EP0512984B1 - Method and apparatus for processing containers - Google Patents
Method and apparatus for processing containers Download PDFInfo
- Publication number
- EP0512984B1 EP0512984B1 EP90907607A EP90907607A EP0512984B1 EP 0512984 B1 EP0512984 B1 EP 0512984B1 EP 90907607 A EP90907607 A EP 90907607A EP 90907607 A EP90907607 A EP 90907607A EP 0512984 B1 EP0512984 B1 EP 0512984B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- container
- wall
- side wall
- jig
- reforming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 14
- 230000002093 peripheral effect Effects 0.000 claims abstract description 11
- 238000002407 reforming Methods 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000013011 mating Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 235000013405 beer Nutrition 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000010409 ironing Methods 0.000 description 3
- 235000014171 carbonated beverage Nutrition 0.000 description 2
- 230000002860 competitive effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D51/00—Making hollow objects
- B21D51/16—Making hollow objects characterised by the use of the objects
- B21D51/26—Making hollow objects characterised by the use of the objects cans or tins; Closing same in a permanent manner
- B21D51/2646—Of particular non cylindrical shape, e.g. conical, rectangular, polygonal, bulged
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/10—Stamping using yieldable or resilient pads
Definitions
- This invention relates generally to two-piece container constructions, and more particularly to a method and apparatus for processing such containers to increase the strength thereof, as well as improve the appearance.
- Two-piece cans are the most common type of metal container used in the beer and beverage industry, as well as for aerosol and food packaging.
- the two-piece container consists of a unitary body, including a side wall open at one end with an integral end wall at the other end.
- the integral end wall is usually formed to a domed-shaped configuration to increase the overall strength of the container.
- An annular portion is usually formed to a special configuration between the center dome panel of the bottom wall and the side wall that defines a reduced diameter support for the container and also provides a nesting feature for nesting with the end of an adjacent container, which is seamed to the open end thereof.
- U.S. Patent No. 4,685,582 An exemplary bottom profile for a drawn and ironed container that has achieved a remarkable degree of commercial success is disclosed in U.S. Patent No. 4,685,582.
- the container disclosed therein also includes an upper end portion that has a reduced neck so that a second end panel or end having a smaller diameter can be utilized to enclose the open-ended drawn and ironed container.
- containers that are used for beer and carbonated beverages are formed from a flat aluminum disc to an outside diameter of 2-11/16th inch (referred to as a "211-container") and the upper open end is reduced in diameter to form a 209-neck (2-9/16th inch) or any other smaller diameter, such as a 2071 ⁇ 2-neck, a 206-neck, and even a 204-neck or smaller so that smaller diameter ends can be utilized in the finished package.
- 211-container 2-11/16th inch
- any other smaller diameter such as a 2071 ⁇ 2-neck, a 206-neck, and even a 204-neck or smaller so that smaller diameter ends can be utilized in the finished package.
- the integral bottom end wall of the container usually has the same metal thickness gauge as the initial disc and the side wall is reduced through a drawing and ironing process to a thickness approaching one-third of the thickness of the original metal disc. Accordingly, to minimize overall weight, the can top or end panel that forms the second piece of the two-piece can is made as diametrically small as possible, while still maintaining the structural integrity of the container, the functionality thereof, and an aesthetically-pleasing appearance.
- a sheet of stock material of predetermined thickness is fed to a cupping press, wherein circular discs are cut from the stock material and are transformed into cups having a diameter which is considerably larger than the ultimate diameter of the finished container.
- the preformed cups are then transferred to a container-forming apparatus, commonly referred to as a "bodymaker", wherein the cup is aligned with a punch carried on a reciprocable ram which cooperates with a plurality of spaced ironing dies and a doming mechanism located at the end of the path of the punch.
- the punch initially cooperates with a redraw assembly in which the shallow cup is redrawn to a smaller diameter that has an internal diameter approximately equal to the internal diameter of the ultimately-finished container and a height that is greater than the height of the original cup.
