DE69412250T2 - Pyridobismidazole enthaltendes rigid-rod-Polymer - Google Patents
Pyridobismidazole enthaltendes rigid-rod-PolymerInfo
- Publication number
- DE69412250T2 DE69412250T2 DE69412250T DE69412250T DE69412250T2 DE 69412250 T2 DE69412250 T2 DE 69412250T2 DE 69412250 T DE69412250 T DE 69412250T DE 69412250 T DE69412250 T DE 69412250T DE 69412250 T2 DE69412250 T2 DE 69412250T2
- Authority
- DE
- Germany
- Prior art keywords
- acid
- polymer
- rod polymer
- article
- phenylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920003252 rigid-rod polymer Polymers 0.000 title claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 69
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 239000000835 fiber Substances 0.000 claims description 60
- OYFRNYNHAZOYNF-UHFFFAOYSA-N 2,5-dihydroxyterephthalic acid Chemical compound OC(=O)C1=CC(O)=C(C(O)=O)C=C1O OYFRNYNHAZOYNF-UHFFFAOYSA-N 0.000 claims description 28
- HOWDQPJMFFMJSR-UHFFFAOYSA-N pyridine-2,3,4,5-tetramine Chemical compound NC1=CN=C(N)C(N)=C1N HOWDQPJMFFMJSR-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 24
- -1 2,5-dihydroxy-p-phenylene Chemical group 0.000 claims description 22
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 20
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 10
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 9
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 8
- RRDBXTBGGXLZHD-UHFFFAOYSA-N benzene-1,4-dicarboperoxoic acid Chemical compound OOC(=O)C1=CC=C(C(=O)OO)C=C1 RRDBXTBGGXLZHD-UHFFFAOYSA-N 0.000 claims description 7
- 125000000732 arylene group Chemical group 0.000 claims description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 4
- 229940098779 methanesulfonic acid Drugs 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 3
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- LVPMIMZXDYBCDF-UHFFFAOYSA-N isocinchomeronic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)N=C1 LVPMIMZXDYBCDF-UHFFFAOYSA-N 0.000 claims description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 2
- CYVYLVVUKPNYKL-UHFFFAOYSA-N quinoline-2,6-dicarboxylic acid Chemical compound N1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 CYVYLVVUKPNYKL-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 235000012438 extruded product Nutrition 0.000 claims 1
- 239000011888 foil Substances 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 8
- 238000003756 stirring Methods 0.000 description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 16
- 238000009987 spinning Methods 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 239000002002 slurry Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 229910021529 ammonia Inorganic materials 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 230000015271 coagulation Effects 0.000 description 5
- 238000005345 coagulation Methods 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- JKXCZYCVHPKTPK-UHFFFAOYSA-N hydrate;trihydrochloride Chemical compound O.Cl.Cl.Cl JKXCZYCVHPKTPK-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002166 wet spinning Methods 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- QCQCHGYLTSGIGX-GHXANHINSA-N 4-[[(3ar,5ar,5br,7ar,9s,11ar,11br,13as)-5a,5b,8,8,11a-pentamethyl-3a-[(5-methylpyridine-3-carbonyl)amino]-2-oxo-1-propan-2-yl-4,5,6,7,7a,9,10,11,11b,12,13,13a-dodecahydro-3h-cyclopenta[a]chrysen-9-yl]oxy]-2,2-dimethyl-4-oxobutanoic acid Chemical compound N([C@@]12CC[C@@]3(C)[C@]4(C)CC[C@H]5C(C)(C)[C@@H](OC(=O)CC(C)(C)C(O)=O)CC[C@]5(C)[C@H]4CC[C@@H]3C1=C(C(C2)=O)C(C)C)C(=O)C1=CN=CC(C)=C1 QCQCHGYLTSGIGX-GHXANHINSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
- RVHSTXJKKZWWDQ-UHFFFAOYSA-N 1,1,1,2-tetrabromoethane Chemical compound BrCC(Br)(Br)Br RVHSTXJKKZWWDQ-UHFFFAOYSA-N 0.000 description 1
