EP0026422A1 - A spray cleaning agent suited for the treatment of textiles - Google Patents
A spray cleaning agent suited for the treatment of textiles Download PDFInfo
- Publication number
- EP0026422A1 EP0026422A1 EP80105681A EP80105681A EP0026422A1 EP 0026422 A1 EP0026422 A1 EP 0026422A1 EP 80105681 A EP80105681 A EP 80105681A EP 80105681 A EP80105681 A EP 80105681A EP 0026422 A1 EP0026422 A1 EP 0026422A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- percent
- average
- ethylene glycol
- glycol ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the present invention relates to a cleaning agent which is suitable for the treatment of heavily soiled areas, such as collars and cuffs, of items of laundry which are subsequently washed in the customary manner.
- a cleaning agent which is suitable for the treatment of heavily soiled areas, such as collars and cuffs, of items of laundry which are subsequently washed in the customary manner.
- Such agents enhance the effect of the detergent against stubborn dirt, generally in a so-called “fine linen” at 30 ° to 40 ° C, and carried out at 50 ° to 60 0 C wash for "easy-care textiles" can not be sufficiently removed.
- Corresponding pretreatment agents are known as paste-like or liquid concentrates or as viscous masses shaped into application pens and also as a spray.
- sprayable agents are particularly valued by consumers, since on the one hand they can be conveniently distributed evenly on the soiled areas without the aid of fingers or a spatula and, on the other hand, in the case of coarsely knit textiles, they penetrate into the deeper fibers and consequently on the surface applied application pen are superior in terms of their cleaning effect.
- the alcohols on which the nonionic surfactant constituents listed under (a) to (c) are based can be straight-chain or methyl-branched in the 2-position, saturated or simply olefinically unsaturated. They can be of natural or synthetic origin, for example obtained by ethylene polymerization or oxo synthesis, or they can be present as mixtures of such alcohols.
- the constituent listed under (a) preferably consists of at least 75 percent by weight of an average of 5 to 7 saturated C 8 alcohols containing ethylene glycol ether groups.
- the component listed under (b) is preferably a mixture of two nonionic compounds (b 1 ) and (b 2 ), which are present in a weight ratio of 1: 4 to 4: 1.
- Component (b 1 ) preferably consists of saturated averages of 2 to 4 ethylene glycol ether groups C 12 -C 14 alcohols.
- the component (b 2 ) preferably consists of an average of 2 to 3 ethylene glycol ether groups, saturated or monounsaturated C 16 -C 18 alcohols, the proportion of saturated C 16 -C 18 alcohols not more than 65 percent by weight and in particular not more than Is 50 percent by weight.
- oleyl alcohol can be used as monounsaturated alcohol.
- the component listed under (c) preferably has an average of 11 to 13 ethylene glycol ether groups and is preferably derived from mono-olefinically unsaturated or saturated C 16 -C 18 alcohols or mixtures thereof. If alcohol mixtures are used as the starting base, these can be 50 to 100% saturated and consist, for example, of mixtures of cetyl, stearyl and optionally oleyl alcohol, such as those obtainable from tallow fatty alcohols.
- the component (d) consists of a high-boiling gasoline fraction, which preferably has a boiling range from 205 to 245 ° C. and is present in particular in an amount of 35 to 45 percent by weight, based on the mixture free of blowing agent.
- the amount of the hydrocarbon is such that the agent is non-combustible in interaction with the other components and can therefore be handled safely in the household.
- the lower chlorinated hydrocarbons according to component (s), which can also be present in a mixture, are preferably present in an amount of 20 to 32 percent by weight, based on the propellant-free components.
- the preferred chlorinated hydrocarbon is methylene chloride. The amount of chlorinated hydrocarbons is so limited that there are no health hazards for humans and pets to fear even when accidentally inhaled.
- the selection and the amount of solvents (d) and (e) guarantees that even wax-like impurities, for example those from candle wax, are sufficiently pre-dissolved so that they can be washed out during the subsequent washing treatment.
- the solvents in the selected composition do not lead to the formation of a ring.
