EP0087412A4 - Method and apparatus for mixing pulp with gases. - Google Patents

Abstract

Process and apparatus for mixing a wood pulp slurry with a chemical at the consistency at which the slurry exits a washer or the subsequent stem mixer, 7 to 15%. The chemicals would include non-condensable or unsaturated gases such as oxygen, ozone, air, chlorine, chlorine dioxide, sulfur dioxide, ammonia, nitrogen, carbon dioxide, hydrogen chloride, nitric oxide or nitrogen peroxide. Highly superheated steam can also be mixed with the pulp. In the process, the pulp slurry would pass through a mixing zone having a swept area in the range of 10,000 to 1,000,000 square meters per metric ton of oven dry pulp. The optimum is considered to be around 65,400 square meters per metric ton of oven dry pulp. An existing extraction stage within the system may be used as a source of alkali. In an existing extraction stage, the mixer (211) and upstream oxygen line (212) would be placed in the line between the steam mixer (206') and the extraction tower (213'). The oxygen may be inserted into the pulp slurry and mixed with the pulp slurry between a pair of washers (71', 91'). The second washer (91') may be a vacuum, pressure or diffusion washer. The oxygen may be inserted into the pulp slurry and mixed with the pulp slurry between a washer (91') and the subsequent storage tank (110'). Washed wood pulp from a continuous digester (14) may be treated with oxygen in the blow line (19) from the digester (14). Most of the treatment occurs within the mixer (40). Following mixing, the pulp may be taken to a subsequent process, a diffusion washer (24), or to a storage tank (24). The pulp is treated several times during a sequence. Some sequences are O-X-O and O-O-X-O in which X may be chlorine, chlorine dioxide, a combination of chlorine and chlorine dioxide and a hypochlorite, a peroxide or ozone. The sequence may be followed by a D stage. Other systems and specific mixer designs are also disclosed.

Description

METHOD AND APPARATUS FOR MIXING PULP WI-TH OXYGEN

BACKGROUND OF THE INVENTION ■*••> Field of the Invention

Apparatus and process for mixing chemicals with wood pulp or treating wood pulp with oxygen. 2- Review of the Prior Art The following definitions will be used in this application.

Pulping is the changing of wood chips or other wood particulate matter to fibrous form. Chemical pulping requires cooking -of the chips in ^" solution with a chemical, and includes partial removal of the coloring matter such as lignin associated with the wood. Bleaching is the treatment of cellulosic fibers to remove or alter the coloring matter associated with the fibers to allow the fiber to reflect white light more truly.

The standard symbols for pulping and bleaching sequences are: S = Sulfite K = Kraft

So = Soda C = Chlorine

H = .Sodium or calcium hypochlorite E = Alkali extraction, usually with sodium hydroxide D = Chlorine dioxide

P = Alkaline peroxide O = Oxygen

A = Acid pretreatment or post treatment

Consistency is the amount of pulp fiber in a slurry, expressed as a percentage of the total weight of the oven dry fiber and the solvent, usually water. It is sometimes called pulp concentration.

The consistency of the pulp will depend upon the type of dewatering equipment used. The following definitions are based on those found in Rydholm Pulping Processes, Interscience Publishers, 1965, pages 862-863 and TAPPI Monograph No. 27, The Bleaching of Pulp, Rapson editor, The Technical Association of Pulp and Paper Industry, 1963, pages 186-187.

V/IPO Low consistency is from 0-6%, usually between 3 and 5%. It is a suspension that is pumpable in an ordinary centrifugal-pump and is obtain¬ able using deckers and filters without press rolls.

Medium consistency is between 6 and 20%. Fifteen percent is a dividing point within the medium-consistency range. Below 15% the consistency can be obtained by filters. This is the consistency of the pulp mat leaving the vacuum drum filters in the brownstock washing system and the bleaching system. The consistency of a slurry from a washer, either a brownstock washer or a bleaching stage washer, is 9-13%. Above 15%, press rolls are needed for dewatering. Rydholm states that the usual range for medium consistency is 10-18%, while Rapson states it is 9-15%. The slurry is pumpable by special machinery even though it is still a coherent liquid phase at higher temperatures and under some compression.

High consistency is from 20-40%. Rydholm states that the usual range is 25-35% and Rapson states that the range is from 20-35%. These consistencies are obtainable only by presses. The liquid phase is completely absorbed by the fibers, and the pulp can be pumped only very short distances. For practical purposes, it is nonpumpable. Pulp quantity is expressed in several ways. Oven dry pulp is considered to be moisture free or bone dry. Its value is determined by drying the pulp in an oven at a temperature of 100 to 105°C until it reaches constant weight. It usually is considered to have reached constant weight after 2-* hours in the oven.

Air dry pulp is assumed to have a ten percent moisture content. One air-dry ton of pulp is equal to 0.9 oven-dry tons of pulp.

It also may be helpful in the understanding of the prior art to describe a typical pulp mill and relate the prior art oxygen bleaching systems as well as the present invention to this typical mill.

Figure 1A-1C is a diagram of a typical pulp mill. In the mill the means of transporting chips or pulp from one operation to another will depend upon the consistency of the pulp and the location of the equipment.

The transportation means may be a conveyer or a chute if the consistency is too high for the pulp or chips to be pumped, or a pipe if the pulp is capable of being pumped. Chips 10, process water II, steam 12 and pulping chemicals D are placed in a digester Ik. The wood chips 10 may be treated prior to entering

CM?I the digester Ik. This is optional. Exemplary of such treatment are presteaming of the chips in a steaming vessel or impregnation of the chips with the digestion chemicals in an impregnation vessel prior to entering the digester. The chemicals 13 will depend on the process being used, be it sulfate, sulfite, or soda, and the digester Ik may either be batch or continuous in operation. A continuous digester is shown. The chips will be cooked under appropriate conditions within the digester. These conditions, which depend on the species of chip and the type of pulping used, are well known. The products of the digestion process are the delignified or partially delignified wood chips, the spent pulping chemicals, and the lignin and carbohydrate products which have been removed from the wood chips in the digestion process. The treatment of the chips, after cooking, will depend in part on the type of digester being used. A major portion of the spent pulping chemicals and lignin products are removed from the chips prior to further processing. In the continuous digester shown, the chips are washed in the washing section of the digester. This is indicated b process water 15 entering and effluent stream 16 leaving the washing stage of digester Ik. The effluent 16 will consist of the lignin and carbohydrates which have been removed from the chips during the digestion process and the spent digestion chemicals. This effluent will be carried to a treating facility. In the case of kraft or sulfate pulp this would be a recovery system in which the liquor is burned to recover the digestion chemicals for reuse.

This washing would not take place in a batch digester. In a batch system, all the washing would occur in the following brownstock washing system.

Following this treatment, the chips will pass from the digester Ik through the blow line to storage or blow tank 22. It is customary in pulp mills to have storage tanks between separate processes so that the entire mill will not shut down if one section of the mill is shut down. Storage tank 22 is one such tank. It would be between the digester stage and the subsequent washing or bleaching stages. The storage tank 22 is open to the atmosphere and so is at atmospheric pressure.

Tank 22 may be a diffusion washer instead of a storage tank. Diffusion washers are described in Rydholm Pulping Processes, Interscience Publishers, 1965, pages 725-730 and illustrated in Figure 10.14 on page 728. The diffusion washer would be followed by a storage tank. The material passing through the blow line is a slurry which contains the remaining lignin and carbohydrates, ^"the spent digestion chemicals, and the fibers formed from the chips as they are blown from the digester. The chips will be formed into fibers when the pressure on the chips is partially released, usually at the outlet of digester Ik. The slurry will still be under some pressure to move it through the blow line. If the digester is continuous, then additional fiberizing may be done by a refiner, or refiners, in the blow line. The refiners will fiberize the large particles that have not been reduced to fibers earlier in the process. In the present diagram, two refiners - 18 and 19 - are shown. In the two-refiner system the first refiner 18 does course refining and the second refiner 19 does fine refining. The refiners are optional. They are usually encountered in a linerboard mill. The digester in a bleached pulp mill normally would not have refiners in the blow line. Neither would they be used with a batch digester.

The blow line is shown in three sections - section 17 between the digester Ik and refiner 18; section 20 between the refiners 18 and 19; and section 21 between the refiner 1 and the storage tank 22.

From the storage tank 22 the fibers and liquor are carried by pump 23 through line 2k to the washers and screens. The system will be described by following the pulp through the system, and then following the wash water through the system.

The pulp slurry is first carried to the brownstock washers 28 where the rest of the lignin and chemicals are removed from the fibers. Four washers are shown. This is the number that would normally be used with a batch digester. The washing section in a continuous digester would replace the first two brownstock washers. Each of these washers is usually a vacuum or pressure drum washer or vacuum or pressure drum filter and the operation of each is the same. The operation of a vacuum or pressure drum washer will be described. Some of the washers may, however, be diffusion washers. In a di fusion washer, the pulp slurry would not be diluted prior to entering the washer.

The pulp slurry from line 2k enters the vat 30 of washer 31. The vacuum drum 32 revolves through the vat, and the vacuum pulls the fibers in the slurry onto the outer surface of the filter drum and holds the fibers, in mat form, against the surface while pulling the liquor or filtrate through the filter cloth to the interior piping of the vacuum drum to be discharged as effluent. The revolving drum carries the fiber mat from the vat past a bank of washer heads that spray a weak filtrate onto the mat to displace the liquor from the mat. The vacuum also pulls this displaced liquid into the interior piping of the drum. The consistency of the mat leaving a washer, either the brownstock washers described here or the bleach washers described later, will usually be between 8 to 15%.

The pulp mat 33 is removed from the face of the drum 32 by a doctor blade, carrier wires or strings between the drum and the mat, rolls or any other standard manner and carried to the vat 50 of the second brownstock washer 51. Again, the fibers are picked up on vacuum drum 52. The pulp mat 53 is washed with still weaker filtrate, removed from the vacuum drum 52 and carried to the vat 70 of brownstock washer 71. The operation of this washer is the same as the others, the vacuum drum being 72 and the mat 73. The mat 73 is carried to the vat 90 of the last brownstock washer 91. Again, the operation of this washer is the same as the others, the vacuum drum being 92 and the mat 93.

From the brownstock washers the pulp mat 93 is carried to storage tank 110 with the aid of thick stock pump 96. In the lower section of tank 110, the pulp is diluted and then carried through line 111 by pump 112 to screens ID in which the larger fiber bundles and knots are removed. The bundles and knots 114 are carried to further treatment by suitable transpor¬ tation means.

The pulp 115 is carried from the screens 113 to the vat 120 of decker 121 in which additional water is removed. The operation of the decker is similar to that of the washers. Washing showers may or may not be used in the decker. The vacuum drum is 122 and the pulp mat is 123. The pulp 123 is carried by thick stock pump 126 to a high-density storage tank

140 in which it is stored until it is bleached. The liquor or filtrate from the vat 120 and the mat 123 flows through piping which extends radially from the vacuum chambers at the surface of the vacuum drum 122 to a pipe in the central shaft of the rotating drum. This liquor or filtrate passes through the central pipe and an external line 128 to a filtrate storage tank or seal tank 129. The tank 129 is called both a storage tank and a seal tank because it acts both to store the filtrate for further use and to seal the vacuum drum 122 from the outside

OMPI atmosphere to maintain the lower pressure of the vacuum system within the drum.

The filtrate from tank 129 may be handled in several ways. Several of the uses may occur simultaneously. Although the following description is specific to the effluent from tank 129, it is also illustrative of how the effluent from any of the washers in brownstock washing system 28 would be handled.

The following description is illustrative of how the ef luent from any of the washers would be handled. First, the filtrate from tank 129 is reused to reduce the consistency of the pulp slurry either entering the decker 121, entering the screens 113 or leaving storage tank 110. Line 130 carries the filtrate to lines 131, 133 and 135. Line Dl and pump D2 carry the filtrate back to screened pulp 115 to reduce the consistency of the pulp slurry entering vat 120 to around 1-1/2%. Line 133 and pump 134 carry the filtrate back to line 111 to reduce the consistency of the pulp slurry entering the screens ID to from 0.2 to 2%. Line 135 and pump D6 carry the filtrate back to storage tank 110 to reduce the consistency of the pulp slurry leaving the tank to around 5%.

Second, the filtrate not reused for dilution may be taken to an effluent treatment system by line 130 and effluent line 29. This treatment may include combining the effluent with the effluent in line 16, or carrying the effluent directly to the cooking liquor recovery system. It should be understood that in a batch digester system the digester effluent is recovered completely from the brownstock washing system while in a continuous digestion system only a portion of the digester effluent would be recovered from the brownstock washers.

All of the remaining filtrate would be handled as effluent if counterf low washing, to be described next, is not used. Some of the filtrate may be handled as effluent even if counterflow washing is used. Third, the filtrate from tank 129 may be used as wash water in the brownstock washing system 28 in a counterflow washing system. In this system, the filtrate flow is counter to the flow of pulp. The line 137 and pump 138 carry the filtrate back to brownstock washer 91 for use as wash water. The filtrate is sprayed on the pulp mat by washer heads 95 and displaces the liquor within the mat. This filtrate may also be sprayed on the carrier wires, strings or rolls after the pulp mat is separated from them to remove any pulp fibers that cling to the wires, strings or rolls if water instead of air is used for this operation. This is done by cleanup washer 94. Additional water may be required to supplement the filtrate. This is provided through process water line 97. The flow of filtrate through brownstock washer 91 is the same as the flow through decker 121. The liquor, either from the mat or the vat, is carried through internal piping to line 98 and through line 98 to filtrate storage tank or seal tank 99. Again, the filtrate from the seal tank 99 may be handled in a number of ways. Line 100 would carry it to effluent line 29. Line 101 and pump 102 would carry the filtrate to pulp 73 to reduce the consistency of the pulp slurry to 1 -1/2 to 3-1/2% as it enters vat 90. Line 103 and pump 104 would carry the filtrate^" to brownstock washer 71 to be used as wash water.

The process in brownstock washers 71, 51 and 31 are, for the most part, identical to the process in brownstock washer 91 so the parts are similarly numbered. The washer heads are 75, 55 and 35 respectively. The cleanup washers are 74, 54 and 34 respectively. The filtrate lines are 78, 58 and 38 and the filtrate storage or seal tanks are 73, 59 and 39. The filtrate lines from the seal tanks to effluent line 29 are 80, 60 and 40. The consistency of the slurry entering any of the vats 70, 50 or

30 should be 1-1/2 to 3-1/2%. The lines and pumps carrying the filtrate to the pulp to reduce the consistency of the slurry entering a vat are 81 and 82, 61 and 62, and 41 and 42, respectively. The counterflow wash water lines and pumps are 83 and 84, and 63 and 64. In brownstock washer 31, line 43 and pump 44 carry the filtrate into storage tank 22 to reduce the consistency of the pulp slurry in the bottom of the tank to 2 to 3-1/2% before it exits the tank.

In each of the brownstock washers, there is a possibility that additional process water may be needed to supplement the filtrate being used as wash water. Lines 77, 57 and 37 are for this purpose. These lines would provide all the wash water to the individual washers if the counter¬ flow system described above is not used and parrallel flow washing is used instead.

The washed pulp which has passed through the brownstock washing system 28, the screens 113 and decker 121 remains in storage tank 140 until it is carried into the bleaching system.

OMPI The bleaching process in Figure 1 will also be described by following the pulp stream through the bleaching system^* from washed pulp to bleached pulp and then by following the wash water from its entry into the process through to bleach plant effluent. The particular bleaching sequence illustrated is D EDED. The process conditions are taken from the TAPPI monograph The Bleaching of Pulp noted earlier.

There are many other bleaching sequences which could be used. Listings of these sequences may be found in the standard texts. As a rule, the first stage is chlorine and subsequent stages use chlorine dioxide, hydrogen peroxide, or a hypochlorite. These stages are interspersed with alkali extraction stages.

The pulp stored in high-density tank 140 normally is at a consistency of approximately 9 to 15%. This pulp slurry is carried from tank 140 through line 141 to tank 146 by pump 142. The pulp in line 141 is diluted with additional water or filtrate to a consistency of around 5%. In mixer 144 in line 141, the slurry is mixed with chlorine dioxide from line 145 as the D step of the first stage D bleach. If the first stage is to be chlorine alone, then this step would be omitted. The treated dilute slurry enters storage tank 146 in which the chlorine dioxide reacts with the unbleached pulp. The size of this tank will depend upon the amount of pulp being treated and the time of the chlorine dioxide treatment. The time of this initial treatment normally is one to five minutes. The slurry exits the tank into line 150 and is treated with chlorine.

Chlorine from line 151 and process water from line 152 are mixed in aspirator 153 and the diluted chlorine flows through line 154 to mixer 155 in which the chlorine is mixed with the dilute pulp slurry in line 150. The treated slurry is moved by pump 156 through line 150B into chlorine bleaching tower 157. The tower 157 is sized to allow the chlorine to react with the extraneous matter in the unbleached pulp. This retention or reaction time will depend, in part, on the water temperature. At minimum temperature, the TAPPI monograph suggests a retention time of about 45 to 60 minutes for sulfite pulp, and 60 to 90 minutes for kraft pulps. The treated slurry exits tank 157 and is carried through line 15S by pump 159.

The slurry in line 158 is combined with additional water or filtrate to reduce the consistency to about 1 to 1-1/2%. This dilute slurry flows into vat 160 of washer 161. Again a vacuum drum washer or filter is shown. The operation of this washer is the same as that of the brownstock washers. The vacuum drum 162 revolves through the vat. The vacuum pulls the fibers in the slurry onto the outer filter .surface of the drum and holds them against the surface, forming a mat, while pulling the liquid or filtrate through the filter cloth to the interior piping of the vacuum system in the drum to be discharged as effluent. The revolving drum 162 carries the fiber mat from the vat past a bank of washer heads which spray water or weak filtrate onto the mat to displace reaction products and unreacted chlorine entrained in the mat. The pulp mat 163 is removed from the face of drum 162. The means of removal is the same as in the brownstock washers - a doctor blade, carrier wires or strings between the drum and the mat, rolls or in any other standard manner. The pulp mat 163 is moved to mixer 166. This movement usually is by gravity fall through a chute from the washer to the mixer. Prior to leaving washer 161, the pulp mat 163 is impregnated with the caustic or alkali extraction solution from line 167. A sodium hydroxide solution is usually used. The alkali solution is applied to the mat just as it is leaving the vacuum drum 162 so that the solution will penetrate the pulp mat but not be carried through the mat into the washer effluent. The amount of alkali added, expressed as sodium hydroxide, will be 0.5 to 7% of the oven-dry weight of the pulp. The alkali may be added to the pulp in the steam mixer 166 instead of at the washer 161.

In steam mixer 166 the treated mat is mixed with steam from line 168 to raise the temperature of the pulp to approximately 62 C. The heated slurry is carried through line 169 into extraction tower 173 by high- density pump 170. In some cases transfer to the extraction tower is by gravity. The extraction tower may be downflow or upflow. The high- density pump 170 for either an upflow or a downflow tower may be at the base of the tower. The pulp would then be carried to the top of a downflow tower by an external line. The location of the pump in the plant is a matter of convenience. Support of the pump and access to the pump for maintenance are primary considerations. The slurry remains in tower 173 to allow the extraction solution to react with and extract the chlorinated materials from the pulp. This time may be one to two hours. Before leaving the extraction tower, the pulp slurry is mixed with water or filtrate in dilution zone 174 to reduce its consistency to

OM?I approximately 5%. The slurry is carried by line 175 and pump 176 from dilution zone 174 to the vat 180 of washer 181. Washer 181 is shown and described as a vacuum or pressure drum washer but it may be a diffusion washer. During its passage through line 175, the slurry is further diluted with water or filtrate until its consistency is approximately 1 to 1-1/2% when it reaches the vat 180. The operation of washer 181 is identical to that of washer 161. The fibers are picked up on the revolving drum 182, washed and removed as pulp mat 183.

