DE507917C - Production of hydrogen-carbon-oxide mixtures - Google Patents

Production of hydrogen-carbon-oxide mixtures

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Publication number
DE507917C
DE507917C DEI29681D DEI0029681D DE507917C DE 507917 C DE507917 C DE 507917C DE I29681 D DEI29681 D DE I29681D DE I0029681 D DEI0029681 D DE I0029681D DE 507917 C DE507917 C DE 507917C
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DE
Germany
Prior art keywords
oxygen
hydrogen
gases
production
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI29681D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Publication date
Priority to DEI29681D priority Critical patent/DE507917C/en
Application granted granted Critical
Publication of DE507917C publication Critical patent/DE507917C/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C01B3/363—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents characterised by the burner used

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)

Description

Herstellung von Wasserstoff-Kohlenoxyd-Gemischen Es wurde gefunden, daß es möglich ist, Wasserstoff-Kohlenoxyd-Gemische mit oder ohne Gehalt an Stickstoff aus Kohlenwasserstoffeh, insbesondere solchen gasförmiger Art, durch Umsetzung mit geeignet bemessenen .Mengen von Sauerstoff oder Luft oder sauerstoffreicher Luft ohne wesentliche Abscheidung von Ruß zu gewinnen, wenn man die Kohlenwasserstoffe bzw. die die Kohlenwasserstoffe enthaltenden Gase tangential von unten in einen-Raum einführt und den in Rotation befindlichen hochsteigenden Gasen durch zahlreiche, zweckmäßig im Kreise angeordnete Öffnungen, z. B. Düsen, zweckmäßig gleichfalls tangential, Sauerstoff oder sauerstoffhaltige Gase zur partiellen Verbrennung zuführt.Production of hydrogen-carbon oxide mixtures It was found that it is possible to use hydrogen-carbon-oxide mixtures with or without a nitrogen content from hydrocarbons, especially those of the gaseous type, by reaction with appropriately sized amounts of oxygen or air or oxygen-rich air without significant deposition of soot, if you gain the hydrocarbons or the gases containing the hydrocarbons tangentially from below into a room and the rising gases in rotation by numerous, appropriately arranged in a circle openings, for. B. nozzles, also expedient tangentially, oxygen or oxygen-containing gases for partial combustion.

An Hand beiliegender Zeichnung sei diese Arbeitsweise näher erläutert: Die zu zersetzenden Gase, z. B. Methan, werden bei d unter einem gewissen Überdruck tangential in die Vorkammer a eingeblasen und bewegen sich rotierend um das Eisenrohr i, das zugleich als Stütze für den Oberbau dient. Die Gase entspannen sich durch den engen -Ringkanal g in die Verbrennungskammer b. In diese wird gleichzeitig Sauerstoff unter Überdruck aus der Ringleitung /t durch zahlreiche wasserge- i;@@°-I-ST`f83@fl@li£h--- iSt:--.-@s1S. bereits rotierende Gas wird durch den zuge- führten Sauerstoff in noch größere Rotationsgeschwindigkeit versetzt und dabei mit diesem innigst gemischt und gleichzeitig bei -hoher Temperatur verbrannt. Es wird nur so viel -Sauerstoff zugeführt, als zur Erzeugung der gewünschten Verbrennungstemperatur (etwa t 5oo°) erforderlich ist. Das .Methan wird hierbei restlos ohne Rußab-Scheidung in Wasserstoff, KohIenoxyd und s --h-- e r wenig Kohlensäure übergeführt. In Fig. 2 ist die Anordnung der Zuleitungsdüsen für den Sauerstoff bzw. die sauerstoffhaltigen Gase, von oben gesehen, wiedergegeben; hierbei bedeutet h die Sauerstoffringleitung, e sind die tangential in die Verbrennungskammer b eingeführten Sauerstoffdüsen, deren Streuung durch die gestrichelten Linien angedeutet ist.This working method is explained in more detail using the accompanying drawing: The gases to be decomposed, e.g. B. methane, are blown tangentially at d under a certain overpressure into the antechamber a and move rotating around the iron pipe i, which also serves as a support for the superstructure. The gases expand through the narrow ring channel g into the combustion chamber b. At the same time, oxygen is drawn into this under excess pressure Ring line / t through numerous water i; @@ ° -I-ST`f83 @ fl @ li £ h --- iSt: --.- @ s1S. the gas that is already rotating is led oxygen set in an even greater speed of rotation and thereby intimately mixed with it and at the same time burned at -high temperature. Only as much oxygen is supplied as is necessary to generate the desired combustion temperature (about t 500 °). The methane is completely converted into hydrogen, carbon oxide and a little carbonic acid without soot separation. In FIG. 2, the arrangement of the feed nozzles for the oxygen or the oxygen-containing gases, viewed from above, is shown; Here, h means the oxygen ring line, e are the oxygen nozzles introduced tangentially into the combustion chamber b, the scattering of which is indicated by the dashed lines.

