EP1353572B1 - Verfahren zum behandeln von tabak - Google Patents
Verfahren zum behandeln von tabak Download PDFInfo
- Publication number
- EP1353572B1 EP1353572B1 EP01964985A EP01964985A EP1353572B1 EP 1353572 B1 EP1353572 B1 EP 1353572B1 EP 01964985 A EP01964985 A EP 01964985A EP 01964985 A EP01964985 A EP 01964985A EP 1353572 B1 EP1353572 B1 EP 1353572B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tobacco
- steam
- treatment
- moisture
- casing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000208125 Nicotiana Species 0.000 title claims description 75
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims description 75
- 238000000034 method Methods 0.000 title claims description 33
- 238000007669 thermal treatment Methods 0.000 claims description 11
- 235000000346 sugar Nutrition 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims 2
- 239000007924 injection Substances 0.000 claims 2
- 230000035484 reaction time Effects 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 238000007796 conventional method Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 229910017464 nitrogen compound Inorganic materials 0.000 description 5
- 150000002830 nitrogen compounds Chemical class 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 229960002715 nicotine Drugs 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 244000303040 Glycyrrhiza glabra Species 0.000 description 1
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003636 conditioned culture medium Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 235000011477 liquorice Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 150000003216 pyrazines Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/04—Humidifying or drying tobacco bunches or cut tobacco
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
Definitions
- the invention relates to a method for treating tobacco, in particular Burley tobacco, by applying Casing and subsequent thermal treatment.
- casings represents a common step in the processing of leaf tobacco before cutting
- the aim of casing treatment is to improve the Processing ability as well as the taste characteristics of the tobacco material.
- Common ingredients of casings are Humectants, e.g. Glycols or glycerin, sugars as well solid natural substances such as cocoa or liquorice. Height Viscosity and the solids content of casings complicate one desired, uniform penetration of the tobacco with the Casing components.
- To improve the tobacco the task of heated takes place Casings together with a moistening by water and Steam in aggregates called casing drums.
- Burley tobaccos generally have relatively high levels of Nitrogen compounds at the same time low sugar contents on. For this reason, can often only by applying zukker Anlagenn Casings in combination with a subsequent thermal Treatment can be achieved an acceptable smoky taste.
- Reaction products such as e.g. Pyrazines are formed, which contribute to the improvement of sensory quality.
- a so-called belt dryer with severalnic cooling zones used in the tobacco of about 30% initial moisture dried to about 5% moisture. To further Processing, especially for cutting, the tobacco must subsequently be moistened again to about 16% to 22%.
- US 5 755 238 describes a method for rapid drying, Cool and rewet with the help of one in several treatment zones subdivided drying unit and the rewet in a separate steam tunnel.
- the hot air temperature of the dryer is about 105 ° C to 115 ° C and the total cycle time about 60 seconds.
- US 4,004,594 discloses a method of conditioning Tobacco, in particular Burley tobacco, impregnating the Tobacco particles with casing, a thermal treatment for expelling of the nitrogen or nitrogen compounds and the Setting the desired moisture content provides.
- the treatment plant consists of a dosing unit, a casing drum, a preconditioning unit for treatment with steam and aggregates for heating, cooling and rewetting the tobacco.
- the tobacco humidities after the dosing unit amount to 14% to 20%, preferably 18%, after the drum casing 30% to 42%, preferably 32%, after preconditioning about 35%, after heating 4% to 7% and after rewetting about 18% to 22%.
- the Pre-conditioning unit is treated with saturated steam of 2.5 bar to 3.5 bar, resulting in a tobacco temperature of about 70 ° C, to improve the penetration of the casing in the To achieve tobacco leaf.
- US 3 402 479 describes a tunnel-like apparatus for Transport and treatment of nitrogen-rich tobacco with Zones for pre-drying, for heating the tobacco without loss of moisture through the use of a suitably conditioned medium and for cooling the material to be treated.
- the entry humidity of the tobacco material is 40% to 50%, the temperature of the medium after predrying approx. 100 ° C and the discharge moisture approx. 16% to 18%.
- the steaming is preferably carried out so that the Tobacco over a period of 0.1 minutes to 10 minutes in As intensive as possible contact with the treatment medium is brought.
- the ratio of the mass flow rate of steam to tobacco is preferably set in a range of 0.1 to 0.5.
- the treatment is in a so-called steam tunnel carried out.
- steam tunnel carried out.
- aggregates are for example of the companies Sagemüller GmbH, Bockhorn or HAUNI Maschinenbau AG, Hamburg available.
- the humidity of the changes Tobacco during steam treatment depending on the choice of process parameters as pressure of the steam and residence time (exposure time of the Steam) only by a few percentage points.
