DK157727B - Polymeriserbart tandreparationsmateriale med accelereret haerdningshastighed - Google Patents
Polymeriserbart tandreparationsmateriale med accelereret haerdningshastighed Download PDFInfo
- Publication number
- DK157727B DK157727B DK189781A DK189781A DK157727B DK 157727 B DK157727 B DK 157727B DK 189781 A DK189781 A DK 189781A DK 189781 A DK189781 A DK 189781A DK 157727 B DK157727 B DK 157727B
- Authority
- DK
- Denmark
- Prior art keywords
- monomer
- material according
- reducing agent
- approx
- compound
- Prior art date
Links
- 239000005548 dental material Substances 0.000 title 1
- 239000000178 monomer Substances 0.000 claims description 55
- -1 peroxy compound Chemical class 0.000 claims description 32
- 239000003638 chemical reducing agent Substances 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 20
- 239000000945 filler Substances 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- IPCRBOOJBPETMF-UHFFFAOYSA-N N-acetylthiourea Chemical group CC(=O)NC(N)=S IPCRBOOJBPETMF-UHFFFAOYSA-N 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- MRIZMKJLUDDMHF-UHFFFAOYSA-N cumene;hydrogen peroxide Chemical compound OO.CC(C)C1=CC=CC=C1 MRIZMKJLUDDMHF-UHFFFAOYSA-N 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 230000008439 repair process Effects 0.000 claims description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N aminothiocarboxamide Natural products NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 239000002685 polymerization catalyst Substances 0.000 claims description 2
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 claims 1
- 239000012141 concentrate Substances 0.000 claims 1
- 239000006072 paste Substances 0.000 description 19
- 125000004432 carbon atom Chemical group C* 0.000 description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000007800 oxidant agent Substances 0.000 description 11
- 239000005749 Copper compound Substances 0.000 description 8
- 150000001880 copper compounds Chemical class 0.000 description 8
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- 229910001431 copper ion Inorganic materials 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 210000000214 mouth Anatomy 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229960005070 ascorbic acid Drugs 0.000 description 3
- 235000010323 ascorbic acid Nutrition 0.000 description 3
- 239000011668 ascorbic acid Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 150000003585 thioureas Chemical class 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- JAEZSIYNWDWMMN-UHFFFAOYSA-N 1,1,3-trimethylthiourea Chemical compound CNC(=S)N(C)C JAEZSIYNWDWMMN-UHFFFAOYSA-N 0.000 description 2
- NARVIWMVBMUEOG-UHFFFAOYSA-N 2-Hydroxy-propylene Natural products CC(O)=C NARVIWMVBMUEOG-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- FULZLIGZKMKICU-UHFFFAOYSA-N N-phenylthiourea Chemical compound NC(=S)NC1=CC=CC=C1 FULZLIGZKMKICU-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- UCGFRIAOVLXVKL-UHFFFAOYSA-N benzylthiourea Chemical compound NC(=S)NCC1=CC=CC=C1 UCGFRIAOVLXVKL-UHFFFAOYSA-N 0.000 description 2
- GMEGXJPUFRVCPX-UHFFFAOYSA-N butylthiourea Chemical compound CCCCNC(N)=S GMEGXJPUFRVCPX-UHFFFAOYSA-N 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- POXAIQSXNOEQGM-UHFFFAOYSA-N propan-2-ylthiourea Chemical compound CC(C)NC(N)=S POXAIQSXNOEQGM-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- GSRPPAKIJBKMEY-UHFFFAOYSA-N (2-methoxyphenyl)methylthiourea Chemical compound COC1=CC=CC=C1CNC(N)=S GSRPPAKIJBKMEY-UHFFFAOYSA-N 0.000 description 1
- HXCHZMHFZXNFIX-UHFFFAOYSA-N (2-methoxyphenyl)thiourea Chemical compound COC1=CC=CC=C1NC(N)=S HXCHZMHFZXNFIX-UHFFFAOYSA-N 0.000 description 1
- BHJYKFUCQNISJA-UHFFFAOYSA-N (3-hydroxyphenyl)thiourea Chemical compound NC(=S)NC1=CC=CC(O)=C1 BHJYKFUCQNISJA-UHFFFAOYSA-N 0.000 description 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- OLTJYOMEFRRCKA-UHFFFAOYSA-N 1,1,3-triphenylthiourea Chemical compound C=1C=CC=CC=1N(C=1C=CC=CC=1)C(=S)NC1=CC=CC=C1 OLTJYOMEFRRCKA-UHFFFAOYSA-N 0.000 description 1
- OVRQXQSDQWOJIL-UHFFFAOYSA-N 1,1-dibutylthiourea Chemical compound CCCCN(C(N)=S)CCCC OVRQXQSDQWOJIL-UHFFFAOYSA-N 0.000 description 1
- DZZWKUMHMSNBSG-UHFFFAOYSA-N 1,3-bis(prop-2-enyl)thiourea Chemical compound C=CCNC(=S)NCC=C DZZWKUMHMSNBSG-UHFFFAOYSA-N 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- UKOJOHPYEVWPNN-UHFFFAOYSA-N 1-(4-chlorophenyl)-3-methylthiourea Chemical compound CNC(=S)NC1=CC=C(Cl)C=C1 UKOJOHPYEVWPNN-UHFFFAOYSA-N 0.000 description 1
- WGTSYSMCCBVJNF-UHFFFAOYSA-N 1-(4-ethenylphenyl)-3-methylthiourea Chemical compound CNC(=S)NC1=CC=C(C=C)C=C1 WGTSYSMCCBVJNF-UHFFFAOYSA-N 0.000 description 1
- WNATTZPFYNVZQG-UHFFFAOYSA-N 1-methyl-1-pentylthiourea Chemical compound CCCCCN(C)C(N)=S WNATTZPFYNVZQG-UHFFFAOYSA-N 0.000 description 1
- JCJDOHYMJAOYPV-UHFFFAOYSA-N 1-methyl-3-pentylthiourea Chemical compound CCCCCNC(=S)NC JCJDOHYMJAOYPV-UHFFFAOYSA-N 0.000 description 1
- MTEZSDOQASFMDI-UHFFFAOYSA-N 1-trimethoxysilylpropan-1-ol Chemical compound CCC(O)[Si](OC)(OC)OC MTEZSDOQASFMDI-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- ONIKNECPXCLUHT-UHFFFAOYSA-N 2-chlorobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1Cl ONIKNECPXCLUHT-UHFFFAOYSA-N 0.000 description 1
- XZETWBTXPADGDR-UHFFFAOYSA-N 3-methyl-1,1-diphenylthiourea Chemical compound C=1C=CC=CC=1N(C(=S)NC)C1=CC=CC=C1 XZETWBTXPADGDR-UHFFFAOYSA-N 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- VKOUCJUTMGHNOR-UHFFFAOYSA-N Diphenolic acid Chemical compound C=1C=C(O)C=CC=1C(CCC(O)=O)(C)C1=CC=C(O)C=C1 VKOUCJUTMGHNOR-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical group CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 description 1
- KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 description 1
- KQJQICVXLJTWQD-UHFFFAOYSA-N N-Methylthiourea Chemical compound CNC(N)=S KQJQICVXLJTWQD-UHFFFAOYSA-N 0.000 description 1
- GMEHFXXZSWDEDB-UHFFFAOYSA-N N-ethylthiourea Chemical compound CCNC(N)=S GMEHFXXZSWDEDB-UHFFFAOYSA-N 0.000 description 1
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 1
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 229960001748 allylthiourea Drugs 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000002668 chloroacetyl group Chemical group ClCC(=O)* 0.000 description 1
