EP1704611A1 - Structure for reducing internal circuit of fuel cell - Google Patents

Structure for reducing internal circuit of fuel cell

Info

Publication number
EP1704611A1
EP1704611A1 EP03777428A EP03777428A EP1704611A1 EP 1704611 A1 EP1704611 A1 EP 1704611A1 EP 03777428 A EP03777428 A EP 03777428A EP 03777428 A EP03777428 A EP 03777428A EP 1704611 A1 EP1704611 A1 EP 1704611A1
Authority
EP
European Patent Office
Prior art keywords
fuel
air
paths
manifold
air side
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03777428A
Other languages
German (de)
French (fr)
Inventor
Tae-Hee Cho
Myung-Seok Wooseong Apt. 107-103 PARK
Hong Seongwon Apt. 308-2204 CHOI
Kyu-Jung Hyundaitown-House Na-101 KIM
Myeong-Ho Cheonggu Apt. 104-1401 LEE
Cheol-Hwan Booyoung Apt. 1205-703 KIM
Yong-Jun LG Electronics Dormitory H-324 HWANG
Seung-Tae Ko
Seong-Geun Namseong Hanvit Apt. HEO
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Electronics Inc
Original Assignee
LG Electronics Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Electronics Inc filed Critical LG Electronics Inc
Publication of EP1704611A1 publication Critical patent/EP1704611A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2484Details of groupings of fuel cells characterised by external manifolds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the present invention relates to a fuel cell, and in particular to an
  • Fuel cell has been presented as a substitute for fossil fuel, and it
  • Figure 1 illustrates an example of a fuel cell. As depicted in Figure 1 ,
  • the hydrogen ions are moved to the air electrode 12 through the
  • One unit fuel cell is constructed with the structure.
  • a fuel cell in order to generate greater electric energy, a fuel cell can be constructed by combining
  • fuel cells can be classified into various kinds according to
  • Figure 2 is a sectional view illustrating an example of a fuel cell using
  • FIG. 3 is a plane view illustrating a stack of the fuel cell
  • Figure 4 is a plane view
  • Figure 5 is a plane view
  • M.E.As membrane electrode assembly 130 are respectively inserted between the bipolar plate 100 and the monopolar plate 110, 120, and an end
  • end plate 140 are fixedly combined by fastening means 150, and
  • monopolar plates 110, 120 are arranged on the same line, and the air side
  • inflow paths 105, 113 are arranged on the same line with the fuel side inflow
  • a fuel side electrode 132 contacted to fuel is
  • side electrode 133 contacted to air is formed on the other side of the
  • electrolyte layer 131 In the M.E.As 130, the same electrode is arranged on
  • first and second manifolds 160, 170 are
  • a fuel side space 162 and an air side space 163 are respectively formed in a
  • air side inflow paths 105, 113 are formed on the bottom of the air side space
  • space 173 are respectively formed in a body unit 171 having a certain
  • the fuel side space 162 of the first manifold is connected to a fuel
  • side space 172 of the second manifold is connected to the fuel tank by an
  • the second manifold flows into the fuel tank through the reproducing means
  • the fuel connects the stacked unit cells electrically so
  • reducing internal circuit of a fuel cell includes adjacently stacked unit cells; a
  • a stack consisting of adjacently stacked unit cells; a first and a
  • first insulating member combined between the stack and the first manifold so
  • connection path of the first manifold and a second insulating member
  • Figure 1 is a sectional view illustrating a general fuel cell
  • Figure 2 is a sectional view illustrating an example of the
  • Figure 3 is a plane view illustrating a stack of a fuel cell in
  • Figures 4 and 5 are plane views respectively illustrating partial-
  • Figure 6 is a sectional view illustrating a fuel cell having a structure
  • Figure 7 is a plane view illustrating the fuel cell in Figure 6;
  • Figure 8 is a sectional view illustrating a fuel cell having an internal
  • Figure 9 is a sectional view illustrating the fuel cell taken along a line
  • Figure 10 is a sectional view illustrating the fuel cell taken along a
  • Figure 11 is a graph showing comparison results of unit cells in
  • Figure 6 is a sectional view illustrating a fuel cell having an internal
  • Figure 7 is a plane view illustrating the fuel cell in
  • invention includes adjacently stacked unit cells (C); a fuel side distributing
  • the fuel side distributing means is a fuel side distributing pipe 240 for
  • distributing pipe 240 distributes fuel to each fuel side inflow path of the unit
  • the air side distributing means is an air side distributing pipe 280 for
  • a fuel inflow pipe 250 is connected to the fuel side distributing
  • inflow pipe 290 in which external air flows is combined with the air side
  • the unit cell (C) consists of a bipolar plate 200; monopolar plates
  • channels 202, 203 are respectively formed
  • inflow paths 204, 205 for transmitting fuel and air respectively to the channels
  • the fuel side inflow path 204 and the air side outflow path 207 are
  • the air side inflow path 205 are formed on another surface (opposed to the above-mentioned surface) of the plate 201.
  • the fuel side outflow path 206 are arranged diagonally, and the air side inflow
  • a channel 212, 222 is formed on a
  • the monopolar plates 210, 220 are respectively arranged on both
  • monopolar plate 210 faces the channel 203 in which air flows of the bipolar
  • the channel 222 of the monopolar plate 220 faces the channel 202 in which
  • air side electrode 233 in which air is contacted is formed on the other side of
  • the M.E.A 230 is inserted between the bipolar plate
  • the fuel side distributing pipe 240 connects the fuel side inflow path
  • the fuel side distributing pipe 240 is curved-formed.
  • fuel inflow pipe 250 is connected to the fuel side distributing pipe 240, and
  • the fuel inflow pipe 250 is connected so as to be arranged on the center of
  • the fuel inflow pipe 250 is connected to a fuel tank 260 for storing
  • a first pump 270 for pumping fuel is installed on the fuel inflow pipe 250,
  • the first pump 270 is arranged between the fuel side distributing pipe 240
  • Fuel of the fuel tank is an electrolyte solution.
  • the fuel side distributing pipe 240 and the fuel inflow pipe 250 are identical to each other.
  • An outflow pipe 208 is respectively combined with the fuel side
  • the air side distributing pipe 290 connects the air side inflow path
  • the air inflow pipe 251 is connected
  • air side distributing pipe 290 and the air inflow pipe 251 are made of an
  • a second pup 271 for pumping air is installed on the air inflow pipe 251.
  • An outflow pipe 281 is respectively connected with the air side
  • fuel in the fuel tank 260 flows into the fuel side distributing pipe 240
  • the electrons are moved to the air side electrode 233 through the bipolar
  • each unit cell (C) flows through the channels 203, 222, electron-
  • connection of the fuel can be restrained by the fuel side distributing pipe 240.
  • the fuel is cut off, and accordingly electric leakage can be prevented.
  • Figure 8 is a sectional view illustrating a fuel cell having an internal
  • Figure 9 is a sectional view illustrating the fuel cell taken
  • Figure 10 is a sectional view illustrating the
  • invention includes a stack consisting of stacked unit cells (C); a first and a
  • first manifold so as to have fuel side through holes for connecting the fuel
  • unit cell (C) with the air side connection path of the second manifold.
  • the stack consists of two unit cells (C).
  • monopolar In the unit cell (C), monopolar
  • the unit cell (C) consists of a bipolar plate, a monopolar plate and a
  • the bipolar plate 300, the monopolar plates 310, 320 and the M.E.A The bipolar plate 300, the monopolar plates 310, 320 and the M.E.A
  • Reference numerals 301 , 311 , 312 are plates, 302 and 303 are
  • channels, 304 and 313 are fuel side inflow paths, 305 and 323 are air side
  • inflow paths, 306 and 314 are fuel side outflow paths, 307 and 324 are air
  • reference numeral 331 is an electrolyte layer
  • 332 is a fuel side electrode
  • 333 is an air side electrode
  • 420 is an end
  • a fuel side connection path 342 is formed on the first manifold 340.
  • air side connection path 343 is formed on the other side of the body 341.
  • fuel side connection path 342 is formed so as to connect fuel side inflow paths 304, 313 of adjacent two unit cells (C).
  • 343 is formed so as to connect air side outflow paths 307, 324 of the two unit cells (C).
  • connection path 343. The part including the fuel side connection path 342
  • a fuel side connection path 352 is
  • an air side connection path 353 is formed on the other side of the
  • the fuel side connection path 352 is formed so as to connect fuel
  • connection path 353 is formed so as to connect air side inflow paths 305, 323
  • connection path 353 The part including the fuel side connection path 352
  • the first and second manifolds 340, 350 can be made of an
  • the first and second manifolds 340, 350 are fixedly combined by
  • the first and second insulating members 360, 370 have a
  • a fuel inflow pipe 390 connected to the fuel tank 380 is connected
  • outflow pipe 391 for discharging air is connected with the air side connection
  • a first pump 392 is installed on the fuel inflow pipe 390, and fuel
  • a fuel outflow pipe 393 for discharging fuel is connected with the fuel
  • a second pump 395 is installed on the air inflow pipe 394.
  • each unit cell (C) flows through the channel 303, 322, electron-
  • connection path 343 and the outflow pipe 391 of the first manifold The fuel
  • unit cells (C) is unstable by height of the fuel side through holes 361 , 371 of
  • first and second insulating members perform functions of an insulating pipe
  • Figure 11 is a graph showing comparison results of unit cells in
  • the unit cell has a structure having little electric leakage