- the tobacco treated by the process according to the invention clearly Homogeneous moisture distribution as such, according to the conventional method was treated with a belt dryer.
- the invention treated Tobacco after steam treatment and cooling with medium volatile Aromastoffen acted in the form of a so-called topdressing which is preferably alcoholic.
- the tobacco alone or after mixing with other tobaccos without further moistening or drying steps fed to the cutting process.
- the so-called fluidized bed dryer (Example 1) represents the application of a conventional method and is based on the principle of the vibrating conveyor with holes in the bottom plate, flows through the material to be treated via the hot air.
- the input humidity (Entry moisture) of the leaf tobacco was uniform 22%.
- Table 1 shows the applied hot air temperatures, the corresponding residence times and the discharge humidities (ie tobacco humidities after treatment in the fluidized bed dryer) of the leaf tobacco.
- Parameter combinations fluidized bed dryer No. Hot air temperature (° C) Residence time (sec) Input humidity (%) Discharge moisture (%) 1 130 15 22 6 2 150 30 22 3 3 200 40 22 ⁇ 1
- the treatment unit used was a conventional steam tunnel with a vibrating conveyor in which hot steam (saturated steam) flowing out of bores in a bottom plate interacts with the leaf tobacco; In principle, there is atmospheric pressure (open system) in the steam tunnel. The pressure of the steam before feeding into the steam tunnel was uniformly about 7 bar and the mass ratio of tobacco to steam 0.2. Table 2 shows the applied parameter combinations.
- the tobacco temperature discharge and the discharge moisture are the tobacco temperature or the tobacco moisture immediately after the steam treatment. Parameter combinations steam tunnel No. 4 Tobacco temperature discharge (° C) 106 Residence time (min) 3 Input humidity (%) 18 Discharge moisture (%) 18 5 108 6 18 17 6 112 9 18 15
- the two tables 3 and 4 compare for each of the two basic tobaccos examined the results obtained according to the parameter combinations 1 to 3 or 4 to 6 described in Tables 1 and 2.
Landscapes
- Manufacture Of Tobacco Products (AREA)
- Breeding Of Plants And Reproduction By Means Of Culturing (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI200130277T SI1353572T1 (en) | 2001-01-24 | 2001-06-15 | Method for the treatment of tobacco |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10103123A DE10103123A1 (de) | 2001-01-24 | 2001-01-24 | Verfahren zum Behandeln von Tabak |
| DE10103123 | 2001-01-24 | ||
| PCT/EP2001/006776 WO2002058490A1 (de) | 2001-01-24 | 2001-06-15 | Verfahren zum behandeln von tabak |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1353572A1 EP1353572A1 (de) | 2003-10-22 |
| EP1353572B1 true EP1353572B1 (de) | 2004-11-17 |
Family
ID=7671586
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01964985A Expired - Lifetime EP1353572B1 (de) | 2001-01-24 | 2001-06-15 | Verfahren zum behandeln von tabak |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US7320326B2 (cs) |
| EP (1) | EP1353572B1 (cs) |
| JP (1) | JP3964789B2 (cs) |
| KR (1) | KR100737116B1 (cs) |
| CN (1) | CN1192725C (cs) |
| AR (1) | AR032513A1 (cs) |
| AT (1) | ATE282333T1 (cs) |
| AU (1) | AU2001285747B2 (cs) |
| BG (1) | BG65441B1 (cs) |
| CA (1) | CA2433412A1 (cs) |
| CZ (1) | CZ297134B6 (cs) |
| DE (2) | DE10103123A1 (cs) |
| ES (1) | ES2231542T3 (cs) |
| HU (1) | HU228295B1 (cs) |
| MA (1) | MA26151A1 (cs) |
| MY (1) | MY128741A (cs) |
| NZ (1) | NZ527489A (cs) |
| PL (1) | PL193410B1 (cs) |
| RU (1) | RU2242147C1 (cs) |
| SI (1) | SI1353572T1 (cs) |
| SK (1) | SK286542B6 (cs) |
