EP1439752B1 - Traitement d'une matiere textile au moyen d'un insecticide - Google Patents

Traitement d'une matiere textile au moyen d'un insecticide Download PDF

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Publication number
EP1439752B1
EP1439752B1 EP02777610A EP02777610A EP1439752B1 EP 1439752 B1 EP1439752 B1 EP 1439752B1 EP 02777610 A EP02777610 A EP 02777610A EP 02777610 A EP02777610 A EP 02777610A EP 1439752 B1 EP1439752 B1 EP 1439752B1
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EP
European Patent Office
Prior art keywords
insecticide
composition
fabric material
insecticide composition
application
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP02777610A
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German (de)
English (en)
Other versions
EP1439752A1 (fr
Inventor
Albin Alexander Wladyslaw Baecker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siamdutch Mosquito Netting Co Ltd
Original Assignee
Siamdutch Mosquito Netting Co Ltd
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Application filed by Siamdutch Mosquito Netting Co Ltd filed Critical Siamdutch Mosquito Netting Co Ltd
Publication of EP1439752A1 publication Critical patent/EP1439752A1/fr
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Anticipated expiration legal-status Critical
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol

Definitions

  • THIS INVENTION relates to the application of an insecticide to a fabric material.
  • an insecticide to a fabric material is required in relation to fabric materials used for tents, clothing items, bed nets, tsetse-fly traps, and the like, particularly where these items are used to provide personal protection against insects and where this protection can be enhanced by killing the insects.
  • the invention as hereinafter referred to provides particularly for the application of an insecticide to a fabric material suitable to form a mosquito net, the invention as hereinafter defined must be interpreted to extend to all other applications which can benefit from the application of an insecticide to a fabric material, and to which parameters as hereinafter set out apply.
  • the application of an insecticide to the fabric material forming the net must provide for the insecticide to remain bioavailable for killing targeted insects, particularly mosquitoes, over an extended time period and particularly after several "washes" of the material.
  • the binder By providing for the insecticide to be released continuously, the binder also allows the insecticide to be washed out. As such, the binders used to date for the above purpose have not proven satisfactory, insofar as the associated insecticides lose their capability to kill insects after a very limited number of washes, i.e. between three and twenty washes. Clearly, where a binder does not permit the insecticide to be washed out, the insecticide may not be released at a sufficient rate and non-bioavailability of the insecticide can thus occur.
  • GB 2 202 243 discloses a method of treating textiles with a composition comprising ammonium polyphosphate, a polyvinyl acetate ethylene copolymer (binding agent), an insecticide and an anionic or nonionic surfactant which assists in dispersing ammonium polyphosphates over the surface to be treated.
  • US 4 623 540 discloses a controlled release insecticide composition comprising a film-forming resin, e.g. a copolymer of styrene and 2-ethylhexyl acrylate and a surfactant which aids in the emulsification of the composition when they are added to water by providing adequate dispersion.
  • JP 61015801 discloses a preparation for coating cloth or nonwoven cloth comprising an insecticide, an emulsion type resin such as ethylenevinyl acetate copolymer and a non-ionic or anionic surfactant.
  • ZA 8 005 769 shows the release of agrochemicals is controlled by using a polymeric additive capable of imparting hydrophobicity e.g. a styrene-2-ethylhexylacrylate copolymer as well as a certain amount of wetting agent capable of reducing the hydrophobicity to a required degree.
  • an insecticide composition for application to a fabric material which composition comprises a mixture including an insecticide; a copolymeric binder in a liquid form that permits application of the composition to a fabric material and that, after drying and while the fabric material is dry, imparts hydrophobicity to the insecticide; and a dispersing agent that, after application of the composition to a fabric and upon wetting of the fabric, reduces the hydrophobicity imparted to the insecticide by the binder to permit limited insecticide release, said dispersing agent is selected from the group including sodium silicates, polyphosphates and lignin derivatives
