EP0333143A2 - Savons biocides - Google Patents
Savons biocides Download PDFInfo
- Publication number
- EP0333143A2 EP0333143A2 EP89104542A EP89104542A EP0333143A2 EP 0333143 A2 EP0333143 A2 EP 0333143A2 EP 89104542 A EP89104542 A EP 89104542A EP 89104542 A EP89104542 A EP 89104542A EP 0333143 A2 EP0333143 A2 EP 0333143A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- biocidal
- liquid
- cleaning agent
- aminopropyl
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
Definitions
- Liquid detergents with a biocidal action which contain a tertiary alkylamine as an active ingredient, have hitherto not been known.
- a combination of the good cleaning action of anionic surfactants with the broad spectrum of microbicides and the high effectiveness of the aliphatic amines would be desirable.
- the object of the invention is to provide liquid cleaning agents based on anionic surfactants with a biocidal effect.
- a liquid biocidal cleaning agent which essentially consists of N, N-bis (3-aminopropyl) laurylamine and an anionic cleaning component or contains these components.
- the active ingredient N, N-bis (3-aminopropyl) laurylamine is preferably used in pure form; however, it is also possible to use mixtures with other N, N-bis (3-aminopropyl) alkylamines if these contain sufficient amounts of N, N-bis (3-aminopropyl) laurylamine.
- Such mixtures can be produced, for example, from corresponding technical fatty amine mixtures, such as, in particular, coconut amine, by known processes.
- Soaps such as sodium stearate, potassium stearate or triethanolamine are preferably found as the anionic cleaning component of the liquid, biocidal cleaning agents according to the invention soaps, sulphonated aromatic hydrocarbons such as n-alkylbenzene sulfonates, sulfonated aliphatic hydrocarbons such as secondary alkane sulfonates, sulfonated ⁇ -olefins, sulphated fatty alcohols such as sodium lauryl sulphate, sulphated fatty alcohol ethers such as Natriumlaurylpolyglykolethersulfat, sulfonated fatty acid methyl ester, as Palmkernsulfofettklamethylester, sulfonated maleic acid esters, such as lauryl, or carboxymethylated Fatty alcohol polyglycol ethers, such as lauryl polyglycol ether acetate, both individually and in combination, use.
- An additional solvent is preferably added to the liquid, biocidal cleaning agents according to the invention for easier handling and metering.
- biocidal cleaning agents As an additional solvent of the liquid, biocidal cleaning agents according to the invention, water or an alcohol with up to 4 C atoms, such as e.g. Methanol, ethanol, n-propanol, iso-propanol, n-butanol, iso-butanol, tert-butanol or sec-butanol, or a mixture of these.
- an alcohol with up to 4 C atoms such as e.g. Methanol, ethanol, n-propanol, iso-propanol, n-butanol, iso-butanol, tert-butanol or sec-butanol, or a mixture of these.
- the N, N-bis (3-aminopropyl) laurylamine as a biocidal active ingredient is preferably used in the form of a 20 to 40% aqueous solution in the preparation of the liquid, biocidal cleaning agents according to the invention, and the anionic cleaning component is preferably in the form of a 20 to 80% aqueous solution, so that the water contained in these components is simultaneously the solvent of the finished formulation represents.
- biocidal cleaning agents it is particularly advantageous to additionally use nonionic surfactants, such as fatty alcohol ethoxylates, alkylphenol ethoxylates, fatty acid ethoxylates, fatty acid alkylolamides, fatty acid alkylolamide ethoxylates, fatty amine ethoxylates or polyalkylene oxide block polymers or mixtures thereof.
- nonionic surfactants such as fatty alcohol ethoxylates, alkylphenol ethoxylates, fatty acid ethoxylates, fatty acid alkylolamides, fatty acid alkylolamide ethoxylates, fatty amine ethoxylates or polyalkylene oxide block polymers or mixtures thereof.
- the amount of solvent used in the production of the liquid, biocidal cleaning agent according to the invention is not critical.
- biocidal cleaning agents which contain solvents such as water or alcohol, 10 to 90% by weight, based on the finished formulation, of solvents are advantageously used.
- biocidal cleaning agents according to the invention, the addition of ethylenediaminetetraacetic acid, nitrilotriacetic acid, phosphonic acids or polycarboxylic acids or salts of the acids, silicates, phosphates, sodium cumene sulfonate or alkalis is also expedient.
- the liquid, biocidal cleaning agents according to the invention can be used as disinfectant cleaners, for example in the food industry, in the kitchen area, or generally for hard surfaces.
- N, N-bis (3-aminopropyl) laurylamine (30% aqueous solution) 50% by weight
- Triethanolamine soap of unsaturated vegetable fatty acids (38% aqueous solution) 10% by weight
- a straight-chain ethoxylate with a degree of ethoxylation of approx. 7, a molar mass of approx. 470 and a hydroxyl number of approx. 120 7% by weight demineralised water 33% by weight
- the liquid, biocidal cleaning agent according to the invention was applied to its microbicidal formulation in the formulation according to the example given in accordance with the "Guidelines for the Testing and Assessment of Chemical Disinfection Methods" (status 1.1.1981) of the German Society for Hygiene and Microbiology, Gustav Fischer Verlag, Stuttgart, 1981 Properties as a surface disinfectant with cleaning properties have been investigated and are effective as surface disinfectants based on the "in vitro tests” and the “tests under practical conditions” in accordance with the "Requirements for inclusion in the VII. List of the German Society for Hygiene and Microbiology" to watch.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1035/88 | 1988-03-18 | ||
CH1035/88A CH675429A5 (fr) | 1988-03-18 | 1988-03-18 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0333143A2 true EP0333143A2 (fr) | 1989-09-20 |
EP0333143A3 EP0333143A3 (en) | 1990-03-28 |
EP0333143B1 EP0333143B1 (fr) | 1994-08-03 |
Family
ID=4200927
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89104542A Expired - Lifetime EP0333143B1 (fr) | 1988-03-18 | 1989-03-14 | Savons biocides |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0333143B1 (fr) |
AT (1) | ATE109501T1 (fr) |
CH (1) | CH675429A5 (fr) |
DE (1) | DE58908124D1 (fr) |
ES (1) | ES2056985T3 (fr) |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0385369A2 (fr) * | 1989-02-27 | 1990-09-05 | Lonza Ag | Méthode de conservation antimicrobienne des tensioactifs |
EP0551975A1 (fr) * | 1992-01-17 | 1993-07-21 | SCHÜLKE & MAYR GMBH | Concentré désinfectant et agent désinfectant basé sur des amines et des alcools et leur usage |
DE4306344C1 (de) * | 1993-02-25 | 1994-08-04 | Schuelke & Mayr Gmbh | Desinfektionsmittelkonzentrat und Desinfektionsmittel auf Amin- und Alkoholbasis |
FR2701037A1 (fr) * | 1993-01-29 | 1994-08-05 | Hakawerk H Kunz Gmbh | Détergents pour articles textiles en fibres de polychlorure de vinyle. |
EP0620013A2 (fr) * | 1993-04-15 | 1994-10-19 | Bode Chemie GmbH & Co. | Désinfectant pour systèmes de toilettes à réservoir et autres équipements |
WO1995000613A1 (fr) | 1993-06-28 | 1995-01-05 | Henkel-Ecolab Gmbh & Co. Ohg | Nettoyant desinfectant |
WO1997001621A1 (fr) * | 1995-06-27 | 1997-01-16 | The Procter & Gamble Company | Procede de nettoyage et d'assainissement, compositions et/ou articles destines a des surfaces non alimentaires et inanimees |
WO1997043368A1 (fr) * | 1996-05-10 | 1997-11-20 | Unilever N.V. | Composition nettoyante et/ou desinfectante |
