EP0372539A3 - Polyol composition, polyisocyanate-based foams prepared therefrom and process for preparing the same - Google Patents

Polyol composition, polyisocyanate-based foams prepared therefrom and process for preparing the same Download PDF

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Publication number
EP0372539A3
EP0372539A3 EP19890122538 EP89122538A EP0372539A3 EP 0372539 A3 EP0372539 A3 EP 0372539A3 EP 19890122538 EP19890122538 EP 19890122538 EP 89122538 A EP89122538 A EP 89122538A EP 0372539 A3 EP0372539 A3 EP 0372539A3
Authority
EP
European Patent Office
Prior art keywords
polyisocyanate
polyol composition
preparing
same
based foams
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19890122538
Other languages
German (de)
French (fr)
Other versions
EP0372539A2 (en
EP0372539B1 (en
Inventor
Henri Jacobus Marie Grunbauer
Johan A. Thoen
Guido Freddy Smits
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23074922&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0372539(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of EP0372539A2 publication Critical patent/EP0372539A2/en
Publication of EP0372539A3 publication Critical patent/EP0372539A3/en
Application granted granted Critical
Publication of EP0372539B1 publication Critical patent/EP0372539B1/en
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/487—Polyethers containing cyclic groups
    • C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5033—Polyethers having heteroatoms other than oxygen having nitrogen containing carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/54—Polycondensates of aldehydes
    • C08G18/546—Oxyalkylated polycondensates of aldehydes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • External Artificial Organs (AREA)
  • Endoscopes (AREA)

Abstract

Rigid closed-cell polyisocyanate-based foams are prepared by the reaction of polyisocyanate with a polyol composition having an average hydroxyl number of 100 to 500 and comprising at least one polyol component containing from 4 to 8 active hydrogen atoms per molecule and having a hydroxyl number of from 100 to 500. The blowing of the foam is essentially with carbon dioxide generated from the reaction of water with polyisocyanate so as to provide foams of the desired density containing at least 40 mole percent carbon dioxide in their cells.
EP89122538A 1988-12-07 1989-12-06 Polyol composition, polyisocyanate-based foams prepared therefrom and process for preparing the same Revoked EP0372539B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/280,860 US4943597A (en) 1988-12-07 1988-12-07 Polyether polyol formulations for hard CFC replacement by water blowing in rigid polyurethane foams
US280860 1988-12-07

Publications (3)

Publication Number Publication Date
EP0372539A2 EP0372539A2 (en) 1990-06-13
EP0372539A3 true EP0372539A3 (en) 1991-01-23
EP0372539B1 EP0372539B1 (en) 1995-03-08

Family

ID=23074922

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89122538A Revoked EP0372539B1 (en) 1988-12-07 1989-12-06 Polyol composition, polyisocyanate-based foams prepared therefrom and process for preparing the same

Country Status (15)