| TW (1) | TWI243650B (cs) |
| UA (1) | UA73842C2 (cs) |
| WO (1) | WO2002058490A1 (cs) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1729602A1 (en) * | 2003-12-22 | 2006-12-13 | U.S. Smokeless Tobacco Company | Conditioning process for tobacco and/or snuff compositions |
| RU2289980C1 (ru) * | 2005-07-08 | 2006-12-27 | Олег Иванович Квасенков | Способ производства ароматизированного взорванного табака |
| RU2289978C1 (ru) * | 2005-07-08 | 2006-12-27 | Олег Иванович Квасенков | Способ обработки табака |
| RU2289995C1 (ru) * | 2005-07-12 | 2006-12-27 | Олег Иванович Квасенков | Способ вспучивания табака |
| RU2289993C1 (ru) * | 2005-07-12 | 2006-12-27 | Олег Иванович Квасенков | Способ обработки табака |
| RU2306815C1 (ru) * | 2006-03-10 | 2007-09-27 | Олег Иванович Квасенков | Способ получения ароматизированной экспандированной табачной жилки |
| RU2306816C1 (ru) * | 2006-03-14 | 2007-09-27 | Олег Иванович Квасенков | Способ производства расширенной табачной жилки |
| RU2306830C1 (ru) * | 2006-03-15 | 2007-09-27 | Олег Иванович Квасенков | Способ получения ароматизированной экспандированной табачной жилки |
| RU2306829C1 (ru) * | 2006-03-15 | 2007-09-27 | Олег Иванович Квасенков | Способ изготовления ароматизированной экспандированной табачной жилки |
| RU2306817C1 (ru) * | 2006-03-15 | 2007-09-27 | Олег Иванович Квасенков | Способ получения ароматизированной табачной жилки |
| RU2306831C1 (ru) * | 2006-03-16 | 2007-09-27 | Олег Иванович Квасенков | Способ изготовления ароматизированной взорванной табачной жилки |
| RU2306832C1 (ru) * | 2006-03-22 | 2007-09-27 | Олег Иванович Квасенков | Способ изготовления расширенной табачной жилки |
| RU2336000C2 (ru) * | 2006-06-13 | 2008-10-20 | Государственное научное учреждение Всероссийский научно-исследовательский институт табака, махорки и табачных изделий | Способ обработки табачного сырья |
| KR100844444B1 (ko) | 2007-05-14 | 2008-07-08 | 주식회사 케이티앤지 | 시가엽과 기능성필터를 이용한 담배 및 이의 제조방법 |
| US20100116281A1 (en) * | 2008-11-07 | 2010-05-13 | Jerry Wayne Marshall | Tobacco products and processes |
| US8434496B2 (en) * | 2009-06-02 | 2013-05-07 | R. J. Reynolds Tobacco Company | Thermal treatment process for tobacco materials |
| ITTV20090160A1 (it) * | 2009-08-07 | 2009-11-06 | Comas Spa | Processo per migliorare la qualita' dei prodotti da utilizzare per il riempimento di articoli da fumo, sigarette, sigari e trinciati |
| GB201012090D0 (en) * | 2010-07-19 | 2010-09-01 | British American Tobacco Co | Cellulosic material |
| CN101904556B (zh) * | 2010-07-23 | 2012-07-04 | 安徽中烟工业公司 | 一种烟梗预处理工艺 |
| TW201233345A (en) * | 2010-12-23 | 2012-08-16 | Philip Morris Prod | Method of treating burley tobacco stems |
| CN102038283B (zh) * | 2011-01-24 | 2012-12-26 | 云南瑞升烟草技术(集团)有限公司 | 一种烤烟烟叶原料的调制方法 |
| US9326547B2 (en) | 2012-01-31 | 2016-05-03 | Altria Client Services Llc | Electronic vaping article |
| CN103504463B (zh) * | 2013-09-27 | 2015-09-30 | 广东中烟工业有限责任公司 | 一种柚皮多糖在烟叶保润中的应用 |
| WO2015098743A1 (ja) * | 2013-12-26 | 2015-07-02 | 日本たばこ産業株式会社 | たばこ材料の製造方法及びその製造方法により製造されたたばこ材料 |
| CN103704865A (zh) * | 2013-12-30 | 2014-04-09 | 红塔烟草(集团)有限责任公司 | 一种卷烟生产的工艺方法 |
| CN103815539B (zh) * | 2014-03-27 | 2016-11-09 | 福建中烟工业有限责任公司 | 一种中式混合型卷烟及其制备方法 |
| CA2970822C (en) * | 2015-01-07 | 2019-04-23 | British American Tobacco (Investments) Limited | Material for inclusion in a smoking article |
| CN106942780B (zh) * | 2017-04-11 | 2018-12-14 | 合肥富通环保新能源科技有限公司 | 一种香烟生产时烟草粗加工的方法 |
| DE102019105417A1 (de) * | 2019-03-04 | 2020-09-10 | Tews Elektronik Gmbh & Co. Kg | Verfahren zur Verarbeitung von mindestens zwei Eingangsmaterialien |
