EP0802039A2 - Injection moulding method for EVA-soles, having a treading surface with coloured sections - Google Patents
Injection moulding method for EVA-soles, having a treading surface with coloured sections Download PDFInfo
- Publication number
- EP0802039A2 EP0802039A2 EP97830141A EP97830141A EP0802039A2 EP 0802039 A2 EP0802039 A2 EP 0802039A2 EP 97830141 A EP97830141 A EP 97830141A EP 97830141 A EP97830141 A EP 97830141A EP 0802039 A2 EP0802039 A2 EP 0802039A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- mould
- linking
- cross
- expanding
- eva
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001746 injection moulding Methods 0.000 title claims abstract description 5
- 238000004132 cross linking Methods 0.000 claims abstract description 20
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000000465 moulding Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 17
- 238000000354 decomposition reaction Methods 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 7
- 238000002347 injection Methods 0.000 claims description 7
- 239000007924 injection Substances 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D35/00—Producing footwear
- B29D35/12—Producing parts thereof, e.g. soles, heels, uppers, by a moulding technique
- B29D35/14—Multilayered parts
- B29D35/144—Heels
Definitions
- This patent application concerns an injection moulding method for soles having a treading surface with coloured sections, and produced with expansible and cross-linking "EVA" compounds.
- EVA refers to "vinyl-acetate ethylene copolymer” which, according to the type of additive used, may be thermoplastic or expansible and cross-linking.
- EVA Expansible and cross-linking
- the purpose of this invention is to design a method which makes it possible to obtain during the same moulding stage, a sole whose treading surface has different coloured sections with respect to the colour of the sole, in order to cut the costs currently sustained to paint the sole after moulding.
- the method in question is based on the idea of equipping the sole mould with one or more inserts premoulded in the same material used to mould the sole but of a different colour; the inserts are moulded by heating the expansible and cross-linking "EVA" compound granules to melting point without reaching the higher temperature which triggers the cross-linking and decomposition process of the expanding fillers.
- the method in question also involves the use of a special mould which, on one hand, ensures that the inserts pre-mounted during the injection stage are securely fixed, and on the other prevents mixing, along the edge of the inserts, between the moulding material of the sole and that of the inserts, which would produce unattractive streaks or stains of different shades of colour with respect to the colours of the two materials.
- the method according to the invention entails the use of a special mould with an impression having the same number of annular ribs on its bottom wall as the coloured inserts which are pre-fitted on the mould and which are housed precisely in the cup delimited by each of said annular ribs.
- the cup is shut with a sealing cap consisting of a shaped pad premoulded in the same material as the sole, which is however heated to melting point without attaining the cross-linking and decomposition temperature of the expansion fillers, as previously mentioned for moulding of the inserts.
- Each cap is fixed to its respective cup by means of a series of closely packed rods projecting from the internal surface of the cover which shuts the mould matrix.
- the seal ensured by said caps together with the annular ribs on the bottom of the matrix impression exclude any possible mixing between the fluid mass injected into the mould and that of the inserts which melt in their respective cups.
- the method according to the invention entails the use of a special mould (1) having an impression (2) with the same number of annular ribs (3) on its bottom wall (2a) delimiting the same number of cups (4) conforming exactly to the coloured inserts (5) pre-mounted on the mould (1); the cover (6) of mould (1) having in proximity of each of the cups (4), a series of closely packed rods (7) projecting from its internal surface (6a).
- the method according to the invention also involves the use of inserts (5) consisting of plates moulded in the same materials used to mould the sole, but of a different colour; said inserts (5) being moulded by heating the granules of expanding and cross-linking "EVA" based compound to melting point, without however reaching the higher temperature which triggers the cross-linking and decomposition of the expanding fillers.
- the method according to the invention also entails the use of caps (8) which shut said cups (4), consisting of pads moulded in the same material used to mould the sole; the caps (8) being moulded by heating the granules of expanding and cross-linking "EVA" based compound to melting point, without however reaching the higher temperature which triggers the cross-linking and decomposition of the expanding fillers.
- said caps (8) are provided on their bottom surface with a perimeter groove (8a) designed to couple precisely with the annular rib (3) delimiting each cup (4) housing the inserts (5).
- the thickness of the coloured inserts (5) is inferior to the height of the annular ribs (3).
