EP0537668B2 - Process for decorating or marking a surface by means of laser radiation and use of a stamping foil in this process - Google Patents
Process for decorating or marking a surface by means of laser radiation and use of a stamping foil in this process Download PDFInfo
- Publication number
- EP0537668B2 EP0537668B2 EP92117433A EP92117433A EP0537668B2 EP 0537668 B2 EP0537668 B2 EP 0537668B2 EP 92117433 A EP92117433 A EP 92117433A EP 92117433 A EP92117433 A EP 92117433A EP 0537668 B2 EP0537668 B2 EP 0537668B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- colour
- stamping foil
- colored
- lacquer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000011888 foil Substances 0.000 title claims abstract description 33
- 230000005855 radiation Effects 0.000 title claims abstract description 11
- 238000012546 transfer Methods 0.000 claims abstract description 7
- 239000010410 layer Substances 0.000 claims description 112
- 230000001681 protective effect Effects 0.000 claims description 13
- 238000005034 decoration Methods 0.000 claims description 11
- 239000012790 adhesive layer Substances 0.000 claims description 10
- 238000013532 laser treatment Methods 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 239000004922 lacquer Substances 0.000 abstract description 84
- 238000013461 design Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 12
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 238000004049 embossing Methods 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- -1 Polyethylene Polymers 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 238000010147 laser engraving Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009500 colour coating Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
- B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
- B44C1/1729—Hot stamping techniques
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/24—Ablative recording, e.g. by burning marks; Spark recording
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/02—Pyrography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/22—Removing surface-material, e.g. by engraving, by etching
- B44C1/228—Removing surface-material, e.g. by engraving, by etching by laser radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/34—Multicolour thermography
Definitions
- the invention relates to a method for decorating or inscribing a surface by means of laser radiation, wherein at least two differently colored layers of colored lacquer are applied one above the other and then at least the first color coating layer facing the viewer by means of the laser radiation removed to create the decoration or lettering and so the differently colored second color lacquer layer uncovered but not completely removed or removed, with at least the first colored lacquer layer is applied to the surface in a transfer process.
- the method of the type mentioned is used in particular when it comes to an accurate Inscription or decoration for objects that are individual pieces or only in small quantities be made.
- the laser beam used to burn out the first colored lacquer layer can, with regard to its Motion path can be controlled very precisely, for example by means of an electron computer, it is also possible to change the strength of the laser line produced by the burnout.
- Devices suitable for this process are commercially available and are offered, for example, by Baasel Lasertech.
- EP-A-0 383 956 also describes a method for producing security markings on a surface known in which an upper layer covered by a laser radiation absorbing layer of color is correspondingly exposed by removing the upper layer by means of a laser beam.
- an upper layer covered by a laser radiation absorbing layer of color is correspondingly exposed by removing the upper layer by means of a laser beam.
- the surface to be decorated for example the front panel of a device, by means of usual process is provided with two differently colored layers of paint.
- the laser beam then turns the Removed the upper layer of lacquer and the according to the desired decoration or pattern or lettering lower layer of paint, which contrasts with the upper layer of paint, is exposed.
- the problem here is that with conventional lacquer layers there are variations in the thickness of the lacquer layer, with the result that with Burning off the upper layer of lacquer by means of the laser jet under certain circumstances this upper layer of lacquer in the areas in which it is relatively thick, is not completely removed. If you use a higher laser power, you can you can ensure that the upper layer of paint is reliably removed even where it is thicker.
- JP-A-1 (1989) -283.703 describes a method for producing a colored lens, in which one of the Opaque membrane covering the lens, consisting of several layers of paint or lacquer, by means of a Laser beam is provided with a variety of slits, the slits light with which the lens from the other Side is lit, should let through.
- the membrane consisting of several layers can, for example be applied in a hot stamping process.
- the laser beam used to create the slits cuts through in the known method in any case all layers of the membrane so that the actual lens is exposed becomes. The possibility of removing only one or more of the layers of the membrane is not indicated.
- the aim of the invention is now to propose a method which allows it with comparatively little effort to achieve a perfect decoration or labeling of a surface using laser beam engraving.
- Another advantage of the procedure according to the invention is that it is known to be without difficulty is possible, e.g. by means of a printing process, on a flexible support, e.g. a plastic film or one Metal tape, layers of paint only to be applied in certain areas, although of course there is also the possibility of different Area of differently colored paints. If one uses one from different colored areas for the decoration of the surface of an object, there are further Design options previously unattainable with reasonable effort. You can, for example, the Divide the decorating surface into different colored areas and then each with a laser beam label. This makes it e.g. possible, certain fonts on the front panel of a device in a different color Execute as the rest of the label to highlight this label or certain operations assigned.
- first but also the first and the second colored lacquer layer in an embossing process from the carrier film of an embossing film, in particular hot stamping film, to the surface be transferred because of itself then let even greater accuracy be achieved.
- This procedure is especially useful if the second, lower colored lacquer layer consists of differently colored areas, which for example gives the possibility is given to attach differently colored labels on the front panel of a device, which means under Operation can be made considerably easier under certain circumstances.
- a transparent protective lacquer layer on the first color lacquer layer before or after laser processing is applied, which has a correspondingly high mechanical strength.
- Hot stamping foils can be readily used in those known from the manufacture of hot stamping foils Establish process.
- Stamping foils in particular hot stamping foils for use in the method according to the invention point one above the other at least a first and a second differently colored colored lacquer layer, the first colored lacquer layer is closer to the carrier film than the second.
- the two layers of colored lacquer are applied according to the desired decorative effect, for example the first colored lacquer layer on the decorated object can be black, while the second color lacquer layer to be exposed by the laser beam, for example is white
- the properties of the colored lacquer layers can still be adjusted so that the first colored lacquer layer can be removed relatively easily by the laser beam, but otherwise comparatively good mechanical Has strength, while the second color lacquer layer, for example due to its coloring or by additions of the laser beam is attacked as little as possible.
- a polyester film is expediently used as the carrier film a thickness of 6 to 100 microns, preferably from 19 to 38 microns used. These films have sufficient Strength, but also flexibility to differentiate them as carriers when transferring the decorative layer from the carrier film to be able to use shaped surfaces.
- To transfer the decorative or colored lacquer layers from the Carriers on the surface to be decorated can use the methods known per se, for example Lifting process, rolling process, or also process in which the corresponding film is placed in an injection mold and then back injected with plastic to form an object, such as the front panel of a device becomes.
- a clear lacquer layer preferably a thickness of 1 to 2 ⁇ m, can be provided as the protective lacquer layer which, if already present on the embossing foil, are also removed during laser engraving got to. It is advantageous if the second colored lacquer layer of the embossing film is thicker than the first colored lacquer layer, the The thickness of the second colored lacquer layer is preferably approximately 2 to 10 ⁇ m, and the thickness of the first colored lacquer layer is preferred is about 1 to 5 ⁇ m.
- first colored lacquer layer and one in contrast thicker second color coat gives the ability to remove the first color coat to be able to set the serving laser beam so high that the first layer of colored paint in the desired one is reliable Area completely removed, possibly even a small part of the second color lacquer layer removed is ensured, however, that a sufficiently thick remnant of the second color lacquer layer remains, on the one hand to give a perfect decoration picture, on the other hand a reliable protection of the surface the decorated object is guaranteed by the second layer of colored lacquer.
- an embossing foil in particular hot stamping foil, comprising a carrier film, preferably made of polyester, on which a separating layer is successively arranged, optionally a protective lacquer layer, at least two differently colored color lacquer layers and an adhesive layer are arranged to produce the at least two differently colored color lacquer layers on one Surface used.
- the hot stamping foil shown schematically in FIG. 1 comprises a carrier film 1, which is preferably here a polyester film with a thickness of 6 to 100 microns, preferably a thickness of 19 to 38 microns.
- the separating layer 2 generally has a maximum thickness 1 ⁇ m.
- the protective lacquer layer 3 must therefore be adequately resistant to mechanical influences. She has in present case, for example, a thickness of 1 to 2 microns.
- Second color lacquer layer 5 Second color lacquer layer 5:
- This layer is colored differently than the first colored lacquer layer 4, for example when the first colored lacquer layer 4 is black, white or ivory.
- the color lacquer layers 4 and 5 can be individually - and therefore also different - be composed of different colored areas.
- Adhesive layer 6 is Adhesive layer 6
- the adhesive layer also, for example, an adhesive that can be activated by pressure or a layer of a permanently sticky one Material.
- the carrier film 1 would then have to face away from the lacquer layers 3, 4, 5 Side with a coating, for example silicone, which prevents the adhesive layer 6 from adhering to the carrier film 1, be provided in order to be able to wind up the embossing foil accordingly.
- the separating layer 2, the lacquer layers 3 to 5 and the adhesive layer 6 can be produced according to the following recipes: Interface layer 2 toluene 95 parts ethanol 5 parts Ester wax (dropping point 90 ° C) 0.1 parts Protective lacquer layer 3 methyl ethyl ketone 35 parts ethyl acetate 10 parts cyclohexanone 8 parts Methyl methacrylate (softening point 108 ° C) 8 parts Hydroxy-functional acrylate (60% in EGA / xylene 1: 1, OH content 4.4%) 4 parts Hydroxy-functional acrylate (60% in EGA, OH content 6%) 4 parts Celiulose nitrate (low viscosity, 35% in alcohol) 8 parts Polyethylene dispersion (24% in xylene) 7 parts Aromatic isocyanate (50% in ethyl acetate, NCO content 8%) 16 parts First colored lacquer layer 4 (black) methyl ethyl ketone 30 parts Butyl
- a substrate 7, for example the front panel of a device is shown in partial section, on the surface thereof 8 the lacquer layers 3 to 5 forming a release layer 9 and adhesive layer 6 of the hot stamping foil according to FIG Fig. 1 are attached in a conventional hot stamping process.
- a corresponding is then used Laser beam to achieve the desired decoration or lettering both the protective lacquer layer 3 as well as the first, in the exemplary embodiment assumed, black colored lacquer layer 4, namely in such a way that at the bottom 10 of the recessed areas 11 formed by removing the layers 3, 4, for example in Form of lines, letters, areas etc., the second one with different colors to the first colored lacquer layer 4 Color layer 5 appears.
- FIG. 2b the ideal state is shown in FIG. 2b, which consists in that the removal of the lacquer layers by means of the laser beam exactly up to the beginning of the second colored lacquer layer 5 goes.
- the protective lacquer layer 3 was already on the hot stamping foil is present, which has the consequence that the surface 10 of the second colored lacquer layer 5 in the case of a finished decorated product exposed. For certain applications, it may be desirable that this area is also protected. In this case there is either the possibility of using a hot stamping foil which has no protective lacquer layer 3 and then to apply a protective lacquer layer after the laser engraving, which then also fills the recessed areas 11. Another possibility that gives better mechanical strength is based on that State according to FIG. 2b additionally apply a further protective lacquer, which may then only be removed Fills areas 11.
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Optics & Photonics (AREA)
- Toxicology (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Duplication Or Marking (AREA)
- Decoration By Transfer Pictures (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Laser Beam Processing (AREA)
- Laminated Bodies (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zur Dekoration oder Beschriftung einer Oberfläche mittels Laserstrahlung, wobei auf die Oberfläche wenigstens zwei unterschiedlich gefärbte Farblackschichten übereinander aufgebracht und anschliessend wenigstens die zum Betrachter weisende erste Farbiackschicht mittels der Laserstrahlung bereichsweise zur Erzeugung der Dekoration oder Beschriftung entfernt und so die unterschiedlich gefärbte zweite Farblackschicht freigelegt aber nicht vollständig abgetragen oder entfernt wird, wobei wenigstens die erste Farblackschicht in einem Transferverfahren auf die Oberfläche aufgebracht wird.The invention relates to a method for decorating or inscribing a surface by means of laser radiation, wherein at least two differently colored layers of colored lacquer are applied one above the other and then at least the first color coating layer facing the viewer by means of the laser radiation removed to create the decoration or lettering and so the differently colored second color lacquer layer uncovered but not completely removed or removed, with at least the first colored lacquer layer is applied to the surface in a transfer process.
Das Verfahren der eingangs erwähnten Art wird insbesondere dann verwendet, wenn es darum geht, eine genaue Beschriftung bzw. Dekoration bei Gegenständen vorzusehen, die Einzelstücke sind oder nur in geringer Stückzahl angefertigt werden. Der zum Ausbrennen der ersten Farblackschicht dienende Laserstrahl kann hinsichtlich seiner Bewegungsbahn beispielsweise mittels eines Elektronenrechners ohne Schwierigkeiten sehr genau gesteuert werden, wobei auch die Möglichkeit besteht, die Stärke des durch das Ausbrennen erzeugten Laserstriches zu verändern. Für dieses Verfahren geeignete Geräte sind handelsüblich und werden beispielsweise von der Fa. Baasel Lasertech angeboten.The method of the type mentioned is used in particular when it comes to an accurate Inscription or decoration for objects that are individual pieces or only in small quantities be made. The laser beam used to burn out the first colored lacquer layer can, with regard to its Motion path can be controlled very precisely, for example by means of an electron computer, it is also possible to change the strength of the laser line produced by the burnout. For Devices suitable for this process are commercially available and are offered, for example, by Baasel Lasertech.
Aus der EP-A O 383 956 ist auch schon ein Verfahren zur Erzeugung von Sicherheitsmarkierungen auf einer Oberfläche bekannt, bei welchem eine von einer Laserstrahlung absorbierenden oberen Schicht abgedeckte Farbschicht durch bereichsweises Abtragen der oberen Schicht mittels eines Laserstrahls entsprechend freigelegt wird. Über die Aufbringung der äußeren Schicht enthält die Druckschrift jedoch keine Angaben.EP-A-0 383 956 also describes a method for producing security markings on a surface known in which an upper layer covered by a laser radiation absorbing layer of color is correspondingly exposed by removing the upper layer by means of a laser beam. About the Application of the outer layer, however, does not contain any information in the publication.
Bisher geht man so vor, dass die zu dekorierende Oberfläche, beispielsweise die Frontplatte eines Gerätes, mittels üblicher Verfahren mit zwei unterschiedlich farbigen Lackschichten versehen wird. Durch den Laserstrahl wird dann die obere Lackschicht entfernt und entsprechend der gewünschten Dekoration bzw. Musterung oder Beschriftung die untere, zu der oberen Lackschicht farblich kontrastierende Lackschicht freigelegt. Hierbei besteht jedoch das Problem, dass bei den konventionellen Lackschichten sich Dickenvariationen der Lackschicht ergeben, mit der Folge, dass beim Abbrennen der oberen Lackschicht mittels des Lassrstrahls unter Umständen diese obere Lackschicht in den Bereichen, in denen sie relativ dick ist, nicht vollständig abgetragen wird. Verwendet man eine höhere Laser-Leistung, kann man zwar erreichen, dass die obere Lackschicht zuverlässig auch dort, wo sie dicker ist abgetragen wird. Es besteht dann jedoch die Gefahr, dass in Bereichen, in denen die obere Lackschicht dünner ist, die untere Lackschicht mit angegriffen wird, was so weit gehen kann, dass auch die untere Lackschicht völlig entfernt oder zumindest stark beschädigt wird. Eine weitere Gefahr ist die, dass der mittels des Laserstrahls erzeugte Strich dann, wenn die Lackschichten unterschiedlich dick sind, trotz gleichbleibender Laserleistung verschiedene Breiten bzw. Stärken aufweist wodurch natürlich auch das Aussehen des entsprechend dekorierten bzw. beschrifteten Gegenstandes beeinträchtigt wird. Um eine brauchbare Laser-Beschriftung zu erzeugen, musste man somit bisher mit ganz erheblichem Aufwand versuchen, die obere, durch den Laserstrahl abzutragende, Lackschicht in möglichst gleichmässiger Dicke aufzutragen, wodurch sich die Herstellung entsprechender Gegenstände ganz erheblich verteuert hat, so dass Laser-Beschriftung bzw. Dekoration bisher nur für einige wenige Einsatzgebiete, insbesondere bei hochwertigen oder sehr teueren Geräten Verwendung fand.So far, one has proceeded so that the surface to be decorated, for example the front panel of a device, by means of usual process is provided with two differently colored layers of paint. The laser beam then turns the Removed the upper layer of lacquer and the according to the desired decoration or pattern or lettering lower layer of paint, which contrasts with the upper layer of paint, is exposed. However, the problem here is that with conventional lacquer layers there are variations in the thickness of the lacquer layer, with the result that with Burning off the upper layer of lacquer by means of the laser jet under certain circumstances this upper layer of lacquer in the areas in which it is relatively thick, is not completely removed. If you use a higher laser power, you can you can ensure that the upper layer of paint is reliably removed even where it is thicker. It exists then, however, there is the danger that in areas in which the upper lacquer layer is thinner, the lower lacquer layer is also attacked is what can go so far that the lower layer of paint is completely removed or at least severely damaged becomes. Another danger is that the line created by means of the laser beam is then when the lacquer layers differ are thick, in spite of constant laser power of different widths or thicknesses, which makes them natural the appearance of the appropriately decorated or labeled object is impaired. To one So far, one had to try to produce usable laser lettering with considerable effort to apply the top layer of lacquer to be removed by the laser beam in a thickness that is as uniform as possible the production of corresponding items has become very expensive, so that laser labeling or decoration So far only for a few areas of application, especially for high-quality or very expensive devices found.
