (en) 2006-08-08 2006-08-08 Lubricating oil composition
US11/772,896 US7923420B2 (en) 2007-07-03 2007-07-03 Lubricating oil composition

Publications (2)

Publication Number Publication Date
EP1889896A2 EP1889896A2 (en) 2008-02-20
EP1889896A3 true EP1889896A3 (en) 2008-09-10

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EP07111837A Pending EP1889896A3 (en) 2006-08-08 2007-07-05 Lubricating oil composition containing detergent additives

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EP (1) EP1889896A3 (en)
JP (1) JP5429728B2 (en)
AU (1) AU2007203663B2 (en)
CA (1) CA2596211C (en)
SG (1) SG139726A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7786057B2 (en) * 2007-02-08 2010-08-31 Infineum International Limited Soot dispersants and lubricating oil compositions containing same
US20090203559A1 (en) * 2008-02-08 2009-08-13 Bera Tushar Kanti Engine Lubrication
EP2135926A1 (en) * 2008-05-20 2009-12-23 Infineum International Limited Marine engine lubrication
EP2123739B1 (en) 2008-05-20 2017-09-27 Infineum International Limited Marine engine lubrication
ES2641591T3 (en) 2008-05-20 2017-11-10 Infineum International Limited Marine engine lubrication
WO2010115594A1 (en) * 2009-04-07 2010-10-14 Infineum International Limited Marine engine lubrication
EP2371932B1 (en) * 2010-04-01 2018-10-17 Infineum International Limited A lubricating oil composition
DK2607462T3 (en) * 2011-12-20 2014-03-31 Infineum Int Ltd Lubrication of the ship's engine
DE102012223638A1 (en) * 2011-12-21 2013-06-27 Infineum International Ltd. A method for reducing the rate of decrease of the basicity of a lubricating oil composition which is used in a motor

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2978423A (en) * 1956-07-11 1961-04-04 Exxon Standard Sa Anti-rust compositions
US5021498A (en) * 1989-11-08 1991-06-04 Nalco Chemical Company Asphaltene dispersants - inhibitors
US5821202A (en) * 1997-04-29 1998-10-13 The Lubrizol Corporation Hydrocarbon stream antifoulant method using bridged alkyl phenates
EP1605034A1 (en) * 2004-06-11 2005-12-14 Infineum International Limited Detergent additive for lubricating oil compositions
EP1693434A2 (en) * 2005-02-18 2006-08-23 Infineum International Limited Soot dispersants and lubricating oil compositions containing same
EP1767611A2 (en) * 2005-09-22 2007-03-28 Clariant Produkte (Deutschland) GmbH Additive for crude oils.

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2747608A1 (en) * 1976-10-28 1978-05-03 Ciba Geigy Ag effective fluessigkeitszusammensetzung
GB8804171D0 (en) * 1988-02-23 1988-03-23 Exxon Chemical Patents Inc Dispersant for marine diesel cylinder lubricant
US6180005B1 (en) 1999-02-18 2001-01-30 Aquafine Corporation Continuous filament matrix for magnetic separator
US6189492B1 (en) 1999-04-07 2001-02-20 Custom Molder, Inc. Automotive fan shroud and method of making
US6750183B2 (en) * 2000-12-22 2004-06-15 Infineum International Ltd. Lubricating oil composition
US20050119140A1 (en) * 2003-10-30 2005-06-02 Laurent Chambard Method of reducing deposit formation in a centrifuge system in a trunk piston diesel engine
CA2509735C (en) * 2004-06-11 2012-09-25 Infineum International Limited Detergent additives for lubricating oil compositions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2978423A (en) * 1956-07-11 1961-04-04 Exxon Standard Sa Anti-rust compositions
US5021498A (en) * 1989-11-08 1991-06-04 Nalco Chemical Company Asphaltene dispersants - inhibitors
US5821202A (en) * 1997-04-29 1998-10-13 The Lubrizol Corporation Hydrocarbon stream antifoulant method using bridged alkyl phenates
EP1605034A1 (en) * 2004-06-11 2005-12-14 Infineum International Limited Detergent additive for lubricating oil compositions
EP1693434A2 (en) * 2005-02-18 2006-08-23 Infineum International Limited Soot dispersants and lubricating oil compositions containing same
EP1767611A2 (en) * 2005-09-22 2007-03-28 Clariant Produkte (Deutschland) GmbH Additive for crude oils.

Also Published As

Publication number Publication date
AU2007203663A1 (en) 2008-02-28
EP1889896A2 (en) 2008-02-20
AU2007203663B2 (en) 2011-05-12
JP2008056933A (en) 2008-03-13
CA2596211A1 (en) 2008-02-08
JP5429728B2 (en) 2014-02-26
SG139726A1 (en) 2008-02-29
CA2596211C (en) 2014-07-08

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