EP1520108A1 - Verfahren zum fördern einer wenigstens ein (meth)acrylmonomeres enthaltenden flüssigkeit - Google Patents
Verfahren zum fördern einer wenigstens ein (meth)acrylmonomeres enthaltenden flüssigkeitInfo
- Publication number
- EP1520108A1 EP1520108A1 EP03738074A EP03738074A EP1520108A1 EP 1520108 A1 EP1520108 A1 EP 1520108A1 EP 03738074 A EP03738074 A EP 03738074A EP 03738074 A EP03738074 A EP 03738074A EP 1520108 A1 EP1520108 A1 EP 1520108A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pump
- liquid
- drive
- chamber
- meth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04D—NON-POSITIVE-DISPLACEMENT PUMPS
- F04D29/00—Details, component parts, or accessories
- F04D29/08—Sealings
- F04D29/10—Shaft sealings
- F04D29/12—Shaft sealings using sealing-rings
- F04D29/126—Shaft sealings using sealing-rings especially adapted for liquid pumps
Definitions
- the present invention relates to a method for conveying a liquid F containing at least one (meth) acrylic monomer by means of a feed pump, the
- the pump chamber contains at least one conveying element for conveying the liquid F;
- the liquid F is supplied to the pump chamber with an input energy
- the liquid F leaves the pump chamber with an output energy that is greater than the input energy
- the at least one conveying element contained in the pump chamber is connected to the drive shaft guided into the pump chamber so that the drive shaft can transmit a torque to the conveying element;
- the separation space is filled with a barrier medium which consists of a barrier gas and / or a barrier liquid and which is different from the liquid F;
- the drive shaft is not supported within the pump chamber.
- the notation (meth) acrylic monomers stands for "acrylic monomers and / or methacrylic monomers".
- acrylic monomer stands for acrylic acid, esters of acrylic acid and / or acrylonitrile.
- methacrylic monomer stands for methacrylic acid, esters of methacrylic acid and / or methacrylonitrile.
- (Meth) acrylic monomers include the following (meth) acrylic acid esters: hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypropyl methacrylate, glycyl acrylate, glycidyl methacrylate, methyl acrylate, methyl methacrylate, n-butyl acrylate, n-butyl methacrylate, tert. -Butyl acrylate, tert.
- (Meth) acrylic monomers are important starting compounds for the preparation of polymers which e.g. find use as adhesives.
- (meth) acrylic acid is predominantly produced by catalytic gas phase oxidation of suitable C 3 ⁇ / C 4 precursor compounds, in particular propene and propane in the case of acrylic acid or isobutene and isobutane in the case of methacrylic acid.
- suitable C 3 ⁇ / C 4 precursor compounds in particular propene and propane in the case of acrylic acid or isobutene and isobutane in the case of methacrylic acid.
- propane, isobutene and isobutane other compounds containing 3 or 4 carbon atoms, for example isobutanol, n-propanol or the methyl ether of isobutanol, are also suitable as starting materials.
- a product gas mixture is usually obtained from which the (meth) acrylic acid must be separated by absorptive, rectificative, extractive and / or crystallizing processes (see e.g. DE-A 10224341).
- (meth) acrylonitrile is catalytic ammoxidation of the aforementioned
- Esters of (meth) acrylic acid are e.g. obtainable by direct reaction of (meth) acrylic acid with the corresponding alcohols.
- product mixtures from which the (meth) acrylic acid esters e.g. have to be separated by rectification and / or extraction.
- the solvent can be both aqueous and an organic solvent.
- the specific type of solvent is essentially irrelevant according to the invention.
- the (meth) acrylic monomer content of solutions to be conveyed can be> 5% by weight, or> 10% by weight, or> 20% by weight, or> 40% by weight, or> 60% by weight , or> 80% by weight, or> 90% by weight, or> 95% by weight, or> 99% by weight.
- the pump to be used should therefore be designed such that, apart from the intended inlet and outlet for the liquid F to be pumped and containing at least one (meth) acrylic monomer, there are no unintentional outlet points. At the same time, however, it should be such that no mechanically extremely stressed components (e.g. bearings of drive shafts) come into contact with the liquid F. Heat is generated on components that are mechanically stressed in such a way, which can cause an undesired free-radical polymerization of the (meth) acrylic monomers.
- mechanically extremely stressed components e.g. bearings of drive shafts
- EP-A 1092874 therefore recommends in FIG. 3 to use a feed pump which is a feed pump as described at the beginning of this document for conveying a liquid F containing at least one (meth) cryl monomer.
- the barrier medium is a gas at normal pressure and a mechanical seal is used to seal the separation chamber from the drive chamber. recommended.
- EP-A 1092874 leaves open the question of sealing the separating space from the pumping space.
- the object of the present invention was to overcome these disadvantages when using a feed pump according to the aforementioned prior art.
- the pump chamber contains at least one delivery element (7) for delivering the liquid F;
- the liquid F is supplied to the pump chamber with an input energy
- the liquid F leaves the pump chamber with an output energy that is greater than the input energy
- the at least one conveyor element contained in the pump chamber is connected to the drive shaft guided into the pump chamber so that the drive shaft can transmit a torque to the conveyor element;
- the separation space is filled with a barrier medium which consists of a barrier gas and / or a barrier liquid and which is different from the liquid F; and the drive shaft is not supported (8) within the pump chamber,
- the pressure of the barrier medium is greater than the pressure in the pump chamber and than the pressure in the drive chamber
- section of the drive shaft leading through the separation space to the pump chamber and to the drive space carries firmly and impermeably connected sliding elements (6) which slide sealingly on the inner walls of the separation space penetrated by the drive shaft (principle of double (on both Sliding element (e.g. ring) seal).
- FIG. 1 of this document shows a schematic illustration of a feed pump to be used according to the invention.
- the addresses (1) and (2) denote the entry and exit points of the liquid F into and out of the feed pump.
- the pressure in the separation chamber is preferably at least 1 bar greater than the pressure at the point in the pump chamber opposite the sliding element.
- This pressure difference is often> 2 bar or> 3 bar. As a rule, this pressure difference will be ⁇ 10 bar.
- a gas is used as the barrier medium in the process according to the invention, it is preferably an oxygen-containing gas, since molecular oxygen has a polymerization-inhibiting effect on (meth) acrylic monomers.
- This polymerization-inhibiting effect develops in particular in interaction with the polymerization inhibitors usually contained in the liquid F, such as e.g. Phenothiazine or methoxyphenol.
- the liquid F in the process according to the invention can also contain any other known polymerization inhibitor.
- the oxygen content of such a sealing gas is preferably 4 to 21% by volume.
- an oxygen content of a barrier gas of 4 to 10% by volume is very particularly preferred.
- barrier liquid for example 2-ethylhexanol
- this is preferably chosen so that it is mixed with the liquid F to be conveyed and contained (meth) acrylic monomers is compatible.
- Barrier liquids preferred according to the invention are mixtures of ethylene glycol and water or the two liquids per se. Mixtures whose ethylene glycol content is 30 to 40% by weight are particularly preferred. The ethylene glycol / water mixtures mentioned show excellent viscosity behavior and are also comparatively freeze-resistant under normal external conditions. According to the invention, barrier liquids are preferred over barrier gases.
- Pumps to be preferably used according to the invention are centrifugal pumps and side channel pumps. They usually contain mechanical seals as sealing elements. These consist of a sliding ring that is firmly connected to the drive shaft and that rotates with the drive shaft, and a mating ring that is fixed in the partition wall.
- a spring normally presses the slide ring against the counter ring with a preload of 1 to 2 bar. During operation, it is supplemented by the increased pressure of the barrier medium located between the mechanical seals. The increased pressure of the barrier medium compared to the pressure prevailing on the pressure side of the pump prevents the liquid F to be conveyed from escaping from the pump chamber.
- this leakage rate can be 0.2 to 5 ml / h, at 1 m 3 / h to 4000 m 3 / h in flow rate.
- the leakage rate is 120 to 150 Nml / h sealing gas based on the same flow rate.
- the leak rate is expediently continuously supplemented from storage containers.
- the barrier medium for example the barrier fluid
- the (meth) acrylic monomer content of the barrier medium in% by weight is lower than that of the liquid F.
- centrifugal pumps and side channel pumps work on the dynamic principle.
- a rotating impeller (the conveying element connected to the drive shaft) transfers work in the form of kinetic energy from the impeller to the liquid F to be conveyed.
- the impeller is a simple disk on which blades are attached, as shown by way of example in FIG. 3.
- the blades create blade channels, the cross-section of which normally increases very greatly from the inside to the outside due to the larger circumference (see dashed lines in FIG. 3). As much liquid F to be pumped can be thrown away through these blade channels as can flow into the center of the impeller. In contrast to the piston pump, the liquid F to be pumped in the centrifugal and side channel pump therefore flows continuously during operation.