EP0835064A1 (fr) * | 1995-06-27 | 1998-04-15 | The Procter & Gamble Company | Procedes de nettoyage/desinfection, compositions et/ou articles pour produits agricoles |
EP0848907A1 (fr) * | 1996-12-21 | 1998-06-24 | B. Braun Medical AG | Préparation désinfectante pulvérisable |
DE19749964A1 (de) * | 1997-11-04 | 1999-05-06 | Ulrich Grajecki Gmbh & Co Dipl | Waschlösung für die Getränke- und Lebensmittelindustrie |
WO2002023990A1 (fr) * | 2000-09-20 | 2002-03-28 | Lonza Ag | Désinfectants |
WO2004003126A1 (fr) * | 2002-06-27 | 2004-01-08 | Ecolab Inc. | Agent de desinfection moussant |
DE19722757B4 (de) * | 1997-05-31 | 2005-12-01 | Bode Chemie Gmbh & Co. Kg | Aldehydfreie Desinfektionsmittel für Flächen und Instrumente |
WO2015026268A1 (fr) | 2013-08-20 | 2015-02-26 | Limited Liability Company "Nearmedic Plus" | Réactif permettant l'inactivation de micro-organismes, l'extraction et le stockage d'adn bactérien sous forme appropriée pour des diagnostics moléculaires extrêmement efficaces |
WO2018089761A1 (fr) * | 2016-11-11 | 2018-05-17 | Lonza Inc. | Composition désinfectante ayant des propriétés biocides résiduelles |
EP3542628A1 (fr) * | 2018-03-22 | 2019-09-25 | Chemische Fabrik Dr. Weigert GmbH & Co. KG | Désinfectant et utilisation de n, n-bis(3-aminopropyl)alkylamine dans les désinfectants |
WO2021195015A1 (fr) * | 2020-03-23 | 2021-09-30 | Ecolab Usa Inc. | Nouvelles compositions 2 en 1 de désinfection et d'adjuvant de rinçage utilisant des tensioactifs à base d'amine dans le lavage de la vaisselle en machine |
US11432545B2 (en) | 2017-06-05 | 2022-09-06 | Arxada, LLC | Fast kill disinfectant wiping composition and premoistened wipes made from same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023067109A1 (fr) * | 2021-10-21 | 2023-04-27 | Arxada Ag | Composition de nettoyage désinfectante à base de triamine |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3717579A (en) * | 1970-10-05 | 1973-02-20 | Goldschmidt Ag Th | Biocidal preparation |
DE3145733A1 (de) * | 1981-11-19 | 1983-05-26 | Hoechst Ag, 6230 Frankfurt | Bis-betaine, verfahren zur deren herstellung und diese enthaltende reinigungsmittel |
EP0080137A1 (fr) * | 1981-11-19 | 1983-06-01 | Hoechst Aktiengesellschaft | Bis-bétaine amineoxydes, procédés de préparation et agents de nettoyage les contenant |
EP0149174A1 (fr) * | 1983-12-30 | 1985-07-24 | Hoechst Aktiengesellschaft | Composés amphotères, mélanges contenant ces composés pour le nettoyage désinfectant et procédé pour la préparation de ces composés et de ces mélanges |
-
1988
- 1988-03-18 CH CH1035/88A patent/CH675429A5/de not_active IP Right Cessation
-
1989
- 1989-03-14 EP EP89104542A patent/EP0333143B1/fr not_active Expired - Lifetime
- 1989-03-14 DE DE58908124T patent/DE58908124D1/de not_active Expired - Lifetime
- 1989-03-14 ES ES89104542T patent/ES2056985T3/es not_active Expired - Lifetime
- 1989-03-14 AT AT89104542T patent/ATE109501T1/de not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3717579A (en) * | 1970-10-05 | 1973-02-20 | Goldschmidt Ag Th | Biocidal preparation |
DE3145733A1 (de) * | 1981-11-19 | 1983-05-26 | Hoechst Ag, 6230 Frankfurt | Bis-betaine, verfahren zur deren herstellung und diese enthaltende reinigungsmittel |
EP0080137A1 (fr) * | 1981-11-19 | 1983-06-01 | Hoechst Aktiengesellschaft | Bis-bétaine amineoxydes, procédés de préparation et agents de nettoyage les contenant |
