EP1872938A1 - Laminierter flammgeschützter Bekleidungsstoff - Google Patents

Laminierter flammgeschützter Bekleidungsstoff Download PDF

Info

Publication number
EP1872938A1
EP1872938A1 EP06116288A EP06116288A EP1872938A1 EP 1872938 A1 EP1872938 A1 EP 1872938A1 EP 06116288 A EP06116288 A EP 06116288A EP 06116288 A EP06116288 A EP 06116288A EP 1872938 A1 EP1872938 A1 EP 1872938A1
Authority
EP
European Patent Office
Prior art keywords
fire retardant
upholstery fabric
laminated fire
fabric according
laminated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06116288A
Other languages
English (en)
French (fr)
Inventor
Luuk Goede
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PinTail International BV
Original Assignee
PinTail International BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PinTail International BV filed Critical PinTail International BV
Priority to EP06116288A priority Critical patent/EP1872938A1/de
Publication of EP1872938A1 publication Critical patent/EP1872938A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47CCHAIRS; SOFAS; BEDS
    • A47C31/00Details or accessories for chairs, beds, or the like, not provided for in other groups of this subclass, e.g. upholstery fasteners, mattress protectors, stretching devices for mattress nets
    • A47C31/001Fireproof means
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other

Definitions

  • the present invention relates to a laminated fire retardant upholstery fabric that useful for rendering upholstered articles, e.g. chairs, cushions and cushioned seats fire retardant as well as water repellent or water impervious.
  • US 4.256.786 discloses an aqueous, chemical protective, fire retardant composition for a polyurethane foam or a textile laminate comprising a phosphoric acid releasing fire retarding agent and an acrylic binder.
  • US 4.806.185 discloses the use of a latex comprising heat conductive metal particles so that a coating of this latex has an improved heat dissipation.
  • US 5.102.701 discloses the use of a mixture of bromochlorinated paraffins and antimony oxide comprising an acrylic binder.
  • GB A 2.231.789 discloses a seating upholstery fabric comprising a fire retardant inner layer (when the fabric is applied to the seat) comprising needled polyacrylate fibres.
  • a similar seating upholstery fabric is disclosed in US 5.405.178 , wherein said fabric comprises a flame-proof layer of an open-cell resilient plastic foam impregnated with a liquid flame-proofing agent, such as powdered melamine resin or aluminium hydroxide.
  • US 2005/0095936 discusses these prior art techniques and the disadvantages thereof.
  • US 2005/0095936 says to provide an improved fire retardant laminate comprising a three-layer structure.
  • This three-layer structure comprises a layer of ticking fabric, a layer of flame and heat retardant cushioning material and a layer of backing fabric. All three layers may comprise fire retardant fibres.
  • the cushioning layer may be composed of thermoplastic fibres that are impregnated with a fire retardant chemical.
  • the ticking layer may also comprise non-fire retardant fibres in which case it is coated with flame retardant chemicals.
  • the laminated fire retardant fabrics of the prior art have the disadvantage that they are not water repellent and/or water impervious, a property highly appreciated in environments where the spoiling of water and aqueous compositions such as beverages is likely to occur, e.g. nursing homes, hospitals.
  • the present invention relates to a laminated fire retardant upholstery fabric comprising:
  • the term “outer” and “inner” are used to indicate the structure of the fabric when applied to upholstered articles, that is when applied the textile layer is observable from the outside. Obviously, the flame retardant coating layer is not observable from the outside.
  • the outer textile layer is preferably a woven or knitted textile layer comprising fibres of natural or synthetic origin or a mixture thereof Natural fibres comprise for example wool and cotton. Synthetic fibres comprise for example polyester, polypropylene, viscose and polyacrylates.
  • the intermediate water repellent or water impervious membrane or film layer can be applied on the textile layer by laminating, coating or spraying techniques.
  • the intermediate layer is applied by lamination, it is preferred that an adhesive based on a moisture curable polyurethane prepolymer composition is used, wherein the prepolymer composition is applied under conditions of a relative humidity of at least 30%, more preferably at least 50%, even more preferably at least 75% and in particular at least 90%.
  • the polyurethane prepolymer composition is applied on a web of the textile layer by e.g. spraying or by using a screen, a doctor blade or a knife.
  • the polyurethane prepolymer composition can be a solution having a solids content of 10 wt. - 50 wt.% of the polyurethane prepolymer. However, it is preferred that the composition has a solids content of about 100 wt.%. These percentages are calculated on the total weight of the polyurethane prepolymer.
  • the polyurethane prepolymer composition has preferably a Brookfield viscosity of 1200 mPa.s (80°C) to 14.000 mPa.s (130°C), more preferably of 1300 mPa.s (80°) to 13.000 mPa.s (130°C).
  • the polyurethane prepolymer composition preferably comprises a free isocyanate content of 0,1 to 3,0%, in particular of 0,5 to 2,0%.
  • the density of the polyurethane prepolymer composition is preferably 1.05 to 1.25 g/m 3 , more preferably 1.10 to 1.20 g/cm 3 .
  • the web of the textile layer is preferably provided with the polyurethane prepolymer composition at a dose of 0.5 to 40 g/m 2 , in particular of 1,0 to 25 g/m 2 .
  • the intermediate water repellent or water impervious membrane or film layer comprises a thermoplastic material which is preferably selected from the group consisting of polyurethanes, polyesters, polyethyleneterephthalates, polyvinylchlorides and combinations thereof.
