EP1744814A1 - Matiere colorante pour fibres keratiniques leur conferant un lustre nacre - Google Patents

Matiere colorante pour fibres keratiniques leur conferant un lustre nacre

Info

Publication number
EP1744814A1
EP1744814A1 EP04790862A EP04790862A EP1744814A1 EP 1744814 A1 EP1744814 A1 EP 1744814A1 EP 04790862 A EP04790862 A EP 04790862A EP 04790862 A EP04790862 A EP 04790862A EP 1744814 A1 EP1744814 A1 EP 1744814A1
Authority
EP
European Patent Office
Prior art keywords
amino
alcohol
composition according
alkanolamide
carrier composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04790862A
Other languages
German (de)
English (en)
Inventor
Manuela Javet
Dominique Le Cruer
Catherine MÜLLER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Deutschland GmbH
Original Assignee
Wella GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wella GmbH filed Critical Wella GmbH
Publication of EP1744814A1 publication Critical patent/EP1744814A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/438—Thermochromatic; Photochromic; Phototropic

Definitions

  • the invention relates to pearlescent agents for dyeing keratin fibers, in particular human hair, containing direct and / or oxidative dyes and a special combination of fatty alcohols, alkanolamides, fatty acid esters and anionic surfactants, and the use of the aforementioned combination to produce a stable Pearlescent in hair dye.
  • Coloring preparations are usually in the form of aqueous — preferably thickened — solutions or emulsions and, in addition to dyes, contain, for example, fatty alcohols and / or other components, emulsifiers and surfactants, and, if appropriate, alcohols.
  • Oxidation colorants generally consist of two components, (i) the dye carrier composition containing the dyes and (ii) the oxidizing agent preparation, which are mixed with one another shortly before use and are then applied to the hair to be colored. If the coloring preparations are in the form of emulsions, these are generally stable creams which, however, require the addition of special pearlescent agents to produce a pearlescent effect.
  • cream-shaped hair colorants which can contain a large number of raw materials, including fatty alcohols and fatty acid alkanolamides as well as fatty acid esters, anionic surfactants and fatty alcohol alkoxylates.
  • these agents have no pearlescent.
  • fatty alcohol alkoxylates PEG-based nonionic surfactants and emulsifiers
  • PEG-based nonionic surfactants and emulsifiers are suspected Make skin more permeable and thus infiltrate pollutants. This possible property of the fatty alcohol alkoxylates is of particular concern in colorants, since an increased penetration rate of dyes can lead to undesirable reactions in the body of the consumer.
  • the present invention therefore relates to a color carrier composition
  • a color carrier composition comprising oxidative and / or non-oxidative (“direct”) dyes, characterized in that it is free from fatty alcohol alkoxylates and a combination of
  • (d) contains at least one anionic surfactant, the weight ratio of fatty alcohol (a) to alkanolamide (b) being 1: 4 to 4: 1.
  • Color carrier compositions in which the fatty alcohol (a) and the alkanolamide (b) are present in a weight ratio of 1: 1.7 to 2: 1 are particularly preferred.
  • the weight ratio of fatty acid ester (c) to anionic surfactant (d) is 1: 7 to 7: 1, a weight ratio from (c) to (d) from 1: 1.5 to 1.5: 1 is particularly preferred.
  • Long-chain fatty alcohols with 14 to 60 carbon atoms which are suitable according to the invention are, for example, cetylic alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, isooctyl alcohol or isotridecyl alcohol and mixtures of C30-C50 alcohols or of C40-C60 alcohols.
