EP0470886A1 - Specific structure for accelerating the reactivity speed of zeolite and method for depositing zeolite on said structure - Google Patents
Specific structure for accelerating the reactivity speed of zeolite and method for depositing zeolite on said structure Download PDFInfo
- Publication number
- EP0470886A1 EP0470886A1 EP91402107A EP91402107A EP0470886A1 EP 0470886 A1 EP0470886 A1 EP 0470886A1 EP 91402107 A EP91402107 A EP 91402107A EP 91402107 A EP91402107 A EP 91402107A EP 0470886 A1 EP0470886 A1 EP 0470886A1
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- European Patent Office
- Prior art keywords
- zeolite
- projections
- structure according
- area
- spaces
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B35/00—Boiler-absorbers, i.e. boilers usable for absorption or adsorption
- F25B35/04—Boiler-absorbers, i.e. boilers usable for absorption or adsorption using a solid as sorbent
Definitions
- the present invention relates to a structure intended to accelerate the speed of reactivity of the zeolite in cooling and / or heating devices containing zeolite in granules or in balls.
- the zeolite must have good adhesion to the support or structure, high adsorption capacities and good heat transfer with the support.
- patent DE-OS-25 36 006 describes a process for depositing zeolite, alumina, activated carbon, under granular or sprayed form, on a metal support which is characterized by the immersion of said support in an adequate chemical solution. The deposit formed is then dried and then filtered.
- the reactivity time of the zeolite is of the order of at least 40 minutes.
- the zeolite, used in the form of granules, has a diameter of between 1 and 3 mm and is held vertically in an aluminum or copper profile.
- the reactivity time of the zeolite is the minimum time to provide it with heat so as to raise its temperature between 200 and 300 ° C.
- the subject of the present invention is a particular structure which makes it possible to improve the speed of reactivity of the zeolite thus presenting markedly improved performance. It is particularly intended to be applied in cooling and / or heating devices of the refrigerator type for example.
- the structure for accelerating the speed of reactivity of the zeolite in cooling and / or heating devices containing zeolite in granules or in balls is characterized in that it consists of a hollow metallic piece whose external surface is shaped in a regular configuration of so as to present a plurality of projections.
- the reactivity time is of the order of a minute.
- the configuration consists of projections arranged horizontally and vertically, in two planes, each of the projections being separated by a small and a large space of parallelepipedal shapes such as the width of the area of the upper face and that of the area of the underside of the small space, between two projections, is of the order of 2 mm, and their lengths of the order of 3 mm, and that the width of the area of the underside and that of the area of the upper face of the large space, between two projections, is between 4 and 5 mm, and their lengths of the same order.
- Said projections are in the form of a volume of parallelepiped shape with a height of between 15 and 30 mm.
- the width of the area of the upper face and that of the area of the lower face of said volume forming a projection are of the order of 3 mm and their respective length is between 4 and 5 mm.
- the metal part is a rolled plate and connected at its two ends by a weld.
- the small spaces are closed off with continuous strips before the zeolite is introduced into the large spaces.
- the metal part is made of aluminum or copper.
- said structure is introduced into a glass tube around which is arranged a device making it possible to induce so-called eddy currents in the metal structure .
- This embodiment of the invention is particularly suitable for being applied to a household refrigerator because of its very simple technical design and its low manufacturing cost.
- Figure 1 is a schematic representation, seen from above, of a part of said structure.
- FIG. 1a is a sectional view of part of the structure along the axis I-I ′ of FIG. 1.
- FIG. 1b is a sectional view of part of the structure along the axis II-II ′ of FIG. 1.
- Figure 2 is a schematic sectional view along I-I 'of a non-limiting embodiment of the structure according to the invention.
- the structure consists of a metal part 1 in which a channel 4 has been dug and on which have been formed series of projections 5 arranged more or less regularly along the same longitudinal plane and the same transverse plane. the axis of channel 4.
- the adsorbent here zeolite 6, adheres to the walls of the projections 5 adjacent to the spaces 2.
