EP0836232B1

EP0836232B1 - Tunnelling device and method of producing a tunnelling device

Info

Publication number: EP0836232B1
Application number: EP97917492A
Authority: EP
Inventors: Sergei Pavlovich Gubin; Vladimir Vladimirovich Kolesov; Evgenii Sergeevich Soldatov; Artem Sergeevich Trifonov; Vladimir Viktorovich Khanin; Genadii Borisovich Khomutov; Sergei Alexandrovich Yakovenko
Original assignee: Samsung Electronics Co Ltd; Khomutov Genadii Borisovich; Trifonov Artem Sergeevich; Yakovenko Sergei Alexandrovich
Current assignee: GUBIN, SERGEI PAVLOVICH; KHANIN, VLADIMIR VIKTOROVICH; Khomutov Genadii Borisovich; KOLESOV, VLADIMIR VLADIMIROVICH; SOLDATOV, EVGENII SERGEEVICH; TRIFONOV, ARTEM SERGEEVICH; Yakovenko Sergei Alexandrovich; Samsung Electronics Co Ltd
Priority date: 1996-03-26
Filing date: 1997-03-25
Publication date: 2003-05-14
Anticipated expiration: 2017-03-25
Also published as: US6057556A; KR19990021970A; EP0836232A1; KR100272702B1; CN1097857C; JP3635409B2; DE69721929D1; EP0836232A4; WO1997036333A1; JPH11500583A; CN1189921A; AU2579297A; DE69721929T2

Description

Technical Field

The present invention relates in general to methods for producing functional elements of nanoelectronics and computer facilities, more specifically it concerns tunnel-effect devices and can find application for producing single-electron logic gates, single-electron memory circuits and sensors operable at room temperature.

Background Art

Fundamentals of modern theory of correlated electronic tunneling have been elaborated as early as several years ago. A worldwide interest displayed in this new domain of physics and technology is concerned with the broadest potentialities and prospects offered by further research in single-electron phenomena and development of new promising technologies based thereon.
From the standpoint of physics the meaning of that phenomenon resides in electronic correlations due to Coulomb electrostatic interaction of electrons in diverse micro- and nano-scale structures. On the other hand, single-electronics is a route towards development of such electronic device that the operating concept of which is based on information coding by lone electrons.
One state-of-the-art three-lead (three-electrode) semiconductor device (US Patent 4,286,275, NPC 357/12, 1981) is known to comprise a combination of the base region having a physical size of the order of the length of a free path of the majority carrier, the emitter region which establishes a first barrier relative to the base region and featuring the barrier width sufficient for quantum-mechanical tunneling, and the collector base forming a lower barrier with respect to the base region than the first barrier and featuring the barrier width high enough to inhibit quantum-mechanical tunneling and ohmic contact with each of the emitter, base, and collector regions.
The three-lead (three-electrode) semiconductor device under discussion featuring a changeover time of about 10 ps (10 picoseconds) and offering a negative dynamic resistance, is created from a thin barrier region in the emitter section having a barrier height exceeding that in a wider barrier region of the collector section which separated by the base section having a width comparable with the length of the length of a free path of the majority carrier. The operation of the device is based on quantum-mechanical tunneling as the principal mechanism of electrical conduction through the base region to the collector region.
Field of application: amplification, changing-over, and establishing dynamic resistance.
Specific features: the collector barrier has such a width that tunneling current flowing there through is but negligible. Emitter-base junction: main conductance due to quantum-mechanical tunneling.

Dimensions:: base - 100 Å (10Å = 1 nm);
width of emitter barrier - 80 Å;
width of collector barrier - 120 to 150 Å.