  • the fatty alcohols can be used individually or in combination with one another in the color carrier composition according to the invention, a mixture of stearyl alcohol and behenyl alcohol in a ratio of 1: 4 to 1: 1 being particularly preferred.
  • Alkanolamides suitable according to the invention are in particular the N-acyl derivatives of monoethanolamine or diethanolamine, for example monoethanolamides and diethanolamides, or ester amides such as coconut fatty acid monoethanolamide.
  • Fatty acid esters suitable according to the invention are, for example, mono- or di-fatty acid esters of glycol, polyethylene glycol or glycerol, such as, for example, glycol distearate, glyceryl dioleate, glyceryl stearate, glyceryl distearate, glyceryl dibehenate and PEG-3 distearate, which for example under the trade name Tegin from the company Th. Goldschmidt, Germany.
  • the glycol distearate is particularly preferred.
  • Anionic surfactants suitable according to the invention are salts and esters of carboxylic acids, alkyl ether sulfates and alkyl sulfates, fatty alcohol ether sulfates, sulfonic acid and their salts (e.g. sulfosuccinates or fatty acid isethienates), phosphoric acid esters and their salts, acylamino acids and their salts.
  • sulfosuccinates or fatty acid isethienates e.g. sulfosuccinates or fatty acid isethienates
  • phosphoric acid esters and their salts e.g. sulfosuccinates or fatty acid isethienates
  • phosphoric acid esters and their salts e.g. sulfosuccinates or fatty acid isethienates
  • phosphoric acid esters and their salts e.g. sulfosuccinates or fatty acid is
  • the fatty alcohol of component (a) and the alkanolamide of component (b) are each used in a total amount of 6 to 20 percent by weight, preferably in each case in a total amount of 7 to 15 percent by weight, in the color carrier composition according to the invention.
  • the fatty acid ester is used in a total amount of 0.1 to 15 percent by weight, preferably 7 to 12 percent by weight; while the anionic surfactant is used in a total amount of 0.1 to 15 percent by weight, preferably in an amount of 0.5 to 10 percent by weight.
  • the color carrier composition according to the invention is preferably free from monomeric quaternary ammonium compounds and cationic emulsifiers and surfactants.
  • a ratio of (c) :( d) from 1: 7 to 7: 1, in particular from 1: 1, 5 to 6: 1, is advantageous both for the formation of the mother-of-pearl character and for a special care effect after rinsing out the color composition ,
  • the dye carrier composition according to the invention preferably contains oxidation dye precursors in which the coloring is produced under the action of oxidizing agents, such as hydrogen peroxide and its adducts, or in the presence of atmospheric oxygen.
  • oxidizing agents such as hydrogen peroxide and its adducts, or in the presence of atmospheric oxygen.
  • Suitable oxidation dye precursors are the following developer substances and coupler substances and self-coupling compounds: (i) Developer substances: 1,4-diamino-benzene (p-phenylenediamine), 1,4-diamino-2-methyl-benzene (p -Toluenediamine), 1,4-diamino-2,6-dimethyl-benzene, 1,4-diamino-3,5-diethyl-benzene, 1,4-diamino-2,5-dimethyl-benzene, 1,4- Diamino-2,3-dimethyl-benzene, 2-chloro-1,4-diaminobenzene, 1,4-diamino-2- (thiophene-2-yl) benzene, 1,4-diamino-2- (thiophene-3- yl) benzene, 1,4-diamino-2- (pyridin-3-yl) benzene, 2,5-di
  • coupler substances N- (3-dimethylaminophenyl) urea, 2,6-diamino-pyridine, 2-amino-4 - [(2-hydroxyethyl) amino] anisole, 2,4-diamino-1-fluorine 5-methyl-benzene, 2,4-diamino-1-methoxy-5-methyl-benzene, 2,4-diamino-1-ethoxy-5-methyl-benzene, 2,4-diamino-1 - (2-hydroxy - ethoxy) -5-methyl-benzene, 2,4-di [(2-hydroxyethyl) amino] -1, 5-dimethoxy-benzene, 2,3-diamino-6-methoxy-pyridine, 3-amino-6- methoxy-2- (methylamino) pyridine, 2,6-diamino-3,5-dimethoxy-pyridine, 3,5-diamino-2,6-dimethoxy-pyridine,