- the agents can also contain fragrances, in particular those which mask the inherent odor of the solvents and the detergent ingredients. In general, amounts of 0.1 to 1 percent by weight of perfume oil are sufficient for this.
- Suitable propellants are conventional propellant gases used for the production of aerosols and low-boiling solvents which are gaseous at room temperature.
- blowing agents for example combustible hydrocarbons such as propane or butane, or fluorine-containing blowing agents, which are considered to be of concern for environmental reasons, can be dispensed with.
- Carbon dioxide is preferably used as the blowing agent, with 2 to 3 parts by weight of carbon dioxide accounting for 98 to 97 parts by weight of blowing agent-free components.
- E0 stands for attached ethylene oxide.
- the percentages mean percent by weight.
Abstract
Description
Gegenstand der vorliegenden Erfindung ist ein Reinigungsmittel, das sich zur Behandlung stark verschmutzter Partien wie Kragen und Manschetten, von Wäschestücken eignet, die anschließend in üblicher Weise gewaschen werden. Derartige Mittel verstärken die Wirkung des Waschmittels gegenüber hartnäckige Verschmutzungen, die im allgemeinen bei einer sogenannten "Feinwäsche" bei 30° bis 40° C beziehungsweise der bei 50° bis 600 C durchgeführten Wäsche für "Pflegeleicht-Textilien" nicht ausreichend entfernt werden. Entsprechende Vorbehandlungsmittel sind als pastenförmige oder flüssige Konzentrate beziehungsweise als zähe, zu Auftragsstiften geformte Massen sowie auch als Spray bekannt. Es hat sich gezeigt, daß versprühbare Mittel vom Verbraucher besonders geschätzt werden, da sie sich einerseits bequem und ohne Zuhilfenahme der Finger oder eines Spatels gleichmäßig auf den verschmutzten Partien verteilen lassen und zum anderen bei grobgewirkten Textilien auch in die tieferliegenden Fasern eindringen und folglich einem oberflächlich angewendeten Auftragsstift hinsichtlich ihrer Reinigungswirkung überlegen sind.The present invention relates to a cleaning agent which is suitable for the treatment of heavily soiled areas, such as collars and cuffs, of items of laundry which are subsequently washed in the customary manner. Such agents enhance the effect of the detergent against stubborn dirt, generally in a so-called "fine linen" at 30 ° to 40 ° C, and carried out at 50 ° to 60 0 C wash for "easy-care textiles" can not be sufficiently removed. Corresponding pretreatment agents are known as paste-like or liquid concentrates or as viscous masses shaped into application pens and also as a spray. It has been shown that sprayable agents are particularly valued by consumers, since on the one hand they can be conveniently distributed evenly on the soiled areas without the aid of fingers or a spatula and, on the other hand, in the case of coarsely knit textiles, they penetrate into the deeper fibers and consequently on the surface applied application pen are superior in terms of their cleaning effect.
An derartige Sprühreinigungsmittel werden eine Reihe von Anforderungen gestellt, die in ihrer Gesamtheit von den bisher bekannten Mitteln noch nicht erfüllt werden. Es sind dies:
- 1. Hohes Lösungsvermögen für Fette, Öle und Wachse,
- 2. Vermeidung einer Kranzbildung durch sich im Textilgut ausbreitende Schmutzränder,
- 3. vollständige Auswaschbarkeit bei der nachfolgenden Wäsche, d. h. die verwendeten Tensidkomponenten sollen ihrerseits nach dem Waschprozeß keinen fettartigen Fleck auf dem Textilgut hinterlassen,
- 4. Vermeidung einer Schaumanhebung beim nachfolgenden Waschprozeß,
- 5. Unbrennbarkeit,
- 6..keine Toxizität für Menschen und Haustiere,
- 7. ausreichende biologische Abbaufähigkeit der verwendeten Waschrohstoffe im Abwasser,
- 8. die Zusammensetzung soll so abgestimmt sein, daß auf den Einsatz von fluorierten Kohlenwassertoffen als Treibmittel verzichtet werden kann.