The pulp is then moved to steam mixer 186 of the chlorine dioxide stage. This transfer may again be by gravity drop through a chute. Prior to leaving washer 181, the mat 183 is treated with a slight amount of alkali from line 187. A sodium hydroxide solution is usually used. It is added to the mat at a point on the drum which will allow the solution to stay in the mat and not pass into the filtrate. The purpose of this treatment is not further extraction but adjustment of the pH of the pulp prior to being treated with chlorine dioxide. The pH of the pulp should be in the range of 5 to 7, preferably 6, for optimum brightness when bleaching with chlorine dioxide. The alkali may be added in the steam mixer 186 instead of the washer 181. In steam mixer 186 the pulp 183 is mixed with steam from line

188. The pulp will have a consistency of approximately 1% less than from the washer when it leaves a steam mixer.

The pulp leaves steam mixer 186 and is carried through line 189 by pump 190 to mixer 191 in which it is combined with chlorine dioxide from line 192. It then enters chlorine dioxide tower 193. This tower usually is an up low-downflow tower. The pulp remains in the tower long enough to allow the -chlorine dioxide to react with it. The reaction is about complete after one hour but normally continues for up to four hours. Consequently, the retention time in the tower is usually four hours. Prior to leaving the tower, the slurry is diluted to a consistency of about 5% in dilution zone 194. It is also treated with a small amount of sulfur dioxide or alkali from line 197. The sulfur dioxide or alkali reacts with any excess chlorine dioxide so there will be no free chlorine dioxide emanating from the waster or the pulp leaving the washer. This diluted slurry is then carried by line 195 and pump 196 to vat

200 of washer 201. During its passage through line 195, the slurry is again diluted to a consistency of about 1 to 1-1/2% when it reaches vat 200, and again treated with additional sulfur dioxide from line 198. The pulp is picked up on vacuum drum 202, and the reaction products and unreacted bleaching chemicals washed rom it prior to being removed as pulp mat 203. This pulp is moved to the steam mixer 206 of the second extraction stage, usually by gravity drop through a chute. Again, sodium hydroxide from line 207 is added on washer 201 or at the mixer 206, and in mixer 206 the treated pulp mat 203 is mixed with steam from line 208. This slurry is then carried through line 209 by pump 210 to extraction tower 2D. The conditions in the extraction stage are the same as those in the first extraction stage. The tower may be downflow or upflow.

After the appropriate dwell time, the pulp enters dilution zone 214, and its consistency is reduced to approximately 5%. The pulp is then carried through line 215 by pump 216 to the vat 220 of washer 221. Washer 221 is also shown and described as a vacuum or pressure drum washer but it may be a diffusion washer. Again, it is diluted to a consistency of about 1 to 1 -1/2% before entering the vat. The slurry is picked up by vacuum drum 222 and washed and discharged as pulp mat 223. If necessary, the pH of the pulp may be adjusted by treating the mat with sodium hydroxide from line 227. This may occur on the drum 222 or in the steam mixer 226.

The pulp enters the last chlorine dioxide stage. The conditions and flow in this stage are the same as in the first chlorine dioxide stage. The pulp is dropped into or carried to steam mixer 226, and mixed with steam from line 228. The slurry is carried through line 229 by pump 230 to mixer 231, mixed with chlorine dioxide from line 232 and carried into the chlorine dioxide tower 233, shown as n upflow-downflow tower, where it remains for one to four hours. The pulp then enters dilution zone 234 where its consistency is reduced to about 5%. It is also treated with a small amount of sulfur dioxide from line 237 to remove any excess chlorine dioxide.

The slurry is carried from dilution zone 234 through line 235 by pump 236. During its travel through line 235, the pulp is again treated with additional sulfur dioxide or alkali from line 238 to remove any free chlorine dioxide and is further diluted so that the slurry is at a consistency of about 1 to 1-1/2% when it reaches vat 240 of washer 241. It is picked up by vacuum drum 242, washed and discharged from the bleaching system as bleached pulp 243.

OMPI uo Pulp from the mat usually adheres to the wire or strings -carrying the pulp mat from the washer and it is necessary to wash these fibers from the wires or strings into the vat prior to their contacting new fibers. This may be done by cleanup washer 164 on washer 161, cleanup washer 184 on washer 181, cleanup washer 204 on washer 201, cleanup washer 224 on washer 221, and cleanup washer 244 on washer 241. Air may also be used.

The passage of liquid through the washer is the same as in the brownstock washers. Wash water is sprayed onto the mat by the washer heads. This water displaces the entrained liquid within the pulp mat on the drum. The displaced liquid is carried through piping internally of the rotating vacuum drum to a pipe in the central shaft of the drum. Here, it is combined with the liquor being pulled into the drum from the washer vat. This combined liquor passes outwardly through a central pipe in the drum and an external line to a seal or storage tank which maintains the vacuum in the drum by providing a seal between the vacuum inside the drum and the ambient pressure externally of the drum.

In washer 161, process water from the washer heads 251 passes into the central shaft of vacuum drum 162, and outwardly through external

- line is 252 to seal or storage tank 253. In washer 181, the washer heads are 271, the external line is 272 and the seal or storage tank is 273. In washer 201, the washer heads are 291, the external line is 292, and the seal or storage tank is 293. In washer 221, the washer heads are 311, the external line is 312, and the seal or storage tank is 3D, and in washer 241 the washer heads are 331, the external line is 332, and the seal or storage tank is 333. The routes taken by the filtrate after it leaves the seal or storage tank are also the same as those in the brownstock washers.

First, the filtrate is used to dilute the slurry within the washing stage or a tower.

For example, the filtrate would dilute the pulp slurry being carried to the vat. The filtrate from the seal tank 253 of the chlorine stage washer 161 would be carried by line 255 and pump 256 into line 158 to be used to dilute the pulp slurry going to vat 160. In the same way, line 275 and pump 276, and line 277 and pump 278, carry the filtrate from the seal tank 273 of the first extraction stage washer 181 into line 175 to dilute the slurry going to vat 180; line 295 and pump 296, and line 297 and pump 298, carry the filtrate rom the seal tank 293 of the first chlorine dioxide stage

OMPI washer 201 into line 195 to dilute the slurry going to vat 200; line 315 and pump 316, and line 317 and pump 318, carry the filtrate from the seal tank 313 of the second extraction stage washer 221 into line 2D to dilute the slurry going to vat 220; and line 335 and pump 336, and line 337 and pump 338, carry the filtrate from the seal tank 333 of the second chlorine dioxide washer 241 into line 235 to dilute the slurry going to vat 240.

In the chlorine stage, line 259 and pump 260 also carry the filtrate to line 141 to dilute the pulp from high-density storage.

In the extraction and chlorine dioxide stages, the filtrate is also supplied to dilute the slurry in "the dilution zone of the tower in the stage. In the first extraction stage, the filtrate from seal tank 273 is carried into the dilution zone 174 by line 281 and pump 282. In the first chlorine dioxide stage, line 301 and pump 302 carry the filtrate from the seal tank 293 into the dilution zone 194. In the second extraction stage, line 321 and pump 322 carry the filtrate from the seal tank 313 into dilution zone 214, and in the second chlorine dioxide stage line 341 and pump 342 carry the effluent from the seal tank 333 into dilution zone 234.

Second, the filtrate not reused for dilution is discharged as effluent or to further processing by line 254 from tank 253, line 274 from tank 273, line 294 from tank 293, line 314 from tank 313, and line 334 from tank 333. The effluent from the chlorine stage washer 161 is separate from the effluent from the other washers because of its high chlorine or salt content and its larger content of residual material. The other lines - 274, 294, 314 and 324 - discharge into effluent line 350. All of the remaining filtrate would be handled as effluent if counterflow washing is not used. Some of the filtrate may be handled as effluent even if counterflow washing is used.

In the counterflow washing system shown, the wash water for the second chlorine dioxide washer 241 is process water from line 330; the wash water for the second extraction washer 221 is partly or wholly filtrate from the second chlorine dioxide washer 241 which is supplied from seal tank 333 by line 343 and pump 344; the wash water for the first chlorine dioxide for washer 201 is partly or wholly filtrate from the second extraction washer 221 which is supplied from seal tank 313 by line 323 and pump 324; the wash water for the first extraction washer 181 is partly or wholly filtrate from the first chlorine dioxide washer 201 which is supplied from seal tank 293 by line

C PI 303 and pump 304; and the wash water for the chlorine washer 161 is partly or wholly filtrate from the first extraction washer 181 which is supplied from seal tank 273 by line 283 and pump 284. Any additional wash water would be supplied through lines 250, 270, 290 and 310. These lines would provide all the wash water to the individual washers if the counterflow system is not used and parallel flow washing is used instead.

The chemical, water and steam supplies to the system are shown in the upper section of Figure 1. Process water is carried through line 360 to the various lines supplying water to the process, line 351 to the digester lines 11 and 15, lines 37, 57, 77 and 97 to the brownstock washers 28, line 152 to the chlorine aspirator 153, and lines 250, 270, 290, 310 and 330 to the bleach system washers. Chlorine is supplied through line 361 to line 151. Alkali line 362 supplies dilute alkali to lines 167, 187, 207 and 227. It is normally a 5-10% solution before entering line 362. aChlorine dioxide line 363 supplies a chlorine dioxide solution to lines 145, 192 and 232. Steam is supplied through line 364 to steam lines 12, 168, 188, 208 and 228. Sulfur dioxide is supplied to lines 197, 198, 237 and 238 from line 365.

Methods of measuring the practicality and efficiency of a* pulping or a bleaching process are the pulp yield, the physical properties of the pulp, the degree of pulp delignif ication, the pulp brightness, and the cost of obtaining the pulp.

Yield may be measured in two ways. The first is the amount, by weight, of carbohydrates and lignin returned per unit of wood. Screened yield is closely related and proportional to this chemical return. A high screened yield means the chemical return is high and a low screened yield means the chemical return is low. The second measurement of yield is fiber yield, by weight, per unit of wood. Rejects or screenings are related to and inversely proportional to the fiber yield. A high reject level means there is a low fiber return and a low reject level means there is a high fiber return. The total yield is the sum of these two yields. The ideal situation would be one in which there is a high chemical return and a high fiber return indicated by a high screened yield and low screenings.

The physical properties are freeness, burst, tear, fold, breaking length, density, and viscosity. Pulp samples are beaten in a PFI machine either for a specified number of revolutions and the freeness determined, or to a specified freeness and the time to freeness determined. The freeness of the pulp, Canadian Standard Freeness (CSF), is determined by TAPPI Standard T 227 M-58, revised August 1958. The beaten pulp is tested for burst, tear, fold, breaking length, and density. Burst is a numerical value obtained by dividing the burst strength in grams per square centimeter by the basis weight of the sheet in grams per square meter and is determined by TAPPI Standard Test T 220 M-60, the 1960 Revised Tentative Standard. This test is also used to determine tear. Tear is a numerical value and equals 100 e/r in which e is the force in grams to tear a single sheet, and r is the weight of the sheet per unit area in grams per square meter. Fold, breaking length in meters and density in grams per cubic centimeter are determined by TAPPI Standard Test T 220 OS-71. Pulp viscosity is in centipoises and is determined by TAPPI Standard Method T 230 SU-66.

There are two principal types of measurements to determine the completeness of the pulping or bleaching process, the degree of delignifi- cation and the brightness of the pulp. There appears to be no correlation between the two becau.se the deiignification factor is a measure of residual lignin within the pulp and the brightness is a measure of reflectivity of the pulp sheet.

There are many methods of measuring the degree of delignifi- cation of the pulp but most are variations of the permanganate test.

The normal permanganate test provides a permanganate or K number - the number of cubic centimeters of tenth normal potassium permanganate solution consumed by one gram of oven dry pulp under specified conditions. It is determined by TAPPI Standard Test T-214. The Kappa number is similar to the permanganate number but is measured under carefully controlled conditions and corrected to be the equivalent of a 50% consumption of the permanganate solution in contact with the specimen. The test gives the degree of deiignification of pulps through a wider range of deiignification than does the permanganate number. It is determined by TAPPI Standard Test T-236.

PBC is also a permanganate test. The test is as follows:

1. Slurry about 5 hand-squeezed grams of pulp stock in a 600- milliliter beaker and remove all shives.

2. Form a hand sheet in a 12.5-centimeter Buckner funnel, washing with an additional 500 milliliters of water. Remove the filter paper from the pulp.

OMPI 3. Dry the hand sheet for 5 minutes at 99 to 104°C.

4. Remove the hand sheet and weigh 0.4~26 grams of it. The operation should be done in a constant time of about 45 seconds to ensure the moisture will be constant, since the dry pulp absorbs more moisture. 5. Slurry the weighed pulp sample in a 1-liter beaker containing

700 milliliters of 25°C tap water.

6. Add 25 milliliters of 4 N sulphuric acid and then 25 milliliters of 0.1000 N potassium permanganate. Start the timer at the start of the permanganate addition. 7. Stop the reaction after exactly 5 minutes by adding 10 milliliters of the 5% potassium iodide solution.

8. Titrate with 0.1000 N sodium thiosulfate. Add a starch indicator near the end of the titration when the solution becomes straw color. The end point is when the blue color disappears. In running the test, the thiosulfate should first be added as rapidly as possible to prevent the liberation of free iodine. During the final part of the titration the thiosulfate is added a drop at a time until the blue color just disappears. The titration should be completed as rapidly as possible to prevent reversion of "the solution from occurring. The PBC number represents the pounds of chlorine needed to completely bleach one hundred pounds of air dried pulp at 20°C in a single theoretical bleaching stage and is equal to the number of milliliters of potassium permanganate consumed as determined by subtra-cting the number of milliliters of thiosulfate consumed from the number of milliliters of potassium permanganate added.

Many variables affect the test, but the most important are the sample weight, the reaction temperature and the reaction time.

There are also a number of methods of measuring pulp bright¬ ness. It usually is a measure of reflectivity and its value is expressed as a percent of some scale. A standard method is GE brightness which is expressed as a percentage of a maximum GE brightness as determined by TAPPI Standard Method TPD-103.

Another measure of the brightness or deiignification is the opacity of the fiber. Opacity as a percent of a standard is determined by TAPPI Standard Test T 425 OS-75.

The cost of a pulping process is measured both by capital cost and operating chemical cost, the capital cost being the cost of the plant and facilities and the operating cost being the ongoing process costs of chemicals, raw materials and labor.

The capital costs of a mill are high because large vessels are required for holding the chips or pulp during each of the lengthy processing steps. For example, The Bleaching of Pulp states that the reaction times for a chlorine bleaching step is 45 to 30 minutes, for a hypochlorite bleaching step 1 to 8 hours, for a chlorine dioxide bleaching step 1 to 4 hours, and for an extraction step 1 to 2 hours. The size of a tower will depend upon the retention time, the rate of production, the effective tower volume, the consistency, the degree of packing, and the uniformity of the pulp flow. Rydholm, noted earlier, indicates that the space demand for one ton of pulp in a vessel will vary from 3 to 15 cubic meters, depending upon the consistency and degree of packing. He suggests a minimu of 7.5 cubic meters per ton of pulp and states that 7-8 cubic meters per ton of pulp is normal for medium-consistency operation. This probably is on an air-dry weight basis, the u.sual basis in the mill.

With this as background, we can now see how researchers attempted to add oxygen into the pulping and bleaching process, or to replace portions of the system with oxygen processing. A continuing concern was the poor solubility of oxygen in water and its poor transference from the gas to the liquid phase and into the fiber. The usual solutions to these problems have been high pressures, high oxygen concentrations, high pulp consistencies or particular vessel configurations to promote the trans¬ fer of oxygen into the fiber. Two articles discuss the use of oxygen in the brownstock washing system. These are Jamieson, et al. "Integration of Oxygen Bleaching in the Brownstock Washing System," Svensa Paprastidning No. 5, 1973, pp. 187-191; and an article describing the actual oxygen system used in the brownstock washing system, Jamieson, et al. "Advances in Oxygen Bleaching III - Oxygen Bleaching Pilot Plant Operation," TAPPI November 1971, Vol. 54, No. 11, pp. 1903-1908. Each of these sytems requires a cylinder press before the oxygen .stage in order that the pulp be at a consistency of 30% before being treated with oxygen.

Other articles describing this process are Jamieson, et al., "Advances in Oxygen Bleaching," TAPPI, November 1971, Vol. 54, No. 11, pages 1903-1908; Jamieson, et al., "Mill Scale Application of Oxygen

OMPI Bleaching in Scandinavia," 1973 TAPPI Alkaline Pulping Conference paper, pages 231-238; and Fary, et al., "Oxygen Bleaching at Chesapeake Corporation," 1973 Alkaline Pulping Conference.

This system, the Modo-CIL system of Modo-Cell, is also described in a number of patents and articles.

The system is described in three U.S. patents. Schleinofer, U.S. Patent 3,703,435, granted November 21, 1972, describes the fluffer for the oxygen reactor. Engstrom, U.S. Patent 3,668,063, granted June 6, 1972 describes the method of removing the entrained air. Engstrom et al., U.S. Patent 4,022,654, granted May 10, 1977 describe a new reactor design. These all require high consistencies. The first has a consistency range of 10 to 50%, preferably 15 to 30%. The second mentions 20% and the third requires consistency of 18 to 40%. It states that consistencies in the range of 3 to 16% were used in the laboratory but these consistencies would not allow good mixing of the oxygen and pulp without excessive power for agitation. It also required a time of 5 minutes to 1 hour. All require high pressures. Since they are all high-pressure reactors, they^" are expensive.

Various protectors have been used to prevent or reduce the degradation of the pulp by the oxygen. There are a number of patents directed to various protectors that might be used. Exemplary are Robert et al., U.S. Patent No. 3,384,533, issued May 21, 1968; Noreus et al., U.S. Patent No. 3,652,386, March 28, 1972; and Smith et al., U.S. Patent No. 3,657,065, issued April 18, 1972.

There has also been a concern about channeling of the oxygen in the system and various ways to prevent channeling have been proposed. The Roymoulik et al., U.S. Patent No. 3,832,276, issued August 27, 1974, and Phillips, U.S. Patent No. 3,951,733, issued April 20, 1976, note this problem and suggest solutions.

The process described in these patents requires a pulp at a consistency of less than 10 percent, preferably about 2 to 6 percent and most desirably between 3 and 4 percent. The pulp is mixed with oxygen in a high shear mixing device and the slurry is introduced into a vessel. The slurry rises upward through the vessel. There is no substantial agitation of the fibers as they travel upward, and the pressure on the pulp is gradually reduced. The maximum pressure difference is between 1 and 10 atmos¬ pheres. This is preferably done in a bleach tower having a height of between 40 and 300 feet. "Generally speaking from about 5 to 120 minutes is suffi¬ cient. For the higher initial pressure provided by^" the higher tower the time can be reduced to a period of from about 1 minute to 60 minutes. With a 40-foot tower providing a pressure differential of roughly about 1 atmosphere about 30 to 60 minutes, preferably about 40 minutes is satisfactory."

The oxygenated pulp does not go directly to the tank. Between the mixer and the tank are a heat exchanger 5, a vent 7, and, optionally, a prepressurizing chamber 6. Several patents and articles describe different types of mixers.

A special oxygen reactor design is shown in Jamieson U.S. Patent No. 3,754,417, issued August 28, 1973. The reactor has a series of trays and the pulp slurry cascades from one tray to another. The oxygen or air is above the tray, and the slurry on the tray is agitated. Kirk et al., "Low Consistency Oxygen Deiignification in a

Pipeline Reactor - Pilot Study," 1977 TAPPI Alkaline Pulping/Secondary Fibers aConference, Washington, D.C., November 7-10, 1977 describes a pipeline reactor in which pulp at a 3% consistency is bleached with oxygen using a waterfall system. Oxygen is introduced incrementally. In Table 2, Kappa numbers were measured at 15 minutes and 30 minutes. Figure 4 is a graph of Kappa number reduction versus time. Kappa numbers were measured at 3, 5, 10, 15, 20 and 30 minutes after oxygen additives.