The device discussed before is based on quantum-mechanical tunneling as the principal mechanism of electrical conduction from the emitter region to the base region, and of transferring hot majority carriers through the base region to the collector region.
One more state-of-the-art three-lead (three-electrode) semiconductor device based on quantum wells (US Patent 4, 912, 531, NPC 357/12, 1990) is known to function as a MOS transistor. This means that in a general sense the three leads of the device may be considered as a source, a gate, and a drain. The output terminal communicates, by virtue of the tunneling effect, with a number of parallel circuits of quantum wells, each of which is adequately small for the energy levels therein to quantize discretely. In each of such pit circuits the second pit is connected to a second common conductor, while the first pit is electronically connected to a first common conductor.
A method for making GaAs-based electric elements of nanoelectronics and computer facilities with an insulating molecular Langmuir-Blodgett layer (US Patent 5,079,179, NPC 37/141, 1992) is known to comprise formation of an insulating layer appearing as Langmuir-Blodgett (LB) film interposed between a GaAs substrate and the conducting terminal.
The thickness of said layer is variable so as to set the functional characteristics of the device. The polar head group of a molecule of LB-film is so selected as to passivate the surface state of GaAs used as the substrate. There are found some preferable acid- and amino-groups for the polar head of molecules. It has been established that the LB-layer increases the height of the control barrier for a field-effect transistor and passivates broken bonds and surface flaws in the GaAs substrate, which makes possible inversion-mode operation. The method is applicable only for preparing macroscopic devices, i.e., field-effect transistor and diodes.
In the article "Single electron memory demonstrated", Electronics World + Wireless World, GB, REED BUSINESS PUBLISHING, Sutto, Surrey, vol. 99, no. 1686, page 363, ISSN: 0959-8332, a single electron memory is described. This memory cell has a gate capacitor and a multiple-tunnel junction. The electron channel is formed within a few atomic layers in an otherwise-insulating GaAs substrate. However the cell only works under a temperature at 0,1 K at present.
The EP 0 696 065 A2 shows a conduction control device. A preferred embodiment of said circuitry comprises a semiconductor substrate on which is formed a conducting channel. A single electron transistor in said channel consist of source region and drain region and an island separated froms these regions by tunnel barriers. The state of the art does not disclose a device with organo-metallic clusters embedded in an organic shell.
The dissertation "Metallic and Semiconductor Nanoparticulate Films Generated Under Monolayers and Between Langmuir-Blodgett Films" by Kyungchee Choi Yi, 1993 UMI Dissertation Services, Ann Arbor, Michigan, USA, shows Langmuir-Blodgett Films forming clusters with metal atoms.
One of the most promising methods for making functional elements of nanoelectronics is a method for making an electronic device involving organic materials (EP 0 469 243 H01L 29/28, 1992), which provides for establishing of electronic devices, wherein electron current flows through an electrically conducting monomolecular or multi-monomolecular film.
Said method for making an electronic device involving organic material consists in establishing a first and a second electrodes on a substrate provided with an insulating film on its surface, etching out the insulating film using the first and second electrodes as a mask; forming a monomolecular or multi-monomolecular film, containing electrolytically polymerizable groups directly or indirectly on the substrate surface which functions as a third electrode; applying a voltage across the first and the second electrodes for the electrolytically polymerizable groups to polymerize; and withdrawing the third electrode from the substrate.
The aforediscussed method for making an organic electronic device is instrumental in forming a monomolecular or a multi-monomolecular film comprising electrolytically polymerizable groups, using the Langmuir-Blodgett technique. In addition, a possibility is provided for developing an electronic device involving an organic material, wherein formation of a monomolecular or a multi-monomolecular film containing polymerizable groups, involves the procedure of forming at least one layer of a monomolecular film by chemical adsorption of a silane-base surfactant, containing polymerizable unsaturated groups, from a nonaqueous organic solvent onto the substrate surface, followed by polymerization of the resultant film.
Furthermore, according to said method for making an electronic device, formation on the substrate surface of at least one layer of a monomolecular film containing electrolytically polymerizable unsaturated groups is followed by electrolytic polymerization of said unsaturated groups by applying an electric voltage across the first electrode and the second electrode in order to establish connection between the first and second electrodes through electrically conducting conjugated groups, while said silane-based surfactant is in fact a chemical substance containing a chlorosilyl group at its end.
An indispensable prerequisite for carrying said method into effect is that the monomolecular or multi-monomolecular films should contain electrically conducting conjugated groups, such as a polythienylene-group, so that bonding between the first and second electrodes be effected by said polythienylene groups.
The known method for making an organic electronic device is featured by forming said first and second electrodes on a solid-state substrate, by an electrolytically polymerized monomolecular or multi-monomolecular layer interposed between said electrodes, and by establishing a third control electrode connected directly or indirectly to said monomolecular or multi-monomolecular layer, as well as to the first and second electrodes. Applying a voltage between the third and second electrodes allows of control over the electric current flowing between the first and second electrodes and depending on a change in the applied voltage.
In view of the foregoing, an inference can be made that the known method is instrumental in making electronic devices involving organic materials and utilizing the electron current flowing through an electrically conducting monomolecular or multi-monomolecular organic film.
The region through which electric current flows is established by conjugated links present in an organic material, specifically in said organic monomolecular or multi-monomolecular organic film, said links resulting from electrolytic polymerization of said film, whereby high functional capabilities and reduced overall dimensions of the device are attained.
It is due to the use of the chemical adsorption or LB-technique along with electrolytic polymerization that polymers having electrically conducting conjugated bonds may very efficiently be made on the concepts of self-organization, for electrically connecting two electrodes, with the result that highly perfect electronic organic devices may be obtained.