  • the insecticide of the insecticide composition may be either one of a single insecticide and a mixture of insecticides selected from a group of insecticides that is suitable for application to mosquito nets.
  • This group of insecticides may include synthetic pyrethroids such as those known in the trade as Alphacypermethrin, Cyfluthrin, Deltamethrin, Etofenprox and Permethrin, other pyrethroids such as that known in the trade as Bifenthrin and non-pyrethroids such as that known in the trade as Carbosulphan.
  • the insecticide also may be included in the insecticide composition as one of a water based insecticide concentrate and a solvent based insecticide concentrate, insecticide concentrates known in the trade as Cislin and K-Orthrine being considered suitable.
  • insecticide forming part of the insecticide composition of the invention also may be selected from other groups suitable for different applications.
  • the copolymeric binder of the insecticide composition of the invention may be prepared as a copolymer emulsion that is derived by an emulsion polymerisation technique from monomers selected from at least one of the groups including:
  • the copolymeric binder for use in the composition, may be prepared as a copolymer emulsion that is derived from monomers selected from the group including:
  • the copolymeric binder of the insecticide composition typically is a styrene 2-ethylhexylacrylate copolymer emulsion having a 50% total solids content prior to formulation as the insecticide composition for application to a fabric material.
  • the quantity of copolymeric binder may be variable and particularly is such that in relation to the quantity of insecticide forming part of the insecticide composition, it can impart required hydrophobicity to the insecticide, after application and drying of the composition on a fabric material.
  • Various other monomers as listed above can be copolymerised to form copolymeric binders having the required properties needed to form the copolymeric binder component of the insecticide composition of the invention.
  • the dispersing agent as used in the insecticide composition of the invention comprises particularly a surface active agent that, with the insecticide composition applied to a fabric material, provides maximum separation of insecticide particles when the fabric is wetted.
  • the dispersing agent is a polymeric electrolyte selected from a group including sodium silicates, polyphosphates and lignin derivatives.
  • the specific dispersing agent selected may be determined by the particular polymeric binder to be used as part of the composition of the invention, considering particularly the hydrophilic properties of the dispersing agent and the hydrophobic properties of the copolymeric binder.
  • the components of the insecticide composition of the invention can be separately provided, or can be provided in different combinations, requiring mixing and/or dilution before application.
  • the invention accordingly extends also to the individual components when provided specifically to form the insecticide composition of the invention.
  • the insecticide composition of the invention may be applied to fabric materials before their formation into required products, i.e. while still in a yarn or sheet form, or after formation of relevant products.
  • Typical fabrics to which the insecticide composition of the invention may be applied may include the fabric materials commonly used for products such as tents, mosquito nets, and the like. As such, the insecticide composition of the invention may be particularly suitable for application to polyester netting as used for mosquito nets.
  • the insecticide composition of the invention may include also an adjuvant that, in use when applied as part of the insecticide composition to a fabric material, can serve to overcome resistance of particular insects to the insecticide included in the composition.
  • the adjuvant may be piperonyl butoxide.
  • the insecticide composition of the invention may include also an anti-foam agent.
  • the anti-foam agent is a silicone anti-foam agent.
  • the insecticide composition of the invention may include UV blockers for protecting UV sensitive insecticides, as well as a disclosing agent that can serve to identify when a fabric to which the composition has been applied, requires application of fresh insecticide composition.
  • the disclosing agent may be of a type that identifies when a fabric to which the composition has been applied requires fresh application of fresh insecticide composition by colour variations.
