EP1661973B1 - Composition de parfum pour le controle de sensibilite a la temperature - Google Patents
Composition de parfum pour le controle de sensibilite a la temperature Download PDFInfo
- Publication number
- EP1661973B1 EP1661973B1 EP04772615A EP04772615A EP1661973B1 EP 1661973 B1 EP1661973 B1 EP 1661973B1 EP 04772615 A EP04772615 A EP 04772615A EP 04772615 A EP04772615 A EP 04772615A EP 1661973 B1 EP1661973 B1 EP 1661973B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- temperature sense
- perfume
- aroma
- person
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
Definitions
- the present invention relates to the use of a perfume composition for temperature sense control, which changes the subjective temperature sense of a person by means of aroma.
- Colors have long been known to affect people's temperature sense, time sense, weight sense, and sense of size. For instance, warm colors such as red, orange, and yellow project a warm or expansive image, and have the effect of changing a person's senses in that direction, whereas cool colors such as black, blue, white, and purple are known to project a cool or contracting image. Meanwhile, it is known that fragrances project sense images such as sweet, thick, transparent, or bracing, and that fragrances can arouse emotions, impart a pleasurable feeling, relieve stress, improve work efficiency, and have other such effects. For example, Japanese Laid-Open Patent Application 2001-49286 discloses an invention related to a perfume component that eases stress caused by lack of sleep. Nevertheless, there has been no research into the relationship between aroma and temperature sense, and it has never once been proposed up to now that temperature sense could be changed by aroma.
- EP 1 121 927 A2 discloses a sensate composition including at least one cooling sensate which is for instance spearmint oil and peppermint oil.
- WO 02/49600 A1 discloses perfume compositions comprising at least five relaxing fragrance materials and non-relaxing fragrance materials and optionally neutral fragrance materials and other fragrance materials.
- the present invention refers to the use of a perfume composition according to claims 1-5.
- the perfume component that raises the temperature sense is a component selected from the group composed of vanillin, 4-tert-butyl- ⁇ -methylhydrocinnamic aldehyde, heliotropine, 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopentabenzopyran, ⁇ -undecalactone, ⁇ -ionone, cumin oil, lavender oil, clove oil, 3 ⁇ ,6,6,9 ⁇ -tetramethyldodecahydronaphtho[2,1-b]furan, and maltol.
- the present invention it is possible to identify a perfume component and perfume composition that can change temperature sense, and to change and control temperature sense by means of an aroma given off by a perfume component. Also, it is possible to easily and reliably select a perfume component and perfume composition capable of changing temperature sense on the basis of a temperature image obtained from a test subject. Also, it is possible to change and control the temperature sense and/or usability/skin feel [experienced by] a person in a space in which the user or aroma is present, by using an article, cosmetic, or the like containing the perfume composition for temperature sense control of the present invention. Furthermore, it is possible to estimate the temperature sense and/or usability/skin feel that can be changed by a perfume component and/or perfume composition by utilizing a perfume map.
- This invention identifies a perfume component that can change a person's temperature sense by aroma, and provides a perfume composition for controlling temperature sense that contains this perfume component.
- the preparation of an article for controlling temperature sense that contains this perfume composition, and the control of temperature sense by volatilizing this perfume composition are also disclosed. Also, discloses is the utilization of a perfume map to allow the desired perfume for controlling temperature sense to be selected easily and reliably.
- the inventors discovered that the aroma given off by a specific perfume component can change the temperature subjectively sensed by a person (temperature sense).
- 12 test subjects put there hands into water held at a constant temperature, and the subjectively sensed temperature of the water was assessed on a seven-point scale in which 7 was hot, 6 was warm, 5 was somewhat warm, 4 was "can't say,” 3 was somewhat cold, 2 was cold, and 1 was extremely cold.
- the same 12 test subjects were asked to smell a peppermint aroma while once again putting their hands into water held at a constant temperature, and the subjectively sensed temperature of the water was assessed on a seven-point scale.
- the temperature sense for a cosmetic brought about by aroma was compared with the usability/skin feel with and without an aroma, for the 24 typical types of perfume discussed below, and an assessment was made versus no aroma.