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

In a structure for reducing internal circuit of a fuel cell including adjacently stacked unit cells (C), a fuel side distributing means for connecting each fuel side inflow path (204) of the unit cells and insulating them; and an air side distributing means for connecting each air side inflow path (205) of the unit cells, electric connection among the stacked plural unit cells by fuel as an electrolyte solution and electric leakage by additional parts can be minimized.

Description

STRUCTURE FOR REDUCING INTERNAL CIRCUIT OF
FUEL CELL
TECHNICAL FIELD The present invention relates to a fuel cell, and in particular to an
structure for reducing internal circuit of a fuel cell capable of minimizing an
internal circuit occurred among plural stacked unit cells.
BACKGROUND ART Fuel cell has been presented as a substitute for fossil fuel, and it
converts chemical energy generated by oxidation of fuel such as hydrogen
into electric energy directly.
Figure 1 illustrates an example of a fuel cell. As depicted in Figure 1 ,
in the fuel cell, when hydrogen-included fuel and air as a oxidant are supplied
to a fuel electrode (anode) 11 and an air electrode (cathode) 12 arranged on
both sides of an electrolyte layer 10 respectively, electrochemical oxidation
reaction occurs on the fuel electrode 11 , hydrogen ions and electrons are
emitted, the hydrogen ions are moved to the air electrode 12 through the
electrolyte layer 10, and the electrons are moved to the air electrode 12
through a load 20 connecting the fuel electrode 11 to the air electrode 12.
Simultaneously electrochemical reduction reaction occurs on the air
electrode 12, and heat and by-products are generated while the hydrogen
ions are combined with oxygen. Herein, current is generated while the electrons emitted from the fuel electrode 11 are moved to the air electrode 12.
One unit fuel cell is constructed with the structure. Herein, in order to generate greater electric energy, a fuel cell can be constructed by combining
plural unit cells. In addition, fuel cells can be classified into various kinds according to
kinds of fuel, operational temperature and catalyzers, etc.
When fuel of hydrogen group such as NaBH4, KBH4, LiA1H4, KH,
NaH, etc. is dissolved in an alkali aqueous solution, the fuel becomes an
electrolyte solution, electrons generated with hydrogen ions are moved
through the electrolyte solution (fuel).
Figure 2 is a sectional view illustrating an example of a fuel cell using
the electrolyte solution as fuel in accordance with the conventional art, Figure
3 is a plane view illustrating a stack of the fuel cell, Figure 4 is a plane view
illustrating a first manifold of the fuel cell, and Figure 5 is a plane view
illustrating a second manifold of the fuel cell.
As depicted in Figures 2 ~ 5, in the fuel cell, monopolar plates 110,
120 are respectively arranged on both sides of one bipolar plate 100, two
M.E.As (membrane electrode assembly) 130 are respectively inserted between the bipolar plate 100 and the monopolar plate 110, 120, and an end
plate 140 is respectively arranged on both sides of the monopolar plates 110,
120. The bipolar plate 100, the monopolar plate 110, 120, the M.E.A 130 and
the end plate 140 are fixedly combined by fastening means 150, and
accordingly a stack is constructed. In the bipolar plate 100, fluid flowing channels 102, 103 are
respectively formed on both sides of a plate 101 having a certain thickness
and area; and inflow paths 104, 105 and outflow paths 106, 107 in which fuel
and air flow respectively are formed so as to be connected with the channels
102, 103.
In the monopolar plates 110, 120, fluid flowing channels 112, 122 are
formed on a side of plates 111 , 121 having a certain thickness and area; and
inflow paths 113, 123 and outflow paths 114, 124 connected to the channels
112, 122 are formed on the plates 111 , 121 so as to receive and discharge a
fluid.
The fuel side inflow paths 104, 123 of the bipolar plate 100 and the
monopolar plates 110, 120 are arranged on the same line, and the air side
inflow paths 105, 113 are arranged on the same line with the fuel side inflow
paths 104, 123 so as to have a certain interval. In the M.E.A 130, a fuel side electrode 132 contacted to fuel is
formed on a side of the electrolyte layer 131 having a certain area, and an air
side electrode 133 contacted to air is formed on the other side of the
electrolyte layer 131. In the M.E.As 130, the same electrode is arranged on
the same position. A first manifold 160 for distributing fuel and air so as to make them
flow into the fuel side inflow paths 104, 123 and the air side inflow paths 105,
113 respectively is arranged on a side of the stack, a second manifold 170 for
gathering fuel and air to be respectively discharged to the fuel side outflow paths 106, 124 and the air side outflow paths 107, 114 is arranged on the
other side of the stack, and the first and second manifolds 160, 170 are
fixedly combined by additional fastening means 180. In the first manifold 160,
a fuel side space 162 and an air side space 163 are respectively formed in a
body unit 162 having a certain thickness and rectangular area, through holes
164 connected with the fuel side inflow paths 104, 123 are formed on the
bottom of the fuel side space 162, and through holes 165 connected with the
air side inflow paths 105, 113 are formed on the bottom of the air side space
163. And, in the second manifold 170, a fuel side space 172 and an air side
space 173 are respectively formed in a body unit 171 having a certain
thickness and rectangular area, through holes 174 connected with the fuel
side outflow paths 106, 124 are formed on the bottom of the fuel side space
172, and through holes 175 connected with the air side outflow paths 107,
