DE69517109T2 - Emulsionen mit ultradünnen tafelförmigen Körnern und neuer Behandlung von Dotiermitteln - Google Patents
Emulsionen mit ultradünnen tafelförmigen Körnern und neuer Behandlung von DotiermittelnInfo
- Publication number
- DE69517109T2 DE69517109T2 DE1995617109 DE69517109T DE69517109T2 DE 69517109 T2 DE69517109 T2 DE 69517109T2 DE 1995617109 DE1995617109 DE 1995617109 DE 69517109 T DE69517109 T DE 69517109T DE 69517109 T2 DE69517109 T2 DE 69517109T2
- Authority
- DE
- Germany
- Prior art keywords
- emulsion
- silver
- tabular grains
- emulsions
- grains
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000839 emulsion Substances 0.000 title claims description 492
- 239000002019 doping agent Substances 0.000 title claims description 81
- 229910052709 silver Inorganic materials 0.000 claims description 202
- 239000004332 silver Substances 0.000 claims description 202
- 206010070834 Sensitisation Diseases 0.000 claims description 142
- 230000008313 sensitization Effects 0.000 claims description 141
- -1 silver halide Chemical class 0.000 claims description 133
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 95
- 230000003595 spectral effect Effects 0.000 claims description 47
- 239000003446 ligand Substances 0.000 claims description 40
- 238000001556 precipitation Methods 0.000 claims description 34
- 230000005540 biological transmission Effects 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 20
- 239000013078 crystal Substances 0.000 claims description 14
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- 230000005855 radiation Effects 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- 150000002504 iridium compounds Chemical class 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims 3
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 241
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 132
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 123
- 239000000975 dye Substances 0.000 description 112
- 238000000407 epitaxy Methods 0.000 description 84
- 238000007792 addition Methods 0.000 description 80
- 108010010803 Gelatin Proteins 0.000 description 66
- 229920000159 gelatin Polymers 0.000 description 66
- 239000008273 gelatin Substances 0.000 description 66
- 235000019322 gelatine Nutrition 0.000 description 66
- 235000011852 gelatine desserts Nutrition 0.000 description 66
- 238000000034 method Methods 0.000 description 52
- 230000035945 sensitivity Effects 0.000 description 47
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 46
- 239000000243 solution Substances 0.000 description 44
- 229910021612 Silver iodide Inorganic materials 0.000 description 42
- 230000012010 growth Effects 0.000 description 42
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 42
- 238000000151 deposition Methods 0.000 description 39
- 230000008021 deposition Effects 0.000 description 38
- 230000006911 nucleation Effects 0.000 description 38
- 238000010899 nucleation Methods 0.000 description 38
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 36
- 229910052717 sulfur Inorganic materials 0.000 description 36
- 239000011593 sulfur Substances 0.000 description 36
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 32
- 229910052737 gold Inorganic materials 0.000 description 32
- 239000010931 gold Substances 0.000 description 32
- 229910052741 iridium Inorganic materials 0.000 description 32
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 32
- 150000004820 halides Chemical class 0.000 description 29
- 239000000203 mixture Substances 0.000 description 26
- 239000011780 sodium chloride Substances 0.000 description 23
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 22
- 229910021607 Silver chloride Inorganic materials 0.000 description 22
- 229930182817 methionine Natural products 0.000 description 22
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 22
- 230000003698 anagen phase Effects 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 18
- 210000000988 bone and bone Anatomy 0.000 description 17
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 16
- 235000011941 Tilia x europaea Nutrition 0.000 description 16
- 239000004571 lime Substances 0.000 description 16
- 230000009102 absorption Effects 0.000 description 15
- 238000010521 absorption reaction Methods 0.000 description 15
- 238000010348 incorporation Methods 0.000 description 15
- 230000001235 sensitizing effect Effects 0.000 description 15
- 230000008901 benefit Effects 0.000 description 14
- 230000006872 improvement Effects 0.000 description 13
- 239000000725 suspension Substances 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 230000006870 function Effects 0.000 description 12
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 12
- 238000000576 coating method Methods 0.000 description 11
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 11
- 229910020252 KAuCl4 Inorganic materials 0.000 description 10
- 238000011160 research Methods 0.000 description 10
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 10
- 159000000000 sodium salts Chemical class 0.000 description 10
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 10
- 235000019345 sodium thiosulphate Nutrition 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 10
- 239000002518 antifoaming agent Substances 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- 238000003860 storage Methods 0.000 description 9
- 238000002834 transmittance Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000010893 electron trap Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- IJHIIHORMWQZRQ-UHFFFAOYSA-N 1-(ethenylsulfonylmethylsulfonyl)ethene Chemical compound C=CS(=O)(=O)CS(=O)(=O)C=C IJHIIHORMWQZRQ-UHFFFAOYSA-N 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 230000008859 change Effects 0.000 description 7
- 239000004848 polyfunctional curative Substances 0.000 description 7
- 238000004626 scanning electron microscopy Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229920002301 cellulose acetate Polymers 0.000 description 6
- 230000003247 decreasing effect Effects 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- SVTFGFLBXLUFME-UHFFFAOYSA-N 2,5-dihydroxy-4-octadecan-2-ylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCCCCCC(C)C1=CC(O)=C(S(O)(=O)=O)C=C1O SVTFGFLBXLUFME-UHFFFAOYSA-N 0.000 description 5
- INVVMIXYILXINW-UHFFFAOYSA-N 5-methyl-1h-[1,2,4]triazolo[1,5-a]pyrimidin-7-one Chemical compound CC1=CC(=O)N2NC=NC2=N1 INVVMIXYILXINW-UHFFFAOYSA-N 0.000 description 5
- 229910019093 NaOCl Inorganic materials 0.000 description 5
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229910052798 chalcogen Inorganic materials 0.000 description 5
- 150000001787 chalcogens Chemical class 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 5
- 206010063836 Atrioventricular septal defect Diseases 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 238000001211 electron capture detection Methods 0.000 description 4
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- 230000002349 favourable effect Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 4
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 4
- 229910052939 potassium sulfate Inorganic materials 0.000 description 4
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000008719 thickening Effects 0.000 description 4
- 238000001429 visible spectrum Methods 0.000 description 4
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 3
- SGYIRNXZLWJMCR-UHFFFAOYSA-M 3-methyl-1,3-benzothiazol-3-ium;iodide Chemical compound [I-].C1=CC=C2[N+](C)=CSC2=C1 SGYIRNXZLWJMCR-UHFFFAOYSA-M 0.000 description 3
- 101100291946 Rattus norvegicus Pmpcb gene Proteins 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- 229940045105 silver iodide Drugs 0.000 description 3
- AGJZCWVTGOVGBS-UHFFFAOYSA-N 1,1'-diethyl-2,2'-cyanine Chemical compound C1=CC2=CC=CC=C2N(CC)\C1=C\C1=CC=C(C=CC=C2)C2=[N+]1CC AGJZCWVTGOVGBS-UHFFFAOYSA-N 0.000 description 2
- IHWDSEPNZDYMNF-UHFFFAOYSA-N 1H-indol-2-amine Chemical compound C1=CC=C2NC(N)=CC2=C1 IHWDSEPNZDYMNF-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
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- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
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- 230000013742 energy transducer activity Effects 0.000 description 1
- ZBKIUFWVEIBQRT-UHFFFAOYSA-N gold(1+) Chemical class [Au+] ZBKIUFWVEIBQRT-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000000411 inducer Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- MILUBEOXRNEUHS-UHFFFAOYSA-N iridium(3+) Chemical compound [Ir+3] MILUBEOXRNEUHS-UHFFFAOYSA-N 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- PANJMBIFGCKWBY-UHFFFAOYSA-N iron tricyanide Chemical compound N#C[Fe](C#N)C#N PANJMBIFGCKWBY-UHFFFAOYSA-N 0.000 description 1