In der US - A - 4515867 ist ein Verfahren beschrieben, das es gestattet, auf zueinander gehörigen Teilen von TV-Bildröhren mittels Laserstrahlung einen Barcode anzubringen. Dabei wird auf die Oberfläche der aus Glas bestehenden Teile eine untere Beschichtung aufgebracht, die von einer wässrigen Suspension erster Pigment-Partikel und eines ersten Alkali-Silikat-Binders gebildet ist. Nach dem Trocknen wird auf die untere Beschichtung eine Deckschicht aufgebracht, die ebenfalls von einer wässrigen Suspension von Pigment-Partikeln und einem Alkali-Silikat-Binder gebildet ist. Um eine Zerstörung der unteren Beschichtung durch Laserstrahlung zu verhindern, enthält diese einen bestimmten Anteil an Glimmer-Partikeln. Nach Trocknung der unteren Beschichtung und der Deckschicht bei Temperaturen unter 100 °C wird letztere durch Laserstrahlung zu Erzeugung des Barcodes bereichsweise mittels Laserstrahlung abgetragen. Anschließend wird der Glasgegenstand mit dem erzeugten Barcode stark erhitzt, um auf diese Weise die Beschichtungen innig mit der Glasoberfläche zu verbinden.A method is described in US Pat. No. 4,515,867 which allows one to belong together Attach a barcode to parts of TV picture tubes using laser radiation. Thereby, the surface of the parts made of glass applied a lower coating, the first of an aqueous suspension Pigment particles and a first alkali silicate binder is formed. After drying, apply to the bottom coating applied a top layer, also from an aqueous suspension of pigment particles and an alkali silicate binder is formed. To destroy the lower coating by laser radiation To prevent this, it contains a certain proportion of mica particles. After drying the bottom coating and the top layer at temperatures below 100 ° C, the latter is generated by laser radiation of the barcode removed in sections by means of laser radiation. Then the glass object with the generated barcode heated strongly, in this way to connect the coatings intimately with the glass surface.
In der JP-A-1(1989)-283.703 ist ein Verfahren zur Herstellung einer farbigen Linse beschrieben, bei dem eine die Linse bedeckende, aus mehreren Farb- bzw. Lackschichten bestehende, lichtundurchlässige Membran mittels eines Laserstrahles mit einer Vielzahl von Schlitzen versehen wird, wobei die Schlitze Licht, mit dem die Linse von der anderen Seite beleuchtet wird, durchlassen sollen. Die aus mehreren Schichten bestehende Membran kann beispielsweise in einem Heissprägeverfahren aufgebracht werden. Der zur Erzeugung der Schlitze dienende Laserstrahl durchschneidet bei dem bekannten Verfahren auf jeden Fall sämtliche Schichten der Membran, damit die eigentliche Linse freigelegt wird. Auf die Möglichkeit, nur eine oder mehrere der Schichten der Membran abzutragen, ist nicht hingewiesen.JP-A-1 (1989) -283.703 describes a method for producing a colored lens, in which one of the Opaque membrane covering the lens, consisting of several layers of paint or lacquer, by means of a Laser beam is provided with a variety of slits, the slits light with which the lens from the other Side is lit, should let through. The membrane consisting of several layers can, for example be applied in a hot stamping process. The laser beam used to create the slits cuts through in the known method in any case all layers of the membrane so that the actual lens is exposed becomes. The possibility of removing only one or more of the layers of the membrane is not indicated.
Ziel der Erfindung ist es nun, ein Verfahren vorzuschlagen, welches es gestattet, bei vergleichsweise geringem Aufwand eine einwandfreie Dekoration bzw. Beschriftung einer Oberfläche mittels Laserstrahl-Gravur zu bewerkstelligen.The aim of the invention is now to propose a method which allows it with comparatively little effort to achieve a perfect decoration or labeling of a surface using laser beam engraving.
Zu diesem Zweck wird nach der Erfindung bei dem Verfahren der eingangs erwähnten Art nun vorgeschlagen derart vorzugehen, dass mindestens die erste Farblackschicht mittels einer die erste Farblackschicht auf einem Trägerfilm umfassenden Prägefolie, vorzugsweise Heißprägefolie, von dem Trägerfilm auf die Oberfläche übertragen wird. For this purpose it is now proposed according to the invention in the method of the type mentioned at the outset to proceed that at least the first color lacquer layer by means of the first color lacquer layer on a Embossing film comprising carrier film, preferably hot stamping film, from the carrier film to the surface is transmitted.
Es ist bekannt, dass sich auf einem Träger, beispielsweise einer Kunststoffolie oder einem Metallband, Farblackschichten ohne grossen Aufwand in sehr gleichmässiger Dicke auftragen bzw. erzeugen lassen. Überträgt man diese Farblackschicht dann auf die zu dekorierende Oberfläche, ist gewährleistet, dass auch die zu dekorierende Oberfläche eine Farblackschicht mit weitgehend gleichbleibender Dicke aufweist. Die Leistung des zum Abtragen dieser Farblackschicht dienenden Lasers kann dann ohne Probleme einmal entsprechend der Dicke der Farblackschicht eingestellt werden. Wird der Laserstrahl dann über die zu dekorierende Oberfläche bewegt, wird tatsächlich nur die obere bzw. erste Farblackschicht entfernt, wobei durch Veränderung der Laserleistung die Schriftstärke bzw. Gravurtiefe variiert werden kann. irgendwelche Abweichungen von dem gewünschten Bild der Dekoration bzw. Beschriftung infolge von Dickenänderungen der ersten Farblackschicht sind bei einem Vorgehen gemäss der Erfindung nicht zu befürchten. Die Übertragung der Farblackschicht auf die Oberfläche kann mittels der bekannten Transferverfahren ohne übermässigen Aufwand durchgeführt werden. Erfindungsgemäss wird also ein Verfahren vorgeschlagen, welches es gestattet, die Qualität der Dekoration einer Oberfläche mittels Laser-Abtrags erheblich zu verbessern, ohne dass hierzu ein übermässiger konstruktiver oder apparativer Aufwand erforderlich wäre.It is known that layers of colored lacquer lie on a carrier, for example a plastic film or a metal strip can be applied or produced in a very uniform thickness without great effort. You transfer this Color coat then on the surface to be decorated, it is guaranteed that the surface to be decorated has a color lacquer layer with largely constant thickness. The performance of removing this layer of colored lacquer serving laser can then be easily adjusted according to the thickness of the colored lacquer layer become. If the laser beam is then moved over the surface to be decorated, only the upper or removed the first layer of colored lacquer, the lettering or engraving depth varying as a result of changing the laser power can be. any deviations from the desired image of the decoration or lettering as a result of Changes in the thickness of the first colored lacquer layer are not to be feared in a procedure according to the invention. The Transfer of the colored lacquer layer to the surface can be carried out by means of the known transfer processes without excessive Effort. According to the invention, a method is therefore proposed which allows the To significantly improve the quality of the decoration of a surface by means of laser ablation, without this being an excessive one constructive or equipment expenditure would be required.