- AHUNLCWALDZRQE-UHFFFAOYSA-N 5-amino-2-azaniumyl-4-sulfanylbenzenethiolate Chemical compound NC1=CC(S)=C(N)C=C1S AHUNLCWALDZRQE-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 101100025412 Arabidopsis thaliana XI-A gene Proteins 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 238000000692 Student's t-test Methods 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 229920000561 Twaron Polymers 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- IAYUQKZZQKUOFL-UHFFFAOYSA-N pyridine-2,3,5,6-tetramine Chemical compound NC1=CC(N)=C(N)N=C1N IAYUQKZZQKUOFL-UHFFFAOYSA-N 0.000 description 1
- LMMZYESITFIBIM-UHFFFAOYSA-N pyridine-2,3,5,6-tetramine;hydrate;trihydrochloride Chemical compound O.Cl.Cl.Cl.NC1=CC(N)=C(N)N=C1N LMMZYESITFIBIM-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000001119 stannous chloride Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/18—Polybenzimidazoles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/32—Polythiazoles; Polythiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/74—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polycondensates of cyclic compounds, e.g. polyimides, polybenzimidazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Artificial Filaments (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Dental Preparations (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL9300722 | 1993-04-28 | ||
| PCT/EP1994/001302 WO1994025506A1 (en) | 1993-04-28 | 1994-04-22 | Rigid rod polymer based on pyridobisimidazole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69412250D1 DE69412250D1 (de) | 1998-09-10 |
| DE69412250T2 true DE69412250T2 (de) | 1999-02-11 |
Family
ID=19862338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69412250T Expired - Lifetime DE69412250T2 (de) | 1993-04-28 | 1994-04-22 | Pyridobismidazole enthaltendes rigid-rod-Polymer |
Country Status (14)
Families Citing this family (148)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1000360C2 (nl) * | 1995-05-15 | 1996-11-18 | Akzo Nobel Nv | Werkwijze ter bereiding van pyridine-2, 6-diamines |
| US5945537A (en) * | 1995-09-19 | 1999-08-31 | Akzo Nobel N.V. | Nitration of pyridine-2, 6-diamines |
| NL1001628C2 (nl) * | 1995-11-10 | 1997-05-13 | Akzo Nobel Nv | Werkwijze voor de tweevoudige carboxylering van dihydrische fenolen en meer in het bijzonder ter bereiding van 2,5-dihydroxytereftaalzuur. |
| EP1032729B1 (en) * | 1997-11-21 | 2005-04-13 | Magellan Systems International, LLC | Flame-retardant materials |
| DE10209419A1 (de) * | 2002-03-05 | 2003-09-25 | Celanese Ventures Gmbh | Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen |
| KR100993157B1 (ko) * | 2002-03-06 | 2010-11-09 | 바스프 푸엘 셀 게엠베하 | 감소된 메탄올 투과성을 갖는 양성자 전도성 전해질 막 및연료 전지에서의 이의 용도 |
| DE10213540A1 (de) * | 2002-03-06 | 2004-02-19 | Celanese Ventures Gmbh | Lösung aus Vinylphosphonsäure, Verfahren zur Herstellung einer Polymerelektrolytmembran aus Polyvinylphosphaonsäure und deren Anwendung in Brennstoffzellen |
| US20050118478A1 (en) * | 2002-03-06 | 2005-06-02 | Joachim Kiefer | Mixture comprising sulphonic acid containing vinyl, polymer electrolyte membrane comprising polyvinylsulphonic acid and the use thereof in fuel cells |
| EP1518282B1 (de) * | 2002-04-25 | 2010-09-08 | BASF Fuel Cell GmbH | Mehrschichtige elektrolytmembran |
| DE10220817A1 (de) * | 2002-05-10 | 2003-11-27 | Celanese Ventures Gmbh | Verfahren zur Herstellung einer gepfropften Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen |
| MXPA05000021A (es) * | 2002-06-27 | 2005-08-26 | Teijin Twaron Bv | Procedimiento para obtener una fibra o pelicula tubular sintetica organica, aromatica heterociclica, con resistencia a la tension o modulo alto. |
| DE10230477A1 (de) | 2002-07-06 | 2004-01-15 | Celanese Ventures Gmbh | Funktionalisierte Polyazole, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
| US7332530B2 (en) | 2002-08-02 | 2008-02-19 | Celanese Ventures Gmbh | Proton-conducting polymer membrane comprising a polymer with sulphonic acid groups and use thereof in fuel cells |
| DE10239701A1 (de) | 2002-08-29 | 2004-03-11 | Celanese Ventures Gmbh | Polymerfolie auf Basis von Polyazolen und deren Verwendung |