  • the thermoplastic material is in the form of a film which is applied by lamination, preferably by using the adhesive comprising the polyurethane prepolymer composition described above.
  • the intermediate water repellent or water impervious membrane or film layer can also be applied by coating, wherein the coating comprises a polyurethane or a polyester.
  • the (inner) flame retardant coating layer comprises a polyurethane, an acrylate or a methacrylate homopolymer or copolymer, optionally in combination with environmentally friendly en non-poisonous flame retarding chemicals. These flame retarding chemicals can be added by impregnation, finishing or coating.
  • the flamer retardant coating layer may comprise flame retardant fibrous materials or flame retardant fibres, e.g. glass fibres or polypropylene fibres.
  • the flame retardant coating layer comprises a foam coating.
  • the laminated fire retardant upholstery fabric according to the present invention has in general a weight of 250 - 750 g/m 2 and is used with a width of about 130 - 150 cm.
  • the laminated fire retardant upholstery fabric is furthermore characterized by a tensile strength of more than 40 N as determined according to ISO 13937-5, preferably more than 80. N and in particular more than 100N.
  • the tensile strength is determined using a ballistic pendulum method (Elmendorf).
  • the seam resistance of the laminated fire retardant upholstery fabric is less than 4 mm as determined according to ISO 13936-2, preferably less than 3 mm and in particular less than 2 mm.
  • the seam resistance or slippage resistance of yarns at a seam in woven fabrics is measured with the fixed load method.
  • the Martindale abrasion of the laminated fire retardant upholstery fabric is more than 35000 rubs, preferably more than 50000 rubs.
  • the Martindale abrasion test is performed according to DIN 61010-98.
  • a special test apparatus is used that is for example available from Qualitest International Inc., Canada. This test apparatus is primarily designed to determine the abrasion resistance of fabrics of all types including fabrics used by the shoe industry. Hence, woven, nonwoven, knit apparel, household and industrial fabrics can be subjected to this test.
  • the abrasion resistance is measured by subjecting a specimen to a rubbing motion in the form of a geometric figure. Resistance to abrasion is evaluated by various means, including comparison to visual aids in the form of photographs or actual samples.
  • Pilling although less likely to affect a textile's functional performance, frequently results in consumer dissatisfaction and subsequent disposal of textile products long before they reach the end of their useful wear life.
  • pills are defined as bunches or balls of tangled fibres which are held to the surface of a fabric by one or more fibres whereas pilling resistance is the resistance to the formation of pills on the surface of a textile fabric.
  • the laminated fire retardant upholstery fabric according to the present invention has a rating in the pilling test according to ISO 105X12 of more than Grade 3, preferably more than Grade 4 and in particular more than Grade 5.
  • the laminated fire retardant upholstery fabric should pass the fire retardancy test according to BS 5852 Part 2, crib-5, and/or to DIN 4102 B2.
  • the BS 5852 Part 2, crib-5, test is used for testing the ignitability of upholstered composites for seating, e.g. furniture and furnishings wherein the test specimen is subjected to a smouldering cigarette.
  • a cleaned test specimen together with a standard untreated flexible cellular polyurethane foam filling material is mounted on a test rig constructed to simulate the seat and back or seat and arm of a typical chair.
  • a smouldering cigarette of specified characteristics is placed between the horizontal and vertical portions of the test rig and the ignitability of the covering and filling materials observed. The extent of any damage which may occur in length, width and depth is recorded for both horizontal and vertical assemblies.
  • the test specimen passes this test when it does not exhibit either progressive smouldering ignition or flaming ignition when tested
  • the ignitability of the laminated fire retardant upholstery fabric is tested inside a test chamber or fire cabinet where the test specimen is mounted vertically.
  • the test specimen is subjected to the edge and/or surface exposure from a gas flame.
  • the time of ignition, burning droplets and whether the flames reach the top marking of the test specimen within the prescribed time period is registered.
  • micro-organisms resistance to micro-organisms (mildew fungi) of fabrics is tested because of the hazards that may be caused to humans.
  • the fabric In the DIN 53931 test, the fabric is directly exposed to the action of micro-organisms resulting in the deterioration of fabric functional properties.
  • the growth of micro-organisms in textiles can bring about allergic reactions, irritations of mucous tunic of nose, throat, eyes and intensify symptoms of asthma. Therefore, manufacturers who want to offer textile products with the highest quality and to ensure that the offered goods pose no hazard to users, have usually their products assessed for the action of micro-organisms.
  • the laminated fire retardant upholstery fabric according to the present invention should also pass the DIN 53931 test.
  • the waterproofness is determined according to ISO 811 and the water column level is preferably more than 7 m, more preferably more than 10 m.
  • the laminated fire retardant upholstery fabric according to the present invention is in particular suitable for upholstering furniture and cushions, in particular those that are in use in nursery homes, geriatric institutions, marine and shipping.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
EP06116288A 2006-06-29 2006-06-29 Laminierter flammgeschützter Bekleidungsstoff Withdrawn EP1872938A1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06116288A EP1872938A1 (de) 2006-06-29 2006-06-29 Laminierter flammgeschützter Bekleidungsstoff

