EP1685193A4 - Dual cure reaction products of self-photoinitiating multifunctional acrylates with cycloaliphatic epoxy compounds - Google Patents
Dual cure reaction products of self-photoinitiating multifunctional acrylates with cycloaliphatic epoxy compoundsInfo
- Publication number
- EP1685193A4 EP1685193A4 EP04810830A EP04810830A EP1685193A4 EP 1685193 A4 EP1685193 A4 EP 1685193A4 EP 04810830 A EP04810830 A EP 04810830A EP 04810830 A EP04810830 A EP 04810830A EP 1685193 A4 EP1685193 A4 EP 1685193A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- oligomeric composition
- liquid oligomeric
- group
- dicarbonyl
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/24—Di-epoxy compounds carbocyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/13—Morphological aspects
- C08G2261/135—Cross-linked structures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/334—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/70—Post-treatment
- C08G2261/76—Post-treatment crosslinking
Definitions
- Michael polyacrylate resin also termed Michael oligomer, Michael adduct, or Michael addition product
- TMPTA Trimethylolpropane triacrylate
- DBU diazabicycloundecene
- EAA Ethyl acetoacetate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/712,044 US7041749B2 (en) | 2002-12-17 | 2003-11-14 | Dual cure reaction products of self-photoinitiating multifunction acrylates with cycloaliphatic epoxy compounds |
PCT/US2004/037807 WO2005048866A2 (en) | 2003-11-14 | 2004-11-12 | Dual cure reaction products of self-photoinitiating multifunctional acrylates with cycloaliphatic epoxy compounds |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1685193A2 EP1685193A2 (en) | 2006-08-02 |
EP1685193A4 true EP1685193A4 (en) | 2006-12-13 |
Family
ID=34619849
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04810830A Withdrawn EP1685193A4 (en) | 2003-11-14 | 2004-11-12 | Dual cure reaction products of self-photoinitiating multifunctional acrylates with cycloaliphatic epoxy compounds |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1685193A4 (en) |
JP (1) | JP2007511641A (en) |
KR (1) | KR20070097294A (en) |
CN (1) | CN1910234A (en) |
BR (1) | BRPI0416519A (en) |
CA (1) | CA2545998A1 (en) |
WO (1) | WO2005048866A2 (en) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4888766B2 (en) * | 2006-07-11 | 2012-02-29 | 日東電工株式会社 | Method for producing polyfunctional compound |
GB0700960D0 (en) * | 2007-01-18 | 2007-02-28 | 3M Innovative Properties Co | High strength epoxy adhesive and uses thereof |
CN102159642B (en) | 2008-07-23 | 2015-07-22 | 3M创新有限公司 | Two-part epoxy-based structural adhesives |
JP2011529118A (en) | 2008-07-23 | 2011-12-01 | スリーエム イノベイティブ プロパティズ カンパニー | Two-component epoxy structural adhesive |
JP5912041B2 (en) | 2008-07-23 | 2016-04-27 | スリーエム イノベイティブ プロパティズ カンパニー | Reactive liquid modifier |
CN102311520A (en) * | 2011-08-05 | 2012-01-11 | 大连方盛塑料有限公司 | Thermoplastic |
PL2995636T3 (en) | 2011-10-07 | 2017-12-29 | Allnex Netherlands B.V. | A composition for use in a process for the preparation of a rma crosslinkable composition |
EP2822381B1 (en) * | 2012-03-05 | 2020-05-27 | Archer Daniels Midland Co. | Use of microemulsions as delivery systems |
JP6183642B2 (en) | 2012-08-10 | 2017-08-23 | 株式会社リコー | Actinic ray curable composition, actinic ray curable ink composition for inkjet printing using the same, and actinic ray curable adhesive composition |
SI2984133T1 (en) | 2013-04-08 | 2018-06-29 | Allnex Netherlands B.V. | Composition crosslinkable by real michael addition (rma) reaction |
DK3201261T3 (en) * | 2014-10-01 | 2019-04-08 | Basf Se | PROCEDURE FOR Curing HARDWARE COMPOSITIONS |
KR102349137B1 (en) | 2015-04-17 | 2022-01-07 | 알넥스 네덜란드 비. 브이. | floor coating composition |