The following patents are exemplary of those describing various oxygen treatment systems. Grangaard et al., U.S. Patent 3,024,158, which issued March 6,

1962 discloses the oxygen treatment of pulp to minimize brightness rever¬ sion. Figures 1 and 2 disclose a two-vessel system in which oxygen is added to the liquor in one vessel and the pulp treated with the oxygenated liquor in a second vessel. The time of the reaction depends upon the temperature of the reaction. The time may be varied between 5 minutes to 3 hours at the reaction temperatures of between 100 and 160°C. Although the process may be used on unbleached kraft and other pulps of low brightness, it is preferable to use it with bleached pulp. Examples 1 -8 of this patent describe treatment of unbleached kraft pulps. The time of treatment was 60, 120 and 180 minutes

OMPI The patent also describes two ratios that are important when using oxygen and the parameters of these ratios. The^" first is the ratio of the oxygen pressure in the atmosphere in contact with the solution to the vapor pressure of the solution at the reaction temperature. It should be at least 0.35 and preferably 0.5 or more. The second is the ratio of the surface area of the solution in contact with the oxygen-containing atmosphere in square feet to the volume of the .solution in cubic feet. It must be greater than 4.

Figure 3 of the patent discloses an in-line system in which pulp is passed through a heat exchanger 23 and then continuously fed through a turbo mixer 24 while oxygen under pressure of at least 40 pounds per square inch is introduced. The treated pulp is then discharged into a stock chest 22.

The Kamyr blow line oxygen system is described in Richter, U.S. Patent 3,963,561 which issued June 15, 1976, and in Kleppe et al., "Oxygen Alkali Deiignification at Kamyr Digester Blow Line Consistency - a status report," 1976 International Pulp Bleaching Conference, May 2-6, 1976, TAPPI November 1976, Vol. 59, No. 11, pps. 77-80. In this system, oxygen is added to the pulp in the blow line between the digester and the oxygen reactor. The oxygen is added just prior to the refiner at the bottom of the reactor. The pulp is at a consistency of 5-20 percent and preferably 8-12 percent. The reactor is of an upflow-downflow type in which the pulp and oxygen are carried upward in a conical inner section of the reactor and low downward in the outer section of the reactor. The oxygen reacts with the pulp in the upflow section of the reactor where the pulp must remain for from 20-30 minutes. During this portion of the cycle, the pulp is 90 percent oxidized. In the pilot plant the retention time in the inner section of the reactor was 40 minutes.

There are a number of mechanical features within the reactor to keep the pulp from floating to the top and to ensure that the pulp remains within the conical inner section of the reactor the appropriate length of time. The patent is directed to the reuse of the excess oxygen within the system.

The article describes the system in use at the Moss Norway plant.

A number of patents and articles describe the South African Pulp and Paper Industry -L'Aire Liquide-Kamyr system as it progressed from the laboratory to commercial production. Exemplary are Robert et al, U.S. Patent No. 3,384,533, issued May 21, 1968; and Smith et al., U.S. Patent No. 3,657,065, issued April 18, 1972.

The pilot plant and the commercial unit were described in a paper by Myburgh et al., at the 23rd TAPPI Alkaline Pulping Conference.

The commercial unit was also described by Myburgh in a later paper

"Operation of Sappi's Oxygen Bleaching Plant" given at the 1973 TAPPI

Alkaline Pulping Conference.

The oxygen reactor used in the commercial version of this sytem is described in Verreyne, et al. U.S. Patent No. 3,660,225 granted May 2, 1972. The reactor is complex, having individual trays for each layer of pulp. The pulp consistency is between 16 and 67%. An example gives the height of pulp in the reaction vessel as 15 meters, the reaction time as 30 minutes, and the pressure as 150 psig. The reactor is a large, costly pressure vessel. The Billeruds system is described in U.S. Patent No. 4,004,967, issued January 25, 1977. This also is a high-consistency, high-pressure system.

The system of Toyo Pulp Company is described in Nagano et al,

U.S. Patent 4,045,279, August 30, 1977 and Nagano et al., "Hopes Oxygen Pulping Proce.ss - Its Basic Concept and Some Aspects of the Reaction of

Oxygen Pulping," TAPPI, October 1974. A high-pressure vessel is used and the-time of the reaction is from 15 to 120 minutes. Figure 5 indicates that the reaction rate becomes greater as the consistency goes higher. Reaction rates for consistencies of 1/10%, 1% and 3% are shown. The Rauma-Repola system is described in the Federal Republic of Germany patent disclosure 24 41 579, March 13, 1975 and in Yrjaia et al.,

New Aspects in Oxygen Bleaching, dated April 18, 1974. The system uses the Vortex mixer shown in Figures 2 and 3 of the patent. It is possible, by using either a number of passes through a single mixer or several mixers in series, to bleach the pulp in from 5 to 15 minutes. The consistency is 3%.

Yrjaia et al., "A new reactor for pulp bleaching" Kemian Teollisuus 29, No. 12: 861-869 (1972) describes a chlorine reactor.

Richter, U.S. Patent No. 4,093,506, issued June 6, 1978, describes a mixer for mixing bleaching fluids such as chlorine or chlorine dioxide with a high-consistency pulp. Rapidly rotating rotor blades essen¬ tially fluidize the pulp and the treatment gas is then added to it. The

OMPI _ Kamyr reactor is also described in an article, "Pilot and Commercial results of Medium Consistency Chlorination," given at the Bleaching Seminar on

Chlorination and Caustic Extraction, November 10, 1977 in Washington,

D.C. The TAPPI monograph "The Bleaching of Pulp" describes and shows on pp. 325 and 332, respectively, single-shaft and double-shaft steam mixers. A steam mixer has a swept area of around 6500 square meters per metric ton of oven dry pulp.

Several patents and articles describe bleaching sequences using oxygen.

Jamieson "The Present and Future Role of Oxygen Bleaching," undated, discloses a number of sequences using oxygen. These include

C_DOD, COD,OCED, OC-OD,ODEDEDand OC_QEDED.

ReroIIe et al. U.S. Patent No. 3,423,282 describe sequences having a central OC sequence. These are OCE, OCP and OCH/. _s;_tu\. The

C stage is reduced from 1 hour to 15 minutes and the amount of chlorine is reduced to 50-70% of the normal amount used.

Smith et al. U.S. Patent No. 3,725,194 notes ODEDED,

SO₂-O₂^SO₂-DED, So₂-O₂-H-DED, and SO₂~O₂-DED sequences. Grigorescu "Oxygen Bleaching of Fibrous Pulps" Celuloza Si

Hirtie 23 (2), 58-62 (1974) describes AODED, COD, CODED and OCDED sequences.

Jamieson et al. "Mill Scale Applications of Oxygen Bleaching in

Scandinavia" 1973 TAPPI Alkaline Bleaching Pulping Conference, 231-238, lists a number of sequences. These are O, OP, OH, OD, ODED, COD,

OCED, OC/DED, CODED, OC/DEHD, OCEDED, OC/DEDED, OHD, OPHD,

OHPD, OC/DPD, OC/DE_HD, and OC

Jamieson et al. "Advances in Oxygen Bleaching" TAPPI, 11/71,

54, No. 11, 1903-1908 compares OC and CO sequences. Soteland "Bleaching of Chemical Pulp with Oxygen and Ozone,"

Pulp and Paper Magazine of Canada, Vol. 75, No. 4, April 1974, pp. 91-96 mentions a number of sequences which include oxygen and high-consistency ozone treatments. These are oxygen-ozone, oxygen-ozone-peroxide, oxygen-ozone-hypochlorite, oxygen-ozone-ozone-peroxide, and oxygen- ozone-ozone-hypochlorite.

Rothenburg, et al. "Bleaching of Oxygen Pulps with Ozone,"

TAPPI, VoL 58, No. 8, August 1975, pp. 182-185 describes oxygen-ozone,

OMPI oxygen-ozone-sodium hydroxide extraction -ozone, oxygen-ozone-peroxide and oxygen-ozone-acetic acid sequences. The ozone treatment is high consistency in each of these sequences.

Kirk et al. "Low Consistency Oxygen Deiignification in a Pipeline Reactor - Pilot Study," 1977 TAPPI Alkaline Pulping/Secondary Fibers Conference, Washington, D.C., November 7-10, 1977, describes a pipeline reactor in which pulp at a 3% consistency is bleached with oxygen using a waterfall system. Oxygen is introduced incrementally. In Table 2, Kappa numbers were measured at 15 minutes and 30 minutes. Figure 4 is a graph of a Kappa number reduction versus time. Kappa numbers were measured at 3, 5, 10, 15, 20 and 30 minutes after oxygen addition.

SUMMARY OF THE INVENTION It has been difficult to add oxygen to pulp at the consistencies at which it exits the washer. It has also been difficult to be able to mix oxygen in a short period of time. Most of the prior art required either long time spans or a great amount of capital equipment.

The usual oxygen systems require a capital investment of several million dollars because of the large vessels employed. The high-consistency • systems require complex machinery to fluff the pulp prior to oxygen treatment. It limits the oxygen treatment to a single stage.

The inventors decided it was necessary to shorten the time of reaction, to provide equipment that was not capital intensive, and to operate at consistencies usually found in a pulping and bleaching system to reduce the horsepower required to operate the system. Pulp usually leaves the washer or subsequent steam mixer at consistencies of around 7 to 15%. It has the same consistency at other places within the pulp mill. They proceeded to attempt mixing with equipment that was more suited to a normal pulp mill environment, could be easily inserted into the pulp mill without major modifications of the equipment presently in the mill, and required less power to operate. In doing this, they determined that the amount of swept area, the area swept by the rotors while the pulp slurry is passing through the mixer, is important. This area is defined by the formula

1440 τr (r, ² - r ²) (R)(N) A = _Z where

2 A = area swept per metric ton, m /t

OMPI r. = outer radius of the rotor, m r₂ = inner radius of the rotor, m R = revolutions per minute of the rotor N = number of rotors t = metric tons (Oven-Dry Basis) of pulp passing through the mixer per day. They discovered that the swept area should be in the range of 10,000 to 1,000,000 square meters per metric ton of oven dry pulp. They determined that within this range there was a range of 25,000 to 150,000 square meters per metric ton of oven dry pulp which had certain character¬ istics that were better: less power was required or the kinetics of the reaction were substantially better. The optimum swept area is around 65,400 square meters per metric ton of oven dry pulp.

It was also determined that the oxygen should be placed within the pulp slurry in the mixing zone. The oxygen should preferably be supplied incrementally to the pulp as it passes through the mixer. This is done by multiple additions of the chemical through the stators which extend into the pulp slurry and reduce the rotation of the pulp slurry as it passes through the mixing zone. The rotors which provide the swept area within the slurry have leading and trailing edges with radii of curvature of 0.5 to 15 mm. Although the radii of curvature of the leading and trailing edge usually are the same, they need not be. The rotor preferably should have a cross section having a shape that is eiliptically generated, preferably elliptical, with its major axis in the direction of rotation. It should also be tapered. The trailing edge of the rotor may have a groove within it, and the groove may be treated with a hydrophobic coating.

It was also discovered that the central shaft in the mixer should have a diameter of about one half of the total interior diameter of the mixer to provide an annular space through which the pulp slurry would pass while being treated. There is a better reaction when the shaft has a diameter that is at least one half of the inner diameter of the mixer than when a shaft which has a smaller diameter.

The mixer should have a mixing zone with a swept area of 10,000 to 1,000,000 square meters per metric ton of oven dry pulp. A preferred range is 25,000 to 150,000 square meters and the optimum range is around

OMPI 65,400 square meters. The rotors in the mixer preferably have leading and trailing edges, each with a radius of curvature of 0^'5 to 15 mm, and an elliptically generated cross section. The oxygen is introduced into the mixing zone through the stators. The inventors decided to investigate both the need for costly expenditures and for lengthy times in which to do oxygen bleaching. They decided to add oxygen to an existing system and determine the results.

They found, contrary to prior art teaching, that the oxygen may be added to

' the pulp and processed at the consistency at which the pulp normally comes from the washer or subsequent steam mixer, that much of the treatment occurs in less than a minute in the mixer and that a long reaction time or large capital-intensive equipment is not required for oxygen treatment.

What is required is relatively small mixing equipment which intensively mixes the pulp and the gas. The oxygen may be added into an extraction stage, between washers, between a washer and a subsequent storage tank or in the blow line of a continuous digester, after the pulp is washed in the digester. Alkali, steam and oxygen are added to the blow line and the oxygen treated with the pulp. The blow line may carry the pulp to either a storage tank, a diffusion washer or other processing. These are not a necessary part of the oxygen treatment.

Several desirable treatment sequences are possible. These are

O-X-O and O-O-X-O in which X is chlorine, chlorine dioxide, a combination of chlorine and chlorine dioxide, a hypochlorite, a peroxide or ozone. The sequence may be followed by a D step.

Though the mixer was originally designed to overcome a problem in the oxygenation of pulp, it is also useful for noncondensable gases such as ozone, air, chlorine, chlorine dioxide, sulfur dioxide, ammonia, nitrogen, carbon dioxide, hydrogen chloride, nitric oxide and nitrogen peroxide. These gases may also be described as unsaturated in that they will not condense into liquid but will be superheated even after contact with the pulp. The mixer may also be used to mix highly superheated steam with the pulp.

BRIEF DESCRIPTION OF THE DRAWINGS

Figure 1 (A-C) is a diagram of a prior art pulping and bleaching process.

Figure 2 is a diagram of the present oxygen system used in the blow line in conjunction with a refiner..

-"^■gϋREX

OMPI Figure 3 is an oxygen diffuser used with a refiner to add the oxygen to the refiner.

Figures 4 and 5 are cross sections of refiners with the diffuser of Figure 3. Figure 6 is a diagram of a modified system used in the blow line.

Figure 7 is a diagram of a prior art oxygen bleaching system.

Figure & is a diagram of the present oxygen bleaching system.

Figure 9 is a diagram of the present oxygen system in an extraction stage. Figure 10 is a diagram of the present oxygen system between washers.

Figure 11 is a diagram of the present oxygen system between a washer and storage.

Figure 12 (A-C) is a diagram of a pulping and bleaching process using the oxygen bleaching systems of Figures 8 and 9, and a modification of Figure II.

Figure 13 (A-C) is a diagram of a pulping and bleaching process using the oxygen bleaching system of Figure 11, and a modification of Figure 11. Figure 14 is another diagram of a prior art bleaching system.

Figure 15 is a diagram of a pulping and bleaching process using the present systems.

Figure 16 is an isometric view of a mixer that may be used in the present invention. Figure 17 is a side plan view of the mixer shown in Figure 16.

Figure 18 is a cross section of the mixer taken along line 18-18 of Figure 17.

Figure 19 is a cross section of the mixer taken along line 19-19 of Figure 18. Figure 20 is a plan view of a rotor.

Figure 21 is a cross section of the rotor taken along line 21-21 of Figure 20.

Figure 22 is a plan view, partially in cross section, of a modified rotor. Figure 23 is a cross section of the modified rotor taken along line 23-23 of Figure 22.

OMPI Figure 24 is a plan view, partially in cross section, of a stator which may be used with the mixer.

Figure 25 is a side plan view, partially in cross section, of a modified stator taken along a line corresponding to line 25-25 of Figure 24. Figure 26 is a cross section of the stator taken along line 26-26 of Figure 24.

Figure 27 is a cross section of a valve taken along line 27-27 of Figure 25.

Figure 28 is an isometric view of a modified mixer. Figure 29 is a side plan view of the mixer of Figure 28.

Figure 30 is a cross section of the mixer taken along line 30-30 of Figure 29.

Figure 31 is a cross section of the mixer taken along line 31-31 of Figure 30. Figure 32 is a cross section of a rotor used in the reactor of

Figures 28-31.

Figure 33 is a cross section of the rotor taken along line 33-33 of Figure 32.

Figure 34 is a graph comparing two mixers. Figure 35 is a cross section of a modi ied mixer.

Figure 36 is a cross section of the modified mixer taken along line 36-36 of Figure 35.

Figure 37 is an enlarged cross section of the interior of the mixer shown in Figure 35. DESCRIPTION OF THE PREFERRED EMBODIMENT

Figures 2-5 show our invention applied in the blow line at the refiner. Figure 2 is a diagram of the process and Figures 3-5 are proposed changes to the refiner to add the oxygen to the pulp slurry nearer to the actual refining mechanism. The system shown in Figure 2 should be contrasted to the blow line oxygen system described in the Kamyr patent and article noted above. It should be remembered that the Kamyr system required a special upflow- downflow tower after the refiner in order to provide a retention time of at least 20 minutes after treating the pulp with oxygen. In contrast to this, our system merely requires adding the oxygen, alkali and heat prior to a refiner in a standard continuous digester

OΣylPI blow line refining system. In a two-refiner system, the second refiner is preferable because there are more individual fibers in this stage. This is the system shown in Figure 2.

In this figure, the reference numerals are identical to those found in Figure 1, 10' being the incoming chips, 11' being the process water, 12' being steam, 13' being the pulping chemicals, and 14* being the continuous digester. Again, the chips 10^* may be treated prior to entering the digester 14' by presteaming or impregation with digestion chemicals or any other type of treatment. Again, any type of pulping process may be used, and the pulping conditions for a particular process will depend upon the species of wood chip and the product desired. The pulping conditions and the amounts of chemical are well known.

The digester 14' should be continuous because a major portion of the deiignification products should be removed prior to the oxygen treat- ment. Otherwise too much of the oxygen will be used in reaction with the deiignification products and not with the pulp fibers.- The washing stage of the continuous digester provides this washing. Reference numerals 15' and 16' refer respectively to tήe wash water entering and the effluent leaving the washing stage of the continuous digester. As in Figure 1, reference numerals 17*, 20', and 21' are the three sections of the blow line, 18' and 19' are the two refiners, 22' is the storage tank, or a diffusion washer and tank, and 23' and 24' are the pump and line carrying pulp from the tank 22' to further processing.

The purpose of the present invention is to treat the washed pulp with oxygen with as little ch.ange to the equipment as possible. Sodium hydroxide and. steam are added to the pulp slurry in line 20' between refiners 18' and 19'. Sodium hydroxide, which both adjusts the pH of the pulp and buffers the oxygen reaction, is added through line 25. Other suitable alkalies, such as white liquor, may also be used. Steam is added through line 26, The steam raises the temperature of the pulp to a temperature appropriate for the oxygen treatment. Oxygen is added to the pulp through line 27. In a two-refiner system, the addition of the chemicals and steam prior to the second refiner is preferable because there are more individual fibers in the second refining stage. The lines used to carry these various chemicals to the process are shown in the upper section of Figure 2. Line 360' carries process water to lines 11' and 15'. Line 362' carries sodium hydroxide to line 25. Line 364' carries steam to lines 12' and 26. Line 366 carries oxygen to line 27. In some instances, the alkali is used both as a digestion chemical and for the oxygen treatment, as in the soda process in which sodium hydroxide is used for both digestion and oxygen treatment, or the kraft process in which white liquor is used for both digestion and oxygen treatment. In this case, line 362' would also supply line 13'.

The amount of oxygen used will depend upon the yield and K or Kappa number of the pulp to be treated, and the desired result of the treatment. Between 5 to 50 kilograms of oxygen per metric ton of oven-dry unbleached wood pulp is required for the oxygen treatment.

In a low yield, low Kappa number pulp the purpose of the oxygen treatment would normally be bleaching. The actual yield and Kappa number would depend on the pulping process used, but these pulps are used for bleached products. The blow line and brownstock Kappa number for pulp being used in bleached products is usually around 30 to around 40. The amount of oxygen used to bleach the pulp would be betw-een 5 and 40 kilograms per metric ton of oven-dry pulp.

In a high yield, high Kappa number pulp of the type usually used for linerboard the purpose of the oxygen treatment is to improve certain properties of the product. The blow line and brownstock Kappa number for this pulp is usually around 80 to 120. This allows the mill either to increase certain property values of the product at the same pulp yield or to maintain the property value while increasing the yield. As an example, the application of 12 to 50 kilograms of oxygen to a high yield, high Kappa number pulp will either increase the ring crush of a liner prepared from the pulp or maintain the ring crush at the same value and increase the yield. Ring crush is determined by TAPPI Standard T 818 OC-76.