  • the total amount of the oxidation dye precursors contained in the dye carrier composition according to the invention is about 0.01 to 12 percent by weight, in particular about 0.2 to 6 percent by weight.
  • conventional natural and / or synthetic direct dyes for example so-called plant dyes such as henna or indigo, triphenylmethane dyes, aromatic nitro dyes, azo dyes, quinone dyes, cationic or anionic dyes, can also be present in the colorant.
  • plant dyes such as henna or indigo, triphenylmethane dyes, aromatic nitro dyes, azo dyes, quinone dyes, cationic or anionic dyes
  • Suitable synthetic dyes are: 1,4-bis [(2-hydroxyethyl) amino] -2-nitrobenzene, 1- (2-hydroxyethyl) amino-2-nitro-4- [di (2-hydroxyethyl) -amino] -benzoI (HC Blue No. 2), 1 -amino-3-methyl-4 - [(2-hydroxyethyl) -amino] -6-nitrobenzene (HC Violet No. 1), 4- [ethyl- ( 2-hydroxyethyl) amino] -1 - [(2-hydroxyethyl) amino] -2-nitrobenzene hydrochloride (HC Blue No.
  • the total amount of direct dyes in the color carrier composition according to the invention is about 0.01 to 7 percent by weight, preferably about 0.2 to 4 percent by weight.
  • the color carrier composition according to the invention may be in the form of a non-oxidative colorant based on the abovementioned direct dyes.
  • antioxidants such as, for example, ascorbic acid, thioglycolic acid or sodium sulfite, as well as complexing agents for heavy metals, for example ethylenediaminotetraacetate or nitriloacetic acid, can be present in the dye carrier composition according to the invention in an amount of up to about 0.5 percent by weight.
  • Perfume oils can be contained in the color carrier composition according to the invention in an amount of up to about 1 percent by weight.
  • the color carrier composition described above may optionally contain other additives customary for hair colorants, such as, for example, thickeners, for example homopolymers of acrylic acid, vegetable gums, cellulose and starch derivatives, algal polyasaccharides, amphiphilic associative thickeners and further preservatives; Antioxidants, for example sodium sulfite, thioglycolic acid or ascorbic acid; complexing; Solvents such as water, lower aliphatic alcohols, for example aliphatic alcohols with 1 to 4 carbon atoms such as ethanol, propanol and isopropanol, or glycols such as Glycene and 1, 2-propylene glycol; Wetting agents or emulsifiers not mentioned in the main claims are from the classes of anionic, amphoteric or nonionic surface-active substances; continue plasticizers; Vaseline; Contain silicone oils, paraffin oil, polysorbates and fatty acids as well as care substances such as cationic polymers or
  • the pH of the color carrier composition according to the invention is in the range from about 5 to 10, preferably 6 to 9, in the case of non-oxidative colorants based on substantive dyes, while the pH in a range of about in the case of oxidative colorants based on oxidation dye precursors 6 to 12, preferably 9 to 11, the pH of the ready-to-use oxidation hair dye (ie the mixture of the dye carrier composition according to the invention with the oxidizing agent) being about 5.5 to 10, preferably 6 to 9.
  • the pH value is preferably set with ammonia, amino acids or organic amines, such as, for example, glucamines, aminomethyl propanol, monoethanolamine or triethanolamine, inorganic bases, for example sodium hydroxide, potassium hydroxide, sodium carbonate or calcium hydroxide, or organic or inorganic acids, such as lactic acid, citric acid, acetic acid or phosphoric acid.
  • the color carrier composition according to the invention is preferably packaged in the form of an aqueous or aqueous-alcoholic preparation, for example as a thickened solution, as an emulsion, as a cream or as a gel.