| DE10242708A1 (de) * | 2002-09-13 | 2004-05-19 | Celanese Ventures Gmbh | Protonenleitende Membranen und deren Verwendung |
| DE10246459A1 (de) * | 2002-10-04 | 2004-04-15 | Celanese Ventures Gmbh | Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen |
| DE10246373A1 (de) * | 2002-10-04 | 2004-04-15 | Celanese Ventures Gmbh | Protonenleitende Polymermembran umfassend Sulfonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen |
| WO2005005486A2 (en) | 2003-02-27 | 2005-01-20 | Fowkes Steven W | Aromatic amide polymer systems and methods for making the same |
| US7820314B2 (en) * | 2003-07-27 | 2010-10-26 | Basf Fuel Cell Research Gmbh | Proton-conducting membrane and use thereof |
| KR101147949B1 (ko) * | 2004-04-14 | 2012-07-06 | 데이진 테크노 프로덕츠 가부시키가이샤 | 강직 복소환 고분자, 그 제조법 및 섬유 |
| EP1614778A1 (en) * | 2004-07-08 | 2006-01-11 | Magellan Systems International, LLC | Process for obtaining a synthetic organic aromatic heterocyclic rod fiber or film with high tensile strength and/or modulus |
| JP4583874B2 (ja) | 2004-10-20 | 2010-11-17 | 三星エスディアイ株式会社 | プロトン伝導性固体高分子電解質膜および燃料電池 |
| US7288493B2 (en) * | 2005-01-18 | 2007-10-30 | Honeywell International Inc. | Body armor with improved knife-stab resistance formed from flexible composites |
| WO2006098495A1 (ja) * | 2005-03-17 | 2006-09-21 | Teijin Limited | 電解質膜 |
| US7754846B2 (en) * | 2005-03-28 | 2010-07-13 | E. I. Du Pont De Nemours And Company | Thermal processes for increasing polyareneazole inherent viscosities |
| WO2006105230A1 (en) * | 2005-03-28 | 2006-10-05 | E. I. Du Pont De Nemours And Company | Process for the production of polyareneazole polymer |
| EP1877602B1 (en) * | 2005-03-28 | 2009-08-26 | E.I. Du Pont De Nemours And Company | Processes for hydrolyzing polyphosphoric acid in shaped articles |
| DE602006019564D1 (de) | 2005-03-28 | 2011-02-24 | Du Pont | Verfahren zur entfernung von phosphor von einer faser oder einem garn |
| WO2006105080A1 (en) * | 2005-03-28 | 2006-10-05 | E.I. Du Pont De Nemours And Company | Processes for increasing polymer inherent viscosity |
| KR20080034830A (ko) * | 2005-03-28 | 2008-04-22 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 측쇄 히드록실 기 및 양이온을 가진 폴리아렌아졸 중합체섬유 |
| DE602006019570D1 (de) * | 2005-03-28 | 2011-02-24 | Du Pont | Verfahren zur entfernung von kationen aus polyarenazol-fasern |
| US7851584B2 (en) * | 2005-03-28 | 2010-12-14 | E. I. Du Pont De Nemours And Company | Process for preparing monomer complexes |
| US7968029B2 (en) * | 2005-03-28 | 2011-06-28 | E. I. Du Pont De Nemours And Company | Processes for hydrolysis of polyphoshoric acid in polyareneazole filaments |
| KR101324822B1 (ko) | 2005-03-28 | 2013-11-01 | 마젤란 시스템즈 인터내셔날, 엘엘시 | 높은 고유 점도 중합체 및 그로부터의 섬유 |
| KR101327714B1 (ko) * | 2005-03-28 | 2013-11-11 | 마젤란 시스템즈 인터내셔날, 엘엘시 | 폴리아렌아졸 실의 제조 방법 |
| DE602006019573D1 (en) * | 2005-03-28 | 2011-02-24 | Du Pont | Fusionsfreie hydrolyse von polyphosphorsäure in multifilament-spun-garnen |
| KR101327706B1 (ko) * | 2005-03-28 | 2013-11-11 | 마젤란 시스템즈 인터내셔날, 엘엘시 | 방사된 실 중의 폴리인산의 고온 표면 가수분해 |
| JP4769291B2 (ja) * | 2005-03-28 | 2011-09-07 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 紡績ヤーン中のポリ燐酸に加水分解を受けさせる方法 |
| EP1879942B1 (en) * | 2005-03-28 | 2008-12-03 | Magellan Systems International, LLC | Processes for preparing high inherent viscosity polyareneazoles using metal powders |
| CN101238164B (zh) * | 2005-03-28 | 2012-10-03 | 纳幕尔杜邦公司 | 制备聚芳并唑聚合物的方法 |
| US7888457B2 (en) * | 2005-04-01 | 2011-02-15 | E. I. Du Pont De Nemours And Company | Process for removing phosphorous from a fiber or yarn |
| US20100015406A1 (en) | 2005-05-16 | 2010-01-21 | Ashok Bhatnagar | Laminated felt articles |
| JP4660287B2 (ja) * | 2005-06-08 | 2011-03-30 | 帝人株式会社 | 剛直系複素環共重合体およびその製造方法 |
| US20070293109A1 (en) * | 2005-06-16 | 2007-12-20 | Ashok Bhatnagar | Composite material for stab, ice pick and armor applications |