Disclosure of the Invention

Therefore the principal object of the present invention is to provide an electronic device operating on the principle of a single-electron tunneling at a rather high (room) temperature.
It is common knowledge that mutual conductance of electrodes in a tunneling junction is rather low, i.e., much lower than the conductance of the tunneling junction itself. After tunneling of one electron the potential difference changes by the value e / C (where e = 1,6 • 10^-19 C [where C is Coulomb]; C being the capacitance of the junction). Accordingly, a characteristic scale of change in the electrostatic energy of the system after tunneling of one electron is e²/2C.
Electrostatic energy of such a system is as follows: E = Q 2 2C ; Q=Q 0 + ne (e>0), where Q₀ is a constant depend upon the difference ϕ₁ between work functions of the electrodes, Q 0 = C(ϕ1-ϕ2), n is the number of electrons that passed through the junction.
The following two principal conditions should be met for attaining the tunneling effect of lone electrons:
1. The condition of a lowest value of thermal fluctuations with respect to the change in the electrostatic energy of the junction: e 2 2C 〉〉 kT, where

k

is the Boltzmann constant;

T

is temperature.
2. The condition of almost complete isolation of the object from the outside world. In this case a weak electron interchanged is possible through the tunneling barrier. The condition of such an isolation has a simple quantitative sense, i.e., the value of tunneling resistance of the resultant junctions should be much higher than the so-called quantum resistance: RQ = h 4 e 2 ≈ 6,5 kΩ, where h is the Planck constant.
Meeting the condition of the Eqn. 1.4 provides for an inhibitory effect on quantum noise which manifests itself in random motion of electrons through the junction even at zero temperature when thermal noise is inhibited completely. In this case electrons will be localized on the object so that its charge will be determined, accordingly.
Thus, the effect of a lone electron tunneling can be observed when thermal (1.3) and quantum (1.4) charge fluctuations are relatively low compared with the energy of system recharging during tunneling.
It is demonstrable that when the junction electric charge Q is in the range of -e / 2<Q< e / 2, tunneling is disadvantageous for the system since its free energy increases in this case. Thus, when no potential difference is applied to the junction or such a difference is too low, no tunneling effect occurs. The phenomenon is called Coulomb blocking.
Now let Q change under, e.g., any source of current connected to the junction, i.e., Q = I(t), so as to extend beyond one of the limits of the Coulomb blocking range and get somewhat in excess of e / 2. As a result, the electron tunneling effect proves to energetically advantageous, whereby the junction charge changes to get a little higher than -e / 2, that is, it falls again into the range of Coulomb blocking. That is why tunneling a next electron proves to be disadvantageous until an external recharging of the junction establishes the conditions of energetic advantage of a new tunneling action, i.e., till an increase in a complete junction charge on e. Thus, single-electron variations of the charge Q at the junction and those of the voltage V = Q / C thereon will occur at a frequency f = I / e, where I denotes an average current passing through the junction. In this case electron tunneling in a single-electron tunneling junction is time-correlated.
In more complicated systems comprising a number of junctions, a strict space correlation of tunneling action in various junctions is possible. In case of two series-connected junctions, electron tunneling through one of these adds to the voltage and hence probability of tunneling through the other junction. Such a space correlation is most markedly pronounced when both of the junctions differ in resistance and hence in tunneling time most widely [1]. Thus, an average tunneling current flowing through the system is determined by the lower-resistance junction. The conditions for electron tunneling in both junctions can be varied by changing the charge on the central electrode externally, e.g., by inducing (or "injecting" through a high (exceeding the quantum one) resistance), with the result that a single-electron transistor is obtained. A relation between current I_t and control V_g with a fixed value of V is called the signal characteristic of a system. Said relation is essentially a periodic one having a period equal to an elementary charge: I(Q + e) = I(Q).
The theory of correlated single-electron tunneling holds true for junctions having adequately large electrodes whose energy spectrum may particularly be assumed as continuous. Of much interest is the point how characteristics of tunneling junctions change when the dimensions of said junctions are so reduced that space quantization of energy spectrum becomes substantial. No rigorous theory describing the effect of discreteness of energy spectrum an correlation process of single-electron tunneling through a very small metallic object (e.g., through a metal granule) or through a molecule (cluster) has so far been developed.
However, the assessments made [4] demonstrate that when an adequately high quantity of electrons are present on the object, the effect of discreteness of energy spectrum boils down to that under certain conditions the voltage-current characteristic may exhibit, apart from single-electron specific features, also the presence of a microstructure accounted for by a dimensional effect in space quantization of electron energy.
It is due to the method that a unique electronic device may be provided, operating on the single-electron tunneling mode at room temperature in an artificially created stable molecular structure.

Brief Description of the Drawings

FIG. la

is a plan view of a functional diagram of the tunnel-effect device, according to the method of the invention;

FIG. 1b

is a side view of FIG. la, wherein:

1 - substrate;
2 - clusters and molecules built into a mono- or multi-monomolecular matrix;
3 - input electrode;
4 - output electrode;
5 - N control electrodes;

FIG. 2

shows a voltage-current characteristic of the tunnel-effect device; and

FIG. 3

presents a signal (control) characteristic of a tunnel-effect device with one control electrode (molecular single-electron transistor) at a temperature of 300 K showing the cluster located close to the control electrode.