114 are formed on the bottom of the air side space 173. The fuel side space 162 of the first manifold is connected to a fuel
tank (not shown) and a pump (not shown) by a pipe (not shown), and the fuel
side space 172 of the second manifold is connected to the fuel tank by an
additional reproducing means (not shown).
In the above-described fuel cell, when fuel in the fuel tank flows into
the fuel side space 162 of the first manifold, simultaneously air flows into the
air side space 163 of the first manifold. The fuel in the fuel side space 162
flows into the bipolar plate 100 and the inflow paths 104, 123 of the
monopolar plate 120 of the stack through the through holes 164. When the fuel flows in the channels 102, 122, electrochemical
oxidation occurs on the fuel side electrode 132 of the M.E.A 130, hydrogen
ions and electrons are generated, the hydrogen ions are moved to the air
side electrode 133 through the electrolyte layer 131 of the M.E.A, and the
electrons are moved to the air side electrode 133 through the bipolar plate
100 or the monopolar plates 110, 12O. Simultaneously, when the air in the air
side space 163 of the first manifold flows into the channels 103, 112 through
the through holes 165 in the air side space, each bipolar plate 100 and the
inflow paths 105, 113 of the monopolar plate 110 of the stack,
electrochemical reduction reaction occurs with the hydrogen ions on the air
side electrode 133 of the M.E.A.
In the meantime, the fuel discharged into the fuel side space 172 of
the second manifold flows into the fuel tank through the reproducing means
and is supplied again to the stack. And, when a load is connected between the monopolar plates 110,
120, electric energy is generated while current flows through the load by
electric potential difference.
However, in the conventional structure, because the electrolyte
solution is used as fuel, the fuel connects the stacked unit cells electrically so
as to construct an internal circuit, electric leakage may occur, and accordingly
electrical loss may occur. TECHNICAL GIST OF THE PRESENT INVENTION In order to solve the above-described problem, it is an object of the present invention to provide a structure for reducing internal circuit of a fuel
cell capable of minimizing electric leakage occurred among plural stacked- unit cells.
In order to achieve the above-mentioned object, a structure for
reducing internal circuit of a fuel cell includes adjacently stacked unit cells; a
fuel side distributing means for connecting each fuel side inflow path of the
unit cells and insulating them electrically; and an air side distributing means
for connecting each air side inflow path of the unit cells.
In addition, a structure for reducing internal circuit of a fuel cell
includes a stack consisting of adjacently stacked unit cells; a first and a
second manifolds respectively arranged on both sides of the stack so as to
have fuel side connection paths for connecting fuel side paths of the unit cells
and air side connection paths for connecting air side paths of the unit cells; a
first insulating member combined between the stack and the first manifold so
as to have fuel side through holes for connecting the fuel side paths of the
unit cell with the fuel side connection path of the first manifold and air side
through holes for connecting the air side paths of the unit cell with the air side
connection path of the first manifold; and a second insulating member
combined between the stack and the second manifold so as to have fuel side
through holes for connecting the fuel side paths of the unit cell with the fuel
side connection path of the second manifold and air side through holes for connecting the air side paths of the unit cell with the air side connection path
of the second manifold.
BRIEF DESCRIPTION OF DRAWINGS The accompanying drawings, which are included to provide a further
understanding of the invention and are incorporated in and constitute a part
of this specification, illustrate embodiments of the invention and together with
the description serve to explain the principles of the invention. In the drawings: Figure 1 is a sectional view illustrating a general fuel cell;
Figure 2 is a sectional view illustrating an example of the
conventional fuel cell;
Figure 3 is a plane view illustrating a stack of a fuel cell in
accordance with the conventional art; Figures 4 and 5 are plane views respectively illustrating partial-
exploded first and second manifolds of the fuel cell in accordance with the
conventional art;
Figure 6 is a sectional view illustrating a fuel cell having a structure
for reducing internal circuit of a fuel cell in accordance with a first
embodiment of the present invention;
Figure 7 is a plane view illustrating the fuel cell in Figure 6; Figure 8 is a sectional view illustrating a fuel cell having an internal
circuit reducing structure in accordance with a second embodiment of the present invention;
Figure 9 is a sectional view illustrating the fuel cell taken along a line
A-B in Figure 8;
Figure 10 is a sectional view illustrating the fuel cell taken along a
line C-D in Figure 8; and
Figure 11 is a graph showing comparison results of unit cells in
accordance with the first and second embodiments of the present invention.
DETAILED DESCRIPTION OF THE INVENTION Hereinafter, the preferred embodiments of the present invention will
be described with reference to accompanying drawings.
First, a structure for reducing internal circuit of a fuel cell in
accordance with a first embodiment of the present invention will be described.
Figure 6 is a sectional view illustrating a fuel cell having an internal
circuit reducing structure in accordance with a first embodiment of the
present invention, and Figure 7 is a plane view illustrating the fuel cell in
Figure 6.
As depicted in Figures 6 and 7, the structure for reducing internal
circuit of a fuel cell in accordance with the first embodiment of the present