- the method according to the invention provides that the moulding phase of the sole occurs as follows:
- the sole (9) obtained with the method according to the invention is provided on its treading surface with one or more sections (10) of different colours with respect to that of the sole (9) delimited by a run (11) that corresponds to the impression produced by the annular rib (3) delimiting the cup (4) in which the insert (5) is fitted and from which each coloured section (10) is produced.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Walking Sticks, Umbrellas, And Fans (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
- This patent application concerns an injection moulding method for soles having a treading surface with coloured sections, and produced with expansible and cross-linking "EVA" compounds.
- The patent protection is also extended to the sole obtained with the method according to the invention.
- The abbreviation "EVA" refers to "vinyl-acetate ethylene copolymer" which, according to the type of additive used, may be thermoplastic or expansible and cross-linking.
- In the case of the latter type, an expanding powder additive is used which decomposes at a specific temperature to produce gases which give rise to a typical phenomenon which occurs in injection moulding using this type of "EVA", consisting of the instantaneous expansion of the part as soon as the mould is opened.
- In particular the dimensions of the part increase rapidly while the proportions and shape remain unaltered thus maintaining a ratio of perfect similarity with respect to the impression of the matrix.
- Expansible and cross-linking "EVA", thanks above all to its low cost, is widely used in the footwear sector for the production of inexpensive injection moulded soles.
- To date it has not been possible to produce injection moulded soles in expansible and cross-linking "EVA" compounds, having a treading surface with one or more different coloured sections with respect to the sole; in fact, this can only be achieved by painting the single-colour sole after moulding.
- The purpose of this invention is to design a method which makes it possible to obtain during the same moulding stage, a sole whose treading surface has different coloured sections with respect to the colour of the sole, in order to cut the costs currently sustained to paint the sole after moulding.
- The method in question is based on the idea of equipping the sole mould with one or more inserts premoulded in the same material used to mould the sole but of a different colour; the inserts are moulded by heating the expansible and cross-linking "EVA" compound granules to melting point without reaching the higher temperature which triggers the cross-linking and decomposition process of the expanding fillers.
- The method in question also involves the use of a special mould which, on one hand, ensures that the inserts pre-mounted during the injection stage are securely fixed, and on the other prevents mixing, along the edge of the inserts, between the moulding material of the sole and that of the inserts, which would produce unattractive streaks or stains of different shades of colour with respect to the colours of the two materials.
- It is important to consider in fact that the granules of the "EVA" based compound are heated to melting point before being injected into the mould, in which the inserts also reach melting temperature, so that one of the most difficult problems resolved was in fact that of avoiding with absolutely security the possibility that streaks or halos of different shades would appear on the treading surface due to the mixing of different coloured molten "EVA" granules.
- In order to resolve this problem, the method according to the invention entails the use of a special mould with an impression having the same number of annular ribs on its bottom wall as the coloured inserts which are pre-fitted on the mould and which are housed precisely in the cup delimited by each of said annular ribs.
- According to the method in question, once each of the cups has been mounted with its respective insert, the cup is shut with a sealing cap consisting of a shaped pad premoulded in the same material as the sole, which is however heated to melting point without attaining the cross-linking and decomposition temperature of the expansion fillers, as previously mentioned for moulding of the inserts.
- Each cap is fixed to its respective cup by means of a series of closely packed rods projecting from the internal surface of the cover which shuts the mould matrix.
- When the cover of the mould is shut over the matrix, said rods penetrate into said caps, which are thus held securely over the cups even during the injection phase, despite the fact that the flow of liquid enters the mould at a very high pressure.
- Moreover, the seal ensured by said caps together with the annular ribs on the bottom of the matrix impression, exclude any possible mixing between the fluid mass injected into the mould and that of the inserts which melt in their respective cups.
- For major clarity the description of the process continues with reference to the enclosed drawings which are intended for purposes of illustration and not in a limiting sense, where:
- Fig. 1 shows the open mould cross-sectioned with a transversal plane of its impression;
- Fig. 2 is similar to fig. 1 with the addition of an insert mounted in the impression of the mould;
- Fig. 3 is similar to fig. 2 with the addition of the cap which shuts the cup housing the insert;
- Fig. 4 is similar to fig. 3 with the addition of the mould cover;
- Fig. 5 shows the treading surface of a sole realised using the method according to the invention;
- Fig. 6 is a cross-section of the sole in Fig. 5 with the transversal plane VI-VI of fig. 5.
- The method according to the invention entails the use of a special mould (1) having an impression (2) with the same number of annular ribs (3) on its bottom wall (2a) delimiting the same number of cups (4) conforming exactly to the coloured inserts (5) pre-mounted on the mould (1); the cover (6) of mould (1) having in proximity of each of the cups (4), a series of closely packed rods (7) projecting from its internal surface (6a).