| US7687412B2 (en) * | 2005-08-26 | 2010-03-30 | Honeywell International Inc. | Flexible ballistic composites resistant to liquid pick-up method for manufacture and articles made therefrom |
| US7601416B2 (en) * | 2005-12-06 | 2009-10-13 | Honeywell International Inc. | Fragment and stab resistant flexible material with reduced trauma effect |
| WO2007145673A2 (en) * | 2005-12-08 | 2007-12-21 | E. I. Du Pont De Nemours And Company | Matrix free non-woven layer of polypyridazle short fiber |
| EP1973434B1 (en) * | 2005-12-16 | 2010-07-28 | E.I. Du Pont De Nemours And Company | Pipd comfort fabrics and articles made therefrom |
| DE602006014196D1 (de) * | 2005-12-16 | 2010-06-17 | Du Pont | Kleidungsstücke mit einem flexiblen äusseren schalengewebe mit hoher wärmeleistung aus polybenzimidazol- und polypyridobisimidazolfasern |
| WO2007076270A2 (en) * | 2005-12-16 | 2007-07-05 | E. I. Du Pont De Nemours And Company | Garments comprising high strength extreme thermal performance outer shell fabric of polybenzimidazole and polypyridobisimidazole fibers |
| JP5219831B2 (ja) * | 2005-12-16 | 2013-06-26 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリピリドビスイミダゾール／難燃処理されたセルロース繊維の配合物から作られた布帛およびそれから作られた物品 |
| EP1959773B1 (en) * | 2005-12-16 | 2009-11-11 | E.I. Du Pont De Nemours And Company | Thermal performance garments comprising an outer shell fabric of pipd and aramid fibers |
| EP1968407B1 (en) * | 2005-12-16 | 2012-03-14 | E.I. Du Pont De Nemours And Company | Thermal performance garments comprising a bleach tolerant outer shell fabric of polypyridobisimidazole and polybenzobisoxazole fibers |
| EP1963568A2 (en) * | 2005-12-21 | 2008-09-03 | E.I. Du Pont De Nemours And Company | Friction papers containing pipd fibers |
| US7727356B2 (en) * | 2005-12-21 | 2010-06-01 | E.I. Du Pont De Nemours And Company | Polyareneazole/wood pulp and methods of making same |
| US7727357B2 (en) * | 2005-12-21 | 2010-06-01 | E. I. Du Pont De Nemours And Company | Polyareneazole/thermoset pulp and methods of making same |
| EP1963567B1 (en) * | 2005-12-21 | 2010-10-27 | E.I. Du Pont De Nemours And Company | Pipd paper and components made therefrom |
| US7744724B2 (en) * | 2005-12-21 | 2010-06-29 | E.I. Du Pont De Nemours And Company | Polyareneazole/thermoplastic pulp and methods of making same |
| KR101426882B1 (ko) * | 2005-12-21 | 2014-08-06 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폴리피리도비스이미다졸 펄프의 제조 방법 |
| US7727358B2 (en) * | 2005-12-21 | 2010-06-01 | E.I. Du Pont De Nemours And Company | Pulp comprising polypyridobisimidazole and other polymers and methods of making same |
| US7686920B2 (en) * | 2005-12-21 | 2010-03-30 | E.I. Du Pont De Nemours And Company | Fibrillated polypyridobisimidazole floc |
| CN101331271B (zh) * | 2005-12-21 | 2011-08-03 | 纳幕尔杜邦公司 | 包含pipd絮凝物的纸及其制造方法 |
| JP2009521620A (ja) * | 2005-12-21 | 2009-06-04 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Ｐｉｐｄパルプを含んでなる紙およびその製造方法 |
| US20070202331A1 (en) * | 2006-02-24 | 2007-08-30 | Davis Gregory A | Ropes having improved cyclic bend over sheave performance |
| US7642206B1 (en) | 2006-03-24 | 2010-01-05 | Honeywell International Inc. | Ceramic faced ballistic panel construction |
| KR101467588B1 (ko) * | 2006-07-31 | 2014-12-01 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폴리아렌아졸 마이크로섬유를 포함하는 부직 웨브 및 그의 제조 방법 |
| CN101568571B (zh) * | 2006-07-31 | 2013-08-21 | 纳幕尔杜邦公司 | 聚芳唑微纤及其制造方法 |
| US8007202B2 (en) | 2006-08-02 | 2011-08-30 | Honeywell International, Inc. | Protective marine barrier system |
| KR101316496B1 (ko) * | 2006-08-23 | 2013-10-10 | 도요보 가부시키가이샤 | 폴리벤자졸 섬유 및 피리도비스이미다졸 섬유 |
| JP4929921B2 (ja) * | 2006-08-23 | 2012-05-09 | 東洋紡績株式会社 | ポリベンザゾール繊維 |
| US7622405B1 (en) | 2006-09-26 | 2009-11-24 | Honeywell International Inc. | High performance same fiber composite hybrids by varying resin content only |
| US7638193B1 (en) * | 2006-10-10 | 2009-12-29 | E. I. Du Pont De Nemours And Company | Cut-resistant yarns and method of manufacture |
| KR101378290B1 (ko) * | 2006-10-31 | 2014-03-25 | 마젤란 시스템즈 인터내셔날, 엘엘시 | 얀 제조 방법 및 장치 |