- the zeolite 6 has a diameter of the order of 3 mm and is in granular form.
- FIG. 2 there is shown an application of the structure.
- the structure is placed in a glass tube 7 around which is placed a medium frequency inductor 8 for example.
- the structure consists in fact of two simple juxtaposed structures having protrusions 5 only on one of their sides and therefore has a configuration such that the two channels 4 are adjacent.
- the hot or cold liquid or gas is introduced via the pipe 11, then it is evacuated, via the tubular connection 9, into the second channel 4b, and finally discharged to the outside by the pipeline 10.
- the zeolite 6 deposition process is carried out as follows:
- the spaces 3 are filled in with the aforementioned plastic strips.
- the zeolite 6 is then introduced into the spaces 2. Then the structure is placed in a bath containing a solution such as that used in FR-A-2 443 485. Once the zeolite has been deposited on the faces of the projections 5, the structure of the bath is removed and the plastic strips are removed. The structure is then introduced into an oven at a temperature of the order of 300 ° C. to effect the sintering of the zeolite 6.
- a thin deposit (0.1 to 0.5 mm) of zeolite 6 is then obtained out of two faces of each projection 5, continuous deposition because the granules or grains of zeolite are also bonded to each other but not completely: we thus notice spaces between two grains or granules, which thus promotes the passage of gas or liquid for the cooling and / or heating of an enclosure. Spaces 2 are also filled with zeolite (see Figures 1a and 1b). Consequently, during the use of the structure, the absence of zeolite 6 on the two other faces of the projections 5 will favor the acceleration of the speed of reactivity of the zeolite 6.
- the heating of the structure placed in a glass tube is accelerated by the medium frequency inductor 8, thus promoting the speed of reactivity of the zeolite 6.
- This structure is particularly suitable for heating and / or cooling devices of the refrigerator type but also for air conditioning of vehicles.
Abstract
Description
La présente invention a trait à une structure destinée à accélérer la vitesse de réactivité de la zéolithe dans des dispositifs de refroidissement et/ou de chauffage contenant de la zéolithe en granulés ou en billes.The present invention relates to a structure intended to accelerate the speed of reactivity of the zeolite in cooling and / or heating devices containing zeolite in granules or in balls.
Elle s'applique notamment aux réfrigérateurs qui nécessitent des dispositifs à adsorption et désorption très rapides pour fabriquer du froid, et a pour objectif de réaliser un dépôt de zéolithe sur ladite structure.It applies in particular to refrigerators which require very rapid adsorption and desorption devices to produce cold, and aims to achieve a deposit of zeolite on said structure.
La zéolithe doit présenter une bonne adhérence sur le support ou structure, des capacités d'adsorption élevées et un bon transfert thermique avec le support.The zeolite must have good adhesion to the support or structure, high adsorption capacities and good heat transfer with the support.
Il existe dans l'état de la technique de nombreuses antériorités décrivant des procédés de dépôt d'un matériau adsorbant sur un support.There are numerous prior art in the state of the art describing methods of depositing an adsorbent material on a support.
Par exemple, le brevet DE-OS-25 36 006 décrit un procédé de dépôt de zéolithe, d'alumine, de charbon activé, sous forme granulaire ou pulvérisé, sur un support métallique qui est caractérisé par l'immersion dudit support dans une solution chimique adéquate. Le dépôt formé est ensuite séché puis filtré.For example, patent DE-OS-25 36 006 describes a process for depositing zeolite, alumina, activated carbon, under granular or sprayed form, on a metal support which is characterized by the immersion of said support in an adequate chemical solution. The deposit formed is then dried and then filtered.
Un autre procédé de dépôt d'un adsorbant sur une plaque support est décrit dans le FR-A-2 443 485, procédé dans lequel l'adsorbant pulvérisé est dispersé dans une solution alcaline et se dépose sur la plaque support après élimination de la plaque solvant.Another method of depositing an adsorbent on a support plate is described in FR-A-2 443 485, method in which the sprayed adsorbent is dispersed in an alkaline solution and is deposited on the support plate after removal of the plate solvent.