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06116288A EP1872938A1 (de) 2006-06-29 2006-06-29 Laminierter flammgeschützter Bekleidungsstoff

Publications (1)

Publication Number Publication Date
EP1872938A1 true EP1872938A1 (de) 2008-01-02

Family

ID=37101369

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06116288A Withdrawn EP1872938A1 (de) 2006-06-29 2006-06-29 Laminierter flammgeschützter Bekleidungsstoff

Country Status (1)

Country Link
EP (1) EP1872938A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI738189B (zh) * 2020-01-21 2021-09-01 東豐纖維企業股份有限公司 多功能紡織品及其製造方法與用途
CN115320192A (zh) * 2022-08-25 2022-11-11 山东太阳鸟安全科技有限公司 一种防静电阻燃窗帘的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2074622A (en) * 1980-04-28 1981-11-04 Milliken Res Corp Soil-resistant textile materials
US6251210B1 (en) * 1996-08-07 2001-06-26 Hi-Tex, Inc. Treated textile fabric
US20040092184A1 (en) * 2002-11-12 2004-05-13 Rus Kingman Flame-retardant substrate
JP2005169655A (ja) * 2003-12-08 2005-06-30 Hiraoka & Co Ltd 経緯方向のクリープバランスに優れたテント構造物用防水性積層膜材

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2074622A (en) * 1980-04-28 1981-11-04 Milliken Res Corp Soil-resistant textile materials
US6251210B1 (en) * 1996-08-07 2001-06-26 Hi-Tex, Inc. Treated textile fabric
US20040092184A1 (en) * 2002-11-12 2004-05-13 Rus Kingman Flame-retardant substrate
JP2005169655A (ja) * 2003-12-08 2005-06-30 Hiraoka & Co Ltd 経緯方向のクリープバランスに優れたテント構造物用防水性積層膜材

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 200551, Derwent World Patents Index; AN 2005-499641, XP002403851 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI738189B (zh) * 2020-01-21 2021-09-01 東豐纖維企業股份有限公司 多功能紡織品及其製造方法與用途
CN115320192A (zh) * 2022-08-25 2022-11-11 山东太阳鸟安全科技有限公司 一种防静电阻燃窗帘的制备方法

Similar Documents

Publication Publication Date Title
CA2586232C (en) Flame resistant filler cloth and mattresses incorporating same
US20110283458A1 (en) Ticking Layers that Reduce Flame Propagation and Upholstered Articles Incorporating Same
US7361617B2 (en) Fire resistant composite material and fabrics therefrom
US20070077839A1 (en) Flame resistant matelasse fabrics
US9435074B2 (en) Fire resistant composite material and fabrics made therefrom
US7601414B2 (en) Stitchbonded inherently flame resistant fabrics
US8822355B2 (en) Fire resistant composite material and fabrics made therefrom
EP2672852B1 (de) Flammenhemmender, wasserdichter, dehnbarer natürlicher stoff und kissen- oder matratzenschutz/-hülle mit dem besagten stoff
Nazaré et al. A review of fire blocking technologies for soft furnishings
EP3579727B1 (de) Flammhemmende abdeckung
Martini et al. Low-cost wool-based fire blocking inter-liners for upholstered furniture
EP1872938A1 (de) Laminierter flammgeschützter Bekleidungsstoff
US20090056029A1 (en) Foam core article with flexible heat-resistant knitted fabric
Wakelyn Environmentally friendly flame resistant textiles
US20090061717A1 (en) Foam core article with flexible heat-resistant knitted fabric
Damant et al. The role of fabric in the cigarette ignition of upholstered furniture
Nazaré et al. Flame retardancy testing and regulation of soft furnishings
Handermann Flame resistant barriers for home furnishings
US10130189B2 (en) Laminated textile materials that reduce flame propagation, articles incorporating same, and methods of making same
EP1780322A2 (de) Feuerhemmende Decke für Federmatratzen
Nazare et al. A review of fire blocking technologies for soft furnishings
MXPA04007263A (es) Material estructural resistente al fuego y telas revestidas elaboradas con dicho material.
GB2542333A (en) A method of forming a fire retardant fabric Without the need to apply a fire retardant composition
WO2009123612A1 (en) Open flame resistant articles
GB2565821A (en) Fire retardant upholstered article and method

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK YU

AKX Designation fees paid
REG Reference to a national code

Ref country code: DE

Ref legal event code: 8566

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20080703