EP0101961B1 - Schmelzhaftkleber und damit überzogene Klebestreifen für Wegwerfwindelverschlusssystem - Google Patents

Schmelzhaftkleber und damit überzogene Klebestreifen für Wegwerfwindelverschlusssystem Download PDF

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Publication number
EP0101961B1
EP0101961B1 EP83107522A EP83107522A EP0101961B1 EP 0101961 B1 EP0101961 B1 EP 0101961B1 EP 83107522 A EP83107522 A EP 83107522A EP 83107522 A EP83107522 A EP 83107522A EP 0101961 B1 EP0101961 B1 EP 0101961B1
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EP
European Patent Office
Prior art keywords
weight
styrene
copolymer
tackifying resin
adhesive composition
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Expired
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EP83107522A
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English (en)
French (fr)
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EP0101961A1 (de
Inventor
Peter J. Butch Iii
Paul P. Puletti
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Ingredion Inc
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National Starch and Chemical Corp
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/387—Block-copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/28—Non-macromolecular organic substances
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/913—Material designed to be responsive to temperature, light, moisture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y10T428/2817—Heat sealable
    • Y10T428/2826—Synthetic resin or polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2883—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer of diene monomer [e.g., SBR, SIS, etc.]

Definitions

  • This invention relates to hot melt pressure sensitive adhesive compositions, particularly to hot melt pressure sensitive adhesive compositions suitable for coating on tapes or labels and most particularly on tapes to be used as closures for disposable diapers.
  • Disposable diapers typically comprise an absorbent filler material and an outer moisture-impervious polyethylene film.
  • the diapers are generally so configured that when they are placed on an infant, they are folded so that two adjacent edges are either juxtaposed or overlapped, with a strip of normally tacky and pressure-sensitive adhesive tape being used to hold the edges together.
  • Hot melt adhesives utilized heretofore for such applications have been based primarily on block copolymers, particularly those of the styrene-isoprene-styrene types, which copolymers are blended with tackifying resins, oils and antioxidants to provide the final adhesive product.
  • block copolymers particularly those of the styrene-isoprene-styrene types, which copolymers are blended with tackifying resins, oils and antioxidants to provide the final adhesive product.
  • Typical of such adhesives are those described in US-A-4 163 077.
  • the adhesives based on the styrene-isoprene-styrene copolymers possess good adhesion to a wide variety of substrates including the polyethylene diaper films, the adhesives are sensitive to oxidation and degradation both during processing and in use.
  • Other adhesive compositions, based on partially hydrogenated block copolymers are known to possess improved resistance to oxidation and degradation but are deficient when formulated into adhesives which are to be used in adhering polyolefin substrates.
  • the present invention provides hot melt pressure sensitives adhesive compositions which exhibit a combination of advantageous properties including adhesion to polyolefin substrates together with superior heat and oxidative resistance.
  • a unique combination of adhesion and heat and oxidative resistance properties can be achieved when a hot melt pressure sensitive adhesive is formulated using as a base resin a mixture of A-B-A type block copolymers, specifically a styrene-isoprenestyrene block copolymer together with a specific selectively hydrogenated block copolymer within critically defined ratios.
  • the hot melt pressure sensitive adhesive composition comprises:
  • An additional embodiment herein is a tape, particularly a tape for securing disposable diapers, which tape is coated with the pressure sensitive adhesive described above.
  • the first A-B-A block copolymer used herein is of the styrene-isoprene-styrene type. Typical copolymers and the synthesis thereof are taught in the US-A-3 239 478. It is to be stressed, however, that the copolymers useful herein are limited to those of the styrene-isoprene-styrene types and only to those wherein the isoprene component is present in amounts less than about 25% by weight of the total block copolymer.
  • copolymers are available commercially from Shell Chemical under the tradenames Kraton D1107; Kraton D1111 and Kraton D1112 and have styrene-isoprene ratios of 14:86, 21:79 and 15:85 respectively.
  • the second class of copolymers required herein is also of the A-B-A type but in these cases, the block copolymers are selectively hydrogenated as taught, for example, in the US-A-3 595 942 and in the US-A-3 700 633.
  • the base resin which is hydrogenated may be of the styrene-isoprene-styrene type or of the styrene-butadiene-styrene type, since the selective hydrogenation is effective in hydrogenating substantially all of the aliphatic double bonds provided by the elastomeric isoprene or ethylene-butylene block units.
  • the hydrogenated copolymers have a relatively low ratio of non-elastomeric A units to elastomeric B units and that the ratio be generally within the range required of the first A-B-A copolymer, i.e. that the non-elastomeric block A units are present in amounts less than about 25% by weight.
  • the only commercially available copolymer is a SEBS styrene-ethylene-butylene-styrene block copolymer provided by Shell Chemical under the tradename Kraton G1657 which has a ratio of non-elastomeric A units to elastomeric B units of about 14:86.
  • the total level of the block copolymers should range from 15 to 40, preferably 20-30%, by weight of the adhesive with the relative amounts of the first copolymer to the second copolymer within the weight range of 10:90 to 40:60, preferably 25:75 to 35:65, and most preferably 30:70.
  • the first copolymer is present in levels above about 40% of the mixture, a phasing in the melt occurs rendering the product non-uniform and unstable.
  • the performance of the adhesive on polyolefin substrates is unacceptable.
  • tackifying resins which are present in the hot melt adhesive used herein serve to extend the adhesive properties of the block copolymer.
  • the term "tackifying resin” includes: (1) natural and modified rosins such, for example, as gum rosin, wood rosin, talloil rosin, distilled rosin, hydrogenated rosin, dimerized rosin, and polymerized rosin; (2) glycerol and pentaerythritol esters of natural and modified rosins, such, for example, as the glycerol ester of pale wood rosin, the glycerol ester of hydrogenated rosin, the glycerol ester of polymerized rosin, the pentaerythritol ester of hydrogenated rosin, and the phenolic modified pentaerythritol ester of rosin; (3) polyterpene resins having a softening point, as determined by ASTM method E28 58T, of from 60
  • phenolic- modified terpene resins such, for example, as the resin product resulting from the condensation, in an acidic medium, of a bicyclic terpene and a phenol; (5) aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from 60° to 140°C., the latter resins resulting from the polymerization of monomers consisting primarily of olefins and diolefins as well as the hydrogenated derivatives thereof; (6) aromatic petroleum hydrocarbon resins and the hydrogenated derivatives thereof; and (7) aliphatic petroleum hydrocarbon resins and the hydrogenated derivatives thereof.
  • resins which are polymerized from a stream of aliphatic petroleum derivatives in the form of dienes and mono-olefins having 5 or 6 carbon atoms generally in accordance with the teachings of the US-A-3 577 398.
  • the resulting solid hydrocarbon resin consists essentially of polymerized structures derived from these aliphatic dienes and mono-olefins of 5 or 6 carbon atoms and since the dienes are more reactive, at least 40 percent by weight and preferably a major proportion of said structures are derived from the dienes.
  • the dienes are piperylene and/or isoprene. However, in some formulations, the percentage of isoprene is extremely low.
  • the molecular weight may range between 900 and 1300 with the mean number average molecular weight being about 1100.
  • This solid resin also has a softening point in the neighborhood of 100°C. In one preferred form, i.e., Wingtack 95 offered by Goodyear Chemical Company, the softening point is 95°C.
  • the plasticizing oils useful herein are of the naphthenic or paraffinic process oil variety. Also useful herein are the polyterpene-type tackifying resins which are liquid at room temperature. Typical of such liquid tackifiers is Wingtack 10 available from Goodyear Tire and Rubber Co. It consists essentially of polymerized structures derived from aliphatic dienes and mono-olefins of 5 or 6 carbon atoms, at least 40% by weight and preferably a major proportion, i.e. about 75%, of which are derived from piperylene orfrom piperylene and isoprene. The resin is liquid at 25°C, has a number average molecular weight of about 530 and appears to have at least about 25% unsaturation.
  • waxes particularly microcrystalline waxes, paraffin, synthetic low molecular weight polyethylene and Fischer-Tropsch waxes, may be used for further diluent properties or in order to reduce the melt viscosity or peel characteristics of the hot melt adhesive compositions without appreciably decreasing their adhesive binding characteristics. If used, they are generally present in levels of less than about 5% by weight of the total adhesive composition.
  • Hindered phenols are well known to those skilled in the art and may be characterized as phenolic compounds which also contain sterically bulky radicals in close proximity to the phenolic hydroxyl group thereof.
  • tertiary butyl groups generally are substituted onto the benzene ring in at least one of the ortho positions relative to the phenolic hydroxy group.