invention includes adjacently stacked unit cells (C); a fuel side distributing
means for connecting each fuel side inflow path of the unit cells (C) and
insulating them (electrically); and an air side distributing means for
connecting each air side inflow path 205 of the unit cells (C). The fuel side distributing means is a fuel side distributing pipe 240 for
connecting each fuel side inflow path of the unit cells (C). The fuel side
distributing pipe 240 distributes fuel to each fuel side inflow path of the unit
cells (C) and simultaneously forms electrically insulating space. The air side distributing means is an air side distributing pipe 280 for
connecting each air side inflow path of the unit cells (C).
And, a fuel inflow pipe 250 is connected to the fuel side distributing
pipe 240, and the fuel inflow pipe 250 is connected to a fuel tank 260. An air
inflow pipe 290 in which external air flows is combined with the air side
distributing means 280.
The unit cell (C) consists of a bipolar plate 200; monopolar plates
210, 220 respectively arranged on both sides of the bipolar plate 200; and a
M.E.A 230 respectively inserted between the bipolar plate 200 and the
monopolar plate 210, 220. The bipolar plate 200, the two monopolar plates
210, 220 and the M.E.A 230 construct one unit cell (C).
In the bipolar plate 200, channels 202, 203 are respectively formed
on both sides of a plate 201 having a certain thickness and rectangular area,
inflow paths 204, 205 for transmitting fuel and air respectively to the channels
202, 203 are formed on the plate 201 , and outflow paths 206, 207 for
discharging the fuel and air of the channels 202, 203 are formed on the plate
201. The fuel side inflow path 204 and the air side outflow path 207 are
formed on a surface of the plate 201 , and the fuel side outflow path 206 and
the air side inflow path 205 are formed on another surface (opposed to the above-mentioned surface) of the plate 201. The fuel side inflow path 204 and
the fuel side outflow path 206 are arranged diagonally, and the air side inflow
path 205 and the air side outflow path 207 are arranged diagonally.
In the monopolar plate 210, 220, a channel 212, 222 is formed on a
side of a surface 211 , 221 having a certain thickness and rectangular area,
and an inflow path 213, 223 and an outflow path 214, 224 for receiving and
discharging a fluid into/from the channel 212, 222 are formed on the plate
211 , 221. The monopolar plates 210, 220 are respectively arranged on both
sides of the bipolar plate 200 so as to make the channels 212, 222 face the
channels 202, 203 of the bipolar plate. Herein, when the channel 212 of the
monopolar plate 210 faces the channel 203 in which air flows of the bipolar
plate 200, fuel flows in the channel 212 of the monopolar plate 210. When
the channel 222 of the monopolar plate 220 faces the channel 202 in which
fuel flows of the bipolar plate 200, air flows in the channel 222 of the
monopolar plate 220.
In the M.E.A 230, a fuel side electrode 232 on which fuel is contacted
is formed on a side of an electrolyte layer 231 having a certain area, and an
air side electrode 233 in which air is contacted is formed on the other side of
the electrolyte layer 231. The M.E.A 230 is inserted between the bipolar plate
200 and the monopolar plate 210, 220 so as to make the electrodes 232, 233
be arranged in the same direction.
The fuel side distributing pipe 240 connects the fuel side inflow path
204 of the bipolar plate to the fuel side inflow path 213 of the monopolar plate in which fuel flows. The fuel side distributing pipe 240 is curved-formed. The
fuel inflow pipe 250 is connected to the fuel side distributing pipe 240, and
the fuel inflow pipe 250 is connected so as to be arranged on the center of
the fuel side distributing pipe 240. The fuel inflow pipe 250 is connected to a fuel tank 260 for storing
fuel, a first pump 270 for pumping fuel is installed on the fuel inflow pipe 250,
and the first pump 270 is arranged between the fuel side distributing pipe 240
and the fuel tank 260. Fuel of the fuel tank is an electrolyte solution.
The fuel side distributing pipe 240 and the fuel inflow pipe 250 are
made of an insulating material.
An outflow pipe 208 is respectively combined with the fuel side
outflow path 206 of the bipolar plate 200 and the fuel side outflow path 214 of
the monopolar plate 210 adjacent to the fuel side outflow path 206 and
having fuel. The air side distributing pipe 290 connects the air side inflow path
205 of the bipolar plate 200 with the air side inflow path 223 of the monopolar
plate 220 adjacent to the air side inflow path 205 and having air. The air side
distributing pipe 290 is curved-formed. The air inflow pipe 251 is connected
to the air side distributing pipe 290, and the air inflow pipe 251 is connected
so as to be arranged on the center of the air side distributing pipe 290. The
air side distributing pipe 290 and the air inflow pipe 251 are made of an
insulating material.
A second pup 271 for pumping air is installed on the air inflow pipe 251.
An outflow pipe 281 is respectively connected with the air side
outflow path 207 of the bipolar plate 200 and the air side outflow path 224 of
the monopolar plate 220 adjacent to the air side outflow path 207 and having
air.
The operation of the structure for reducing internal circuit of a fuel
cell will be described.
First, when the first pump 270 and the second pump 271 are
operated, fuel in the fuel tank 260 flows into the fuel side distributing pipe 240
through the fuel inflow pipe 250. The fuel in the fuel side distributing pipe 240
is distributed and flows into the fuel side inflow paths 204, 213 of each unit
cell (C), the fuel in the fuel side inflow paths 204, 213 flows through the
channels 202, 212. While the fuel flows through the channels 202, 212,
