EP1061317B1 - Method and support for firing - Google Patents

Method and support for firing Download PDF

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Publication number
EP1061317B1
EP1061317B1 EP00401664A EP00401664A EP1061317B1 EP 1061317 B1 EP1061317 B1 EP 1061317B1 EP 00401664 A EP00401664 A EP 00401664A EP 00401664 A EP00401664 A EP 00401664A EP 1061317 B1 EP1061317 B1 EP 1061317B1
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EP
European Patent Office
Prior art keywords
plate
bars
oven
elements
support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00401664A
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German (de)
French (fr)
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EP1061317A1 (en
Inventor
Ceric
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ceric
Original Assignee
Ceric SARL
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Filing date
Publication date
Application filed by Ceric SARL filed Critical Ceric SARL
Publication of EP1061317A1 publication Critical patent/EP1061317A1/en
Application granted granted Critical
Publication of EP1061317B1 publication Critical patent/EP1061317B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/06Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity heated without contact between combustion gases and charge; electrically heated
    • F27B9/10Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity heated without contact between combustion gases and charge; electrically heated heated by hot air or gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/12Travelling or movable supports or containers for the charge
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D5/00Supports, screens, or the like for the charge within the furnace
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149Honeycomb-like

Definitions

  • the subject of the present invention is a support intended to receive products to be baked in an oven or dried in a dryer.
  • This support is more particularly intended for the firing of ceramic products "honeycomb" type like catalyst supports.
  • honeycomb elements generally consist of blocks parallelepipedic or cylindrical which are traversed right through by a multiplicity of square or triangular section channels which may be less than 1 millimeter with partitions from 1 mm to 3/100 of a millimeter thick.
  • perforated plates does not allow circulation homogeneous in all the channels from where the problems related to the differences of flow between open or closed channels.
  • the present invention relates to a method providing a solution to this problem.
  • the method according to the invention consists in placing the catalyst elements to be cooked or dry, their channels being vertical, on a parallelepipedic support constituted by a ceramic foam so that the catalyst element channels are in position vertical to the support which causes the hot gases to pass through the support from side to side and penetrate into said channels.
  • Ceramic foam is a known product which is mainly used as filter in foundry molds: molten metal is poured over these foam filters of ceramic, the molten metal passes through this filter and fills the mold.
  • Porous ceramic foam plates are already known and applied to the Lours estate (EP-A-307,319).
  • the ceramic support must not be too thick, because the pressure drop which the flow of hot gases undergoes when passing through it would be such that this gas flow would not circulate, or at least would circulate poorly inside channels passing through the catalyst support block.
  • the support must therefore be a thin plate, that is to say of a thickness between 1 and 5 centimeters.
  • these means consist of bars carrying the plate in ceramic foam, these bars resting on the load-bearing elements of the oven.
  • the device according to the invention is consisting of a plate 1, of small thickness, that is to say between 1.5 and 2.5 centimeters, which is ceramic foam.
  • This plate 1 is intended to serve as a support for one or more elements in catalytic ceramics that will be deposited on it so that the multiple channels that cross them right through are vertical or perpendicular to the surface upper 2 of plate 1.
  • the catalyst support elements which are not part of the invention, are not shown.
  • the plate 1 having only a very low resistance to punching, cannot not be deposited directly on the load-bearing elements 4. In addition, having only one very low mechanical resistance, it risks breaking between the load-bearing elements such as elements 4.
  • the bars 5 are cylindrical and the grooves 6 are semi-cylindrical.
  • the bars 5 are placed on the load-bearing elements 4.
  • the carrier elements 4 include notches 7 corresponding to the grooves 6.
  • the complementary bars 15 are arranged inside the mass of the plate 1 in bores made for this purpose.
  • the plate 1 can be made up of two parts 1a and 1b placed side by side on the bars 5.
  • bars 5 can, like additional bars 15, be arranged in the mass of the plate 1. But as it is necessary that the foam ceramic is not in contact with the supports 4, cleaning on the underside 3 of the plate 1 of the grooves 7 which make the bars 5 appear so that they come in contact with load-bearing elements 4.
  • the present invention has been described in its application to cooking elements catalytic but it is not limited to this particular application; she may be advantageously used for any product to be crossed vertically by a hot gas flow.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)

Description

La présente invention a pour objet un support destiné à recevoir des produits devant être cuits dans un four ou séchés dans un séchoir.The subject of the present invention is a support intended to receive products to be baked in an oven or dried in a dryer.