- the arms were each coated with an unscented cream while the subjected smelled the aroma of the cotton, and the subjectively sensed temperature of the cream was assessed on a five-point scale in which 5 was warm, 4 was somewhat warm, 3 was "can't say,” 2 was somewhat cold, and 1 was cold.
- the 24 types of raw material perfume were vanillin, 4-tert-butyl- ⁇ -methylhydrocinnamic aldehyde, heliotropine, 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopentabenzopyran, ⁇ -undecalactone, ⁇ -ionone, cumin oil, lavender oil, clove oil, 3 ⁇ ,6,6,9 ⁇ -tetramethyldodecahydronaphtho[2,1-b]furan, peppermint oil, bergamot oil, spearmint oil, lime oil, 7-methyl-3,4-dihydro-(2H)-1,5-benzodioxepin-3-one, chamomile oil, 2,4-dimethyl-3-cyclohexenyl carboxyaldehyde, marjoran oil, patchouli oil, jasmine absolute, sandalwood oil, geranium oil, rose oil, and methyl-N-3,7-di
- perfume raw materials having a warm temperature image and raw material perfumes capable of raising temperature sense were vanillin, 4-tert-butyl- ⁇ -methylhydrocinnamic aldehyde, heliotropine, 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopentabenzopyran, ⁇ -undecalactone, ⁇ -ionone, cumin oil, lavender oil, clove oil, 3 ⁇ ,6,6,9 ⁇ -tetramethyldodecahydronaphtho[2,1-b]furan, and maltol.
- a syrup perfume, chocolate perfume and coconut perfume also can raise temperature sense.
- perfume raw materials having a cool temperature image and raw material perfumes capable of lowering temperature sense were peppermint oil, bergamot oil, spearmint oil, lime oil, 7-methyl-3,4-dihydro-(2H)-1,5-benzodioxepin-3-one, chamomile oil, 2,4-dimethyl-3-cyclohexenyl carboxyaldehyde, marjoran oil, patchouli oil, jasmine absolute, sandalwood oil, geranium oil, rose oil, and methyl-N-3,7-dimethyl-7-hydroxyoctylidene-anthranilate. Furthermore, the effect of the aroma is the same not only for the perfume component, but for the fragrance of the perfume composition as a whole.
- the present invention identifies a perfume component that can change temperature sense, and is designed to be used as a perfume composition that contains this perfume component and is for controlling the temperature sense of a person, and even with other perfume raw materials besides the 24 types discussed above, the present invention encompasses perfume components that can change temperature sense and are identified on the basis of a temperature image obtained from test subject assessment. Also, the perfume map discussed below allows a person's impression of the aroma of a perfume to be utilized to evaluate the temperature sense, as well as the usability/skin feel, of perfume raw materials whose temperature sense is unknown, and the present invention also encompasses perfume raw materials thus evaluated and identified.
- the correlation of aroma-induced cosmetic temperature sense, usability, and how the cosmetic actually felt on the skin, and the correlation with the image of the aroma were tested for the above-mentioned 24 different raw material perfumes.
- the test method for a cream involved comparing the aroma-induced temperature sense, usage feel of the cream, and skin feel with those obtained without any aroma.
- the aroma image was assessed on a seven-point scale from 0 to 6, while the usability/skin feel was assessed on a five-point scale from 5 ("I agree") to 1 ("I disagree”).
- the impression of the aroma of the perfume was also assessed at the same time.
- a method was employed in which the perfume component was not directly added to the cream, but was instead applied to the cotton and smelled.
- the words used to express usability/skin feel and the words used to express impressions of aroma are nothing more than examples, and [the present invention] is not limited to or by these words.
- the aroma assessment terms disclosed in Japanese Laid-Open Patent Application 2001-174450 can be employed as words for expressing aroma impressions.
- Table 1 gives average values for the assessment of aroma images and usability/skin feel, and the change in the temperature sense of a cream produced by aroma, for eight types of typical perfume raw material.
- FIG. 2 is a graph of the relationship between the change in cream temperature sense brought about by aroma and the "freshness of the skin.”
- FIG. 3 is a graph of the relationship between temperature sense and the "moistness of the skin.” It can be seen from Table 1 and FIGS. 2 and 3 that a cream having an aroma that is sensed to be cold gives a greater sense of skin freshness, non-stickiness, and tightness than an unscented cream, while a cream having an aroma that is sensed to be warm gives a greater sense of skin moistness and smoothness than an unscented cream.