Country Link
US (1) US4943597A (en)
EP (1) EP0372539B1 (en)
JP (1) JPH02251514A (en)
AT (1) ATE119554T1 (en)
BR (1) BR8906397A (en)
CA (1) CA2004727A1 (en)
DE (1) DE68921564T2 (en)
DK (1) DK615089A (en)
ES (1) ES2068880T3 (en)
FI (1) FI895823A0 (en)
MX (1) MX167973B (en)
NO (1) NO177314C (en)
NZ (1) NZ231622A (en)
PT (1) PT92505A (en)
YU (1) YU229189A (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0236217A (en) * 1988-07-27 1990-02-06 Hitachi Ltd Rigid polyurethane foam, its production, heat-insulating material and refrigerator manufactured therewith
JPH02248419A (en) * 1989-03-22 1990-10-04 M D Kasei Kk Production of heat-resistant urethane-modified polyisocyanurate foam
US5091438A (en) * 1989-07-14 1992-02-25 Takeda Chemical Industries, Ltd. Method of producing rigid urethane foam
EP0450197A1 (en) * 1990-04-02 1991-10-09 Shell Internationale Researchmaatschappij B.V. Foam formulations suitable for preparing water-blown heat-insulating material using polyols as softening point improvers and heat-insulating material obtained therewith
GB2244714B (en) * 1990-05-31 1993-10-06 Sanyo Chemical Ind Ltd Foamed polyurethane-forming composition,foamed polyurethane and process for making the same
US5373028A (en) * 1991-08-20 1994-12-13 The Dow Chemical Company Polyurethane foams having reduced visible emissions during curing
US5254601A (en) * 1991-09-20 1993-10-19 Miles Inc. HCEC blown rigid foams with low thermal conductivity
US5308885A (en) * 1991-09-20 1994-05-03 Miles Inc. HCFC blown rigid foams with low thermal conductivity
US5272183A (en) * 1991-09-20 1993-12-21 Miles Inc. HCFC blown rigid foams with low thermal conductivity
WO1994005718A1 (en) * 1992-08-27 1994-03-17 Stepan Company Process for production of low density water-blown rigid foams with flow and dimensional stability
US5332860A (en) * 1993-06-29 1994-07-26 The Dow Chemical Company Polyols useful for preparing polyurethane foams having improved retention of insulative properties, polyurethane foams prepared therewith and methods for the preparation thereof
US5690855A (en) * 1994-01-11 1997-11-25 Sealed Air Corporation Polyol blend, cellular polyurethane foam product made therefrom, and halogenated hydrocarbon-free process therefor
JP4610782B2 (en) * 2001-05-01 2011-01-12 日本ポリウレタン工業株式会社 Construction method of embankment and manufacturing method of polyurethane foam for civil engineering
US20030213189A1 (en) * 2002-05-16 2003-11-20 Goldman Arthur S. Thermoplastic polymer extrusion bending
EP1435366B1 (en) * 2003-01-03 2008-08-13 Dow Global Technologies Inc. Polyisocyanurate foam and process for its preparation
US6846850B2 (en) * 2003-01-22 2005-01-25 Bayer Materialscience Llc Rigid polyurethane foams with improved properties
US7151121B2 (en) * 2004-05-26 2006-12-19 Danisco A/S Polyurethane containing a polyol composition comprising a highly branched polysaccharide, mix and process for preparation thereof
US8258198B2 (en) * 2004-05-28 2012-09-04 Air Products And Chemicals, Inc. Fast demold/extended cream time polyurethane formulations
US20060122355A1 (en) * 2004-10-15 2006-06-08 O'connor James Derivatized highly branched polysaccharide and a mix for production of polyurethane thereof
DE102005025970A1 (en) 2005-06-03 2006-12-07 Basf Ag Porous polyisocyanate polyaddition products
RU2631250C2 (en) * 2012-03-15 2017-09-20 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Hard polyurethane with low density, exposed only under the action of water
PL3518924T3 (en) 2016-09-30 2023-01-09 Salix Pharmaceuticals, Inc. Solid dispersion forms of rifaximin
JP7258879B2 (en) * 2017-11-28 2023-04-17 ダウ グローバル テクノロジーズ エルエルシー Polyurethane insulation board

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4273882A (en) * 1980-06-02 1981-06-16 Olin Corporation Preparation of thermally stable rigid polyurethane foam
US4585858A (en) * 1967-01-03 1986-04-29 Cpc International Inc. Starch-based polyether polyols
EP0308733A1 (en) * 1987-09-15 1989-03-29 Bayer Ag Process for the preparation of rigid polyurethane foams

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3865806A (en) * 1970-12-28 1975-02-11 Dow Chemical Co Low viscosity, low equivalent weight polyether polyols and a method for their preparation
JPS5432479B2 (en) * 1973-11-28 1979-10-15
JPS53130800A (en) * 1977-04-21 1978-11-15 Dai Ichi Kogyo Seiyaku Co Ltd Preparation of new flame retardant polyurethane foam

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4585858A (en) * 1967-01-03 1986-04-29 Cpc International Inc. Starch-based polyether polyols
US4273882A (en) * 1980-06-02 1981-06-16 Olin Corporation Preparation of thermally stable rigid polyurethane foam
EP0308733A1 (en) * 1987-09-15 1989-03-29 Bayer Ag Process for the preparation of rigid polyurethane foams

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 90, no. 14, April 1979, page 41, abstract no. 104906z, Columbus, Ohio, US; & JP-A-53 130 800 (DAIICHI KOGYO SEIYAKU CO., LTD) 15-11-1978 *
KUNSTSTOFFE, vol. 72, no. 2, May 1982, pages 279-282, Munich, DE; W. KLINGELHÖFER: "Alternativen zu Fluorkohlenwasserstoff als Treibmittel für Polyurethan-Hartschaumsysteme" *

Also Published As

Publication number Publication date
NO894877D0 (en) 1989-12-06
PT92505A (en) 1990-06-29
CA2004727A1 (en) 1990-06-07
NZ231622A (en) 1991-05-28
DE68921564D1 (en) 1995-04-20
FI895823A0 (en) 1989-12-05
NO177314B (en) 1995-05-15
US4943597A (en) 1990-07-24
ATE119554T1 (en) 1995-03-15
DE68921564T2 (en) 1995-07-13
DK615089D0 (en) 1989-12-06
NO894877L (en) 1990-06-08
MX167973B (en) 1993-04-26
DK615089A (en) 1990-06-08
YU229189A (en) 1991-02-28
EP0372539A2 (en) 1990-06-13
BR8906397A (en) 1990-08-28
NO177314C (en) 1995-08-23
EP0372539B1 (en) 1995-03-08
JPH02251514A (en) 1990-10-09
ES2068880T3 (en) 1995-05-01

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