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000004956 cyclohexylene group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- CGMRCMMOCQYHAD-UHFFFAOYSA-J dicalcium hydroxide phosphate Chemical compound [OH-].[Ca++].[Ca++].[O-]P([O-])([O-])=O CGMRCMMOCQYHAD-UHFFFAOYSA-J 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000004680 hydrogen peroxides Chemical class 0.000 description 1
- 125000001867 hydroperoxy group Chemical group [*]OO[H] 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- VAVFWTOVXLDJFG-UHFFFAOYSA-N n-(butylcarbamothioyl)butanamide Chemical compound CCCCNC(=S)NC(=O)CCC VAVFWTOVXLDJFG-UHFFFAOYSA-N 0.000 description 1
- DBOBDMZHSHKLSJ-UHFFFAOYSA-N n-(phenylcarbamothioyl)acetamide Chemical compound CC(=O)NC(=S)NC1=CC=CC=C1 DBOBDMZHSHKLSJ-UHFFFAOYSA-N 0.000 description 1
- DQMWMUMCNOJLSI-UHFFFAOYSA-N n-carbamothioylbenzamide Chemical compound NC(=S)NC(=O)C1=CC=CC=C1 DQMWMUMCNOJLSI-UHFFFAOYSA-N 0.000 description 1
- DXZVIWFRNGADRH-UHFFFAOYSA-N n-carbamothioyloctanamide Chemical compound CCCCCCCC(=O)NC(N)=S DXZVIWFRNGADRH-UHFFFAOYSA-N 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QAKUNEDFMJPMGO-UHFFFAOYSA-N octylthiourea Chemical compound CCCCCCCCNC(N)=S QAKUNEDFMJPMGO-UHFFFAOYSA-N 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- QKMGIVQNFXRKEE-UHFFFAOYSA-L sodium;copper(1+);3-[(n-prop-2-enyl-c-sulfidocarbonimidoyl)amino]benzoate Chemical compound [Na+].[Cu+].[O-]C(=O)C1=CC=CC(NC([S-])=NCC=C)=C1 QKMGIVQNFXRKEE-UHFFFAOYSA-L 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical class CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000005628 tolylene group Chemical group 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 239000005052 trichlorosilane Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/40—Redox systems
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epidemiology (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14519980A | 1980-04-29 | 1980-04-29 | |
| US14519980 | 1980-04-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DK189781A DK189781A (da) | 1981-10-30 |
| DK157727B true DK157727B (da) | 1990-02-12 |
Family
ID=22512027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK189781A DK157727B (da) | 1980-04-29 | 1981-04-29 | Polymeriserbart tandreparationsmateriale med accelereret haerdningshastighed |
Country Status (20)
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3928987A1 (de) * | 1989-09-01 | 1991-03-28 | Siegfried Reiss | Verfahren und formmasse zur herstellung von formlingen fuer den dentalbereich |
| DE4339399A1 (de) * | 1993-11-18 | 1995-05-24 | Thera Ges Fuer Patente | Durch Polymerisation einer ethylenisch polymerisierbaren Masse in Formen hergestellte Formkörper (Inserts) |
| US20070100019A1 (en) * | 2005-08-02 | 2007-05-03 | Fuming Sun | Catalyst system for dental compositions |
| DE102005039590B4 (de) * | 2005-08-19 | 2008-05-21 | Heraeus Kulzer Gmbh | Polymerisierbare Dentalzusammensetzung mit einem 2-Komponenten-Initiatorsystem |
| EP1849449A1 (en) * | 2006-04-26 | 2007-10-31 | 3M Innovative Properties Company | Filler containing composition and process for production and use thereof |
| WO2008134024A2 (en) * | 2007-04-25 | 2008-11-06 | Dentsply International Inc. | Self-adhesive dental cement |
| JP2009292761A (ja) * | 2008-06-04 | 2009-12-17 | Kuraray Medical Inc | 歯科用硬化性組成物 |
| JP5388482B2 (ja) * | 2008-06-04 | 2014-01-15 | クラレノリタケデンタル株式会社 | 歯科用硬化性組成物 |
| CN102702405B (zh) * | 2012-07-05 | 2014-04-09 | 东营市诺尔化工有限责任公司 | 一种超低残留吸水树脂的制备方法 |
| JP6112887B2 (ja) * | 2013-02-05 | 2017-04-12 | 株式会社トクヤマデンタル | 歯科用硬化性組成物 |
| JP6086797B2 (ja) * | 2013-04-25 | 2017-03-01 | クラレノリタケデンタル株式会社 | 歯科用重合性組成物 |
| JP6857600B2 (ja) | 2014-07-10 | 2021-04-14 | スリーエム イノベイティブ プロパティズ カンパニー | 二成分自己接着性歯科用組成物、その製造方法、及び使用 |
| EP3256094A4 (en) * | 2015-02-09 | 2018-10-10 | Zest IP Holdings, LLC | Dental compositions and methods of use |
| AU2018394851B2 (en) * | 2017-12-26 | 2021-03-11 | Tokuyama Dental Corporation | Chemical polymerization initiator, adhesive composition, adhesive composition kit, dental material, dental material kit, and method of storing adhesive composition |
| EP3808324A1 (en) * | 2019-09-26 | 2021-04-21 | Shofu Inc. | Curable composition containing transition metal adsorbent |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB714868A (en) * | 1951-12-24 | 1954-09-01 | Dental Fillings Ltd | Improvements in or relating to polymerisation products |
| GB1177879A (en) * | 1967-09-04 | 1970-01-14 | Sumitomo Chemical Co | Catalyst System and process for the Polymerisation of Vinyl Compounds |
| JPS4842467B1 (enrdf_load_stackoverflow) * | 1970-12-04 | 1973-12-12 | ||
| DE2420351C3 (de) * | 1973-04-26 | 1987-07-09 | National Patent Development Corp., New York, N.Y. | Verwendung einer Zusammensetzung als Wurzelkanalfüllkomponente |
| JPS587646B2 (ja) * | 1974-05-31 | 1983-02-10 | 東亞合成株式会社 | ニエキセイコウカセイソセイブツ |
| JPS516224A (enrdf_load_stackoverflow) * | 1974-07-05 | 1976-01-19 | Johnson & Johnson | |
| US3991008A (en) * | 1974-08-12 | 1976-11-09 | The Kendall Company | Dental compositions having improved color stability |
| JPS51131197A (en) * | 1975-05-08 | 1976-11-15 | Sankin Ind Co | Uniiliquid type dental cement |
-
1981
- 1981-04-16 ZA ZA00812567A patent/ZA812567B/xx unknown
- 1981-04-16 NZ NZ196864A patent/NZ196864A/en unknown
- 1981-04-23 DE DE19813116132 patent/DE3116132A1/de not_active Withdrawn
- 1981-04-27 SE SE8102634A patent/SE450547B/sv not_active IP Right Cessation
- 1981-04-27 AT AT0187781A patent/AT376125B/de not_active IP Right Cessation
- 1981-04-28 BR BR8102607A patent/BR8102607A/pt unknown
- 1981-04-28 AU AU69911/81A patent/AU554532B2/en not_active Ceased
- 1981-04-28 BE BE0/204628A patent/BE888599A/fr not_active IP Right Cessation
- 1981-04-28 FR FR8108413A patent/FR2481114A1/fr active Granted
- 1981-04-28 CH CH2760/81A patent/CH649465A5/de not_active IP Right Cessation
- 1981-04-28 ES ES501695A patent/ES501695A0/es active Granted
- 1981-04-28 NO NO811448A patent/NO158991C/no unknown
- 1981-04-28 CA CA000376461A patent/CA1223696A/en not_active Expired
- 1981-04-28 PH PH25567A patent/PH17044A/en unknown
- 1981-04-29 DK DK189781A patent/DK157727B/da not_active Application Discontinuation
- 1981-04-29 IE IE958/81A patent/IE51152B1/en unknown
