EP0620865B1 - Gleisteile sowie verfahren zur herstellung dieser - Google Patents
Gleisteile sowie verfahren zur herstellung dieser Download PDFInfo
- Publication number
- EP0620865B1 EP0620865B1 EP93901743A EP93901743A EP0620865B1 EP 0620865 B1 EP0620865 B1 EP 0620865B1 EP 93901743 A EP93901743 A EP 93901743A EP 93901743 A EP93901743 A EP 93901743A EP 0620865 B1 EP0620865 B1 EP 0620865B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- rail
- section
- railway
- track element
- steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/04—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rails
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S148/00—Metal treatment
- Y10S148/902—Metal treatment having portions of differing metallurgical properties or characteristics
Definitions
- the invention relates to track parts made using steel.
- the invention further relates to a method for producing track parts by at least rolling steel.
- C carbon
- Mn manganese
- Si silicon
- Cr chromium
- Pmax phosphorus max
- Smax sulfur max
- Rm tensile strength
- A5 elongation at break.
- a disadvantage of martensitic tempering i.e. austenitizing, quenching and tempering, is insufficient hardening and / or tensile strengths below 1300 N / mm for hardnesses below 400 HV.
- the material group of the rail steels was replaced by tempered steels.
- Steels such as 50 Cr Mo4 and 50 Cr V4 are used.
- the hardening is carried out to tensile strengths of 1100 N / mm to 1350 N / mm.
- Fine pearlizing is based on UIC 900 A rails according to Table 1 or a comparable AREA quality. Good hardening depths are achieved, although the maximum values are limited to ⁇ 400 HV.
- the yield strength and tensile strength are 850 N / mm and 1250 N / mm, respectively (see, for example, "testing high-strength, naturally hard rails on the Gotthard line", Ch. Hoffmann, W. Heller, J. rempligge, R. Schweitzer, ETR 38 (1989), pages 775/781.
- the combination of fine pearlitization with simultaneous precipitation hardening allows hardening from 400 HV to 440 HV with yield strengths from 800 N / mm to 900 N / mm.
- the steels used are at the limit of the permissible fracture toughness.
- a tensile strength of 1400 N / mm is generally considered to be the upper limit.
- DE 31 11 420 A1 shows an essentially pearlitic steel alloy in which the austenitizing temperature is above 743 ° C. in order to rule out undesirable martensite formation during rolling or slipping between a wheel and a rail.
- it is proposed according to EP 0 247 021 A2 to heat the steel to austenitizing temperature, to accelerate cooling using gaseous and / or liquid coolant, using at least two nozzle assemblies.
- the present invention is based on the problem of providing track parts or a method for producing them which can be used both for normal track and for the turnout area, the steel when used as a rail material in its fracture toughness and thus in the fracture resistance of pearlitic splints of corresponding strength levels should be clearly superior.
- the strength and the associated yield strength should also ensure resistance to plastic deformation, in particular can occur in highly stressed switches.
- the steel is a vacuum-treated steel with 0.53 to 0.62% C, 0.15 to 0.25% Si, 0.65 to 1.1% Mn, 0.8 to 1, 3% Cr, 0.05 to 0.11% Mo, 0.05% to 0.11% V, ⁇ 0.02% P, optionally up to 0.025% Al, optionally up to 0.5% Nb, residual iron and usual melting-related Impurities, the ratio of Mn to Cr being approximately 0.80 M Mn: Cr 0,8 0.85 and the ratio of Mo to V being approximately 1 that the track part in the form of a rail is rolled steel with a pearlitic structure and that the track part in the form of a switch section is a rolled rail section as the starting material, which by tempering has a martensitic structure at least in the rail head.
- the Al content without controlled additions of Al should be between 0.001% and 0.005%, if possible below 0.003%. If Al is an alloy component, 0.015 to 0.025% Al should be added.
- the hydrogen content should be below 2 ppm in all fillings.
- the steel can have niobium (Nb) in a proportion of, preferably between 0.002% and 0.04%.
- the problem is solved according to the invention in that a vacuum-treated steel with 0.53 to 0.62% C, 0.15 to 0.25% Si, 0.65 to 1.1% Mn, 0.8 to 1.3 % Cr, 0.05 to 0.11% Mo, 0.05 to 0.11% V, ⁇ 0.2% P optionally up to 0.025% Al, optionally up to 0.5% Nb.