EP0149174A1 (fr) * | 1983-12-30 | 1985-07-24 | Hoechst Aktiengesellschaft | Composés amphotères, mélanges contenant ces composés pour le nettoyage désinfectant et procédé pour la préparation de ces composés et de ces mélanges |
Cited By (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0385369A2 (fr) * | 1989-02-27 | 1990-09-05 | Lonza Ag | Méthode de conservation antimicrobienne des tensioactifs |
EP0385369A3 (fr) * | 1989-02-27 | 1992-01-02 | Lonza Ag | Méthode de conservation antimicrobienne des tensioactifs |
EP0551975A1 (fr) * | 1992-01-17 | 1993-07-21 | SCHÜLKE & MAYR GMBH | Concentré désinfectant et agent désinfectant basé sur des amines et des alcools et leur usage |
DE4201038A1 (de) * | 1992-01-17 | 1993-07-22 | Schuelke & Mayr Gmbh | Desinfektionsmittelkonzentrat und desinfektionsmittel auf amin- und alkoholbasis und deren verwendung |
US5393789A (en) * | 1992-01-17 | 1995-02-28 | Eastman Kodak Company | Amine-and alcohol-based disinfectant concentrate and disinfectant and use thereof |
FR2701037A1 (fr) * | 1993-01-29 | 1994-08-05 | Hakawerk H Kunz Gmbh | Détergents pour articles textiles en fibres de polychlorure de vinyle. |
DE4306344C1 (de) * | 1993-02-25 | 1994-08-04 | Schuelke & Mayr Gmbh | Desinfektionsmittelkonzentrat und Desinfektionsmittel auf Amin- und Alkoholbasis |
US5554656A (en) * | 1993-02-25 | 1996-09-10 | Reckitt & Colman Inc. | Disinfectant concentrates and disinfectants on amine and alcohol base and their use |
EP0620013A3 (fr) * | 1993-04-15 | 1996-06-05 | Bode Chemie Gmbh & Co | Désinfectant pour systèmes de toilettes à réservoir et autres équipements. |
DE4311840A1 (de) * | 1993-04-15 | 1994-10-20 | Bode Chemie Gmbh & Co | Desinfektionsmittel für Sammeltoilettensysteme und ähnliche Anlagen |
DE4311840C2 (de) * | 1993-04-15 | 1999-04-01 | Bode Chemie Gmbh & Co | Desinfektionsmittel für Sammeltoilettensysteme und ähnliche Anlagen |
EP0620013A2 (fr) * | 1993-04-15 | 1994-10-19 | Bode Chemie GmbH & Co. | Désinfectant pour systèmes de toilettes à réservoir et autres équipements |
FR2708278A1 (fr) * | 1993-06-28 | 1995-02-03 | Paragerm Snc | Composition nettoyante et désinfectante pour milieu hospitalier. |
TR27796A (tr) * | 1993-06-28 | 1995-08-29 | Henkel Ecolab Gmbh & Co Ohg | Temizleme ve dezenfeksiyon maddeleri. |
WO1995000613A1 (fr) | 1993-06-28 | 1995-01-05 | Henkel-Ecolab Gmbh & Co. Ohg | Nettoyant desinfectant |
WO1997001621A1 (fr) * | 1995-06-27 | 1997-01-16 | The Procter & Gamble Company | Procede de nettoyage et d'assainissement, compositions et/ou articles destines a des surfaces non alimentaires et inanimees |
US6613731B1 (en) | 1995-06-27 | 2003-09-02 | The Procter & Gamble Company | Cleaning/sanitizing methods, compositions, and/or articles for non-food inanimate surfaces |
EP0835064A1 (fr) * | 1995-06-27 | 1998-04-15 | The Procter & Gamble Company | Procedes de nettoyage/desinfection, compositions et/ou articles pour produits agricoles |
EP1146109A3 (fr) * | 1995-06-27 | 2001-10-24 | The Procter & Gamble Company | Procédés de nettoyage/desinfection, compositions et/ou articles destinés à des surfaces non alimentaires et inanimées |
EP1146109A2 (fr) * | 1995-06-27 | 2001-10-17 | The Procter & Gamble Company | Procédés de nettoyage/desinfection, compositions et/ou articles destinés à des surfaces non alimentaires et inanimées |