- Each cup then passes through a series of ironing dies having progressively reduced diameters so that the side wall of the container is progressively reduced in thickness, while the height of the container increases.
- the end of the container is forced into a predetermined configuration to form an integral end wall that has a central inwardly-domed panel and a specially-configured peripheral annular bead or support portion.
- the drawn and ironed container is then trimmed to a selected height and coated and labeled, and a reduced tapered neck is produced on the open end.
- the Assignee of the present invention has developed a die necking operation for sequentially reducing the upper open end of the container to a smooth die neck configuration. This is done through a plurality of steps until the desired reduction for an end, such as a 206- or 204-end, is achieved.
- This process is disclosed in U.S. Patent No. 4,774,839, incorporated herein by reference.
- a container of the type having a bottom profile, such as disclosed in U.S. Patent No. 4,685,582, and a smooth die neck configuration illustrated in the above-referenced patent has increased strength characteristics and the overall aesthetic appearance has been enhanced.
- a method of furthering production of a container having a longitudinal axis and a side wall which is integral with a bottom having a center domed portion, and a countersink having an annular, substantially longitudinal inner wall and an outer annular wall
- the step of reforming the bottom characterized by: supporting said container in a jig, said jig having a bottom peripheral profile portion substantially corresponding in shape to said outer annular wall of said container; mating the bottom peripheral profile portion of said jig with said outer annular wall; and bringing a reforming roller into engagement with said inner wall, said reforming roller rotating along said inner wall and about an arcuate path in substantially radial alignment with said mating of said jig and said outer annular wall.
- the invention includes apparatus, according to claim 5.
- WO83/02577 which forms the base of the preambles of claims 1 and 5 discloses various embodiments for reforming the bottom countersink of a container.
- the container 10 is supported at its open end by a rotatable pad and at its closed end by various configurations of a support chuck.
- the support chuck is positioned within the bottom countersink of the container. A work roll is then moved radially inwardly to engage the outer annular wall of the container.
- the container produced by the method of the present invention can be formed from a stock material, preferably an aluminum flat disc having a thickness of less than 0,0305 cm (0.0120 inch) and meet the minimum crush and buckle requirements of 1110 N (250 pounds) and 1,6 N/mm2 (90 psi), respectively.
- the container which is formed from a flat metal disc, preferably aluminum, includes a bottom wall that has a thickness substantially equal to the thickness of the stock material and a reduced side wall thickness that is on the order of 1/3 the thickness of the stock material, with the bottom wall having a central inwardly-domed panel connected to the side wall through a countersink that has outer and inner, generally flat, substantially vertical walls.
- the container that has been formed in accordance with known teachings has even more significantly improved performance characteristics by reforming the bottom end wall of the container from the initial configuration, as disclosed in the above-mentioned '582 patent.
- the fluted container has been necked and flanged and has been internally spray coated and externally printed the bottom profile, more specifically the countersink or chime area of the bottom wall, is reshaped by reforming the inner wall of the countersink to further improve buckle resistance and decrease can growth.
- This particular process would also allow further reduction in stock metal thickness without any change in the cut edge diameter of the initial disc.
- the finished drawn and ironed container is supported in a suitable jig 150 that has an internal opening 152 which corresponds to the outer peripheral diameter of the container C.
- the jig has a lower profile portion 154 that conforms to the countersink wall portion of the bottom wall of the container, as orginally formed in accordance with the process disclosed in the '582 patent.
- a plug 156 is inserted into the upper end of the opening and securely held in the top of the container.
- the bottom peripheral profile 154 of the jig 150 is in extended contact with the container bottom 137.
- a reforming roller 160 is brought into engagement with the outside of the domed end 162 of the container and is supported on a shaft 164 that is designed to be rotated along an arcuate path around the center axis for the container C.