•Other conditions may need adjustment for oxygen treatment. The pH for any oxygen treatment in any environment should be between 8 and 14. In this environment, the amount of alkali, expressed as sodium hydroxide, required to obtain this pH is between 0.25 to 8% of the oven-dry weight of the unbleached wood pulp. The temperature for any oxygen treatment in any environment is usually between around 65° C to around 121°aC The usual oxygen stage temperatures are around 82°C to around 99°C. However, the actual temperature in any oxygen stage will depend

OMPI upon the ability to heat the pulp, so it may vary from around 65°C to around 121°C depending on the location of the oxygen stage^* in the system. The pulp from the digester may be at the temperature required for the oxygen reaction, li not, the pulp would be heated to either adjust it to or maintain it at the temperature required for the oxygen reaction during the mixing step.

In Figure 2, there are three sample points labeled A, B and C. A is in the blow line 17' after the continuous digester 14'; B is in the blow line 21' after refiner 19'; and C is in the outlet from storage tank 22'. These are the three points at which samples were taken and tested in a mill trial of this system.

The pulp left the continuous digester 14^« at 71°C and 1380 kPa gage. Its pH was 10.5. The amount of unbleached pulp passing through the system from the digester throughout the test was 14.3 oven-dry metric tons per hour. The pulp passed through the refiner 19' in up to about 1.5 seconds, and remained in storage tank 22' about 50 minutes. The storage tank 22' was open to the atmosphere, and blow line 21' poured the slurry into the open tank. .

The system was first tested for a period of approximately 6 hours to determine the amount of residual lignin in the unbleached pulp at point A and point C to determine if there were any bleaching e fects in a standard system. Samples were taken at points A and C at the time intervals indicated in Table I, and the Kappa number of each of the samples was determined. The accuracy of the measurements of these discrete samples was checked during the test by taking a number of samples, averaging the Kappa numbers of these samples and comparing this average to the Kappa number of the discrete sample. These, the A Avg and C Avg Kappa numbers in Table I, and the discrete sample Kappa numbers are within experimental accuracy. The various Kappa numbers for the samples of unbleached pulp are shown in Table I. TABLE I

Time Kappa Number

A C Diff A Avg C Avg

0:01 28.0

0:35 35.4

1:00 33.2

1:30 31.2

2:00 32.4

2:30 31.9

3:00 ' 32.0 32.5

3:30 29.9 32.7

4:00 37.6

4:30 38.7

5:00 36.4

5:30 36.8 37.8

Avg 33.3 34.0 +0.7

From the.se results, it can be seen that no bleaching occurred between sample point A, the outlet of the continuous digester 14', and sample point C, the outlet of storage tank 22'.

Following the 6 -hour control test without oxygen there was a 5-1/4 hour test using oxygen. The pH and temperature were between 7 and 14 and between around 65°C and around 121°C respectively. During this test, the amount of oxygen added to the pulp was measured approximately every half hour and recorded as pounds of oxygen added per hour. This has been converted to kilograms. Since the flow of unbleached pulp was substantially constant at 14.3 oven-dry metric tons per hour, it was possible to determine the amount of oxygen added in kilograms of oxygen per oven-dry metric ton of unbleached wood pulp.

During the test, the oxygen flow varied from a low of 6.7 kilograms per oven-dry metric ton of unbleached pulp to a high of 40 kilograms per oven-dry metric ton of unbleached pulp. The average oxygen rate was 15 kilograms per oven-dry metric ton of unbleached pulp. Sodium hydroxide was added at a rate of 64 kilograms per oven-dry metric ton of unbleached pulp, and the steam was added at a rate of 612 kilograms per oven-dry metric ton of unbleached pulp. The pulp entered the second refiner 19' at a temperature of 70-97°C, a pressure of 621 kPa gage and a pH of 12.5. Pulp samples were again taken at points A and C at the time intervals indicated in Table II and the Kappa numbers of the pulp sample

OMPI measured. This was to determine whether the oxygen bleached the pulp. These Kappa numbers are given in columns A, and C, in Table II. The Kappa number at point C was, on the average, 7.5 points less than the Kappa number at point A during the oxygen treatment, showing that bleaching occurred.

Another series of tests were made to determine where bleaching occurred in the system.

In the first part of these tests, samples were taken again at points A and C to see if there was a correlation between these tests and the other A_j-C, bleaching tests being made at the same time. The results of these correlation tests are in columns A₂ and C₂ in Table II. It may be seen that the average Kappa number drop for the K and C₂ tests, 7.8, and the Kappa number drop for the A, and C, tests, 7.5, are within experimental accuracy. The second part of the tests was done during the A₂-C₂ tests.

Samples were also taken at A and B and the Kappa numbers determined. The samples at B were taken at approximately the same time as the samples at A because the pulp is in the refiner 19' for up to about 1_*5 to 2 seconds. The maximum time in the refiner would be 10 seconds. The results of these are in columns A₂ and B of Table π. From these tests it can be seen that the Kappa number drop across the refiner 19' was 7.5, substantially the entire Kappa number drop between point A and point C These tests indicate, within experimental accuracy, that the entire Kappa number drop, or deiignification, occurs in the refiner between points A and B. The first Kappa number at B, 28.5, is the same as the corresponding number at C_j, and the second Kappa number B, 31.4, is almost the same as the corres¬ ponding number at C₂, 31.5. Consequently, these tests have shown that bleaching occurs in the refiner 19' between the oxygen addition and point B. TABLE II

Time Or Kappa Number

•2 O ^.2

A, kg/hr kg/ODt Diff A 2 \ Diff B Diff A

6:00 35.0 36

6:30 26.4

6:32 196 13.7

7:00 381 26.7 35.4

7:30 27.2

7:32 95 6.7

7:45 36.3

8:00 35.1 37.4

8:02 238 16.7

8:15 36.8 28.0

8:30 23.2 28.3

8:31 191 13.3

9:00 191 13.3 36.0 37.4 29.7 37.4 28.5 -8.9

9:30 28.7 28.5

9:40 179 12.5

10:00 32.1 37.4 37.4 31 .4 -6.0

10:05 286 20

10:15 429 30

10:30 29.0 31.5

10:35 143 10

10:50 191 13.3

10:55 572 40

11:15 28.8

Avg 214 15 34.7 27.2 -7.5 37.0 29.2 -7.8 37.4 29.9 -7.5

The brightness of samples taken at points A and C was also checked. The average brightness of A₂ pulp samples^" was 18.9 and of C₂ pulp samples was 22.3. During the oxygen tests, a number of other measurements were taken. The shives, unbroken fiber bundles, were measured at points A and C. The average shive content was 2.2 percent of the oven-dry weight of the pulp at point A, and 0.67 percent of the oven-dry weight of the pulp at point C. The filtrate solids in the blow line material were 3.6 percent of the oven-dry weight of the pulp.

The physical properties of the pulp were also tested. These properties were freeness, burst, tear, fold, breaking length, density and viscosity.

The results of these tests are given in Table in. Three sets of data are given. The first set is for an average of all the bleached pulps tested. The second set is for a specific sample of pulp. The third set is for a control and is an average of tests of unbleached pulps produced on the apparatus before and after the bleaching trial.

OMPI TABLE HI

Physical Test Test Test Control Pulp Pulp Pulp Avg Sample

Initial CSF 703 708 715

Time to 550 CSF 30 min 29 min 34 min Time to 400 CSF 49 min 50 min 53 min Time to 250 CSF 67 min 68 min 70 min

Burst Initial 14.3 12.1 12.8 Burst (3 550 CSF 64.4 62.1 67.1 Burst (3 400 CSF 72.7 69.7 72.4 Burst (3 250 CSF 75.6 73.1 74.3

Tear Initial 229 206 225 Tear (3 550 CSF 176 179 159 Tear _ 400 CSF 160 157 151 Tear (3 250 CSF 151 149 147

Fold Initial 7 11 5 Fold (3 550 CSF 610 705 545 Fold (3 400 CSF 1045 1045 660 Fold (3 250 CSF 1570 1365 810

Breaking Length Initial 2700 m 2700 m 2700 m Breaking Length (3 550 CSF 7700 m 7300 8000 m Breaking Length (3 400 CSF 8700 m 7800 m 8500 m Breaking Length (3 250 CSF 9000 m 8200 m 8900 m

Density Initial .49 .49 .47 Density (3 550 CSF .58 .58 .58 Density (3 400 CSF .61 .62 .62 Density (3 250 CSF .62 .63 .62

Viscosity 75 76 61

It was necessary during this test that the means for adding the oxygen, steam, and sodium hydroxide be of the simplest possible type. In each instance, the chemicals were added through pipes extending into the blow line 20'. The lines were upstream of refiner 19'.

To determine the ability of oxygen to change the properties of pulp, a pulp having a Kappa number of 120 and a yield of 58.6 was treated with oxygen in pilot plant equipment. The equivalent of 20 kilograms of oxygen per metric ton of oven-dry pulp was applied to the pulp. The temperature was 90°C Sodium hydroxide addition was 4% of the weight of the oven-dry pulp. No protector, such as magnesium oxide, was added. In fact, no protector was used in any of the experiments described in this application.

The treated pulp had a Kappa number of about 65. It was compared to a kraft pulp having a 58 Kappa number. The tests were at 675 Canadian Standard Freeness. The oxygen treated pulp had a ring crush 15% greater than the kraft pulp and a burst 2% greater than the kraft pulp.

Again the actual chemical application will depend upon the starting pulp and whether it is desired to increase properties or yield. The oxygen application may be from 12 to 50 kilograms per metric ton of oven- dry pulp. The alkali addition, expressed as sodium hydroxide, would normally be from 3.6 to 4.9% and the temperature would normally be from 82 to 95°C. A slight amount of protector might be used. This would not exceed 0.5% based on the weight of the oven-dry pulp. The final product would have a Kappa ranging from 65 to 69; a ring crush, compared to a kraft pulp, of from 3% less when yield is increased to 28% more if better properties are desired; and a burst, compared to kraft pulp, of the same number if yield is increased to 6%. greater if better properties are desired. Much of the treatment would occur in the mixer and a majority in the mixer and through to the back pressure valve or top of the pipe in the mixer outlet line.

Figures 3, 4 and 5 show a unit that would provide better distribution of oxygen. Figure 3 shows the distribution unit by itself and Figures 4 and 5 show cross sections of refiners which include the unit.

The unit 370 consists of an inlet sleeve 371 which fits into the refiner casing inlet and is ixed in place by bolts which extend through holes 372 in flange 373. There are a plurality of L-shaped tubular diffusers 374 equally spaced and oriented axially around the sleeve and flange. Each diffuser has an inlet section 375 and an outlet section 376. The inlet section 375 extends radially along flange 373 and the outlet section 376 extends longitudinally of the sleeve 371. The tube may have any cross section. There are several ways of attaching the diffusers 374 to the sleeve and flange. The inlet section 375 may be along the interior or exterior face of flange 373, be fitted in recesses in the interior or exterior face of flange 373, or be within and formed by the walls of the flange. In the latter design,

OMPI an outlet tube would extend radially from the flange 373 as shown in Figure 2. Similarly, the outlet section 376 could be affixed to the inner or outer wall of the sleeve 371, fitted into recesses in the inner or outer walls of the sleeve or be within and formed by the walls of the sleeve. They would be formed within and by the walls by casting when the sleeve and flange are formed or by drilling through the wall. The preferred form is shown in Figure 3. The inlet section 375 is formed in the flange and the outlet section 376 affixed to the inner wall of the sleeve. The diffuser will have one or more outlets for oxygen. Six diffusers should adequately disperse the oxygen in the pulp.

In Figure 4, the unit is shown with a refiner. A single disc refiner is shown. Only the major portions of the refiner are identified.

The refiner 380 has an inlet 381, a screw conveyer section 382, a refiner section 383, and an outlet 384. The refiner shaft 385 is within the casing. Attached to the shaft are screw conveyer 386 and the revolving refiner member 387. The revolving refiner plate 388 is attached to member 387. Attached to the refiner casing 389 are the fixed refiner member 390 and the fixed refiner plate 391 which is aligned with revolving plate 388. The shaft 385, conveyer 386, revolving refiner member 387 and plate 388 are rotated by a suitable motor 392.

In this refiner, the unit 370 would be part of the wear plate for the conveyer. The diffusers 374 would either be recessed in the sleeve 371 or formed in the sleeve as described above. This would allow the oxygen to be admitted after the conveyer section. Oxygen is fed to the diffusers through the oxygen manifold 394. The oxygen^" enters the diffusers 374 through the manifold 394 and is added to the pulp after the conveyer 386. The oxygenated pulp leaves the refiner through the outlet 384. The blow line 20' is attached to inlet 381.

Figure 5 shows the use of unit 370 in a refiner that does not have a conveyer section. The reference numerals are the same as in Figure 3.

In any type of refiner there is relative rotative movement between two opposed surfaces which are spaced to allow passage of material between them. Disc refiners are normally used because of the ability to change the clearance and pressure on the plates, depending on the furnish to the refiner and the end product desired. There are other types of refiners that may be used. In the usual double-disc refiner, the rotating disc has

OMPI ^WI?° refiner plates on both faces which act against opposing fixed plates. Another type of double-disc refiner has both refiner plates mounted on discs which rotate in opposite directions to provide both a rolling and an abrading action. The discs are mounted on separate shafts which may be concentric. A conical refiner may also be used.

In some installations, there is no refiner in the blow line between the continous digester 14 and the blow tank 22. It is now possible to achieve good treatment by the simple addition of the alkali, steam and oxygen lines, and a mixer, such as mixer 116, into the blow line. This is shown in Figure 6. The other reference numerals are the same as those in Figure 2.

Mixer 116 may be a refiner such as the refiner shown in Figures 4 or 5. For example, the refiner, when stopped, may be used as a mixing device. The clearance between discs has been tested at around 13 mm and can be up to 75 mm. Consequently, the clearance may be from a few millimeters to around 75 millimeters. This narrow passage causes the pulp slurry and oxygen to mix. Another suitable mixer would be one that is relatively small and intensively mixes the pulp and gas. Several suitable mixers are described later in this application.

There should be a back pressure on the pulp in the mixer or refiner. This may be provided by an upflow line after the mixer which creates a hydrostatic head at the mixer. A pressure valve is preferred. The valve may be combined with the upflow line. The valve may be placed in the blow line 21' downstream of the refiner 19* or line 21' * downstream of the mixer 116. The valve may be either right after the mixer or refiner or at the top of the line before the outlet.

The maximum pressure in the mixer would normally not exceed 830 kPa gage, and at the top of the pipe would normally not exceed 345 kPa gage.

Figures 7 and 8 compare the size and complexity of a prior art oxygen bleaching system of the type shown in Verreyne et al, U.S. Patent No. 3,660,225 with the present system. Both drawings are to the same scale. Both units would handle the same amount of pulp in an oven-dry weight basis.

In the prior art system shown in Figure 7, pulp 400 from mill 401 is carried by pump 402 to a storage tank 403. In storage tank 403 the pulp is mixed with an alkali solution 404 from filtrate storage tank 405. A protector would be added to the pulp at this time also. The treated pulp mixture 406 is moved by pump 407 to a dewatering press 408 which removes enough water from the pulp to raise the consistency of the pulp slurry to around 20-30%. This material is then carried by pump 409 to the top of the oxygen reactor. The pump 409 is a series of screw conveyers, the only way to pressurize pulp of this consistency. At the top of the reactor 410 is a fluffer 411 which spreads the pulp uniformly over the top tray 412 of the reactor. The pulp passes down through the other trays 413-416 and is treated with oxygen during its passage through the trays. From the bottom of the trays the bleached pulp 417 is carried to storage tank 418.

This mill should be contrasted to the present system shown in Figure 8. The mixing tank 403, filtrate storage tank 405, press 408, pump 409, and reactor 410 have been replaced by a simple mixer 420 in which the oxygen is mixed with the pulp 400*. By comparison, the system of Figure 7 requires a power six times as large as the mixer or system of Figure 8. For the same quantity of pulp, the system of Figure 7 would require an aggregate of 2238 kW in motors to operate the reactor and the various pieces of equipment associated with the reactor, while the mixer of Figure 8 would require a 373 kW motor. The mixer of Figure 8 is also able to operate at consistencies usually found in pulping and bleaching systems. This would usually be the consistency of pulp leaving the washer or the subsequent steam mixer, a consistency of around 8 to 15% from the washer and around 1% less for the steam mixer. Figure 9 shows the oxygen mixer in a standard caustic extraction stage of a bleaching system. It shows that a simple change can turn a caustic extraction stage into an oxygen treatment stage. To allow com¬ parison of this extraction stage with the same one in Figure 1, the same reference numerals have been used. The operation of the various pieces of equipment - the washers 201' and 221', the steam mixer 206', the extraction tower 213* and the seal tanks 293' and 313' - are the same as in the prior art extraction stage in Figure 1.

The flows of pulp and wash water through the system are also the same as in Figure 1. The pulp 195' enters washer 201' where it is washed, dewatered and treated with alkali, usually sodium hydroxide. The consistency of the pulp leaving the washer is usually in the range of 8 to 15%. The exiting pulp 203' then Is mixed with the alkali and steam in steam mixer 206'. Pulp consistency is reduced about 1% in the steam mixer. From the steam mixer the pulp goes to extraction tower 213' where it remains for the usual period of time. It is diluted and carried to washer 221', where it is washed and dewatered.

Although washer 221' may be a diffusion washer, it is shown and described as a vacuum or pressure drum washer.

In washer 221' the water is either fresh process water through line 310', counterflow filtrate through line 343' or a combination of these, and in washer 201' the wash water is either fresh process water through line 290', or counterflow filtrate through line 323', or a combination of these.

The filtrate from washer 201' is stored in seal tank 293' and is used as dilution water through lines 295', 297' and 301*, as wash water through line 303*, or sent to effluent treatment through line 294'. It is shown being treated separately from effluent in line 350' because the effluent, if from a chlorine stage, would be treated separately from effluent from an oxygen stage.

Similarly, the filtrate from washer 221' is stored in seal tank 313' and used as dilution water through lines 315', 317* and 321', as wash water through line 323', or treated as effluent through line 314'. Since the oxygen effluent has little, if any, chlorine components, it may be combined with the effluent from the brownstock washers and the digester and be treated in the recovery furnace thus reducing the amount of material that must be sewered to an adjacent stream or body of water.

The supply lines are 360"' for process water, 362'" for sodium hydroxide solution, and 364'" for steam.

The description of the stage so far is, with the exception of splitting the effluent stream, identical to the description of the extraction stage in Figure 1. Only one minor change is required to turn this extraction stage into an oxygen stage. That is the addition of the oxygen mixer 211 into line 209', of the oxygen line 212 to either the mixer 211 or the line 209'A just in front of the mixer and of the oxygen supply line 366". The pulp leaves steam mixer 206' through line 209'A and enters the oxygen mixer 211 and the oxygenated pulp leaves the mixer 211 through line 209'B and enters the extraction tower 213*. The amount of oxygen supplied to the pulp would be 11 to 28 kilograms per metric ton of oven-dry pulp. A preferred range is 17 to 22 kilograms of oxygen per metric ton of oven-dry pulp.

All conditions - time, temperature, pressure, consistency, pH and chemical addition - may remain about the same as they were in the extraction stage shown in Fig 1. The temperature would normally be increased from 71-77°C for an extraction stage to 82-88°C for an oxygen treatment stage, because the treatment is improved at higher temperatures. Again, the temperature may be as high as 121°C. The amount of alkali, expressed as sodium hydroxide, is 0.5 to 7% of the weight of the oven-dry pulp. Channeling of the oxygen after mixing is of no particular conse¬ quence. If the extraction tower was a downflow tower, it remains a downflow tower. The physical location of mixer 211 is a matter of convenience, the simplicity of installation and maintenance being the sole criteria. If it can be placed in an existing line, it will be. If convenience requires that it be placed on the floor of the bleach plant, it will be placed on the floor of the bleach plant and an external pipe can carry the pulp slurry to the top of the extraction tower 213*.