KR102321564B1 (en) | 2015-04-17 | 2021-11-04 | 알넥스 네덜란드 비. 브이. | Methods of Curing RMA Crosslinkable Resin Coatings, RMA Crosslinkable Compositions and Resins for Use Therein |
CN107667146B (en) | 2015-04-17 | 2021-01-01 | 欧尼克斯荷兰有限公司 | Process for producing crosslinkable compositions |
EP3283585B1 (en) | 2015-04-17 | 2023-11-15 | Allnex Netherlands B.V. | Adhesion promotor for real michael addition crosslinkable compositions |
EP3115381A1 (en) * | 2015-07-10 | 2017-01-11 | Université de Haute Alsace | Polymerization system using double click michael addition and photopolymerization |
CN105082669B (en) * | 2015-09-23 | 2016-09-28 | 李会录 | A kind of production method of epoxy glass-fiber-fabric copper-clad plate |
US10486452B2 (en) * | 2016-02-26 | 2019-11-26 | Amcor Flexibles Selestat Sas | Flexible packaging substrates compromising thermally-stable prints |
KR102065717B1 (en) * | 2016-12-26 | 2020-01-13 | 주식회사 엘지화학 | Polarizer protecting film, polarizer plate comprising the same, liquid crystal display comprising the polarizer plate, and coating composition for polarizer protecting film |
CN108641550A (en) * | 2018-05-25 | 2018-10-12 | 广州惠利电子材料有限公司 | A kind of curing insulation protection glue and its preparation method and application |
EP3909702A1 (en) * | 2018-12-18 | 2021-11-17 | Lonza Solutions AG | Isocyanate free binder |
CN112552483B (en) * | 2020-11-16 | 2023-06-30 | 新丰见微化工实业有限公司 | Self-photosensitive epoxy methacrylate resin and synthetic method thereof |
WO2024064659A1 (en) * | 2022-09-20 | 2024-03-28 | Ppg Industries Ohio, Inc. | A multi-layer coating system |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5565525A (en) * | 1993-10-27 | 1996-10-15 | Nippon Paint Co., Ltd. | Unsaturated carbonyl and active hydrogen components with onium salt and epoxy compound |
US5667901A (en) * | 1993-10-22 | 1997-09-16 | Eastman Chemical Company | Crosslinkers based on 2-acetylglutarate esters of polyols |
JPH1192546A (en) * | 1997-09-22 | 1999-04-06 | Toyo Ink Mfg Co Ltd | Curable resin composition |
US5945489A (en) * | 1997-09-19 | 1999-08-31 | Ashland, Inc. | Liquid oligomers containing unsaturation |
US6576297B1 (en) * | 1997-12-09 | 2003-06-10 | International Coatings Ltd. | Curable resin compositions |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5218018A (en) * | 1989-12-29 | 1993-06-08 | Kansai Paint Co., Ltd. | Hydroxyl and carboxyl groups-containing resin with alicyclic polyepoxide |
JPH0748472A (en) * | 1993-08-06 | 1995-02-21 | Mitsubishi Rayon Co Ltd | Crosslinking agent |
US6025410A (en) * | 1997-09-19 | 2000-02-15 | Ashland Inc. | Liquid oligomers containing acrylate unsaturation |
CA2378938A1 (en) * | 2001-03-27 | 2002-09-27 | Takashi Irie | Thermosetting coating composition and coating film forming method using the same |
TWI329105B (en) * | 2002-02-01 | 2010-08-21 | Rigel Pharmaceuticals Inc | 2,4-pyrimidinediamine compounds and their uses |
US6706414B1 (en) * | 2002-09-26 | 2004-03-16 | Ashland Inc. | Liquid uncrosslinked Michael addition oligomers prepared in the presence of a catalyst having both an epoxy moiety and a quaternary salt |
JP2005041923A (en) * | 2003-07-23 | 2005-02-17 | Dainippon Ink & Chem Inc | Ultraviolet-curable composition |
US7169825B2 (en) * | 2003-07-29 | 2007-01-30 | Ashland Licensing And Intellectual Property Llc | Dual cure reaction products of self-photoinitiating multifunctional acrylates with thiols and synthetic methods |
-
2004
- 2004-11-12 CA CA002545998A patent/CA2545998A1/en not_active Abandoned
- 2004-11-12 WO PCT/US2004/037807 patent/WO2005048866A2/en active Application Filing
- 2004-11-12 EP EP04810830A patent/EP1685193A4/en not_active Withdrawn
- 2004-11-12 CN CNA2004800400102A patent/CN1910234A/en active Pending
- 2004-11-12 KR KR1020067009414A patent/KR20070097294A/en not_active Application Discontinuation
- 2004-11-12 JP JP2006539903A patent/JP2007511641A/en active Pending