- The method according to the invention also involves the use of inserts (5) consisting of plates moulded in the same materials used to mould the sole, but of a different colour; said inserts (5) being moulded by heating the granules of expanding and cross-linking "EVA" based compound to melting point, without however reaching the higher temperature which triggers the cross-linking and decomposition of the expanding fillers.
- The method according to the invention also entails the use of caps (8) which shut said cups (4), consisting of pads moulded in the same material used to mould the sole; the caps (8) being moulded by heating the granules of expanding and cross-linking "EVA" based compound to melting point, without however reaching the higher temperature which triggers the cross-linking and decomposition of the expanding fillers.
- In particular, said caps (8) are provided on their bottom surface with a perimeter groove (8a) designed to couple precisely with the annular rib (3) delimiting each cup (4) housing the inserts (5).
- In order to ensure said coupling, the thickness of the coloured inserts (5) is inferior to the height of the annular ribs (3).
- In consideration of the foregoing, the method according to the invention provides that the moulding phase of the sole occurs as follows:
- a) - fitting onto the mould (1) of the inserts (5), each of which is housed into a corresponding cup (4);
- b) - fitting onto the mould (1) of the caps (8), each of which is housed above a corresponding cup (4) so as to ensure coupling between the perimeter groove (8a) of the cap (8) and the rib (3) delimiting the cup (4);
- c) - closing of the mould;
- d) - injection of the moulding material;
- e) - opening of the mould after a time that ensures cross-linking and decomposition of the expanding fillers simultaneously in the injected mass, in the molten mass of the inserts (5) and in the molten mass of the caps (8).
- As shown in figures 5 and 6, the sole (9) obtained with the method according to the invention is provided on its treading surface with one or more sections (10) of different colours with respect to that of the sole (9) delimited by a run (11) that corresponds to the impression produced by the annular rib (3) delimiting the cup (4) in which the insert (5) is fitted and from which each coloured section (10) is produced.
Claims (3)
- A method for injection moulding soles realised with expanding and cross-linking "EVA" based compounds having coloured sections on the treading surface, characterised by:- the provision of shaped inserts (5) consisting of plates moulded with the same type of expanding and cross-linking "EVA" based compound used to mould the sole, but of a different colour, whose granules are heated to melting point without however reaching the higher temperature which triggers cross-linking and decomposition of the expanding fillers;- provision and use of a special mould (1) whose impression (2) is provided on its bottom wall (2a) with the same number of annular ribs (3) delimiting the same number of cups (4) exactly conforming to the above coloured inserts (5), while the cover (6) of the mould (1) is provided on each of the cups (4) with a series of closely packed rods (7) projecting from its internal surface (6a);- the provision of caps (8) which seal said cups (4), consisting of shaped pads moulded with the same expanding and cross-linking "EVA" based compound used to mould the sole, whose granules are heated to melting point without however attaining the higher temperature which triggers cross-linking and decomposition of the expanding fillers;- fitting onto the mould (1) of the inserts (5), each of which is housed into its respective cup (4);- fitting onto the mould (1) of the caps (8), each of which is housed above its corresponding cup (4);- closing of the mould (1);- injection of the moulding material into the mould (1);- opening of the mould (1) after a time that ensures cross-linking and decomposition of the expanding fillers simultaneously in the injected mass, in the molten mass of the inserts (5) and in the molten mass of the caps (8).
- A method according to the previous claim characterised by the provision of caps (8) to shut said cups (4) having a perimeter groove (8a) at the bottom which couples with the annular rib (3) of the cup (4) shut by the cap (8).