- 1. High solubility for fats, oils and waxes,
- 2. Avoidance of wreath formation due to dirt edges spreading out in the textile material,
- 3. complete washability in the subsequent washing, ie the surfactant components used should in turn not leave a greasy stain on the textile after the washing process,
- 4. Avoiding foam increase in the subsequent washing process,
- 5. non-flammability,
- 6..no toxicity for humans and pets,
- 7. sufficient biodegradability of the washing raw materials used in the waste water,
- 8. The composition should be coordinated so that the use of fluorinated hydrocarbons as blowing agents can be dispensed with.
Diesen Anforderungen entspricht das erfindungsgemäße Mittel. Es betrifft ein zur Textilbehandlung geeignetes, ein bei Raumtemperatur gasförmiges Treibmittel enthaltendes Sprühreinigungsmittel, dadurch gekennzeichnet, daß die treibmittelfreien Bestandteile die folgende Zusammensetzung aufweisen:
- a) 6 bis 16 Gewichtsprozent an durchschnittlich 4 bis 8 Ethylenglykolethergruppen aufweisenden C6-C10 Alkoholen, deren Anteil an gesättigtem C8-Alkohol mindestens 50 Gewichtsprozent beträgt,
- b) 6 bis 10 Gewichtsprozent an durchschnittlich 2 bis 4 Ethylenglykolethergruppen aufweisenden C12-C18-Alkoholen, deren Anteil an gesättigten C16-C18-Alkoholen nicht mehr als 50 Gewichtsprozent beträgt,
- c) 6 bis 10 Gewichtsprozent an durchschnittlich 10 bis 15 Ethylenglykolethergruppen aufweisenden C16-C18-Alkoholen,
- d) 20 bis 50 Gewichtsprozent an aliphatischen Kohlenwasserstoffen mit einem Siedebereich von 180 bis 260°C,
- e) 10 bis 35 Gewichtsprozent mindestens eines Chlorkohlenwasserstoffes aus der Reihe Methylenchlorid, Ethylenchlorid, 1,1,1-Trichlorethan und Perchlorethylen, wobei der Gehalt an den unter den Bestandteilen (a) bis (c) 20 bis 35 Gewichtsprozent und der an den Lösungsmitteln (d) und (e)65 bis 80 Gewichtsprozent beträgt
- a) 6 to 16 percent by weight of an average of 4 to 8 C 6 -C 10 alcohols containing ethylene glycol ether groups, the proportion of saturated C 8 alcohol of which is at least 50 percent by weight,
- b) 6 to 10 percent by weight of on average 2 to 4 C 12 -C 18 alcohols containing ethylene glycol ether groups, the proportion of saturated C 16 -C 18 alcohols of which is not more than 50 percent by weight,
- c) 6 to 10 percent by weight of C 16 -C 18 alcohols having an average of 10 to 15 ethylene glycol ether groups,
- d) 20 to 50 percent by weight of aliphatic hydrocarbons with a boiling range of 180 to 260 ° C,
- e) 10 to 35 percent by weight of at least one chlorinated hydrocarbon from the series methylene chloride, ethylene chloride, 1,1,1-trichloroethane and perchlorethylene, the content of the components (a) to (c) being 20 to 35 percent by weight and that of the solvents (d) and (e) is 65 to 80 weight percent
Die den unter (a) bis (c) aufgeführten nichtionischen Tensid-Bestandteilen zugrundeliegenden Alkohole können geradkettig oder in 2-Stellung methylverzweigt, gesättigt oder einfach olefinisch ungesättigt sein. Sie können natürlichen oder synthetischen Ursprungs, beispielsweise durch Ethylenpolymerisation oder Oxo-Synthese gewonnen sein beziehungsweise als Gemische solcher Alkohole vorliegen.The alcohols on which the nonionic surfactant constituents listed under (a) to (c) are based can be straight-chain or methyl-branched in the 2-position, saturated or simply olefinically unsaturated. They can be of natural or synthetic origin, for example obtained by ethylene polymerization or oxo synthesis, or they can be present as mixtures of such alcohols.