Lorsqu'on fait circuler, sous vide, un fluide caloporteur dans un profilé creux destiné à être utilisé dans des dispositifs de refroidissement et/ou de chauffage du type réfrigérateur par exemple, et dont la face externe est revêtue de zéolithe, revêtement réalisé selon l'un des procédés ci-dessus décrits, le temps de réactivité de la zéolithe est de l'ordre de 40 minutes au moins. La zéolithe, utilisée sous forme de granules, présente un diamètre compris entre 1 et 3 mm et est maintenue verticalement dans un profilé en aluminium ou en cuivre.When circulating, under vacuum, a heat transfer fluid in a hollow profile intended to be used in cooling and / or heating devices of the refrigerator type for example, and the external face of which is coated with zeolite, coating produced according to the 'One of the methods described above, the reactivity time of the zeolite is of the order of at least 40 minutes. The zeolite, used in the form of granules, has a diameter of between 1 and 3 mm and is held vertically in an aluminum or copper profile.
Le temps de réactivité de la zéolithe est le temps minimum pour lui apporter de la chaleur de façon à monter sa température entre 200 et 300°C.The reactivity time of the zeolite is the minimum time to provide it with heat so as to raise its temperature between 200 and 300 ° C.
La présente invention a pour objet une structure particulière qui permet d'améliorer la vitesse de réactivité de la zéolithe présentant ainsi des performances nettement améliorées. Elle est particulièrement destinée à être appliquée dans les dispositifs de refroidissement et/ou de chauffage du type réfrigérateur par exemple.The subject of the present invention is a particular structure which makes it possible to improve the speed of reactivity of the zeolite thus presenting markedly improved performance. It is particularly intended to be applied in cooling and / or heating devices of the refrigerator type for example.
Selon l'invention, la structure pour accélérer la vitesse de réactivité de la zéolithe dans des dispositifs de refroidissement et/ou de chauffage contenant de la zéolithe en granulés ou en billes est caractérisée en ce qu'elle est constituée d'une pièce métallique creuse dont la surface externe est façonnée selon une configuration régulière de façon à présenter une pluralité de saillies. Ainsi, le temps de réactivité est de l'ordre de la minute.According to the invention, the structure for accelerating the speed of reactivity of the zeolite in cooling and / or heating devices containing zeolite in granules or in balls is characterized in that it consists of a hollow metallic piece whose external surface is shaped in a regular configuration of so as to present a plurality of projections. Thus, the reactivity time is of the order of a minute.
De façon avantageuse, la configuration est constituée par des saillies rangées horizontalement et verticalement, dans deux plans, chacune des saillies étant séparée par un petit et un grand espaces de formes parallélépipédiques tels que la largeur de l'aire de la face supérieure et celle de l'aire de la face inférieure du petit espace, entre deux saillies, est de l'ordre de 2 mm, et leurs longueur de l'ordre de 3 mm, et que la largeur de l'aire de la face inférieure et celle de l'aire de la face supérieure du grand espace, entre deux saillies, est comprise entre 4 et 5 mm, et leurs longueurs du même ordre.Advantageously, the configuration consists of projections arranged horizontally and vertically, in two planes, each of the projections being separated by a small and a large space of parallelepipedal shapes such as the width of the area of the upper face and that of the area of the underside of the small space, between two projections, is of the order of 2 mm, and their lengths of the order of 3 mm, and that the width of the area of the underside and that of the area of the upper face of the large space, between two projections, is between 4 and 5 mm, and their lengths of the same order.
Lesdites saillies se présentent sous la forme d'un volume de forme parallélépipédique avec une hauteur comprise entre 15 et 30 mm.Said projections are in the form of a volume of parallelepiped shape with a height of between 15 and 30 mm.
De façon préférentielle, la largeur de l'aire de la face supérieure et celle de l'aire de la face inférieure dudit volume formant une saillie sont de l'ordre de 3 mm et leur longueur respective est comprise entre 4 et 5 mm.Preferably, the width of the area of the upper face and that of the area of the lower face of said volume forming a projection are of the order of 3 mm and their respective length is between 4 and 5 mm.