Ein weiterer Vorzug des Vorgehens gemäss der Erfindung ist darin zu sehen, dass es bekanntlich ohne Schwierigkeiten möglich ist, z.B. mittels eines Druckverfahrens, auf einem flexiblen Träger, z.B. einer Kunststoffolie oder einem Metallband, Lackschichten nur bereichsweise aufzubringen, wobei natürlich auch die Möglichkeit besteht, in unterschiedlichen Bereich unterschiedlich gefärbte Lacke aufzutragen. Verwendet man eine solche, aus unterschiedlich gefärbten Bereichen bestehende Farblackschicht zur Dekoration der Oberfläche eines Gegenstandes, bieten sich weitere, bisher mit vertretbarem Aufwand nicht erreichbare Gestaltungsmöglichkeiten. Man kann beispielsweise die zu dekorierende Oberfläche in unterschiedlich farbige Bereiche aufteilen und diese dann jeweils mittels eines Laserstrahls beschriften. Hierdurch ist es z.B. möglich, bestimmte Schriften auf der Frontplatte eines Gerätes in einer anderen Farbe auszuführen als die restliche Beschriftung, um diese Beschriftung hervorzuheben oder bestimmten Bedienungsvorgängen zuzuordnen. Wollte man dies bisher tun, musste man die zu dekorierende Oberfläche entsprechend abdecken und dann die einzelnen Bereiche in unterschiedlichen Arbeitgsgängen beispielsweise mit Lacken der gewünschten Farbe spritzen. Es leuchtet ein, dass es bei einer derartigen Vorgehensweise nahezu ausgeschlossen ist, auch nur annähernd gleiche Dicke für die verschieden gefärbten Lackbereiche zu erzielen, nachdem ja die Dicke der Lackschicht sowohl von der Viskosität des aufgespritzten Lackes als auch von dessen Pigmentierung sowie den Verlaufseigenschaften abhängt.Another advantage of the procedure according to the invention is that it is known to be without difficulty is possible, e.g. by means of a printing process, on a flexible support, e.g. a plastic film or one Metal tape, layers of paint only to be applied in certain areas, although of course there is also the possibility of different Area of differently colored paints. If one uses one from different colored areas for the decoration of the surface of an object, there are further Design options previously unattainable with reasonable effort. You can, for example, the Divide the decorating surface into different colored areas and then each with a laser beam label. This makes it e.g. possible, certain fonts on the front panel of a device in a different color Execute as the rest of the label to highlight this label or certain operations assigned. If you wanted to do this up to now, you had to cover the surface to be decorated accordingly then the individual areas in different work steps, for example with paints of the desired color squirt. It is obvious that with such a procedure it is almost impossible, even approximately to achieve the same thickness for the differently colored lacquer areas, after all the thickness of the lacquer layer both of the viscosity of the sprayed-on lacquer and of its pigmentation and flow properties depends.
Besonders zweckmässig ist es, wenn nicht nur die erste sondern sowohl die erste als auch die zweite Farblackschicht in einem Prägeverfahren vom Trägerfilm einer Prägefolie, insbes. Heißprägefolie, auf die Oberfläche übertragen werden, weil sich dann noch grössere Genauigkeiten erreichen lassen. Dieses Verfahren ist vorallem auch dann zweckmässig, wenn die zweite, untere Farblackschicht aus unterschiedlich gefärbten Bereichen besteht, wodurch zum Beispiel die Möglichkeit gegeben ist, auf der Frontplatte eines Gerätes unterschiedlich farbige Beschriftungen anzubringen, wodurch unter Umständen die Bedienung erheblich erleichtert werden kann.It is particularly expedient if not only the first but also the first and the second colored lacquer layer in an embossing process from the carrier film of an embossing film, in particular hot stamping film, to the surface be transferred because of itself then let even greater accuracy be achieved. This procedure is especially useful if the second, lower colored lacquer layer consists of differently colored areas, which for example gives the possibility is given to attach differently colored labels on the front panel of a device, which means under Operation can be made considerably easier under certain circumstances.
Um die mechanische Beständigkeit der dekorierten Oberfläche zu verbessern, kann man vorteilhafterweise so vorgehen, dass auf die erste Farblackschicht vor oder nach der Laserbearbeitung eine transparente Schutzlackschicht aufgebracht wird, die eine entsprechend hohe mechanische Festigkeit aufweist.In order to improve the mechanical resistance of the decorated surface, one can advantageously proceed as follows: that a transparent protective lacquer layer on the first color lacquer layer before or after laser processing is applied, which has a correspondingly high mechanical strength.
In der Praxis wird man zweckmässig so vorgehen, dass sämtliche Lackschichten mittels einer Prägefolie, insbesondere Heißprägefolie, aufgebracht werden, die einen Trägerfilm und auf diesem ablösbar die Lackschichten aufweist. Derartige Heissprägefolien lassen sich ohne weiteres in den von der Fertigung von Heissprägefolien her bekannten Verfahren herstellen.In practice, it is advisable to proceed in such a way that all layers of paint are embossed using in particular hot stamping foil, which are applied to a carrier film and removable thereon Has layers of paint. such Hot stamping foils can be readily used in those known from the manufacture of hot stamping foils Establish process.
Prägefolien, insbesondere Heissprägefolien zur Verwendung in dem erfindungsgemässen Verfahren weisen übereinander wenigstens eine erste und eine zweite unterschiedlich farbige Farblackschicht auf, wobei die erste Farblackschicht näher beim Trägerfilm angeordnet ist als die zweite. Die beiden Farblackschichten werden gemäss dem gewünschten Dekorationseffekt gefärbt, wobei zum Beispiel die erste, am dekorierten Gegenstand obere Farblackschicht schwarz sein kann, während die zweite, durch den Laserstrahl freizulegende Farblackschicht beispielsweise weiss ist Die Eigenschaften der Farblackschichten lassen sich weiterhin so einstellen, dass die erste Farblackschicht relativ leicht durch den Laserstrahl abgetragen werden kann, jedoch ansonsten vergleichsweise gute mechanische Festigkeit besitzt, während die zweite Farblackschicht, beispielsweise infolge ihrer Farbgebung oder durch Zusätze, von dem Laserstrahl möglichst wenig angegriffen wird. Als Trägerfilm wird bei solchen Prägefolien zweckmässig ein Polyesterfilm einer Dicke von 6 bis 100 µm, vorzugsweise von 19 bis 38 µm eingesetzt. Diese Filme besitzen hinreichende Festigkeit, aber auch Flexibilität, um sie als Träger bei Übertragung der Dekorschicht von dem Trägerfilm auf unterschiedlich geformte Oberflächen verwenden zu können. Zum Übertragen der Dekor- bzw. Farblackschichten von dem Träger auf die zu dekorierende Oberfläche können die an sich bekannten Verfahren verwendet werden, beispielsweise Hubverfahren, Abrollverfahren, oder auch Verfahren, bei denen die entsprechende Folie in eine Spritzgiessform eingelegt und dann mit Kunststoff zur Bildung eines Gegenstandes, beispielsweise der Frontplatte eines Gerätes, hinterspritzt wird. Als Schutzlackschicht kann eine Klarlackschicht, vorzugsweise einer Dicke von 1 bis 2 µm, vorgesehensein die, wenn sie bereits von Haus aus auf der Prägefolie vorhanden ist bei der Laser-Gravur ebenfalls abgetragen werden muss. Vorteilhaft ist, wenn die zweite Farblackschicht der Prägefolie dicker ist als die erste Farblackschicht, wobei die Dicke der zweiten Farblackschicht vorzugsweise ca. 2 bis 10 µm, die Dicke der ersten Farblackschicht vorzugsweise etwa 1 bis 5 µm beträgt. Die Verwendung einer vergleichsweise dünnen ersten Farblackschicht und einer demgegenüber dickeren zweiten Farblackschicht gibt die Möglichkeit, die Leistung des zum Abtragen der ersten Farblackschicht dienenden Laserstrahls so hoch einstellen zu können, dass zuverlässig die erste Farblackschicht in dem gewünschten Bereich vollständig abgetragen, gegebenenfalls sogar ein kleiner Teil der zweiten Farblackschicht mit weggenommen wird, trotzdem jedoch gewährleistet ist, dass noch ein hinreichend dicker Rest der zweiten Farblackschicht verbleibt, um einerseits ein einwandfreies Dekorationsbild zu ergeben, andererseits aber ein zuverlässiger Schutz der Oberfläche des dekorierten Gegenstandes durch die zweite Farblackschicht gewährleistet bleibt.Stamping foils, in particular hot stamping foils for use in the method according to the invention point one above the other at least a first and a second differently colored colored lacquer layer, the first colored lacquer layer is closer to the carrier film than the second. The two layers of colored lacquer are applied according to the the desired decorative effect, for example the first colored lacquer layer on the decorated object can be black, while the second color lacquer layer to be exposed by the laser beam, for example is white The properties of the colored lacquer layers can still be adjusted so that the first colored lacquer layer can be removed relatively easily by the laser beam, but otherwise comparatively good mechanical Has strength, while the second color lacquer layer, for example due to its coloring or by additions of the laser beam is attacked as little as possible. In such stamping foils, a polyester film is expediently used as the carrier film a thickness of 6 to 100 microns, preferably from 19 to 38 microns used. These films have sufficient Strength, but also flexibility to differentiate them as carriers when transferring the decorative layer from the carrier film to be able to use shaped surfaces. To transfer the decorative or colored lacquer layers from the Carriers on the surface to be decorated can use the methods known per se, for example Lifting process, rolling process, or also process in which the corresponding film is placed in an injection mold and then back injected with plastic to form an object, such as the front panel of a device becomes. A clear lacquer layer, preferably a thickness of 1 to 2 µm, can be provided as the protective lacquer layer which, if already present on the embossing foil, are also removed during laser engraving got to. It is advantageous if the second colored lacquer layer of the embossing film is thicker than the first colored lacquer layer, the The thickness of the second colored lacquer layer is preferably approximately 2 to 10 μm, and the thickness of the first colored lacquer layer is preferred is about 1 to 5 µm. The use of a comparatively thin first colored lacquer layer and one in contrast thicker second color coat gives the ability to remove the first color coat to be able to set the serving laser beam so high that the first layer of colored paint in the desired one is reliable Area completely removed, possibly even a small part of the second color lacquer layer removed is ensured, however, that a sufficiently thick remnant of the second color lacquer layer remains, on the one hand to give a perfect decoration picture, on the other hand a reliable protection of the surface the decorated object is guaranteed by the second layer of colored lacquer.