- closed impellers ( Figure 4) can also be used.
- the blade channels are simply covered by a second disc that has an opening in the middle.
- FIG. 5 The top view of a paddle wheel is shown in FIG. 5.
- the paddle curvature generally runs in the same way as the natural path of a drop of water on a rotating, smooth disk from the perspective of a co-rotating observer when the drop of water is dropped on the center of the disk.
- This blade shape is referred to as a "backward-curved" blade.
- blades it is also possible for blades to be curved slightly forward, and also for helical, ie, twisted, backward-curved blades which protrude with their cutting edges into the impeller inlet and capture the liquid F like a propeller. can be used (see. Fig. 6 and 7, top view).
- FIGS. 8 a, b The functioning of a centrifugal pump (a centrifugal pump chamber) is illustrated by way of example in FIGS. 8 a, b. It consists of the pump housing (a) and the rotating impeller (b) which is provided with blades (c). The liquid F enters axially through the suction port (d). It is steered radially outwards by centrifugal force and accelerated to high speed in this way by the impeller.
- the pump housing has the task of collecting the liquid F from all the blade channels so that it collected through the pressure outlets (f) can be forwarded.
- the pump housing also has the task of converting kinetic energy of the liquid F into pressure.
- stator is built into the pump housing and is designed as an annular space. It surrounds the impeller.
- Guide vanes (h) are arranged in the guide wheel and form channels which continuously widen towards one another (FIGS. 9 and 10).
- the liquid F is not thrown directly into the pump housing, but first flows through the vane channels of the stator. By expanding in the direction of flow, they in turn slow down the flow speed and the pressure build-up that this causes.
- the direction of the stator channels is normally opposite to the direction of the impeller channels and corresponds on the inner circumference of the stator to the direction of the exit velocity of the conveyed liquid from the impeller.
- Another task of the stator is to collect the liquid F in two-stage centrifugal pumps and to lead it to the entrance of the second stage.
- stator and volute casing can also be used. This means that the liquid F is first collected in the stator before it can reach the volute casing.
- Snow-running engines such as electric motors, internal combustion engines or steam turbines drive the impeller in a direct clutch.
- the clutch is accomplished by a drive shaft. They can only be stored in the drive room be housed, as shown in Figure 3 of EP-A 1092874. If necessary, it can also be stored in the separation room. It is advantageous according to the invention that centrifugal and side channel pumps can manage with a simple mounting of the drive shaft. This is due to the lightness of the impeller.
- the pump chamber of the method according to the invention can also be designed as a multi-stage centrifugal pump, as described in Pumps in the Fire Service, Part I, Introduction to Hydromechanics, Mode of Operation of Centrifugal Pumps, 4th Edition 1998, W. Kohlhammer, Berlin. Single-stage centrifugal pumps are preferred according to the invention.
- a narrow impeller (a) with open blades (b) rotates in the housing (c), in which a side channel extends over most of the circumference in addition to the blades.
- the liquid to be conveyed does not enter the blade chambers through the axis but through a slot (d) from the end face, at the same time the liquid already in the chambers is driven outwards by centrifugal force.
- the flow on the housing wall is diverted into the side channel, where it describes a screw path and re-enters the impeller after a short distance. This process is repeated for a liquid particle on the way from the suction to the pressure port, depending on the throughput, e.g.
- the liquid is accelerated to the circumferential speed of the wheel in addition to the radial direction. With this peripheral speed and the superimposed circulation speed, the liquid particle passes from the impeller into the side channel.
- the circulation component is only slightly slowed down by wall friction, whereas the peripheral component is slowed down considerably and essentially only as a result of the pressure build-up. The loss of kinetic energy of the resulting flow is always compensated for in the impeller.
- Pumps to be used according to the invention are e.g. manufactured by Hermetic-Pumpen GmbH, Germany.
- the pump chamber and the drive chamber can not necessarily be arranged one above the other, but preferably next to one another according to the invention. The latter necessarily causes horizontally mounted drive shafts, what longer terms guaranteed.
- the drive space, including the drive can be designed as in FIG. 3 of EP-A 1092874.
- the pump chamber is preferably made of stainless steel 1.4571 (according to DIN EN 10020). But it can also be made of plastic, concrete, ceramic or cast iron. SiC is preferred as the material for the sliding elements (mechanical seals).