Selon un autre mode de réalisation de l'invention, la pièce métallique est une plaque roulée et reliée à ses deux extrémités par une soudure.According to another embodiment of the invention, the metal part is a rolled plate and connected at its two ends by a weld.
Selon un aspect important de dépôt de la zéolithe dans l'invention, les petits espaces sont obturés par des lamelles continues avant qu'on introduise la zéolithe dans les grands espaces.According to an important aspect of depositing the zeolite in the invention, the small spaces are closed off with continuous strips before the zeolite is introduced into the large spaces.
De façon préférentielle, la pièce métallique est en aluminium ou en cuivre.Preferably, the metal part is made of aluminum or copper.
Selon un autre mode de réalisation de l'invention, pour une bonne application de la zéolithe sur la structure, on introduit ladite structure dans un tube en verre autour duquel est disposé un dispositif permettant d'induire des courants dits de Foucault dans la structure métallique. Cette réalisation de l'invention est particulièrement appropriée pour être appliquée au réfrigérateur ménager du fait de sa conception technique très simple et de son faible coût de fabrication.According to another embodiment of the invention, for a good application of the zeolite on the structure, said structure is introduced into a glass tube around which is arranged a device making it possible to induce so-called eddy currents in the metal structure . This embodiment of the invention is particularly suitable for being applied to a household refrigerator because of its very simple technical design and its low manufacturing cost.
La présente invention concerne également un procédé de dépôt d'une couche de zéolithe sur les saillies de la structure décrite précédemment, caractérisé en ce qu'il comporte les étapes suivantes :
- obturation des petits espaces par des lamelles plastiques,
- introduction de zéolithe dans les grands espaces,
- introduction de ladite structure dans un bain contenant une solution telle que celle utilisée dans le FR-A-2 443 485,
- enlèvement des lamelles plastiques de la structure une fois sortie du bain, dès que le dépôt de zéolithe sur les saillies est réalisé et
- frittage du dépôt de zéolithe sur la structure, réalisé dans un four à la température de 350°C.
- sealing small spaces with plastic slats,
- introduction of zeolite in large spaces,
- introduction of said structure into a bath containing a solution such as that used in FR-A-2 443 485,
- removal of the plastic strips from the structure once out of the bath, as soon as the zeolite is deposited on the projections and
- sintering of the zeolite deposit on the structure, carried out in an oven at a temperature of 350 ° C.
Les autres caractéristiques et avantages de l'invention résulteront de la description suivante, en se rapportant aux dessins annexés dans lesquels :Other features and advantages of the invention Will result from the following description, referring to the accompanying drawings in which:
La figure 1 est une représentation schématique, vue de dessus, d'une partie de ladite structure.Figure 1 is a schematic representation, seen from above, of a part of said structure.
La figure 1a est une vue en coupe d'une partie de la structure selon l'axe I-I′ de la figure 1.FIG. 1a is a sectional view of part of the structure along the axis I-I ′ of FIG. 1.
La figure 1b est une vue en coupe d'une partie de la structure selon l'axe II-II′ de la figure 1.FIG. 1b is a sectional view of part of the structure along the axis II-II ′ of FIG. 1.
La figure 2 est une vue schématique en coupe selon I-I′ d'une forme d'exécution non limitative de la structure selon l'invention.Figure 2 is a schematic sectional view along I-I 'of a non-limiting embodiment of the structure according to the invention.
Selon la figure 1, la structure est constituée d'une pièce métallique 1 dans laquelle a été creusé un canal 4 et sur laquelle ont été façonnées des séries de saillies 5 disposées plus ou moins régulièrement selon un même plan longitudinal et un même plan transversal à l'axe du canal 4.According to FIG. 1, the structure consists of a metal part 1 in which a
L'adsorbant, ici de la zéolithe 6, adhère aux parois des saillies 5 adjacentes aux espaces 2. La zéolithe 6 présente un diamètre de l'ordre de 3 mm et se présente sous forme granulaire.The adsorbent, here zeolite 6, adheres to the walls of the
Avant introduction de la zéolithe 6 dans les volumes 2, on dispose dans les espaces 3 des lamelles plastiques non représentées sur les figures.Before introduction of the zeolite 6 into the
Selon la figure 2, on a représenté une application de la structure. La structure est placée dans un tube de verre 7 autour duquel est disposé un inducteur de moyenne fréquence 8 par exemple. La structure est constituée en fait de deux structures simples juxtaposées comportant des saillies 5 uniquement sur un de leurs côtés et présente par conséquent une configuration telle que les deux canaux 4 sont adjacents. Par un des deux canaux 4a on introduit le liquide ou gaz chaud ou froid par l'intermédiaire de la canalisation 11, puis il est évacué, via la liaison tubulaire 9, dans le second canal 4b, et rejeté enfin à l'extérieur par la canalisation 10.According to Figure 2, there is shown an application of the structure. The structure is placed in a
La mise en oeuvre du procédé de dépôt de la zéolithe 6 est réalisée de la manière suivante :The zeolite 6 deposition process is carried out as follows:
On comble les espaces 3 par des lamelles plastiques précitées. On introduit ensuite la zéolithe 6 dans les espaces 2. Puis on place la structure dans un bain contenant une solution telle que celle utilisée dans le FR-A-2 443 485. Une fois le dépôt de zéolithe réalisé sur les faces de saillies 5, on retire la structure du bain et on ôte les lamelles de plastique. On introduit alors la structure dans un four à une température de l'ordre de 300°C pour réaliser le frittage de la zéolithe 6. On obtient alors un dépôt peu épais (0,1 à 0,5 mm) de zéolithe 6 sur deux des faces de chaque saillie 5, dépôt continu car les granulés ou grains de zéolithe sont aussi collés les uns aux autres mais pas complètement : on remarque ainsi des espaces entre deux grains ou granulés, ce qui favorise ainsi le passage du gaz ou liquide pour le refroidissement et/ou le chauffage d'une enceinte. Les espaces 2 sont aussi remplis de zéolithe (voir figures 1a et 1b). Par conséquent, lors de l'utilisation de la structure, l'absence de zéolithe 6 sur les deux autres faces des saillies 5 va favoriser l'accélération de la vitesse de réactivité de la zéolithe 6. Cette vitesse est accélérée car le dépôt de zéolithe 6 effectué uniquement sur les deux faces des saillies 5 présente une très faible épaisseur (entre 0,1 et 0,5 mm) favorisant donc les échanges et accélérant les opérations de refroidissement/chaufffage. En outre, la disposition des billes ou granulés de zéolithe (6) collés en partie seulement les uns aux autres va aussi favoriser les échanges : le liquide ou le gaz passe entre les billes ou les granulés, accélérant ainsi la vitesse de réactivité de la zéolithe 6. Lesdites saillies 5 peuvent être comparées à des puits de chaleur.The
Selon la figure 2, le chauffage de la structure disposée dans un tube de verre est accéléré par l'inducteur de moyenne fréquence 8, favorisant ainsi la vitesse de réactivité de la zéolithe 6.According to FIG. 2, the heating of the structure placed in a glass tube is accelerated by the
Cette structure est particulièrement adaptée pour les dispositifs de chauffage et/ou de refroidissement du type réfrigérateur mais aussi pour la climatisation de véhicules.This structure is particularly suitable for heating and / or cooling devices of the refrigerator type but also for air conditioning of vehicles.