Bei dem erfindungsgemässen Verfahren wird eine Prägefolie, insbesondere Heissprägefolie, umfassend einen vorzugsweise aus Polyester bestehenden Trägerfilm, auf dem aufeinanderfolgend eine Trennschicht, gegebenenfalls eine Schutzlackschicht, wenigstens zwei unterschiedlich farbige Farblackschichten sowie eine Kleberschicht angeordnet sind, zur Erzeugung der wenigstens zwei unterschiedlich gefärbten Farblackschichten auf einer Oberfläche verwendet.In the method according to the invention, an embossing foil, in particular hot stamping foil, comprising a carrier film, preferably made of polyester, on which a separating layer is successively arranged, optionally a protective lacquer layer, at least two differently colored color lacquer layers and an adhesive layer are arranged to produce the at least two differently colored color lacquer layers on one Surface used.
Weitere Einzelheiten und Vorteile der Erfindung ergeben sich aus der folgenden Beschreibung eines Ausführungsbeispiels einer Heissprägefolie zur Verwendung gemäss der Erfindung sowie der schematischen Erläuterung des erfindungsgemässen Verfahrens an Hand der Zeichnung. Es zeigen:
- Fig. 1
- einen Teilschnitt durch eine Heissprägefolie,
- Fig. 2a
- im Teilschnitt ein mit einer entsprechenden Heissprägefolie oberflächlich versehenes Substrat und
- Fig. 2b
- einen Schnitt entsprechend Fig. 2a nach Durchführung der Laserbehandlung.
- Fig. 1
- a partial section through a hot stamping foil,
- Fig. 2a
- in partial section a substrate provided with a corresponding hot stamping foil and
- Fig. 2b
- a section corresponding to Fig. 2a after performing the laser treatment.
Die in Fig. 1 schematisch gezeigte Heissprägefolie umfasst einen Trägerfilm 1, wobei es sich hier vorzugsweise um einen Polyesterfilm einer Dicke von 6 bis 100 µm, bevorzugt einer Dicke von 19 bis 38 µm handelt.The hot stamping foil shown schematically in FIG. 1 comprises a carrier film 1, which is preferably here a polyester film with a thickness of 6 to 100 microns, preferably a thickness of 19 to 38 microns.
Auf diesem Trägerfilm 1 sind nacheinander folgende Schichten vorhanden, die in dem an sich von der Herstellung von Heissprägefolien bekannten üblichen Verfahren aufgebracht sind:The following layers are present in succession on this carrier film 1, which in the production process itself conventional methods known from hot stamping foils are applied:
Hierbei handelt es sich im allgemeinen um eine bei Wärmeeinwirkung weich werdende Schicht, die die Ablösung der weiteren Schichten von dem Trägerfilm 1 gestattet. Die Trennschicht 2 hat im allgemeinen eine Dicke von höchstens 1 µm.This is generally a layer softening when exposed to heat, which is the detachment the further layers of the carrier film 1 are permitted. The separating layer 2 generally has a maximum thickness 1 µm.
Es handelt sich dabei um eine transparente Lackschicht mit der Aufgabe, die freie Oberfläche des mit der Heissprägefolie dekorierten Gegenstandes gegen mechanische Beschädigungen weitgehend zu schützen. Die Schutzlackschicht 3 muss deswegen gegen mechanische Einwirkungen entsprechend widerstandsfähig sein. Sie hat im vorliegenden Fall beispielsweise eine Dicke von 1 bis 2 µm.It is a transparent lacquer layer with the task of covering the free surface with the hot stamping foil to largely protect decorated object against mechanical damage. The protective lacquer layer 3 must therefore be adequately resistant to mechanical influences. She has in present case, for example, a thickness of 1 to 2 microns.
Hierbei handelt es sich beispielsweise um eine mittels Russ entsprechend gefärbte Lackschicht einer Dicke von etwa 1 bis 5 µm, die mit Hilfe eines Laserstrahls abgetragen werden kann.This is, for example, a layer of lacquer correspondingly colored with carbon black about 1 to 5 µm, which can be removed with the help of a laser beam.
Diese Schicht ist anders gefärbt als die erste Farblackschicht 4, beispielsweise, wenn die erste Farblackschicht 4 schwarz ist, weiss oder elfenbeinfarbig.This layer is colored differently than the first colored lacquer layer 4, for example when the first colored lacquer layer 4 is black, white or ivory.