| CN110495630B (zh) * | 2019-08-06 | 2022-02-25 | 河南中烟工业有限责任公司 | 气冲烟叶的处理方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB508264A (en) | 1937-08-26 | 1939-06-28 | Guardite Corp | Improvements in or relating to the treating, impregnating or moistening of bulk products, for example organic products, particularly tobacco |
| LU49860A1 (cs) * | 1965-11-17 | 1966-01-17 | ||
| US3828798A (en) * | 1972-11-20 | 1974-08-13 | Brown & Williamson Tobacco Corp | Aromatic tobacco forming process |
| DE2402538C2 (de) | 1974-01-19 | 1985-05-09 | Hauni-Werke Körber & Co KG, 2050 Hamburg | Verfahren und Vorrichtung zum Konditionieren von Tabak |
| DE2638446A1 (de) * | 1976-08-26 | 1978-03-02 | Hauni Werke Koerber & Co Kg | Tabaktrockner |
| DE3119330C2 (de) | 1981-05-15 | 1983-06-01 | H.F. & Ph.F. Reemtsma Gmbh & Co, 2000 Hamburg | Verfahren zur Verbesserung der Füllfähigkeit von Tabaken |
| GB8822574D0 (en) * | 1988-09-26 | 1988-11-02 | Gbe International Plc | Vibratory steaming conveyor |
| JP2604263B2 (ja) * | 1990-04-19 | 1997-04-30 | 三洋電機株式会社 | マグネトロン駆動装置 |
| DE4142631A1 (de) * | 1991-12-21 | 1993-06-24 | Hauni Werke Koerber & Co Kg | Verfahren und anordnung zum trennen von tabakrippenfasern und zusammengeklebten tabakblattfasern |
| TW296974B (cs) * | 1992-10-30 | 1997-02-01 | Philip Morris Prod | |
| DE19543263C2 (de) * | 1995-11-20 | 2001-04-19 | Bat Cigarettenfab Gmbh | Verfahren und Anlage zur Behandlung von Tabakblättern für die Herstellung von Schnittabak |
| US5755238A (en) * | 1996-10-17 | 1998-05-26 | Brown & Williamson Tobacco Corporation | Method and apparatus for low residence time redrying of tobacco |
| IT1295858B1 (it) * | 1997-11-10 | 1999-05-28 | Anna Mastrolilli | Impianto per conciare il tabacco triciato (foglia e costola) e i frasami, particelle di foglia aventi dimensioni uguali o inferiori a |
| GB9922746D0 (en) * | 1999-09-24 | 1999-11-24 | Rothmans International Ltd | Tobacco processing |
-
2001
- 2001-01-24 DE DE10103123A patent/DE10103123A1/de not_active Withdrawn
- 2001-06-15 CZ CZ20032263A patent/CZ297134B6/cs not_active IP Right Cessation
- 2001-06-15 CA CA002433412A patent/CA2433412A1/en not_active Abandoned
- 2001-06-15 JP JP2002558832A patent/JP3964789B2/ja not_active Expired - Fee Related
- 2001-06-15 PL PL01365043A patent/PL193410B1/pl unknown
- 2001-06-15 NZ NZ527489A patent/NZ527489A/en not_active IP Right Cessation
- 2001-06-15 AU AU2001285747A patent/AU2001285747B2/en not_active Expired
- 2001-06-15 EP EP01964985A patent/EP1353572B1/de not_active Expired - Lifetime
- 2001-06-15 SI SI200130277T patent/SI1353572T1/xx unknown
- 2001-06-15 WO PCT/EP2001/006776 patent/WO2002058490A1/de not_active Ceased
- 2001-06-15 HU HU0302739A patent/HU228295B1/hu unknown
- 2001-06-15 ES ES01964985T patent/ES2231542T3/es not_active Expired - Lifetime
- 2001-06-15 UA UA2003087878A patent/UA73842C2/uk unknown
- 2001-06-15 DE DE50104569T patent/DE50104569D1/de not_active Expired - Lifetime
- 2001-06-15 KR KR1020037009296A patent/KR100737116B1/ko not_active Expired - Lifetime
- 2001-06-15 RU RU2003125857/12A patent/RU2242147C1/ru active
- 2001-06-15 SK SK1065-2003A patent/SK286542B6/sk not_active IP Right Cessation
- 2001-06-15 US US10/466,843 patent/US7320326B2/en not_active Expired - Lifetime
- 2001-06-15 CN CNB018222315A patent/CN1192725C/zh not_active Expired - Lifetime
- 2001-06-15 AT AT01964985T patent/ATE282333T1/de active
-
2002
- 2002-01-16 TW TW091100570A patent/TWI243650B/zh not_active IP Right Cessation
- 2002-01-22 MY MYPI20020242A patent/MY128741A/en unknown
- 2002-01-23 AR ARP020100223A patent/AR032513A1/es not_active Application Discontinuation
-
2003
- 2003-07-03 MA MA27224A patent/MA26151A1/fr unknown
- 2003-08-22 BG BG108126A patent/BG65441B1/bg unknown
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