- Residual iron and usual impurities due to melting are used, the ratio of Mn to Cr being approximately 0.80 M Mn: Cr 0,8 0.85 and the ratio of Mo to V being approximately 1, that for the production of a rail as a track part the steel is rolled and has a pearlitic structure with a minimum strength of 900 N / mm, that for the production of a switch section as a track part a section of the rolled rail at least in the area of its head to an austenitizing temperature of approx. 850 ° Heated to approx. 1050 ° C, using cooling fluids in 60 to 120 seconds from a temperature of approx. 850 ° C to approx. 500 ° C and in 140 to 400 seconds from a temperature of approx. 500 ° C to approx. 200 ° C cooled and then tempered to a minimum strength of 1,500 N / mm. Further cooling to room temperature can take place, for example, in air.
- the Al content without controlled addition of Al should be between 0.001% and 0.005%, if possible below 0.003%. In the case of Al alloy constituents, 0.015 to 0.025% Al should be added.
- the rail section is preferably inductively heated and then compressed air at a cooling rate of about 175 ° C / minute from about 850 ° C to about 500 ° C, then at a cooling rate of about 75 ° C / minute of about 500 ° C to about 200 ° C, optionally then cooled to room temperature in still air and then subjected to a tempering treatment at about 500 ° C, which preferably lasts in about 30 minutes to 120 minutes.
- the possibility has been created through material and heat treatment of a pearlitic steel in the rolled state, which is of the same type with standard and special grades and can be butt welded, with initial strengths of ⁇ 900 N / mm or ⁇ 1000 N / mm or ⁇ 1100 N / mmm by hardening and tempering in the rail head to set strengths above 1500 N / mm corresponding to a hardness ⁇ 450 HV.
- the steel in the rolled state is cracked in its fracture toughness and thus in fracture resistance
- the strength and the associated yield strength make it resistant to plastic deformations, which occur particularly in high-stress switches.
- the desired strength levels can be achieved with steels, the directional analyzes of which can be found in Table 2: stolen strength C. Si Mn Cr Mo / V P max N / mm % ⁇ 0.02 % ⁇ 0.05 % ⁇ 0.10 % ⁇ 0.10 % ⁇ 0.01 % 1 ⁇ 900 0.55 0.20 0.75 0.90 0.06 0.020 2nd ⁇ 1000 0.58 0.20 0.85 1.00 0.08 0.020 3rd ⁇ 1100 0.60 0.20 1.00 1.20 0.10 0.015
- the rail parts tempered according to the invention also show considerable advantages in terms of their mechanical properties compared to finely pearlized rails, as shown in Table 4 below: treatment Rp 0.2 Rm Flexural fatigue strength K IC N / mm N / mm N / mm N / mm 3/2 finely pearlized 850 1250 400 1050 according to the invention 1390 1550 700 1800 + 59% + 24% + 75% + 71%
- the yield point Rp02 which is important for maintaining the geometry in turnouts, has increased by 59%, the tensile strength Rm by 24% compared to fine pearlized turnouts.
- the flexural fatigue strength which determines the resistance to fatigue damage such as breakouts, has improved by 75%.
- the fracture toughness K IC could be increased by approximately 70%.
- the teaching according to the invention results in considerable advantages both in track construction and in particular in switch construction.
- the expected long service life brings an improvement in safety against breakage, driving comfort and economy.
- FIG. 1 shows a cross section of a track part (10) produced according to the invention in the form of a rail, which comprises a rail foot (12), a web (14) and a rail head (16).
- a vacuum-treated steel analysis was used to manufacture the rail, which can be seen in Table 2.
- the Al content is preferably 0.001% and 0.005%, if possible below 0.003%.
- aluminum with a proportion of 0.01% to 0.05% and niobium with a proportion of 0.02% to 0.04% can also be present.
- the rail is formed by rolling and after rolling has a pearlitic structure with a strength of 900 N / mm to 1220 N / mm with fracture toughness above 1500 N / mm 3/2 .
- tempering is carried out, that is to say martensitic hardening and tempering.
- the rail head (16) is heated to the hardening temperature, ie to the austenitizing temperature in the range from 850 ° C. to 1,050 ° C., preferably heated inductively.