- a cosmetic containing a perfume component capable of controlling temperature sense will be able to change the usability/skin feel by its aroma, so it is possible to control the usability/skin feel of a cosmetic by means of aroma.
- A is peppermint
- B is 4-tert-butyl- ⁇ -methylhydroxycinnamic aldehyde
- C is vanillin
- D is majolaine
- E is 2,4-dimethyl-3-cyclohexenyl carboxyaldehyde
- F is cumin
- G is ⁇ -undecalactone
- H lime.
- Table 3 shows the correlation coefficients for aroma image and the temperature sense and/or usability/skin feel that changes with the aroma. It can be seen from Table 3 that an aroma that makes the skin feel fresh scores high in terms of being bright, transparent, and bracing, and scores low in terms of being mild, sweet, and thick. An aroma that makes the skin feel moist scores high in terms of being mild and sweet, and low in terms of being bracing. An aroma that gives the sense of light spreading and quick absorption scores high in terms of being bright and transparent, and low in terms of being thick.
- FIG. 4 shows a perfume map with which an image of the aroma perceived when a person smells a perfume component and/or perfume composition is obtained by positioning a specific perfume component and/or perfume composition, on the basis of the aroma image, on a coordinate plane (map) having X and Y axes, with the X axis having "tender” (mild, sweet) and “sharp” (bracing) at opposite ends, and the Y axis having "natural” (transparent, bright) and “rich” (thick, sultry) at opposite ends, and [how much] the temperature sense and/or usability/skin feel is changed by this perfume component and/or perfume composition is estimated from the position on the map.
- the X axis of the perfume map in FIG. 4 is the axis of temperature sense that changes with aroma, with "warm” on the right end and “cold” on the left end.
- the X axis is also the axis of "fresh-moist” for usability/skin feel, with “moist (skin feels soft, skin is moist)" on the right end, and “fresh (skin feels nicely tight, skin feels fresh, skin feels supple, and skin feels non-sticky)" on the left end.
- the Y axis is the aroma impression axis, with the top end being “natural” and the bottom end “rich,” and at the same time, the Y axis is the axis of usability/skin feel indicating whether spreading is light or heavy, with the top end being “light spreading (fast absorption into the skin, skin looks youthful, skin is not sticky)", and the bottom end “heavy spreading (cream is thick, skin is plump, skin is firm).”
- This Y axis is not correlated to temperature sense.
- perfume raw materials that give the perception of heavy-spreading usability/skin feel include cumin oil, patchouli oil, clove oil, jasmine absolute, methyl-N-3,7-dimethyl-7-hydoroxyoctylidene-anthranilate, and vanillin
- perfume raw materials that give the perception of light-spreading usability/skin feel include ⁇ -undecalactone, 4-tert-butyl- ⁇ -methylhydrocinnamic aldehyde, heliotropine, rose oil, 7-methyl-3,4-dihydro-(2H)-1,5-benzodioxepin-3-one, lime oil, geranium oil, chamomile oil, bergamot oil, peppermint oil, ⁇ -ionone, marjoran oil, 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopentabenzopyran, lavender oil, 2,4-dimethyl
- FIG. 5 is a graph of the assessment results, and it can be seen that the temperature sense of a person located in a space can be changed by aroma.
- the concentration of the aroma is preferably 0.01 to 10 ppm.
- peppermint oil for instance, about 0.4 ppm is favorable.
- FIG. 6 is a graph of the assessment of the sense of warmth or cold inside the boxes, and shows that the temperature sense perceived by the face changes with the aroma.
- FIG. 8 is a graph of the assessment of the aroma intensity inside the box, as a function of concentration.
- the means for dispersing the aroma is not limited to the above, and a filter impregnated with an aromatic may be removably attached to the discharge opening of the above-mentioned air conditioner or the like.
- the cold-sensation perfumes 1 to 4 and warm-sensation perfumes 1 to 4 discussed below are favorable as this aromatic, but the present invention is not limited to these.
- Components Amount contained Dipropylene glycol 3.7 Dihydromyrcenol 200 Borneol 1 Precyclemon B (IFF) 15 Basil oil 1 Dynascone 10 2 Rosemary oil 130 Juniper berry oil 130 Peppermint oil 300 Rose oxide 0.3 Mandarinal 1 Ambroxan 15 Cyclogalbanate 20 Triplal 2 Dimetol 5 Lemon oil 40 Clary sage oil 2 Galbanum oil 2 Lavender oil 25 Bergamot oil 100 Hexyl salicylate 5 Total 1000
- Components Amount contained Dipropylene glycol 8 Menthone 50 Isomenthone 50 Shinus molle oil 10 Rosemary oil 300 Cardamon oil 2 Juniper berry oil 130 Peppermint oil 400 Lime distilled oil 50 Total 1000
- Components Amount contained Methy dihydrojasmonate 300 Lilial 50 Galaxolide(50% BB) 50 Linalool 50 Menthol 200 Linalyl acetate 50 Ambroxan(10% DPG) 20 Peppermint 60 Green base 10 Helional 10 Triethyl citrate 100 Bergamot 100 Total 1000
- Components Amount contained Dipropylene glycol 89.4 Hedione 300 Hexyl cinnamic aldehyde 50 Lilial 30 Iso-E-Super 100 Galaxolide 30 Indole 0.2 Phenyl ethyl alcohol 35 Phenylacetaldehyde 0.1 Beta-ionone 20 Eugenol 3 Florosa (Quest) 50 Givescone (GIV) 1 Tagete oil 1 Basil oil 5 Prunella (FIR) 1 Ambroxan 5 Bacdanol (IFF) 10 Undecalactone gamma 0.2 Jasmal (IFF) 10 Ethyl linalool 100 Sandalore (GIV) 60 Orange oil 5 Manzanate (Quest) 0.1 Ethyl vanillin 2 Cyclopentadecanone 2 Citronellol 30 Geraniol 25 Geranyl acetate 10 Vanillin 10 Methyl ionoe gamma 15 Total 1000
- Components Amount contained Orange oil 15 Linalyl acetate 10 Ethyl linalool 35 Styrallyl acetate 1 Citronellol 10 Florosa (Quest) 20 Nerol 2 DPG [ sic ] Methyl ionone gamma 25 Alpha-ionone 2 Geraniol 7 Cedryl methyl ether 5 Polysantol (FIR) 15 Iso-E-Super (IFF) 200 Lilial 15 Anbroxan 10 Bacdanol 70 Canthoxal 10 Heliotropine 10 Pentalide 10 Cis-3-hexenyl salicylate 20 Hedione 250 Habanolide 25 Galaxolide 100 Exaltenone (fir) 15 Ambrettolide 3 Coumarine 5 Lyral 40 Vanillin 10 Ethylene brassylate 50 Raspberry ketone 10 Total 1000
- Components Amount contained Methyl dihydrojasmonate 200 Iso-E-Super 100 Galaxolide (50% BB) 200 Linalool 30 Linalyl acetate 20 Beta-ionone 50 Orange oil 30 Milk lactone 100 Ethyl acetate(10% DPG) 20 Ald. C 12 kauric (50% BB) 5 Triethyl citrate 125 Ethyl vanillin 20 ak moss 100 Total 1000
- Astringent lotion Ethanol 40 Dipropylene glycol 1 Polyoxyethylene polyoxypropylene decyl tetradecyl ether 0.1 Cinnamic anhydride 1 Salicylic acid 0.1 Sodium citrate 0.2 Zinc paraphenolsulfonate 0.2 Dipotassium glycyrrizinate 0.1 Pyridoxine hydrochloride 0.1 L-menthol 0.05 Trisodium HEDTA 0.05 Cellulose powder 1 Bentonite 0.8 Cold-sensation perfume 1 0.002 Purified water balance
- Part A was heated and dissolved at 80°C, after which part B was added and the system was cooled. At the point when the system reached 60°C, the uniformly dissolved part C was added under stirring, and the solution thus obtained was poured into a vessel and then allowed to stand, cool to room temperature, and solidify, which gave a gelled aromatic.