- 125000001518 isoselenocyanato group Chemical group *N=C=[Se] 0.000 description 1
- 125000000239 isotellurocyanato group Chemical group *N=C=[Te] 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- SCWKACOBHZIKDI-UHFFFAOYSA-N n-[3-(5-sulfanylidene-2h-tetrazol-1-yl)phenyl]acetamide Chemical compound CC(=O)NC1=CC=CC(N2C(N=NN2)=S)=C1 SCWKACOBHZIKDI-UHFFFAOYSA-N 0.000 description 1
- XDZOVXPAGVIXBS-UHFFFAOYSA-N n-[4-[(4-acetamidophenyl)disulfanyl]phenyl]acetamide Chemical compound C1=CC(NC(=O)C)=CC=C1SSC1=CC=C(NC(C)=O)C=C1 XDZOVXPAGVIXBS-UHFFFAOYSA-N 0.000 description 1
- KBDYPDHUODKDRK-UHFFFAOYSA-N n-acetyl-n-phenylacetamide Chemical compound CC(=O)N(C(C)=O)C1=CC=CC=C1 KBDYPDHUODKDRK-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000035040 seed growth Effects 0.000 description 1
- CRDYSYOERSZTHZ-UHFFFAOYSA-M selenocyanate Chemical compound [Se-]C#N CRDYSYOERSZTHZ-UHFFFAOYSA-M 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 101150018444 sub2 gene Proteins 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- GWIKYPMLNBTJHR-UHFFFAOYSA-M thiosulfonate group Chemical group S(=S)(=O)[O-] GWIKYPMLNBTJHR-UHFFFAOYSA-M 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/46—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein having more than one photosensitive layer
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/297,195 US5576168A (en) | 1994-08-26 | 1994-08-26 | Ultrathin tabular grain emulsions with sensitization enhancements |
US08/297,430 US5503971A (en) | 1994-08-26 | 1994-08-26 | Ultrathin tabular grain emulsions containing speed-granularity enhancements |
US08/296,562 US5503970A (en) | 1994-08-26 | 1994-08-26 | Ultrathin tabular grain emulsions with novel dopant management |
US08/359,251 US5494789A (en) | 1994-08-26 | 1994-12-19 | Epitaxially sensitized ultrathin tabular grain emulsions |
US08/441,489 US5614358A (en) | 1995-05-15 | 1995-05-15 | Ultrathin tabular grain emulsions with reduced reciprocity failure |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69517109D1 DE69517109D1 (de) | 2000-06-29 |
DE69517109T2 true DE69517109T2 (de) | 2001-02-01 |
Family
ID=27540811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1995617109 Expired - Fee Related DE69517109T2 (de) | 1994-08-26 | 1995-08-21 | Emulsionen mit ultradünnen tafelförmigen Körnern und neuer Behandlung von Dotiermitteln |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0699950B1 (ja) |
JP (1) | JPH08171163A (ja) |
DE (1) | DE69517109T2 (ja) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4053708B2 (ja) | 2000-02-23 | 2008-02-27 | 富士フイルム株式会社 | ハロゲン化銀写真乳剤及びこれを用いたハロゲン化銀写真感光材料 |
JP4053746B2 (ja) | 2000-09-19 | 2008-02-27 | 富士フイルム株式会社 | ハロゲン化銀写真乳剤及びこれを用いたハロゲン化銀写真感光材料 |
JP4053742B2 (ja) | 2000-09-19 | 2008-02-27 | 富士フイルム株式会社 | ハロゲン化銀写真乳剤 |
DE60143154D1 (de) | 2001-04-17 | 2010-11-11 | Fujifilm Corp | Photographisches Silberhalogenidmaterial enthaltend einen Methinfarbstoff |
US8370711B2 (en) | 2008-06-23 | 2013-02-05 | Ramot At Tel Aviv University Ltd. | Interruption criteria for block decoding |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL62395C (ja) | 1939-02-02 | |||
US2448534A (en) | 1946-07-06 | 1948-09-07 | Eastman Kodak Co | Sensitized photographic cellulose ester silver halide emulsion |
GB1059782A (en) | 1962-09-11 | 1967-02-22 | Eastman Kodak Co | Photographic silver halide emulsions and sensitive materials prepared therefrom |
US3320069A (en) | 1966-03-18 | 1967-05-16 | Eastman Kodak Co | Sulfur group sensitized emulsions |
US3574628A (en) | 1968-01-29 | 1971-04-13 | Eastman Kodak Co | Novel monodispersed silver halide emulsions and processes for preparing same |
US3737313A (en) | 1971-06-17 | 1973-06-05 | Eastman Kodak Co | Paper radiographic element containing silver halide grains rhodium salt sensitized,thioether ripened and polyvalent metal ion stabilized |
JPS5232569B2 (ja) | 1972-08-31 | 1977-08-23 | ||
US4435501A (en) | 1981-11-12 | 1984-03-06 | Eastman Kodak Company | Controlled site epitaxial sensitization |
US4433048A (en) | 1981-11-12 | 1984-02-21 | Eastman Kodak Company | Radiation-sensitive silver bromoiodide emulsions, photographic elements, and processes for their use |