Es besteht aber auch die Möglichkeit, die zweite Farblackschicht 5 -ebenso wie die erste Farblackschicht 4-nicht
über die gesamte Fläche der Heissprägefolie und damit nicht über die gesamte zu dekorierende Oberfläche in der gleichen
Farbstellung vorzusehen. Die Farblackschichten 4 und 5 können vielmehr einzeln -und damit auch unterschiedlich-
aus verschiedenfarbigen Bereichen zusammengesetzt sein.However, there is also the possibility of not using the second colored lacquer layer 5 - just like the first colored lacquer layer 4
over the entire surface of the hot stamping foil and therefore not over the entire surface to be decorated in the same
Color scheme to be provided. Rather, the
Hierbei handelt es sich um eine bei Heissprägefolien an sich übliche und bekannte Kleberschicht einer Dicke von
etwa 1 bis 10 µm, wobei die Kleberschicht für eine Heissprägefolie so zusammengesetzt ist, dass sie erst bei entsprechender
Wärmeeinwirkung klebrig wird. Für Prägefolien, die ohne Wärmeeinwirkung verarbeitet werden sollen, kann
die Kleberschicht auch beispielsweise ein durch Druck aktivierbarer Kleber oder eine Schicht eines ständig klebrigen
Materials sein. Im letzteren Falle müsste allerdings dann der Trägerfilm 1 auf der den Lackschichten 3, 4, 5 abgekehrten
Seite mit einer ein Anhaften der Kleberschicht 6 am Trägerfilm 1 verhindernden Beschichtung, beispielsweise Silikon,
versehen sein, um die Prägefolie entsprechend aufwickeln zu können.This is an adhesive layer which is customary and known per se in hot stamping foils and has a thickness of
about 1 to 10 µm, whereby the adhesive layer for a hot stamping foil is composed in such a way that it only takes
Heat becomes sticky. For stamping foils that are to be processed without exposure to heat
the adhesive layer also, for example, an adhesive that can be activated by pressure or a layer of a permanently sticky one
Material. In the latter case, however, the carrier film 1 would then have to face away from the lacquer layers 3, 4, 5
Side with a coating, for example silicone, which prevents the
Die Trennschicht 2, die Lackschichten 3 bis 5 sowie die Kleberschicht 6 können nach folgenden Rezepturen hergestellt
sein:
In Fig. 2a ist im Teilschnitt ein Substrat 7, beispielsweise die Frontplatte eines Gerätes, gezeigt, an dessen Oberfläche
8 die eine Ablöseschicht 9 bildenden Lackschichten 3 bis 5 sowie Kleberschicht 6 der Heissprägefolie gemäss
Fig. 1 in einem üblichen Heissprägevorgang angebracht sind.In Fig. 2a, a
Ausgehend von der im wesentlichen einheitlich dekorierten Oberfläche gemäss Fig. 2a wird dann mittels eines entsprechenden
Laserstrahls zur Erzielung der gewünschten Dekoration bzw. Beschriftung sowohl die Schutzlackschicht
3 als auch die erste, beim Ausführungsbeispiel angenommen schwarze Farblackschicht 4 abgetragen, und zwar derart,
dass am Grund 10 der durch Abtragung der Schichten 3, 4 entstandenen vertieften Bereiche 11, beispielsweise in
Form von Strichen, Buchstaben, Flächen etc., die zur ersten Farblackschicht 4 farblich unterschiedliche zweite
Farblackschicht 5 zum Vorschein kommt. Dabei ist allerdings in Fig. 2b der Idealzustand gezeigt, der darin besteht,
dass die Abtragung der Lackschichten mittels des Laserstrahls genau bis zum Beginn der zweiten Farblackschicht 5
geht. Tatsächlich wird man im allgemeinen so vorgehen, dass noch eine geringe Menge der Farblackschicht 5 mit abgetragen
wird, um sicherzustellen, dass die freigelegten Bereiche der zweiten Farblackschicht 5 ein einheitliches Aussehen
besitzen. Sofern die Farblackschicht 5 über die Oberfläche des zu dekorierenden Gegenstandes aus Bereichen
unterschiedlicher Farbe zusammengesetzt ist, werden natürlich die freigelegten Teile 10 der zweiten Farblackschicht 5
entsprechend unterschiedliche Farbe besitzen.Starting from the essentially uniformly decorated surface according to FIG. 2a, a corresponding is then used
Laser beam to achieve the desired decoration or lettering both the protective lacquer layer
3 as well as the first, in the exemplary embodiment assumed, black colored lacquer layer 4, namely in such a way
that at the bottom 10 of the recessed areas 11 formed by removing the layers 3, 4, for example in
Form of lines, letters, areas etc., the second one with different colors to the first colored lacquer layer 4
Im Ausführungsbeispiel wurde davon ausgegangen, dass die Schutzlackschicht 3 bereits auf der Heissprägefolie
vorhanden ist, was zur Folge hat, dass die Oberfläche 10 der zweiten Farblackschicht 5 bei fertig dekoriertem Produkt
freiliegt. Für bestimmte Anwendungsfälle kann es gewünscht sein, dass auch diese Fläche geschützt ist. In diesem Fall
besteht entweder die Möglichkeit, eine Heissprägefolie zu verwenden, die keine Schutzlackschicht 3 aufweist und dann
insgesamt nach der Laser-Gravur eine Schutzlackschicht anzubringen, die dann auch die vertieften Bereiche 11 ausfüllt.
Eine andere Möglichkeit, die eine bessere mechanische Festigkeit ergibt, besteht darin, ausgehend von dem
Zustand gemäss Fig. 2b zusätzlich einen weiteren Schutzlack aufzubringen, der dann eventuell nur die abgetragenen
Bereiche 11 ausfüllt.In the exemplary embodiment, it was assumed that the protective lacquer layer 3 was already on the hot stamping foil
is present, which has the consequence that the
Claims (5)
- Method of decorating or inscribing a surface (8) by means of laser radiation, in which at least two different-coloured colour laminae (4, 5) are applied over one another to the surface (8) and then at least the first colour lamina (4), facing the observer, is locally removed by means of the laser radiation in order to produce the decoration or inscription, and in this way the different-coloured, second colour lamina (5) is exposed, but not completely eroded or removed, in which at least the first colour lamina (4) is applied to the surface (8) in a transfer process, characterized in that at least the first colour lamina (4) is transferred from the carrier film (1) to the surface (8) by means of a stamping foil, preferably hot-stamping foil, comprising the first colour lamina (4) on a carrier film (1).
- Method according to Claim 1, characterized in that the first and the second colour laminae (4, 5) are transferred from the carrier film (1) of a stamping foil, especially of a hot-stamping foil, to the surface (8) in a stamping process.
- Method according to Claim 1 or 2, characterized in that a transparent protective lamina (3) is applied to the first colour lamina (4) prior to or after the laser treatment.
- Method according to one of the preceding claims, characterized in that all the laminae (3, 4, 5) are applied by means of a stamping foil comprising a carrier film (1) and, detachably thereon, the laminae (3, 4, 5).
- Method according to one of the preceding claims, characterized in that to produce the at least two different-coloured, mutually superposed colour laminae (4, 5) on a surface (8), use is made of a stamping foil, especially hot-stamping foil, comprising a carrier film (1) which preferably consists of polyester and on which, in succession, a release layer (2), optionally a protective lamina (3), at least two different-coloured colour laminae (4, 5) and an adhesive layer (6) are disposed.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4134271 | 1991-10-17 | ||
DE4134271A DE4134271C1 (en) | 1991-10-17 | 1991-10-17 |
Publications (4)
Publication Number | Publication Date |
---|---|
EP0537668A2 EP0537668A2 (en) | 1993-04-21 |
EP0537668A3 EP0537668A3 (en) | 1995-01-18 |
EP0537668B1 EP0537668B1 (en) | 1997-06-18 |
EP0537668B2 true EP0537668B2 (en) | 2004-01-02 |
Family
ID=6442817