Best Method of Carrying Out the Invention

According to the proposed method for producing a tunnel-effect device, an ordered molecular structure is formed in a system of planar metal (or semiconductor) electrodes on a substrate, by fixing special molecules and clusters which provide formation of tunneling junctions and single-electron correlated electron tunneling in the device rather than a simple monolayer of inert molecules which forms a dielectric interlayer, i.e., a tunneling barrier.
Accordingly, when such molecules and clusters are fixed using the known Langmuir technique, a combined multicomponent layer is established on a water surface, said layer being constituted by amphiphilic molecules or clusters establishing single-electron tunneling junctions, whereupon the resultant multicomponent monomolecular layer is transferred from the water surface onto the substrate surface.
A method for establishing an ordered molecular satisfying the conditions of a single-electron correlated tunneling consists in the following: a combined layer of molecules and clusters 2 is deposited on a substrate 1 with prepared metal electrodes 3, 4, and 5, using a chemical adsorption or Langmuir-Blodgett technique.
Organo-metallic clusters possess a set of properties unique for establishing molecular single-electron circuits for correlated tunnel transport, that is, the cluster nucleus consisting of but a few metal atoms has an electronic structure allowing of the presence of a variable number of additional electrons which, however, do not affect the atomic structure of the cluster. Typical of the cluster nucleus is the presence of closely positioned free electron levels, whereby a tunneling electron is enabled to rapidly pass, at a high temperature, from one level to another for a time shorter than an average time of electron tunneling onto the cluster nucleus. As a result, there is no quantum limitations of arrangement of a next tunneling electron, a feature that basically distinguishes the situation from resonance tunneling and is inherent just in systems considered in the theory of single-electron tunneling. It is worth emphasizing that the temperature in clusters having but a few metal electrons in their nucleus, at which the effects of electron quantizing as to the levels of electron structure of the nucleus become substantial, is much lower than the working temperature of a single-electron device.
An organic shell of a cluster is in fact a fixed tunneling barrier whose properties are independent of the presence of a tunneling electron. Characteristic dimensions of the cluster shell provide high tunneling penetrability and hence short tunneling time. In addition, tunneling resistance of a barrier is substantially higher than the quantum one (∼6,5 kΩ), which is a fundamental requirement imposed by the theory of single-electron correlated tunneling.
There exists a wide selection of types of organo-metallic clusters featuring diverse combinations of types of the shell and nucleus, which makes it possible to vary both the parameters of the tunneling structure (i.e., effective capacitance and conductance) and merely chemical properties of the cluster shell which are important for its physicochemical fixing in a specific system, that is, the tunnel-effect device. Besides, operation in the mode of single-electron correlated tunneling is also possible in a system of other active molecules and clusters (other than organo-metallic) possessing the appropriate physicochemical properties, e.g., carboran, fulleren, etc. which can also be used for making the device.
Two principal problems are to be solved when producing a single-electron tunnel-effect device:

Selecting adequately stable active molecules or clusters possessing such properties that provide a single-electron transport of electrons;
Forming on a substrate an ordered structure from such molecules and clusters.