| US8652570B2 (en) * | 2006-11-16 | 2014-02-18 | Honeywell International Inc. | Process for forming unidirectionally oriented fiber structures |
| US7358391B1 (en) * | 2006-11-28 | 2008-04-15 | E.I. Du Pont De Nemours And Company | Process for the synthesis of hydroxy aromatic acids |
| US7345195B1 (en) * | 2006-11-28 | 2008-03-18 | E.I. Du Pont De Nemours And Company | Process for the synthesis of 2,5-dihydroxyterephthalic acid |
| US7351856B1 (en) | 2006-11-28 | 2008-04-01 | E.I. Du Pont De Nemours And Company | Process for the synthesis of hydroxy aromatic acids |
| US7355070B1 (en) * | 2006-11-28 | 2008-04-08 | E. I. Du Pont De Nemours And Company | Process for the synthesis of 2,5-dihydroxyterephthalic acid |
| US7339076B1 (en) * | 2006-11-28 | 2008-03-04 | E.I. Du Pont De Nemours And Company | Process for the synthesis of 2,5-dihydroxyterephthalic acid |
| US7335791B1 (en) | 2006-11-28 | 2008-02-26 | E.I. Du Pont De Nemours And Company | Process for the synthesis of hydroxy aromatic acids |
| US7345194B1 (en) | 2006-11-28 | 2008-03-18 | E.I. Du Pont De Nemours And Company | Process for the synthesis of 2,5-dihydroxyterephthalic acid |
| US7378547B1 (en) * | 2006-11-28 | 2008-05-27 | E.I. Du Pont De Nemours And Company | Process for the synthesis of hydroxy aromatic acids |
| US7762175B1 (en) | 2006-11-30 | 2010-07-27 | Honeywell International Inc. | Spaced lightweight composite armor |
| US7794813B2 (en) * | 2006-12-13 | 2010-09-14 | Honeywell International Inc. | Tubular composite structures |
| US20100203273A1 (en) * | 2006-12-13 | 2010-08-12 | Jhrg, Llc | Anti-chafe cable cover |
| KR20090101264A (ko) * | 2006-12-21 | 2009-09-24 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 방향족 산의 에테르의 합성 방법 |
| JP2010513502A (ja) * | 2006-12-21 | 2010-04-30 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | グルタロニトリルからジアミノピリジンを合成する方法 |
| WO2008079225A1 (en) * | 2006-12-21 | 2008-07-03 | E. I. Du Pont De Nemours And Company | Process for the synthesis of ethers of aromatic acids |
| WO2008082500A2 (en) | 2006-12-21 | 2008-07-10 | E.I. Du Pont De Nemours And Company | Process for the synthesis of 2,6-diaminopyridines from glutarimidines |
| KR20090097197A (ko) * | 2006-12-21 | 2009-09-15 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 할로겐화 방향족 이산의 합성 방법 |
| EP2125687B1 (en) * | 2006-12-21 | 2010-08-11 | E. I. Du Pont de Nemours and Company | Process for the synthesis of ethers of aromatic acids |
| US7985825B2 (en) * | 2006-12-21 | 2011-07-26 | E. I. Du Pont De Nemours And Company | Process for the synthesis of ethers of aromatic acids |
| US7994074B1 (en) | 2007-03-21 | 2011-08-09 | Honeywell International, Inc. | Composite ballistic fabric structures |
| US8017529B1 (en) | 2007-03-21 | 2011-09-13 | Honeywell International Inc. | Cross-plied composite ballistic articles |
| US7993478B2 (en) | 2007-03-28 | 2011-08-09 | Honeywell International, Inc. | Method to apply multiple coatings to a fiber web |
| KR20100050524A (ko) | 2007-08-01 | 2010-05-13 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 다이아미노피리딘 및 관련 화합물의 합성 방법 |
| US8256019B2 (en) | 2007-08-01 | 2012-09-04 | Honeywell International Inc. | Composite ballistic fabric structures for hard armor applications |
| JP2010536784A (ja) * | 2007-08-17 | 2010-12-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ３−ヒドロキシグルタロニトリルの合成方法 |
| US7700191B2 (en) * | 2007-08-22 | 2010-04-20 | E.I. Du Pont De Nemours And Company | Flame resistant spun staple yarns made from blends of fibers derived from diamino diphenyl sulfone and high modulus fibers and fabrics and garments made therefrom and methods for making same |
| US8166743B2 (en) * | 2007-08-22 | 2012-05-01 | E.I. Du Pont De Nemours And Company | Spun staple yarns made from blends of rigid-rod fibers and fibers derived from diamino diphenyl sulfone and fabrics and garments made therefrom and methods for making same |