Ce support est plus particulièrement destiné à la cuisson de produits céramiques de type "nid d'abeille" comme les supports catalyseur.This support is more particularly intended for the firing of ceramic products "honeycomb" type like catalyst supports.

Ces éléments en nid d'abeille sont généralement constitués de blocs parallélépipédiques ou cylindriques qui sont traversés de part en part d'une multiplicité de canaux de section carrée ou triangulaire pouvant être inférieure à 1 millimètre avec des cloisons de 1 mm à 3/100 de millimètre d'épaisseur.These honeycomb elements generally consist of blocks parallelepipedic or cylindrical which are traversed right through by a multiplicity of square or triangular section channels which may be less than 1 millimeter with partitions from 1 mm to 3/100 of a millimeter thick.

Du fait de leur faible section et de leur relativement grande longueur (par rapport à la section), ces canaux sont très difficilement traversés par les gaz chauds du four de cuisson et leur cuisson est irrégulière ce qui nuit gravement à leur qualité.Due to their small cross-section and their relatively long length (compared in section), these channels are very difficult for the hot gases from the furnace to pass through. cooking and their cooking is irregular which seriously affects their quality.

L'utilisation de plaques perforées ne permet pas d'obtenir une circulation homogène dans tous les canaux d'où les problèmes liés aux différences de flux entre canaux ouverts ou fermés.The use of perforated plates does not allow circulation homogeneous in all the channels from where the problems related to the differences of flow between open or closed channels.

La présente invention a pour objet un procédé apportant une solution à ce problème.The present invention relates to a method providing a solution to this problem.

Le procédé selon l'invention consiste à placer les éléments catalyseurs à cuire ou sécher, leurs canaux étant verticaux, sur un support parallélépipédique constitué par une mousse céramique de sorte que les canaux de l'élément catalyseur soient en position verticale par rapport au support ce qui a pour effet que les gaz chauds traversent le support de part en part et pénètrent dans lesdits canaux.The method according to the invention consists in placing the catalyst elements to be cooked or dry, their channels being vertical, on a parallelepipedic support constituted by a ceramic foam so that the catalyst element channels are in position vertical to the support which causes the hot gases to pass through the support from side to side and penetrate into said channels.

La mousse céramique est un produit connu qui est principalement utilisé comme filtre dans les moules de fonderie : on verse le métal en fusion sur ces filtres en mousse de céramique, le métal en fusion traverse ce filtre et remplit le moule.Ceramic foam is a known product which is mainly used as filter in foundry molds: molten metal is poured over these foam filters of ceramic, the molten metal passes through this filter and fills the mold.

Plaques poreuses en mousse céramique sont déjà connues et appliquées au domaine de Lours (EP-A-307 319).Porous ceramic foam plates are already known and applied to the Lours estate (EP-A-307,319).

Les travaux de la demanderesse ont permis de découvrir que l'on pouvait faire remplir à cette matière, la mousse céramique, une fonction totalement différente que celle pour laquelle elle a été conçue.The plaintiff's work revealed that it was possible to do fill this material, ceramic foam, with a completely different function than the one for which it was designed.

Il s'avère cependant qu'il ne faut pas que le support en matière céramique soit trop épais, parce que la perte de charge que subit le flux de gaz chauds en le traversant serait tel que ce flux gazeux ne circulerait pas, ou du moins circulerait mal à l'intérieur des canaux traversant le bloc support de catalyseurs.It turns out, however, that the ceramic support must not be too thick, because the pressure drop which the flow of hot gases undergoes when passing through it would be such that this gas flow would not circulate, or at least would circulate poorly inside channels passing through the catalyst support block.

Il faut donc que le support soit une plaque mince, c'est-à-dire d'une épaisseur comprise entre 1 et 5 centimètres.The support must therefore be a thin plate, that is to say of a thickness between 1 and 5 centimeters.

Mais alors, comme la mousse céramique a une très faible résistance au poinçonnement et à la flexion, il faut prévoir des moyens pour la rigidifier.But then, as the ceramic foam has a very low resistance to punching and bending, means must be provided to stiffen it.