- pumps without a drive shaft such as e.g. Diaphragm pumps, preferably compressed air diaphragm pumps, can be used. They also meet the requirement profile on which the object according to the invention is based (no contact of the liquid to be conveyed with mechanically stressed parts such as bearings, no leaks for the liquid F). However, they are not as efficient as the feed pumps to be used according to the invention.
- diaphragm pumps work like piston pumps, whereby a flexible diaphragm, which can be made of plastic or stainless steel, represents the piston.
- the membrane - whose lifting and lowering alternately draws and ejects the liquid via valves - is achieved by direct coupling with e.g. a drive linkage in motion.
- the membrane completely separates the working area (pumping area) from the drive.
- the sealing problem relevant to the invention therefore does not exist with them.
- any drive bearings are necessarily outside the work area.
- Typical operating data of feed pumps to be used according to the invention are:
- Viscosity of the liquid F (mPas): 0.5 to 50 speed (min " 1 ): 800 to 3000
- a bearing is to be understood in general as a machine element for carrying or guiding machine parts that are movable relative to one another, wherein it absorbs the forces that occur and transfers them to the housing, component or foundation.
- the process according to the invention is particularly suitable when the (meth) acrylic monomer is (meth) acrylic acid. Especially when the (meth) acrylic acid content is> 95% by weight. It- However, it is also suitable if the liquid to be conveyed contains other unsaturated monomers, for example (meth) acrolein, instead of (meth) acrylic monomers.
- a gaseous product gas mixture with the following composition was generated by two-stage catalytic gas phase oxidation of propylene 10 with molecular oxygen:
- Remaining amount up to 100% by weight propionic acid, furfural, propane, 20 propene, nitrogen, oxygen and carbon oxides.
- This gaseous product gas mixture was cooled in a spray cooler (direct cooler, quench) by injecting crude acrylic acid (4000 l / h) (the temperature of the crude acrylic acid was
- the crude acrylic acid used for direct cooling contained 1.1% by weight of water and 1000% by weight of phenothiazine as a polymerization inhibitor as starting concentrations).
- the crude acrylic acid used for quenching was circulated by means of a circulation pump over a heat exchanger and was continually added to the
- a centrifugal pump according to the invention of the type Hermetic pump, model HK (manufacturer: Hermetic-Pumpen GmbH, DE) was used as the circulation pump.
- 2-ethylhexanol was used as the barrier liquid.
- the leak rate was 14 g 2-ethylhexanol per day.
- the barrier liquid was under a pressure of 4 bar.
- the separation area was equipped with double-acting mechanical seals made of SiC (material of the rotating disc).
- the drive shaft was mounted horizontally.
- the cooled gas mixture leaving the spray cooler and containing the acrylic acid to be separated was led below the bottom tray into a rectification column equipped with 27 bubble trays and at the top of the column with a spray condenser.
- the temperature at the top of the column was 20 ° C. and the bottom temperature of the rectification column was 90 ° C.
- the condensate obtained in the spray condenser which mainly consisted of water, was discharged and after the addition of 300 ppm by weight hydroquinone and cooling in a heat exchanger as a spray liquid at a temperature of 17 ° C. via the spray condenser as a return to the top column bottom applied.
- the reflux ratio was 4.
- the crude acrylic acid obtained in the bottom of the rectification column was partly discharged (430 g / h), partly (250 g / h) after the addition of 1000 ppm by weight of phenothiazine for the purpose of inhibiting the rectification column from polymerizing onto the 13th tray of the column (from below calculated) and partially (approx. 15 l / h) first passed through a heat exchanger and then returned at a temperature of 100 ° C. to the second bottom of the column (calculated from below) to adjust the column temperature.
- Another portion of the crude acrylic acid obtained in the column bottom was fed to the quench in a level-controlled manner via a heat exchanger upstream of the quench at a temperature of 102 ° C.
- the crude acrylic acid removed contained 97.2% by weight of acrylic acid, 1.6% by weight of acetic acid, 0.024% by weight of propionic acid, 0.4% by weight of maleic acid, 0.005% by weight of acrolein, 0.02% by weight .-% furfural and 1.2% by weight water as well as 500 ppm by weight phenothiazine and 300 ppm by weight hydroquinone.
- Example 2 The procedure was as in Example 1. However, a compressed air diaphragm pump of the type Almatec pump series FP-100, version polytetrafluoroethylene (PTFE) from Almatec Maschinenbau GmbH, DE was used as the circulation pump in the quench. The pump was made entirely of Teflon. Here, too, the entire quench circuit, including the pump, was still free of polymer deposits after 10 days.
- PTFE polytetrafluoroethylene
- Example 1 A Hermetic-Pump type ZML hermetic gear pump from Hermetic-Pumpen GmbH, DE was used as the circulation pump in the quench. With a gear pump, the liquid to be pumped is displaced by mutually rotating and intermeshing gearwheels and thereby conveyed further.
- the drive shafts of the gear wheels were also stored in the pump room due to their weight.
- These plain bearings were made from graphite-bonded coal.
- the gear pump was blocked by polymer formation within less than 10 hours of operation.
- Example 1 A centrifugal pump of the type CP pump, pump type MKP 32-160 (CP-Pumpen AG, DE) was used as the circulation pump in the quench. Pump room and drive room are separated by a metal wall. The drive in the pump room was magnetically coupled. The drive shaft was supported in the pump room with a shaft bearing made of SiC.
- the centrifugal pump was blocked by polymer formation within less than 10 hours of operation.
- Example 1 A centrifugal pump of the type Hermetic Pump Model HK (Hermetic Pumpen GmbH) was used as the circulation pump in the quench.
- the pump was converted according to the invention using a dry-running, contact-free and gas-lubricated shaft seal and was equipped with double-acting mechanical seals made of SiC.
- Air was used as the sealing gas, which was under a pressure of 4 bar.
- the leak rate was 100 Nml / h.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10228859 | 2002-06-27 | ||
DE10228859A DE10228859A1 (de) | 2002-06-27 | 2002-06-27 | Verfahren zum Fördern einer wenigstens ein (Meth)acrylmonomeres enthaltenden Flüssigkeit F |
PCT/EP2003/006516 WO2004003389A1 (de) | 2002-06-27 | 2003-06-20 | Verfahren zum fördern einer wenigstens ein (meth)acrylmonomeres enthaltenden flüssigkeit f |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1520108A1 true EP1520108A1 (de) | 2005-04-06 |
Family
ID=29723502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03738074A Withdrawn EP1520108A1 (de) | 2002-06-27 | 2003-06-20 | Verfahren zum fördern einer wenigstens ein (meth)acrylmonomeres enthaltenden flüssigkeit |
Country Status (8)
Country | Link |
---|---|
US (1) | US7284951B2 (zh) |
EP (1) | EP1520108A1 (zh) |
JP (1) | JP2005530954A (zh) |
CN (1) | CN100460690C (zh) |
AU (1) | AU2003245976A1 (zh) |
DE (1) | DE10228859A1 (zh) |
MY (1) | MY141484A (zh) |
WO (1) | WO2004003389A1 (zh) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006045089A1 (de) | 2006-09-21 | 2008-03-27 | Basf Ag | Verfahren zum Durchmischen einer in einem im wesentlichen abgeschlossenen Behälter befindlichen Flüssigkeit oder Mischung aus einer Flüssigkeit und einem feinteiligen Feststoff |
DE102006045088A1 (de) | 2006-09-21 | 2008-03-27 | Basf Ag | Verfahren zum Durchmischen einer in einem im wesentlichen abgeschlossenen Behälter befindlichen Flüssigkeit oder Mischung aus einer Flüssigkeit und einem feinteiligen Feststoff |
DE102008001435A1 (de) | 2008-04-28 | 2009-10-29 | Basf Se | Verfahren zur Übertragung von Wärme auf eine monomere Acrylsäure, Acrylsäure-Michael-Oligomere und Acrylsäurepolymerisat gelöst enthaltende Flüssigkeit |
DE102008054587A1 (de) * | 2008-12-12 | 2010-06-17 | Basf Se | Verfahren zur Rückspaltung von in einer Flüssigkeit F enthaltenen Michael-Addukten, die bei der Herstellung von Acrylsäure oder deren Ester gebildet wurde |
DE102009000987A1 (de) | 2009-02-18 | 2010-04-15 | Basf Se | Verfahren zum reinigenden Abtrennen einer chemischen Zielverbindung aus einer Suspension ihrer Kristalle in Mutterlauge |
DE102009027401A1 (de) | 2009-07-01 | 2010-02-18 | Basf Se | Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung |
WO2011000808A2 (de) | 2009-07-01 | 2011-01-06 | Basf Se | Verfahren der abtrennung von acrylsäure aus dem produktgasgemisch einer heterogen katalysierten partiellen gasphasenoxidation wenigstens einer c3-vorläuferverbindung |
DE102010001228A1 (de) | 2010-01-26 | 2011-02-17 | Basf Se | Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung |
US8461383B2 (en) | 2009-10-16 | 2013-06-11 | Basf Se | Process for starting up a separating process for purifying removal of acrylic acid crystals from a suspension S of crystals thereof in mother liquor |
DE102010030279A1 (de) | 2010-06-18 | 2010-10-28 | Basf Se | Verfahren der Inbetriebnahme eines Trennverfahrens zur reinigenden Abtrennung von Acrylsäurekristallen aus einer Suspension S ihrer Kristalle in Mutterlauge |
DE102009045767A1 (de) | 2009-10-16 | 2010-08-12 | Basf Se | Verfahren der Inbetriebnahme eines Trennverfahrens zur reinigenden Abtrennung von Acrylsäurekristallen aus einer Suspension S ihrer Kristalle in Mutterlauge |
DE102010000706A1 (de) | 2010-01-06 | 2010-10-14 | Basf Se | Verfahren zum Fördern eines Stroms einer (Meth)acrylmonomere enthaltenden Flüssigkeit F |
DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
DE102018205931A1 (de) * | 2018-04-18 | 2019-10-24 | Henkel Ag & Co. Kgaa | Pumpe mit einer Produktkammer |
WO2022096422A1 (de) | 2020-11-03 | 2022-05-12 | Basf Se | Fördern einer (meth)acrylmonomere enthaltenden flüssigkeit mittels einer pumpe |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1206830A (en) * | 1967-02-08 | 1970-09-30 | Borg Warner | Mechanical seal with flushing arrangement |
JPH0875012A (ja) * | 1994-09-06 | 1996-03-19 | Toagosei Co Ltd | 回転機器の軸封部分における重合防止方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2645755A1 (de) * | 1976-10-09 | 1978-04-13 | Klein Schanzlin & Becker Ag | Wellendichtung |
EP0265264A3 (en) * | 1986-10-23 | 1989-10-11 | Denis Michael William Winslow | Seal protection apparatus |
US5553867A (en) * | 1995-04-21 | 1996-09-10 | Environamics Corporation | Triple cartridge seal having one inboard and two concentric seals for chemical processing pump |
SE518871C2 (sv) * | 1996-11-14 | 2002-12-03 | Flygt Ab Itt | Plantätningsarrangemang |
JP2001114705A (ja) * | 1999-10-12 | 2001-04-24 | Nippon Shokubai Co Ltd | 易重合性化合物の移送方法 |
DE10224341A1 (de) | 2002-05-29 | 2003-07-17 | Basf Ag | Verfahren zur Herstellung von Acrylsäure und/oder deren Ester sowie von Propionsäure und/oder deren Ester im Verbund |
-
2002
- 2002-06-27 DE DE10228859A patent/DE10228859A1/de not_active Withdrawn
-
2003
- 2003-06-10 MY MYPI20032161A patent/MY141484A/en unknown
- 2003-06-20 EP EP03738074A patent/EP1520108A1/de not_active Withdrawn
- 2003-06-20 JP JP2004516629A patent/JP2005530954A/ja active Pending
- 2003-06-20 US US10/516,498 patent/US7284951B2/en active Active
- 2003-06-20 CN CNB03815093XA patent/CN100460690C/zh not_active Expired - Lifetime
- 2003-06-20 WO PCT/EP2003/006516 patent/WO2004003389A1/de active Application Filing
- 2003-06-20 AU AU2003245976A patent/AU2003245976A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1206830A (en) * | 1967-02-08 | 1970-09-30 | Borg Warner | Mechanical seal with flushing arrangement |
JPH0875012A (ja) * | 1994-09-06 | 1996-03-19 | Toagosei Co Ltd | 回転機器の軸封部分における重合防止方法 |
Non-Patent Citations (1)
Title |
---|
See also references of WO2004003389A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20050232782A1 (en) | 2005-10-20 |
CN1666024A (zh) | 2005-09-07 |
DE10228859A1 (de) | 2004-01-15 |
US7284951B2 (en) | 2007-10-23 |
CN100460690C (zh) | 2009-02-11 |
MY141484A (en) | 2010-04-30 |
WO2004003389A1 (de) | 2004-01-08 |
AU2003245976A1 (en) | 2004-01-19 |
JP2005530954A (ja) | 2005-10-13 |
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