| US7700190B2 (en) * | 2007-08-22 | 2010-04-20 | E.I. Du Pont De Nemours And Company | Flame resistant spun staple yarns made from blends of fibers derived from diamino diphenyl sulfone and textile fibers and fabrics and garments made therefrom and methods for making same |
| US8115007B2 (en) * | 2007-11-27 | 2012-02-14 | E. I. Du Pont De Nemours And Company | Synthesis of diaminodinitropyridine |
| US8143450B1 (en) | 2007-12-18 | 2012-03-27 | E. I. Du Pont De Nemours And Company | Process for the preparation of derivatives of tetraaminobenzene |
| US8003831B1 (en) | 2007-12-18 | 2011-08-23 | E.I. Dupont De Nemours And Company | Process for the synthesis of dihalodinitrobenzenes |
| US7994075B1 (en) | 2008-02-26 | 2011-08-09 | Honeywell International, Inc. | Low weight and high durability soft body armor composite using topical wax coatings |
| US8015617B1 (en) | 2008-05-14 | 2011-09-13 | E. I. Du Pont De Nemours And Company | Ballistic resistant body armor articles |
| KR100962914B1 (ko) | 2008-05-23 | 2010-06-10 | 엘에스전선 주식회사 | 고내열 절연 전선 |
| US7999057B2 (en) | 2008-07-08 | 2011-08-16 | E. I. Du Pont De Nemours And Company | Gas-phase process for the synthesis of diaminopyridines from glutaronitriles |
| WO2010080488A1 (en) | 2008-12-18 | 2010-07-15 | E. I. Du Pont De Nemours And Company | Continuous liquid-phase process for the synthesis of diaminopyridines from glutaronitriles |
| CN102361762A (zh) | 2009-03-20 | 2012-02-22 | 纳幕尔杜邦公司 | 轮胎胎面花纹块组合物 |
| US9562744B2 (en) | 2009-06-13 | 2017-02-07 | Honeywell International Inc. | Soft body armor having enhanced abrasion resistance |
| TW201127805A (en) * | 2009-09-02 | 2011-08-16 | Du Pont | Process for the synthesis of fluorinated ethers of aromatic acids |
| TW201127801A (en) * | 2009-09-02 | 2011-08-16 | Du Pont | Process for the synthesis of fluorinated ethers of aromatic acids |
| TW201127806A (en) * | 2009-09-02 | 2011-08-16 | Du Pont | Process for the synthesis of fluorinated ethers of aromatic acids |
| TW201127809A (en) * | 2009-09-02 | 2011-08-16 | Du Pont | Process for the synthesis of fluorinated ethers of aromatic acids |
| TW201114732A (en) * | 2009-09-02 | 2011-05-01 | Du Pont | Process for the synthesis of fluorinated ethers of aromatic acids |
| WO2011075361A1 (en) | 2009-12-18 | 2011-06-23 | E. I. Du Pont De Nemours And Company | Low noise tire |
| EP2652010A1 (en) | 2010-12-16 | 2013-10-23 | E.I. Du Pont De Nemours And Company | Flame resistant spun staple yarns made from blends of fibers derived from sulfonated polyoxadiazole polymers |
| WO2012082433A1 (en) | 2010-12-16 | 2012-06-21 | E. I. Du Pont De Nemours And Company | Preparation of sulfonated polyoxadiazole polymers |
| CN103261274A (zh) | 2010-12-16 | 2013-08-21 | 纳幕尔杜邦公司 | 磺化聚噁二唑聚合物制品 |
| US9023450B2 (en) | 2011-09-06 | 2015-05-05 | Honeywell International Inc. | High lap shear strength, low back face signature UD composite and the process of making |
| US9023452B2 (en) | 2011-09-06 | 2015-05-05 | Honeywell International Inc. | Rigid structural and low back face signature ballistic UD/articles and method of making |
| US20130059496A1 (en) | 2011-09-06 | 2013-03-07 | Honeywell International Inc. | Low bfs composite and process of making the same |
| US9291433B2 (en) | 2012-02-22 | 2016-03-22 | Cryovac, Inc. | Ballistic-resistant composite assembly |
| US9273418B2 (en) | 2012-05-17 | 2016-03-01 | Honeywell International Inc. | Hybrid fiber unidirectional tape and composite laminates |
| WO2013188328A1 (en) | 2012-06-15 | 2013-12-19 | E. I. Du Pont De Nemours And Company | Sulfonated polyoxadiazole polymers articles |
| US9150693B2 (en) | 2012-06-15 | 2015-10-06 | E I Du Pont De Nemours And Company | Preparation of sulfonated naphthalene polyoxadiazoles polymers |
| CN104508007B (zh) | 2012-06-15 | 2019-07-23 | 纳幕尔杜邦公司 | 磺化萘聚噁二唑聚合物 |
| EP2861789B1 (en) | 2012-06-15 | 2020-09-09 | DuPont Safety & Construction, Inc. | Flame resistant spun staple yarns made from blends of fibers derived from sulfonated naphthalene polyoxadiazole polymers |
| US10132010B2 (en) | 2012-07-27 | 2018-11-20 | Honeywell International Inc. | UHMW PE fiber and method to produce |
| CN104685117B (zh) | 2012-08-06 | 2018-02-02 | 霍尼韦尔国际公司 | 聚合物带材、无纺层压材料、纺织织物和制造它们的方法 |
| US9850596B2 (en) | 2012-08-22 | 2017-12-26 | TJC Polymer Inc. | Composites comprising rigid-rod polymers and graphene nanoparticles and process for making the same |
| US20140082808A1 (en) | 2012-09-21 | 2014-03-27 | E I Du Pont De Nemours And Company | Ballistic resistant body armor articles |
| JP2016505724A (ja) | 2012-12-04 | 2016-02-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 紡績短繊維糸条を含む補強構造体 |
| EP2943358B1 (en) | 2013-01-09 | 2022-06-22 | DuPont Safety & Construction, Inc. | Tire overlay composition |
| US9074321B2 (en) | 2013-09-24 | 2015-07-07 | E I Du Pont De Nemours And Company | Fibrous pulp and use thereof in a composite |
| CN103588703B (zh) * | 2013-11-29 | 2015-08-05 | 中蓝晨光化工研究设计院有限公司 | 一种2,3,5,6-四氨基吡啶磷酸盐的制备方法 |
| WO2015130776A1 (en) | 2014-02-27 | 2015-09-03 | E. I. Du Pont De Nemours And Company | Micropulp-elastomer masterbatches and compounds based thereon |
| US9909240B2 (en) | 2014-11-04 | 2018-03-06 | Honeywell International Inc. | UHMWPE fiber and method to produce |
| US10612189B2 (en) | 2015-04-24 | 2020-04-07 | Honeywell International Inc. | Composite fabrics combining high and low strength materials |
| CN105297166B (zh) * | 2015-11-17 | 2017-12-19 | 中国科学院长春应用化学研究所 | 一种聚酰亚胺纤维及其制备方法 |
| US20170297295A1 (en) | 2016-04-15 | 2017-10-19 | Honeywell International Inc. | Blister free composite materials molding |
| US11059942B2 (en) | 2018-08-21 | 2021-07-13 | University Of Florida Research Foundation, Incorporated | Aromatic polyesters from biosuccinic acid |
| BR112021015554A2 (pt) | 2019-02-06 | 2021-10-05 | Barrday Corp. | Compósito resistente a balística com isocianato bloqueado |
| WO2021225658A2 (en) | 2020-02-06 | 2021-11-11 | Barrday Corp. | Ballistic-resistant composite with maleic anhydride-grafted polypropylene |
| CN111440316A (zh) * | 2020-04-07 | 2020-07-24 | 华南理工大学 | 一种含聚吡啶并咪唑的杂环聚合物的制备方法及其应用 |
| KR20240109246A (ko) | 2021-11-10 | 2024-07-10 | 듀폰 세이프티 앤드 컨스트럭션, 인크. | 부직 섬유 없이 기계적으로 얽힌 직조 직물로 제조된 내탄도성 재료 및 그 제조 방법 |
| CN116969883A (zh) * | 2023-07-29 | 2023-10-31 | 东华大学 | 一种高纯度2,3,5,6-四氨基吡啶-2,5-二羟基对苯二甲酸盐的连续制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH463537A (de) * | 1964-09-02 | 1968-10-15 | Alpine Chemische Ag | Verfahren zur Herstellung von 2,5-Dihydroxy-terephthalsäure |
| US4079039A (en) * | 1974-03-04 | 1978-03-14 | Horizons Research Incorporated | Polyheterocyclic polymers derived from substituted tetraamino pyridines |
| US4002679A (en) * | 1974-08-07 | 1977-01-11 | The United States Of America As Represented By The Secretary Of The Air Force | Preparation of polybenzimidazoles |
| US4533692A (en) * | 1982-09-17 | 1985-08-06 | Sri International | Liquid crystalline polymer compositions, process, and products |
| US5136012A (en) * | 1990-03-23 | 1992-08-04 | United States Of America As Represented By The Secretary Of The Air Force | Dihydroxy-pendant rigid-rod benzobisazole copolymer |
| US5039778A (en) * | 1990-03-23 | 1991-08-13 | The United States Of America As Represented By The Secretary Of The Air Force | Dihydroxy-pendant rigid-rod benzobisazole copolymer |
| US5041522A (en) * | 1990-03-23 | 1991-08-20 | The United States Of America As Represented By The Secretary Of The Air Force | Dihydroxy-pendant rigid-rod benzobisazole polymer |
-
1994
- 1994-04-22 EP EP94915120A patent/EP0696297B1/en not_active Expired - Lifetime
- 1994-04-22 US US08/535,225 patent/US5674969A/en not_active Expired - Lifetime
- 1994-04-22 AT AT94915120T patent/ATE169317T1/de not_active IP Right Cessation
- 1994-04-22 WO PCT/EP1994/001302 patent/WO1994025506A1/en active IP Right Grant
- 1994-04-22 CA CA002161663A patent/CA2161663C/en not_active Expired - Fee Related
- 1994-04-22 DE DE69412250T patent/DE69412250T2/de not_active Expired - Lifetime
- 1994-04-22 CN CN94191918A patent/CN1041208C/zh not_active Expired - Lifetime
- 1994-04-22 KR KR1019950704414A patent/KR100306676B1/ko not_active Expired - Lifetime
- 1994-04-22 ES ES94915120T patent/ES2120042T3/es not_active Expired - Lifetime
- 1994-04-22 JP JP52386794A patent/JP3527740B2/ja not_active Expired - Lifetime
- 1994-04-22 DK DK94915120T patent/DK0696297T3/da active
- 1994-04-26 TW TW083103743A patent/TW283716B/zh active
- 1994-04-28 MX MXPA94003094A patent/MXPA94003094A/es active IP Right Grant
- 1994-04-29 ZA ZA942967A patent/ZA942967B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08509516A (ja) | 1996-10-08 |
| KR100306676B1 (ko) | 2001-11-30 |
| US5674969A (en) | 1997-10-07 |
| EP0696297B1 (en) | 1998-08-05 |
| CA2161663C (en) | 2005-02-15 |
| TW283716B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1996-08-21 |
| JP3527740B2 (ja) | 2004-05-17 |
| DK0696297T3 (da) | 1999-05-10 |
| ATE169317T1 (de) | 1998-08-15 |
| MXPA94003094A (es) | 2003-11-18 |
| ES2120042T3 (es) | 1998-10-16 |
| ZA942967B (en) | 1995-01-19 |
| EP0696297A1 (en) | 1996-02-14 |
| CA2161663A1 (en) | 1994-11-10 |
| CN1121728A (zh) | 1996-05-01 |
| KR960701925A (ko) | 1996-03-28 |
| CN1041208C (zh) | 1998-12-16 |
| WO1994025506A1 (en) | 1994-11-10 |
| DE69412250D1 (de) | 1998-09-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69412250T2 (de) | Pyridobismidazole enthaltendes rigid-rod-Polymer | |
| DE69011458T2 (de) | Polyamidgarn mit hoher Festigkeit und hohem Modul. | |
| DE69027108T2 (de) | Aramidemonofilament und verfahren zur herstellung | |
| DE69611539T2 (de) | Verfahren zur herstellung von filamenten aus regenerierter zellulose | |
| DE60029085T2 (de) | Verfahren zur herstellung von meta-aromatischen polyamidfasern | |
| DE69115346T2 (de) | Verfahren zur Herstellung von Polyketonfasern | |
| DE69024074T2 (de) | Herstellung von Aramidfasern | |
| DE2556883A1 (de) | Aromatische copolyamide, hieraus gefertigte formgegenstaende und verfahren zu deren herstellung | |
| GB2044669A (en) | High young's modulus poly - p - phenylene - terephthalamide fibres | |
| US5093063A (en) | Method of producing polyvinyl alcohol fibers | |
| DE69226086T2 (de) | Aramid-blockcopolymere | |
| DE69921410T2 (de) | Verfahren zur Herstellung von Hochdenier-Filamenten aus thermotropischen Flüssigkristallpolymeren | |
| EP0364893A2 (de) | Vollaromatische Polyamide, Verfahren zu ihrer Herstellung und daraus geformte Gebilde | |
| DE69009825T2 (de) | Verfahren zur Herstellung von Poly(paraphenylenterephthalamid) enthaltenden Zusammensetzungen in der Form eines faserigen Gels und Verfahren zur Erzeugung von aus dieser Zusammensetzung hergestelltem Papier. | |
| DE69516157T2 (de) | Flüssigkristalllösungen basierend auf zellulose und wenigstens einer phosphorsäure | |
| DE68917190T2 (de) | Polyvinylalkoholfaser mit ausgezeichnetem Widerstand gegen heisses Wasser und Verfahren zur Herstellung derselben. | |
| EP0424860A2 (de) | Vollaromatische Polyamide, Verfahren zu ihrer Herstellung und daraus geformte Gebilde | |
| DE69206975T2 (de) | Verfahren zum spinnen von poly(p-phenylen terephthalamid)fasern mit hoher festigkeit und mit hoher bruchdehnung | |
| DE69301605T2 (de) | Verstreckbare hochfeste aramide | |
| EP0647731B1 (de) | Aramidfasern hoher Festigkeit und hohen Titers, Verfahren zu deren Herstellung sowie deren Verwendung | |
| DE69015575T2 (de) | Vollaromatisches Copolyamid und damit hergestellte Artikel. | |
| DE2232504C3 (de) | Fasern aus einem aromatischen Copolyhydrazid und Verfahren zu deren Herstellung | |
| DE2454118C2 (de) | Verfahren zur Herstellung eines hydrophilen Blockcopolymeren und dessen Verwendung | |
| DE69027709T2 (de) | Verfahren zur Herstellung von Fasern mit Verbesserter Hydrolysebeständigkeit. | |
| DE3781316T2 (de) | Metallsalze enthaltendes nylon. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: MAGELLAN SYSTEMS INTERNATIONAL LLC., BETHESDA, MD. |