Selon l'invention, ces moyens sont constitués par des barres portant la plaque en mousse céramique, ces barres reposant sur les éléments porteurs du four.According to the invention, these means consist of bars carrying the plate in ceramic foam, these bars resting on the load-bearing elements of the oven.

A titre d'exemple non limitatif et pour faciliter la compréhension de l'invention on a représenté aux dessins annexés :

  • Figure 1 : une vue schématique, en perspective, d'un premier exemple de mise en oeuvre de l'invention ;
  • Figure 2 : une vue schématique, en perspective, d'un deuxième exemple de mise en oeuvre de l'invention ;
  • Figure 3 : une vue schématique, en perspective, d'un troisième exemple de mise en oeuvre de l'invention ;
  • Figure 4 : une vue schématique, en perspective, d'un quatrième exemple de mise en oeuvre de l'invention ;
  • Figure 5 une vue schématique en bout d'un sixième exemple de mise en oeuvre de l'invention.
  • By way of nonlimiting example and to facilitate understanding of the invention, the accompanying drawings show:
  • Figure 1: a schematic perspective view of a first example of implementation of the invention;
  • Figure 2: a schematic perspective view of a second example of implementation of the invention;
  • Figure 3: a schematic perspective view of a third example of implementation of the invention;
  • Figure 4: a schematic perspective view of a fourth example of implementation of the invention;
  • Figure 5 a schematic end view of a sixth example of implementation of the invention.
  • En se reportant à la figure 1, on voit que le dispositif selon l'invention est constitué par une plaque 1, d'épaisseur faible, c'est-à-dire comprise entre 1,5 et 2,5 centimètres, qui est en mousse céramique.Referring to FIG. 1, it can be seen that the device according to the invention is consisting of a plate 1, of small thickness, that is to say between 1.5 and 2.5 centimeters, which is ceramic foam.

    Cette plaque 1 est destinée à servir de support à un ou plusieurs éléments en céramique catalytiques qui seront déposés dessus de façon que les canaux multiples qui les traversent de part en part soient verticaux ou encore perpendiculaires à la surface supérieure 2 de la plaque 1.This plate 1 is intended to serve as a support for one or more elements in catalytic ceramics that will be deposited on it so that the multiple channels that cross them right through are vertical or perpendicular to the surface upper 2 of plate 1.

    Les éléments support de catalyseurs, ne faisant pas partie de l'invention, ne sont pas représentés. The catalyst support elements, which are not part of the invention, are not not shown.

    La plaque 1 doit être portée par les éléments porteurs 4 du four (également non représentés).Plate 1 must be carried by the load-bearing elements 4 of the oven (also not shown).

    Mais la plaque 1, n'ayant qu'une très faible résistance au poinçonnement, ne peut pas être déposée directement sur les éléments porteurs 4. De plus, n'ayant qu'une très faible résistance mécanique, elle risque de se briser entre les éléments porteurs tels que les éléments 4.But the plate 1, having only a very low resistance to punching, cannot not be deposited directly on the load-bearing elements 4. In addition, having only one very low mechanical resistance, it risks breaking between the load-bearing elements such as elements 4.

    Pour éliminer cet inconvénient on dispose une pluralité de barres 5 (deux au minimum), ces barres 5 étant parallèles entre elles et reposant sur les éléments porteurs 4.To eliminate this drawback, there are a plurality of bars 5 (two at the minimum), these bars 5 being parallel to each other and resting on the load-bearing elements 4.

    Mais au contact entre la face inférieure 3 de la plaque 1 et les barres 5, la matière dont est constituée la plaque 1 ne va pas résister aux efforts de poinçonnement.But on contact between the underside 3 of the plate 1 and the bars 5, the material of which the plate 1 is made up will not resist the punching forces.

    Pour éliminer cet inconvénient on ménage dans la face inférieure 3 des rainures 6 dans lesquelles les barres 5 vont venir s'encastrer.To eliminate this drawback, grooves are formed in the lower face 3 6 in which the bars 5 will come to fit.

    Dans tous les exemples représentés aux figures 1 à 6, les barres 5 sont cylindriques et les rainures 6 sont semi-cylindriques.In all the examples shown in FIGS. 1 to 6, the bars 5 are cylindrical and the grooves 6 are semi-cylindrical.

    Il en résulte que les barres 5 font saillie au-delà de la surface de la face inférieure 3 de la plaque 1 d'environ la moitié de leur diamètre.As a result, the bars 5 protrude beyond the surface of the underside 3 of plate 1 about half their diameter.

    Les barres 5 sont posées sur les éléments porteurs 4.The bars 5 are placed on the load-bearing elements 4.

    Mais comme lesdites barres 5 font saillie au-delà de la face inférieure 3 de la plaque 1, la mousse céramique ne vient pas en contact avec les éléments porteurs 4.But as said bars 5 protrude beyond the underside 3 of the plate 1, the ceramic foam does not come into contact with the supporting elements 4.

    Ainsi, il n'y a pas de phénomène de poinçonnement sur la face inférieure 3 de la plaque 1 et il n'y a pas de phénomène de flexion de ladite plaque 1.Thus, there is no punching phenomenon on the underside 3 of the plate 1 and there is no phenomenon of bending of said plate 1.

    De préférence, comme cela est représenté, les éléments porteurs 4 comportent des encoches 7 correspondant aux rainures 6.Preferably, as shown, the carrier elements 4 include notches 7 corresponding to the grooves 6.

    Sur la figure 2 les mêmes éléments portent les mêmes références.In Figure 2 the same elements have the same references.

    La seule différence avec l'exemple de la figure 1 provient de ce que la distance séparant les deux éléments porteurs 4 est supérieure à la longueur de la plaque 1.The only difference with the example in figure 1 is that the distance separating the two carrying elements 4 is greater than the length of the plate 1.

    Sur la figure 3 également, les mêmes éléments portent les mêmes références. Also in FIG. 3, the same elements have the same references.

    Sur cette figure, on voit que en plus des barres 5 qui s'étendent sur toute la longueur de la plaque 1, on a disposé des barres complémentaires 15, qui sont perpendiculaires aux barres 5.In this figure, we see that in addition to the bars 5 which extend over the entire length of the plate 1, additional bars 15 have been placed, which are perpendicular to the bars 5.

    Alors que les barres 5 font saillie au-delà de la surface de la face inférieure 3 de la plaque 1, les barres complémentaires 15 sont disposées à l'intérieur de la masse de la plaque 1 dans des alésages ménagés à cet effet.While the bars 5 protrude beyond the surface of the underside 3 of the plate 1, the complementary bars 15 are arranged inside the mass of the plate 1 in bores made for this purpose.

    Sur cette figure 3 on voit également que la plaque 1 peut être constituée de deux parties 1a et 1b placées côte à côte sur les barres 5.In this figure 3 we also see that the plate 1 can be made up of two parts 1a and 1b placed side by side on the bars 5.

    Sur la figure 4, on voit que les barres complémentaires 15 peuvent reposer sur des éléments de support complémentaires 14.In FIG. 4, it can be seen that the complementary bars 15 can rest on complementary support elements 14.

    Sur la figure 5 on voit que les barres 5 peuvent, comme les barres additionnelles 15, être disposées dans la masse de la plaque 1. Mais comme il faut que la mousse céramique ne soit pas en contact avec les supports 4, on ménage dans la face inférieure 3 de la plaque 1 des rainures 7 qui font apparaítre les barres 5 afin qu'elles viennent en contact avec les éléments porteurs 4.In Figure 5 we see that bars 5 can, like additional bars 15, be arranged in the mass of the plate 1. But as it is necessary that the foam ceramic is not in contact with the supports 4, cleaning on the underside 3 of the plate 1 of the grooves 7 which make the bars 5 appear so that they come in contact with load-bearing elements 4.

    La présente invention a été décrite dans son application à la cuisson d'éléments catalytiques mais elle n'est pas limitée à cette application particulière ; elle peut être avantageusement utilisée pour tout produit devant être traversé verticalement par un flux de gaz chauds.The present invention has been described in its application to cooking elements catalytic but it is not limited to this particular application; she may be advantageously used for any product to be crossed vertically by a hot gas flow.