- An injection moulded sole realised in expanding and cross-linking "EVA" based compound having coloured sections on its treading surface, and produced with the method described in the previous claims.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITAN960009 | 1996-04-19 | ||
IT96AN000009A IT1286974B1 (en) | 1996-04-19 | 1996-04-19 | METHOD FOR INJECTION PRINTING SOLES MADE WITH EXPANDABLE AND CROSS-LINKABLE "EVA" BASED COMPOUNDS AND LAYING ON THE PLANT OF |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0802039A2 true EP0802039A2 (en) | 1997-10-22 |
EP0802039A3 EP0802039A3 (en) | 1998-04-08 |
EP0802039B1 EP0802039B1 (en) | 2001-10-04 |
Family
ID=11333961
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97830141A Expired - Lifetime EP0802039B1 (en) | 1996-04-19 | 1997-03-25 | Injection moulding method for EVA-soles, having a treading surface with coloured sections |
Country Status (6)
Country | Link |
---|---|
US (1) | US5814254A (en) |
EP (1) | EP0802039B1 (en) |
AT (1) | ATE206353T1 (en) |
DE (1) | DE69707042D1 (en) |
IT (1) | IT1286974B1 (en) |
TW (1) | TW349051B (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004105534A2 (en) | 2003-05-23 | 2004-12-09 | Crocs, Inc. | Footwear pieces and methods for manufacturing such |
US6993858B2 (en) | 2003-05-23 | 2006-02-07 | Crocs, Inc. | Breathable footwear pieces |
ES2255795A1 (en) * | 2003-12-01 | 2006-07-01 | Semic, S.A. | Mould for two colour shoe soles includes bottom ridges for discontinuous bottom layer formation below a continuous top sole layer |
EP1803364A2 (en) | 2003-05-23 | 2007-07-04 | Crocs, Inc. | Footwear pieces and methods for manufacturing such |
EP2074899A1 (en) * | 2007-12-21 | 2009-07-01 | Thermoshoe S.n.c. di Baldin & C. | Method and mold for manufacturing antistatic shoes and molded antistatic shoe |
WO2016109258A1 (en) | 2014-12-30 | 2016-07-07 | 3M Innovative Properties Company | Waterproof, polymeric brace |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5972257A (en) * | 1998-09-21 | 1999-10-26 | Liu; Kun-Chung | Process for making a foamed shoe sole |
US6129798A (en) * | 1999-12-14 | 2000-10-10 | Shun-Feng Lu | Process for manufacturing an ethylene vinyl acetate insole |
US6238602B1 (en) | 1999-12-14 | 2001-05-29 | Kun-Chung Liu | Two-stage forming process for producing an expanded sole |
US6299806B1 (en) * | 2000-03-14 | 2001-10-09 | Ching-Chin Chen | Method for manufacturing EVA outsoles |
GB2361662B (en) * | 2000-04-26 | 2004-08-04 | Matthew James Lewis-Aburn | A method of manufacturing a moulded article and a product of the method |
US7118793B2 (en) * | 2002-05-22 | 2006-10-10 | Swei Mu Wang | Three-dimensional foamable structure with wear-resistant feature |
US6743385B2 (en) * | 2002-05-22 | 2004-06-01 | Swei Mu Wang | Wear-resistant three-dimensional foamable structure and the method for manufacturing it |
US6776939B2 (en) * | 2002-08-05 | 2004-08-17 | Kun-Chung Liu | Method for making an expanded shoe sole |
KR20020073125A (en) * | 2002-09-05 | 2002-09-19 | 이동락 | manufacturing method and mould for the shoe-sole which has different colors or hardness |
US20040231190A1 (en) * | 2003-05-23 | 2004-11-25 | Western Brands Llc | Footwear pieces and methods for manufacturing such |
CN100358701C (en) * | 2004-01-16 | 2008-01-02 | 许圣慈 | Injection moulding method for ethylene-vinyl acetate copolymer foaming |
US20050173821A1 (en) * | 2004-02-05 | 2005-08-11 | Kun-Chung Liu | Method for making an outsole having a tread member |
US7157028B2 (en) * | 2004-06-03 | 2007-01-02 | Jer-Chin Ou | Method of making ventilative insole |
US7832116B2 (en) * | 2006-03-29 | 2010-11-16 | Payless Shoesource Worldwide, Inc. | System and method for making footwear with injected color |
US8371044B2 (en) | 2007-08-01 | 2013-02-12 | Polliwalks, Inc. | Shoes |
US8371043B2 (en) * | 2007-08-01 | 2013-02-12 | Polliwalks, Inc. | Shoes |
US20100260880A1 (en) * | 2009-04-13 | 2010-10-14 | Kun-Chu Lin | Mold for Manufacturing an Outsole with Fabric Bottom |
US8815138B2 (en) | 2010-12-31 | 2014-08-26 | North Pass, Ltd. | Method of producing a recoil pad for a weapon |