US4439520A (en) | 1981-11-12 | 1984-03-27 | Eastman Kodak Company | Sensitized high aspect ratio silver halide emulsions and photographic elements |
US4672027A (en) | 1985-10-23 | 1987-06-09 | Eastman Kodak Company | Multicolor photographic element with a minus blue recording tabular grain emulsion layer overlying a blue recording emulsion layer |
CA1284050C (en) | 1985-12-19 | 1991-05-14 | Joe E. Maskasky | Process for precipitating a tabular grain emulsion in the presence of a gelatino-peptizer and an emulsion produced thereby |
GB8624704D0 (en) | 1986-10-15 | 1986-11-19 | Minnesota Mining & Mfg | High contrast scanner photographic elements |
US4814264A (en) * | 1986-12-17 | 1989-03-21 | Fuji Photo Film Co., Ltd. | Silver halide photographic material and method for preparation thereof |
US4810626A (en) | 1987-02-25 | 1989-03-07 | Eastman Kodak Company | Silver halide photosensitive materials containing thiourea and analogue compounds |
US4749646A (en) | 1987-03-23 | 1988-06-07 | Eastman Kodak Company | Silver halide photosensitive materials containing thiourea and analogue derivatives |
US4933272A (en) | 1988-04-08 | 1990-06-12 | Eastman Kodak Company | Photographic emulsions containing internally modified silver halide grains |
US4937180A (en) | 1988-04-08 | 1990-06-26 | Eastman Kodak Company | Photographic emulsions containing internally modified silver halide grains |
JPH0743508B2 (ja) | 1988-05-18 | 1995-05-15 | 富士写真フイルム株式会社 | ハロゲン化銀写真用乳剤 |
EP0362699A3 (en) | 1988-10-03 | 1991-03-13 | Eastman Kodak Company | Reduced dispersity high aspect ratio tabular grain emulsions |
JPH07111554B2 (ja) | 1988-11-04 | 1995-11-29 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料 |
US4902611A (en) | 1989-01-06 | 1990-02-20 | Leubner Ingo H | Preparation of silver halide emulsions containing iridium |
US4942120A (en) | 1989-04-28 | 1990-07-17 | Eastman Kodak Company | Modified peptizer twinned grain silver halide emulsions and processes for their preparation |
GB8916042D0 (en) | 1989-07-13 | 1989-08-31 | Kodak Ltd | Process of preparing a tabular grain silver bromoiodide emulsion and emulsions produced thereby |
GB8916041D0 (en) | 1989-07-13 | 1989-08-31 | Kodak Ltd | Process of preparing a tubular grain silver bromoiodide emulsion and emulsions produced thereby |
US5037732A (en) | 1989-08-28 | 1991-08-06 | Eastman Kodak Company | Photographic emulsions containing internally modified silver halide grains |
US4981781A (en) | 1989-08-28 | 1991-01-01 | Eastman Kodak Company | Photographic emulsions containing internally modified silver halide grains |
JP2559281B2 (ja) * | 1989-12-18 | 1996-12-04 | 富士写真フイルム株式会社 | ハロゲン化銀写真乳剤およびそれを用いた感光材料 |
JPH03189641A (ja) | 1989-12-19 | 1991-08-19 | Fuji Photo Film Co Ltd | ハロゲン化銀写真乳剤及びハロゲン化銀写真感光材料 |
US5229263A (en) | 1990-05-15 | 1993-07-20 | Fuji Photo Film Co., Ltd. | Silver halide photographic material and process for the development thereof |
US5049485A (en) | 1990-11-16 | 1991-09-17 | Eastman Kodak Company | Photographic silver halide material comprising gold compound |
JPH04318544A (ja) * | 1991-01-31 | 1992-11-10 | Eastman Kodak Co | 溶解物理現像包含処理用ハロゲン化銀乳剤 |
US5250403A (en) | 1991-04-03 | 1993-10-05 | Eastman Kodak Company | Photographic elements including highly uniform silver bromoiodide tabular grain emulsions |
CA2067559A1 (en) * | 1991-05-14 | 1992-11-15 | Ramesh Jagannathan | High edge cubicity tabular grain emulsions |
US5360712A (en) | 1993-07-13 | 1994-11-01 | Eastman Kodak Company | Internally doped silver halide emulsions and processes for their preparation |
US5372927A (en) | 1993-10-21 | 1994-12-13 | Eastman Kodak Company | Process for the low pag preparation of high aspect ratio tabular grain emulsions with reduced grain thicknesses |
-
1995
- 1995-08-21 DE DE1995617109 patent/DE69517109T2/de not_active Expired - Fee Related
- 1995-08-21 EP EP19950420240 patent/EP0699950B1/en not_active Expired - Lifetime
- 1995-08-25 JP JP21782295A patent/JPH08171163A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
EP0699950B1 (en) | 2000-05-24 |
DE69517109D1 (de) | 2000-06-29 |
JPH08171163A (ja) | 1996-07-02 |
EP0699950A1 (en) | 1996-03-06 |
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Legal Events
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8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |