EP0020709B1 - Dispenser for solid block detergent compositions - Google Patents

Dispenser for solid block detergent compositions Download PDF

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Publication number
EP0020709B1
EP0020709B1 EP80900105A EP80900105A EP0020709B1 EP 0020709 B1 EP0020709 B1 EP 0020709B1 EP 80900105 A EP80900105 A EP 80900105A EP 80900105 A EP80900105 A EP 80900105A EP 0020709 B1 EP0020709 B1 EP 0020709B1
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EP
European Patent Office
Prior art keywords
detergent
dispenser
cartridge
block
receptacle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP80900105A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0020709A4 (en
EP0020709A1 (en
Inventor
James Lee Copeland
Peter James Fernholz
Spencer Brian Larson
Duane Leroy Salmonson
Michael D. Weick
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab Inc
Original Assignee
Economics Laboratory Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Economics Laboratory Inc filed Critical Economics Laboratory Inc
Publication of EP0020709A1 publication Critical patent/EP0020709A1/en
Publication of EP0020709A4 publication Critical patent/EP0020709A4/en
Application granted granted Critical
Publication of EP0020709B1 publication Critical patent/EP0020709B1/en
Expired legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0052—Cast detergent compositions
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00—Washing or rinsing machines for crockery or tableware
    • A47L15/42—Details
    • A47L15/44—Devices for adding cleaning agents; Devices for dispensing cleaning agents, rinsing aids or deodorants
    • A47L15/4436—Devices for adding cleaning agents; Devices for dispensing cleaning agents, rinsing aids or deodorants in the form of a detergent solution made by gradually dissolving a powder detergent cake or a solid detergent block
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F21/00—Dissolving
    • B01F21/20—Dissolving using flow mixing
    • B01F21/22—Dissolving using flow mixing using additional holders in conduits, containers or pools for keeping the solid material in place, e.g. supports or receptacles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means

Definitions

  • This invention relates to a dispenser for solid block detergent compositions which comprise a housing configured for fixed mounting to a solid surface, said housing defining a substantially enclosed inner cavity and an access port and a discharge port opening into said cavity, a detergent agent containing holder for holding and maintaining in position a solid block of detergent agent, so as to expose for use at least one surface of said block to said cavity, and furthermore spray-forming nozzle means mounted to extend into said cavity for directing a pressurized spray of liquid at. the entire exposed surface of said detergent block such that the hydraulic action of said nozzle directed spray disolves a portion of said detergent block forming a concentrated detergent solution for passage through said discharge port, which is disposed adjacent the lower portion of the cavity. More particularly, this invention relates to a detergent dispenser which converts solid block-type detergent compositions into concentrated detergent solution, which is particularly useful for institutional dishwashing and fabric washing machines.
  • Automated institutional and industrial spray washing machines are generally configured to embody at least one wash tank or reservoir for maintaining a readily available supply of detergent solution for use by the washing machine.
  • the washing machine repeatedly drawns upon or reuses the detergent solution within the wash tank reservoir, over a period of time (e.g. such as over an entire day), until it is replenished by a fresh solution.
  • a part or all of the rinse water is diverted to the wash tank reservoir and a certain amount of the detergent solution is drained off via a stand pipe (for example, in warewashing applications, with food particles and grease), to keep the remaining solution as clean as possible.
  • the proper reservoir solution level may also be maintained by adding water to the reservoir, which reduces or dilutes the detergent concentration of the reservoir solution. Accordingly, to maintain the reservoir solution at the desired detergent concentration level required for proper cleaning, concentrated detergent solution is periodically added to the reservoir by auxiliary detergent dispenser apparatus.
  • the detergent dispenser apparatus used for replenishing the wash tank solution have typically been designed to hold sizable amounts of detergent, and for automatic or semi-automatic operation.
  • Such use of automated detergent dispensers eliminates the need of constant operator attention to the status of the reservoir solution, minimizes operator errors due to operator misjudgment in timing or in the amount of detergent to be added to the reservoir, and provides greater accuracy in maintaining the actual concentration level of the detergent solution within the reservoir.
  • the supplying or replenishing of concentrated detergent solution to the wash tank reservoir may be performed on a "demand" basis, whereby the detergent concentration level within the wash tank reservoirs monitored by a conductivity cell which typically forms part of an electrical bridge or sensor circuit connected to control the emissions of concentrated detergent solution from the detergent dispenser.
  • the dispenser may be hydraulically linked to the wash tank, for example, by a by-pass line from the rinse line of the washer apparatus; with such a by-pass line, each time a rinse cycle of the washing apparatus is executed, the detergent dispenser is activated, dispensing to the wash tank reservoir an amount of concentrated detergent solution in pre-determined proportion to the volume of rinse water used.
  • the rinse water is generally diverted to the wash tank, the combined effects of dilution by the rinse water and enrichment by the concentrated detergent solution typically maintains the desired detergent concentration.
  • a by-pass from the wash pump manifold may also be connected to the dispenser, for example, when the "demand" basis is employed.
  • Such solid detergent dispensers of the prior art have used a number of different techniques for converting solid detergent into concentrated detergent solution.
  • the majority of such devices have been designed to convert solid detergent from its "powdered” form.
  • the modes of operation of such dispensers depends somewhat upon the type of washing apparatus with which such dispensers are used, and upon the volume of washing performed by the wash machine apparatus over any given period of time.
  • the detergent dispenser may be remotely located (usually in a different physical location) from the washing apparatus and may be configured to convey the solid detergent directly from its shipping container (see for example U.S. Patent 3,595,438, issued July 27, 1971 to Daley, et al and 4,020,865, issued May 3, 1977 to Moffat et al).
  • Dispensers of the type usually have self-contained reservoirs for maintaining a supply of concentrated detergent solution produced thereby, and a pump for transferring on demand the concentrated detergent solution to the primary wash tank reservoir of the washing apparatus proper.
  • a pump for transferring on demand the concentrated detergent solution to the primary wash tank reservoir of the washing apparatus proper.
  • Such dispensers hold relatively smaller amounts of detergent, but offer the flexibility of being immediately accessible for loading by an operator of the washing apparatus, and are thus generally more versatile in their application, than are the larger remotely located dispensers, (see for example, U.S. Patent 4,063,663, issued December 20, 1977 to Larson et al).
  • dispensers are generally loaded from the top, and directly supply the adjacent washing apparatus reservoir with their produced detergent solution by gravity feed, thus eliminating the need and expense for pumps, whole providing an added dimension of reliability. It will be understood that the below-described prior art techniques used for converting solid detergent to concentrated liquid detergent, apply both to the large, remotely located, self-contained reservoir dispensers as well as to the smaller, wall or wash machine mounted, direct gravity feed types of dispensers.
  • One detergent dispenser technique for converting powdered detergent is the so-called "water-in-reservoir” type.
  • the powdered detergent is completely submerged under an aqueous solution in a holding tank or pot of the dispenser.
  • a standpipe usually located near the center of the dispenser tank, maintains a constant water/solution level within the dispenser tank.
  • a concentrated, saturated detergent solution or slurry is formed by the swirling action or agitation of the powdered detergent by the injected water.
  • the added water also causes a portion of the saturated solution in the pot to flow into the standpipe, which is connected to supply the wash tank reservoir of the washing apparatus.
  • the concentration level of the detergent solution produced by such a dispenser over a period of time can significantly vary as the detergent within the dispenser pot is diluted. Further, such techniques are not practical for use with powdered detergents containing active chlorine, since most of the chlorine contained in such detergents is quickly lost through decomposition once the detergent is wetted. Further, there may be safety hazards involved with use of such dispensers if the operator does not carefully follow directions when charging the dispenser. Charging or recharging of such dispensers requires an operator to pour powdered detergent directly into the standing water of the dispenser tank or pot.
  • Another technique for converting powder detergent into concentrated liquid detergent involves the technique of placing the powdered detergent over an inverted curved (usually conically or hemispherically shaped) screen having a mesh size smaller than the powdered detergent particles supported thereby. That powdered detergent which directly overlies the support screen is dissolved as needed, by a fine mist spray from a nozzle disposed below the screen.
  • the concentrated detergent solution formed by the spray falls by gravity into an underlying reservoir, or is directed by a conduit to the wash tank reservoir of the washing apparatus.
  • powdered detergent dispensers such as described by the Daley, Moffat and Larson patents have represented significant contributions to the art of detergent dispensing
  • the use of solid detergent in powdered form has a number of drawbacks in commercial applications. Due to increased sanitary standards and demands for shorter wash times, recently developed powdered detergents have relatively more complex detergent compositions that are more hazardous to the user, less stable and more difficult to dissolve in a satisfactorily uniform manner. Powdered detergents dissolve generally readily because of their high specific surface areas.
  • powdered detergents include a mixture of a number of components having relatively different dissolving times
  • such detergents are susceptible to differential solubility problems in automatic detergent dispensers, depending upon the rate of dispensing or the residence (dwell) time of contact between the detergent powder and the dissolving liquid.
  • Those particles having the greatest rate of solubility as well as the greatest specific surface tend to dissolve first, whereas those having the least specific surface and/or the lowest solubility rate tend to dissolve relatively slower.
  • Another problem with powdered detergents relates to possible incompatibility of those constituent components or particles required in the make-up of the detergent so as to perform the required washing function. This problem is particularly acute with those detergents required to contain an active chlorine source and an organic defoamer.
  • the problem associated with such detergents is that there is a substantial loss of available chlorine from such detergents in a relatively short period of time, due to the instability of the chlorine component.
  • the chlorine instability problem is even more acute with high alkalinity powdered detergents because many defoamers and chlorine-containing components are not stable in the presence of highly alkyline chemicals such as sodium hydroxide.
  • powdered detergent Another problem inherent with powdered detergent, if its components are of different particle sizes and densities, is segregation of those constituents particles during manufacturing, shipping and handling. Even when uniform distribution can be achieved during manufacture, subsequent shipping and handling may cause segregation, leading to non-uniformity in the composition of the detergent when it is withdrawn from the container.
  • powdered detergents are also subject to user misuse and possible abuse, due to user inefficiency, carelessness, or negligence. For example, due to their powdered form, such detergents are often misused for purposes for which they were not designed, and in applications wherein they may present safety problems to the user.
  • powdered detergents when handled in bulk form is that they are quite susceptible to spillage onto the floor, on the washing machine, etc. by the user. Also, as previously mentioned with respect to the water-in-reservoir type of dispenser, if such powdered detergents are added too quickly or in excessive quantities to the reservoir tank of such dispensers, they may present safety hazards to the user due to boil-over and spattering.
  • briquette Another form of solid detergent is the "briquette” form, comprising pre-shaped briquettes of solid detergent.
  • Dispensing systems for dissolving detergent briquettes are known in the art. See, for example, U.S. Patent Nos. 2,382,163, 2,382,164 and 2,382,165 all issued August 14, 1945 to MacMahon, and U.S. Patent No. 2,412,819, issued December 17, 1946 to MacMahon.
  • the detergent briquettes are dispensed from a modified water-in-reservoir pot-shaped dispenser wherein a number of the briquettes are held in a mesh basket forming a slot across the diameter of the pot.
  • a stream of water directed against the lowermost briquette, in combination with the swirling action of water engaging the submerged portion of the lowermost briquettes provides the dissolving action.
  • the primary advantage of using detergent briquettes in such dispensers is that the user can visually determine when the detergent dispenser reservoir needs a replenishing charge of detergent.
  • water-in-reservoir type of dispenser however, water is left standing in the reservoir, and a portion of the briquettes are submerged within that water. Accordingly, where there are incompatible components within the detergent briquettes, there can be undesirable interaction therebetween.
  • the briquette detergent approach has not attained that degree of commercial success in the conventional institutional and industrial washing machine art as has the powdered detergent dispensing approach.
  • a dispenser with the features of the first paragraph of this specification and the pre-characterizing part of claim 1 is known from FR-A-389 523.
  • the soap block is placed in a casing having a water- permeable bottom directly above a spray-forming nozzle which sprays water into the casing to dissolve the soap block placed therein.
  • the cover thereof has to be removed and the block has to be touched by hand which is not acceptable in the block comprises of detergent compositions of highly caustic kind since in this event the operator handling the block can be injured by the caustic detergent.
  • the concentration of the dissolved soap is not constant but varies and becomes more diluted as the soap block dissolves, since the surface area of the soap block being acted on by the impinging water decreases as the block is used up.
  • the present invention is intended to remedy the above mentioned disadvantages of the prior art dispensers. It solves the problem how to design a dispenser for solid block detergent compositions which can easily and safely be handled and which supplies a detergent solution of constant concentration until the detergent composition is exhausted.
  • the advantages offered by the invention are mainly that a concentrated detergent solution for use by washing machines (either of the type remotely located or the type located on or immediately adjacent the dispenser) is provided by proportionately dissolving as needed, solid block-type detergent compositions such as solid-cast detergents, detergent cakes and other solid detergents having significant geometric volume.
  • the dispenser of the present invention provides a simple, efficient, non-hazardous and reliable technique for producing highly concentrated detergent solution either on a demand basis or by the hydraulically linked by-pass method.
  • the concentrated detergent solution produced by the dispenser of this invention is substantially uniform throughout the conversion of the entire block of solid detergent, and the detergent charge can be rapidly and safely replaced by the user.
  • the dispenser of the present invention includes a housing member suitable for a fixed mounting to a solid surface, such that the housing member maintains a pre-determined position with respect to the mounting surface.
  • the housing is configured for mounting to a vertical wall; however, the housing could equally well be configured for mounting to fixed surfaces of other shapes and angular attitudes.
  • the detergent dispenser of the invention could be mounted directly to a washing apparatus to which the concentrated detegent solution is to be supplied, adjacent to such washing apparatus, or at a position remote from such washing apparatus.
  • the dispenser housing defines an inner cavity and access and discharge ports opening into the inner cavity.
  • the access port is of suitable configuration for accepting a cartridge containing solid block detergent into the inner cavity, in a manner such that at least one surface of the block detergent is exposed and substantially enclosed within the cavity.
  • the discharge port may be of any size and configuration suitable for providing a passageway through which the concentrated detergent solution produced by the dispenser can leave the inner cavity, for subsequent use by a washing machine. Such discharge port may open directly into an underlying collector or reservoir of the dispenser, into a wash tank reservoir of a washing machine, into a fluid-flow conduit, or into other appropriate means, for transportably carrying the concentrated detergent solution produced by the dispenser.
  • Nozzle means are mounted to extend into the housing cavity for directing a pressurized spray of pre-determined pattern and direction into the cavity, for dissolving the solid block detergent in the cavity by hydraulic and erosive action of the spray pattern upon the exposed surface of the block detergent.
  • a cartridge containing a charge of solid block detergent is introduced into the cavity of the dispenser housing through its access port.
  • the cartridge positions and retainably holds the received block detergent in fixed position within the cavity, to position the exposed surface of the block detergent in cooperative predetermined alignment with the nozzle means, such that the spray pattern from the nozzle means impinges generally uniformly upon substantially the entire exposed surface of the held block detergent.
  • One embodiment of the invention includes safety switch means for blocking fluid flow to the nozzle means whenever the solid block detergent cartridge is not properly disposed in its pre-determined fixed position within the housing cavity.
  • the solid block detergent charge is retainably held by a cartridge, which holds a geometrically shaped volume of the solid block detergent so as to expose at least one surface thereof.
  • the cartridge is configured for insertion into the access port of the housing.
  • the retaining means is disposed to accept the cartridge and to releasably maintain the cartridge in fixed position relative thereto such that the exposed surface of the held block detergent lies substantially enclosed within the cavity and in fixed pre-determined position with respect to the nozzle means.
  • substantially the entire detergent holding portion of the cartridge is configured for insertion within the inner cavity of the housing; however, other cartridges could be configured according to the principles of this invention, wherein a portion of the cartridge lies outside of the housing, for example, in a manner such that the cartridge itself forms a part of the housing which defines the inner cavity.
  • the cartridge may include a disposable receptacle member for retainably holding the solid block detergent.
  • the disposable cartridge is particularly useful when the dispenser is used with solid detergent compositions of the cast type, wherein the disposable cartridge receptacle may comprise the actual mold in which the cast detergent is manufactured.
  • the detergent cartridge would be configured to retainably accept and hold at least one charge of solid block detergent, and such that a spent or depleted detergent charge could be readily replaced by a fresh charge when desired or required.
  • the invention applies both to dispenser configurations wherein the nozzle spray is directed toward the exposed detergent surface from a position below the exposed surface as well as to configurations wherein the spray is directed from a position above the exposed detergent surface.
  • the nozzle means is generally disposed above the exposed detergent surface and such that the longitudinal spray axis of the nozzle means is generally at a right angle to the general plane of the exposed detergent surface.
  • the exposed detergent surface is maintained at a predetermined fixed angle within the cavity, between 10 degrees and 90 degrees with the horizonal, such that the spray from the nozzle means dissolves the solid detergent both by hydraulic action through direct impingement upon the surface and by erosive action of the converted spray liquid which cascades by gravity down the exposed detergent surface.
  • the cartridge for the solid block detergent can be designed within the scope of this invention.
  • the cartridge preferably would include a screen mesh member mounted below the solid detergent block either for supportably holding the block detergent, or for preventing particles thereof from falling into the underlying collection reservoir for the concentrated detergent solution.
  • One embodiment of the cartridge includes a mesh member overlying the exposed surface of the detergent block, to prevent solid particles of the retainably held detergent block from passing directly to the discharge port of the cavity.
  • a preferred configuration of such an insertable cartridge comprises a plurality of receptacles for retainably holding a plurality of different blocks of solid detergent compositions.
  • Such plurality of receptacles may be configured and sized to hold incompatible detergent compositions, whereby the pressurized spray of the nozzle means simultaneously dissolves the solid detergent compositions from each of the plurality of receptacles in desired proportions, depending upon the relative sizes of the receptacles and the particular compositions of the solid detergents held respectively thereby.
  • a detergent dispenser 20 for solid detergent compositions of the block-type generally constructed according to the principles of this invention. That embodiment of the dispenser 20 illustrated in the Figures is one of the type suitable for servicing relatively smaller wash applications, wherein the detergent dispenser is generally mounted directly to the washing machine or immediately adjacent thereto, such that the concentrated detergent solution formed by the dispenser will flow by gravity into the wash tank of the washing machine proper (not illustrated). It will be understood that the particular embodiment described in the Figures, represents only one of many possible embodiments and applications for the invention and that the invention is not limited to those embodiments herein disclosed.
  • the dispenser 20 has a housing portion 21, constructed of any suitable material capable of withstanding exposure to highly caustic detergent solutions, and is preferably configured of stainless steel or molded plastic material.
  • the housing 21 has a generally planar back wall 21 a suitable for direct engagement with and mounting to a vertical mounting surface or wall 15 (Fig. 7).
  • the back wall 21 a includes a plurality of mounting slots 22 formed therethrough, to enable fixed mounting of the housing 21 to a solid vertical surface such as a vertical wall of a washing machine or a vertical wall disposed adjacent a washing machine. It will be understood that the housing 21 could be configured for mounting to any solid surface, and is not limited to mounting to a vertical, or even to a planar surface.
  • the housing 21 defines a substantially enclosed inner cavity 30.
  • the upper portion of the inner cavity will be referred to as the spray region 30a of the cavity, and the lower portion of the inner cavity 30 will be referred to as the collector region 30b thereof.
  • the upper portion of the housing 21 defines a mouth or access port 32 opening into the inner cavity 30, and a discharge port 34 (Figs. 5 and 6) opening into the inner cavity 30 and forming a passageway through the housing 21 for concentrated detergent solution collected or accumulated within the lower portion of the inner cavity 30 of the housing 21.
  • the housing 21 has a hose clamp extension 35 configured around the discharge port 34, having a plurality of annular ribs configured for engaging the inner walls of a connecting conduit or hose(not illustrated), for directing fluid flow from the discharge port 34. While a specific configuration of the discharge port 34 is illustrated in the embodiment of the invention disclosed in the Figures, it will be understood that other configurations of the discharge port are possible depending upon the overall configuration of the dispenser 20.
  • the entire bottom portion of the inner cavity 30 may comprise the discharge port 34, which would directly open into the underlying reservoir of such a dispenser apparatus, (see for example such an outlet port configuration as illustrated in U.S. Patent 4,020,865, issued May 3, 1977 to Moffat et al).
  • the access port 32 can assume many varied configurations, and need not necessarily be disposed so as to open into the upper portion of the inner cavity 30.
  • the access port may be located at the bottom of the dispenser housing, and may also comprise the outlet port of such a dispenser.
  • An upper front wall 21 b of the housing 21 projects downwardly from the access port 32 at an inclined angle to the horizontal.
  • the upper front wall 21 b forms an angle of approximately 60 degrees with the horizontal.
  • the upper front wall 21 b terminates at and is continuous with a first lower wall 21 c of the housing 21, which is also slightly inclined with respect to the horizontal and lies in a plane generally parallel to that of the upper front wall 21 b.
  • the lower front wall 21 d terminates at and is continuous with a bottom wall 21 e of the housing, through which the discharge port 34 is formed.
  • the bottom wall 21 e is generally planar, however the bottom wall 21 e could assume many different configurations (such as ramp-shaped or funnel-shaped), and is generally configured so as to direct liquids accumulated within the lower collector region 30c of the housing to the discharge port 34.
  • the back wall 21 a extends between the bottom wall 21 and an upper wall, generally designated at 21f, which extends to and defines one edge of the access port 32.
  • an upper wall generally designated at 21f, which extends to and defines one edge of the access port 32.
  • that region of the inner cavity 30 generally located between the upper front wall 21 b, the first lower wall 21 c and the back wall 21a and the upper wall 21f comprises the upper spray region 30a; whereas that region of the inner cavity 30 generally located between the lower front wall 21 d and the back wall 21 a, and extending down to the bottom wall 21 e generally comprises the collector region 30b.
  • the housing 21 further has a pair of oppositely disposed side walls 21g generally vertically extending between the bottom upper wall 21 and the upper wall 21f, and laterally extending between the back wall 21 a and the frontwall 21b, the first lower wall 21 and the lower front wall 21 d.
  • the side walls 21 g are each configured to define a flange or land region 24 extending into the inner cavity 30 in generally parallel spaced relationship to one another and being generally co-planar with one another so as to lie in a plane generally parallel to that of the upper front wall 21 b.
  • the land regions 24 are disposed to extend from the access port 32 downwardly to the bottom wall 21 e, and cooperatively form with the front wall 21 b oppositely disposed channels or races within the inner cavity 30 for slidably retainably engaging a cartridge 40.
  • the cartridge 40 is basically a receptacle or container-shaped member suitable for retainably holding in fixed position relative thereto a block of solid detergent composition.
  • solid block detergent composition refers to any geometric volume or mass of solid detergent regardless of the method in which such detergent is manufactured, such as a cast detergent, a cake detergent, and agglomerate- type detergent, or other types of solid detergents having substantial volume or mass (as distinguished from solid "powdered” or "liquid” detergents).
  • the cartridge 40 generally comprises a bottom surface 41, a lower peripheral side wall portion 42, an intermediate ledge region 43 and an upper peripheral side wall portion 44. While the cartridge 40 may assume any geometric configuration suitable for exposing at least one broad surface of a solid block detergent composition retainably held thereby, the particular configuration of the cartridge illustrated in Fig. 2 is of a generally rectangular shape.
  • the lower peripheral side wall portions 42 extend between the bottom surface 41 and the intermediate ledge region 43, with all except one surface of the lower peripheral side walls (that surface designated as 42a) being disposed generally perpendicular to the bottom surface 41.
  • the non-perpendicular lower peripheral side wall portion 42a is configured to define an angle with the bottom surface 41 corresponding to the included angle defined between the upper front wall 21b and the first lower wall 21c of the dispenser housing 21 (see Fig. 8).
  • the intermediate ledge region 43 of the cartridge 40 lies in a plane generally parallel to the bottom surface 41.
  • the upper peripheral side wall portion 44 projects upwardly from the intermediate ledge region 43, with the walls on three sides thereof lying generally perpendicular thereto.
  • the fourth side of the upper peripheral side wall 44a forms an included angle with the general plane of the intermediate ledge region 43 substantially equal to that of the included angle formed between the lower front wall 21 d and the bottom wall 21 e of the dispenser housing 21 (see Fig. 8).
  • the 43a portion of the intermediate ledge region is disposed between the lower and upper peripheral side wall portions 44a and 44 respectively, and is somewhat wider (as measured between corresponding upper and lower peripheral side wall portions) than the width of the intermediate ledge region 43 of the other portions of the cartridge 40.
  • a plurality of raised land areas or mounting surfaces 45 project upwardly from the intermediate ledge region 43a, the upper surfaces respectively thereof lying generally in a common plane.
  • the lower peripheral side walls 42 and 42a cooperatively define with the bottom surface 41 a first receptacle-shaped container 46 for retainably holding a geometrically shaped volume or mass of solid block detergent composition 100 (see Fig. 8).
  • the first receptacle-shaped container 46 of the cartridge 40 retainably holds a solid "cast" detergent composition which is poured directly into the receptacle-shaped container portion 46 of the cartridge 40, the container portion 46 physically forms the mold in which the solid cast detergent 100 is manufactured.
  • the retainably held charge of solid detergent 100 within the container portion 46 of the cartridge 40 defines a broad, generally planar upper surface 100a lying generally in the same plane as the intermediate ledge region 43, or slightly therebelow.
  • the upper detergent surface 100a is disposed for exposure to spray from a nozzle means, hereinafter described in more detail.
  • the elongated intermediate ledge region 43a defines the bottom surface of a second receptacle-shaped container, generally designed at 47 (see Figs. 2 and 8).
  • a screen or mesh member 50 is configured for mounting to the intermediate ledge region 43 (other than at the extended intermediate ledge region portion 43a) and to the raised mounting surfaces 45, in spaced relationship to the underlying extended intermediate ledge region 43a, so as to overlie respectively the first and second receptacle-shaped container region 46 and 47.
  • the screen member 50 has a first generally planar portion 50a, (Fig. 2) a second generally planar portion 50b and an interconnecting wall portion 50c.
  • the first screen portion 50a is sized to fit between the opposing upper peripheral side walls 44 and is configured for mounting to the three contiguous portions of the intermediate ledge regions 43, exclusive of ledge region 43a, for substantially overlying the first receptacle-shaped container portion 46 of the cartridge 40.
  • the second portion 50b of the screen member 50 lies in a plane generally parallel to and spaced above that of the first screen portion 50a, and is configured for mounting to the plurality of raised mounting surfaces 45 so as to substantially overlie the extended intermediate ledge region 43a and the second receptacle-shaped container region 47 of the cartridge 40.
  • the interconnecting wall portion 50c of the screen member 50 forms included angles with the first and second 50a and 50b portions of the screen member 50, substantially the same as those included angles which the lower peripheral side wall portion 42a forms with the bottom surface 41 and with the intermediate ledge region 43a of the cartridge 40.
  • the interconnecting wall portion 50c of the screen member 50 forms included angles with the first and second 50a ahd 50b portions of the screen member 50, substantially the same as those included angles which the lower peripheral side wall portion 42a forms with the bottom surface 41 and with the intermediate ledge region 43a of the cartridge 40.
  • the interconnecting wall portion 50c of the screen member 50 lies generally co-planar with the lower peripheral side wall portion 42a, and operatively forms an extension thereof, to define with the extended intermediate ledge region 43a and the upper peripheral side wall portion 44a and those oppositely disposed portions of the upper peripheral side wall 44 lying contiguous with the extended intermediate ledge region 43a, the second receptacle-shaped container 47.
  • the cartridge 40 may be constructed of any suitable material that is capable of withstanding exposure to highly caustic detergent solutions, and is preferably configured or molded plastic material such as polyethylene or polypropylene.
  • the cartridge can be supplied with solid block detergent and sold as an article of commerce, wherein the entire cartridge 40 or portions thereof can be discarded after the detergent charge retainably held thereby has been exhausted.
  • the screen member 50 would be permanently welded or bonded to the intermediate ledge region 43 and the plurality of raised land areas 45.
  • the cartridge 40 could be a reusable item, possibly constructed of stainless steel, wherein the screen member 50 could be detachably secured to the underlying cartridge 40 so as to enable re-charging of the solid block detergent retainably held by the various receptacles of the cartridge.
  • the screen member 50 may be of any suitable material capable of withstanding exposure to highly caustic detergent solutions, and is in the preferred embodiment, preferably constructed of a plastic material.
  • the mesh size of the screen member 50 is configured so as to be small enough to prevent solid particles of the solid block detergent held by the receptacle-shaped containers of the cartridges 40 from passing therethrough, yet must be large enough so as to permit relatively unobstructed passage therethrough of a pressurized spray pattern directed at the underlying exposed surfaces of the solid block detergent.
  • the mesh size of the screen member 50 should be no larger than the largest dimension of the discharge port 34, so as to prevent any solid chunks or pieces of the solid block detergent which would pass therethrough, from clogging the free flow of concentrated detergent solution through the discharge port 34
  • the first receptacle-shaped container 46 of the cartridge 40 is configured to hold the primary solid detergent composition used in the cleaning operation.
  • the preferred usage of the first receptacle-shaped container 46 would be for retainably holding a solid "cast" block detergent; however, other forms of solid block-type detergent could be retainably held by the first receptacle-shaped container 46.