Vorzugsweise besteht der unter (a) aufgeführte Bestandteil zu mindestens 75 Gewichtsprozent aus einem durchschnittlich 5 bis 7 Ethylenglykolethergruppen aufweisenden, gesättigten C8-Alkohol. The constituent listed under (a) preferably consists of at least 75 percent by weight of an average of 5 to 7 saturated C 8 alcohols containing ethylene glycol ether groups.
Bei dem unter (b) aufgeführten Bestandteil handelt es sich vorzugsweise um ein Gemisch zweier nichtionischer Verbindungen (b1) und (b2), die im Gewichtsverhältnis 1 : 4 bis 4 : 1 vorliegen. Dabei besteht der Bestandteil (b1) vorzugsweise aus durchschnittlich 2 bis 4 Ethylenglykolethergruppen aufweisenden gesättigten C12-C14-Alkoholen. Der Bestandteil (b2) besteht vorzugsweise aus durchschnittlich 2 bis-3 Ethylenglykolethergruppen aufweisenden, gesättigten oder einfach ungesättigten C16-C18-Alkoholen, deren Anteil an gesättigten C16-C18-Alkoholen nicht mehr als 65 Gewichtsprozent und insbesondere nicht mehr als 50 Gewichtsprozent beträgt. Als einfach ungesättigter Alkohol kommt beispielsweise Oleylalkohol in Frage..The component listed under (b) is preferably a mixture of two nonionic compounds (b 1 ) and (b 2 ), which are present in a weight ratio of 1: 4 to 4: 1. Component (b 1 ) preferably consists of saturated averages of 2 to 4 ethylene glycol ether groups C 12 -C 14 alcohols. The component (b 2 ) preferably consists of an average of 2 to 3 ethylene glycol ether groups, saturated or monounsaturated C 16 -C 18 alcohols, the proportion of saturated C 16 -C 18 alcohols not more than 65 percent by weight and in particular not more than Is 50 percent by weight. For example, oleyl alcohol can be used as monounsaturated alcohol.
Der unter (c) aufgeführte Bestandteil weist vorzugsweise durchschnittlich 11 bis 13 Ethylenglykolethergruppen auf und leitet sich vorzugsweise von einfach olefinisch ungesättigten oder gesättigten C16-C18-Alkoholen beziehungsweise deren Gemischen ab. Bei Ver- wendung von Alkoholgemischen als Ausgangsbasis können diese zu 50 bis 100 % gesättigt sein und z.B. aus Gemischen von Cetyl-, Stearyl- und gegebenenfalls Oleylalkohol bestehen, wie sie beispielsweise aus Talgfettalkoholen zugänglich sind.The component listed under (c) preferably has an average of 11 to 13 ethylene glycol ether groups and is preferably derived from mono-olefinically unsaturated or saturated C 16 -C 18 alcohols or mixtures thereof. If alcohol mixtures are used as the starting base, these can be 50 to 100% saturated and consist, for example, of mixtures of cetyl, stearyl and optionally oleyl alcohol, such as those obtainable from tallow fatty alcohols.
Es hat sich gezeigt, daß der Bestandteil (b) und in noch etwas stärkerem Maße das Gemisch aus (b1) und (b 2) verantwortlich für die gute Auswaschbarkeit von fett- beziehungsweise wachsartigen Verschmutzungen sind. Als niedrig ethoxylierte Verbindungen sind sie jedoch in mäßig warmen Waschmittellösungen vergleichsweise schlecht emulgierbar und können aufgrund ihrer mangelhaften Auswaschbarkeit auf dem Textilgut fettartige Flecken und Kränze hinterlassen. Durch die zusätzliche Anwendung der unter (a) und (c) aufgeführten Bestandteile wird dieser Nachteil jedoch vollständig aufgehoben und darüber hinaus die schmutzlösenden Eigenschaften der Mittel noch erhöht.It has been shown that the component (b) and to a somewhat greater extent the mixture of (b 1 ) and ( b 2 ) are responsible for the good washability of grease or wax-like soiling. As low ethoxylated compounds, however, they are comparatively poorly emulsifiable in moderately warm detergent solutions and, owing to their poor washability, can leave greasy stains and wreaths on the textile. However, the additional use of the components listed under (a) and (c) completely eliminates this disadvantage and further increases the dirt-removing properties of the compositions.