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92117433A Expired - Lifetime EP0537668B2 (en) | 1991-10-17 | 1992-10-13 | Process for decorating or marking a surface by means of laser radiation and use of a stamping foil in this process |
Country Status (8)
Country | Link |
---|---|
US (1) | US5985078A (en) |
EP (1) | EP0537668B2 (en) |
JP (1) | JP2858513B2 (en) |
AT (1) | ATE154550T1 (en) |
DE (2) | DE4134271C1 (en) |
DK (1) | DK0537668T3 (en) |
ES (1) | ES2104788T5 (en) |
HK (1) | HK1006297A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022082044A1 (en) * | 2020-10-16 | 2022-04-21 | Avery Dennison Retail Information Services Llc | Engravable heat transfer labels and embellishments |
Families Citing this family (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4419197A1 (en) * | 1993-06-11 | 1994-12-15 | Volkswagen Ag | Process for the production of a paint finish with a coloured decoration |
DE4421865A1 (en) * | 1994-06-22 | 1996-01-04 | Beiersdorf Ag | Single-layer laser label |
DE4422548C2 (en) * | 1994-06-28 | 1997-08-07 | Uniroyal Englebert Gmbh | Applying a mark to a visible surface of a tire |
DE4439097C2 (en) * | 1994-11-02 | 1997-05-15 | Orga Kartensysteme Gmbh | Chip and / or magnetic stripe card |
WO1996024495A1 (en) * | 1995-02-10 | 1996-08-15 | Klaus Kall | Method of coating a transparent carrier plate and coated carrier plate produced according to this method |
DE19509505C1 (en) * | 1995-03-16 | 1996-01-25 | Beiersdorf Ag | Multilayer laser codable label |
DE19512157C1 (en) | 1995-03-31 | 1996-05-23 | Klaus Kall | Coating of a transparent carrier plate |
DE19540563C2 (en) * | 1995-10-31 | 1999-05-12 | Ebers & Mueller Fibrit | Interior trim part |
DE59602945D1 (en) * | 1996-01-24 | 1999-10-07 | Borsi Kg F | Process for coating a transparent carrier plate and then coated, transparent carrier plate, in particular for a display box |
DE19642040C1 (en) * | 1996-10-11 | 1998-01-15 | Schreiner Etiketten | Label with hologram, written by laser beam passing through clear, protective upper film |
US6075223A (en) * | 1997-09-08 | 2000-06-13 | Thermark, Llc | High contrast surface marking |
DE19813314A1 (en) * | 1998-03-26 | 1999-09-30 | Kurz Leonhard Fa | Stamping foil, especially hot stamping foil |
US6372293B1 (en) * | 1999-09-20 | 2002-04-16 | Matrix Technologies Corporation | Test tube with data matrix code markings |
TW567375B (en) | 2000-04-25 | 2003-12-21 | Koninkl Philips Electronics Nv | Method for providing a surface of an article with a decoration or text |
PT1330368E (en) | 2000-11-04 | 2004-11-30 | Kurz Leonhard Fa | A SYNTHETIC MATERIAL BODY CONFIGURATED AS A SHEET, FOR EXAMPLE, A TRANSFER SHEET OR LAMINATED SHEET, OR PROVIDED WITH ONE OF THESE SHEETS, AND A PROCESS FOR THE PRODUCTION OF A POLYCHROMATIC IMAGE ON ONE OR IN A SYNTHETIC DEMATERIAL BODY OF THAT GENE |
DE10139719A1 (en) | 2000-11-04 | 2002-05-08 | Kurz Leonhard Fa | Multi-layer body, in particular multi-layer film and method for increasing the security against forgery of a multi-layer body |
DE10116633A1 (en) * | 2001-04-04 | 2002-10-10 | Valeo Schalter & Sensoren Gmbh | Button or panel, in particular button or panel for a switch, and method of manufacture |
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DE10139653A1 (en) * | 2001-08-11 | 2003-02-20 | Tesa Ag | Label with increased protection against counterfeiting |
DE10141751A1 (en) * | 2001-08-29 | 2003-03-27 | Siemens Ag | Production method for display dial, especially for motor vehicle use, lacquers outer surface of base, produces markings by laser removal of lacquer surface |
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US7694887B2 (en) | 2001-12-24 | 2010-04-13 | L-1 Secure Credentialing, Inc. | Optically variable personalized indicia for identification documents |
CA2471457C (en) | 2001-12-24 | 2011-08-02 | Digimarc Id Systems, Llc | Covert variable information on id documents and methods of making same |
ATE555911T1 (en) | 2001-12-24 | 2012-05-15 | L 1 Secure Credentialing Inc | METHOD FOR FULL COLOR MARKING OF ID DOCUMENTS |
EP1467834A4 (en) | 2001-12-24 | 2005-04-06 | Digimarc Id Systems Llc | Laser etched security features for identification documents and methods of making same |
US7728048B2 (en) | 2002-12-20 | 2010-06-01 | L-1 Secure Credentialing, Inc. | Increasing thermal conductivity of host polymer used with laser engraving methods and compositions |
DE10213111A1 (en) | 2002-03-23 | 2003-10-02 | Tesa Ag | Multi-layer laser transfer film for permanent marking of components |
AU2003221894A1 (en) | 2002-04-09 | 2003-10-27 | Digimarc Id Systems, Llc | Image processing techniques for printing identification cards and documents |
US7824029B2 (en) | 2002-05-10 | 2010-11-02 | L-1 Secure Credentialing, Inc. | Identification card printer-assembler for over the counter card issuing |
DE10222477A1 (en) * | 2002-05-22 | 2004-01-22 | Eissmann Gmbh | Top plate for control switch in car is made from transparent material with coating on reverse side which has gaps forming symbol showing purpose of switch, second coating of different color then being applied to it |
DE10235018A1 (en) * | 2002-07-31 | 2004-02-12 | Merck Patent Gmbh | Laser-markable flexible carrier unit |
US6635846B1 (en) * | 2002-08-02 | 2003-10-21 | Albert S. Rieck | Selective laser compounding for vitrescent markings |
US7238396B2 (en) * | 2002-08-02 | 2007-07-03 | Rieck Albert S | Methods for vitrescent marking |
WO2004049242A2 (en) | 2002-11-26 | 2004-06-10 | Digimarc Id Systems | Systems and methods for managing and detecting fraud in image databases used with identification documents |
DE10327083A1 (en) * | 2003-02-11 | 2004-08-19 | Giesecke & Devrient Gmbh | Security paper, for the production of bank notes, passports and identity papers, comprises a flat substrate covered with a dirt-repellent protective layer comprising at least two lacquer layers |
EP1614064B1 (en) | 2003-04-16 | 2010-12-08 | L-1 Secure Credentialing, Inc. | Three dimensional data storage |
US20070080146A1 (en) * | 2003-11-10 | 2007-04-12 | Werner Stockum | Coloured laser marking |
WO2006031169A1 (en) * | 2004-09-14 | 2006-03-23 | Pergo (Europe) Ab | A decorative laminate board |
DE102005006074B4 (en) * | 2005-02-10 | 2009-12-10 | Leonhard Kurz Gmbh & Co. Kg | Decorated injection molded article and method of making the decorated injection molded article |
ES2369515T3 (en) * | 2005-02-23 | 2011-12-01 | Flooring Industries Ltd. | METHOD FOR THE MANUFACTURE OF SOIL PANELS, AS WELL AS SOIL PANEL OBTAINED BY MEANS OF SUCH METHOD. |
JP4535955B2 (en) * | 2005-07-13 | 2010-09-01 | 日本カーバイド工業株式会社 | Laminate for brittle laser printing |
DE102005046264B4 (en) * | 2005-09-27 | 2013-10-17 | Kronotec Ag | Method for producing a panel with a surface coating |
ITMI20070168A1 (en) * | 2007-02-01 | 2008-08-02 | Emanuele Acatti | PROCEDURE FOR THE PRODUCTION OF THERMO-ADHESIVE LABELS WITH LASER TECHNOLOGY AND LABELS SO OBTAINED |
DE102007029007A1 (en) * | 2007-06-23 | 2008-12-24 | Albea Kunststofftechnik Gmbh | Process for producing a labeled plastic molding and labeled plastic molding |
US7857474B2 (en) * | 2007-11-16 | 2010-12-28 | Continental Automotive Systems Us, Inc. | Laser etched graphic for a decorative surface |
DE102007055356A1 (en) * | 2007-11-19 | 2009-05-20 | Tesa Ag | Laser inscribable foil |
FR2927839B1 (en) * | 2008-02-22 | 2013-04-05 | Novatec | PROCESS FOR THE TRACEABILITY OF BOTTLES BY INALTERABLE MARKING AND AUTOMATICALLY READABLE. |
US9073383B2 (en) | 2008-06-06 | 2015-07-07 | Illinois Tool Works Inc. | Heat transfer label variable data indicator and method of making same |
CH699407A1 (en) * | 2008-08-25 | 2010-02-26 | Tecan Trading Ag | Sample tube with labeling. |