  • the dye carrier composition described above is mixed with an oxidizing agent immediately before use and an amount sufficient for dyeing, usually about 60 to 200 grams, of the ready-to-use preparation is applied to the fiber.
  • the dye carrier composition according to the invention contains no oxidation dye precursors or contains oxidation dye precursors which can easily be oxidized with atmospheric oxygen, it can be applied directly to the keratin fiber without prior mixing with an oxidizing agent.
  • the main oxidizing agents used to develop the color are hydrogen peroxide or its addition compounds with urea, melamine or sodium borate in the form of a 1 to 12 percent, preferably 1.5 to 6 percent aqueous solution.
  • the mixing ratio of color carrier mass to oxidizing agent depends on the concentration of the oxidizing agent and is usually about 5: 1 to 1: 2, preferably 1: 1, the content of oxidizing agent in the ready-to-use preparation preferably being about 0.5 to 8 percent by weight, in particular 1 to 4 percent by weight.
  • the ready-to-use colorant is allowed to act on the keratin fiber (for example human hair) at 15 to 50 ° C. for about 10 to 45 minutes, preferably for about 15 to 30 minutes, and the fiber is then rinsed with Water out. If necessary, this rinse is washed with a shampoo and possibly rinsed with a weak organic acid, such as tartaric acid. Finally, the keratin fiber is dried.
  • the keratin fiber for example human hair
  • the color carrier composition according to the invention has a uniform consistency and a very cosmetic pearlescent appearance.
  • a colorant produced with the color carrier composition according to the invention fulfills the requirements made with regard to the adhesive properties, the application behavior and the viscosity adjustment in an outstanding manner and offers an extremely cosmetic appearance due to the pearlescent character.
  • a significantly improved care result after rinsing is achieved compared to known colorants.
  • Another object of the present application is the use of a combination of
  • 50 g of the above pearlescent color carrier mass are mixed immediately before use with 50 g of a ⁇ percent aqueous hydrogen peroxide solution.
  • a homogeneous, pearlescent, cosmetic-looking dye preparation is obtained.
  • the mixture thus obtained is then applied to blonde hair. After an exposure time of 30 minutes at 40 ° C, the hair is rinsed with water and dried. The hair gets a medium blonde color.
  • Example 4 Hair dye with substantive dyes
  • the pearlescent cream-like coloring is applied to the washed and towel-dried blonde natural hair with gloves and left to act for 20 to 25 minutes.
  • the excess paint is washed out with water and shampoo. A beautiful, shiny reddish-blonde tone is achieved.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention a pour objet une substance porteuse de colorant, contenant une matière colorante oxydante et/ou non-oxydante, et (a) au moins un alcool gras de 14 à 60 atomes de carbone, (b) au moins un alcanolamide, (c) au moins un ester d'acide gras, et (d) au moins un tensio-actif anionique, le rapport pondéral alcool gras (a) à alcanolamide (b) étant compris entre 1 :4 et 4 :1. L'invention a également pour objet l'utilisation de la combinaison précitée des composants (a) à (b) pour l'obtention d'un effet de lustre nacré dans des substances porteuses de colorant et des matières colorantes pour fibres kératiniques.
EP04790862A 2004-02-05 2004-10-26 Matiere colorante pour fibres keratiniques leur conferant un lustre nacre Withdrawn EP1744814A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004005767A DE102004005767A1 (de) 2004-02-05 2004-02-05 Färbemittel für Keratinfasern mit Perlglanz
PCT/EP2004/012079 WO2005074873A1 (fr) 2004-02-05 2004-10-26 Matiere colorante pour fibres keratiniques leur conferant un lustre nacre