electrochemical oxidation occurs by the fuel side electrode 232 of the M.E.A,
hydrogen ions and electrons are generated, the hydrogen ions are moved to
the air side electrode 233 through the electrolyte layer 231 of the M.E.A, and
the electrons are moved to the air side electrode 233 through the bipolar
plate 200.
Simultaneously, when external air flows into the air side distributing
pipe 290 through the air inflow pipe 251 and flows into the air side inflow path
205, 223 of each unit cell (C). While the air in the air side inflow path 205,
223 of each unit cell (C) flows through the channels 203, 222, electron-
chemical oxidation occurs on the air side electrode 233 of the M.E.A with the hydrogen ions.
The fuel passing the channel 202, 212 of each unit cell (C) is
respectively discharged through the fuel side discharge path 206, 214 and
the discharge pipe 280. The air passing the channel 203, 222 of each unit
cell (C) is discharged through the air side outflow path 207, 224 and the
outflow pipe 281. The fuel discharged through the outflow pipe 280 passes
an additional reproducing means (not shown) and flows again into the fuel
tank 260.
When a load is connected between the monopolar plates 210, 220,
electric energy is generated while current flows through the load by the
electric potential difference.
In that process, because the fuel supplied from the fuel tank 260 is
distributed through the fuel side distributing pipe 240 and flows into the fuel
side electrode 232 of each unit cell (C), electric leakage occurred by electric
connection of the fuel can be restrained by the fuel side distributing pipe 240.
In more detail, because the fuel as the electrolyte solution flowing into each
unit cell (C) is connected through the fuel side distributing pipe 240 having a
certain length, electric connection by the fuel is unstable, and accordingly
electric leakage can be minimized. In addition, the fuel passing each unit cell (C) is respectively
discharged through an additional discharge pipe 280, electric connection by
the fuel is cut off, and accordingly electric leakage can be prevented.
In the meantime, in the present invention, by installing respectively a pump 270, 271 for pumping fuel and air, the number of pumps can be
minimized.
And, an internal ground current reducing structure of a fuel cell in
accordance with a second embodiment of the present invention will be
described.
Figure 8 is a sectional view illustrating a fuel cell having an internal
circuit reducing structure in accordance with a second embodiment of the
present invention, Figure 9 is a sectional view illustrating the fuel cell taken
along a line A-B in Figure 8, and Figure 10 is a sectional view illustrating the
fuel cell taken along a line C-D in Figure 8.
As depicted in Figures 8 - 10, the structure for reducing internal
circuit of a fuel cell in accordance with the second embodiment of the present
invention includes a stack consisting of stacked unit cells (C); a first and a
second manifolds respectively arranged on both sides of the stack so as to
have a fuel side connection path for connecting fuel side paths of the unit
cells (C) and an air side connection path for connecting air side paths of the
unit cells (C); a first insulating member combined between the stack and the
first manifold so as to have fuel side through holes for connecting the fuel
side paths of the unit cell (C) with the fuel side connection path of the first
manifold and air side through holes for connecting the air side paths of the
unit cell (C) with the air side connection path of the first manifold; and a
second insulating member combined between the stack and the second
manifold so as to have fuel side through holes for connecting the fuel side paths of the unit cell (C) with the fuel side connection path of the second
manifold and air side through holes for connecting the air side paths of the
unit cell (C) with the air side connection path of the second manifold.
The stack consists of two unit cells (C). In the unit cell (C), monopolar
plates 310, 320 are respectively arranged on both sides of one bipolar plate
300, and a M.E.A 330 is respectively inserted between the bipolar plate 300
and the monopolar plate 310, 320.
The unit cell (C) consists of a bipolar plate, a monopolar plate and a
M.E.A. The bipolar plate 300, the monopolar plates 310, 320 and the M.E.A
330 have the same structure with the bipolar plate 200, the monopolar plates
210, 220 and the M.E.A 230 of the structure in accordance with the first
embodiment.
Reference numerals 301 , 311 , 312 are plates, 302 and 303 are
channels, 304 and 313 are fuel side inflow paths, 305 and 323 are air side
inflow paths, 306 and 314 are fuel side outflow paths, 307 and 324 are air
side outflow paths. In addition, reference numeral 331 is an electrolyte layer,
332 is a fuel side electrode, 333 is an air side electrode, and 420 is an end
plate. In the first manifold 340, a fuel side connection path 342 is formed on
a side of a body 341 having a certain thickness and rectangular area, and an
air side connection path 343 is formed on the other side of the body 341. The
fuel side connection path 342 is formed so as to connect fuel side inflow paths 304, 313 of adjacent two unit cells (C). The air side connection path
343 is formed so as to connect air side outflow paths 307, 324 of the two unit cells (C).
In modification of the first manifold 340, it is divided into a part
including the fuel side connection path 342 and a part including the air side
connection path 343. The part including the fuel side connection path 342
and the part including the air side connection path 343 are formed so as to
have a certain thickness and rectangular area.
In the second manifold 350, a fuel side connection path 352 is
formed on a side of a body 351 having a certain thickness and rectangular