- the roller has a peripheral configuration 166 which defines a substantially vertical upwardly and outwardly tapered wall having a generally arcuate upper portion 168 so that the inner wall 170 of the countersink is reformed to a more vertical profile while the dome 162 is stretched to a small degree.
- the outer wall 172 is held to its original configuration. Alternatively, the outer wall could also be reformed with the inner wall.
- the container produced according to the method and apparatus of the present invention has significantly less container growth during internal pressurization, and also has improved buckle resistance.
- the container constructed in accordance with the present invention has been found to be capable of being produced from stock flat disc material having a significantly reduced thickness.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Supplying Of Containers To The Packaging Station (AREA)
- Prostheses (AREA)
- Surgical Instruments (AREA)
- Automatic Analysis And Handling Materials Therefor (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Rigid Containers With Two Or More Constituent Elements (AREA)
Abstract
Description
- This invention relates generally to two-piece container constructions, and more particularly to a method and apparatus for processing such containers to increase the strength thereof, as well as improve the appearance.
- Two-piece cans are the most common type of metal container used in the beer and beverage industry, as well as for aerosol and food packaging. The two-piece container consists of a unitary body, including a side wall open at one end with an integral end wall at the other end. The integral end wall is usually formed to a domed-shaped configuration to increase the overall strength of the container. An annular portion is usually formed to a special configuration between the center dome panel of the bottom wall and the side wall that defines a reduced diameter support for the container and also provides a nesting feature for nesting with the end of an adjacent container, which is seamed to the open end thereof.
- An exemplary bottom profile for a drawn and ironed container that has achieved a remarkable degree of commercial success is disclosed in U.S. Patent No. 4,685,582. The container disclosed therein also includes an upper end portion that has a reduced neck so that a second end panel or end having a smaller diameter can be utilized to enclose the open-ended drawn and ironed container.
- In most cases, containers that are used for beer and carbonated beverages are formed from a flat aluminum disc to an outside diameter of 2-11/16th inch (referred to as a "211-container") and the upper open end is reduced in diameter to form a 209-neck (2-9/16th inch) or any other smaller diameter, such as a 207½-neck, a 206-neck, and even a 204-neck or smaller so that smaller diameter ends can be utilized in the finished package.
- An important competitive objective in the packaging industry is to reduce the total can weight as much as possible, while maintaining its strength and performance, in accordance with industry requirements. For pressurized contents, such as soft drinks or beer, the integral bottom end wall of the container usually has the same metal thickness gauge as the initial disc and the side wall is reduced through a drawing and ironing process to a thickness approaching one-third of the thickness of the original metal disc. Accordingly, to minimize overall weight, the can top or end panel that forms the second piece of the two-piece can is made as diametrically small as possible, while still maintaining the structural integrity of the container, the functionality thereof, and an aesthetically-pleasing appearance.
- In the manufacture of containers of this type, a sheet of stock material of predetermined thickness is fed to a cupping press, wherein circular discs are cut from the stock material and are transformed into cups having a diameter which is considerably larger than the ultimate diameter of the finished container.
- The preformed cups are then transferred to a container-forming apparatus, commonly referred to as a "bodymaker", wherein the cup is aligned with a punch carried on a reciprocable ram which cooperates with a plurality of spaced ironing dies and a doming mechanism located at the end of the path of the punch. During the forming process, the punch initially cooperates with a redraw assembly in which the shallow cup is redrawn to a smaller diameter that has an internal diameter approximately equal to the internal diameter of the ultimately-finished container and a height that is greater than the height of the original cup.
- Each cup then passes through a series of ironing dies having progressively reduced diameters so that the side wall of the container is progressively reduced in thickness, while the height of the container increases. At the end of the stroke for the punch or ram, the end of the container is forced into a predetermined configuration to form an integral end wall that has a central inwardly-domed panel and a specially-configured peripheral annular bead or support portion. The drawn and ironed container is then trimmed to a selected height and coated and labeled, and a reduced tapered neck is produced on the open end.