Publications (1)

Publication Number Publication Date
EP1744814A1 true EP1744814A1 (fr) 2007-01-24

Family

ID=34813146

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04790862A Withdrawn EP1744814A1 (fr) 2004-02-05 2004-10-26 Matiere colorante pour fibres keratiniques leur conferant un lustre nacre

Country Status (6)

Country Link
US (1) US20070101513A1 (fr)
EP (1) EP1744814A1 (fr)
JP (1) JP2007520499A (fr)
BR (1) BRPI0418501A (fr)
DE (1) DE102004005767A1 (fr)
WO (1) WO2005074873A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2889947B1 (fr) 2005-08-25 2012-03-09 Oreal Composition oxydante comprenant des composes insolubles, procedes mettant en oeuvre cette composition
FR2889945B1 (fr) * 2005-08-25 2011-07-29 Oreal Composition de coloration directe comprenant des composes oxygenes insolubles, procedes mettant en oeuvre cette composition.
US7905925B2 (en) 2005-08-25 2011-03-15 L'oreal S.A. Dye composition comprising at least one insoluble compound and processes using this composition
FR2940092B1 (fr) * 2008-12-19 2011-02-18 Oreal Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras amide ou ester
JP2013537165A (ja) * 2010-09-08 2013-09-30 ロレアル ケラチン繊維用化粧料組成物
EP2729115B1 (fr) * 2011-07-05 2016-12-28 L'oreal Composition tinctoriale comprenant un éther d'alcool gras alcoxylé et un alcool gras ou un ester d'acide gras
BR112013032002A2 (pt) 2011-07-05 2017-10-03 Oreal Composição para tingir fibras de queratina, método para tingir fibras de queratina e dispositivo de múltiplos compartimentos
FR2977482B1 (fr) 2011-07-05 2013-11-08 Oreal Composition de coloration mettant en oeuvre un ether a longue chaine d'un alcool gras alcoxyle et un polymere cationique, procedes et dispositifs
FR2977480B1 (fr) * 2011-07-05 2013-07-05 Oreal Composition de coloration comprenant un ether d'alcool gras alcoxyle et un alcool gras
US11446222B2 (en) * 2016-07-26 2022-09-20 L'oreal Composition for treating keratin fibers comprising an amphoteric or cationic polymer and neutralized fatty acid
JP7184314B2 (ja) * 2017-10-31 2022-12-06 ホーユー株式会社 染毛用第１剤組成物

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US4728457A (en) * 1986-08-25 1988-03-01 The Proctor & Gamble Company Process for making a silicone-containing shampoo
ATE125689T1 (de) * 1989-06-21 1995-08-15 Colgate Palmolive Co Haarpflegeshampoo, das als bestandteil einen langketten-alkohol enthält.
US4997641A (en) * 1990-04-09 1991-03-05 Colgate-Palmolive Company Hair conditioning shampoo containing C6 -C10 alkyl sulfate or alkyl alkoxy sulfate
KR100292708B1 (ko) * 1995-10-16 2001-10-26 데이비드 엠 모이어 콘디쇼닝샴푸조성물
EP1028697A2 (fr) * 1997-09-17 2000-08-23 The Procter & Gamble Company Compositions de soins des cheveux, contenant des azurants optiques et des tonifiants capillaires
FR2803196B1 (fr) * 1999-12-30 2002-03-15 Oreal Composition pour la teinture d'oxydation des fibres keratiniques comprenant un alcool gras ayant plus de vingt atomes de carbone et un tensioactif non-ionique oxyalkylene de hlb superieure a 5
DE10016497A1 (de) * 2000-04-01 2001-10-18 Goldwell Gmbh Verfahren und Zusammensetzung zum oxidativen Färben von menschlichen Haaren
DE10102005A1 (de) * 2001-01-18 2002-07-25 Cognis Deutschland Gmbh Perlglanzmittel
US6608011B2 (en) * 2001-06-11 2003-08-19 Colgate-Palmolive Company Shampoos with behenyl-alcohol
EP1293192A3 (fr) * 2001-09-12 2003-05-02 KPSS-Kao Professional Salon Services GmbH Teinture pour cheveux et procédé de teinture pour la chevelure humaine
EP1366752A1 (fr) * 2002-05-28 2003-12-03 Kao Corporation Composition pour la coloration des cheveux
DE60309121T2 (de) * 2002-12-10 2007-08-23 Kao Corp. Wässrige Haarreinigungszusammensetzung

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Title
None *
See also references of WO2005074873A1 *

Also Published As

Publication number Publication date
US20070101513A1 (en) 2007-05-10
DE102004005767A1 (de) 2005-09-01
WO2005074873A1 (fr) 2005-08-18
BRPI0418501A (pt) 2007-05-22
JP2007520499A (ja) 2007-07-26

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