Beispiel Durch Verbrennung von 150 m3 durch Regeneration vorgewärmtes Leuchtgas, enthaltend: CO@ 2,0 % CmH" 3,00/0 CO 6,o Q!o H, 52,0 % CHI 340 0,10 6,o °/o mit etwa 50 m3 Sauerstoff in dem oben beschriebenen Ofen erhält man ein Gasgemisch von etwa folgender Zusammensetzung: C O., 2,8 0!o CO 28,7 olo H, 6.1, r % CH, 0,2 % N2 42 0YoExample Light gas preheated by regeneration by burning 150 m3, containing: CO @ 2.0% CmH "3.00 / 0 CO 6, o Q! O H, 52.0% CHI 340 0.10 6, o ° / o with about 50 m3 of oxygen in the furnace described above, a gas mixture of approximately the following composition is obtained: CO, 2.8 % CO 28.7 % H, 6.1% CH, 0.2% N2 42%

Claims (1)

PATRNTANSPRUCH: Verfahren zur Herstellung von stickstofffreien oder stickstoffhaltigen Wasserstoff-Kohlenoxyd-Gemischen aus Kohlenwasserstoffeh, insbesondere solchen gasförmiger Natur, durch partielle Verbrennung mit Sauerstoff oder Luft oder sauerstoffreicher Luft, dadurch gekennzeichnet, daß man die Kohlenwasserstoffe bzw. die Kohlenwasserstoffe enthaltenden Gase tangential in einen Raum einführt und den in Rotation befindlichen Gasen durch zahlreiche, zweckmäßig im Kreise angeordnete öffnungen, zweckmäßig gleichfalls tangential, Sauerstoff oder sauerstoffhaltige Gase zur partiellen Verbrennung zuführt.CLAIM: Process for the production of nitrogen-free or nitrogen-containing hydrogen-carbon oxide mixtures of hydrocarbons, in particular of such a gaseous nature, by partial combustion with oxygen or air or oxygen-rich air, characterized in that the hydrocarbons or introduces the hydrocarbon-containing gases tangentially into a space and the rotating gases by numerous, suitably arranged in a circle Openings, expediently also tangential, oxygen or oxygen-containing Supplies gases for partial combustion.
DEI29681D Production of hydrogen-carbon-oxide mixtures Expired DE507917C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEI29681D DE507917C (en) Production of hydrogen-carbon-oxide mixtures

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Application Number Priority Date Filing Date Title
DEI29681D DE507917C (en) Production of hydrogen-carbon-oxide mixtures

Publications (1)

Publication Number Publication Date
DE507917C true DE507917C (en) 1930-09-22

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1023456B (en) * 1952-08-23 1958-01-30 Frank Joseph Jenny Method and device for generating synthesis gas
DE1041013B (en) * 1954-10-29 1958-10-16 Bataafsche Petroleum Process for the production of gases containing hydrogen and carbon oxides from liquid hydrocarbons
DE1041010B (en) * 1955-05-07 1958-10-16 Basf Ag Process for the continuous implementation of chemical reactions with the formation of gaseous or liquid products
DE1063125B (en) * 1955-08-16 1959-08-13 Helmuth Ehlermann Dipl Ing Process for the physical or chemical treatment and simultaneous air classification of fine material
DE1064934B (en) * 1958-10-28 1959-09-10 Basf Ag Production of alkali cyanide solutions
DE1076091B (en) * 1954-09-28 1960-02-25 Montedison Spa Process for the thermal production of synthesis gases and burners for performing this process
DE1091268B (en) * 1953-09-29 1960-10-20 Texaco Development Corp Device for generating a fuel gas by gasifying a solid, finely divided fuel
DE1122928B (en) * 1955-05-25 1962-02-01 Drahomir Sokol Device for the continuous implementation of chemical reactions
DE1181175B (en) * 1961-05-26 1964-11-12 Wistra Ofenbau Device for carrying out endothermic reactions
DE1226545B (en) * 1959-02-24 1966-10-13 Huettenwerk Oberhausen Ag Process for the production of a mainly carbon monoxide and hydrogen containing, low carbon dioxide gas from hydrocarbons

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1023456B (en) * 1952-08-23 1958-01-30 Frank Joseph Jenny Method and device for generating synthesis gas
DE1091268B (en) * 1953-09-29 1960-10-20 Texaco Development Corp Device for generating a fuel gas by gasifying a solid, finely divided fuel
DE1076091B (en) * 1954-09-28 1960-02-25 Montedison Spa Process for the thermal production of synthesis gases and burners for performing this process
DE1041013B (en) * 1954-10-29 1958-10-16 Bataafsche Petroleum Process for the production of gases containing hydrogen and carbon oxides from liquid hydrocarbons
DE1041010B (en) * 1955-05-07 1958-10-16 Basf Ag Process for the continuous implementation of chemical reactions with the formation of gaseous or liquid products
DE1122928B (en) * 1955-05-25 1962-02-01 Drahomir Sokol Device for the continuous implementation of chemical reactions
DE1063125B (en) * 1955-08-16 1959-08-13 Helmuth Ehlermann Dipl Ing Process for the physical or chemical treatment and simultaneous air classification of fine material
DE1064934B (en) * 1958-10-28 1959-09-10 Basf Ag Production of alkali cyanide solutions
DE1226545B (en) * 1959-02-24 1966-10-13 Huettenwerk Oberhausen Ag Process for the production of a mainly carbon monoxide and hydrogen containing, low carbon dioxide gas from hydrocarbons
DE1181175B (en) * 1961-05-26 1964-11-12 Wistra Ofenbau Device for carrying out endothermic reactions

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