  • the presence of these sterically bulky substituted radicals in the vicinity of the hydroxyl group serves to retard its stretching frequency and correspondingly, its reactivity, this steric hindrance thus providing the phenolic compound with its stabilizing properties.
  • hindered phenols include: 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benziene; pentaerythrityl tetrakis-3-(3,5-di-tert-butyt-4-hydroxypherr/t)propionate, n-octadecyi-3-(3,5-di-tert-butyt-4-hydroxyphenyl)propionate, 4,4'-methylenebis(2,6-di-tert-buty,lphenol); 2,2'methylenebis(4-methyl-6-tert-butylphenol); 4,4'-thiobis(6-tert-butyl-o-cresol); 2,6-di-tert-butylphenol; 6-(4-hydroxyphenoxy)-2,4-bis(n-octyt- thio)-1,3,5-triazine); 2,4,6-tris(4-hydroxy-3,5-d
  • antioxidants may be further enhanced by utilizing, in conjunction therewith (1) synergists such, for example, as thiodipropionate esters and phosphites; and (2) chelating agents and metal deactivators such, for example, as ethylenediamine tetraacetic acid.
  • Optional additives may be incorporated into the hot melt compositions in order to modify certain properties thereof.
  • colorants such as titanium dioxide
  • fillers such as talc and clay.
  • the hot melt pressure sensitive adhesives taught herein typically contain the mixture of block copolymers in amounts from 15 to 40%, preferably 20-30%; the tackifying resin in amounts from 30 to 70%, preferably 50-60%; the oil or liquid tackifying resin in amounts of at least 5%, preferably 15-25%, and the antioxidant in amounts of 0.5 to 2%, preferably about 0.5%, the latter concentrations being based on a 100% solids total weight of the hot melt composition.
  • hot melt pressure sensitive adhesive compositions may be formulated using techniques known in the art.
  • An exemplary procedure involves placing approximately half of the total tackifying resin concentration in a jacketed mixing kettle, preferably in a jacketed heavy duty mixer of the Baker-Perkins or Day type, which is equipped with rotors and thereupon raising the temperature to a range of from 121-177°C (250-350°F), the precise temperature utilized depending on the melting point of the particular tackifying resin.
  • stirring is initiated and the block polymer and stabilizer are added together with any optional additives whose presence may be desired, the addition of the latter components being extended over a prolonged period in order to avoid the formation of lumps.
  • the resultant hot melt adhesives are generally produced with an oil in bulk form and packaged in release coated tube or boxes.
  • a number of methods which may be employed to coat the resulting hot melt pressure-sensitive adhesive composition onto a flexible backing sheet to form a pressure sensitive sheet or tape For instance, coating techiques such as hot reverse roll coating, hot gravure coating and hot knife coating may be employed. Furthermore, these techniques may be varied such as by using a hot roller or rod in place of a conventional blade in the so-called knife coating process.
  • a preferred technique is to pump the hot melt composition through a hot die and then wipe the sheet over the die to pick up an adhesive layer of the desired weight or thickness.
  • the amount of adhesive applied to the sheet by the technique will depend upon the die opening and internal pressure and the speed of the sheet passing the die.
  • the tapes prepared thereby may be either structures in which the adhesive is firmly bonded to a conventional backing or a structure in which the adhesive is removably bonded to the release-coated surface of a backing, the latter type being known as "transfer tapes".
  • the backing substrate itself may be any of the conventionally employed materials such as polypropylene or treated crepe paper.
  • the hold was measured at room temperature, i.e. 25°C., by noting the time in hours that it takes for a 1.27 cm. (0.5 in.) wide strip of tape to be pulled from a stainless steel plate by a 1000 g. weight attached to the bottom of the tape.
  • This example illustrates the preparation of hot melt pressure sensitive adhesive compositions using varying ratios of the two block copolymer components.
  • Irganox is the tradename of the Ciba-Geigy Co. for a high molecular weight multifunctional antioxidant (2,2-bis[3-[3,5-bis(1,1 -dimethylethyl)-4-hydroxyphenyl]-1-oxopropoxy]methyl]-1,3-propanediyl 3,5-bis(1,1-dimethylethyl)-4-hydroxy- benzenepropanoate). Heating and stirring were continued until a homogeneous mass was obtained whereupon the remainder of the tackifying resin and the oil were admixed therewith. The molten mixture was then poured into a siliconized paper tube and cooled to room temperature.
  • This example shows a variation in the ratio of the total rubber content (i.e. the mixture of the two block copolymers) to the resin and oil used in the adhesives of the invention.
  • the amounts and tests results are shown in Table II.
  • an adhesive was prepared using formulation D of Table I and substituting a variety of different tackifying resins including Arkon P-85 (Arakawa) (hydrogenated aromatic resin) and Nirez 1115 (an alpha pinene resin). Comparable results were obtained, indicating a wide variety of tackifying resins can be used.