- To produce a container that can be price competitive and yet meet the rigid industry requirements, particularly for pressurized contents, such as beer and carbonated beverages, the Assignee of the present invention has developed a die necking operation for sequentially reducing the upper open end of the container to a smooth die neck configuration. This is done through a plurality of steps until the desired reduction for an end, such as a 206- or 204-end, is achieved. This process is disclosed in U.S. Patent No. 4,774,839, incorporated herein by reference. A container of the type having a bottom profile, such as disclosed in U.S. Patent No. 4,685,582, and a smooth die neck configuration illustrated in the above-referenced patent has increased strength characteristics and the overall aesthetic appearance has been enhanced.
- In order to further enhance the overall appearance of the two-piece drawn and ironed container, it has also been proposed to deform the container side wall to produce a fluted appearance, such as disclosed in U.S. Patent Nos. DES 283,011 and DES 290,688.
- According to the present invention there is provided a method of furthering production of a container, having a longitudinal axis and a side wall which is integral with a bottom having a center domed portion, and a countersink having an annular, substantially longitudinal inner wall and an outer annular wall comprising the step of reforming the bottom characterized by:
supporting said container in a jig, said jig having a bottom peripheral profile portion substantially corresponding in shape to said outer annular wall of said container;
mating the bottom peripheral profile portion of said jig with said outer annular wall; and
bringing a reforming roller into engagement with said inner wall, said reforming roller rotating along said inner wall and about an arcuate path in substantially radial alignment with said mating of said jig and said outer annular wall. - The invention includes apparatus, according to claim 5.
- WO83/02577 (Claydon, et. al.) which forms the base of the preambles of claims 1 and 5 discloses various embodiments for reforming the bottom countersink of a container. According to Claydon, the container 10 is supported at its open end by a rotatable pad and at its closed end by various configurations of a support chuck. In each embodiment of Claydon, the support chuck is positioned within the bottom countersink of the container. A work roll is then moved radially inwardly to engage the outer annular wall of the container.
- The container produced by the method of the present invention can be formed from a stock material, preferably an aluminum flat disc having a thickness of less than 0,0305 cm (0.0120 inch) and meet the minimum crush and buckle requirements of 1110 N (250 pounds) and 1,6 N/mm² (90 psi), respectively.
- The container, which is formed from a flat metal disc, preferably aluminum, includes a bottom wall that has a thickness substantially equal to the thickness of the stock material and a reduced side wall thickness that is on the order of 1/3 the thickness of the stock material, with the bottom wall having a central inwardly-domed panel connected to the side wall through a countersink that has outer and inner, generally flat, substantially vertical walls.
-
- Figure 1
- is a fragmentary cross-sectional view showing the apparatus utilised for reforming the container bottom wall;
- Figure 2
- is an enlarged fragmentary cross-sectional view similar to Fig. 1.
-
- According to the invention, the container that has been formed in accordance with known teachings has even more significantly improved performance characteristics by reforming the bottom end wall of the container from the initial configuration, as disclosed in the above-mentioned '582 patent. Thus, as shown in Figs 1 and 2, after the fluted container has been necked and flanged and has been internally spray coated and externally printed the bottom profile, more specifically the countersink or chime area of the bottom wall, is reshaped by reforming the inner wall of the countersink to further improve buckle resistance and decrease can growth. This particular process would also allow further reduction in stock metal thickness without any change in the cut edge diameter of the initial disc.