area, and an air side connection path 353 is formed on the other side of the
body 351. The fuel side connection path 352 is formed so as to connect fuel
side outflow paths 306, 314 of adjacent two unit cells (C). The air side
connection path 353 is formed so as to connect air side inflow paths 305, 323
of the two unit cells (C).
In modification of the second manifold 350, it is divided into a part
including the fuel side connection path 352 and a part including the air side
connection path 353. The part including the fuel side connection path 352
and the part including the air side connection path 353 are formed so as to
have a certain thickness and rectangular area.
The first and second manifolds 340, 350 can be made of an
insulating material, herein, usage of the first and second insulating members
360, 370 can be excluded. The first and second manifolds 340, 350 are fixedly combined by
additional fastening means 400.
The first and second insulating members 360, 370 have a
rectangular shape and a certain thickness, and a fuel side through hole 361 ,
371 and an air side through hole 362, 372 are respectively formed in them.
When the fuel side through hole 361 , 371 and the air side through hole 362,
372 are filled with fuel, there is an insulating space.
A fuel inflow pipe 390 connected to the fuel tank 380 is connected
with the fuel side connection path 342 of the first manifold 340, and an
outflow pipe 391 for discharging air is connected with the air side connection
path 343. A first pump 392 is installed on the fuel inflow pipe 390, and fuel
stored in the fuel tank 380 is an electrolyte solution.
A fuel outflow pipe 393 for discharging fuel is connected with the fuel
side connection path 352 of the second manifold 350, and an air inflow pipe
394 in which external air flows is connected with the air side connection path
353. A second pump 395 is installed on the air inflow pipe 394.
Hereinafter, the operation of the structure for reducing internal circuit
of a fuel cell in accordance with the second embodiment of the present
invention will be described. First, fuel in the fuel tank 380 flows into the fuel side connection path
342 of the first manifold through the fuel inflow pipe 390 and flows into the
fuel side inflow path 304, 313 of each unit cell (C) of the stack, and the fuel
in the fuel side inflow path 304, 313 flows through the channels 302, 312. While the fuel flows through the channel 302, 312, electrochemical oxidation
reaction occurs by the fuel side electrode 332 of the M.E.A, hydrogen ions
and electrons are generated, the hydrogen ions are moved to the air side
electrode 333 through the electrolyte layer 331 of the M.E.A, and the
electrons are moved to the air side electrode 333 through the bipolar plate
300.
Simultaneously, when external air flows into the air side connection
path 353 through the air inflow pipe 394 and flows into the air side inflow path
305, 323 of each unit cell (C). While the air in the air side inflow path 305,
323 of each unit cell (C) flows through the channel 303, 322, electron-
chemical oxidation reaction occurs on the air side electrode 333 of the M.E.A
with the hydrogen ions.
The fuel passing the channel 302, 312 of each unit cell (C) is
respectively discharged through the fuel side discharge path 306, 314, the
discharge pipe 393 and the fuel side connection path 352 of the second
manifold. The air passing the channels 303, 322 of each unit cell (C) is
discharged through the air side outflow paths 307, 324, the air side
connection path 343 and the outflow pipe 391 of the first manifold. The fuel
discharged through the outflow pipe 393 passes an additional reproducing
means (not shown) and flows again into the fuel tank 380.
When a load is connected between the monopolar plates 310, 320,
electric energy is generated while current flows through the load by the
electric potential difference. In that structure, because the first and second insulating members
360, 370 are combined between the first and second manifolds 340, 350,
electric leakage performed by the stack, the first manifold 340, the stack and
the second manifold 350 can 'be prevented. In addition, by the first and second insulating members 360, 370,
electric leakage occurred by connection of the fuel as the electrolyte can be
minimized. In more detail, the electric connection of the fuel formed with the
fuel side connection path 342 of the first manifold, the fuel side connection
path 352 of the second manifold and the paths in which the fuel flows of the
unit cells (C) is unstable by height of the fuel side through holes 361 , 371 of
the first and second insulating members 360, 370, and accordingly leakage
can be minimized. In more detail, the fuel side through holes 361 , 371 of the
first and second insulating members perform functions of an insulating pipe,
electric connection by the fuel is unstable, and leakage can be minimized. In the meantime, when the first and second manifolds 340, 350 are
made of an insulating material, electric connection by the fuel is unstable,
and accordingly leakage can be minimized.
Figure 11 is a graph showing comparison results of unit cells in
accordance with the first and second embodiments of the present invention. As depicted in Figure 11 , in the first and second embodiments, it can
be known electric loss due to electric leakage is small in comparison with a
general unit cell. The unit cell has a structure having little electric leakage
caused by fuel and additional parts. INDUSTRIAL APPLICABILITY
As described-above, in the a structure for reducing internal circuit of
a fuel cell in accordance with the present invention, among stacked plural
unit cells, by minimizing electric connection by fuel as an electrolyte solution
and electric leakage occurred by electric connection by additional parts,
electric energy efficiency of a unit cell can be improved.