Der Bestandteil (d) besteht aus einer hochsiedenden Benzinfraktion, die vorzugsweise einen Siedebereich von 205 bis 245°C aufweist und insbesondere in einer Menge von 35 bis 45 Gewichtsprozent, bezogen auf treibmittelfreies Gemisch, vorliegt. Die Menge des Kohlenwasserstoffs ist so bemessen, daß das Mittel im Zusammenwirken mit den übrigen Bestandteilen nicht brennbar ist und somit im Haushalt gefahrlos gehandhabt werden kann.The component (d) consists of a high-boiling gasoline fraction, which preferably has a boiling range from 205 to 245 ° C. and is present in particular in an amount of 35 to 45 percent by weight, based on the mixture free of blowing agent. The amount of the hydrocarbon is such that the agent is non-combustible in interaction with the other components and can therefore be handled safely in the household.
Die niederen Chlorkohlenwasserstoffe gemäß Bestandteil(e), die auch im Gemisch vorliegen können, sind vorzugsweise in einer Menge von 20 bis 32 Gewichtsprozent, bezogen auf treibmittelfreie Bestandteile, anwesend. Der bevorzugte Chlorkohlenwasserstoff ist Methylenchlorid. Die Menge der Chlorkohlenwasserstoffe ist so begrenzt, daß bei der Anwendung auch bei unbeabsichtigtem Einatmen keine gesundheitlichen Schäden für Mensch und Haustiere zu befürchten sind.The lower chlorinated hydrocarbons according to component (s), which can also be present in a mixture, are preferably present in an amount of 20 to 32 percent by weight, based on the propellant-free components. The preferred chlorinated hydrocarbon is methylene chloride. The amount of chlorinated hydrocarbons is so limited that there are no health hazards for humans and pets to fear even when accidentally inhaled.
Die Auswahl und die Menge der Lösungsmittel (d) und (e) garantiert, daß auch wachsartige Verunreinigungen, beispielsweise solche von Kerzenwachs, hinreichend vorgelöst werden, so daß sie bei der nachfolgenden Waschbehandlung ausgewaschen werden können. Darüber hinaus führen die Lösungsmittel in der gewählten Zusammensetzung nicht zu einer Kranzbildung.The selection and the amount of solvents (d) and (e) guarantees that even wax-like impurities, for example those from candle wax, are sufficiently pre-dissolved so that they can be washed out during the subsequent washing treatment. In addition, the solvents in the selected composition do not lead to the formation of a ring.
Außer den aufgeführtenn Bestandteilen können die Mittel noch Duftstoffe enthalten, insbesondere solche, die den Eigengeruch der Lösungsmittel und der waschwirksamen Bestandteile überdecken. Im allgemeinen sind Mengen von 0,1 bis 1 Gewichtsprozent an Parfümöl hierfür ausreichend.In addition to the ingredients listed, the agents can also contain fragrances, in particular those which mask the inherent odor of the solvents and the detergent ingredients. In general, amounts of 0.1 to 1 percent by weight of perfume oil are sufficient for this.