- Thus, as shown in Fig 1, the finished drawn and ironed container is supported in a
suitable jig 150 that has aninternal opening 152 which corresponds to the outer peripheral diameter of the container C. The jig has alower profile portion 154 that conforms to the countersink wall portion of the bottom wall of the container, as orginally formed in accordance with the process disclosed in the '582 patent. - A
plug 156 is inserted into the upper end of the opening and securely held in the top of the container. The bottomperipheral profile 154 of thejig 150 is in extended contact with the container bottom 137. A reformingroller 160 is brought into engagement with the outside of thedomed end 162 of the container and is supported on ashaft 164 that is designed to be rotated along an arcuate path around the center axis for the container C. The roller has aperipheral configuration 166 which defines a substantially vertical upwardly and outwardly tapered wall having a generally arcuateupper portion 168 so that theinner wall 170 of the countersink is reformed to a more vertical profile while thedome 162 is stretched to a small degree. Theouter wall 172 is held to its original configuration. Alternatively, the outer wall could also be reformed with the inner wall. - It has been found that this reforming operation significantly improves buckle resistance and decreases the amount of can growth, i.e., the amount that the bottom end wall is elongated when pressure is applied internally of the container.
- Thus, in summary, the container produced according to the method and apparatus of the present invention has significantly less container growth during internal pressurization, and also has improved buckle resistance. The container constructed in accordance with the present invention has been found to be capable of being produced from stock flat disc material having a significantly reduced thickness.
Claims (6)
- A method of furthering production of a container, having a longitudinal axis and a side wall (129) which is integral with a bottom (137) having a center domed portion (162), and a countersink having an annular, substantially longitudinal inner wall (170) and an outer annular wall (172) comprising the step of reforming the bottom (137) characterised by:
supporting said container in a jig (150), said jig (150) having a bottom peripheral profile portion (154) substantially corresponding in shape to said outer annular wall (172) of said container;
mating the bottom peripheral profile portion (154) of said jig (150) with said outer annular wall (172); and
bringing a reforming roller (160) into engagement with said inner wall (170), said reforming roller (160) rotating along said inner wall (170) and about an arcuate path in substantially radial alignment with said mating of said jig (150) and said outer annular wall (172). - The method of claim 1, said reforming roller (160) being rotated about an arcuate path equidistant from said longitudinal axis.
- The method of claim 1, wherein said inner wall (170) is reformed to a more vertical position.
- The method of claim 1, wherein said roller (160) has a peripheral configuration (166) which defines a substantially vertical upwardly and outwardly tapered wall having a generally arcuate portion (168).
- An apparatus for furthering production of a container having a longitudinal axis and a side wall (129) which is integral with a bottom (137) having a center domed portion (162), and a countersink having an annular, substantially longitudinal inner wall (170) and an outer annular wall (173) by reforming the bottom (137), said apparatus being characterized by :
a jig (150) having a bottom peripheral profile portion (154) substantially corresponding in shape to said outer annular wall (172) of said container;
means for supporting said container in said jig (150);
means for bringing a reforming roller (160) into engagement with said inner wall (170);