Claims

1. A structure for reducing internal circuit of a fuel cell, comprising: adjacently stacked unit cells; a fuel side distributing means for connecting each fuel side inflow
path of the unit cells and insulating them electrically; and an air side distributing means for connecting each air side inflow path
of the unit cells.
2. The structure of claim 1, wherein the fuel side distributing
means is a fuel side distributing pipe for connecting fuel side inflow paths of
the unit cells and forming an insulating space, and the fuel side distributing
pipe is made of an insulating material.
3. The structure of claim 1 , wherein the fuel side inflow paths
and the air side inflow paths are arranged so as to be opposite to each other.
4. The structure of claim 1 , wherein a pump for supplying fuel is
installed as the fuel side distributing means.
5. The structure of claim 1, wherein outflow pipes are
respectively connected with fuel side outflow paths of the unit cells.
6. The structure of claim 1 , wherein a pump for supplying air is
installed as the air side distributing means.
7. A structure for reducing internal circuit of a fuel cell, comprising: a stack consisting of adjacently stacked unit cells; a first and a second manifolds respectively arranged on both sides of
the stack so as to have fuel side connection paths for connecting fuel side
paths of the unit cells and air side connection paths for connecting air side
paths of the unit cells; a first insulating member combined between the stack and the first
manifold so as to have fuel side through holes for connecting the fuel side
paths of the unit cell with the fuel side connection path of the first manifold
and air side through holes for connecting the air side paths of the unit cell
with the air side connection path of the first manifold; and a second insulating member combined between the stack and the
second manifold so as to have fuel side through holes for connecting the fuel
side paths of the unit cell with the fuel side connection path of the second
manifold and air side through holes for connecting the air side paths of the
unit cell with the air side connection path of the second manifold.
8. The structure of claim 7, wherein the first and second insulating members respectively have a certain thickness so as to make
internal through holes thereof have an insulating space.
9. The structure of claim 7, wherein the first and second
manifolds are made of an insulating material.
10. The structure of claim 7, wherein the fuel side connection
path of the first manifold is formed so as to connect fuel side inflow paths of
adjacent two unit cells with each other, and the air side connection path of
the first manifold is formed so as to connect air side outflow paths of the two
unit cells with each other.
11. The structure of claim 7, wherein the first manifold is divided
into a part including the fuel side connection path and a part including the air
side connection path.
12. The structure of claim 7, wherein the fuel side connection
path of the second manifold is formed so as to connect fuel side outflow
paths of adjacent two unit cells with each other, and the air side connection
path of the second manifold is formed so as to connect air side inflow paths
of the two unit cells with each other.
13. The structure of claim 7, wherein the second manifold is divided into a part including the fuel side connection path and a part including
the air side connection path.
EP03777428A 2003-12-12 2003-12-12 Structure for reducing internal circuit of fuel cell Withdrawn EP1704611A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/KR2003/002731 WO2005057709A1 (en) 2003-12-12 2003-12-12 Structure for reducing internal circuit of fuel cell