Als Treibmittel eignen sich übliche, zur Herstellung von Aerosolen verwendete Treibgase und niedrigsiedende, bei Raumtemperatur gasförmig vorliegende Lösungsmittel. Der besondere Vorteil der erfindungsgemäßen Mittel liegt jedoch darin, daß auf derartige Treibmittel, z.B. auf die Brennbarkeit erhöhende Kohlenwasserstoffe, wie Propan oder Butan, beziehungsweise auf fluorhaltige Treibmittel, die aus umweltbedingten Gründen als bedenklich gelten, verzichtet werden kann. Vorzugsweise wird Kohlendioxid als Treibmittel verwendet, wobei 2 bis 3 Gewichtsteile Kohlendioxid auf 98 bis 97 Gewichtsteile an treibmittelfreien Bestandteilen entfallen. Zwar sind auch höhere Anteile Kohlendioxid, beispielsweise bis zu einem Verhältnis von 3,6 Gewichtsteilen Kohlendioxid zu 96,4 Gewichtsteilen an treibmittelfreien Bestandteilen möglich, jedoch erfordern diese Gemische aufwendigere Sprühdosen mit einer Druckfestigkeit von mehr als.15 kp/cm2, während man bei Einhaltung der oben angegebenen Verhältnisse mit einer Druckfestigkeit van 10 bis 15 kp/cm 2 auskommt.Suitable propellants are conventional propellant gases used for the production of aerosols and low-boiling solvents which are gaseous at room temperature. The particular advantage of the agents according to the invention is, however, that such blowing agents, for example combustible hydrocarbons such as propane or butane, or fluorine-containing blowing agents, which are considered to be of concern for environmental reasons, can be dispensed with. Carbon dioxide is preferably used as the blowing agent, with 2 to 3 parts by weight of carbon dioxide accounting for 98 to 97 parts by weight of blowing agent-free components. Although higher proportions of carbon dioxide are possible, for example up to a ratio of 3.6 parts by weight of carbon dioxide to 96.4 parts by weight of propellant-free constituents, these mixtures require more complex spray cans with a compressive strength of more than 15 kp / cm 2 , while at Adherence to the above conditions with a compressive strength of 10 to 15 kp / cm 2 is sufficient.
In den folgenden Beispielen steht "E0" für angelagertes Ethylenoxid. Die Prozentangaben bedeuten Gewichtsprozent.In the following examples, "E0" stands for attached ethylene oxide. The percentages mean percent by weight.
Claims (8)
wobei der Gehalt an den unter den Bestandteilen (a) bis (c) 20 bis 35 Gewichtsprozent und der an den Lösungsmitteln(d) und (e) 65 bis 80 Gewichtsprozent beträgt.1. A spray cleaning agent suitable for textile treatment and containing gaseous blowing agents at room temperature, characterized in that the blowing agent-free components have the following composition:
wherein the content of the components (a) to (c) is 20 to 35 percent by weight and that of the solvents (d) and (e) 65 to 80 percent by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT80105681T ATE8662T1 (en) | 1979-10-01 | 1980-09-22 | SPRAY CLEANING AGENT SUITABLE FOR TEXTILE TREATMENT. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19792939810 DE2939810A1 (en) | 1979-10-01 | 1979-10-01 | SPRAY CLEANER SUITABLE FOR TEXTILE TREATMENT |
DE2939810 | 1979-10-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0026422A1 true EP0026422A1 (en) | 1981-04-08 |
EP0026422B1 EP0026422B1 (en) | 1984-07-25 |
Family
ID=6082421
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80105681A Expired EP0026422B1 (en) | 1979-10-01 | 1980-09-22 | A spray cleaning agent suited for the treatment of textiles |
Country Status (5)
Country | Link |
---|---|
US (1) | US4288339A (en) |
EP (1) | EP0026422B1 (en) |
AT (1) | ATE8662T1 (en) |
BR (1) | BR8006289A (en) |
DE (2) | DE2939810A1 (en) |