The mixing produces an intimate contact between the gas and the slurry, and appears to divide the gas into mostly small bubbles. There may be some larger bubbles and gas pockets, however. The presence of some large bubbles and gas pockets up to the size of the pipe through which the pulp slurry was passing have been observed. These have not affected the quality of the pulp or the treatment of the pulp.

Again there should be a back pressure on the pulp in the mixer. This may be provided by an upflow line after the mixer which creates a hydrostatic head at the mixer. A pressure valve is preferred. The valve may be combined with the upflow line. The valve may be placed in the line 209'B downstream of the mixer 211. The valve may be either right after the mixer or at the top of the line before the outlet. The maximum pressure in the mixer would normally not exceed

830 kPa gage, and the top of the pipe would normally not exceed 345 kPa gage- In a mill trial of the system, sampling was done at D, E and F.

At point E, sampling was at the top of the tower 213' rather than directly after the mixer 211 because it was not possible to sample after the mixer.

It required about 1 minute for the slurry to reach point E from the mixer. In

OMPI these tests the mixer was on the bleach plant floor and an external line carried the slurry to the top of the tower.

Table IV PBC D E F

1.4 1.13 0.95

1.41 1.13 0.90

Figure 10 shows the oxygen mixer between two washers. In this case the washers are brownstock washers. Again, the reference numerals are the same as those found in Figure 1 and the conditions in these two washers are the same as those noted in Figure I.

The differences between this unit and that in Figure 1 are the addition of steam mixer 86, pump 76, mixer 88, and lines 85, 87 and 89. Line 85 adds alkali onto the mat 73'A as it is leaving the washer 71'. The amount of alkali, expressed as sodium hydroxide, placed on the mat is between 0.1 and 6%, preferably between 2 and 4%, based on the oven-dry weight of the pulp. The treated mat 73'A is then carried to steam mixer 86 in which it is mixed with -the alkali and with steam from line 87 to increase the temperature of the pulp to 65-88°C and possibly as high as 121 C. From steam mixer 86 the pulp slurry 73'B is carried by a pump 76 to a mixer 88 in which it is mixed with oxygen from line 89. The amount of oxygen added will depend upon the K number of the pulp and the desired result. The reasons for adding oxygen in the brownstock washers are the same as for adding it in the blow line and the same amounts would be used. This will normally range from 5 to 50 kilograms per metric ton of oven-dry pulp. Two standard ranges for bleaching in a brownstock system are 22 to 28 and 8 to 17 kilograms of oxygen per metric ton of oven-dry pulp. The latter is a preferred range. The oxygenated pulp 73'C then passes to the vat 90' of washer 91*.

The washer after the mixer may be a diffusion washer. Again there should be a back pressure on the mixer. This pressure is provided in the same way that the pressure is provided to mixer 211, by an upflow line, a pressure valve or a combination of these. The placement of the valve and the maximum pressure are the same as those for mixer 211.

OMPI Figure 11 discloses a system placed between a washer .such as brownstock washer 91" and a storage tank such as storage tank 110'. Again the reference numerals are same as those used in Figure 1. The changes are the addition of steam mixer 106, mixer 108, alkali line 105 and its supply line 362"'", steam line 107 and its supply line 364"'", and oxygen line 109 and its supply line 366"". The amount of alkali and oxygen added to the pulp, the temperature of the pulp, and the time between alkali addition and oxygen addition and the pressure at the mixer and in the outlet line and the methods of obtaining these pressures are the same as in the system of Figure 10. The other operating conditions would remain the same as in Figure 1.

In each of these systems, the time between alkali addition and oxygen addition is usually from 1 to 5 minutes. The exact time will depend upon equipment placement and pulp speed.

A mill trial was run using the system shown in Figure 11. In this system, the mixer 108 was floor mounted and the pipe 93"C carried the slurry from mixer 108 to the top of tower 110'. The tower was open to the atmosphere. A partially closed valve near the outlet of pipe 93"C created a

276 kPa gage back pressure in the line. The hydrostatic pressure in the line was 241.5 kPa gage, so the pressure within the mixer was 517.5 kPa gage. Four trial runs were made under slightly different conditions to determine both the overall deiignification effect of the system and the percentage of deiignification taking place within each section of the system.

K number measurements were taken before and after mixer 108, at the outlet of pipe 93"C, at the outlet of tank 110', and at the outlet of the decker 121' (Figure 7b) downstream of the tank 110'.

In a control run in which no oxygen was added to the system, it was determined that the K number was reduced by 1 number between the inlet of mixer 108 and the outlet of decker 121*. This probably was due to screening. In the overall deiignification computation, the numbers were corrected for this 1 K number drop.

The various K numbers were taken within the system to deter¬ mine the percentage of the total deiignification or K number reduction taking place through the mixer 108, through pipe 93"C, through tank 110', and through decker 121'. Washer showers had been added to the decker for these tests. The slurry required between 10 to 15 seconds to pass through mixer 108, 2-1/2 to 3-1/2 minutes through pipe 93"C, and 1/2 to 3 hours

OMPI through tank 110' or decker 121'. It was determined that in these tests, 30% of the total deiignification occurred in mixer 108, 40% occurred in pipe 93"C, 8% occurred in tank 110', and 21% occurred between the tank and the decker. This latter reduction is caused by screening of the pulp. Table V gives the actual conditions in the mixer: the tempera¬ ture in degrees C; the kilograms of caustic, expressed as sodium hydroxide, and oxygen per oven-dry metric ton of pulp; the pressure in kilopascals gage; the K numbers at the various locations within the system; and the percent K number reduction. In Run No. 1, the percent reduction at the decker outlet in the last line is the reduction between the tip of the pipe and the decker outlet.

TABLE V

Runs

1 2 3 4 Mixer Conditions

Temp. °C 79.5 82 93 88 Caustic, kg/O.D.t. 15.1 20.2 15.1 20.2 Oxygen, kg/O.D.t. 22.7 25.2 20.2 25.2 Pre.ssure, kPa gage 517.5 517.5 517.5 517.5

Overall Deiignification

Before Mixer K No. 19.6 25.4 19.9 24.1 K No. Corrected 18.6 24.4 18.9 23.1

After Decker K No. 15.6 19.2 15.1 17.8 % K No. Reduction 16 21 20 23

Deiignification Within System

Mixer Inlet K No. 19.6 25.4 19.9 24.1

Mixer Outlet K No. 18.5 23.3 18.6 21.3 % of Total Reduction 25 34 27 29

Top of Pipe K No. 16.8 21.5 16.0 19.8 % of Total Reduction 44 29 54 40

Tank Outlet K No. - 20.5 16.0 19.3 % of Total Reduction 16 0 8

Decker Outlet K No. 15.6 19.2 15.1 17.8 % of Total Reduction 31 21 19 23

This data indicates that in any of the systems described in this application, a valve should be placed in the line downstream of the oxygen mixer to provide back pressure on the mixer. It also indicates that much of the deiignification occurs in less than a minute in the mixer. It may be in 10-15 seconds or less. Most will occur in a few minutes in the mixer and the outlet pipe immediately after the mixer.

The maximum pressure in a mixer would normally not exceed 830 kPa gage, and the pressure at the top of the pipe if a hydrostatic leg is used would normally not exceed 345 kPa gage. The mixer has also been operated under a hydrostatic pressure only.

The oxygen systems of Figures 9, 10 and 11 are shown in a bleaching system in Figure 12. Figure 12 shows the same overall system as Figure 1 and the same reference numerals are used throughout these figures. The system shown in Figure 1 includes digestion of the wood chips in either a batch or continuous digester, brownstock washing, screening, dewatering in decker 121 and a D EDED bleach sequence. Figure 12 shows digestion, brownstock washing, screening, and an OOCOD bleach sequence. For the most part, the operating conditions - time, temperature, pH, consistency and chemical addition - are the same in Figure 12 as they were in Figure 1.

The differences between the system in Figure 12 and that in Figure 1 is indicated by brackets at the bottom of Figure 12.

The first difference between the process shown in Figure 12 and that shown in Figure 1 is indicated by bracket 430. This is the washer oxygen system of Figure 10 and again the reference numerals and operating conditions for this oxygen stage are the same as that given for the oxygen stage in Figure 10. Since an oxygen treatment stage should have washed pulp, the oxygen stage 430 in Figure 11 is shown after the third brownstock washer to indicate its placement after a batch digester in which no washing would occur in the digester. With a continuous digester, there would be fewer brownstock washers, and the oxygen .stage could be earlier in the brownstock system.

The next change is shown by bracket 431. This is a modification of the washer oxygen system of Figure 11. There should be at least two stages of washing after an oxygen bleach stage. The two washing stages after the oxygen stage at bracket 430 are washer 91"' and decker 121' which is converted to a washer. If the oxygen stage at bracket 430 had been after the second brownstock washer 51' rather than the third brownstock washer 71", then the oxygen system 431 could have been between washer 91'" and storage tank 110" as shown in Figure 11.

In the system shown, the decker 121' has been converted to a washer by the addition of washer heads 125, a process water line 127 and a clean-up washer 124. The system has been further modified into an oxygen system by the addition of an alkali line 425, a steam mixer 426, a steam line 427, an oxygen mixer 428 and an oxygen line 429. These are placed between

- UREX

OMPI the decker 121' and the high-density storage tank 140'. The operation is the same as that described for Figure 11.

The next change is at bracket 432. This shows, in dotted line, the elimination of the chlorine and chlorine dioxide equipment. The chlorine dioxide mixer 144', the chlorine dioxide tower 146', the chlorine aspirator 153', the chlorine mixer 155', the chlorine tower 157*, and the pump 159' are eliminated. The piping and chemicals associated with this equipment are also eliminated.

The next change is at bracket 433. This bracket indicates the elimination of the extraction equipment between washers 161' and 181' so that these washers may be used as the two stages of washing after the oxygen stage at bracket 431. This is also indicated by the elements in dotted line. The eliminated items are the steam mixer 166', the extraction tower 173', and the pumps 170*, 176', 278' and 282'. Again, the piping and chemical additions required by an extraction stage are also eliminated. The pump 170' may be retained to move the pulp 163' to washer 181' if this is necessary.

The next two changes are shown by brackets 434 and 435. Bracket 434 indicates the elimination of the chlorine dioxide stage and bracket 435 its replacement by a chlorine mixer. The elimination of the chlorine dioxide stage results in the elimination of steam mixer 186', chlorine dioxide mixer 191', chlorine dioxide tower 193', and pumps 190', 196', 298" and 302", their associated piping and chemicals. These are replaced by a small chlorine mixer 438 and the chlorine supply line 151'. A chlorine tower is not required. The pump 190' may be retained if it is required to move the pulp 183' to the mixer 430. The chlorine effluent in line 294" is maintained separate from the oxygen effluent.

The time in this mixer, as in the oxygen mixer, is less than 1 minute, and normally would be only a few seconds. Pulp traveling at 18.3 meters per second would pass through an 2.4 or 3 meter long reactor in an exceedingly short time. The chlorine would be treated at the temperature of the pulp off the washer, 54 to 60°C, rather than the cooler chlorination temperature.

The last change is shown by bracket 436. This is the oxygen addition to an extraction stage as shown in Figure 3. The reference numerals and operating conditions are again the same as in Figure 9.

OMPI Each of the gas mixers should be under a back pressure as described earlier.

Figure 13 shows another arrangement in which the bleach sequence is OCODED, Again, the changes between Figure 13 and Figure 1 are shown by the brackets in Figure 13. Changes 431 '-436' are the same as those shown in Figure 12. The same reference numerals and operating conditions are used in Figures 1, 12 and 13.

There is one other change indicated by bracket 437. This is the addition of E and D stages at the end of process. Again, the process conditions for this last extraction stage are the same as those for the other extraction stages and for this last chlorine dioxide stage are the same as those for the other chlorine dioxide stages. It should also be realized that the only additional equipment required for these two stages are the two additional washers. The extraction equipment that was eliminated at 433' can be used in this extraction stage and the chlorine dioxide equipment eliminated at 434* can be used in this chlorine dioxide stage. In an actual modification, this equipment would be left in place and repiped.

For the purposes of the present description, however, new reference numerals will be used for these last stages. In the E stage, the steam mixer is 446, the alkali line 447, the steam line 448, the slurry line 449, the pump 450, the extraction tower 453, the dilution zone 454, the line from the tower to the washer 455 and the pump 456.

In the extraction washer, the vat is 460, the washer 461, the drum 462, the exiting pulp 463, the cleanup washer 464, the incoming process water 490, the washer heads 491, the filtrate line 492, the seal tank 493, the effluent line 494, the dilution lines 495, 497 and 501 and their respective pumps 496, 498 and 502, and the counterflow wash water line 503 and its pump 504. In the last chlorine dioxide stage, the steam mixer is 466, the alkali line 467, the steam line 468, the pulp slurry line 469, the pump 470, the chlorine dioxide mixer 471, the chlorine dioxide line 472, the chlorine dioxide tower 473, the dilution zone 474, the line from the tower to the washer 475, its pump 476, and the sulfur dioxide lines 477 and 478. In the last washer, the vat is 480, the washer 481, the drum 482, the exiting pulp 483, the cleanup washer 484, the incoming process water 510, the washer heads 511, the filtrate line 512, the seal tank 513, the effluent line 514, the dilution lines 515, 517 and 521 ^'and their pumps 516, 518 and 522, and the counterflow wash line 523 and its pump 524.

Again, each of the gas mixers should be under a back pressure, as described earlier.

The next two figures, 14 and 15, illustrate the difference in equipment between a prior art bleach plant having a D EDED bleach sequence and a plant using the present system having an OOCOD sequence. Each sequence starts at the brownstock washers and ends at a storage tank. The sequence in Figure 14 is the same as in Figure 1 - D EDED. The sequence in Figure 15 is the same as in Figure 12 - OOCOD. The reference numerals in Figures 14 and 15 are the same as those used in Figures 1 and 12 and relate to the same pieces of equipment.

In Figure 14, the pulp 93"'" from brownstock washers 28'" is carried by thick stock pump 96"" to high-density storage 110"". From storage, the pulp slurry is moved through line 111"" by pump 112"" to a mix tank 116 in which it is mixed with water to reduce its consistency. From tank 116, a pump 117 carries the pulp slurry through line 118 to screens - 113'". Then the pulp slurry 115'" enters decker 121'" where it is dewatered. The filtrate goes through filtrate line 128'" into seal tank 129'", while the pulp 123'" is moved by thick stock pump 126'" to high-density storage 140'".

From high-density storage 140'", the pulp is moved through line

141'" by pumps 142"' and 156' and mixed with chlorine dioxide in tank 144'".

Thereafter it goes into chlorine dioxide tower 146'" and leaves this tower through line 150'. While in line 150', it is mixed with chlorine in mixer 155"' and carried to chlorine tower 157'". The chlorinated material leaves the chlorine tower 157'" through line 158' and the extraneous material is washed from it in washer 161'". The filtrate passes through line 251'" into seal tank

253'". The pulp 163"' exits the washer, goes to steam mixer 166'" and is mixed with sodium hydroxide and steam and carried though line 169' by a thick stock pump 170'" to extraction tower 173'". The alkali in this extraction stage, as in the other, may be added at the washer or the steam mixer. The extracted pulp is moved through line 175' by pump 176'" to washer 181"'. The filtrate from this washing step leaves through line 272'" into seal tank 273'". The pulp 183"' passes to steam mixer 186'" and again

OMPI WIPO mixed with steam and sodium hydroxide. It then is carried through line 189" by thick stock pump 190'" to chlorine dioxide mixeT 191'" and chlorine dioxide tower 193"'. From the chlorine dioxide tower, the pulp slurry is carried through line 195"" by pump 196'" to washer 201"". Again, the filtrate from this washer is carried through line 292"" to seal tank 293"" while the exiting pulp 203"" passes to steam mixer 206"" to be mixed with sodium hydroxide and steam and carried through line 209"" by thick stock pump 210"" to extraction tower 213"".

From the tower, the slurry is carried through line 215"" by pump 216"" to washer 221"" and washed. The filtrate leaves the washer through line 312"" to seal tank 313"", while the pulp 223"" is mixed with steam and possibly sodium hydroxide in steam mixer 226'". From the mixer, the pulp is carried through line 229'" by thick stock pump 230'" to the chlorine dioxide mixer 231"' and the chlorine dioxide tower 233'". The pulp slurry is then carried through line 235"' by pump 236"' to washer 241'" where it is again washed. The filtrate passes through line 332'" to seal tank 333'". The pulp 243"' is carried by thick stock pump 450' through line 455* to storage tank 527. From the storage tank, the material is carried by pump 528 through line 529 to any additional processing. This should be contrasted with the oxygen system shown in

Figure 15. The eight storage tanks of the prior system become four storage tanks in the present system. This number could be reduced to three because the one chlorine dioxide tower in the system shown in Figure 15 can also be eliminated. Its purpose is as a storage tank within the system. It need not be used as a chlorine dioxide tower.

In both systems, the material begins with the same PBC and ends with the same PBC Consequently, this same result is achieved with a great decrease in capital cost in our new system. There are other savings also.

In the system shown in Figure 15, the pulp 93"""A from brown- stock washers 28"" is mixed with sodium hydroxide and steam in steam mixer 106' and carried through line 93"""B by thick stock pump 96'"" to oxygen mixer 180' and thereafter through line 93"""C to high-density storage tank 110""^*.

From this first oxygen stage, the pulp slurry is carried through Hne 111"'" by pump 112'"" to tank 116' and from there through Hne 118' by pump 117' to screens 113"". From the screens, the pulp 115"" goes across

-gTJlE^ OMPI decker 121"". The filtrate from the decker is carried through line 128"" to seal tank 129"", while the pulp 123""A is carried to steam mixer 426", mixed with sodium hydroxide and steam and then carried through line 123""B by thick stock pump 126"" to oxygen mixer 428". From the oxygen mixer, the material passes through line 123""C to high-density storage 140"".

The pulp slurry from the high-density storage is carried through line 141"" by pump 142"" to washers 161"" and 181"". The filtrate from these two washers passes through lines 252"" and 272"" to seal tanks 253"" and 273"" respectively. The pulp 183"" from washer 181"" is carried by thick stock pump 190"" to chlorine mixer 438". From the mixer, the slurry passes through line 195"" to washer 201"'". The filtrate from this washer passes through line 292'"" to seal tank 293"'". The pulp 203"'" is carried to steam mixer 206'"", mixed with sodium hydroxide and steam and then carried through line 209'"" by thick stock pulp 210'"" to oxygen mixer 211'". From the oxygen mixer, the pulp passes through line 215'"" to washer 221'"". The filtrate from this washer passes through line 312'"" to seal tank 313"'".

The pulp 223'"" from washer 221""' passes to steam mixer 226"", is mixed with sodium hydroxide and steam and carried through line 229"" by thick stock pump 230"" to chlorine dioxide mixer 231"". From the mixer, it goes to chlorine dioxide tower 233"". This tower is optional.

After the tower, the pulp slurry is carried through line 235"" by pump 236"" to washer 241"". The filtrate from this washer passes through line 332"" to seal tank 333"" and the pulp 243"" is moved by thick stock pump 450" through line 455" to storage tank 527*. From this tank, it may be moved by pump 528' through line 529' to any subsequent operation.

In these two figures, the sodium hydroxide, or other alkali, may be added either at a washer or at a steam mixer.

The washer after the mixer may be a diffusion washer.

Again there should be a back pressure on the mixer. This pressure is provided in the same way that the pressure is provided to mixer

211, by an upflow line, a pressure valve or a combination of these. The placement of the valve and the maximum pressures are the same as those for mixer 211.

These illustrate OCO and OCO sequences, and are exemplary of O-O-X and O-X-O sequences in general. In either sequence X may be chlorine, chlorine dioxide, a combination of chlorine or chlorine dioxide -

OMPI C_j-_j, D or a mixture of chlorine and chlorine dioxide, hypochlorites, peroxides or ozone. The mixers to be described may be used to mix these. The pulp may be treated with ozone by the treatment described in United States Patent Application serial number 836,449 filed September 26, 1977 or United States Patent Application serial number 2,491 dated January 11, 1979.

The amount of oxygen and the chemical used will depend, of course, on the K number of the unbleached pulp, the desired brightness and the number of bleach stages. As an example, an OOCOD sequence might use 14 to 20 kilograms of oxygen and 22 to 28 kilograms of sodium hydroxide per metric ton of oven-dry pulp in the first stage; 11 to 17 kilograms of oxygen and 17 to 22 kilograms of sodium hydroxide per metric ton of oven- dry pulp in the second stage; around 56 kilograms of chlorine per metric ton of oven-dry pulp in the third stage; 8 to 11 kilograms of oxygen per metric ton of oven-dry pulp in the fourth stage; and 14 to 16 kilograms of chlorine dioxide per metric ton of oven-dry pulp in the last stage. The temperature of the pulp would not be changed from the temperature of the washer for the chlorine treatment.

The remaining figures show several types of mixer that may be used with these systems. The exterior is the same in each; however, the internal structure does change.

In Figures 16-19 the mixer 550 has a cylindrical body 551 and two head plates 552 and 553. The pulp slurry enters through pipe 554, passes through the body of the mixer and exits through pipe 555. The oxygen manifolds 558, which supply oxygen to the stators 580 within the mixer, are supplied by oxygen lines 559.

A shaft 560 extends longitudinally of the mixer and is supported on bearings 561 and 562 and is rotated by rotational means 563. A chain belt drive is shown, but any other type of rotational means may be used. Rotors 570 are attached to the shaft 560. A typical rotor construction is shown in Figures 20-21. The rotor 570 has a body 571 which is tapered outwardly from the shaft and has an elliptically generated cross section. The preferred cross section is an ellipse. The major axis of the rotor is aligned with the direction of rotation of the rotor. Each of its leading and trailing edges 572 and 573 has a radius of the curvature in the range of 0.5 to 15 mm. The radii are usually the same, though they need not

OMPI be. If different, then the leading edge would have a greater radius than the trailing edge.

A modification is shown in Figures 22-23. A groove 574 is formed in the trailing edge 573' of the rotor. The groove is about 0.1 mm across. The groove may be coated with a hydrophobic material.

The number of rotors and the speed of the rotors will depend on the amount of pulp passing through the mixer and the consistency of the pulp passing through the mixer. The area swept by the rotors should be in the range of 10,000 to 1,000,000 square meters per metric ton of oven-dry pulp. The preferred range is 25,000 to 150,000 square meters per metric ton of oven-dry pulp. The optimum is considered to be around 65,400 square meters per metric ton of oven-dry pulp. This area is determined by the formula

1440 TT (r_χ ² - r₂ ²) (RXN)

A = where

2 A = area swept per metric ton, m /t r, = outer radius of the rotor, m txm = inner radius of the rotor, m

R = revolutions per minute of the rotor

N = number of rotors t = metric tons (Oven-Dry Basis) of pulp passing through the mixer per day.

There is a trade-off between the length of the individual rotors and the number of rotors. The rotors are usually arranged in rings on the central shaft. The number of rotors in a ring will depend upon the circumference of the central shaft and the size of the rotor base. A greater number of rotors would reqμire a longer and stiffer shaft. Fewer rotors would require longer rotors. Consequently, space for the mixer would determine the actual rotor configuration. Normally, there are a total of 4 to 400 rotors, and from 2 to 20 rotors in a ring.

The rotors rotate transversely of the direction of pulp movement through the mixer, describing a helical path through the pulp. The speed of rotation of the rotors would be determined by the motor, and the drive ratio between the motor and the central shaft.

OMPI The diameter of the central shaft 560 is at least one half of the internal diameter of the mixer, forming an annular space 568 through which the slurry passes.

The enlarged shaft requires scraper bars 564 and 565 on shaft ends 566 and 567. There normally would be four bars on each end. The bars remove fibers that tend to build up between the shaft and the mixer head plate. This prevents binding of the shaft in the mixer.

The stators are shown in Figures 24-26. The stators add oxygen to the pulp in the mixing zone and also act as friction devices to reduce or stop the rotation of the pulp with the rotors so that there is relative rotative movement between the rotors and the pulp. Each stator 580 has a body 581, a central passage 582 and a base plate 583. The stators extend through apertures 556 in body 551. There are two ways of attaching the stators. In Figure 24, the stator is attached to the body 551 by a friction fit using a Van Stone flange 584. This allows the stator to be rotated if it is desired to change the oxygen placement. In Figure 25, the base plate 583' is attached directly to the body 551 either by bolts or studs. The oxygen enters the mixer through check valves 590. The stators are round and tapered and the face having the check valves is flattened. The check valves face across a transverse plane of the mixer and in the direction of rotation of the rotors.

The purpose of the check valve 590 is to prevent the pulp fibers from entering the passage 582. A typical check valve is shown in Figure 27. The valve 590 consists of a valve body 591 which is threaded into stator body 581. The valve body has a valve seat 592. The valve itself consists of a bolt 593 and nut 594 which are biased into a closed position by spring 595.

The number of check valves in a stator may vary from 0 to 4. In some mixers, the major portion of the gas would be added at the mixer entrance, requiring up to 4 check valves, and little or no gas would be added near the mixer outlet, requiring 1 check valve or no check valves, and these stators would then only act as friction drag against pulp rotation. For example, between 60 to 70% of the oxygen could be added in the first half of the mixer. The first one third of the stators would have 3 or 4 check valves, the next one third might have 2 check valves, and the last one third might have 1 or no check valves.

The stators may also be arranged in rings. There being one ring of stators for each one or two rings of rotors. The number of stators in a

OMPI ring will depend upon the size of the mixer. Usually, there are 4 stators in a ring, but this can normally vary from 2 to 8.

Both the rotors and the stators should extend across the annular space. A normal clearance between the rotor and the inner wall of the mixer, or the stator and the outer wall of the central shaft is about 13 mm. This ensures that all of the pulp is contacted by the oxygen and there is no short circuiting of the pulp through the mixer without contact with oxygen. The rotors and stators should be between the inlet and outlet to ensure that all the pulp would pass through the swept area, and would be contacted with oxygen.

Figures 28-33 disclose a modification to the basic mixer. Oxygen is carried to the rotors through pipe 600 and passage 601 which extends centrally of shaft 560'. Radial passages 602 carry the oxygen to the outer annular manifold 603. The oxygen passes from the manifold to the pulp through central passage 604 of rotor body 605 and through -check valve 590". These valves are the same as valve 590.

The rotor is shown as round and tapered, but its shape may be different. The rotor may be round or square and nontapered such as those normally found in steam mixers. The round rotors would have radii of curvature exceeding 30 mm. Tapered rotors 606 having a rectangular cross section may also be used.

Figure 34 compares the operation of a modified mixer similar to that shown in Figures 28-33 with the operation of the mixer of Figures

16-27 and indicates the increasing efficacy of the mixer as the swept area is . increased and the shaft diameter is expanded. The casing of both mixers was the same. It had an interior diameter of 0.914 m. The inlet and the outlet were the same. In both, the outer radius of the rotor was the same,

0.444 m. Both processed pulp at the same rate, 810 metric tons of oven-dry pulp per day. The modified mixer had a speed of rotation of 435 RPM. There were 32 stators in 8 rings and 36 rotors in 9 rings. Each ring of rotors had 2 pegs and 2 blades. The blades were rectangular in cross section. The stators and rotor pegs were round, tapered outwardly and 0.254 m long.

Oxygen was admitted through the stators only. The diameter of the shaft was 0.38 m and the swept area was 14,100 square meters per metric ton of oven-dry pulp. The mixer of Figures 16-27 had the same internal diameter but had a central shaft that was 0.508 m in diameter. There were 224 rotors. The rotors were elliptical and linealy tapered. The major axis of the rotor extended in the direction of rotation of the rotor. The leading and trailing edges of the rotor had radii of curvature of 3.8 mm. The rotors were 19 cm long and extended to within about 13 mm of the reactor wall, and the stators extended to within about 13 mm of the central shaft. The speed of rotation of the rotors was 435 RPM. The swept area of the reactor was 72,200 square meters per metric ton of oven-dry pulp. Oxygen was admitted through the stators.

Figure 34 compares the extracted K number of the pulp with the additional K number drop after passing through the mixer, and shows that the mixer achieved a greater K number drop than the modified mixer. It was also found that the mixer needed only half the amount of oxygen as in the modified mixer to obtain the same amount of deiignification; that is, with the other operating conditions remaining the same, to achieve the same K number drop, 11 kilograms of oxygen per metric ton of oven-dry pulp were required in the modified mixer, but only 5 kilograms of oxygen per metric ton of oven-dry pulp were required in the mixer. It was also found that the mixer could mix greater amounts of oxygen with the pulp than the modi ied mixer. Between 1-1/2 to 2 times as much oxygen could be mixed with the pulp with the mixer than with the modified mixer. For example, the modified mixer could mix a maximum of 15.1-20.2 kilograms of oxygen with a metric ton of oven-dry pulp. The mixer could mix 30.2-35.3 kilograms of oxygen with a metric ton of oven-dry pulp.

The optimum swept area is achieved by reducing the number of rotors in the mixer from 224 to 203.

Figures 35-37 illustrate a different type of rotor and stator arrangement and a different type of oxygen admission. . In this modification, an oxygen manifold 610 surrounds the outer body 551" of the mixer and the gas enters the mixer through holes 611 in body 551". An annular dam 612, located between each ring of holes 611, is attached to the inner wall of body 551". The dams 612 create a pool of gas adjacent the mixer wall. The stators 585 are attached to the dams 612. The rotors 575 are aligned with the spaces between the dams 612. The outer radius -of the rotors 575 is greater than the inner radius of the dams 612 so that the rotors extend beyond the inner wall 608 of the dam into the trapped gas between the dams. This construction allows the rotor to extend into a gas pocket and for the gas to flow down the trailing edge of the rotor as it passes through the pulp slurry. The rotors and stators may be flat with rounded leading and trailing edges. Again, the radius of curvature of the leading and trailing edges would be in the range of 0.5 to 15 mm, and the radii need not be the same. The rotors and stators may be as narrow as 6.35 mm in width.

This design could also include the groove in the trailing edge of the rotor which may be covered with a hydrophobic coating.

OMPI

Claims

1. The process of mixing a chemical selected from the group consisting of noncondensable gases, unsaturated gases and highly super¬ heated steam with a wood pulp having a consistency of 7 to 15%, comprising passing said pulp through a mixing zone, adding said chemical to said pulp in said mixing zone, said mixing zone having a series of rotating members passing through said pulp In a direction transverse the direction of travel of said pulp, said members having a major axis extending in the direction of rotation, said members providing a swept area through said pulp of 10,000 to 1,000,000 square meters per metric ton of oven dry pulp, said members having leading and trailing edges, said leading edge having a radius of curvature in the range of 0.5 to 15 mm. ^*

2. The process of claim 1 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

3. The process of claim 1 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

4. The process of claim 1 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

5. The process of claims 1, 2, 3 or 4 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 6. The process of claims 1, 2, 3 or 4 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

7. The process of claims 1, 2, 3 or 4 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm. 8. The proce.ss of claims 1, 2, 3 or 4 in which said chemical is added incrementally to said-pulp.

9. The process of claims 1, 2, 3 or 4 in which said mixing takes place under a pressure of up to 830 kPa gage. 10. The process of claims 1, 2, 3 or 4 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation, and said mixing takes place under a pressure of up to 830 kPa gage.

11. The process of claims 1, 2, 3 or 4 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space, and said mixing takes place under a pressure of up to 830 kPa gage.

12. The process of claims 1, 2, 3 or 4 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm, and said mixing takes place under a pressure of up to 830 kPa gage.

13. The process of claim 1 further comprising adjusting said pulp to said consistency of 7 to 15%. 14. The process of claim 13 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

15. The process of claim 13 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

16. The process of claim 13 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

17. The process of claims 13, 14, 15 or 16 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

18. The process of claims 13, 14, 15 or 16 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

19. The process of claims 13, 14, 15 or 16 in which

-£tTRΪ -*

OMPI said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

20. The process of claims 13, 14, 15 or 16 in which said chemical is added incrementally to said pulp. 21. The process of claims 13, 14, 15 or 16 in which said mixing takes place under a pressure of up to 830 kPa gage.

22. The process of claims 13, 14, 15 or 16 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation, and said mixing takes place under a pressure of up to 830 kPa gage.

23. The process of claims 13, 14, 15 or 16 in which said mixing zone is an annular space in which the interior surface of said space has a radius of least one half of the radius of the exterior surface of said space, and said mixing takes place under a pressure of up to 830 kPa gage.

24. The process of claims 13, 14, 15 or 16 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, and said mixing takes place under a pressure of up to 830 kPa gage. 25. The process of claim 1 in which said chemical is selected from the group consisting of oxygen, ozone, air, chlorine, chlorine dioxide, sulphur dioxide, ammonia, nitrogen, carbon dioxide, hydrogen chloride, nitric oxide, nitrogen peroxide and highly superheated steam.

26. The process of claim 25 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

27. The process of claim 25 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp. 28. The process of claim 25 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

29. The process of claims 25, 26, 27 or 28 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

30. The process of claims 25, 26, 27 or 28 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half- of the radius of the exterior surface of said space.

31. The proce.ss of claims 25, 26, 27 or 28 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

32. The process of claims 25, 26, 27 or 28 in which said chemical is added incrementally to said pulp.

33. The process of claims 25, 26, 27 or 28 in which said mixing takes place under a pressure of up to 830 kPa gage.

34. The process of claims 25, 26, 27 or 28 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation, and said mixing takes place under a pressure of up to 830 kPa gage. 35. The process of claims 25, 26, 27 or 28 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space, and said mixing takes place under a pressure of up to 830 kPa gage. 36. The process of claims 25, 26, 27 or 28 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, and said mixing takes place under a pressure of up to 830 kPa gage.

37. The process of claim 25 further comprising adjusting said pulp to said consistency of 7 to 15%.

38. The process of claim 37 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

39. The process of claim 37 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

40. The process of claim 37 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp. 41. The process of claims 37, 38, 39 or 40 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 42. The process of claims 37, 38, 39 or 40 in which said mixing occurs in an annular space m which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space. 43. The process of claims 37, 38, 39 or 40 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

44. The process of claims 37, 38, 39 or 40 in which said chemical is added incrementally to said pulp slurry. 45. The process of claims 37, 38, 39 or 40 in which said mixing takes place under a pressure of up to 830 kPa gage.

46. The process of claims 37, 38, 39 or 40 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation, and said mixing takes place under a pressure of up to 830 kPa gage.

47. The process of claims 37, 38, 39 or 40 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space, and said mixing takes place under a pressure of up to 830 kPa gage.

48. The process of claims 37, 38, 39 or 40 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, and said mixing takes place under a pressure of up to 830 kPa gage. 49. The process of claim 1 in which said chemical is oxygen.

50. The process of claim 49 in which intimate contact is created between .said wood pulp and oxygen, and said pulp is treated with said oxygen, comprising adding said oxygen to said pulp, intimately mixing said oxygen with said pulp, said mixing occurring in said mixing zone, transporting said pulp to a storage tank, and storing said pulp in said storage tank. 51. The process of claim 50 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

OM 52. The process of claim 50 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

53. The process of claim 50 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

54. The process of claims 50, 51, 52 or 53 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 55. The process of claims 50, 51, 52 or 53 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

56. The process of claims 50, 51, 52 or 53 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

57. The process of claims 50, 51, 52 or 53 in which said oxygen is added incrementally to said pulp.

58. The process of claims 50, 51, 52 or 53 in which the amount of oxygen added to said pulp is 5 to 50 kilograms per metric ton of oven dry pulp.

59. The process of claims 50, 51, 52 or 53 in which the amount of oxygen added to said pulp is 22 to 28 kilograms per metric ton of oven dry pulp. 60. The process of claims 50, 51, 52 or 53 in which the amount of oxygen added to said pulp is 8 to 17 kilograms per metric ton of oven dry pulp.

61. The process of claims 50, 51, 52 or 53 in which said mixing of said oxygen takes place in less than 1 minute. 62. The process of claims 50, 51, 52 or 53 in which said mixing of said oxygen takes place under a pressure of up to 830 kPa gage.

63. The process of claim 50 further comprising before said mixing step, heating said pulp so that it will be at a temperature in_. the range of around 65°C to around 121°C during said mixing step.

OMPI 64. The process of claim 63 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

65. The process of claim 63 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

66. The process of claim 63 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp. 67. The process of claims 63, 64, 65 or 66 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

68. The proce.ss of claims 63, 64, 65 or 66 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

69. The process of claims 63, 64, 65 or 66 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm. 70. The process of claims 63, 64, 65 or 66 in which said oxygen is added incrementally to said pulp. 71. The process of claims 63, 64, 65 or 66 in which the amount of oxygen added to said pulp is 5 to 50 kilograms per metric ton of oven dry pulp. 72. The process of claims 63, 64, 65 or 66 in which the amount of oxygen added to said pulp is 22 to 28 kilograms per metric ton of oven dry pulp.

73. The process of claims 63, 64, 65 or 66 in which the amount of oxygen added to said pulp is 8 to 17 kilograms per metric ton of oven dry pulp.

74. The process of claims 63, 64, 65 or 66 in which said mixing of said oxygen takes place in less than 1 minute.

75. The process of claims 63, 64, 65 or 66 in which said mixing of said oxygen takes place under a pressure of up to 830 kPa gage.

76. The process of claim 50 further comprising adjusting said pulp to said consistency of 7 to 15%.

77. The process of claim 76 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. 78. The process of claim 76 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

79. The process of claim 76 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

80. The process of claims 76, 77, 78 or 79 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

81. The process of claims 76, 77, 78 or 79 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

82. The process of claims 76, 77, 78 or 79 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

83. The process of claims 76, 77, 78 or 79 in which said oxygen is added incrementally to said pulp.

84. The process of claims 76, 77, 78 or 79 in which the amount of oxygen added to said pulp is 5 to 50 kilograms per metric ton of oven dry pulp.

85. The process of claims 76, 77, 78 or 79 in which the amount of oxygen added to said pulp is 22 to 28 kilograms per metric ton of oven dry pulp.

86. The process of claims 76, 77, 78 or 79 in which the amount of oxygen added to said pulp is 8 to 17 kilograms per metric ton of oven dry pulp.

87. The process of claims 76, 77, 78 or 79 in which said mixing of said oxygen takes place in less than 1 minute.

88. The process of claims 76, 77, 78 or 79 in which said mixing of said oxygen takes place under a pressure of up to 30 kPa gage.

OMFI

WΓFO 89. The process of claim 76 further comprising before said mixing step, heating said pulp so that it will be at a temperature in the range of around 65°C to around 121°C during said mixing step. 90. The process of claim 89 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

91. The process of claim 89 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

92. The process of claim 89 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

93. The process of claims 89, 90, 91 or 92 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

94. The process of claims 89, 90, 91 or 92 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

95.. The process of claims 89, 90, 91 or 92 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

96. The process of claims 89, 90, 91 or 92 in which said oxygen is added incrementally to said pulp.

97. The process of claims 89, 90, 91 or 92 in which the amount of oxygen added to said pulp is 5 to 50 kilograms per metric ton of oven dry pulp.

98. The process of claims 89, 90, 91 or 92 in which the amount of oxygen added to said pulp is 22 to 28 kilograms per metric ton of oven dry pulp.

99. The process of claims 89, 90, 91 or 92 in which the amount of oxygen added to said pulp is 8 to 17 kilograms per metric ton of oven dry pulp. 100. The process of claims 89, 90, 91 or 92 in which said mixing of said oxygen takes place in less than 1 minute.