    Claims (6)

    1. A method for supporting in an oven products through which a flow of hot gases has to pass in a vertical direction, consisting of laying said products on a plate of porous ceramic foam (1), said plate being reinforced by bars (5, 15) passing through the mass of said plate and being borne by the carrying elements (4, 14) of the oven by means of said bars.
    2. A device for implementing the process according to Claim 1, consisting of a thin plate (1) of ceramic foam, this plate being borne by the carrying elements (4) of the oven by means of the bars (5).
    3. A device according to Claim 2, in which the bars (5) are embedded in grooves (6) formed in the lower face (3) of the plate (1) but project from this lower face (3) such that the material of the thin plate (1) does not come into contact with the carrying elements (4) of the oven.
    4. A device according to Claim 3, in which complementary bars (15) which are perpendicular to the bars (5) pass through the mass of the plate (1).
    5. A device according to Claim 4, in which the complementary bars (15) project from the plate (1) to come to bear on additional carrying elements (14) of the oven.
    6. A device according to Claim 2, in which two perpendicular sets of bars (5 and 15) pass through from one side of the plate (1) to the other, the lower face (3) of the plate (1) being provided with grooves (7) which reveal the support bars (5) so that they come into contact with the carrying elements (4) of the oven.
    EP00401664A 1999-06-14 2000-06-13 Method and support for firing Expired - Lifetime EP1061317B1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    FR9907476 1999-06-14
    FR9907476A FR2794632B1 (en) 1999-06-14 1999-06-14 COOKING SUPPORT

    Publications (2)

    Publication Number Publication Date
    EP1061317A1 EP1061317A1 (en) 2000-12-20
    EP1061317B1 true EP1061317B1 (en) 2004-04-21

    Family

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    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP00401664A Expired - Lifetime EP1061317B1 (en) 1999-06-14 2000-06-13 Method and support for firing

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    US (1) US6503080B1 (en)
    EP (1) EP1061317B1 (en)
    DE (1) DE60009984T2 (en)
    FR (1) FR2794632B1 (en)

    Families Citing this family (2)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    FR2840191B1 (en) 2002-05-30 2005-02-18 Guilloux Pierre Le DYNAMIC EXTERNAL FIXER FOR JOINT
    FR2885207B1 (en) * 2005-04-29 2007-08-17 Ceric Wistra Sa METHOD OF ADJUSTING THE FLOW OF DRYING FLUID

    Family Cites Families (14)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US3589694A (en) * 1969-08-19 1971-06-29 Philips Corp Supporting plate for objects to be subjected to a thermal treatment
    US4014968A (en) * 1974-07-19 1977-03-29 Corning Glass Works Shrinkage control of cellular ceramic bodies having axial cavities
    US4416618A (en) * 1976-04-07 1983-11-22 Smith Thomas M Gas-fired infra-red generators and use thereof
    DE2656989A1 (en) * 1976-12-16 1978-06-22 Riedhammer Ludwig Fa Tunnel kiln for sintering ferrite(s) - using conveyors consisting of heat insulating plates fitted with skids gliding along rails
    US4174950A (en) * 1977-12-19 1979-11-20 United Technologies Corporation Ceramic base and cap useful in firing ceramic shell molds
    US4568595A (en) * 1984-04-26 1986-02-04 Morris Jeffrey R Coated ceramic structure and method of making same
    JPS6237683A (en) * 1985-08-09 1987-02-18 東芝セラミツクス株式会社 Tool for baking ceramic
    US4808558A (en) * 1987-08-26 1989-02-28 Lanxide Technology Company, Lp Ceramic foams
    JPS6471571A (en) * 1987-09-11 1989-03-16 Senju Metal Industry Co Reflow furnace
    US5406058A (en) * 1993-11-30 1995-04-11 Corning Incorporated Apparatus for drying ceramic structures using dielectric energy
    US5582784A (en) * 1995-08-16 1996-12-10 Northrop Grumman Corporation Method of making ceramic matrix composite/ceramic foam panels
    DE19810411A1 (en) * 1998-03-11 1999-09-16 Schunk Ingenieurkeramik Gmbh Holder for a ceramic car body for holding blanks made of ceramic material to be burned
    US6330904B2 (en) * 1999-02-17 2001-12-18 Micro Electronics Group Inc. Microwave-based process for dental casting
    US6254998B1 (en) * 2000-02-02 2001-07-03 Materials And Electrochemical Research (Mer) Corporation Cellular structures and processes for making such structures

    Also Published As

    Publication number Publication date
    DE60009984T2 (en) 2005-05-04
    US6503080B1 (en) 2003-01-07
    DE60009984D1 (en) 2004-05-27
    FR2794632B1 (en) 2001-09-07
    FR2794632A1 (en) 2000-12-15
    EP1061317A1 (en) 2000-12-20

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