US10040888B1 (en) | 2013-06-14 | 2018-08-07 | Cooper-Standard Automotive Inc. | Composition including silane-grafted polyolefin |
US10100139B2 (en) | 2013-08-01 | 2018-10-16 | Cooper-Standard Automotive Inc. | Hose, composition including silane-grafted polyolefin, and process of making a hose |
CN111853380A (en) | 2014-07-02 | 2020-10-30 | 库博标准汽车配件有限公司 | Hose, abrasion resistant composition and hose manufacturing process |
WO2018107107A1 (en) | 2016-12-10 | 2018-06-14 | Cooper-Standard Automotive Inc. | Static seals, compositions, and methods of making the same |
EP3411438A1 (en) | 2016-12-10 | 2018-12-12 | Cooper-Standard Automotive, Inc. | Polyolefin elastomer compositions and methods of making the same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4762654A (en) * | 1985-11-05 | 1988-08-09 | Bridgestone Corporation | Method for making foamed articles having a laminated structure |
US5318645A (en) * | 1993-02-22 | 1994-06-07 | Yang Kuo Nan | EVA insole manufacturing process |
US5362435A (en) * | 1993-08-06 | 1994-11-08 | Quabaug Corporation | Process of molding multi-durometer soles |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4436276A (en) * | 1982-01-22 | 1984-03-13 | Voplex Corporation | Pin support and mold for foaming and curing resin exterior over ball core |
US4674204A (en) * | 1983-02-28 | 1987-06-23 | Sullivan James B | Shock absorbing innersole and method for preparing same |
US4876053A (en) * | 1986-04-04 | 1989-10-24 | New Balance Athletic Shoe, Inc. | Process of molding a component of a sole unit for footwear |
EP0485639B1 (en) * | 1990-11-10 | 1995-03-29 | Kuo-Nan Yang | EVA insole manufacturing process |
JP2708084B2 (en) * | 1992-03-23 | 1998-02-04 | ワイケイケイ株式会社 | Method of attaching hook-and-loop fastener to seat cushion material and foam molding die |
JPH08227637A (en) * | 1994-02-23 | 1996-09-03 | Matsushita Electric Works Ltd | Control switch and manufactur thereof |
US5503786A (en) * | 1995-08-15 | 1996-04-02 | Yang; Kuo-Nan | Method for forming air chamber in shoe sole |
-
1996
- 1996-04-19 IT IT96AN000009A patent/IT1286974B1/en active IP Right Grant
- 1996-11-13 TW TW085113839A patent/TW349051B/en active
-
1997
- 1997-02-26 US US08/806,683 patent/US5814254A/en not_active Expired - Fee Related
- 1997-03-25 EP EP97830141A patent/EP0802039B1/en not_active Expired - Lifetime
- 1997-03-25 DE DE69707042T patent/DE69707042D1/en not_active Expired - Lifetime
- 1997-03-25 AT AT97830141T patent/ATE206353T1/en not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4762654A (en) * | 1985-11-05 | 1988-08-09 | Bridgestone Corporation | Method for making foamed articles having a laminated structure |
US5318645A (en) * | 1993-02-22 | 1994-06-07 | Yang Kuo Nan | EVA insole manufacturing process |
US5362435A (en) * | 1993-08-06 | 1994-11-08 | Quabaug Corporation | Process of molding multi-durometer soles |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004105534A2 (en) | 2003-05-23 | 2004-12-09 | Crocs, Inc. | Footwear pieces and methods for manufacturing such |
US6993858B2 (en) | 2003-05-23 | 2006-02-07 | Crocs, Inc. | Breathable footwear pieces |
US7146751B2 (en) | 2003-05-23 | 2006-12-12 | Crocs, Inc. | Footwear pieces |
EP1803364A2 (en) | 2003-05-23 | 2007-07-04 | Crocs, Inc. | Footwear pieces and methods for manufacturing such |
ES2255795A1 (en) * | 2003-12-01 | 2006-07-01 | Semic, S.A. | Mould for two colour shoe soles includes bottom ridges for discontinuous bottom layer formation below a continuous top sole layer |
EP2074899A1 (en) * | 2007-12-21 | 2009-07-01 | Thermoshoe S.n.c. di Baldin & C. | Method and mold for manufacturing antistatic shoes and molded antistatic shoe |
WO2016109258A1 (en) | 2014-12-30 | 2016-07-07 | 3M Innovative Properties Company | Waterproof, polymeric brace |
Also Published As
Publication number | Publication date |
---|---|
ITAN960009A0 (en) | 1996-04-19 |
US5814254A (en) | 1998-09-29 |
ITAN960009A1 (en) | 1997-10-19 |
EP0802039A3 (en) | 1998-04-08 |
DE69707042D1 (en) | 2001-11-08 |
IT1286974B1 (en) | 1998-07-24 |
ATE206353T1 (en) | 2001-10-15 |
TW349051B (en) | 1999-01-01 |
EP0802039B1 (en) | 2001-10-04 |
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