EA201791362A1 - Способ получения содержащего кобальт катализатора на подложке для синтеза фишера-тропша - Google Patents

Способ получения содержащего кобальт катализатора на подложке для синтеза фишера-тропша

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Publication number
EA201791362A1
EA201791362A1 EA201791362A EA201791362A EA201791362A1 EA 201791362 A1 EA201791362 A1 EA 201791362A1 EA 201791362 A EA201791362 A EA 201791362A EA 201791362 A EA201791362 A EA 201791362A EA 201791362 A1 EA201791362 A1 EA 201791362A1
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EA
Eurasian Patent Office
Prior art keywords
substrate
cobalt
containing catalyst
extrudate
granulate
Prior art date
Application number
EA201791362A
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English (en)
Other versions
EA036728B1 (ru
Inventor
Юэн Фергюсон
Александер Патерсон
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Бп П.Л.К.
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Application filed by Бп П.Л.К. filed Critical Бп П.Л.К.
Publication of EA201791362A1 publication Critical patent/EA201791362A1/ru
Publication of EA036728B1 publication Critical patent/EA036728B1/ru

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Abstract

В заявке описан способ получения содержащего кобальт катализатора для синтеза Фишера-Тропша, обладающего хорошими физическими характеристиками и высоким содержанием кобальта. Одним объектом настоящего изобретения является способ получения содержащего кобальт катализатора на подложке для синтеза Фишера-Тропша, указанный способ включает следующие стадии: (a) пропитка подложки, представляющей собой порошок или гранулят, содержащим кобальт соединением; (b) прокаливание пропитанной подложки, представляющей собой порошок или гранулят, и экструзия с получением экструдата; или экструзия пропитанной подложки, представляющей собой порошок или гранулят, с получением экструдата и прокаливание экструдата; и (c) пропитка прокаленного продукта содержащим кобальт соединением; или получение порошка или гранулята из прокаленного продукта, пропитка содержащим кобальт соединением и экструзия с получением экструдата.
EA201791362A 2014-12-19 2015-12-21 Способ получения содержащего кобальт катализатора на подложке для синтеза фишера-тропша EA036728B1 (ru)

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PCT/EP2015/080745 WO2016097402A1 (en) 2014-12-19 2015-12-21 Process for preparation of a supported cobalt-containing fischer-tropsch synthesis catalyst

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201702251D0 (en) * 2017-02-10 2017-03-29 Bp Plc Process for producting a fischer-tropsch synthesis catalyst
CA3094171A1 (en) * 2018-03-22 2019-09-26 Bp P.L.C. A supported cobalt-containing fischer-tropsch catalyst, process for preparing the same and uses thereof
KR102248115B1 (ko) * 2019-07-01 2021-05-03 한국화학연구원 피셔―트롭쉬 합성반응용 촉매 및 그 제조방법
CN112642429B (zh) * 2019-10-12 2023-06-06 中国石油化工股份有限公司 浸渍液及其制备方法和催化剂及其制备方法和应用以及废气的处理方法
CN117427673A (zh) * 2023-10-24 2024-01-23 安徽大学 一种高导热高活性CoO/MXene催化剂及其制备方法和应用

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4794099A (en) * 1987-01-28 1988-12-27 Exxon Research And Engineering Company SiO2 -promoted cobalt catalyst on a support of TiO2 for converting synthesis gas to heavy hydrocarbons
GB8925979D0 (en) * 1989-11-16 1990-01-04 Shell Int Research Process for the preparation of extrudates,extrudates,and use of the extrudates
AU735070B2 (en) 1997-12-30 2001-06-28 Shell Internationale Research Maatschappij B.V. Cobalt based fisher-tropsch catalyst
US6262132B1 (en) * 1999-05-21 2001-07-17 Energy International Corporation Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems
BR0111556B1 (pt) * 2000-06-12 2012-08-21 processos para preparação de um precursor de catalisador à base de cobalto, e, para preparação de um catalisador de fischer-tropsch à base de cobalto.
MY122994A (en) * 2000-07-03 2006-05-31 Shell Int Research Catalyst and process fo rthe preparation of hydrocarbons
GB0222240D0 (en) * 2002-09-25 2002-10-30 Ici Plc Cobalt catalysts
WO2005030680A1 (en) * 2003-09-30 2005-04-07 Shell Internationale Research Maatschappij B.V. Titania supports for fisher-tropsch catalysts
US7084180B2 (en) * 2004-01-28 2006-08-01 Velocys, Inc. Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor
WO2008003731A1 (en) 2006-07-07 2008-01-10 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
JP5522724B2 (ja) * 2006-12-08 2014-06-18 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 精製合成ガス流の製造方法
EP1935964A1 (en) * 2006-12-19 2008-06-25 Bp Exploration Operating Company Limited Fischer-Tropsch catalyst
AU2008206983B2 (en) * 2007-01-18 2010-06-24 Shell Internationale Research Maatschappij B.V. Catalyst, catalyst precursor, catalyst carrier, preparation and use of thereof in Fischer-Tropsch synthesis
WO2008090105A2 (en) * 2007-01-23 2008-07-31 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
CN102076413B (zh) 2008-06-24 2013-06-19 克斯莫石油株式会社 费歇尔-托罗普希合成用催化剂以及烃类的制备方法
JP5128526B2 (ja) 2009-03-23 2013-01-23 コスモ石油株式会社 フィッシャー・トロプシュ合成用触媒及び炭化水素類の製造方法
GB0819847D0 (en) * 2008-10-30 2008-12-03 Johnson Matthey Plc Cobalt catalysts
US20100160464A1 (en) 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
JP5442776B2 (ja) * 2009-02-26 2014-03-12 サソール テクノロジー(プロプライエタリー)リミテッド フィッシャー・トロプシュ触媒の調製およびその使用
RU2414296C1 (ru) * 2009-10-29 2011-03-20 Инфра Текнолоджиз Лтд. Катализатор для синтеза углеводородов из со и h2 и способ его получения
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst
EP2525908A2 (en) * 2010-01-19 2012-11-28 Rentech, Inc. Protected fischer-tropsch catalyst and method of providing same to a fischer-tropsch process
EP2531294A4 (en) * 2010-02-01 2017-03-15 Conocophillips Company Water-forming hydrogenation reactions utilizing enhanced catalyst supports and methods of use
AU2011366455B2 (en) 2011-04-28 2016-07-14 Basf Nederland B.V. Catalysts
JP5961694B2 (ja) * 2011-09-21 2016-08-02 サソル テクノロジー (ピーティーワイ)リミテッド コバルト含有のフィッシャー・トロプシュ触媒を調製する方法
FR2991199B1 (fr) 2012-05-30 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur mettant en oeuvre une etape de sechage rapide et son utilisation pour la synthese fischer-tropsch
JP6007167B2 (ja) * 2013-11-18 2016-10-12 Jxエネルギー株式会社 フィッシャー・トロプシュ合成用触媒の製造方法及び炭化水素の製造方法

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