  • an insecticide composition in accordance with the present invention and a mosquito net of a fabric material, the insecticide composition being applied to the fabric material forming the mosquito net.
  • a particular example of an insecticide composition which is suitable for use in the treatment of polyester netting as used for mosquito nets is described hereafter, as well as the mode of use of the insecticide composition and the mode of release of the insecticide forming part of the composition, following application of the composition to a mosquito net.
  • the insecticide composition suitable for use in the treatment of polyester netting as used for mosquito nets, in accordance with the invention, particularly includes as insecticide 1,0 parts dry microcrystalline Deltamethrin; as a copolymeric binder 25.0 parts wet styrene 2-ethylhexylacrylate copolymer emulsion at 50% total solids content; as dispersing agent 73,5 parts wet 20% solution of sodium hexametaphosphate; and 1,5 parts wet silicone anti-foam agent at 20% solids content.
  • the insecticide composition is thus provided in a wet form in which it can be conveniently applied to the polyester netting to be treated, typically by a conventional application process such as by dipping, spraying, brushing, and the like. Following the application of the insecticide composition to the polyester netting it is allowed to dry, the copolymeric binder imparting sufficient hydrophobicity to the insecticide to prevent effectively the release of the insecticide from the composition as applied, i.e. from the netting, while retained in a dry form.
  • the dispersing agent Upon wetting of the netting, the dispersing agent will reduce the hydrophobicity imparted to the insecticide, permitting limited release of the insecticide, effectively to the surface of the composition as applied to the polyester netting and, as such, effectively to the surface of the polyester netting.
  • the quantity of insecticide so released particularly will be determined by the quantity of dispersing agent included in the insecticide composition.
  • a precalculated and precisely controlled rate of insecticide release as governed and maintained by the specific chemical reaction kinetics of that release, can be provided for.
  • the chemical reaction kinetics may be particularly predetermined by virtue of being preset by the intimate contact of the types, amounts and proportions of the chemical reagents specifically selected to make up the composition. Different conditions and requirements can thus be taken into account in order to accommodate the formulation of the insecticide composition.
  • the insecticide available on the surface of the polyester netting will fulfil the purpose of killing mosquitoes for as long sufficient insecticide is "exposed".
  • the washing process will provide for additional insecticide to be released from the composition as applied to the mosquito net, thus rendering the net effective for killing mosquitoes for an additional time period.
  • the Applicants have established that the mosquito net can remain effective for killing mosquitoes even after fifty washes carried out in accordance with the World Health Organization Standard Methods.
  • Soln 1 A Dispersant White spirits 92.60% (m/m) Phosphatides in form of soya lecithin 0.74% B Monomer/Copolymer Binder Styrene-2ethylhexylacrylate 0.19% Soln 2: C Insecticide Acetone 2.52% Deltamethrin 0.15% White Spirits 3.80% Total 100.00%
  • Soln 1 A Dispersant White spirits 46.08% Phosphatides in form of soya lecithin 0.37% B Surfactant Synperonic NP9 0.15% C Monomer/Copolymer Binder Styrene-2ethylhexylacrylate 0.10% Soln 2: D Insecticide Acetone 1.25% Deltamethrin 0.15% White Spirits 1.90% Soln 3: E Emulsifying Medium Water 49.85% Synperonic NP9 0.15% Total 100.00%
  • the insecticide composition as described above also may include UV blockers for protecting insecticides that could be exposed to deterioration as a result of UV radiation, whereas a disclosing agent also can form a part of the composition.
  • the disclosing agent may be of a type that can indicate when re-treatment of a fabric material is necessary, the insecticide composition of the invention clearly being suitable to permit the multiple treatment of fabric materials.
  • the invention extends also to particular fabric materials treated with an insecticide composition, in accordance with the invention, as well as to particular products and, particularly, mosquito nets, formed of fabric materials treated with, or rendered suitable for treatment with, the insecticide composition of the invention.

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Claims (16)

  1. Composition insecticide à appliquer sur un matériau textile, comprenant un mélange de :
    un insecticide,
    un liant copolymère sous forme liquide, qui permet l'application de la composition sur un matériau textile et qui, après séchage et lorsque le matériau textile est sec, confère un caractère hydrophobe à l'insecticide, et
    un agent de dispersion, qui après application de la composition sur le textile et par mouillage du textile, réduit le caractère hydrophobe conféré à l'insecticide par le liant, pour permettre une libération limitée de l'insecticide, ledit agent de dispersion est un électrolyte polymère choisi parmi le groupe comprenant les silicates de sodium, les polyphosphates et des dérivés de la lignine.
  2. Composition insecticide selon la revendication 1, dans laquelle l'insecticide est un seul insecticide ou un mélange d'insecticides choisis parmi un groupe d'insecticides, qui est approprié pour une application sur des moustiquaires.
  3. Composition insecticide selon la revendication 2, dans laquelle le groupe d'insecticides comprend les pyréthroïdes synthétiques comme ceux connus sous les marques Alphacyperméthrine, Cyfluthrine, Deltaméthrine, Etofenprox et Perméthrine, d'autres pyréthroïdes comme ceux connus sous la marque Bifenthrine et des non-pyréthroïdes comme ceux connus sous la marque Carbosulphan.
  4. Composition insecticide selon l'une quelconque des revendications 1 à 3, dans laquelle l'insecticide est incorporé sous forme d'un concentré insecticide à base d'eau et d'un concentré insecticide à base de solvant.
  5. Composition insecticide selon l'une quelconque des revendications précédentes, dans laquelle le liant copolymère à utiliser dans la composition est préparée sous forme d'une émulsion copolymère, qui dérive d'une technique de polymérisation en émulsion à partir de monomères choisis parmi au moins un des groupes suivants :
    a) des esters vinyliques d'acide aliphatique ayant 1-18 atomes de carbone, comme l'acétate de vinyle et le versatate de vinyle ;
    b) des esters acrylate et méthacrylate d'alcools ayant 1-18 atomes de carbone, comme l'acrylate de butyle, l'acrylate de 2-éthylhexyle et l'acrylate de méthyle, et
    c) des hydrocarbures mono- ou diéthyléniquement insaturés, comme le styrène et des diènes aliphatiques comme le butadiène.
  6. Composition insecticide selon la revendication 5, dans laquelle le liant copolymère, à utiliser dans la composition, est préparé sous forme d'une émulsion copolymère, qui dérive des monomères choisis parmi le groupe :
    i) ester vinylique de l'acide versatique avec acrylate de butyle ;
    ii) ester vinylique de l'acide versatique avec acrylate de 2-éthylhexyle ;
    iii) méthacrylate de méthyle avec acrylate de 2-éthylhexyle ;
    iv) styrène avec acrylate de 2-éthylhexyle ;
    v) styrène avec butadiène ;
    vi) butadiène avec acrylonitrile ;
    vii) styrène avec acrylate de butyle, et
    viii) acétate de vinyle avec acrylate de 2-éthylhexyle.
  7. Composition insecticide selon la revendication 6, dans laquelle le liant copolymère est une émulsion copolymère styrène-acrylate de 2-éthyl-hexyle, ayant une teneur totale en matières solides de 50% avant formulation comme une composition insecticide à appliquer sur un matériau textile.
  8. Composition insecticide selon l'une quelconque des revendications précédentes, dans laquelle l'agent dispersant comprend un agent tensioactif, qui avec la composition insecticide appliquée sur un matériau textile, procure une séparation maximale des particules d'insecticide lorsque la matériau textile est mouillé.
  9. Composition insecticide selon l'une quelconque des revendications précédentes, qui comprend un adjuvant, qui lors de l'utilisation lorsqu'il est appliqué comme partie d'une composition insecticide sur un matériau textile, peut servir à surmonter la résistance d'insectes particuliers à l'insecticide incorporé dans la composition.
  10. Composition insecticide selon la revendication 9, dans laquelle l'insecticide est l'insecticide connu sous la marque Deltaméthrine, qui est procuré pour tuer un type particulier de moustiques, et l'adjuvant est le butoxyde de pipéronyle.
  11. Composition insecticide selon l'une quelconque des revendications précédentes, dans laquelle le mélange formant la composition comprend un agent anti-mousse.
  12. Composition insecticide selon la revendication 11, dans laquelle l'agent anti-mousse est un agent anti-mousse silicone.
  13. Composition insecticide selon l'une quelconque des revendications précédentes, dans laquelle le mélange formant l'insecticide comprend un agent bloquant les U.V..
  14. Composition insecticide selon l'une quelconque des revendications précédentes, dans laquelle le mélange formant la composition comprend un agent de révélation, qui peut servir à déterminer lorsqu'un tissu sur lequel la composition a été appliquée, nécessite l'application de composition fraíche.
  15. Composition insecticide selon la revendication 1, qui comprend un mélange de :
    comme insecticide, 1,0 partie de Deltaméthrine microcristalline sèche ;
    comme liant copolymère, 25,0 parties d'émulsion humide de copolymère styrène-acrylate de 2-éthylhexyle à une teneur totale en matières solides de 50% ;
    comme agent de dispersion, 73,5 parties d'une solution humide à 20% d'hexamétaphosphate de sodium ; et
    1,5 partie d'agent anti-mousse silicone humide à une teneur en matières solides de 20%.
  16. Combinaison d'une composition insecticide selon l'une quelconque des revendications 1 à 15 et d'un moustiquaire en un matériau textile, la composition insecticide étant appliquée sur le matériau textile formant le moustiquaire.
EP02777610A 2001-10-25 2002-10-21 Traitement d'une matiere textile au moyen d'un insecticide Revoked EP1439752B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA200108812 2001-10-25
ZA200108812 2001-10-25
PCT/IB2002/004327 WO2003034823A1 (fr) 2001-10-25 2002-10-21 Traitement d'une matiere textile au moyen d'un insecticide

Publications (2)

Publication Number Publication Date
EP1439752A1 EP1439752A1 (fr) 2004-07-28
EP1439752B1 true EP1439752B1 (fr) 2005-08-24

Family

ID=25589358

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02777610A Revoked EP1439752B1 (fr) 2001-10-25 2002-10-21 Traitement d'une matiere textile au moyen d'un insecticide

Country Status (5)

Country Link
EP (1) EP1439752B1 (fr)
AT (1) ATE302546T1 (fr)
DE (1) DE60205767D1 (fr)
WO (1) WO2003034823A1 (fr)
ZA (1) ZA200403868B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
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DE102007027063A1 (de) * 2007-06-12 2008-12-18 Derin-Holzapfel & Co. Grundbesitz Und Beteiligungs Kg Gebilde umfassend einen Vektorenschutz sowie dessen Herstellung und Verwendung
WO2011131742A1 (fr) * 2010-04-20 2011-10-27 Ppg Coatings Europe B.V Liant pour un revêtement antisalissure auto-polissant
CN107258809A (zh) * 2017-07-21 2017-10-20 无锡市林业总站 桔小实蝇食物引诱剂与化学药剂的协同防治方法

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US20050132500A1 (en) * 2003-12-22 2005-06-23 Basf Aktiengesellschaft Composition for impregnation of fibers, fabrics and nettings imparting a protective activity against pests
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US20080242174A1 (en) 2007-03-29 2008-10-02 Invista North America S.A R.L. Wash resistant synthetic polymer compositions containing active compounds
ES2381900T3 (es) * 2007-06-12 2012-06-01 Basf Se Formulación acuosa y procedimiento de impregnación de materiales inertes para impartir una actividad protectora frente a plagas
DK2211662T3 (da) * 2007-06-29 2014-08-11 Vestergaard Frandsen Sa Insektdræbende barriere delvis med synergist
CN103479052B (zh) * 2007-06-29 2015-04-15 韦斯特高凡德森有限公司 部分带有协同剂的杀虫性障壁
MX2011000266A (es) 2008-07-30 2011-03-03 Basf Se Redes impregnadas con insecticidas y su uso para la proteccion contra parasitos.
TW201028088A (en) 2008-08-06 2010-08-01 Vestergaard Frandsen Sa Insecticidal polymer matrix comprising PBO and DM
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WO2011131742A1 (fr) * 2010-04-20 2011-10-27 Ppg Coatings Europe B.V Liant pour un revêtement antisalissure auto-polissant
CN102933666A (zh) * 2010-04-20 2013-02-13 Ppg涂料欧洲有限责任公司 用于自抛光抗污涂料的粘合剂
US9382431B2 (en) 2010-04-20 2016-07-05 Ppg B.V. Coating composition
CN102933666B (zh) * 2010-04-20 2018-10-09 Ppg涂料欧洲有限责任公司 用于自抛光抗污涂料的粘合剂
CN107258809A (zh) * 2017-07-21 2017-10-20 无锡市林业总站 桔小实蝇食物引诱剂与化学药剂的协同防治方法

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ATE302546T1 (de) 2005-09-15
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WO2003034823A1 (fr) 2003-05-01
DE60205767D1 (de) 2005-09-29

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