- 2004-11-12 BR BRPI0416519-5A patent/BRPI0416519A/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5667901A (en) * | 1993-10-22 | 1997-09-16 | Eastman Chemical Company | Crosslinkers based on 2-acetylglutarate esters of polyols |
US5565525A (en) * | 1993-10-27 | 1996-10-15 | Nippon Paint Co., Ltd. | Unsaturated carbonyl and active hydrogen components with onium salt and epoxy compound |
US5945489A (en) * | 1997-09-19 | 1999-08-31 | Ashland, Inc. | Liquid oligomers containing unsaturation |
JPH1192546A (en) * | 1997-09-22 | 1999-04-06 | Toyo Ink Mfg Co Ltd | Curable resin composition |
US6576297B1 (en) * | 1997-12-09 | 2003-06-10 | International Coatings Ltd. | Curable resin compositions |
Also Published As
Publication number | Publication date |
---|---|
JP2007511641A (en) | 2007-05-10 |
BRPI0416519A (en) | 2007-03-06 |
WO2005048866A2 (en) | 2005-06-02 |
EP1685193A2 (en) | 2006-08-02 |
CN1910234A (en) | 2007-02-07 |
KR20070097294A (en) | 2007-10-04 |
CA2545998A1 (en) | 2005-06-02 |
WO2005048866A3 (en) | 2005-09-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7041749B2 (en) | Dual cure reaction products of self-photoinitiating multifunction acrylates with cycloaliphatic epoxy compounds | |
US7169825B2 (en) | Dual cure reaction products of self-photoinitiating multifunctional acrylates with thiols and synthetic methods | |
WO2005048866A2 (en) | Dual cure reaction products of self-photoinitiating multifunctional acrylates with cycloaliphatic epoxy compounds | |
EP1756035B1 (en) | Radiation-curable coatings for metal substrates from multifunctional acrylate oligomers | |
EP1740621B1 (en) | Radiation-curable michael addition resins having built-in photoinitiators | |
WO2004029118A2 (en) | Liquid uncrosslinked michael addition oligomers prepared in the presence of a catalyst having both an epoxy moiety and a quaternary salt | |
CA2564314A1 (en) | Self-photoinitiating water-dispersable acrylate ionomers and synthetic methods | |
WO2005111105A2 (en) | Radiation-curable coatings for wood substrates from multifunctional acrylate oligomers | |
JP3649331B2 (en) | Photocurable composition, cured product thereof, and method for producing photocurable resin | |
CA2502210A1 (en) | Oligomers from multifunctional acrylates | |
JP4880249B2 (en) | Photoradical crosslinking polymer and photocurable resin composition | |
JPH01306424A (en) | Curable resin composition | |
KR20070022061A (en) | Radiation-curable coatings for metal substrates from multifunctional acrylate oligomers | |
CN112708078A (en) | High-crosslinking photo-curing water-dispersible epoxy acrylic resin and preparation method thereof | |
PL244107B1 (en) | Method for producing an epoxy(meth)acrylate varnish binder and a film-forming composition based on an epoxy(meth)acrylate binder | |
JP2004010772A (en) | Photo-setting resin, and resin composition and coating material containing the resin | |
JP2004107448A (en) | Polymer containing alicycle group having endocyclic olefin on side chain and active energy ray-curing type composition containing the polymer | |
JP2003192743A (en) | Process for producing acrylic photo-setting resin |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20060602 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LU MC NL PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL HR LT LV MK YU |
|
A4 | Supplementary search report drawn up and despatched |
Effective date: 20061115 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C08G 16/00 20060101ALI20061109BHEP Ipc: C08G 59/40 20060101ALI20061109BHEP Ipc: C09D 163/00 20060101AFI20061109BHEP |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC |
|
17Q | First examination report despatched |
Effective date: 20081124 |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20090729 |