Claims (10)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9009907A FR2665516A1 (en) | 1990-08-02 | 1990-08-02 | PARTICULAR STRUCTURE FOR ACCELERATING THE REACTIVITY SPEED OF THE ZEOLITE AND METHOD OF DEPOSITING THE ZEOLITE ON THE SAME. |
| FR9009907 | 1990-08-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0470886A1 true EP0470886A1 (en) | 1992-02-12 |
Family
ID=9399369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP91402107A Ceased EP0470886A1 (en) | 1990-08-02 | 1991-07-26 | Specific structure for accelerating the reactivity speed of zeolite and method for depositing zeolite on said structure |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0470886A1 (en) |
| JP (1) | JPH05133659A (en) |
| FR (1) | FR2665516A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994011685A1 (en) * | 1992-08-14 | 1994-05-26 | Rocky Research | Improved method and apparatus for achieving high reaction rates |
| EP0669161A2 (en) * | 1994-02-23 | 1995-08-30 | ZEO-TECH Zeolith Technologie GmbH | Coating of adsorption agent on metals and its process of fabrication |
| US5598721A (en) | 1989-03-08 | 1997-02-04 | Rocky Research | Heating and air conditioning systems incorporating solid-vapor sorption reactors capable of high reaction rates |
| US5628205A (en) * | 1989-03-08 | 1997-05-13 | Rocky Research | Refrigerators/freezers incorporating solid-vapor sorption reactors capable of high reaction rates |
| US5666819A (en) * | 1989-03-08 | 1997-09-16 | Rocky Research | Rapid sorption cooling or freezing appliance |
| AT410716B (en) * | 2001-02-23 | 2003-07-25 | Vaillant Gmbh | ADSORBER / DESORBER FOR A ZEOLITH HEATER |
| WO2012085716A1 (en) * | 2010-12-22 | 2012-06-28 | International Business Machines Corporation | Solid sorption refrigeration |
| WO2015104719A3 (en) * | 2014-01-10 | 2015-09-17 | Bry Air (Asia) Pvt. Ltd. | Hybrid adsorber heat exchanging device and method of manufacture |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9613211D0 (en) * | 1996-06-24 | 1996-08-28 | Johnson Matthey Plc | Improvements in heat transfer materials |
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|---|---|---|---|---|
| US1622522A (en) * | 1923-11-06 | 1927-03-29 | Nat Refrigerating Company | Refrigeration |
| US1814358A (en) * | 1928-03-01 | 1931-07-14 | Wright Leonard Kay | Refrigeration apparatus |
| GB379391A (en) * | 1930-05-31 | 1932-09-01 | Electrolux Ltd | Improvements in or relating to the operation of absorption refrigerating apparatus |
| FR754099A (en) * | 1932-04-11 | 1933-10-30 | ||
| FR804937A (en) * | 1935-06-13 | 1936-11-05 | Absorber-boiler usable in particular for refrigerating machines with dry absorption and periodic operation | |
| FR835049A (en) * | 1937-03-11 | 1938-12-09 | Siemens Ag | Absorber-cooker for periodic absorption devices |
| FR2443485A1 (en) * | 1978-12-06 | 1980-07-04 | Rhone Poulenc Ind | Deposit of adsorbent layer e.g. of zeolite or alumina on support - giving prod. used for recovery of solar energy |
| EP0131270A1 (en) * | 1983-07-08 | 1985-01-16 | Schiedel GmbH & Co. | Absorber using a solid for an absorption cycle |
| FR2593588A1 (en) * | 1986-01-28 | 1987-07-31 | Nishiyodo Air Conditioner | REFRIGERATED MACHINE WITH ADSORPTION |
| FR2604100A1 (en) * | 1986-09-18 | 1988-03-25 | Simonny Roger | Enclosure device for adsorbers or vacuum evaporators |
-
1990
- 1990-08-02 FR FR9009907A patent/FR2665516A1/en not_active Withdrawn
-
1991
- 1991-07-26 EP EP91402107A patent/EP0470886A1/en not_active Ceased
- 1991-07-31 JP JP19167091A patent/JPH05133659A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1622522A (en) * | 1923-11-06 | 1927-03-29 | Nat Refrigerating Company | Refrigeration |