- the temperature range between 850 ° C and 500 ° C being run in 60 to 120 seconds and the temperature range from 500 ° C to 200 ° C in 140 to 400 seconds.
- the higher cooling rate should be used in the lower alloy area and the lower in the upper alloy area reach.
- bainite fractions of up to 70% are formed between 500 ° C and 250 ° C. They prevent the build-up of high cooling and transformation stresses in the transition to the base material and allow the use of comparatively high C contents without the formation of stress cracks.
- the area marked with the reference symbol (18) is the compensation area
- the region marked with the reference symbol (20) is the transition region
- the region below and with the reference symbol (22) is the region that corresponds to the Corresponds to the rolling condition.
- This area (22) extends from the lower part of the rail head (16) over the web (14) to the rail base (12).
- tempering takes place in the temperature range between 450 ° C and 600 ° C depending on the selected duration.
- FIG. 2 shows a semi-schematic representation of the temperature-time curve in the heat treatment provided.
- the area (24) corresponds to the heating, the area (26) to the temperature compensation, the area (28) to the cooling area between 950 ° C and 500 ° C, the area (30) to the cooling area between 500 ° C and 200 ° C, the area (32) the cooling area between 200 ° C and 20 ° C.
- the region (34) starts the tempering, ie the heating to the tempering temperature.
- the area (36) shows the holding time at the starting temperature.
- the area (38) is intended to reflect the cooling to room temperature.
- the scatter band (48) corresponds to a fine pearlization according to DE 34 46 794 C1.
- the scatter band (50) is said to be a fine pearlizing according to "head-hardened rail for the highest operational demands", H. Schmedders, H. Bienzeisler, K.-H. Tucke and K. Wick, ETR (1990) Issue 4.
- the entire cross section of the track part (10) can thus be austenitized and cooled in such a way that the area (18) in FIG. 1 forms martensite, the area (20) predominantly bainite and the remaining cross section forms pearlite structure. Starting is done as already described.
- An advantage of this variant is that no softening occurs in the transition from the heat-treated area to the base material.
- the entire cross section can be hardened and the areas (18) and (20) can be left on as described.
- the remaining cross section is additionally tempered at a temperature which is 100 to 150 ° C higher in such a way that the strength in this area is approximately 400 N / mm lower than in areas (18) and (20).
- the advantage of this variant is that a particularly high level of break resistance is set in the web (14) and foot (12) of the rail section (10).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Heat Treatment Of Articles (AREA)
- Heat Treatment Of Steel (AREA)
- Magnetic Heads (AREA)
- Laminated Bodies (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Adornments (AREA)
- Manufacturing Of Magnetic Record Carriers (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4200545 | 1992-01-11 | ||
| DE4200545A DE4200545A1 (de) | 1992-01-11 | 1992-01-11 | Gleisteile sowie verfahren zur herstellung dieser |
| PCT/EP1993/000035 WO1993014230A1 (de) | 1992-01-11 | 1993-01-10 | Gleisteile sowie verfahren zur herstellung dieser |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0620865A1 EP0620865A1 (de) | 1994-10-26 |
| EP0620865B1 true EP0620865B1 (de) | 1996-04-24 |
Family