US6054139A (en) * | 1996-05-10 | 2000-04-25 | Diversey Lever Inc. | Cleaning and/or disinfecting composition |
WO1997043368A1 (fr) * | 1996-05-10 | 1997-11-20 | Unilever N.V. | Composition nettoyante et/ou desinfectante |
EP0848907A1 (fr) * | 1996-12-21 | 1998-06-24 | B. Braun Medical AG | Préparation désinfectante pulvérisable |
DE19722757C5 (de) * | 1997-05-31 | 2010-01-21 | Bode Chemie Gmbh | Aldehydfreie Desinfektionsmittel für Flächen und Instrumente |
DE19722757B4 (de) * | 1997-05-31 | 2005-12-01 | Bode Chemie Gmbh & Co. Kg | Aldehydfreie Desinfektionsmittel für Flächen und Instrumente |
DE19749964B4 (de) * | 1997-11-04 | 2004-05-13 | Dipl.-Ing. Ulrich Grajecki (Gmbh & Co) | Waschlösung für die Getränke- und Lebensmittelindustrie |
DE19749964A1 (de) * | 1997-11-04 | 1999-05-06 | Ulrich Grajecki Gmbh & Co Dipl | Waschlösung für die Getränke- und Lebensmittelindustrie |
JP2004509138A (ja) * | 2000-09-20 | 2004-03-25 | ロンザ ア−ゲ− | 消毒剤 |
EP1671541A1 (fr) * | 2000-09-20 | 2006-06-21 | Lonza Ag | Désinfectant |
WO2002023990A1 (fr) * | 2000-09-20 | 2002-03-28 | Lonza Ag | Désinfectants |
US6939840B2 (en) | 2000-09-20 | 2005-09-06 | Lonza Ag | Disinfectant |
WO2004003126A1 (fr) * | 2002-06-27 | 2004-01-08 | Ecolab Inc. | Agent de desinfection moussant |
US8097265B2 (en) | 2002-06-27 | 2012-01-17 | Ecolab Usa Inc. | Foam disinfectant |
EA032990B1 (ru) * | 2013-08-20 | 2019-08-30 | Общество С Ограниченной Ответственностью "Ниармедик Плюс" | Реагент для обработки и хранения биологического образца |
WO2015026268A1 (fr) | 2013-08-20 | 2015-02-26 | Limited Liability Company "Nearmedic Plus" | Réactif permettant l'inactivation de micro-organismes, l'extraction et le stockage d'adn bactérien sous forme appropriée pour des diagnostics moléculaires extrêmement efficaces |
WO2018089761A1 (fr) * | 2016-11-11 | 2018-05-17 | Lonza Inc. | Composition désinfectante ayant des propriétés biocides résiduelles |
US10149471B2 (en) | 2016-11-11 | 2018-12-11 | Lonza Inc. | Disinfectant composition having residual biocidal properties |
US10631537B2 (en) | 2016-11-11 | 2020-04-28 | Lonza Llc | Disinfectant composition having residual biocidal properties |
US11432545B2 (en) | 2017-06-05 | 2022-09-06 | Arxada, LLC | Fast kill disinfectant wiping composition and premoistened wipes made from same |
EP3542628A1 (fr) * | 2018-03-22 | 2019-09-25 | Chemische Fabrik Dr. Weigert GmbH & Co. KG | Désinfectant et utilisation de n, n-bis(3-aminopropyl)alkylamine dans les désinfectants |
WO2021195015A1 (fr) * | 2020-03-23 | 2021-09-30 | Ecolab Usa Inc. | Nouvelles compositions 2 en 1 de désinfection et d'adjuvant de rinçage utilisant des tensioactifs à base d'amine dans le lavage de la vaisselle en machine |
CN115038333A (zh) * | 2020-03-23 | 2022-09-09 | 埃科莱布美国股份有限公司 | 在器皿清洗中使用胺基表面活性剂的新型2合1杀菌漂洗助剂组合物 |
US11718813B2 (en) | 2020-03-23 | 2023-08-08 | Ecolab Usa Inc. | 2-in-1 sanitizing and rinse aid compositions employing amine based surfactants in machine warewashing |
Also Published As
Publication number | Publication date |
---|---|
ES2056985T3 (es) | 1994-10-16 |
EP0333143A3 (en) | 1990-03-28 |
ATE109501T1 (de) | 1994-08-15 |
EP0333143B1 (fr) | 1994-08-03 |
CH675429A5 (fr) | 1990-09-28 |
DE58908124D1 (de) | 1994-09-08 |
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