means for rotating said reforming roller (160) along said inner wall (170) and about an arcuate path in substantially radial alignment with said bottom profile (154) of said jig (15) and said outer annular wall (172). - The apparatus of claim 5, including means for rotating said reforming roller (160) about an arcuate path equidistant from the axis of the container.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1990/000451 WO1991011275A1 (en) | 1990-01-26 | 1990-01-26 | Method and apparatus for processing containers |
| CA002074526A CA2074526C (en) | 1990-01-26 | 1990-01-26 | Method and apparatus for processing containers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0512984A1 EP0512984A1 (en) | 1992-11-19 |
| EP0512984B1 true EP0512984B1 (en) | 1994-12-14 |
Family
ID=25675363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP90907607A Expired - Lifetime EP0512984B1 (en) | 1990-01-26 | 1990-01-26 | Method and apparatus for processing containers |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0512984B1 (en) |
| JP (1) | JP3149945B2 (en) |
| AT (1) | ATE115447T1 (en) |
| AU (1) | AU655754B2 (en) |
| CA (1) | CA2074526C (en) |
| DE (1) | DE69015210T2 (en) |
| ES (1) | ES2066204T3 (en) |
| WO (1) | WO1991011275A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX9101632A (en) * | 1990-10-22 | 1992-06-05 | Ball Corp | METHOD AND APPARATUS TO REINFORCE THE BASE OR BOTTOM OF A CONTAINER |
| MY106990A (en) * | 1990-12-21 | 1995-08-30 | Metal Box Plc | Containers |
| US5261558A (en) * | 1990-12-21 | 1993-11-16 | Carnaudmetalbox Plc | Can bodies |
| US5341667A (en) * | 1992-05-01 | 1994-08-30 | Reynolds Metals Company | Container bottom wall reforming apparatus and method |
| GB9324910D0 (en) * | 1993-12-04 | 1994-01-26 | Metal Box Plc | Containers |
| JP3441317B2 (en) * | 1996-10-21 | 2003-09-02 | 大和製罐株式会社 | Method for producing deformed metal can having irregular pattern on body |
| MY175342A (en) | 2010-08-20 | 2020-06-19 | Alcoa Inc | Shaped metal container and method for making same |
| US9327338B2 (en) | 2012-12-20 | 2016-05-03 | Alcoa Inc. | Knockout for use while necking a metal container, die system for necking a metal container and method of necking a metal container |
| JP6043843B1 (en) * | 2015-08-10 | 2016-12-14 | 株式会社マジカル | Plum food holder |
| CN118287592B (en) * | 2024-04-25 | 2024-09-20 | 山东省乐启新材料科技有限公司 | Tank neck shrinking device |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2039528A1 (en) | 1970-08-08 | 1972-02-10 | Alusuisse | Method and device for the production of can bases from sheet metal |
| US4316375A (en) * | 1979-11-30 | 1982-02-23 | Reynolds Metals Company | Apparatus for corrugating can body flanges |
| US4519232A (en) * | 1982-12-27 | 1985-05-28 | National Can Corporation | Method and apparatus for necking containers |
| US4578976A (en) * | 1984-04-09 | 1986-04-01 | National Can Corporation | Container processing apparatus |
| US4685582A (en) * | 1985-05-20 | 1987-08-11 | National Can Corporation | Container profile with stacking feature |
| CH673790A5 (en) * | 1987-07-07 | 1990-04-12 | Elpatronic Ag | |
| CH676210A5 (en) * | 1988-07-19 | 1990-12-28 | Elpatronic Ag |
-
1990
- 1990-01-26 JP JP50745290A patent/JP3149945B2/en not_active Expired - Lifetime
- 1990-01-26 DE DE69015210T patent/DE69015210T2/en not_active Expired - Lifetime
- 1990-01-26 CA CA002074526A patent/CA2074526C/en not_active Expired - Lifetime
- 1990-01-26 AT AT90907607T patent/ATE115447T1/en not_active IP Right Cessation
- 1990-01-26 EP EP90907607A patent/EP0512984B1/en not_active Expired - Lifetime
- 1990-01-26 ES ES90907607T patent/ES2066204T3/en not_active Expired - Lifetime
- 1990-01-26 AU AU56371/90A patent/AU655754B2/en not_active Expired
- 1990-01-26 WO PCT/US1990/000451 patent/WO1991011275A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CA2074526A1 (en) | 1991-07-27 |
| ES2066204T3 (en) | 1995-03-01 |
| WO1991011275A1 (en) | 1991-08-08 |
| AU655754B2 (en) | 1995-01-12 |
| CA2074526C (en) | 2002-07-16 |
| JP3149945B2 (en) | 2001-03-26 |
| DE69015210D1 (en) | 1995-01-26 |
| EP0512984A1 (en) | 1992-11-19 |
| AU5637190A (en) | 1991-08-21 |
| ATE115447T1 (en) | 1994-12-15 |
| JPH05503878A (en) | 1993-06-24 |
| DE69015210T2 (en) | 1995-08-03 |
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