- 1981-04-29 NL NL8102128A patent/NL8102128A/nl not_active Application Discontinuation
- 1981-04-29 GB GB8113265A patent/GB2075035B/en not_active Expired
- 1981-04-29 MX MX187116A patent/MX156002A/es unknown
- 1981-04-30 JP JP6615881A patent/JPS56169609A/ja active Pending
-
1983
- 1983-08-11 GB GB838321611A patent/GB8321611D0/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| NZ196864A (en) | 1984-04-27 |
| FR2481114B1 (enrdf_load_stackoverflow) | 1984-11-30 |
| AU6991181A (en) | 1981-11-05 |
| ATA187781A (de) | 1984-03-15 |
| ZA812567B (en) | 1982-11-24 |
| IE810958L (en) | 1981-10-29 |
| IE51152B1 (en) | 1986-10-15 |
| JPS56169609A (en) | 1981-12-26 |
| SE450547B (sv) | 1987-07-06 |
| PH17044A (en) | 1984-05-17 |
| AT376125B (de) | 1984-10-10 |
| MX156002A (es) | 1988-06-14 |
| SE8102634L (sv) | 1981-10-30 |
| NO158991C (no) | 1988-11-23 |
| GB2075035A (en) | 1981-11-11 |
| NO811448L (no) | 1981-10-30 |
| BE888599A (fr) | 1981-08-17 |
| DK189781A (da) | 1981-10-30 |
| AU554532B2 (en) | 1986-08-28 |
| GB2075035B (en) | 1984-07-25 |
| CH649465A5 (de) | 1985-05-31 |
| GB8321611D0 (en) | 1983-09-14 |
| ES8206560A1 (es) | 1982-08-16 |
| NO158991B (no) | 1988-08-15 |
| NL8102128A (nl) | 1981-11-16 |
| FR2481114A1 (fr) | 1981-10-30 |
| ES501695A0 (es) | 1982-08-16 |
| CA1223696A (en) | 1987-06-30 |
| BR8102607A (pt) | 1982-01-19 |
| DE3116132A1 (de) | 1982-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DK157727B (da) | Polymeriserbart tandreparationsmateriale med accelereret haerdningshastighed | |
| DE2635595C2 (de) | Polymerisierbare Zahnfüllmasse | |
| Moszner et al. | Recent developments of new components for dental adhesives and composites | |
| US7632877B2 (en) | Dental resins, dental composite materials, and method of manufacture thereof | |
| JP4851454B2 (ja) | ナノジルコニアフィラーを含有する歯科用組成物 | |
| EP1587489B1 (en) | Dental whitening compositions and methods | |
| JP5202790B2 (ja) | アミド官能性ポリマー、組成物および方法 | |
| EP1393705B9 (en) | Dental restorative compounds | |
| AU6690398A (en) | Ternary photoinitiator system for curing of epoxy/polyol resin compositions | |
| JPH0667816B2 (ja) | 歯科用修復材 | |
| JPS59137404A (ja) | 歯科用接着剤 | |
| DE69012702T2 (de) | Dentalzusammensetzung. | |
| IE910516A1 (en) | Swellable bead polymers containing fillers | |
| US7470728B2 (en) | Dental glazes and method of manufacture and use thereof | |
| JP2000500486A (ja) | フッ化物を遊離する組成物 | |
| US7589132B2 (en) | Dental resins, dental composite materials, and method of manufacture thereof | |
| JPS6210005A (ja) | 抗歯髄等組織刺激性及び抗為害性組成物 | |
| WO2021010154A1 (ja) | 抗菌ポリマー粒子、組成物及び物品 | |
| JPH02212455A (ja) | イタコン酸モノエステル化合物及びそれらを含有してなる接着剤 | |
| JPS63316709A (ja) | 光重合性歯科用組成物 | |
| JPS6032801A (ja) | 光重合可能な組成物、その製法及び硬化製品の製法 | |
| EP3558212A1 (en) | Direct dental filling composition | |
| EP3903759A1 (en) | Dental composition having characteristic in silane coupling material compounding index | |
| EP3675800B1 (en) | Photoinitiator modified polyacidic polymer | |
| JP2022529600A (ja) | 歯科用組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PHB | Application deemed withdrawn due to non-payment or other reasons |