- Body soap Propylene glycol 2.0 Ethylene glycol distearate 2.0 Coconut oil fatty acid diethanolamide 6.0 Sodium dodecan-1,2-diol acetic acid ether 2.0 Polyoxyethylene lauryl ether sodium sulfate 7.5 Polyoxyethylene lauryl ether sulfuric acid triethanolamine 3.0 Coconut oil fatty acid methyltaurine sodium 3.0 Coconut oil fatty acid amide propyl betaine 1.0 Citric acid (50% solution) 0.5 Sodium citrate 1.0 Sodium benzoate appropriate amount Disodium edetate appropriate amount Cold-sensation perfume 3 0.5 Pure water balance
- Antiperspirant aerosol cosmetic A. Powder component Aluminum hydroxychloride 3 mass% Zinc oxide 2 Silica 3 Cornstarch 0.1 Calcium stearate 0.1 B. Oil phase component Dimethylpolysiloxane 2 Cetyl octane 2 POE (10) POP (10) dimethyl ether (random copolymer) 10 Sorbitan oleate 1 Antioxidant appropriate amount Cold-sensation perfume 4 0.05 C. Propellant Liquefied petroleum gas balance
- the powder (A) and the oil phase component (B) were mixed, and the propellant (C) was charged into this mixture, which gave an antiperspirant aerosol cosmetic.
- Emulsion Dimethylpolysiloxane 2 Behenyl alcohol 1 Batyl alcohol 0.5 Glycerin 5 1,3-butylene glycol 7 Erythritol 2 Hydrogenated oil 3 Squalane 6 Tetra-2-ethylhexanoic acid pentaerythritol 2 Polyoxyethylene glyceryl isostearate 1 Polyoxyethylene glycerin monostearate 1 Potassium hydroxide appropriate amount Sodium hexametaphosphate 0.05 Phenoxyethanol appropriate amount Carboxyvinyl polymer 0.1 Warm-sensation perfume 1 0.05 Purified water balance
- Moisturizing cream Liquid paraffin 10 Dimethylpolysiloxane 2 Glycerin 10 1,3-butylene glycol 2 Erythritol 1 Polyethylene glycol 1500 5 Squalane 15 Tetra-2-ethylhexanoic acid pentaerythritol 5 Potassium hydroxide 0.1 Sodium hexametaphosphate 0.05 Tocopherol acetate 0.05 p-Hydroxybenzoic acid ester appropriate amount Hydroxypropyl methyl cellulose 0.3 Polyvinyl alcohol 0.1 Carboxyvinyl polymer 0.2 Acrylic acid-alkyl methacrylate copolymer (Pemulen TR-2) 0.1 Warm-sensation perfume 2 0.03 Purified water balance
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
Claims (5)
- Utilisation d'une composition de parfum pour élever la température détectée subjectivement par une personne (détection de température) en utilisant l'odorat de la personne pour le contrôle de détection de température, contenant un agent parfumant qui déclenche la détection de température en utilisant l'odorat de la personne, où l'agent parfumant qui déclenche la détection de température est un élément choisi dans le groupe constitué par la vanilline,
l'aldéhyde 4-tert-butyl-α-méthylhydrocinnamique, l'héliotropine,
le 4,6,6,7,8,8-hexaméthyl-1,3,4,6,7,8-hexahydrocyclopentabenzopyrane, le γ-undécalactone, le β-ionone, l'huile de cumin, l'huile de lavande, l'huile de clou de girofle, et
le 3α,6,6,9α-tétraméthyldodecahydronaphtho[2,1-b]furanne, et le maltol. - Utilisation d'une composition de parfum pour augmenter sa teneur en humidité en utilisant l'odorat de la personne pour le contrôle de détection de température, contenant un agent parfumant qui élève la température détectée subjectivement par une personne (détection de température) en utilisant l'odorat de la personne,
où l'agent parfumant qui augmente la détection de température est un élément choisi dans le groupe constitué par la vanilline,
l'aldéhyde 4-tert-butyl-α-méthylhydrocinnamique, l'héliotropine,
le 4,6,6,7,8,8-hexaméthyl-1,3,4,6,7,8-hexahydrocyclopentabenzopyrane, le γ-undécalactone, le β-ionone, l'huile de cumin, l'huile de lavande, l'huile de clou de girofle, et