  • the second receptacle-shaped container 47 is configured for retainably holding a long narrow block of a second solid block detergent composition 102 (see Fig. 10) or a plurality of pillow-shaped pieces, briquettes, tablets or pellets of a second solid detergent composition, such as a chlorine source (e.g. calcium hypochlorite) or a defoamer detergent composition.
  • the briquette or tablet form of the second detergent composition retainably held by the second receptacle-shaped container 47 is illustrated at 103 in Fig. 8.
  • the cartridge 40 illustrated in Figs. 2 and 8 includes two receptacle-shaped containers for separately holding two different solid block-type detergent compositions
  • the cartridge 40 need not necessarily contain a plurality of separably distinct receptacles.
  • the cartridge could comprise a single recep- tacte-shaped container for retainably holding a single mass or block of solid detergent composition which detergent composition could be uniform or could contain "cores" or "pockets” or entire sections of different detergent compositions such as chlorine sources, defoamers, etc.
  • the receptacle 40 could be modified to include more than two receptacle-shaped containers, as indicated in Fig.
  • first receptacle-shaped container 46 is partitioned by means of a dividing wall 48, to define a pair of receptacle-shaped containers 46a and 46b for retainably holding two distinct masses or geometrically shaped volumes of solid block detergent compositions.
  • the broad exposed surface 100a of the retainably held solid block detergent mass 100 is disclosed as a generally planar surface, other configurations and shapes of such surface are possible, for example, but not limited to concave convex, spherical, pyramidical, conical, etc. shapes.
  • the exposed detergent surface 100a is generally illustrated as lying co-extensive with the outer peripheral boundaries of the cartridge 40 (e.g. generally co-planar with the intermediate ledge region 43 thereof), the cartridge retaining the solid block detergent need not necessarily engage the solid block detergent on all but one side thereof.
  • the cartridge actually retainably holds and maintains the position of the solid block detergent relative thereto, such that the exposed surface or surfaces thereof, wherever they may be, are maintained in predetermined fixed positions relative to the projected spray pattern or patterns from a nozzle means, hereinafter described in more detail.
  • the height and width of the cartridge 40 are sized for cooperative insertion within the access port 32 of the housing 21, as illustrated in Fig. 1.
  • the lower portions of the intermediate ledge regions 43, which lie on oppositely disposed sides of the cartridge 40 are configured to slidably engage and be directed by the land or flange portions 24 of the sidewalls 21 g of the housing 21, such that the flange portions 24 of the side walls 21g cooperatively guide the cartridge 40 from its receipt through the access port 34 into a fixed pre-determined position with respect to the housing, (as indicated in Fig. 8).
  • the cartridge 40 lowers under the force of gravity and is directed by the guiding flanges 24 into the inner cavity 30, until the lower peripheral side wall portion 42a comes into resting engagement with the first lower wall 21 c of the housing 21.
  • the upper peripheral side wall portion 44a located at the "top" portion of the positioned cartridge 40 cooperatively engages the side wall flanges 24 and the upper wait 21f f of the housing 21 for preventing liquid spray out from the upper spray region 30a of the inner cavity 30 through the access port 32.
  • That portion of the upper peripheral side wall 44 oppositely disposed from the side wall portion 44a defines a semi-circular projection 44b comprising a "handle", allowing an index or middle finger to be inserted in the hollow of such handle to permit ease of holding and removal of the cartridge 40 from the dispenser housing 21.
  • a conduit member 60 is secured to the upper wall 21f of the housing 21 and projects therethrough into the upper spray region 30a of the inner cavity 30.
  • a spray-forming nozzle 61 is threaded or otherwise properly secured to that end of the conduit 60 extending into the inner cavity 30 and is disposed therein, so as to project a spray pattern of pre-determined shape at substantially the entire respective exposed solid, detergent block surfaces of the detergent within the various receptacle members of the cartridge 40.
  • the nozzle 61 is oriented, relative to the "fixed" position of the cartridge 40 within the inner cavity 30, such that the longitudinal spray axis 62 from the nozzle is disposed generally perpendicular to the broad exposed upper surface 100a of the solid block detergent volume 100.
  • the spray nozzle 61 may be of any suitable configuration and construction for projecting a pressurized spray of aqueous liquid (preferably water) received through the conduit 60, in a pre-determined pattern, configured to directly impinge upon substantially the entire exposed surfaces of the solid block detergent retainably held by the cartridge 40.
  • aqueous liquid preferably water
  • the particular spray nozzle produces a "square" spray pattern (as viewed in a plane generally perpendicular to the longitudinal spray axis 62) for directing the spray pattern ejected therefrom at substantially the entire exposed surface 100a as well as at the exposed surface or surfaces of the solid block detergent retainably held by the second receptacle-shaped container 47.
  • the water supply conduit 60 passes through a siphon breaker 63 and is connected, in operation, to a suitable pressurized source of water, generally ranging between 5 and 70 psi.
  • a safety valve 64 preferably as a solenoid valve, may also be inserted between the nozzle 61 and the pressurized water source for selectively blocking the flow of water through the conduit 60 to the nozzle 61 (see Fig. 9).
  • a safety switch configuration is mounted within the housing 21 for sensing the operative position of the cartridge 40 within the inner cavity 30.
  • the safety mechanism comprises a reed switch 70 mounted in a fixed position within the collector region 30b of the inner cavity 30 by means of a mounting bracket 71 (see Fig. 8).
  • the upper peripheral side wall portion 44a of the cartridge 40 contains an encapsulated magnet 72.
  • the position of the magnet and the reed switch 70 are relatively disposed with respect to one another, such that the reed switch 70 is activated by the magnetic flux of the magnet 72 only when the cartridge 40 has been fully accepted into the inner cavity 30 of the dispenser 21 in its pre-determined fixed position (as illustrated Fig.
  • the access port 32 of the housing 21 is substantially closed by the positioned cartridge member 40.
  • the reed switch 70 is activated by the magnet 72, so as to energize the solenoid valve 64 by means of the signal flow path 73 (and by any appropriate circuit means, not illustrated in the Figures) to "open" the valve 64, thus permitting pressurized fluid flow to the nozzle 61 only when the cartridge 40 is positioned in its predetermined fixed position within the inner cavity 30 of the housing 21.
  • the reed switch changes its energization state, providing an appropriate energizing (or de-energizing) signal to the valve 64, to block pressurized fluid flow through the conduit 60 to the nozzle 61.
  • the cartridge 40 retainably holds the charge of solid block detergent, and is configured as a disposable item such that once the charge of solid detergent contained thereby is depleted by the spray action within the dispenser, the cartridge itself is rapidly removed from the housing and discarded.
  • the volume of solid block detergent 100 retainably held by the first receptacle-shaped container 46 comprises a volume of solid cast block detergent which has been formed during manufacture thereof directly into the first receptacle-shaped container 46, or can be cut from a larger block of such solid detergent to fit the retaining shape of the first receptacle-shaped container 46.
  • the volume of solid block detergent 100 comprises the primary detergent composition (generally highly alkaline) required for cleaning operations within the washing machine which the detergent dispenser 20 is servicing.
  • the second receptacle-shaped container 47 contains a relatively smaller charge of solid block detergent composition formed into tablets or pellets.
  • the solid block detergent tablets 103 are comprised of calcium hypro- chlorite, or other active chlorine sources, and provide a source of chlorine when subjected to contact with an aqueous solution.
  • the pellets or tablets 103 could also contain or be replaced by a defoamer detergent composition.
  • both the chlorine and/or the defoamer compositions, if desired; could be included within the larger solid detergent block 100; could be mixed with one another in tablet form in the second receptacle-shaped container 47; could be formed as isolated inserts or cores .
  • the density and composition of the solid detergent compositions contained within a single cartridge 40 are selected, and the relative solid detergent blocks are sized with respect to one another such that the proper desired mixture results therefrom when the nozzle spray is directed upon the exposed surfaces thereof.
  • the physical make-up of the respective solid detergent blocks is also designed such that the dissolution rates thereof are somewhat uniform with respect to their respective volumes, such that all receptacles of the cartridge 40 are depleted generally uniformly.
  • Charging the dispenser 20 with a cartridge 40 is a simple and relatively fool-proof technique.
  • An operator grasps the loaded cartridge 40 by means of the handle 44b and merely aligns the forward end thereof (i.e. the 44a, 43a and 42a portion) with the access port 32 of the dispenser 21 and drops the cartridge 40 into the access port 32, as indicated in the Figures.
  • the land or flange regions 24 of the side walls 21 g of the dispenser 21 automatically cooperatively engage the corresponding intermediate ledge regions 43 of the cartridge 40, to slidably guide and position the cartridge 40 within the inner cavity 30 of the dispenser 21, such that the broad upper surface 100a of the solid detergent block 100 comes to rest when the cartridge 40 is fully inserted within the housing 21, at predetermined fixed position relative to the overlying nozzle 61.
  • the unique configuration of the cartridge 40 will not cooperatively engage the guiding flange portions 24 of the side walls 21 g of the dispenser 21, thus preventing the cartridge 40 from proceeding downwardly to its predetermined resting position within the cavity 30.
  • the magnet 72 comes into cooperative activating position with respect to the reed switch 70 enabling the solenoid valve 64 to open the fluid flow path through conduit 60 to the spray nozzle 61.
  • the magnet 72 would not come into the activating or "safe" proximity range of the reed switch 70, which would cause the reed switch 70 and associated circuitry connected therewith (not illustrated), to energize the solenoid valve 64 so as to block fluid flow through conduit 60 to the nozzle 61.
  • the masses or volumes of solid detergent blocks retainably held by the various receptacles within the cartridge 40 are dissolved at a pre-determined rate, by the pressurized spray from the nozzle 61.
  • a pressurized source of water is provided to the nozzle 61 as commanded by appropriate control means within the washing machine proper which the detergent dispenser services.
  • appropriate control means within the washing machine proper which the detergent dispenser services.
  • an electronic control network such as described in U.S. Patent No. 3,680,070 to Nystuen could be used to selectively provide pressurized water to the nozzle 61.
  • the hydraulic by-pass method as previously described, could be employed, as well as any other appropriate control mechanism.
  • the nozzle Once pressurized fluid flow is applied to the nozzle 61, the nozzle generates a pressurized spray pattern of pre-determined configuration, which is uniformly directed across substantially the entire upper exposed surface 1 00a of the solid detergent block 100, as well as against the exposed surfaces of the solid detergent block materials 102 or 103 contained within the second receptacle-shaped container 47.
  • the spray pattern passes through the mesh of the screen member 50 and impinges directly upon the exposed surfaces of the retainably held solid detergent blocks, dissolving by means of the hydraulic action of the spray itself, a portion of the solid detergent blocks, at their respective exposed surfaces.
  • the spray After striking the exposed surface 100a of the detergent block 100, the spray (now converted into a liquid), flows by gravity down the exposed surface 100a, dissolving by erosive action, further detergent at the exposed upper surface 100a.
  • the concentrated liquid solution cascades over and through the solid detergent chlorine-source or defoamer pellets or tablets 103 held within the second receptacle-shaped container 47, to release a predetermined proportionate amount of chlorine or defoamer components therefrom- all of which passes in solution as concentrated detergent solution to the lower collector region 30b of the dispenser 21.
  • the "collected" concentrated detergent solution passes by gravity through the discharge port 34 and hose clamp extension 35 into appropriate conduit means or directly into an underlying wash tank reservoir for subsequent use by a washing machine. Besides the erosive action of solution passing from the upper exposed surface 100a of the detergent mass 100, the volume of solid detergent contained within the second receptacle-shaped container 47 is further directly dissolved by hydraulic action from the spray projected from the nozzle 61.
  • the invention applies to dispenser configurations wherein the nozzle 61 is mounted below the exposed detergent surface, it is generally preferable to position the nozzle 61 in a position overlying the solid detergent block to be dissolved, and to place the exposed surface or surfaces of the solid block detergent at an angle with respect to the horizontal (preferably between 10° and 90°), to supplement the hydraulic dissolution with the erosive dissolution caused by the solution flowing down the exposed surface(s).
  • an inclination of the exposed detergent surface 100a of approximately 60° with the horizontal provides adequate dwell time for the downwardly flowing water, while maintaining a sufficiently small response time for the dispenser (i.e. that elapsed time after which the pressurized spray is projected from the nozzle 61 to the time in which the majority of the concentrated detergent solution produced thereby passes in solution out of the discharge port 34).
  • the first lower wall 21 c of the dispenser housing 21, as well as the upper and lower peripheral side wall portions 44a and 42a of the cartridge 40 are inclined slightly with respect to the horizontal (when the dispenser and enclosed cartridge 40 are mounted in operative position), to insure drainage of any liquid solutions (either the projected spray or resultant concentrated detergent solution) therefrom. Any liquid coming in contact with these surfaces is directed toward the collector region 30b of the cavity 30.
  • the cartridge Whenever the charge of solid detergent contained within the various receptacles of the cartridge 40 are depleted, the cartridge is rapidly replaced by slidably removing the spent cartridge from the inner cavity 30, through the access port 32, and simply replacing the spent cartridge with a fully charged cartridge 40.
  • the disposable cartridge which could be physically re-charged before replacement thereof into the housing 21.
  • cartridge 40 illustrated in the Figures illustrates a cartridge which is completely insertable within the inner cavity 30 of the housing 21
  • other dispenser housing configurations could be employed within the scope of this invention, wherein the access port 32 would comprise a void or hole within one or more walls of the housing 21 and wherein the cartridge would be configured as an integral part of the housing proper, such that the cartridge 40 itself, when properly positioned in its pre-determined fixed resting position, prevents hazardous spray from the nozzle 61 out of the access port 32.
  • the access and discharge ports 32 and 34 respectively could in fact comprise the same openings, for example in a "bottom loading" dispenser.
  • the preferred embodiment of the invention has been generally described in reference to spray washing machines, the concept is equally adaptable to soaker-type machines as well as fabric washing machines.
  • the dispenser of this invention is particularly suitable for efficiently and safely dispensing generally incompatible detergent compositions in a manner that provides uniformity in detergent concentration over the entire charge of detergent held by the dispenser.
  • Usage of solid detergent in the block form eliminates or minimizes the handling, segregation, misuse, safety and other problems associated with the use and dispensing of liquid detergents and solid detergents in powdered form.
  • the replaceable and disposable cartridge techniques of loading the dispenser further simplifies its use and provides an added dimension of safety.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Washing And Drying Of Tableware (AREA)
  • Cleaning In General (AREA)
  • Detail Structures Of Washing Machines And Dryers (AREA)
  • Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
EP80900105A 1978-12-05 1980-06-17 Dispenser for solid block detergent compositions Expired EP0020709B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US96662078A 1978-12-05 1978-12-05
US966620 1978-12-05

Publications (3)

Publication Number Publication Date
EP0020709A1 EP0020709A1 (en) 1981-01-07
EP0020709A4 EP0020709A4 (en) 1981-05-15
EP0020709B1 true EP0020709B1 (en) 1985-01-16

Family

ID=25511646

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80900105A Expired EP0020709B1 (en) 1978-12-05 1980-06-17 Dispenser for solid block detergent compositions

Country Status (8)

Country Link
EP (1) EP0020709B1 (enrdf_load_stackoverflow)
JP (2) JPS6233918B2 (enrdf_load_stackoverflow)
AT (1) ATE11212T1 (enrdf_load_stackoverflow)
CA (1) CA1140426A (enrdf_load_stackoverflow)
DE (1) DE2967361D1 (enrdf_load_stackoverflow)
GB (2) GB2047753B (enrdf_load_stackoverflow)
SE (1) SE8005526L (enrdf_load_stackoverflow)
WO (1) WO1980001160A1 (enrdf_load_stackoverflow)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4687121A (en) * 1986-01-09 1987-08-18 Ecolab Inc. Solid block chemical dispenser for cleaning systems
EP0245759A3 (de) * 1986-05-14 1990-05-02 Henkel Kommanditgesellschaft auf Aktien Vorratspackung eines festen Reinigerblocks und Verfahren zu deren Herstellung
DE3620900A1 (de) * 1986-06-21 1987-12-23 Lang Apparatebau Gmbh Einspuel- und dosiergeraet
ATE76730T1 (de) * 1987-03-12 1992-06-15 Tripp Eberhard Etol Werk Vorrichtung zum dosierten einspeisen eines reinigers in spuelmaschinen.
US5167350A (en) * 1988-05-02 1992-12-01 Henkel Kommanditgesellschaft Aut Aktien Detergent dispensing device
DE3831778A1 (de) * 1988-09-19 1990-03-22 Henkel Kgaa Waschmitteldosiervorrichtung
GB2226233A (en) * 1988-12-22 1990-06-27 Unilever Plc Dispenser
DE3930974A1 (de) * 1989-09-16 1991-03-28 Miele & Cie Dosiergeraet fuer geschirrspuelmaschinen oder waschmaschinen
US5262132A (en) * 1990-04-30 1993-11-16 Diversey Corporation Solid detergent dispensing system
DE69123763T2 (de) * 1991-10-25 1997-07-10 Unilever Nv Dosiergerät für reinigungsmittel
US5194230A (en) * 1991-12-02 1993-03-16 Ecolab Inc. Solid product static brake for solid block chemical dispensers
US6737464B1 (en) 2000-05-30 2004-05-18 University Of South Carolina Research Foundation Polymer nanocomposite comprising a matrix polymer and a layered clay material having a low quartz content
US20130294978A1 (en) * 2012-05-03 2013-11-07 Reynato Mariano Chemical dissolving dispenser
BR112016011846B1 (pt) * 2013-11-26 2021-02-17 Ecolab Usa Inc. embalagem de produtos e sistema dispensador para dispensar um bloco de produto sólido solúvel
WO2018159357A1 (ja) * 2017-03-03 2018-09-07 パナソニックＩｐマネジメント株式会社 衣類洗浄装置
US12043942B2 (en) 2020-01-24 2024-07-23 Midea Group Co., Ltd. Dispenser for a laundry washing machine with overflow configuration
US11421368B2 (en) * 2020-01-24 2022-08-23 Midea Group Co., Ltd. Dispenser for a laundry washing machine
TR202021290A1 (tr) * 2020-12-22 2022-07-21 Vestel Beyaz Esya Sanayi Ve Ticaret Anonim Sirketi Bir montaj plakası bulunan bir kurutucu cihaz.

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Publication number Priority date Publication date Assignee Title
FR389523A (fr) * 1908-04-23 1908-09-11 Leonard Evans Travis Perfectionnements apportés aux porte-savon
US1945351A (en) * 1932-02-12 1934-01-30 Foster D Snell Inc Soap dispenser

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Publication number Priority date Publication date Assignee Title
GB256336A (en) * 1925-05-09 1926-08-09 Arthur Davall Hopkins An improved portable clothes washing machine
US2387944A (en) * 1943-04-23 1945-10-30 Clean Ite Chemical Co Dispenser for washing compounds
US2686080A (en) * 1945-12-26 1954-08-10 Soapsudzer Inc Process of impregnating a liquid with a substance miscible therewith
US4063663A (en) * 1975-12-15 1977-12-20 Economics Laboratory, Inc. Powdered detergent dispenser

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
FR389523A (fr) * 1908-04-23 1908-09-11 Leonard Evans Travis Perfectionnements apportés aux porte-savon
US1945351A (en) * 1932-02-12 1934-01-30 Foster D Snell Inc Soap dispenser

Also Published As

Publication number Publication date
JPH0217199B2 (enrdf_load_stackoverflow) 1990-04-19
GB2123041B (en) 1984-08-01
GB2047753A (en) 1980-12-03
ATE11212T1 (de) 1985-02-15
WO1980001160A1 (en) 1980-06-12
EP0020709A4 (en) 1981-05-15
GB8312666D0 (en) 1983-06-15
SE8005526L (sv) 1980-08-04
JPS55501049A (enrdf_load_stackoverflow) 1980-12-04
EP0020709A1 (en) 1981-01-07
CA1140426A (en) 1983-02-01
JPS61143092A (ja) 1986-06-30
GB2123041A (en) 1984-01-25
JPS6233918B2 (enrdf_load_stackoverflow) 1987-07-23
GB2047753B (en) 1983-12-21
DE2967361D1 (en) 1985-02-28

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