It is mainly due to its stability that a carboran cluster has been selected among a wide variety of the heretofore-known clusters. The carboran cluster having a characteristic size of about 15 Å, hence a substrate whereon said cluster is to be arranged should feature a characteristic surface irregularity much less than 15 Å. It is necessary that the cluster is held to the substrate stably; besides, the substrate should be electrically conducting. The aforementioned requirements are met by substrates made of highly oriented pyrolytic graphite due to their having adequately high conductance and a characteristic surface irregularity of about 1 Å, with the graphite lattice spacing equal to 2,46 Å.
To attain a reliable holding of molecules to the substrate use is made of the Langmuir-Blodgett technique. The Langmuir-Blodgett films are in effect single- or multilayer coatings constituted by amphiphilic molecules on a solid substrate, prepared by transferring one strictly monomolecular layer of molecules after another when the substrate passes through the surface of a water phase coated with a monolayer.
The structure of the molecular component of the present device is as follows: a combined film of stearic acid with carboran clusters incorporated thereinto is applied to an atomically smooth surface of pyrolytic graphite, using the LB technique, said film featuring the molecules of the clusters fixed on the substrate with the matrix of the stearic acid.
As far as the use of the effect of correlated electron tunneling for constructing nanoelectronics circuitry is concerned, of much importance is the problem of a possibility of controlling the tunneling current in such a double-junction structure, using an independent signal.
The following pattern is selected for constructing a single-electron transistor: a substrate-supported cluster is positioned near a control electrode insulated from the substrate, said electrode establishing a charge on the cluster by virtue of the field effect. Numerical assessment of the mutual capacitance of such electrode and cluster demonstrates that its value necessary for constructing said single-electron transistor can be attained when the spacing between the electrode and the cluster is not in excess of 100 nm. A voltage of the order of a few volts should be applied to the electrode in this case.
Actually, such a structure appears as a double-layer (dielectric - conductor) system of fine stripes evaporation-deposited upon the substrate which is made of a highly oriented pyrolytic graphite having a surface finish in a scale of the order of one hundred nanometers equalling the size of one cell of the graphite crystal lattice (2,46 Å). Used as the dielectric is Al₂O₃ and as the conductor, Au.
The system of such electrodes is prepared with the aid of the techniques of modern nanolithography. The configuration of the electrodes appears as a "comb" of a number (of the order of a hundred) of long narrow stripes. The interstripe spacing should be small enough so that the probability of a cluster to be near a stripe be adequately high. On the other hand, said spacing should be so large (of the order of a few hundreds of nanometers) that the needle of a scanning tunnel microscope may scan the surface. As a result of a compromise between these and other technological conditions the spacing between the neighboring electrodes is selected to be about 400 nm, the electrode width measuring alike.
The herein-proposed method for preparing a single-electron tunnel-effect device uses the developed technology of reliable fixing the clusters and molecules on the surface of a solid-state substrate. The gist of the adopted technology consists in incorporating the tunnel-active clusters and molecules into the matrix of Langmuir's film based on amphiphilic substances (e.g., stearic acid). The proposed technology provides for obtaining a monolayer structure of cluster molecules. The technology is based on research of the physicochemical properties multicomponent Langmuir's films containing nanoparticles. The matrix of the Langmuir's monolayer of a polymerized amphiphilic substance fixes reliably active clusters and molecules, thus preventing them from motion under the effect of an electric field of electrodes. For more reliable fixing of active clusters and molecules they are to be mixed with amphiphilic substances, e.g., stearic acid in such a ratio that each cluster and molecule be surrounded completely with the stearic acid molecules.
At present, it is the scanning tunnel microscopy and spectroscopy technique that proves to be the sole technique of registering the characteristics of lone structures having such minute dimensions, said technique making possible observation and studying the objects with atomic resolution.
For the purpose of demonstrating the functional capabilities of the proposed tunnel-effect device use is made of the scanning tunnel microscopy and spectroscopy (STS) technique. Use of a scanning tunnel microscope (STM) enables one to measure the characteristics of single-electron systems having arbitrarily small (down to the atom's) dimensions.
The construction of a scanning tunnel microscope is instrumental in obtaining a three-dimensional patter representing the surface relief, and also make it possible to connect the desired objects to the needle-substrate circuit.
The direct-current mode is used for measurements. In said mode a direct tunneling current is maintained, while the respective position of the needle over the surface is maintained and fixed with the aid of a feedback circuit.
For constructing the proposed tunnel-effect device use is made of metal-containing carboran clusters measuring about 20 Å. Use of such clusters as an active element enables one to observe single-electron phenomena in such a system at a temperature of liquid nitrogen (about 77 K) and at room temperature (about 300 K) (FIG. 2).
The "needle - cluster nucleus" and "cluster nucleus - substrate" junctions serve as the tunneling junctions in the single-electron STM-based transistor under construction. The charge Q₀ induced onto the cluster, using the field effect upon applying a voltage to the control electrode 3 (FIG.1), modifies the conditions for current flowing through the system and functions as the control.
Clusters and cluster molecules differ from other organic and inorganic molecules in that they consist of a dense heavy nucleus featuring a symmetry, as a rule, approximating the spherical one, and surrounded with a ligand shell of light atoms or elementary molecules. A specific feature of the electronic structure of cluster molecules, i.e., the presence of a dense network of closely spaced highest occupied molecular orbitals and the respective lowest unoccupied molecular orbitals (both of them being as a rule weakly bonding), is responsible, on the one hand, for appearance in clusters multiple single-electron. reversible junctions and, on the other hand, it imparts an adequate stability to the core of cluster molecules after adding or removing an electron.
According to the present invention, used as the active elements of the proposed tunnel-effect device which establish therein tunneling barriers and interbarrier space (the regions where tunneling electrons are localized) are the appropriate molecules and clusters (in particular, metal-containing molecular clusters) having the required characteristic dimensions (below 100 Å) and capable of exhibiting the effect of Coulomb blocking of electron tunneling in an ordered structure of such molecules and clusters, without imposing any definite limitations upon the structure of the energy spectrum of electrons in such molecules and clusters. These molecules and clusters (a single molecule as a particular case), on which tunneling electrons are localized, are arranged in appropriately ordered manner in the space confined between the metal (or semiconductor) input, output, and control electrodes (FIG. 1). In this case tunnel current flows on the input electrode 3 and the output electrode 4, while the control electrodes 5 provide for an efficient control over the tunnel current of electrons (FIG. 3), with the result that when the voltage on the control electrode 5 changes steadily, a periodic unsteady change in tunneling current is noticed. When the proposed device is used for preparing diverse sensors, tunneling current varies under some external effects, such as electromagnetic fields, interaction between the environmental components and the active region of the device (i.e., single-electron tunneling junctions). Spatial ordered stabilization of active molecules on which tunneling electrons are localized, is provided due to an ordered arrangement of said molecules in the matrix of a chemically inert substance, or by virtue of chemical bonds with the components of the device.