OMPI 101. The process of claims 89, 90, 91 or 92 in which said mixing of said oxygen takes place under a pressure of up to 830 kPa gage.

102. The process of claim 49 in which intimate contact is created between said wood pulp and said pulp is treated with said oxygen, comprising adding oxygen to said pulp, mixing said oxygen with said pulp, said mixing occurring in said mixing zone, transporting said pulp to a washer, and washing said pulp in said washer.

103. The process of claim 102 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. 104. The process of claim 102 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

105. The process of claim 102 in which said swept area is around 65,400.square meters per metric ton of oven dry pulp.

106. The process of claims 102, 103, 104 or 105 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

107. The process of claims 102, 103, 104 or 105 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

108. The process of claims 102, 103, 104 or 105 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

109. The process of claims 102, 103, 104 or 105 in which ^' said oxygen is added incrementally to said pulp.

110. The process of claims 102, 103, 104 or 105 in which the amount of oxygen added to said pulp is from 5 to 50 kilograms per metric ton of oven dry pulp.

111. The process of claims 102, 103, 104 or 105 in which

OMPI ^• the amount of oxygen added to said pulp is from 22 to 28 kilograms per metric ton of oven dry pulp.

112. The process of claims 102, 103, 104 or 105 in which the amount of oxygen added to said pulp is from 8 to 17 kilograms per metric ton of oven dry pulp.

113. The process of claims 102, 103, 104 or 105 in which said mixing takes place in less than 1 minute.

114. The process of claims 102, 103, 104 or 105 in which said mixing takes place under a pressure of up to 830 kPa gage. 115. The process of claim 102 further comprising prior to said mixing, heating said pulp so that it will be at a temperature in the range of around 65°C to around 121°C during said mixing.

116. The process of claim 115 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

117. The process of claim 115 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp. 118. The process of claim 115 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

119. The process of claims 115, 116, 117 or 118 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

120. The process of claims 115, 116, 117 or 118 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space. 121. The process of claims 115, 116, 117 or 118 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

122. The process of claims 115, 116, 117 or 118 in which said oxygen is added incrementally to said pulp. 123. The process of claims 115, 116, 117 or 118 in which the amount of oxygen added to said pulp is from 5 to 50 kilograms per metric ton of oven dry pulp.

OMPI 124. The process of claims 115, 116, 117 or 118 in which the amount of oxygen added to said pulp is from 22 to 28 kilograms per metric ton of oven dry pulp.

125. The process of claims 115, 116, 117 or 118 in which the amount of oxygen added to said pulp is from 8 to 17 kilograms per metric ton of oven dry pulp.

126. The process of claims 115, 116, 117 or 118 in which said mixing takes place in less than 1 minute.

127. The process of claims 115, 116, 117 or 118 in which said mixing takes place under a pressure of up to 830 kPa gage.

128. The proce.ss of claim 102 further comprising adjusting said pulp to said consistency of 7 to 15%.

129. The process of claim 128 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

130. The process of claim 128 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

131. The process of claim 128 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

132. The process of claims 128, 129, 130 or 131 in which said members have elliptically generated cross sections having a * major axis extending in the direction of rotation. 133. The process of claims 128, 129, 130 or 131 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

134. The process of claims 128, 129, 130 or 131 in which said trailing edge has a radius of curvature in the range of 0.5 to

15mm.

135. The process of claims 128, 129, 130 or 131 in which said oxygen is added incrementally to said pulp.

136. The process of claims 128, 129, 130 or 131 in which the amount of oxygen added to said pulp is from 5 to 50 kilograms per metric ton of oven dry pulp. 137. The process of claims 128, 129, 130 or 131 in which the amount of oxygen added to said pulp is from 22 to 28 kilograms per metric ton of oven dry pulp.

138. The process of claims 128, 129, 130 or 131 in which the amount of oxygen added to said pulp is from 8 to 17 kilograms per metric ton of oven dry pulp.

139. The process of claims 128, 129, 130 or 131 in which said mixing takes place in less than 1 minute.

140. The process of claims 128, 129, 130 or 131 in which said mixing takes place under a pressure of up to 830 kPa gage.

141. The process of claim 128 further comprising prior to said mixing, heating said pulp so that it will be at a temperature in the range of around 65°C to around 121°C during said mixing. 142. The process of claim 141 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. .

143. The process of claim 141 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

144. The process of claim 141 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

145. The process of claims 141, 142, 143 or 144 in which said members have elliptically generated cross setions having a major axis extending in the direction of rotation.

146. The process of claims 141, 142, 143 or 144 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

147. The process of claims 141, 142, 143 or 144 In which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

148. The process of claims 141, 142, 143 or 144 in which said oxygen is added incrementally to said pulp.

149. The process of claims 141, 142, 143 or 144 in which

-£ REA ζT

OMPI the amount of oxygen added to said pulp is from 5 to 50 kilograms per metric ton of oven dry pulp.

150. The process of claims 141, 142, 143 or 144 in which the amount of oxygen added to said pulp is from 22 to 28 kilograms per metric ton of oven dry pulp.

151. The process of claims 141, 142, 143 or 144 in which the amount of oxygen added to said pulp is from 8 to 17 kilograms per metric ton of oven dry pulp.

152. The process of claims 141, 142, 143 or 144 in which said mixing takes place in less than 1 minute.

153. The process of claims 141, 142, 143 or 144 in which said mixing takes place under a pressure of up to 830 kPa gage.

154. The process of claim 49 in which intimate contact is created between oxygen and said wood pulp and said pulp is treated with said oxygen while using an alkali to extract bleaching by-products from pulp, comprising transporting said pulp to a storage tank, storing said pulp in said storage tank for a time of 1/2 to 4 hours, and after said storage, washing extraction by-products from said pulp, before said storage step, adding alkali to said pulp, said alkali being added in an amount in the range of 1/2 to 7%, expressed as sodium hydroxide, based on the oven dry weight of said pulp, and heating said pulp; and between said heating and said storage steps, adding said oxygen to said pulp, intimately mixing said oxygen with said pulp, said mixing occurring in said mixing zone.

155. The process of claim 154 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

156. The process of claim 154 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp. 157. The process of claim 154 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp. 158. The process of claims 154, 155, 156 or 157 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

159. The process of claims 154, 155, 156 or 157 in which said mixing occurs in -an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

160. The process of claims 154, 155, 156 or 157 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

161. The process of claims 154, 155, 156 or 157 in which said oxygen is added incrementally to said pulp.

162. The process of claims 154, 155, 156 or 157 in which the amount of oxygen added to said pulp is from 9 to 23 kilograms per metric ton of oven-dry pulp.

163. The process of claims 154, 155, 156 or 157 in which said mixing takes place in less than 1 minute.

164. The process of claims 154, 155, 156 or 157 in which said mixing takes place under a pressure of up to 830 kPa gage. 165. The process of claim 154 in which the consistency of said pulp is reduced to 1 to 2% between said storage step and said washing step.

166. The process of claim 165 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

167. The process of claim 165 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

168. The process of claim 165 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

169. The process of claims 165, 166, 167 or 168 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 170. The process of claims 165, 166, 167 or 168 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half- of the radius of the exterior surface of said space.

171. The process of claims 165, 166, 167 or 168 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

172. The process of claims 165, 166, 167 or 168 in which said oxygen is added incrementally to said pulp.

173. The process of claims 165, 166, 167 or 168 in which the amount of oxygen added to said pulp is from 9 to 23 kilograms per metric ton of oven dry pulp.

174. The process of claims 165, 166, 167 or 168 in which said mixing takes place in less than 1 minute.

175. The process of claims 165, 166, 167 or 168 in which said mixing takes place under a pressure of up to 830 kPa gage.

176. The process of claim 154 further comprising adjusting said pulp slurry to said consistency of 7 to 15%.

177. The process of claim 176 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

178. The process of claim 176 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

179. The process of claim 176 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp.

180. The process of claims 176, 177, 178 or 179 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 181. The process of claims 176, 177, 178 or 179 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

182. The process of claims 176, 177, 178 or 179 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

^* giTB.EA7

OMPI 183. The process of claims 176, 177, 178 or 179 in which said oxygen is added incrementally to said pulp.

184. The process of claims 176, 177, 178 or 179 in which the amount of oxygen added to said pulp is from 9 to 23 kilograms per metric ton of oven dry ton.

185. The process of claims 176, 177, 178 or 179_. in which said mixing takes place in less than 1 minute.

__ 186. The process of claims 176, 177, 178 or 179 in which said mixing takes place under a pressure of up to 830 kPa gage. 0 187. The process of claim 176 in which the consistency of said pulp is reduced to 1 to 2% between said storage step and said washing step.

188. The process of claim 187 in which said swept area is 14,100 to 1,000,000 square meters per metric -5 ton of oven dry pulp.

189. The process of claim 187 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

190. The process of claim 187 in which 0 said swept area is around 65,400 square meters per metric ton of oven dry pulp.

191. The process of claims 187, 188, 189 or 190 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 5 192. The process of claims 187, 188, 189 or 190 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

193. The process of claims 187, 188, 189 or 190 in which 0 said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

194. The process of claims 187, 188, 189 or 190 in which said oxygen is added incrementally to said pulp.

195. The process of claims 187, 188, 189 or 190 in which 5 the amount of oxygen added to said pulp is from 9 to 23 kilograms per metric ton of oven dry pulp.

-^JRE ^ 196. The process of claims 187, 188, 189 or 190 in which said mixing takes place in less than 1 minute^":

197. The process of claims 187, 188, 189 or 190 in which said mixing takes place under a pressure of up to 830 kPa gage. 198. The process of claim 49 comprising treating said pulp at a consistency of 7 to 15% with oxygen at an alkaline pH and a temperature of around 65°C to around 121°C, washing said oxygen treated pulp, treating said washed pulp with a bleaching chemical selected from a group consisting of chlorine, chlorine dioxide, combinations of chlorine and chlorine dioxide, hypochlorites, peroxides and ozone, washing said bleaching chemical treated pulp, and treating said latter washed pulp at a consistency of 7 to 15% with oxygen at an alkaline pH and a temperature of around 65 C to around 121°C, said oxygen in each of said oxygen treatments being mixed with said pulp in one of said mixing zones.

199. The process of claim 198 in which in each of said oxygen mixings said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

200. The process of claim 198 in which in each of said oxygen mixings said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

201. The process of claim 198 in which in each of said oxygen mixings said swept area is around 65,400 square meters per metric ton of oven dry pulp.

202. The process of claims 198, 199, 200 or 201 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 203. The process of claims 198, 199, 200 or 201 in which each of said oxygen mixings occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

204. The process of claims 198, 199, 200 or 201 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm. 205. The process of claims 198, 199, 200 or 201 in which in each of said oxygen mixings said oxygen is added incrementally to said pulp.

206. The process of claims 198, 199, 200 or 201 in which in each of said oxygen mixings said mixing takes place under a pressure of up to 830 kPa gage.

207. The process of claims 198, 199, 200 or 201 in which prior to each of said oxygen mixings said pulp is heated to said temperature of around 65°C to around 121 C in said oxygen mixing. 208. The process of claim 198 in which said first oxygen treatment is preceded by a treatment of said pulp at a consistency of 7 to 15% with oxygen at an alkaline pH and a temperature of around 65°C to around 121 C, and washing said oxygen pretreated pulp, said oxygen being mixed with said pulp in a mixing zone.

209. The process of claim 208 in which

- in each of said oxygen mixings said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

210. The process of claim 208 in which in each of said oxygen mixings said swept area is 25,000 to

150,000 square meters per metric ton of oven dry pulp.

211. The process of claim 208 in which in each of said oxygen mixings said swept area is around 65,400 square meters per metric ton of oven dry pulp. 212. The process of claims 208, 209, 210 or 211 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

213. The process of claims 208, 209, 210 or 211 in which each of said oxygen mixings occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

214. The process of claims 208, 209, 210 or 211 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm. 215. The process of claims 208, 209, 210 or 211 in which in each of said oxygen mixings said oxygen is added incrementally to said pulp. ^

OMPI 216. The process of claims 208, 209, 210 or 211 in which in each of said oxygen mixings said mixing- takes place under a pressure of up to 830 kPa gage.

217. The process of claims 208, 209, 210 or 211 in which prior to each of said oxygen mixings said pulp is heated to said temperature of around 65°C to around 121°C in said oxygen mixing.

218. The process of claim 198 further comprising prior to each of said oxygen mixings adjusting said pulp to said consistency of 7 to 15%. 219. The process of claim 218 in which in each of said oxygen mixings said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

220. The process of claim 218 in which in each of said oxygen mixings said swept are is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

221. The process of claim 218 in which in each of said oxygen mixings said swept area is around 65,400 square meters per metric ton of oven dry pulp.

222. The process of claims 218, 219, 220 or 221 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

223. The process of claims 218, 219, 220 or 221 in which each of said oxygen mixings occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

224. The process of claims 218, 219, 220 or 221 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

225. The process of claims 218, 219, 220 or 221 in which in each of said oxygen mixings said oxygen is added incrementally to said pulp.

226. The process of claims 218, 219, 220 or 221 in which in each of said oxygen mixings said mixing takes place under a pressure of up to 830 kPa gage. 227. The process of claims 218, 219, 220 or 221 in which prior to each of said oxygen mixings said pulp is heated to said temperature of around 65°C to around 121°C in said oxygen mixing. 228. The process of claim 218 in which said first oxygen treatment is preceded by_a treatment of said pulp at a consistency of 7 to 15% with oxygen at an alkaline pH and a temperature of around 65°C to around 121°C, and washing said oxygen pretreated pulp, said oxygen being mixed with said pulp in one of said mixing zones.

229. The process of claim 228 in which in each of said oxygen mixings said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. _ 230. The process of claim 228 in which in each of said oxygen mixings said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

231. The process of claim 228 in which in each of said oxygen mixings said swept area is around 65,400 square meters per metric ton of oven dry pulp.

232. The process of claims 228, 229, 230 or 231 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation. 233. The process of claims 228, 229, 230 or 231 in which each of said oxygen mixings occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

234. The process of claims 228, 229, 230 or 231 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

235. The process of claims 228, 229, 230 or 231 in which in each of said oxygen mixings said oxygen is added incrementally to said pulp. 236. The process of claims 228, 229, 230 or 231 in which in each of said oxygen mixings said mixing takes place under a pressure of up to 830 kPa gage.

237. The process of claims 228, 229, 230 or 231 in which prior to each of said oxygen mixings said pulp is heated to said temperature of around 65°C to around 121°C in said oxygen mixing.

238. The process of claim 49 further comprising

OMPI forming said pulp by continuously digesting wood chips with chemicals under heat and pressure to form deiignification products and delignified wood chips, removing at least a part of said deiignification products, forming said pulp from said delignified wood chips by partially releasing the pressure from said wood chips, transporting a slurry containing said wood pulp and remaining deiignification products under pressure to a storage tank, and storing said slurry in said tank, prior to said storage, adjusting the pH of said slurry to a pH in the range of 8 to 14, between said pH adjustment and said storage, adding said oxygen to said slurry, between said pH adjustment and said storage, mixing said oxygen with said slurry in said mixing zone.

239. The process of claim 238 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

240. The process of claim 238 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

241. The process of claim 238 in which said swept area is around 65,400 square meters per metric ton of oven dry pulp. 242. The process of claims 238, 239, 240 or 241 in which

.said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

243. The process of claims 238, 239, 240 or 241 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

244. The process of claims 238, 239, 240 or 241 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm. 245. The process of claims 238, 239, 240 or 241 in which said oxygen is added incrementally to said pulp.

OMPI 246. The process of claims 238, 239, 240 or 241 in which the amount of oxygen added to said pulp is from 5 to 50 kilograms per metric ton of oven dry ton.

247. The process of claims 238, 239, 240 or 241 In which the pH is adjusted by adding alkali, expressed as sodium hydroxide, in an amount in the range of 0.25 to 8% based on the oven dry weight of said pulp.

248. The process of claims 238, 239, 240 or 241 in which prior to said mixing, heating said slurry to a temperature in the range of around 65°C to around 121 °C during said mixing.

249. The process of claims 238, 239, 240 or 241 in which said slurry is subject to a pressure of up to 830 kPa gage during said mixing.

250. The process of claim 49 further comprising forming said pulp by continuously digesting wood chips with chemicals under heat and pressure to form deiignification products and delignified wood chips, removing at least a part of said deiignification products, forming said pulp from said delignified wood chips by partially releasing the pressure from said wood chips, transporting a slurry containing said pulp and remaining deiigni¬ fication products under pressure to a diffusion washer, washing said pulp in said diffusion washer, prior to said diffusion washing adjusting the pH of said slurry to a pH in the range of 8 to 14, between said pH adjustment and said diffusion washing, adding oxygen to said slurry, between said pH adjustment and said diffusion washing, mixing said oxygen with said slurry in said mixing zone. 251. The process of claim 250 in which said swept area is 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

252. The process of claim 250 in which said swept area is 25,000 to 150,000 square meters per metric ton of oven dry pulp.

253. The process of claim 250 in which

MP said swept area is around 65,400 square meters per metric ton of oven dry pulp.

254. The process of claims 250, 251, 252 or 253 in which said members have elliptically generated cross sections having a major axis extending in the direction of rotation.

255. The process of claims 250, 251, 252 or 253 in which said mixing occurs in an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space. 256. The process of claims 250, 251, 252 or 253 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

257. The process of claims 250, 251, 252 or 253 in which said oxygen is added incrementally to said pulp. 258. The process of claims 250, 251, 252 or 253 in which the amount of oxygen added to said pulp is from 5 to 50 kilograms per metric ton of oven dry ton.

259. The process of claims 250, 251, 252 or 253 in which said pH is adjusted by adding alkali, expressed as sodium hydroxide, in an amount in the range of 0.25 to 8% based on the oven dry weight of said pulp.

260. The process of claims 250, 251, 252 or 253 in which prior to said mixing, heating said slurry to a temperature in the range of around 65°C to around 121°C during said mixing. 261. The process of claims 250, 251, 252 or 253 in which said slurry is subject to a pressure of up to 830 kPa gage during said mixing.

262.^" A mixer for mixing a chemical selected from the group consisting of noncondensable gases, unsaturated gases and highly super- heated steam with a slurry comprising a casing, an inlet at one end of said casing and an outlet at the opposite end of said casing, a shaft in said casing, said casing, said inlet and said outlet, and said shaft defining a mixing zone,

OMFI V/IP a plurality or rotors on said shaft in said mixing zone, said rotors having leading and trailing edges, said leading edge having a radius of curvature in the range of 0.5 to 15 mm, said rotors being rotatable through said slurry in a direction transverse to the direction of travel of said slurry, said rotors having a major axis extending in the direction of rotation, means for rotating said rotors, and said rotors providing a swept area of 10,000 to 1,000,000 square meters per metric ton of oven dry solid material in said slurry.

263. The mixer of claim 262 in -which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry solid material in said slurry.

264. The mixer of claim 262 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry solid material in said slurry.

265. The mixer of claim 262 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry solid material is said slurry. 266. The mixer of claims 262, 263, 264 or 265 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of. rotation.

267. The mixer of claims 262, 263, 264 or 265 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one-half of the radius of the exterior surface of said space.

268. The mixer of claims 262, 263, 264 or 265 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm. 269. The mixer of claims 262, 263, 264 or 265 in which said trailing edge has a groove extending lengthwise of said trailing edge.

270. The mixer of claims 262, 263, 264 or 265 in which said rotors are tapered outwardly. 271. The mixer of claims 262, 263, 264 or 265 further comprising

&TFIEA

OMPI a plurality of stators extending into said mixing zone from said casing, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

272. The mixer of claims 262, 263, 264 or 265 further comprising said rotors having elliptically generated cross sections having a major axis extending in the direction of rotation, a plurality of stators extending into said mixing zone from said casing, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

273. The mixer of claims 262, 263, 264 or 265 further comprising said mixing zone being an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space, a plurality of stators extending into said mixing zone from said casing, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

274. The mixer of claims 262, 263, 264 or 265 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, a plurality of stators extending into said mixing zone from said casing, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

- TlR£A OMPI IPO 275. The mixer of claims 262, 263, 264 or 265 further comprising circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams.

276. The mixer of claims 262, 263, 264 or 265 further comprising said mixing zone being an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the Interior edge of said dams.

277. The mixer of claims 262, 263, 264 or 265 further comprising said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams.

278. The mixer of claims 262, 263, 264 or 265 further comprising circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams, and a plurality of stators extending into said mixing zone from said dams.

279. The mixer of claims 262, 263, 264 or 265 further comprising said mixing zone being an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams, and a plurality of stators extending into said mixing zone from said dams.

OMPI 280. The mixer of claims 262, 263, 264 or 265 further comprising said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams, a plurality of stators extending into said mixing zone from said dams. 281. The mixer of claims 262, 263, 264 or 265 further comprising circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams, apertures in said mixer casing, said apertures being aligned with the spaces between said dams, and means for delivering said chemical to said apertures.

282. The mixer of claims 262, 263, 264 or 265 further comprising said mixing zone being an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams, apertures in said mixer casing, said apertures being aligned with the spaces between said dams, and means for delivering said chemical to said apertures.

283. The mixer of claims 262, 263, 264 or 265 further comprising said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams, apertures in said mixer casing, said apertures being aligned with the spaces between said dams, and

OMPI means for delivering said chemical to said apertures.

284. The mixer of claims 262, 263, 264 or 265 further comprising circumferential dams in the interior of said casing, said rotors being aligned with the spaces between .said dams, said rotors extending beyond the interior edge of said dams, a plurality of stators extending into said mixing zone from said dams, apertures in said mixer casing, said apertures being aligned with the spaces between said dams, and means for delivering said chemical to said apertures.

285. The mixer of claims 262, 263, 264 or 265 further comprising said mixing zone being an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior .surface of said space, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the .interior edge of said dams, a plurality of stators extending into said mixing zone from said dams, apertures in said mixer casing, said apertures being aligned with the spaces between said dams, and means for delivering said chemical to said apertures. 286. The mixer of claims 262, 263, 264 or 265 further comprising said trailing edge has a radius of curvature in the range of 0.5 to 15 mm, circumferential dams in the interior of said casing, said rotors being aligned with the spaces between said dams, said rotors extending beyond the interior edge of said dams, a plurality of stators extending into said mixing zone from said dams, apertures in said mixer casing, said apertures being aligned with the spaces between said dams, and means for delivering said chemical to said apertures.

-f JREΛ cT OMPI 287. The apparatus of claim 262 for intimately mixing said slurry with oxygen, said slurry being a pulp having a consistency of 7 to 15%, and treating said pulp with said oxygen_?- further comprising means for transporting said pulp to a storage tank, and a storage tank, before said storage tank, means for adding alkali to said pulp, means for adding oxygen to said pulp, and means for mixing said oxygen with said pulp, said mixing means having said mixing zone.

288. The apparatus of claim 287 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

289. The apparatus of claim 287 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

290. The apparatus of claim 287 in which

. said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp. 291. The apparatus of claims 287, 288, 289 or 290 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

292. The apparatus of claims 287, 288, 289 or 290 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one-half of the radius of the exterior surface of said space.

293. The apparatus of claims 287, 288, 289 or 290 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm. 294. The apparatus of claims 287, 288, 289 or 290 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage. 295. The apparatus of claim 287, 288, 289 or 290 further comprising a valve in said transportation means between said mixing means and said storage tank. 296. The apparatus of claim 287 further comprising before said mixing means, means for heating said pulp so that it will be at a temperature in the range of around 65°C to around 121 C in said mixing means.

297. The apparatus of claim 296 in which said rotors provide a swept are of 14,000 to 1,000,000 square meters per metric ton of oven dry pulp.

298. The apparatus of claim 296 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp. 299. The apparatus of claim 296 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

. 300. The apparatus of claims 296, 297, 298 or 299 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

301. The apparatus of claims 296, 297, 298 or 299 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space. 302. The apparatus of claims 296, 297, 298 or 299 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

303. The apparatus of claims 296, 297, 298 or 299 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said zone lengthwise through said stator and a second passage communicating between said first passage and said zone, and a check valve in said second passage. 304. The apparatus of claims 296, 297, 298 or 299 further comprising a valve in said transportation means between said mixing means and said storage tank.

305. The apparatus of claim 287 further comprising means, prior to said addition means, for adjusting said consistency of said pulp to 7 to 15%.

306. The apparatus of claim 305 in which said rotors provide a swept are of 14,000 to 1,000,000 square meters per metric ton of oven dry pulp.

307. The apparatus of claim 305 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

308. The apparatus of claim 305 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp. 309. The apparatus of claims 305, 306, 307 or 308 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

310. The apparatus of claims 305, 306, 307 or 308 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

311. The apparatus of claims 305, 306, 307 or 308 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm. 312. The apparatus of claims 305, 306, 307 or 308 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said zone lengthwise through said stator and a second passage communicating between said first passage and said zone, and a check valve in said second passage.

313. The apparatus of claims 305, 306, 307 or 308 further comprising a valve in said transportation means between said mixing means and said storage tank.

314. The apparatus of claim 305 further comprising

CMPI before said mixing means, means for heating said pulp so that it will be at a temperature in the range of around 65°C to around 121°C in said mixing means.

315. The apparatus of claim 314 in which

5 said rotors provide a swept are of 14,000 to 1,000,000 square meters per metric ton of oven dry pulp.

316. The apparatus of claim 314 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp. 10 317. The apparatus of claim 314 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

318. The apparatus of claims 314, 315, 316 or 317 in which said rotors have elliptically generated cross sections having a 15 major axis extending in the direction of rotation.

319. The apparatus of claims 314, 315, 316 or 317 in which said mixing zone is an annular space in which the interior surface of said space has a radius_, of at least one half of the radius of the exterior surface of said space. 20 320. ^• The apparatus of claims 314, 315, 316 or 317 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

321. The apparatus of claims 314, 315, 316 or 317 further comprising 25 a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said zone lengthwise through said stator and a second passage communicating between said first passage and said zone, and a check valve in said second passage. 30 322. The apparatus of claims 314, 315, 316 or 317 further comprising a valve in said transportation means between said mixing means and said storage tank.

323. The apparatus of claim 262 comprising a pulp extraction ^' 35 stage in which said slurry is a pulp comprising means for adjusting the consistency of said pulp to 7 to 15%,

^g JR^EX

OMPI means for transporting said pulp from said consistency adjustment means to a storage tank, said storage tank, means, after said tank, for washing said pulp, means, before said tank, for adding alkali to said pulp, means, between said consistency adjustment means and said tank, for heating said pulp, between said heating means and said storage tank, means for adding oxygen to said pulp, and means for mixing said oxygen with said pulp, said mixing means having said mixing, zone.

324. The apparatus of claim 323 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. 325. The apparatus of claim 323 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

326. The apparatus of claim 323 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

327. The apparatus of claims 323, 324, 325 or 326 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

328. The apparatus of claims 323, 324, 325 or 326 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one-half of the radius of the exterior surface of said space.

329. The apparatus of claims 323, 324, 325 or 326 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

330. The apparatus of claims 323, 324, 325 or 326 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

331. The apparatus of claims 323, 324,- 325 or 326 further comprising a valve in said transportation means between said mixing means and said storage tank.

332. The apparatus of claim 323 further comprising means, before said washing means, for reducing the consistency of said pulp to 1 to 2% in said subsequent washing means.

333. The apparatus of claim 332 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

334. The apparatus of claim 332 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp. 335. The apparatus of claim 332 in which said rotors provide a swept area of around 65,400 .square meters per metric ton of oven dry pulp.

336. The apparatus of claims 332, 333, 334 or 335 further comprising said rotors having elliptically generated cross sections having a major axis extending in the direction of rotation.

337. The apparatus of claims 332, 333, 334 or 335 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

338. The apparatus of claims 332, 333, 334 or 335 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

339. The apparatus .of claims 332, 333, 334 or 335 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve In said second passage.

340. The apparatus of claims 332, 333, 334 or 335 further comprising

a valve in said transportation means between said mixing means and said storage tank.

341. The apparatus of claim 262 for creating intimate contact between said slurry and oxygen, said slurry being a pulp having a consistency of 7 to 15%, and treating said pulp with said oxygen, further comprising means for transporting said pulp to a washing means, and said means for washing said pulp, before said washing means, means for adding alkali to said pulp, means for adding oxygen to said pulp, and means for mixing said oxygen- with said pulp^", said mixing means having said mixing zone.

342. The apparatus of claim 341 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

343. The apparatus of claim 341 in which said rotors provide a swept area of 25,000 to 150>000 square meters per metric ton of oven dry pulp.

344. The apparatus of claim 341 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

345. The apparatus of claims 341, 342, 343 or 344 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation. 346. The apparatus of claims 341, 342, 343 or 344 in which said mixing zone is an annular space in which the interior space of said space has a radius of at least one-half of the radius of the exterior surface of said space.

347. The apparatus of claims 341, 342, 343 or 344 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

348. The apparatus of claims 341, 342, 343 or 344 further comprising a plurality of stators extending into said mixing zone from said casing,

O -TPI - IP - at least some of said stators having a first passage extending from outside of said mixing zone Iengthwi.se through said -stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage. 349. The apparatus of claims 341, 342, 343 or 344 further comprising a valve in said transportation means between said mixing means and said washing means.

350. The apparatus of claim 341 further comprising before said mixing means, means for heating said pulp so that it will be at a temperature in the range of around 65°C to around 121°C in said mixing means.

351. The apparatus of claim 350 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

352. The apparatus of claim 350 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

353. The apparatus of claim 350 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

354. The apparatus of claims 350, 351, 352 or 353 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation. 355. The apparatus of claims 350, 351, 352 or 353 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

356. The apparatus of claims 350, 351, 352 or 353 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

357. The apparatus of claims 350, 351, 352 or 353 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and 35

a check valve in said second passage.

358. The apparatus of claims 350, 351, ^* 352 or 353 further comprising a valve in said transportation means between said mixing means and said washing means.

359. The apparatus of claim 341 further comprising means for adjusting said consistency of said pulp to 7 to 15%.

360. The apparatus of claim 359 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

361. The apparatus of claim 359 in which „ said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

362. The apparatus of claim 359 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

363. The apparatus of claims 359, 360, 361 or 362 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation. 364. The apparatus of claims 359, 360, 361 or 362 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

365. The apparatus of claims 359, 360, 361 or 362 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

366. The apparatus of claims 359, 360, 361 or 362 further comprising a plurality of stators extending into said mixing zone from said casing, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage. 367. The apparatus of claims 359, 360, 361 or 362 further comprising

OMPI a valve in said transportation means between said mixing means and said washing means.

368. The apparatus of claim 359 further comprising before said mixing means, means for heating said pulp so that it will be at a temperature in the range of around 65°C to around 121°C in said mixing means.

369. The apparatus of claim 368 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. 370. The apparatus of claim 368 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

371. The apparatus of claim 368 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

372. The apparatus of claims 368, 369, 370 or 371 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

373. The apparatus of claims 368, 369, 370 or 371 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

374. The apparatus of claims 368, 369, 370 or 371 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

375. The apparatus of claims 368, 369, 370 or 371 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

376. The apparatus of claims 368, 369, 370 or 371 further comprising a valve in said transportation means between said mixing means and said washing means.

C:.-?l 377. The apparatus of claim 262 in which said slurry is a pulp slurry comprising first means for adding a pH adjustment chemical to pulp, second means after said first means for adding oxygen to said pulp, third means for mixing said oxygen with said pulp, fourth means after said third means for washing said oxygen treated pulp, fifth means after said fourth means for adding a chemical selected from the group consisting of chlorine, chlorine dioxide, a combina¬ tion of chlorine and chlorine dioxide, hypochlorite, peroxide and ozone to said pulp, sixth means for mixing said latter chemical with said pulp, seventh means after said sixth means for washing said pulp, eighth means after said seventh means for adding a pH adjustment chemical to said pulp, ninth means after said eighth means for adding oxygen to said pulp, tenth means for mixing said oxygen with said pulp, eleventh means for transporting said pulp from said first through tenth means, each of said oxygen mixing means having said mixing zone.

378. The apparatus of claim 377 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

379. The apparatus of claim 377 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

380. The apparatus of claim 377 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

381. The apparatus of claims 377, 378, 379 or 380 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation. 382. The apparatus of claims 377, 378, 379 or 380 in which

-^ΌREAT

OMPI said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

383. The apparatus of claims 377, 378, 379 or 380 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

384. The apparatus of claims 377, 378, 379 or 380 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

385. The apparatus of claims 377, 378, 379 or 380 further comprising means, prior to each of said oxygen mixing means, for heating said pulp so that it will be at a temperature in the range of around 65°C to around 121°C in said mixing means.

386. The apparatus of claims 377, 378, 379 or 380 further comprising a valve in said transportation means after each of said oxygen mixing means.

387. The apparatus of claim 377 further comprising first additional means for adding a pH adjustment chemical to said pulp, second additional means after said first additional means for adding oxygen to said pulp, third additional means for mixing said oxygen with said pulp, and fourth additional means after said third additional means and prior to said first means for washing said pulp, said oxygen mixing means having said mixing zone.

388. The apparatus of claim 387 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. 389. The apparatus of claim 387 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

OMPI 390. The apparatus of claim 387 in which said rotors provide a swept area of around ^"65,400 square meters per metric ton of oven dry pulp.

391. The apparatus of claims 387, 388, 389 or 390 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

392. The apparatus of claims 387, 388, 389 or 390 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

393. The apparatus of claims 387, 388, 389 or 390 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

394. The apparatus of claims 387, 388, 389 or 390 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

395. The apparatus of claims 387, 388, 389 or 390 further comprising means, prior to each of said oxygen mixing means, for heating said pulp so that it will be at a temperature in the range of around 65 C to around 121 °C in said mixing means.

396. The apparatus of claims 387, 388, 389 or 390 further comprising a valve in said transportation means after each of said oxygen mixing means. 397. The apparatus of claim 377 further comprising means, prior to each of said oxygen mixing means, for adjusting the consistency of said pulp to 7 to 15%.

398. The apparatus of claim 397 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp.

399. The apparatus of claim 397 in which

OMPI said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

400. The apparatus of claim 397 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

401. The apparatus of claims 397, 398, 399 or 400 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

402. The apparatus of claims 397, 398, 399 or 400 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

403. The apparatus of claims 397, 398, 399 or 400 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

404. The apparatus of claims 397, 398, 399 or 400 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

405. The apparatus of claims 397, 398, 399 or 400 further comprising means, prior to each of said oxygen mixing means, for heating said pulp so that it will be at a temperature in the range of around 65°C to around 121 C in said mixing means.

406. The apparatus of claims 397, 398, 399 or 400 further comprising a valve in said transportation means after each of said oxygen mixing means.

407. The apparatus of claim 397 further comprising first additional means for adding a pH adjustment chemical to said pulp, second additional means after said first additional means for adding oxygen to said pulp,

OMPI third additional means for mixing said oxygen with said pulp, and fourth additional means after said third additional means and prior to said first means for washing said pulp, said oxygen mixing means having said mixing zone. 408. The apparatus of claim 407 in which said rotors provide a swept area of 14,100 to 1 ,000,000 square meters per metric ton of oven dry pulp.

409. The apparatus of claim 407 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

410. The apparatus of claim 407 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

411. The apparatus of claims 407, 408, 409 or 410 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

412. The apparatus of claims 407, 408, 409 or 410 in which said mixing zone is an annular space in which the interior surface * of said space has a radius of at least one half of the radius of the exterior surface of said space.

413. The apparatus of claims 407, 408, 409 or 410 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm.

414. The apparatus of claims 407, 408, 409 or 410 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

415. The apparatus of claims 407, 408, 409 or 410 further comprising means, prior to each of said oxygen mixing means, for heating said pulp so that it will be at a temperature in the range of around 65 C to around 121°C in said mixing means.

416. The apparatus of claims 407, 408, 409 or 410 further comprising .. .

-ftO ET

OMPI a valve in said transportation means after each of said oxygen mixing means.

417. The apparatus of claim 262 in which said slurry is a pulp slurry further comprising a continuous digester for continuously digesting wood chips to form deiigni ication products and deligni ied wood chips, and a washer associated with said digester for removing at least a part of said deiignification products, said digester having a pressure relief valve for forming wood pulp from said delignified wood chips by partially releasing the pressure from said wood chips, a pipe for transporting a slurry containing said wood pulp and remaining deiignification products under pressure from said digester to a storage tank, and said storage tank, means, prior to said storage tank, for adding a pH adjustment chemical to said slurry, means, between said pH adjustment chemical addition means and said storage tank, for adding oxygen to said slurry, and means, prior to said storage tank, for mixing said oxygen with said slurry, said mixing means having said mixing zone.

418. The apparatus of claim 417 in which said rotors provide a swept area of 14,100 to 1,000,000 square meters per metric ton of oven dry pulp. 419. The apparatus of claim 417 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

420. The apparatus of claim 417 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp.

421. The apparatus of claims 417, 418, 419 or 420 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

422. The apparatus of claims 417, 418, 419 or 420 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

OMPI 423. The apparatus of claims 417, 418, 419 or 420 in which said trailing edge has a radius of curvature in the range of 0.5 to

15 mm.

424. The apparatus of claims 417, 418, 419 or 420 further comprising means, prior said mixing means, for heating said slurry so that it will be at a temperature in the range of around 65°C to around 121 C in said mixing means.

425. The apparatus of claims 417, 418, 419 or 420 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

426. The apparatus of claims 417, 418, 419 or 420 in which a valve in said pipe between said mixing means and said storage tank.

427. • The apparatus of claim 262 in which said slurry is a pulp slurry further comprising a continuous digester for continuously digesting wood chips to form deiigni ication products and delignified wood chips, and a washer associated with said digester for removing at least a part of said deiignification products, said digester having a pressure relief valve for forming wood pulp from said delignified wood chips by partially releasing the pressure from said wood chips, a pipe for transporting a slurry containing said wood pulp and remaining deiignification products under pressure from said digester to a diffusion washer, and said diffusion washer, means, prior to said diffusion washer, for adding a pH adjustment chemical to said slurry, means, between said pH adjustment chemical addition means and said storage tank, for adding oxygen to said slurry, and means, prior to said storage tank, for mixing said oxygen with said slurry, said mixing means having said mixing zone. 428. The apparatus of claim 427 in which said rotors provide a swept area of 14,100- to 1,000,000 square meters per metric ton of oven dry pulp.

429. The apparatus of claim 427 in which said rotors provide a swept area of 25,000 to 150,000 square meters per metric ton of oven dry pulp.

430. The apparatus of claim 427 in which said rotors provide a swept area of around 65,400 square meters per metric ton of oven dry pulp. 431. The apparatus of claims 427, 428, 429 or 430 in which said rotors have elliptically generated cross sections having a major axis extending in the direction of rotation.

432. The apparatus of claims 427, 428, 429 or 430 in which said mixing zone is an annular space in which the interior surface of said space has a radius of at least one half of the radius of the exterior surface of said space.

433. The apparatus of claims 427, 428, 429 or 430 in which said trailing edge has a radius of curvature in the range of 0.5 to 15 mm. 434. -The apparatus of claims 427, 428, 429 or 430 further comprising means, prior said mixing means, for heating said slurry so that it will be at a temperature in the range of around 65°C to around 121 C in said mixing means. 435. The apparatus of claims 427, 428, 429 or 430 further comprising a plurality of stators extending into said mixing zone, at least some of said stators having a first passage extending from outside of said mixing zone lengthwise through said stator and a second passage communicating between said first passage and said mixing zone, and a check valve in said second passage.

436. The apparatus of claims 427, 428, 429 or 430 further comprising a valve in said pipe between said mixing means and said diffusion washer.

^IREA -

OMPI