| US1814358A (en) * | 1928-03-01 | 1931-07-14 | Wright Leonard Kay | Refrigeration apparatus |
| GB379391A (en) * | 1930-05-31 | 1932-09-01 | Electrolux Ltd | Improvements in or relating to the operation of absorption refrigerating apparatus |
| FR754099A (en) * | 1932-04-11 | 1933-10-30 | ||
| FR804937A (en) * | 1935-06-13 | 1936-11-05 | Absorber-boiler usable in particular for refrigerating machines with dry absorption and periodic operation | |
| FR835049A (en) * | 1937-03-11 | 1938-12-09 | Siemens Ag | Absorber-cooker for periodic absorption devices |
| FR2443485A1 (en) * | 1978-12-06 | 1980-07-04 | Rhone Poulenc Ind | Deposit of adsorbent layer e.g. of zeolite or alumina on support - giving prod. used for recovery of solar energy |
| EP0131270A1 (en) * | 1983-07-08 | 1985-01-16 | Schiedel GmbH & Co. | Absorber using a solid for an absorption cycle |
| FR2593588A1 (en) * | 1986-01-28 | 1987-07-31 | Nishiyodo Air Conditioner | REFRIGERATED MACHINE WITH ADSORPTION |
| FR2604100A1 (en) * | 1986-09-18 | 1988-03-25 | Simonny Roger | Enclosure device for adsorbers or vacuum evaporators |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5441716A (en) * | 1989-03-08 | 1995-08-15 | Rocky Research | Method and apparatus for achieving high reaction rates |
| US5598721A (en) | 1989-03-08 | 1997-02-04 | Rocky Research | Heating and air conditioning systems incorporating solid-vapor sorption reactors capable of high reaction rates |
| US5628205A (en) * | 1989-03-08 | 1997-05-13 | Rocky Research | Refrigerators/freezers incorporating solid-vapor sorption reactors capable of high reaction rates |
| US5666819A (en) * | 1989-03-08 | 1997-09-16 | Rocky Research | Rapid sorption cooling or freezing appliance |
| WO1994011685A1 (en) * | 1992-08-14 | 1994-05-26 | Rocky Research | Improved method and apparatus for achieving high reaction rates |
| EP0669161A2 (en) * | 1994-02-23 | 1995-08-30 | ZEO-TECH Zeolith Technologie GmbH | Coating of adsorption agent on metals and its process of fabrication |
| EP0669161A3 (en) * | 1994-02-23 | 1995-09-20 | Zeolith Tech | |
| AT410716B (en) * | 2001-02-23 | 2003-07-25 | Vaillant Gmbh | ADSORBER / DESORBER FOR A ZEOLITH HEATER |
| WO2012085716A1 (en) * | 2010-12-22 | 2012-06-28 | International Business Machines Corporation | Solid sorption refrigeration |
| CN103270378A (en) * | 2010-12-22 | 2013-08-28 | 国际商业机器公司 | Solid sorption refrigeration |
| GB2499938A (en) * | 2010-12-22 | 2013-09-04 | Ibm | Solid sorption refrigeration |
| GB2499938B (en) * | 2010-12-22 | 2015-07-22 | Ibm | Solid sorption refrigeration |
| CN103270378B (en) * | 2010-12-22 | 2016-01-27 | 国际商业机器公司 | Solid adsorption refrigeration |
| US9855595B2 (en) | 2010-12-22 | 2018-01-02 | International Business Machines Corporation | Solid sorption refrigeration |
| US10688553B2 (en) | 2010-12-22 | 2020-06-23 | International Business Machines Corporation | Solid sorption refrigeration |
| WO2015104719A3 (en) * | 2014-01-10 | 2015-09-17 | Bry Air (Asia) Pvt. Ltd. | Hybrid adsorber heat exchanging device and method of manufacture |
| AU2015205332B2 (en) * | 2014-01-10 | 2018-08-23 | Bry Air (Asia) Pvt. Ltd. | Hybrid adsorber heat exchanging device and method of manufacture |
| US11859877B2 (en) | 2014-01-10 | 2024-01-02 | Bry-Air [Asia] Pvt. Ltd. | Hybrid adsorber heat exchanging device and method of manufacture |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2665516A1 (en) | 1992-02-07 |
| JPH05133659A (en) | 1993-05-28 |
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