The proposed method is carried into effect as follows.
Use is made of the Langmuir-Blodgett technique for preparing a monomolecular layer of lone clusters fixed in an inert molecular matrix. The aforementioned technique is instrumental in establishing on the liquid phase surface monomolecular films of substance of a definite class, and in transferring said films onto a solid substrate.
In order to produce combined Langmuir's monolayers containing carboran clusters and stearic acid, there are prepared solutions of the cluster and of stearic acid in tetrahydrofuran, having a concentration of 10^-3 M. Then both of the solutions are used for preparing therefrom solutions, containing stearic acid and carboran clusters in the following ratios: 1:32; 1:20; 1:16; 1:12, 1:8; 1:4; 1:1; 2:1; 4:1; 8:1; 12:1; 16;1; 20:1, 32:1, respectively. To establish a monolayer, a solution of stearic acid and/or carboran cluster in tetrahydrofuran is applied to the surface of a water subphase (pH = 5,6), the concentration of said solution being 4·10^-4 M (in terms of a total number of the stearic acid molecules and of clusters). In 5 minutes required for the solvent to evaporate the monolayer is compressed at a rate of 3 Å² per molecule per minute. Before transferring the monolayer from the water surface onto the graphite substrate the monolayer is compressed with a movable barrier till a surface pressure of 25 mN/m, whereupon said monolayer is transferred onto a freshly prepared spalled graphite surface at a rate of 0,5 mm/min, using the Scheffer technique. When transferring the monolayer onto the substrate a surface pressure of 25 mN/m is maintained constant. In order to prepare a monolayer oriented with the hydrophobic tails outwards, the substrate is submerged in water before applying the monolayer to the water surface. When preparing a monolayer oriented with the hydrophilic tails outwards, once the substrate has been submerged in water completely, the monolayer is compressed to a maximum degree until a collapse occurs, whereupon the monolayer is sucked out with a water pump, and the bath area is increased to a maximum extent, after which the substrate is withdrawn from water.
With a view to elucidating the possibilities and specific feature of building carboran clusters into a Langmuir monolayer based on stearic acid, there have been studied the isotherms of compression of combined monolayers made of stearic acid and carboran clusters on the surface of deionized water (pH = 5,6). Carboran clusters free from stearic-acid molecules do not form stable Langmuir monolayers on water surface, and the surface pressure is not in excess of 3 mN/m in response to compression of the carboran "monolayer". When doped with stearic acid molecules (with stearic acid/cluster ratio k being within 0,6 and 12) carboran clusters establish stable amphiphilic monolayers displaying pronounced cooperative properties, i.e., the value P_max of surface pressure equals 70 mN/m, whereas that of P_max for stearic acid and carboran clusters per se equals 55 mN/m and 3 mN/m, respectively.
Thus, stable combined Langmuir monolayers of a pronounced cooperative nature have been prepared by incorporating nonamphiphilic molecules, i.e., carboran clusters into classic Langmuir monolayers of stearic acid.
In this case the active molecules and clusters themselves might not form LB films altogether. That is why use is made of combined LB films of fatty acids with cluster molecules built thereinto, since said acids are well studied and are convenient for application. Thus, the problem of selecting the type of clusters useable in single-electron electronics has been separated from that of fixing the selected clusters on substrate, and both of the problems have been solved. The novelty of the proposed invention resides in that a combined film of a fatty acid and clusters is prepared on water surface, whereupon said film is transferred onto a substrate. With a definite concentration of cluster molecules in LB film they form their own ordered structure.
When measuring voltage-current characteristics and spectrum (i.e., the analog derivative of voltage-current characteristic with respect to voltage) of a monomolecular layer of stearic acid with clusters incorporated thereinto, using STM at a temperature of 300 K, some peculiarities of voltage-current characteristics have been found, which agree well with the data of the existing theory of single-electron tunneling. Thereby an experimental evidence has been obtained of a stable reproducible realization of a single-electron tunneling at room temperature in an artificially established stable molecular structure.
Measurements taken at room temperature demonstrate that current flowing through the transistor molecular tunneling structure "STM needle - cluster - substrate" at a fixed working point, depends unsteadily, and moreover, periodically on a steady voltage variation on the control electrode. Thus, there is found compliance of an experimental relationship between tunnel current and control voltage, that is, signal characteristic of a molecular single-electronic transistor, with a theoretical relationship derived from the theory of single-electron electronics. Each period on signal characteristic is explained, in accordance with the orthodox" theory of single-electron electronics, by a change of the cluster charge by one electron.
Symmetry of the signal characteristic, on the one hand, and the presence of steps in the voltage-current characteristic, on the other hand is explained by the fact that in the double-junction system "STM needle - cluster - substrate" the junctions "STM needle - cluster" and "cluster - substrate" have approximately the same capacitance values but differ widely in the values of their resistance.
According to the method for preparing a tunnel-effect device, an ordered molecular structure is established on a substrate in a system of planar metal (or semiconductor) electrodes, by fixing active molecules and clusters which provide for formation of tunneling junctions and a single-electron correlated electron tunneling in the device rather than a mere monolayer of inert molecules forming a dielectric interlayer, i.e., tunneling barrier.
Accordingly, when fixing such molecules and clusters, using the known Langmuir technique, a multicomponent combined monomolecular layer is established on water surface, said layer being constituted by inert amphiphilic molecules and active molecules and clusters forming single-electron tunneling junctions, whereupon the thus-formed multicomponent monomolecular layer from water surface onto the surface of the formed substrate.
When using chemical adsorption of molecules on the substrate surface for forming a system of single-electron tunneling junctions, active molecules and clusters should contain the corresponding chemical groups which bond said molecules and clusters with the substrate surface. Further on a chemical reaction of bonding the corresponding molecules and clusters with the substrate. Building of active molecules and clusters into the preformed molecular layer of inert molecules is also possible.
Once the mono- or multilayer molecular structures have been established, using the Langmuir-Blodgett technique or chemical adsorption procedure, the resultant molecular structures are made to polymerize with a view to increasing their stability and resistance to external effects.
Use of active molecules and clusters forming single-electron tunneling junctions, as the molecules establishing an ordered molecular structure on the surface of a solid-state substrate in a system of planar electrodes makes it possible to provide a novel useful property of the proposed device, that is, its functioning on the base of a single-electron correlated electron tunneling.
The herein-proposed tunnel-effect device is distinguished for the following advantages: the active elements of the device (molecules and clusters) have strictly fixed and identical structure (atomic composition) and hence dimensions. This provides for identity of the active elements of the devices and, accordingly, reproducibility of their functional parameters and the same response to a definite external effect.

Industrial Applicability

The proposed tunnel-effect device is instrumental in developing digital and analog devices based on both the traditional concepts of circuitry construction and the quite new concepts of information coding, wherein individual electrons function as information carrying medium.
Active elements of the device (active molecules and clusters) are featured by extremely small dimensions (e.g., the molecule of a carboran cluster measures about 20 Å), which opens prospects for substantial miniaturization of single-electron devices developed with the use of said elements.
It is due to the use of molecules and clusters having nanometer dimensions as the active elements of the device that the characteristic dimensions of the active regions (single-electron tunneling junctions) of the device become small enough to provide a controlled single-electron correlated tunneling at relatively high (room) temperatures, and that an extremely high sensitivity of the device is attained at those temperatures towards changes in the charge on the active elements of the device (10²² C/Hz^½).
As distinct from the known tunnel-effect device functioning on the base of resonance tunneling, the proposed tunnel-effect device operates on the base of controlled single-electron correlated electron tunneling in a system of molecules or clusters having an arbitrary energy spectrum of electrons rather than resonance tunneling between quantum-mechanical wells with discrete energy levels. That is why no definite restrictions are imposed in the proposed device upon the structure of energy spectrum of electrons in molecules and clusters which establish single-electron tunnel junctions therein. As to the speed of response the proposed device is not inferior to the prototype, i.e., the device functioning on the effect of resonance tunneling. Energy release during electron tunneling in the proposed device is lower than in the known tunnel-effect devices. As distinct from the prototype, wherein no direct association is provided between the tunneling processes and the current measured on the output electrode, the tunneling current is directly registered in the proposed device.
Used as active elements in the proposed device are molecules or clusters (metal-containing ones inclusive) rather than semiconductor islands as in the prototype.
The herein-proposed tunnel-effect device functions on the base of controlled single-electron correlated electron tunneling. The phenomenon of single-electron correlated electron tunneling was theoretically predicted and described, and afterwards demonstrated experimentally. Possibility of controlling such tunneling current opens the way to constructing various electronic circuits on the base of single-electron tunneling junctions and hence to preparing single-electron analog and digital devices. Preparing such devices is very promising and important for further development of microelectronics engineering, since they operate on a new principle of information coding, consisting in that individual electrons perform the function of information carriers. Thus, such devices are featured by rather high speed characteristics. Theoretical assessment of the speed response corresponding to the dimensional parameters of the proposed device gives the value of ∼3·10^-14 s, as well as the value of energy release during the process of the single-electron transfer equal to ∼10^-24 J. The principal concepts of constructing the circuitry analog and digital devices on the base of controlled single-electron tunneling are at present developed theoretically, though single-electron devices developed on the principle of the traditional solid-state planar technology are operable only at extremely low temperatures (< 1 K). It follows from theory that in order that a single-electron device functions at room temperature, the characteristic dimensions of its active regions (that is, single-electron tunneling junction) should be below 100 Å. However, the heretofore-known solid-state microelectronic technologies cannot at present (and probably in the nearest future) develop such devices reproducibly.
The method for making tunnel-effect devices having its active region measuring below 100 A initiated the development of devices of a new class, i.e., nanoelectronics. The effect of discrete tunneling of individual current carriers through tunneling barriers at room temperature used in the tunnel-effect device may also be applied in a single-electron transistor and used for constructing single-electron gate circuits, wherein logical "1" and "0" are identified with the presence or absence of an electron.
The effect of discrete single-electron tunneling used in tunnel-effect devices prepared by the proposed method allows of creating a quite number of analog and digital devices featuring different degrees of integration and very high performance characteristics.
The greatest prospects are offered in the development of very large-scale integrated circuits, wherein said devices can provide a combination of extremely low energy dissipation, very low dimensions of the devices themselves, and high speed characteristics, as well as in the development of new high-sensitivity sensors.

Claims

A tunnel-effect device comprising:

an input electrode (3);

an output electrode (4); and

control electrodes (5) of number N;

wherein said input, output and control electrodes are separated with tunnel barriers, characterized in that

the tunnel barriers and an interbarrier apace consist of an arrangement of molecules and organo-metallic clusters (2) forming tunneling junctions which provide for single-electron correlated electron tunneling in the device;

the cluster nuclei have an electronic structure allowing the presence of a variable number of additional electrons which do not affect the atomic structure of the cluster;

the tunnel harriers have properties that are independent of the presence of a tunneling electron, and have a tunneling resistance that is substantially higher than the quantum resistance;

each of the control electrodes (5) being located in a region of said arrangement of molecules and organo-metallic clusters (2).
A tunnel-effect device as set forth in claim 1, characterized in that the input, output, and control electrodes (3, 4, 5) are located on the surface of a solid-state substrate (1).
A tunnel-effect device as set forth in claim 1, characterized in that the input electrode (3) and control electrodes (5) of number K, are located on the surface of the solid-state substrate (1), and control electrodes of number N-K (5) and the output electrode (4) are situated in the region of the arrangement of molecules and organo-metallic clusters outside the surface of the solid-state substrate, where N > 1, K > 0 and K < N.
A tunnel-effect device as set forth in claims 1, 2 or 3, characterized in that the substrate (1) is made of graphite.
A tunnel-effect device as set forth in claims 1 through 4, characterized in that the input, output, and control electrodes (3, 4, 5) are made of gold.
A method for preparing the tunnel-effect device as set forth in claims 1 through 5, consisting in establishing an input (3), an output (4), and a control electrode (5) on the surface of atomically smooth solid-state substrate (1), followed by formation of a monomolecular or multi-monomolecular film, characterized is that the monomolecular or multi-monomolecular film appears as an inert dielectric molecular matrix with fixedly built-in active molecules and organo-metallic clusters which are the localization centers of tunneling electrons and establish tunneling junctions which provide for single-electron correlated electron tunneling, additional control electrodes of number N-1 being additionally formed on the surface of the atomically smooth solid-state substrate wherein

the cluster nuclei have an electronic structure allowing the presence of a variable number of additional electrons which do not affect the atomic structure of the cluster;

the tunnel barriers hava properties chat are independent of the presence of a tunneling electron, and have a tunneling resistance that is substantially higher than the quantum resistance;

each of the control electrodes (5) being located in a region of said arrangement of moleculas and organo-metallic clusters (2).
A method for preparing the tunnel-effect device as set forth in claim 6, characterized in that the inert dielectric molecular matrix with the active molecules and clusters built therein is established using the Langmuir-Blodgett technique.
A method for preparing the tunnel-effect device as set forth in claims 6 or 7, characterized in that for establishing said inert dielectric molecular matrix molecules containing polymerizable chemical groups are used.
A method for preparing the tunnel-effect device as set forth in claims 6, 7 or 8, characterized in that formation of the inert dielectric molecular matrix with fixedly built-in active molecules and clusters which are the localization centers of the tunneling electrons and establish single-electron tunneling junctions is followed by additional polymerization of the molecular structure.
A method for preparing the tunnel-effect device as set forth in claim 6, characterized in that the inert dielectric molecular matrix with fixedly built-in active molecules and clusters is established by the chemical adsorption technique.
A method for preparing the tunnel-effect device as set forth in claim 10, characterized in that for establishing the inert dielectric molecular matrix molecules containing polymerizable chemical groups are used.
A method for preparing the tunnel-effect device as set forth in claim 10 or 11, characterized in that formation of the inert dielectric molecular matrix with fixedly built-in active molecules and clusters which are the localization centers of the tunneling electrons and establish single-electron tunneling junctions is followed by additional polymerization of the molecular structure.