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EP0871808A1 (en) * | 1995-11-27 | 1998-10-21 | The Procter & Gamble Company | Composition for treating stains on laundry items and method of treatment |
EP1149945A1 (en) * | 2000-04-29 | 2001-10-31 | Ciba Spezialitätenchemie Pfersee GmbH | Composition for the pretreatment of fibrous materials |
WO2013107579A1 (en) * | 2012-01-18 | 2013-07-25 | Henkel Ag & Co. Kgaa | Washing, cleaning or pre-treatment agent with increased cleaning power |
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US4438009A (en) | 1981-08-14 | 1984-03-20 | S. C. Johnson & Son, Inc. | Low solvent laundry pre-spotting composition |
DE3514364A1 (en) * | 1985-04-20 | 1986-10-23 | Henkel KGaA, 4000 Düsseldorf | GRINNY DETERGENT WITH IMPROVED CLEANING CAPACITY |
US4820436A (en) * | 1985-06-22 | 1989-04-11 | Henkel Kommanditgesellschaft Auf Aktien | Detergents for low laundering temperatures |
US4810411A (en) * | 1986-04-16 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Solvent-based fabric protector |
DE3626224A1 (en) * | 1986-08-02 | 1988-02-04 | Henkel Kgaa | CLEANING SUPPLIES |
DE3730179A1 (en) * | 1987-09-09 | 1989-03-23 | Henkel Kgaa | Thickened corrosive surfactant solutions, in particular for their use in the field of cosmeetic preparations |
US4954286A (en) * | 1988-04-14 | 1990-09-04 | Lever Brothers Company | Fabric pretreatment cleaning compositions |
BR9306062A (en) * | 1992-03-12 | 1997-11-18 | Henkel Kgaa | Degreasing agent |
EP0616028A1 (en) * | 1993-03-19 | 1994-09-21 | The Procter & Gamble Company | Cleaning compositions with short chain nonionic surfactants |
US5981455A (en) * | 1993-03-19 | 1999-11-09 | The Procter & Gamble Company | Cleaning compositions with short chain nonionic surfactants |
US5435936A (en) * | 1993-09-01 | 1995-07-25 | Colgate Palmolive Co. | Nonaqueous liquid microemulsion compositions |
US5925608A (en) * | 1995-07-13 | 1999-07-20 | The Procter & Gamble Company | Packaged foaming composition |
EP0753558A1 (en) * | 1995-07-13 | 1997-01-15 | The Procter & Gamble Company | Packaged foaming composition |
US6021926A (en) * | 1995-07-13 | 2000-02-08 | The Procter & Gamble Company | Packaged foaming composition |
US5968202A (en) * | 1995-07-13 | 1999-10-19 | The Procter & Gamble Company | Method of cleaning textile fabrics |
EP0753556B1 (en) * | 1995-07-13 | 2003-10-15 | The Procter & Gamble Company | Packaged foaming composition |
US20040214737A1 (en) * | 2003-04-25 | 2004-10-28 | John Billman | Foamy composition for pretreatment of stains on fabrics |
EP1988986B1 (en) * | 2006-02-22 | 2009-12-02 | Basf Se | Surfactant mixture containing short-chain and also long-chain components |
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DE1279273B (en) * | 1965-03-30 | 1968-10-03 | Henkel & Cie Gmbh | Liquid stain treatment concentrates for the local direct treatment of soiled textile parts |
FR2013197A6 (en) * | 1968-07-18 | 1970-03-27 | Henkel & Cie Gmbh | Low foaming textile detergents |
AU429637B2 (en) * | 1970-08-24 | 1972-10-30 | R & C Products Pty Limited | An improved method of and preparation forthe removal of soils from textile articles and materials |
DE2323605A1 (en) * | 1972-03-27 | 1974-11-21 | Minnesota Mining & Mfg | DIRT AND STAIN REMOVER |
DE2628480A1 (en) * | 1976-06-25 | 1978-01-05 | Oreal | Cleaning compsn. for fabrics - contg. emulsion of water and organic solvent |
GB1518676A (en) * | 1975-10-30 | 1978-07-19 | Procter & Gamble Ltd | Detergent compositions |
GB2011944A (en) * | 1978-01-09 | 1979-07-18 | Unilever Ltd | Liquid nonionic detergent composition |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1617119A1 (en) * | 1966-11-18 | 1971-02-18 | Henkel & Cie Gmbh | Low-foaming stain treatment agent for textiles |