Publications (1)

Publication Number Publication Date
EP1704611A1 true EP1704611A1 (en) 2006-09-27

Family

ID=34675619

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03777428A Withdrawn EP1704611A1 (en) 2003-12-12 2003-12-12 Structure for reducing internal circuit of fuel cell

Country Status (5)

Country Link
US (1) US20050130019A1 (en)
EP (1) EP1704611A1 (en)
CN (1) CN1701456A (en)
AU (1) AU2003286938A1 (en)
WO (1) WO2005057709A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102018219200A1 (en) 2018-11-12 2020-05-14 Audi Ag Fuel cell device
JP2022148754A (en) * 2021-03-24 2022-10-06 本田技研工業株式会社 fuel cell system

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4579788A (en) * 1983-10-18 1986-04-01 Institute Of Gas Technology High temperature fuel cell wet seal
US4849308A (en) * 1988-03-17 1989-07-18 The United States Of America As Represented By The United States Department Of Energy Manifold seal for fuel cell stack assembly
WO2002054519A1 (en) * 2000-12-28 2002-07-11 Mitsubishi Materials Corporation Fuel cell module and structure for gas supply to fuel cell
SE516741C2 (en) * 2001-02-27 2002-02-26 Cellkraft Ab Bipolar plate for fuel cell or electrochemical reactor and use of the plate in a fuel cell stack or electrochemical reactor
JP3826833B2 (en) * 2002-04-19 2006-09-27 トヨタ自動車株式会社 Fuel cell system and control method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2005057709A1 *

Also Published As

Publication number Publication date
WO2005057709A1 (en) 2005-06-23
CN1701456A (en) 2005-11-23
AU2003286938A1 (en) 2005-06-29
US20050130019A1 (en) 2005-06-16

Similar Documents

Publication Publication Date Title
KR100549683B1 (en) Solid polymer fuel cell assembly, fuel cell stack, and reaction gas supply method of fuel cell
US8415068B2 (en) Fuel cell
US7867666B2 (en) Fuel cell with triangular buffers for reactant gas and coolant
US20070178359A1 (en) Bipolar plate for fuel cell
US7569301B2 (en) Fuel cell
JP4820068B2 (en) Fuel cell stack
US7759014B2 (en) Fuel cell having a seal member
US7951508B2 (en) Fuel cell
US7572538B2 (en) Fuel cell
US7794891B2 (en) Fuel cell with interweaving current collector and membrane electrode assembly
JP2004319279A (en) Fuel cell
US20060003206A1 (en) Fuel cell
US20120231362A1 (en) Fuel cell
US20050130019A1 (en) Structure for reducing internal circuit of fuel cell
US20040038103A1 (en) Solid polymer electrolyte fuel cell assembly
KR101932803B1 (en) Separator, and Fuel cell stack comprising the same
US20110104584A1 (en) Metal supported solid oxide fuel cell
JP4304955B2 (en) Solid polymer electrolyte fuel cell
KR100823924B1 (en) Structure for reducing internal circuit of fuel cell
JP2007234315A (en) Fuel cell
EP1852929B1 (en) Solid oxide fuel cell
JP3906975B2 (en) Polymer electrolyte fuel cell
KR100622077B1 (en) Monopolar Cell Stack Structure
US20240250276A1 (en) Separator for fuel cell and fuel cell stack
US20250092538A1 (en) Cross-flow component for electrochemical device

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20060711

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR

RIN1 Information on inventor provided before grant (corrected)

Inventor name: HEO, SEONG-GEUN,NAMSEONG HANVIT APT.

Inventor name: HWANG, YONG-JUN,SAMSUNG JUTAEK 401

Inventor name: CHO, TAE-HEE

Inventor name: KIM, KYU-JUNG,HYUNDAITOWN-HOUSE NA-101

Inventor name: KO, SEUNG-TAE

Inventor name: PARK, MYUNG-SEOK,JUGONG APT. 1306-807

Inventor name: LEE, MYEONG-HO,CHEONGGU APT. 104-1401

Inventor name: CHOI, HONG,SAMSUNG RAEMIAN APT. 102-17014

Inventor name: KIM, CHEOL-HWAN,BOOYOUNG APT. 1205-703

DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20090701