ID=6449363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP93901743A Expired - Lifetime EP0620865B1 (de) | 1992-01-11 | 1993-01-10 | Gleisteile sowie verfahren zur herstellung dieser |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5482576A (cs) |
| EP (1) | EP0620865B1 (cs) |
| KR (1) | KR950700434A (cs) |
| AT (1) | ATE137272T1 (cs) |
| AU (1) | AU3258893A (cs) |
| BR (1) | BR9305723A (cs) |
| CZ (1) | CZ292435B6 (cs) |
| DE (2) | DE4200545A1 (cs) |
| DK (1) | DK0620865T3 (cs) |
| ES (1) | ES2089783T3 (cs) |
| FI (1) | FI98313C (cs) |
| GR (1) | GR3020593T3 (cs) |
| HU (1) | HUT67897A (cs) |
| NO (1) | NO942577L (cs) |
| PL (1) | PL171175B1 (cs) |
| RU (1) | RU94040705A (cs) |
| WO (1) | WO1993014230A1 (cs) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19735285C2 (de) * | 1997-08-14 | 2001-08-23 | Butzbacher Weichenbau Gmbh | Verfahren zur Herstellung eines Gleisteils |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9313060D0 (en) * | 1993-06-24 | 1993-08-11 | British Steel Plc | Rails |
| AU680976B2 (en) * | 1993-12-20 | 1997-08-14 | Nippon Steel Corporation | Rail of high abrasion resistance and high tenacity having pearlite metallographic structure and method of manufacturing the same |
| RU2139946C1 (ru) * | 1996-04-15 | 1999-10-20 | Ниппон Стил Корпорейшн | Обладающие превосходной износостойкостью и свариваемостью рельсы из низколегированной термообработанной перлитной стали, а также способ их производства |
| DE19621017C1 (de) * | 1996-05-24 | 1998-01-08 | Butzbacher Weichenbau Gmbh | Verfahren zur Herstellung eines Gleisoberbauteils sowie Gleisoberbauteil |
| US20050172894A1 (en) * | 2004-02-10 | 2005-08-11 | Farnworth Warren M. | Selective deposition system and method for initiating deposition at a defined starting surface |
| DE102006029818B3 (de) * | 2006-06-28 | 2007-12-06 | Siemens Ag | Führungsschiene sowie Verfahren zum Herstellen einer Führungsschiene |
| KR100815985B1 (ko) * | 2007-02-08 | 2008-03-24 | 조용삼 | 엘레베이터용 가이드 레일의 제조방법 |
| US7591909B2 (en) * | 2007-08-23 | 2009-09-22 | Transportation Technology Center, Inc. | Railroad wheel steels having improved resistance to rolling contact fatigue |
| US9040882B2 (en) * | 2007-09-12 | 2015-05-26 | Inductotherm Corp. | Electric induction heating of a rail head with non-uniform longitudinal temperature distribution |
| AU2013253561B2 (en) | 2012-04-23 | 2014-12-18 | Nippon Steel Corporation | Rail |
| KR102370219B1 (ko) * | 2020-07-29 | 2022-03-08 | 한국철도기술연구원 | 철도차량 연결기용 합금강 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2541978C3 (de) * | 1975-09-20 | 1978-08-24 | Butzbacher Weichenbau Gmbh, 6308 Butzbach | Verfahren zur Wärmebehandlung von Weichenteilen im Durchlaufverfahren |
| JPS52138427A (en) * | 1976-05-17 | 1977-11-18 | Nippon Steel Corp | Production of rail having excellent wear resistance and damage resistance as rolled |
| JPS52138428A (en) * | 1976-05-17 | 1977-11-18 | Nippon Steel Corp | Production of rail having excellent wear resistance and damage resistance as rolled |
| DE2821227C2 (de) * | 1978-05-16 | 1982-12-23 | Krupp Stahl Ag, 4630 Bochum | Verfahren zur Herstellung von Schienen mit verminderter Riffelbildung |
| JPS5919173B2 (ja) * | 1979-03-17 | 1984-05-02 | 新日本製鐵株式会社 | 溶接性低合金熱処理硬頭レ−ルの製造法 |
| SU804702A2 (ru) * | 1979-04-16 | 1981-02-15 | Украинский Ордена Трудового Крас-Ного Знамени Научно-Исследовательс-Кий Институт Металлов | Способ термической обработкиРЕльСОВ |
| BE884443A (fr) * | 1980-07-23 | 1981-01-23 | Centre Rech Metallurgique | Perfectionnements aux procedes de fabrication de rails a haute resistance |
| US4404047A (en) * | 1980-12-10 | 1983-09-13 | Lasalle Steel Company | Process for the improved heat treatment of steels using direct electrical resistance heating |
| CH648600A5 (de) * | 1981-03-13 | 1985-03-29 | Schweizerische Lokomotiv | Gegenstaende mit erhoehter bestaendigkeit gegen oberflaechenbeschaedigung durch abroll- und/oder reibungsvorgaenge. |
| LU84417A1 (fr) * | 1982-10-11 | 1984-05-10 | Centre Rech Metallurgique | Procede perfectionne pour la fabrication de rails et rails obtenus par ce procede |
| DE3336006A1 (de) * | 1983-10-04 | 1985-04-25 | Krupp Stahl Ag, 4630 Bochum | Schiene mit hoher verschleissfestigkeit im kopf und hoher bruchsicherheit im fuss |
| BE899617A (fr) * | 1984-05-09 | 1984-11-09 | Centre Rech Metallurgique | Procede et dispositif perfectionnes pour la fabrication de rails. |
| DE3446794C1 (de) * | 1984-12-21 | 1986-01-02 | BWG Butzbacher Weichenbau GmbH, 6308 Butzbach | Verfahren zur Waermebehandlung perlitischer Schienenstaehle |
| JPS6299438A (ja) * | 1985-10-24 | 1987-05-08 | Nippon Kokan Kk <Nkk> | 不安定破壊伝播停止能力を有する耐摩耗性高性能レ−ル |
| AT384624B (de) * | 1986-05-22 | 1987-12-10 | Voest Alpine Ag | Einrichtung zur gesteuerten waermebehandlung von weichenteilen |
| JPH0730401B2 (ja) * | 1986-11-17 | 1995-04-05 | 日本鋼管株式会社 | 靭性の優れた高強度レ−ルの製造方法 |
-
1992
- 1992-01-11 DE DE4200545A patent/DE4200545A1/de not_active Withdrawn
-
1993
- 1993-01-10 ES ES93901743T patent/ES2089783T3/es not_active Expired - Lifetime
- 1993-01-10 DK DK93901743.0T patent/DK0620865T3/da active
- 1993-01-10 CZ CZ19941662A patent/CZ292435B6/cs not_active IP Right Cessation
- 1993-01-10 RU RU94040705/02A patent/RU94040705A/ru unknown
- 1993-01-10 AU AU32588/93A patent/AU3258893A/en not_active Abandoned
- 1993-01-10 KR KR1019940702417A patent/KR950700434A/ko not_active Abandoned
- 1993-01-10 HU HU9402027A patent/HUT67897A/hu unknown
- 1993-01-10 WO PCT/EP1993/000035 patent/WO1993014230A1/de not_active Ceased
- 1993-01-10 BR BR9305723A patent/BR9305723A/pt not_active Application Discontinuation
- 1993-01-10 AT AT93901743T patent/ATE137272T1/de not_active IP Right Cessation
- 1993-01-10 EP EP93901743A patent/EP0620865B1/de not_active Expired - Lifetime
- 1993-01-10 DE DE59302373T patent/DE59302373D1/de not_active Expired - Lifetime
- 1993-01-10 PL PL93304470A patent/PL171175B1/pl not_active IP Right Cessation
-
1994
- 1994-07-08 NO NO942577A patent/NO942577L/no unknown
- 1994-07-08 US US08/256,148 patent/US5482576A/en not_active Expired - Fee Related
- 1994-07-11 FI FI943293A patent/FI98313C/fi not_active IP Right Cessation
-
1996
- 1996-07-23 GR GR960401952T patent/GR3020593T3/el unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19735285C2 (de) * | 1997-08-14 | 2001-08-23 | Butzbacher Weichenbau Gmbh | Verfahren zur Herstellung eines Gleisteils |
Also Published As
| Publication number | Publication date |
|---|---|
| DE59302373D1 (de) | 1996-05-30 |
| NO942577D0 (no) | 1994-07-08 |
| DK0620865T3 (da) | 1996-09-02 |
| KR950700434A (ko) | 1995-01-16 |
| BR9305723A (pt) | 1996-12-31 |
| HUT67897A (en) | 1995-05-29 |
| RU94040705A (ru) | 1996-06-27 |
| WO1993014230A1 (de) | 1993-07-22 |
| EP0620865A1 (de) | 1994-10-26 |
| PL171175B1 (pl) | 1997-03-28 |
| ES2089783T3 (es) | 1996-10-01 |
| FI943293L (fi) | 1994-07-11 |
| ATE137272T1 (de) | 1996-05-15 |
| FI98313C (fi) | 1997-05-26 |
| AU3258893A (en) | 1993-08-03 |
| GR3020593T3 (en) | 1996-10-31 |
| CZ292435B6 (cs) | 2003-09-17 |
| CZ166294A3 (en) | 1995-04-12 |
| FI98313B (fi) | 1997-02-14 |
| FI943293A0 (fi) | 1994-07-11 |
| HU9402027D0 (en) | 1994-09-28 |
| NO942577L (no) | 1994-09-09 |
| DE4200545A1 (de) | 1993-07-15 |
| US5482576A (en) | 1996-01-09 |
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