US3707506A (en) * | 1968-08-19 | 1972-12-26 | Basf Wyandotte Corp | Nonionic detergent compositions for cleaning polyester fabrics |
US3741902A (en) * | 1971-05-24 | 1973-06-26 | Purex Corp | Laundry prespotter composition |
US3870647A (en) * | 1972-06-05 | 1975-03-11 | Seneca Chemicals Inc | Liquid cleaning agent |
DE2362114C2 (en) * | 1973-12-14 | 1984-07-05 | Henkel KGaA, 4000 Düsseldorf | Liquid foam-regulated detergent and cleaning agent |
US4093417A (en) * | 1974-06-01 | 1978-06-06 | Karl Hans Heinlein | Method for processing textile material |
GB1497747A (en) * | 1975-03-04 | 1978-01-12 | Shell Int Research | Detergent composition |
DE2703998C3 (en) * | 1977-02-01 | 1981-10-01 | Henkel KGaA, 4000 Düsseldorf | Liquid detergent concentrate with low foaming power |
US4178262A (en) * | 1977-03-23 | 1979-12-11 | Basf Wyandotte Corporation | Spotting-agent composition |
US4199482A (en) * | 1977-03-31 | 1980-04-22 | Colgate-Palmolive Company | Laundry pre-spotter composition and method of using same |
US4161458A (en) * | 1977-08-29 | 1979-07-17 | Scott's Liquid Gold Incorporated | Stable aqueous aerosol system with carbon dioxide propellant |
GR67588B (en) * | 1978-01-09 | 1981-08-31 | Unilever Nv |
-
1979
- 1979-10-01 DE DE19792939810 patent/DE2939810A1/en not_active Withdrawn
-
1980
- 1980-09-15 US US06/187,521 patent/US4288339A/en not_active Expired - Lifetime
- 1980-09-22 DE DE8080105681T patent/DE3068694D1/en not_active Expired
- 1980-09-22 EP EP80105681A patent/EP0026422B1/en not_active Expired
- 1980-09-22 AT AT80105681T patent/ATE8662T1/en not_active IP Right Cessation
- 1980-09-30 BR BR8006289A patent/BR8006289A/en unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1279273B (en) * | 1965-03-30 | 1968-10-03 | Henkel & Cie Gmbh | Liquid stain treatment concentrates for the local direct treatment of soiled textile parts |
FR2013197A6 (en) * | 1968-07-18 | 1970-03-27 | Henkel & Cie Gmbh | Low foaming textile detergents |
AU429637B2 (en) * | 1970-08-24 | 1972-10-30 | R & C Products Pty Limited | An improved method of and preparation forthe removal of soils from textile articles and materials |
DE2323605A1 (en) * | 1972-03-27 | 1974-11-21 | Minnesota Mining & Mfg | DIRT AND STAIN REMOVER |
GB1518676A (en) * | 1975-10-30 | 1978-07-19 | Procter & Gamble Ltd | Detergent compositions |
DE2628480A1 (en) * | 1976-06-25 | 1978-01-05 | Oreal | Cleaning compsn. for fabrics - contg. emulsion of water and organic solvent |
GB2011944A (en) * | 1978-01-09 | 1979-07-18 | Unilever Ltd | Liquid nonionic detergent composition |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0871808A1 (en) * | 1995-11-27 | 1998-10-21 | The Procter & Gamble Company | Composition for treating stains on laundry items and method of treatment |
EP0871808A4 (en) * | 1995-11-27 | 1999-04-28 | Procter & Gamble | Composition for treating stains on laundry items and method of treatment |
EP1149945A1 (en) * | 2000-04-29 | 2001-10-31 | Ciba Spezialitätenchemie Pfersee GmbH | Composition for the pretreatment of fibrous materials |
WO2001083879A1 (en) * | 2000-04-29 | 2001-11-08 | Ciba Spezialitätenchemie Pfersee GmbH | Composition for pretreating fiber materials |
WO2013107579A1 (en) * | 2012-01-18 | 2013-07-25 | Henkel Ag & Co. Kgaa | Washing, cleaning or pre-treatment agent with increased cleaning power |
Also Published As
Publication number | Publication date |
---|---|
ATE8662T1 (en) | 1984-08-15 |
US4288339A (en) | 1981-09-08 |
BR8006289A (en) | 1981-04-07 |
DE2939810A1 (en) | 1981-04-16 |
DE3068694D1 (en) | 1984-08-30 |
EP0026422B1 (en) | 1984-07-25 |
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