US8480511B2 (en) * | 2011-07-15 | 2013-07-09 | Taylor Made Golf Company, Inc. | Methods for marking golf club ferrule |
WO2014017995A2 (en) * | 2012-02-16 | 2014-01-30 | Cms Jant Ve Makine Sanayii A.S. | Laser gravure application on wheel |
DE102012003519A1 (en) * | 2012-02-24 | 2013-08-29 | Polysecure Gmbh | Workpiece with marking |
ITMI20131339A1 (en) * | 2013-08-05 | 2015-02-06 | Emmegierre S R L | HELMET OF PROTECTION AND METHOD FOR ITS PRODUCTION. |
DE102014202444A1 (en) * | 2014-02-11 | 2015-08-13 | BSH Hausgeräte GmbH | Front panel for a household appliance |
ES2551653B1 (en) * | 2014-05-20 | 2016-09-14 | Bsh Electrodomésticos España, S.A. | METHOD FOR PRODUCING A DOMESTIC APPLIANCE COMPONENT WITH A HOT STAMPED COATING, AND DOMESTIC APPLIANCE COMPONENT |
US9744559B2 (en) | 2014-05-27 | 2017-08-29 | Paul W Harrison | High contrast surface marking using nanoparticle materials |
DE202014105598U1 (en) | 2014-11-20 | 2015-01-15 | Alu Custom Design Gmbh | Foil for decorating and / or protecting the surfaces of objects |
KR102430212B1 (en) * | 2015-03-30 | 2022-08-05 | 다이니폰 인사츠 가부시키가이샤 | Decorative sheet |
CN104786688A (en) * | 2015-04-02 | 2015-07-22 | 贵州航天电子科技有限公司 | Method for carving characters on lacquered panel |
DE102016107180A1 (en) * | 2016-04-19 | 2017-10-19 | Lisa Dräxlmaier GmbH | Making a vehicle interior part |
CN108357230B (en) * | 2017-12-29 | 2019-10-11 | 东莞光群雷射科技有限公司 | The laser gold blocking film and its production technology of a kind of aluminum substrates and application |
JP7131919B2 (en) * | 2018-01-29 | 2022-09-06 | リンテック株式会社 | LASER MARKER LABEL AND LASER MARKER LABEL MANUFACTURING METHOD |
DE102018116292A1 (en) * | 2018-07-05 | 2020-01-09 | Dr. Ing. H.C. F. Porsche Aktiengesellschaft | vehicle part |
DE102018123473A1 (en) * | 2018-09-24 | 2020-03-26 | Leonhard Kurz Stiftung & Co. Kg | Decorative film, transfer film, use of a transfer film, process for producing a transfer film, process for decorating a molded plastic part and molded plastic part |
DE102019123495A1 (en) * | 2019-09-03 | 2021-03-04 | Bayerische Motoren Werke Aktiengesellschaft | Process for the production of a multicolored visible component |
BR112022026524A2 (en) * | 2020-10-02 | 2023-04-04 | Illinois Tool Works | MULTI-COLOR HOT STAMPING PRINTING SYSTEM |
DE102022102052A1 (en) * | 2022-01-28 | 2023-08-03 | Leonhard Kurz Stiftung & Co. Kg | Method of making an article, module and apparatus |
US20240066814A1 (en) * | 2022-08-30 | 2024-02-29 | Jin Ya Dian Technology Co.,Ltd. | Method of fabricating light-transmitting decorated molding article |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2240553A1 (en) † | 1972-08-17 | 1974-02-28 | Siemens Ag | PROCEDURE FOR LABELING AND / OR MARKING DIALS OR SIGNS OF EQUIPMENT |
US3930924A (en) † | 1971-12-08 | 1976-01-06 | Satoshi Oka | Process for making identification cards |
DE8130861U1 (en) † | 1981-10-22 | Beiersdorf Ag, 2000 Hamburg | Multi-layer label | |
US4515867A (en) † | 1982-09-20 | 1985-05-07 | Rca Corporation | Method for ablating a coded marking into a glass workpiece and product thereof |
DE3926578C1 (en) † | 1989-08-11 | 1990-07-26 | Leonhard Kurz Gmbh & Co, 8510 Fuerth, De |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR353121A (en) * | 1905-04-07 | 1905-09-04 | Fernand Beauvois | Attachment mode for non-slip elastic bandages |
GB1046411A (en) * | 1964-02-04 | 1966-10-26 | Letraset International Ltd | Transfer materials |
GB1233543A (en) * | 1967-06-01 | 1971-05-26 | ||
CH536388A (en) * | 1970-02-18 | 1973-04-30 | Ciba Geigy Ag | Process for printing leather |
US3926707A (en) * | 1971-08-04 | 1975-12-16 | Noridem Sa | Use of temporary printing carriers |
JPS5324323Y2 (en) * | 1973-04-19 | 1978-06-22 | ||
JPS5248224B2 (en) * | 1974-06-14 | 1977-12-08 | ||
JPS5919834B2 (en) * | 1980-06-02 | 1984-05-09 | 株式会社中山化学紙工所 | Transfer foil base material |
DE3048733C2 (en) * | 1980-12-23 | 1983-06-16 | GAO Gesellschaft für Automation und Organisation mbH, 8000 München | "Identity card and process for producing the same" |
JPS5867496A (en) * | 1981-10-19 | 1983-04-22 | Toshiba Corp | Marking method |
JPS6189899A (en) * | 1984-10-09 | 1986-05-08 | 凸版印刷株式会社 | Transfer sheet and manufacture of decorative material using said sheet |
JPH0635205B2 (en) * | 1985-06-28 | 1994-05-11 | 大日本印刷株式会社 | Transfer sheet |
JPS623982A (en) * | 1985-06-29 | 1987-01-09 | Nissha Printing Co Ltd | Transfer material |
JPS6270080A (en) * | 1985-09-24 | 1987-03-31 | Mitsubishi Electric Corp | Manufacture of metallic decorative panel |
JPS6280283A (en) * | 1985-10-01 | 1987-04-13 | Mitsubishi Electric Corp | Production of display parts |
JPS631483A (en) * | 1986-06-19 | 1988-01-06 | Mitsubishi Electric Corp | Coloration of metal decorative panel |
FR2602904B1 (en) * | 1986-08-05 | 1989-12-01 | Filotex Sa | LASER MARKABLE ELECTRIC CABLE |
FR2621762B1 (en) * | 1987-10-09 | 1994-06-17 | Thomson Csf | METHOD AND DEVICE FOR LASER IMAGE RECORDING, AND DEVICE OBTAINED BY THIS METHOD |
JPH01103493A (en) * | 1987-10-16 | 1989-04-20 | Tomoegawa Paper Co Ltd | Thermal recording medium |
JPH01267092A (en) * | 1988-04-19 | 1989-10-24 | Miyachi Electric Co | Laser marking method |
JPH01283703A (en) * | 1988-05-09 | 1989-11-15 | Stanley Electric Co Ltd | Forming method for body color lens |
FR2634690B1 (en) * | 1988-07-26 | 1990-11-09 | Breger Guy | POLYCHROME LASER PRINTING PROCESS |
JPH02100213A (en) * | 1988-10-06 | 1990-04-12 | Alps Electric Co Ltd | Manufacture of key top |
-
1991
- 1991-10-17 DE DE4134271A patent/DE4134271C1/de not_active Expired - Lifetime
-
1992
- 1992-10-13 AT AT92117433T patent/ATE154550T1/en not_active IP Right Cessation
- 1992-10-13 JP JP4273891A patent/JP2858513B2/en not_active Expired - Fee Related
- 1992-10-13 DK DK92117433.0T patent/DK0537668T3/en active
- 1992-10-13 ES ES92117433T patent/ES2104788T5/en not_active Expired - Lifetime
- 1992-10-13 EP EP92117433A patent/EP0537668B2/en not_active Expired - Lifetime
- 1992-10-13 DE DE59208628T patent/DE59208628D1/en not_active Expired - Fee Related
- 1992-10-14 US US07/960,892 patent/US5985078A/en not_active Expired - Fee Related
-
1998
- 1998-06-17 HK HK98105529A patent/HK1006297A1/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE8130861U1 (en) † | 1981-10-22 | Beiersdorf Ag, 2000 Hamburg | Multi-layer label | |
US3930924A (en) † | 1971-12-08 | 1976-01-06 | Satoshi Oka | Process for making identification cards |
DE2240553A1 (en) † | 1972-08-17 | 1974-02-28 | Siemens Ag | PROCEDURE FOR LABELING AND / OR MARKING DIALS OR SIGNS OF EQUIPMENT |
US4515867A (en) † | 1982-09-20 | 1985-05-07 | Rca Corporation | Method for ablating a coded marking into a glass workpiece and product thereof |
DE3926578C1 (en) † | 1989-08-11 | 1990-07-26 | Leonhard Kurz Gmbh & Co, 8510 Fuerth, De |
Non-Patent Citations (1)
Title |
---|
ICI-Films - Melinex - Polyester Film - Metallising; Industry Note MX203 sixth edition, 1986, Seiten 4,5,6,8 † |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022082044A1 (en) * | 2020-10-16 | 2022-04-21 | Avery Dennison Retail Information Services Llc | Engravable heat transfer labels and embellishments |
Also Published As
Publication number | Publication date |
---|---|
HK1006297A1 (en) | 1999-02-19 |
DE59208628D1 (en) | 1997-07-24 |
EP0537668A2 (en) | 1993-04-21 |
US5985078A (en) | 1999-11-16 |
JP2858513B2 (en) | 1999-02-17 |
ATE154550T1 (en) | 1997-07-15 |
EP0537668B1 (en) | 1997-06-18 |
ES2104788T5 (en) | 2004-09-01 |
JPH05305763A (en) | 1993-11-19 |
ES2104788T3 (en) | 1997-10-16 |
DK0537668T3 (en) | 1998-01-12 |
EP0537668A3 (en) | 1995-01-18 |
DE4134271C1 (en) | 1992-12-24 |
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