le 3α,6,6,9α-tétraméthyldodecahydronaphtho[2,1-b]furanne, et le maltol. - Utilisation d'une composition de parfum pour réduire le taux de sébum de la peau en utilisant l'odorat de la personne pour le contrôle de détection de température, contenant un agent parfumant qui abaisse la température détectée subjectivement par une personne (détection de température) en utilisant l'odorat de la personne,
où l'agent parfumant qui abaisse la détection de température est un élément choisi dans le groupe constitué par l'huile de menthe poivrée, l'essence de bergamote, l'huile de menthe verte, l'huile de citron vert, le 7-méthyl-3,4-dihydro-(2H)-1,5-benzodioxépin-3-one, l'huile de camomille,
le 2,4-diméthyl-3-cyclohexényle carboxyaldéhyde, l'huile de marjolaine, l'huile de patchouli, l'absolu de jasmin, l'huile de bois de santal, l'huile de géranium, l'huile de rose, et
le méthyl-N-3,7-diméthyl-7-hydroxyoctylidène-anthranilate. - Utilisation de la composition de parfum pour le contrôle de détection de température, où la détection de température réalisée par une personne à l'intérieur d'un espace spécifique est augmentée par la libération d'un agent parfumant, selon la revendication 1, à l'intérieur de cet espace.
- Utilisation de la composition de parfum pour le contrôle de détection de température selon la revendication 4, où la concentration d'agent parfumant dispersé dans l'espace va de 0,01 à 10 ppm.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003314742 | 2003-09-05 | ||
PCT/JP2004/012659 WO2005023968A1 (fr) | 2003-09-05 | 2004-09-01 | Composition de parfum pour le controle de sensibilite a la temperature, article de controle de sensibilite, procede de controle de sensibilite et carte de parfums |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1661973A1 EP1661973A1 (fr) | 2006-05-31 |
EP1661973A4 EP1661973A4 (fr) | 2010-02-17 |
EP1661973B1 true EP1661973B1 (fr) | 2013-02-27 |
Family
ID=34269814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04772615A Expired - Lifetime EP1661973B1 (fr) | 2003-09-05 | 2004-09-01 | Composition de parfum pour le controle de sensibilite a la temperature |
Country Status (6)
Country | Link |
---|---|
US (2) | US20060270587A1 (fr) |
EP (1) | EP1661973B1 (fr) |
JP (3) | JPWO2005023968A1 (fr) |
KR (1) | KR20060090974A (fr) |
CN (1) | CN1845983A (fr) |
WO (1) | WO2005023968A1 (fr) |
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JP5388267B2 (ja) * | 2008-03-28 | 2014-01-15 | 株式会社 資生堂 | 皮膚血流改善剤および皮膚温度上昇剤 |
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-
2004
- 2004-09-01 EP EP04772615A patent/EP1661973B1/fr not_active Expired - Lifetime
- 2004-09-01 KR KR1020067004558A patent/KR20060090974A/ko not_active Application Discontinuation
- 2004-09-01 US US10/570,634 patent/US20060270587A1/en not_active Abandoned
- 2004-09-01 JP JP2005513655A patent/JPWO2005023968A1/ja active Pending
- 2004-09-01 WO PCT/JP2004/012659 patent/WO2005023968A1/fr active Application Filing
- 2004-09-01 CN CNA2004800250622A patent/CN1845983A/zh active Pending
-
2009
- 2009-08-24 US US12/545,914 patent/US20100048686A1/en not_active Abandoned
-
2010
- 2010-06-21 JP JP2010141061A patent/JP2010254704A/ja active Pending
- 2010-10-13 JP JP2010230627A patent/JP2011026613A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
US20100048686A1 (en) | 2010-02-25 |
JP2010254704A (ja) | 2010-11-11 |
JPWO2005023968A1 (ja) | 2007-11-08 |
KR20060090974A (ko) | 2006-08-17 |
EP1661973A4 (fr) | 2010-02-17 |
EP1661973A1 (fr) | 2006-05-31 |
US20060270587A1 (en) | 2006-11-30 |
WO2005023968A1 (fr) | 2005-03-17 |
JP2011026613A (ja) | 2011-02-10 |
CN1845983A (zh) | 2006-10-11 |
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