Claims (11)

1. Schmelzhaftkleberzusammensetzung, gekennzeichnet durch einen Gehalt von
a) 15 bis 40 Gew.-% einer Mischung eines A-B-A-Styrol-Isopren-Styrol-Copolymers und eines selektiv hydrierten Block-Copolymers vom A-B-A-Typ, worin die nicht-elastomeren Block-A-Einheiten in beiden A-B-A-Copolymeren in Mengen von weniger als etwa 25 Gew.-% vorliegen und wobei das Gewichtsverhältnis des Styrol-Isopren-Styrol-Copolymers zu dem selektiv hydrierten Copolymer innerhalb des Bereiches von 10:90 bis 40:60 liegt;
b) 30 bis 70 Gew.-% eines klebrig-machenden Harzes,
c) mindestens 5 Gew.-% eines plastifizierenden Öls oder eines flüssigen klebrig-machenden Harzes vom Polyterpen-Typ;
wobei die Prozentangaben zu den obigen Merkmalen den Mengenanteil des folgenden Bestandteils d) nicht einschließen;
d) 0,05 bis 2,0 Gew.-% eines Antioxidationsmittels, wobei die letztere Konzentration auf 100% Feststoffgesamtgewicht der Schmelzhaftkleberzusammensetzung beruht.
2. Kleberzusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das Verhältnis der nicht-elastomeren Block-A-Einheiten zu den elastomeren Block-B-Einheiten in dem selektiv hydrierten Copolymer 14:86 ist.
3. Kleberzusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das Verhältnis des Styrol-Isopren-Styrol-Copolymers zu dem selektiv hydrierten Copolymer innerhalb des Bereiches von 25:75 bis 35:65 liegt.
4. Kleberzusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das Verhältnis des Styrol-Isopren-Styrol-Copolymers zu dem selektiv hydrierten Copolymer 30:70 ist.
5. Kleberzusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß die Zusammensetzung 20 bis 30% der Mischung des Block-Copolymers, 50 bis 60% des klebrig-machenden Harzes, 15 bis 25% des Öls oder des flüssigen klebrig-machenden Harzes und etwa 0,5% des Antioxidationsmittels enthält.
6. Kleberzusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das klebrig-machende Harz aus der Klasse ausgewählt worden ist, die besteht aus natürlichen und modifizierten Terpentinharzen, Glyzerin- und Pentaerythritestern natürlicher und modifizierter Terpentinharze, Polyterpenharzen eines Erweichungspunktes, bestimmt nach der ASTM Methode E28 58T, von 60 bis 140°C, aliphatischen Petroleumkohlenwasserstoffharzen eines Kugel-Ring-Erweichungspunktes von 60 bis 140°C und hydrierten Derivaten davon, aromatischen Petroleumkohlenwasserstoffharzen und hydrierten Derivaten davon und alicyclischen Petroleumkohlenwasserstoffharzen und den hydrierten Derivaten davon.
7. Kleberzusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das plastifizierende Öl ein naphthenisches oder paraffinisches Prozeßöl ist.
8. Kleberzusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das flüssige klebrig-machende Polyterpen-Harz im wesentlichen aus polymerisierten Strukturen, abgeleitet von aliphatischen Dienen und Monoolefinen von 5 oder 6 Kohlenstoffatomen, besteht.
9. Haftklebeband mit einer blattförmigen Verstärkung, die mit einer Schicht eines normalerweise klebigen Schmelzhaftklebers beschichtet ist, gekennzeichnet durch einen Gehalt von
a) 15 bis 40 Gew.-% einer Mischung eines A-B-A-Styrol-lsopren-Styrol-Copolymers und eines selektiv hydrierten Block-Copolymers vom A-B-A-Typ, worin die nicht-elastomeren Block-A-Einheiten in beiden A-B-A-Copolymeren in Mengen von weniger als etwa 25 Gew.-% vorliegen, wobei das Gewichtsverhältnis des Styrol-Isopren-Styrol-Copolymers zu dem selektiv hydrierten Copolymer innerhalb des Bereiches von 10:90 bis 40:60 liegt,
b) 30 bis 70 Gew.-% eines klebrig-machenden Harzes,
c) mindestens 5 Gew.-% eines plastifizierenden Öls oder des flüssigen klebrig-machenden Harzes vom Polyterpen-Typ,
wobei die Prozentangaben der vorgenannten Merkmale den Mengenanteil des folgenden Bestandteils d) nicht einschließen,
d) 0,05 bis 2,0 Gew.-% eines Antioxidationsmittels, wobei die letztere Konzentration auf 100% Feststoffgesamtgewicht der Schmelzhaftkleberzusammensetzung beruht.
10. Druckempfindliches Band nach Anspruch 9, dadurch gekennzeichnet, daß der Klebstoff 20 bis 30% der Mischung des Block-Copolymers, 50 bis 60% des klebrig-machenden Harzes, 15 bis.25% des Öls oder flüssigen klebrig-machenden Harzes und etwa 0,5% des Antioxidationsmittels enthält.
EP83107522A 1982-08-16 1983-07-30 Schmelzhaftkleber und damit überzogene Klebestreifen für Wegwerfwindelverschlusssystem Expired EP0101961B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/408,357 US4411954A (en) 1982-08-16 1982-08-16 Hot melt pressure sensitive adhesive and diaper tape closures coated therewith
US408357 1989-09-18

Publications (2)

Publication Number Publication Date
EP0101961A1 EP0101961A1 (de) 1984-03-07
EP0101961B1 true EP0101961B1 (de) 1986-04-16

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US (1) US4411954A (de)
EP (1) EP0101961B1 (de)
JP (1) JPS5949277A (de)
AU (1) AU540749B2 (de)
CA (1) CA1198538A (de)
DE (1) DE3363067D1 (de)

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US4761198A (en) * 1985-08-12 1988-08-02 National Starch And Chemical Corporation Use of a thermoplastic elastic adhesive for elastic banding
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JPH0329107B2 (de) 1991-04-23
AU540749B2 (en) 1984-11-29
JPS5949277A (ja) 1984-03-21
EP0101961A1 (de) 1984-03-07
US4411954A (en) 1983-10-25
AU1738683A (en) 1984-02-23
DE3363067D1 (en) 1986-05-22
CA1198538A (en) 1985-12-24

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