DE4213202A1 - Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren - Google Patents
Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in FeststoffreaktorenInfo
- Publication number
- DE4213202A1 DE4213202A1 DE4213202A DE4213202A DE4213202A1 DE 4213202 A1 DE4213202 A1 DE 4213202A1 DE 4213202 A DE4213202 A DE 4213202A DE 4213202 A DE4213202 A DE 4213202A DE 4213202 A1 DE4213202 A1 DE 4213202A1
- Authority
- DE
- Germany
- Prior art keywords
- sodium
- reaction
- aluminum
- magnesium
- chlorides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000011734 sodium Substances 0.000 title claims abstract description 29
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 title claims abstract description 29
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims abstract description 27
- 229910052708 sodium Inorganic materials 0.000 title claims abstract description 27
- YSTQWZZQKCCBAY-UHFFFAOYSA-L methylaluminum(2+);dichloride Chemical class C[Al](Cl)Cl YSTQWZZQKCCBAY-UHFFFAOYSA-L 0.000 title claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 16
- 239000007787 solid Substances 0.000 title claims description 12
- 238000002360 preparation method Methods 0.000 title claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011777 magnesium Substances 0.000 claims abstract description 12
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 claims 1
- 238000005246 galvanizing Methods 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 239000007790 solid phase Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- HYZXMVILOKSUKA-UHFFFAOYSA-K chloro(dimethyl)alumane;dichloro(methyl)alumane Chemical compound C[Al](C)Cl.C[Al](Cl)Cl HYZXMVILOKSUKA-UHFFFAOYSA-K 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- -1 B. by a stirrer Chemical compound 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010327 methods by industry Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/062—Al linked exclusively to C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4213202A DE4213202A1 (de) | 1992-04-22 | 1992-04-22 | Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren |
| ES93103725T ES2118845T3 (es) | 1992-04-22 | 1993-03-09 | Proceso para la preparacion de trimetilaluminio por reaccion de cloruros de metilaluminio con sodio en reactores de estado solido. |
| DE59308818T DE59308818D1 (de) | 1992-04-22 | 1993-03-09 | Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren |
| EP93103725A EP0566851B1 (de) | 1992-04-22 | 1993-03-09 | Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren |
| AT93103725T ATE169024T1 (de) | 1992-04-22 | 1993-03-09 | Verfahren zur herstellung von trimethylaluminium durch reaktion von methylaluminiumchloriden mit natrium in feststoffreaktoren |
| US08/045,973 US5380898A (en) | 1992-04-22 | 1993-04-09 | Process for preparing trimethylaluminum by reacting methylaluminum chlorides with sodium in solids reactors |
| JP09419793A JP3342913B2 (ja) | 1992-04-22 | 1993-04-21 | トリメチルアルミニウムの製法、ポリオレフィン製造用触媒及びアルミニウム電気鍍金での電解質成分 |
| FI931814A FI105187B (fi) | 1992-04-22 | 1993-04-22 | Menetelmä trimetyylialumiinin valmistamiseksi metyylialumiinikloridien reaktiolla natriumin kanssa kiintoainereaktoreissa |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4213202A DE4213202A1 (de) | 1992-04-22 | 1992-04-22 | Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4213202A1 true DE4213202A1 (de) | 1993-10-28 |
Family
ID=6457224
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4213202A Withdrawn DE4213202A1 (de) | 1992-04-22 | 1992-04-22 | Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren |
| DE59308818T Expired - Fee Related DE59308818D1 (de) | 1992-04-22 | 1993-03-09 | Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59308818T Expired - Fee Related DE59308818D1 (de) | 1992-04-22 | 1993-03-09 | Verfahren zur Herstellung von Trimethylaluminium durch Reaktion von Methylaluminiumchloriden mit Natrium in Feststoffreaktoren |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5380898A (es) |
| EP (1) | EP0566851B1 (es) |
| JP (1) | JP3342913B2 (es) |
| AT (1) | ATE169024T1 (es) |
| DE (2) | DE4213202A1 (es) |
| ES (1) | ES2118845T3 (es) |
| FI (1) | FI105187B (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8066433B2 (en) | 2008-03-14 | 2011-11-29 | Pro-Mart Industries, Inc. | Valve for vacuum storage bag |
| CN114011353B (zh) * | 2021-11-10 | 2022-12-27 | 贵州威顿晶磷电子材料股份有限公司 | 一种高纯三甲基铝制备装置及其使用方法 |
| CN115057879A (zh) * | 2022-07-08 | 2022-09-16 | 安徽亚格盛电子新材料有限公司 | 一种粗品三甲基铝的除氯提纯的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA580631A (en) * | 1959-08-04 | Zosel Kurt | Manufacture of trialkylaluminium compounds | |
| US2619330A (en) * | 1949-09-09 | 1952-11-25 | Willems Peter | Mixing and dispersing device |
| GB767400A (en) * | 1952-05-13 | 1957-02-06 | Ziegler Karl | Process for the manufacture of trialkylaluminium compounds |
| DE916167C (de) * | 1952-05-14 | 1954-08-05 | Dr E H Karl Ziegler Dr | Verfahren zur Herstellung von Aluminiumtrialkylen |
| US2839556A (en) * | 1952-07-28 | 1958-06-17 | Ziegler | Production of aluminum hydrocarbons |
| GB734541A (en) * | 1953-03-05 | 1955-08-03 | May Wright | Improvements in dartboard backboards |
| US2954389A (en) * | 1957-01-18 | 1960-09-27 | Nat Distillers Chem Corp | Preparation of trimethylaluminum |
| GB980765A (en) * | 1962-10-29 | 1965-01-20 | Muanyagipari Ki | Process and equipment for producing triethyl aluminium |
| DE2363888A1 (de) * | 1973-12-21 | 1975-07-03 | Auer Hans Heinrich | Vorrichtung mit rotierenden werkzeugen zur kontinuierlichen behandlung von stoffen in fliessfaehiger form |
| US5015750A (en) * | 1990-10-31 | 1991-05-14 | Texas Alkyls, Inc. | Preparation of trimethylaluminum |
-
1992
- 1992-04-22 DE DE4213202A patent/DE4213202A1/de not_active Withdrawn
-
1993
- 1993-03-09 ES ES93103725T patent/ES2118845T3/es not_active Expired - Lifetime
- 1993-03-09 EP EP93103725A patent/EP0566851B1/de not_active Expired - Lifetime
- 1993-03-09 DE DE59308818T patent/DE59308818D1/de not_active Expired - Fee Related
- 1993-03-09 AT AT93103725T patent/ATE169024T1/de not_active IP Right Cessation
- 1993-04-09 US US08/045,973 patent/US5380898A/en not_active Expired - Fee Related
- 1993-04-21 JP JP09419793A patent/JP3342913B2/ja not_active Expired - Fee Related
- 1993-04-22 FI FI931814A patent/FI105187B/fi active
Also Published As
| Publication number | Publication date |
|---|---|
| EP0566851B1 (de) | 1998-07-29 |
| DE59308818D1 (de) | 1998-09-03 |
| JP3342913B2 (ja) | 2002-11-11 |
| EP0566851A3 (es) | 1994-02-02 |
| US5380898A (en) | 1995-01-10 |
| ES2118845T3 (es) | 1998-10-01 |
| FI931814A0 (fi) | 1993-04-22 |
| FI105187B (fi) | 2000-06-30 |
| JPH06145178A (ja) | 1994-05-24 |
| ATE169024T1 (de) | 1998-08-15 |
| EP0566851A2 (de) | 1993-10-27 |
| FI931814A (fi) | 1993-10-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |